CN105419069A - 一种高耐磨高回弹性橡塑鞋底材料及其制备方法 - Google Patents

一种高耐磨高回弹性橡塑鞋底材料及其制备方法 Download PDF

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CN105419069A
CN105419069A CN201510867778.7A CN201510867778A CN105419069A CN 105419069 A CN105419069 A CN 105419069A CN 201510867778 A CN201510867778 A CN 201510867778A CN 105419069 A CN105419069 A CN 105419069A
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谢志东
朱婉茹
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Fujian Jinjiang Dongfeng Shoes & Plastic Co Ltd
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    • C08J9/10—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent developing nitrogen, the blowing agent being a compound containing a nitrogen-to-nitrogen bond
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Abstract

本发明公开一种高耐磨高回弹性橡塑鞋底材料极其制备方法，属于橡塑鞋材加工技术领域，所述高耐磨高回弹性橡塑鞋底材料由以下重量百分比的原料组成：VA含量为26％的EVA25％-35％、VA含量为40％的EVA10％-20％、三元乙丙橡胶5％-15％、异戊二烯橡胶2％-8％、聚烯烃弹性体POE5％-15％、热塑性橡胶SEBS5％-10％、滑石粉2％-6％、耐磨剂5％-15％、高活性氧化锌1％-3％、硬脂酸锌0.5％-1.5％、硬脂酸0.5％-1.5％、架桥剂DCP0.5％-1.5％、偶氮二甲酰胺1％-3％。其制备方法包括密炼、开炼、造粒等步骤，制备工艺合理简单。通过改进原材料的配方含量及合理的工艺设计，使所述橡塑鞋底材料具有高耐磨、高回弹性，且可回收再利用。

