CN105543488A - 一种高砷物料的升华脱砷方法 - Google Patents
一种高砷物料的升华脱砷方法 Download PDFInfo
- Publication number
- CN105543488A CN105543488A CN201511012639.2A CN201511012639A CN105543488A CN 105543488 A CN105543488 A CN 105543488A CN 201511012639 A CN201511012639 A CN 201511012639A CN 105543488 A CN105543488 A CN 105543488A
- Authority
- CN
- China
- Prior art keywords
- arsenic
- minutes
- distillation
- hot blast
- temperature
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229910052785 arsenic Inorganic materials 0.000 title claims abstract description 93
- 238000000034 method Methods 0.000 title claims abstract description 38
- 239000000463 material Substances 0.000 title claims abstract description 18
- 238000000859 sublimation Methods 0.000 title abstract 7
- 230000008022 sublimation Effects 0.000 title abstract 7
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 claims abstract description 33
- 239000002245 particle Substances 0.000 claims abstract description 8
- 239000000428 dust Substances 0.000 claims description 35
- 239000008188 pellet Substances 0.000 claims description 25
- 238000010792 warming Methods 0.000 claims description 16
- 238000004821 distillation Methods 0.000 claims description 14
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 6
- 238000005469 granulation Methods 0.000 claims description 5
- 230000003179 granulation Effects 0.000 claims description 5
- 238000010438 heat treatment Methods 0.000 claims description 4
- 238000009413 insulation Methods 0.000 claims description 3
- 229910052742 iron Inorganic materials 0.000 claims description 3
- 238000001704 evaporation Methods 0.000 claims description 2
- 230000008020 evaporation Effects 0.000 claims description 2
- 239000008187 granular material Substances 0.000 claims description 2
- 229910052751 metal Inorganic materials 0.000 abstract description 10
- 239000003500 flue dust Substances 0.000 abstract description 7
- 238000000926 separation method Methods 0.000 abstract description 6
- 238000004519 manufacturing process Methods 0.000 abstract description 2
- 230000004927 fusion Effects 0.000 abstract 1
- 239000002184 metal Substances 0.000 description 8
- 229910052787 antimony Inorganic materials 0.000 description 5
- 229960002594 arsenic trioxide Drugs 0.000 description 5
- GOLCXWYRSKYTSP-UHFFFAOYSA-N arsenic trioxide Inorganic materials O1[As]2O[As]1O2 GOLCXWYRSKYTSP-UHFFFAOYSA-N 0.000 description 5
- KTTMEOWBIWLMSE-UHFFFAOYSA-N diarsenic trioxide Chemical compound O1[As](O2)O[As]3O[As]1O[As]2O3 KTTMEOWBIWLMSE-UHFFFAOYSA-N 0.000 description 5
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 3
- 238000009835 boiling Methods 0.000 description 3
- 239000003517 fume Substances 0.000 description 3
- 229910052718 tin Inorganic materials 0.000 description 3
- 229910052797 bismuth Inorganic materials 0.000 description 2
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 238000005070 sampling Methods 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 229910000990 Ni alloy Inorganic materials 0.000 description 1
- 238000003723 Smelting Methods 0.000 description 1
