CN105489264B - 一种复合聚苯胺导电材料及其制备方法 - Google Patents
一种复合聚苯胺导电材料及其制备方法 Download PDFInfo
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- CN105489264B CN105489264B CN201510892460.4A CN201510892460A CN105489264B CN 105489264 B CN105489264 B CN 105489264B CN 201510892460 A CN201510892460 A CN 201510892460A CN 105489264 B CN105489264 B CN 105489264B
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- Prior art keywords
- parts
- conductive material
- composite
- ether
- methylpyrrolidone
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Links
- 239000002131 composite material Substances 0.000 title claims abstract description 66
- 239000004020 conductor Substances 0.000 title claims abstract description 43
- -1 polyphenylene Polymers 0.000 title claims abstract description 38
- 229920000265 Polyparaphenylene Polymers 0.000 title claims abstract description 37
- 150000001412 amines Chemical class 0.000 title claims abstract description 37
- 238000002360 preparation method Methods 0.000 title claims abstract description 17
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims abstract description 63
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical class CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 claims abstract description 48
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical class CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 claims abstract description 31
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims abstract description 29
- 229920000767 polyaniline Polymers 0.000 claims abstract description 26
- 229920003210 poly(4-hydroxy benzoic acid) Polymers 0.000 claims abstract description 22
- 229920001230 polyarylate Polymers 0.000 claims abstract description 22
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims abstract description 22
- 239000002253 acid Substances 0.000 claims abstract description 21
- 239000004696 Poly ether ether ketone Substances 0.000 claims abstract description 20
- 239000012528 membrane Substances 0.000 claims abstract description 20
- 229920002530 polyetherether ketone Polymers 0.000 claims abstract description 20
- 229930185605 Bisphenol Natural products 0.000 claims abstract description 15
- FEPBITJSIHRMRT-UHFFFAOYSA-N 4-hydroxybenzenesulfonic acid Chemical compound OC1=CC=C(S(O)(=O)=O)C=C1 FEPBITJSIHRMRT-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000011521 glass Substances 0.000 claims abstract description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 10
- 238000005266 casting Methods 0.000 claims description 9
- 239000000203 mixture Substances 0.000 claims description 9
- 238000003756 stirring Methods 0.000 claims description 9
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 5
- 239000000463 material Substances 0.000 claims description 5
- ZHNUHDYFZUAESO-UHFFFAOYSA-N Formamide Chemical compound NC=O ZHNUHDYFZUAESO-UHFFFAOYSA-N 0.000 claims description 4
- MTZQAGJQAFMTAQ-UHFFFAOYSA-N ethyl benzoate Chemical compound CCOC(=O)C1=CC=CC=C1 MTZQAGJQAFMTAQ-UHFFFAOYSA-N 0.000 claims description 2
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 claims 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims 1
- 239000005864 Sulphur Substances 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 6
- 238000004519 manufacturing process Methods 0.000 abstract description 2
- 239000004615 ingredient Substances 0.000 abstract 1
- 229940106691 bisphenol a Drugs 0.000 description 7
- 230000000052 comparative effect Effects 0.000 description 5
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 5
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 3
- SRSXLGNVWSONIS-UHFFFAOYSA-N benzenesulfonic acid Chemical compound OS(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-N 0.000 description 3
- 229940092714 benzenesulfonic acid Drugs 0.000 description 3
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- 239000004721 Polyphenylene oxide Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 229920000547 conjugated polymer Polymers 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 229920000570 polyether Polymers 0.000 description 2
- 230000004580 weight loss Effects 0.000 description 2
- 239000007848 Bronsted acid Substances 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- MVIOINXPSFUJEN-UHFFFAOYSA-N benzenesulfonic acid;hydrate Chemical compound O.OS(=O)(=O)C1=CC=CC=C1 MVIOINXPSFUJEN-UHFFFAOYSA-N 0.000 description 1
- 238000005253 cladding Methods 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 125000004494 ethyl ester group Chemical group 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 238000003754 machining Methods 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 229960003742 phenol Drugs 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 229920006389 polyphenyl polymer Polymers 0.000 description 1
- 150000004040 pyrrolidinones Chemical class 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
- H01B1/06—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances
- H01B1/12—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances organic substances
- H01B1/124—Intrinsically conductive polymers
- H01B1/128—Intrinsically conductive polymers comprising six-membered aromatic rings in the main chain, e.g. polyanilines, polyphenylenes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L79/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen with or without oxygen or carbon only, not provided for in groups C08L61/00 - C08L77/00