Description

一种高耐磨高回弹性橡塑鞋底材料及其制备方法
技术领域
本发明属于橡塑鞋材加工技术领域，特别是一种高耐磨高回弹性橡塑鞋底材料的生产配方及其制备方法。
背景技术
随着人们对生活要求的提高，当今鞋材技术的发展及品质不断被要求提高，鞋底的功能性直接制约着鞋材的好坏，现有市场上的鞋底存在诸多问题，其中较为常见的是弹性不好，易变形，且耐磨度较差，易断裂，使得鞋底的寿命大大的降低。
发明内容
本发明的目的在于正对上述现有技术的不足之处而提供一种高耐磨高回弹性橡塑鞋底材料及其制备方法。
本发明实现上述目的所采取的技术方案是：一种高耐磨高回弹性橡塑鞋底材料，由以下重量百分比的原料组成：VA含量为26％的EVA25％-35％、VA含量为40％的EVA10％-20％、三元乙丙橡胶5％-15％、异戊二烯橡胶2％-8％、聚烯烃弹性体POE5％-15％、热塑性橡胶SEBS5％-10％、滑石粉2％-6％、耐磨剂5％-15％、高活性氧化锌1％-3％、硬脂酸锌0.5％-1.5％、硬脂酸0.5％-1.5％、架桥剂DCP0.5％-1.5％、偶氮二甲酰胺1％-3％。
一种高耐磨高回弹性橡塑鞋底材料的制备方法，包括以下几个步骤：
A、称取上述重量百分比的原料组份备用，分别将VA含量为26％的EVA、VA含量为40％的EVA、三元乙丙橡胶、异戊二烯橡胶、聚烯烃弹性体POE、热塑性橡胶SEBS、滑石粉、耐磨剂、高活性氧化锌、硬脂酸锌、硬脂酸混合，加入密炼机进行密炼，密炼控制温度为80℃-85℃，持续时间20min-30min，继而调整密炼温度为90℃-95℃，进行翻料操作，持续时间5min-6min，再调整密炼温度为95℃-100℃，持续时间10min-15min，得到混合料一；
B、将混合料一进行翻料，加入架桥剂DCP、偶氮二甲酰胺，继续翻料持续时间7min-8min，调整密炼温度为110℃-120℃，再次进行翻料，持续时间5min-6min，调整密炼温度为125℃-130℃，密炼时间持续9min-10min，得到混合料二；
C、混合料二密炼结束后，倒入开炼机进行开练步骤，开练控制温度为75℃-80℃，开练步骤中将混合料二打薄3次，开炼机滚轮间隙为2mm-3mm，得到混合料三；
D、将混合料三进行造粒步骤，采用一次射出成型工艺，一次射出成型时控制温度为175℃-185℃，时间为7min，得到具有高耐磨高回弹性橡塑鞋底材料。
本发明的有益效果为：
1、鞋底的材料配方科学合理，成本低且制备工艺简单；
2、鞋底材料可再回收利用，具有高耐磨、高回弹性；
3、由本专利的鞋底材料生产的鞋底耐弯折度高，而且比重较轻；
4、由本专利的鞋底材料生产的鞋底具有舒适性好、使用寿命长的特性。
具体实施方式
实施例1
本实施例的一种高耐磨高回弹性橡塑鞋底材料，由以下重量百分比的原料组成：VA含量为26％的EVA30份、VA含量为40％的EVA15份、三元乙丙橡胶10份、异戊二烯橡胶5份、聚烯烃弹性体POE10份、热塑性橡胶SEBS8份、滑石粉5份、耐磨剂10份、高活性氧化锌2份、硬脂酸锌1份、硬脂酸1份、架桥剂DCP1份、偶氮二甲酰胺2份。
本发明上述一种高耐磨高回弹性橡塑鞋底材料的制备方法如下：
A、称取上述重量百分比的原料组份备用，分别将VA含量为26％的EVA、VA含量为40％的EVA、三元乙丙橡胶、异戊二烯橡胶、聚烯烃弹性体POE、热塑性橡胶SEBS、滑石粉、耐磨剂、高活性氧化锌、硬脂酸锌、硬脂酸混合，加入密炼机进行密炼，密炼控制温度为80℃-85℃，持续时间20min-30min，继而调整密炼温度为90℃-95℃，进行翻料操作，持续时间5min-6min，再调整密炼温度为95℃-100℃，持续时间10min-15min，得到混合料一；
B、将混合料一进行翻料，加入架桥剂DCP、偶氮二甲酰胺，继续翻料持续时间7min-8min，调整密炼温度为110℃-120℃，再次进行翻料，持续时间5min-6min，调整密炼温度为125℃-130℃，密炼时间持续9min-10min，得到混合料二；
C、混合料二密炼结束后，倒入开炼机进行开练步骤，开练控制温度为75℃-80℃，开练步骤中将混合料二打薄3次，开炼机滚轮间隙为2mm-3mm，得到混合料三；
D、将混合料三进行造粒步骤，采用一次射出成型工艺，一次射出成型时控制温度为175℃-185℃，时间为7min，得到具有高耐磨高回弹性橡塑鞋底材料。
实施例2
本实施例的一种高耐磨高回弹性橡塑鞋底材料，由以下重量百分比的原料组成：VA含量为26％的EVA25份、VA含量为40％的EVA20份、三元乙丙橡胶5份、异戊二烯橡胶8份、聚烯烃弹性体POE15份、热塑性橡胶SEBS8份、滑石粉4份、耐磨剂8份、高活性氧化锌3份、硬脂酸锌0.5份、硬脂酸0.5份、架桥剂DCP1.5份、偶氮二甲酰胺1.5份。
上述一种高耐磨高回弹性橡塑鞋底材料的制备方法同实施例1。
实施例3
本实施例的一种高耐磨高回弹性橡塑鞋底材料，由以下重量百分比的原料组成：VA含量为26％的EVA35份、VA含量为40％的EVA10份、三元乙丙橡胶12份、异戊二烯橡胶3份、聚烯烃弹性体POE6份、热塑性橡胶SEBS10份、滑石粉3份、耐磨剂13份、高活性氧化锌3份、硬脂酸锌1.5份、硬脂酸1.5份、架桥剂DCP1份、偶氮二甲酰胺1份。
上述一种高耐磨高回弹性橡塑鞋底材料的制备方法同实施例1。
将由三种实施例得到的鞋底材料经生产制得的鞋底进行检测，结果显示鞋底性能如下：
1、硬度：58-63°；
2、DIN指数：≤100mm3；
3、回弹性：≥50％；
4、密度：≤0.4mg/mm3；
5、耐折指数：≥6万次。

Claims (2)