- JEMGLEPMXOIVNS-UHFFFAOYSA-N arsenic copper Chemical group [Cu].[As] JEMGLEPMXOIVNS-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000002309 gasification Methods 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 238000005272 metallurgy Methods 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 230000001698 pyrogenic effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000007363 ring formation reaction Methods 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B7/00—Working up raw materials other than ores, e.g. scrap, to produce non-ferrous metals and compounds thereof; Methods of a general interest or applied to the winning of more than two metals
- C22B7/02—Working-up flue dust
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B7/00—Working up raw materials other than ores, e.g. scrap, to produce non-ferrous metals and compounds thereof; Methods of a general interest or applied to the winning of more than two metals
- C22B7/005—Separation by a physical processing technique only, e.g. by mechanical breaking
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Abstract
Description
Claims (7)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201511012639.2A CN105543488B (zh) | 2015-12-31 | 2015-12-31 | 一种从高砷物料中脱砷以回收其中有价金属的方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201511012639.2A CN105543488B (zh) | 2015-12-31 | 2015-12-31 | 一种从高砷物料中脱砷以回收其中有价金属的方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN105543488A true CN105543488A (zh) | 2016-05-04 |
CN105543488B CN105543488B (zh) | 2017-07-21 |
Family
ID=55823044
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201511012639.2A Active CN105543488B (zh) | 2015-12-31 | 2015-12-31 | 一种从高砷物料中脱砷以回收其中有价金属的方法 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN105543488B (zh) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106591598A (zh) * | 2016-12-30 | 2017-04-26 | 耒阳市焱鑫有色金属有限公司 | 一种低熔点合金作浮体精细控制的三氧化二砷升华提纯炉 |
CN107164786A (zh) * | 2017-05-24 | 2017-09-15 | 江西理工大学 | 一种铜电解液沉淀脱杂的方法 |
CN107779608A (zh) * | 2017-11-21 | 2018-03-09 | 红河砷业有限责任公司 | 一种利用高砷烟尘直接生产砷的设备及生产方法 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102517439A (zh) * | 2012-01-10 | 2012-06-27 | 中南大学 | 选择性焙烧分离含锡锌砷复合铁矿中锡、锌、砷的方法 |
CN103952563A (zh) * | 2014-04-25 | 2014-07-30 | 云南锡业集团有限责任公司研究设计院 | 一种白烟尘脱砷的方法 |
CN104593610A (zh) * | 2014-12-30 | 2015-05-06 | 郴州丰越环保科技有限公司 | 含砷烟灰脱砷的方法 |
TW201520342A (zh) * | 2013-10-02 | 2015-06-01 | Outotec Finland Oy | 從煙道灰塵中去除砷及/或銻之方法及工廠 |
-
2015
- 2015-12-31 CN CN201511012639.2A patent/CN105543488B/zh active Active
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102517439A (zh) * | 2012-01-10 | 2012-06-27 | 中南大学 | 选择性焙烧分离含锡锌砷复合铁矿中锡、锌、砷的方法 |
TW201520342A (zh) * | 2013-10-02 | 2015-06-01 | Outotec Finland Oy | 從煙道灰塵中去除砷及/或銻之方法及工廠 |
CN103952563A (zh) * | 2014-04-25 | 2014-07-30 | 云南锡业集团有限责任公司研究设计院 | 一种白烟尘脱砷的方法 |
CN104593610A (zh) * | 2014-12-30 | 2015-05-06 | 郴州丰越环保科技有限公司 | 含砷烟灰脱砷的方法 |
Non-Patent Citations (1)
Title |
---|
魏昶 等: "重有色金属冶炼中砷的脱除与回收", 《有色金属》 * |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106591598A (zh) * | 2016-12-30 | 2017-04-26 | 耒阳市焱鑫有色金属有限公司 | 一种低熔点合金作浮体精细控制的三氧化二砷升华提纯炉 |
CN106591598B (zh) * | 2016-12-30 | 2017-10-13 | 耒阳市焱鑫有色金属有限公司 | 一种低熔点合金作浮体精细控制的三氧化二砷升华提纯炉 |
CN107164786A (zh) * | 2017-05-24 | 2017-09-15 | 江西理工大学 | 一种铜电解液沉淀脱杂的方法 |
CN107164786B (zh) * | 2017-05-24 | 2019-03-15 | 江西理工大学 | 一种铜电解液沉淀脱杂的方法 |
CN107779608A (zh) * | 2017-11-21 | 2018-03-09 | 红河砷业有限责任公司 | 一种利用高砷烟尘直接生产砷的设备及生产方法 |
Also Published As
Publication number | Publication date |
---|---|
CN105543488B (zh) | 2017-07-21 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN105543488A (zh) | 一种高砷物料的升华脱砷方法 | |