- C08L79/02—Polyamines
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B13/00—Apparatus or processes specially adapted for manufacturing conductors or cables
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/04—Antistatic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
Abstract
Description
产品名称 | 导电率(S/cm) | 重量损失%(600℃下) | 电导率有所波动温度(℃) | 表面电阻(Ω) |
实施例1 | 2.01 | 6.4 | 392 | 8.9×103 |
实施例2 | 2.03 | 6.2 | 395 | 8.8×103 |
实施例3 | 2.05 | 5.5 | 398 | 8.7×103 |
实施例4 | 2.1 | 4.9 | 410 | 8.5×103 |
实施例5 | 2.05 | 5.7 | 403 | 8.8×103 |
对照例1 | 2.04 | 12.4 | 281 | 8.8×103 |
对照例2 | 2.05 | 5.8 | 387 | 1.01×104 |
Claims (5)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201510892460.4A CN105489264B (zh) | 2015-12-08 | 2015-12-08 | 一种复合聚苯胺导电材料及其制备方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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CN201510892460.4A CN105489264B (zh) | 2015-12-08 | 2015-12-08 | 一种复合聚苯胺导电材料及其制备方法 |
Publications (2)
Publication Number | Publication Date |
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CN105489264A CN105489264A (zh) | 2016-04-13 |
CN105489264B true CN105489264B (zh) | 2017-08-29 |
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CN201510892460.4A Expired - Fee Related CN105489264B (zh) | 2015-12-08 | 2015-12-08 | 一种复合聚苯胺导电材料及其制备方法 |
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CN (1) | CN105489264B (zh) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108485232A (zh) * | 2018-05-08 | 2018-09-04 | 温州市赢创新材料技术有限公司 | 一种有机导电聚合物改性质子膜及其制备方法 |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN100381485C (zh) * | 2005-01-25 | 2008-04-16 | 中国科学院化学研究所 | 导电导磁聚苯胺复合微球及其制备方法 |
CN101280094A (zh) * | 2008-05-27 | 2008-10-08 | 厦门大学 | 具生物活性水凝胶-导电聚合物纳米复合材料及合成方法 |
DE102010012180A1 (de) * | 2010-03-19 | 2011-09-22 | Heraeus Clevios Gmbh | Sulfonierte Polyketone als Gegenion leitfähiger Polymere |
CN104962050B (zh) * | 2015-06-16 | 2016-08-17 | 中原工学院 | 以聚苯胺为导电剂的多相复合导电材料的制备方法 |
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2015
- 2015-12-08 CN CN201510892460.4A patent/CN105489264B/zh not_active Expired - Fee Related
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Publication number | Publication date |
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CN105489264A (zh) | 2016-04-13 |
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Inventor after: Bie Mimai Inventor after: Fan Meifen Inventor before: Zheng Chunqiu |
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Effective date of registration: 20170710 Address after: 350208 Fuzhou Province, Changle City, the town of crane on the river, the village of No. 16 Applicant after: Jiang Yu Address before: Zhujiang Road Wuzhong District Mudu town of Suzhou city in Jiangsu province 215000 No. 999 building 3 room B228 Applicant before: SUZHOU XINDEJIE ELECTRONICS Co.,Ltd. |
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Effective date of registration: 20170726 Address after: 350208 Fuzhou Province, Changle City, the town of crane on the river, the village of No. 16 Applicant after: Li Liexiong Address before: 350208 Fuzhou Province, Changle City, the town of crane on the river, the village of No. 16 Applicant before: Jiang Yu |
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Address after: 435500 two groups of egg ridge village, bitter bamboo township, Huangmei County, Huanggang, Hubei Patentee after: Li Liexiong Address before: 350208 16 Yun Jiang Village, Heshang Town, Changle City, Fuzhou, Fujian Patentee before: Li Liexiong |
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Effective date of registration: 20190320 Address after: 213000, No. five ho he road, West Taihu science and Technology Industrial Park, Changzhou, Jiangsu, to run five buildings. Patentee after: Jiangsu wit Patent Operation Co.,Ltd. Address before: 435500 two groups of egg ridge village, bitter bamboo township, Huangmei County, Huanggang, Hubei Patentee before: Li Liexiong |
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Effective date of registration: 20190416 Address after: 19 / F, Li Lin Building, 93-107 Lockhart Road, Wanchai, Hongkong, China Patentee after: Jinyao Technology Co.,Ltd. Address before: 213000, No. five ho he road, West Taihu science and Technology Industrial Park, Changzhou, Jiangsu, to run five buildings. Patentee before: Jiangsu wit Patent Operation Co.,Ltd. |
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Effective date of registration: 20190429 Address after: No. 601, Changjiang East Road, Huaiyin District, Huaian, Jiangsu Patentee after: Huaian Core Storage Integrated Circuit Co.,Ltd. Address before: 19 / F, Li Lin Building, 93-107 Lockhart Road, Wanchai, Hongkong, China Patentee before: Jinyao Technology Co.,Ltd. |
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Effective date of registration: 20210512 Address after: 528000 2nd floor, No.33, Ronggang Road, Ronggui Desheng neighborhood committee, Shunde District, Foshan City, Guangdong Province Patentee after: Foshan Hengyuan Electronics Co.,Ltd. Address before: No. 601, East Changjiang Road, Huaiyin District, Huai'an City, Jiangsu Province 213300 Patentee before: Huaian Core Storage Integrated Circuit Co.,Ltd. |
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Granted publication date: 20170829 Termination date: 20211208 |