1.一种高耐磨高回弹性橡塑鞋底材料，其特征在于：由以下重量百分比的原料组成：VA含量为26％的EVA25％-35％、VA含量为40％的EVA10％-20％、三元乙丙橡胶5％-15％、异戊二烯橡胶2％-8％、聚烯烃弹性体POE5％-15％、热塑性橡胶SEBS5％-10％、滑石粉2％-6％、耐磨剂5％-15％、高活性氧化锌1％-3％、硬脂酸锌0.5％-1.5％、硬脂酸0.5％-1.5％、架桥剂DCP0.5％-1.5％、偶氮二甲酰胺1％-3％。
2.一种高耐磨高回弹性橡塑鞋底材料的制备方法，其特征在于：包括以下几个步骤：
A、称取如权利要求1所述的重量百分比的原料组份备用，分别将VA含量为26％的EVA、VA含量为40％的EVA、三元乙丙橡胶、异戊二烯橡胶、聚烯烃弹性体POE、热塑性橡胶SEBS、滑石粉、耐磨剂、高活性氧化锌、硬脂酸锌、硬脂酸混合，加入密炼机进行密炼，密炼控制温度为80℃-85℃，持续时间20min-30min，继而调整密炼温度为90℃-95℃，进行翻料操作，持续时间5min-6min，再调整密炼温度为95℃-100℃，持续时间10min-15min，得到混合料一；
B、将所述混合料一进行翻料，加入架桥剂DCP、偶氮二甲酰胺，继续翻料持续时间7min-8min，调整密炼温度为110℃-120℃，再次进行翻料，持续时间5min-6min，调整密炼温度为125℃-130℃，密炼时间持续9min-10min，得到混合料二；
C、所述混合料二密炼结束后，倒入开炼机进行开练步骤，开练控制温度为75℃-80℃，开练步骤中将混合料二打薄3次，开炼机滚轮间隙为2mm-3mm，得到混合料三；
D、将所述混合料三进行造粒步骤，采用一次射出成型工艺，一次射出成型时控制温度为175℃-185℃，时间为7min，得到具有高耐磨高回弹性橡塑鞋底材料。
CN201510867778.7A 2015-12-02 2015-12-02 一种高耐磨高回弹性橡塑鞋底材料及其制备方法 Pending CN105419069A (zh)

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Cited By (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106243535A (zh) * 2016-08-19 2016-12-21 许文谈 一种超轻橡胶发泡胶粒及其制备方法
CN107746482A (zh) * 2017-01-18 2018-03-02 泉州嘉泰鞋业有限公司 橡胶微发泡注射大底及其制造方法
CN107936448A (zh) * 2017-12-07 2018-04-20 福建省安源橡胶科技有限公司 鞋材专用模内压一体成型橡塑片及其制作工艺
CN108359155A (zh) * 2018-03-16 2018-08-03 唐旭 一种弹性组合物及应用该弹性组合物的鞋
CN108440826A (zh) * 2018-02-05 2018-08-24 林雅诗 一种具有高耐磨的橡塑复合材料及其制备方法
CN108864556A (zh) * 2018-04-09 2018-11-23 广东国立科技股份有限公司 一种抗冲击的eva发泡鞋材及其制备方法
CN109456529A (zh) * 2018-03-09 2019-03-12 乔丹体育股份有限公司 一种运动鞋鞋底材料
CN110615994A (zh) * 2019-09-12 2019-12-27 福建鸿星尔克体育用品有限公司 一种弹力减震运动鞋底及其制备工艺
CN110845787A (zh) * 2019-11-30 2020-02-28 晋江市志协鞋塑有限公司 高回弹性改性eva材料、高回弹性eva鞋底及其制作方法
CN110845820A (zh) * 2019-12-16 2020-02-28 泉州师范学院 一种轻质高回弹sebs发泡鞋底的制备方法
CN111923525A (zh) * 2020-09-23 2020-11-13 歌尔股份有限公司 振膜和发声装置
CN112029181A (zh) * 2020-08-07 2020-12-04 福建鸿星尔克体育用品有限公司 一种高弹透光材料及其制备方法和采用该材料制备的鞋底
CN113133567A (zh) * 2020-01-17 2021-07-20 图特成艾索托纳公司 鞋底、靴子及凉鞋
CN113881130A (zh) * 2021-11-08 2022-01-04 安踏（中国）有限公司 一种高耐磨的鞋用eva发泡材料及其制备方法
JP2022187476A (ja) * 2021-06-07 2022-12-19 李長榮化學工業股▲ふん▼有限公司 架橋性及び発泡性組成物、それによって得られる発泡体、発泡のための組成物並びにその使用
US11737512B2 (en) 2016-11-04 2023-08-29 Totes Isotoner Corporation Footwear sole, boot and sandal