JPH11310832A (ja) | 製鋼廃棄物の金属酸化物の処理法 | |
CN105648228B (zh) | 用于处理含铅锌冶炼渣的转底炉 | |
US3448973A (en) | Apparatus for purifying metals and recovery of metal products therefrom | |
CN101412538A (zh) | 从含砷金精矿粉焙烧烟尘中提取三氧化二砷的方法 | |
CN109136576A (zh) | 一种含砷烟尘脱除砷的方法 | |
CN104451188B (zh) | 一种真空处理脆硫铅锑矿分离铅锑的方法 | |
CN104451171A (zh) | 一种含砷烟尘流态化脱砷的方法 | |
US2290843A (en) | Method of recovering manganese | |
CN106319232A (zh) | 处理锌挥发窑渣的方法和系统 | |
CN104818384A (zh) | 一种锌锡合金粉真空还原分离锌和锡的方法 | |
CN108300865A (zh) | 一种含砷烟尘中铅锌砷的提取方法 | |
US4055621A (en) | Process for obtaining titanium tetrachloride, chlorine and iron oxide from ilmenite | |
CN107574305A (zh) | 一种高砷铅冰铜综合回收铜和硫工艺 | |
JP7151404B2 (ja) | 酸化亜鉛鉱の製造方法 | |
WO2017113267A1 (zh) | 一种高砷物料的升华脱砷方法 | |
CN108138260A (zh) | 由含铜和含硫的材料制备各种金属及其衍生物的方法 | |
CN205907330U (zh) | 直接还原铅渣的处理系统 | |
CA2966706C (en) | Treatment of complex sulfide concentrate | |
JPS60128228A (ja) | 鉄鋼ダストの還元焙焼方法 | |
CN102586611A (zh) | 铅锑水渣电炉分段控温回收铅、锑、锌、锡、铟 | |
CN106957958A (zh) | 一种低品位含铬型钒钛磁铁矿钙化氧化‑浸出提钒的方法 | |
CN206256099U (zh) | 处理铁矾渣和锌挥发窑渣的系统 | |
CN103834819A (zh) | 一种含高氯和氟的锌物料直接法生产高等级氧化锌的方法 | |
DE1758715A1 (de) | Kontinuierliches Verfahren zur Gewinnung von hochhaltigem Zinkoxyd aus zinkhaltigen Mineralien |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
GR01 | Patent grant | ||
TR01 | Transfer of patent right |
Effective date of registration: 20180115 Address after: 421800 East Deer neighborhood committee of Leiyang City, Leiyang City, Hunan Province, East Deer neighborhood committee Patentee after: YANXIN ENVIRONMENTAL PROTECTION TECHNOLOGY Co.,Ltd. Address before: 421800 Hunan city of Hengyang province Leiyang city Chong Xiang ao Village stone Patentee before: LEIYANG YANXIN NON-FERROUS METALS Co.,Ltd. |
|
TR01 | Transfer of patent right | ||
TR01 | Transfer of patent right | ||
TR01 | Transfer of patent right |
Effective date of registration: 20220302 Address after: 421817 dashichong, Aoshan village, Dashi Township, Leiyang City, Hengyang City, Hunan Province Patentee after: LEIYANG YANXIN NON-FERROUS METALS Co.,Ltd. Address before: 421800 16 groups of Donglu neighborhood committees in Leiyang, Hunan Patentee before: YANXIN ENVIRONMENTAL PROTECTION TECHNOLOGY Co.,Ltd. |
|
PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: A method for removing arsenic from high arsenic materials to recover valuable metals Effective date of registration: 20230811 Granted publication date: 20170721 Pledgee: Hunan Leiyang Rural Commercial Bank Co.,Ltd. Pledgor: LEIYANG YANXIN NON-FERROUS METALS Co.,Ltd. Registration number: Y2023980051856 |
|
PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
PC01 | Cancellation of the registration of the contract for pledge of patent right |
Granted publication date: 20170721 Pledgee: Hunan Leiyang Rural Commercial Bank Co.,Ltd. Pledgor: LEIYANG YANXIN NON-FERROUS METALS Co.,Ltd. Registration number: Y2023980051856 |
|
PC01 | Cancellation of the registration of the contract for pledge of patent right | ||
PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: A method for removing arsenic from high arsenic materials to recover valuable metals Granted publication date: 20170721 Pledgee: Hunan Leiyang Rural Commercial Bank Co.,Ltd. Pledgor: LEIYANG YANXIN NON-FERROUS METALS Co.,Ltd. Registration number: Y2024980009661 |
|
PE01 | Entry into force of the registration of the contract for pledge of patent right |