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103205054A (zh) * 2013-04-28 2013-07-17 泰亚鞋业股份有限公司 一种射出发泡橡塑运动鞋鞋底及其制造方法
CN104403192A (zh) * 2014-12-25 2015-03-11 贵人鸟股份有限公司 柔软高耐磨橡塑射出发泡材料
CN104448529A (zh) * 2014-12-25 2015-03-25 贵人鸟股份有限公司 柔软高耐磨橡塑射出发泡材料的制作工艺

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103205054A (zh) * 2013-04-28 2013-07-17 泰亚鞋业股份有限公司 一种射出发泡橡塑运动鞋鞋底及其制造方法
CN104403192A (zh) * 2014-12-25 2015-03-11 贵人鸟股份有限公司 柔软高耐磨橡塑射出发泡材料
CN104448529A (zh) * 2014-12-25 2015-03-25 贵人鸟股份有限公司 柔软高耐磨橡塑射出发泡材料的制作工艺

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
大石不二夫: "《高分子材料实用技术》", 31 October 1985 *
王高潮: "《材料科学与工程导论》", 31 January 2006 *

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CN106243535A (zh) * 2016-08-19 2016-12-21 许文谈 一种超轻橡胶发泡胶粒及其制备方法
US11737512B2 (en) 2016-11-04 2023-08-29 Totes Isotoner Corporation Footwear sole, boot and sandal
CN107746482A (zh) * 2017-01-18 2018-03-02 泉州嘉泰鞋业有限公司 橡胶微发泡注射大底及其制造方法
CN107936448A (zh) * 2017-12-07 2018-04-20 福建省安源橡胶科技有限公司 鞋材专用模内压一体成型橡塑片及其制作工艺
CN108440826A (zh) * 2018-02-05 2018-08-24 林雅诗 一种具有高耐磨的橡塑复合材料及其制备方法
CN109456529A (zh) * 2018-03-09 2019-03-12 乔丹体育股份有限公司 一种运动鞋鞋底材料
CN108359155A (zh) * 2018-03-16 2018-08-03 唐旭 一种弹性组合物及应用该弹性组合物的鞋
CN108864556A (zh) * 2018-04-09 2018-11-23 广东国立科技股份有限公司 一种抗冲击的eva发泡鞋材及其制备方法
CN110615994A (zh) * 2019-09-12 2019-12-27 福建鸿星尔克体育用品有限公司 一种弹力减震运动鞋底及其制备工艺
CN110845787A (zh) * 2019-11-30 2020-02-28 晋江市志协鞋塑有限公司 高回弹性改性eva材料、高回弹性eva鞋底及其制作方法
CN110845820A (zh) * 2019-12-16 2020-02-28 泉州师范学院 一种轻质高回弹sebs发泡鞋底的制备方法
CN113133567A (zh) * 2020-01-17 2021-07-20 图特成艾索托纳公司 鞋底、靴子及凉鞋
EP3850977A1 (en) * 2020-01-17 2021-07-21 Totes Isotoner Corporation Footwear sole, boot and sandal
AU2021200171B2 (en) * 2020-01-17 2023-04-20 Totes Isotoner Corporation Footwear sole, boot and sandal
CN112029181A (zh) * 2020-08-07 2020-12-04 福建鸿星尔克体育用品有限公司 一种高弹透光材料及其制备方法和采用该材料制备的鞋底
CN112029181B (zh) * 2020-08-07 2023-05-02 福建鸿星尔克体育用品有限公司 一种高弹透光材料及其制备方法和采用该材料制备的鞋底
CN111923525A (zh) * 2020-09-23 2020-11-13 歌尔股份有限公司 振膜和发声装置
JP2022187476A (ja) * 2021-06-07 2022-12-19 李長榮化學工業股▲ふん▼有限公司 架橋性及び発泡性組成物、それによって得られる発泡体、発泡のための組成物並びにその使用
CN113881130A (zh) * 2021-11-08 2022-01-04 安踏（中国）有限公司 一种高耐磨的鞋用eva发泡材料及其制备方法

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