CN105408385B - 具有高断裂韧性的可硬化组合物 - Google Patents

具有高断裂韧性的可硬化组合物 Download PDF

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Publication number
CN105408385B
CN105408385B CN201480007725.1A CN201480007725A CN105408385B CN 105408385 B CN105408385 B CN 105408385B CN 201480007725 A CN201480007725 A CN 201480007725A CN 105408385 B CN105408385 B CN 105408385B
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CN
China
Prior art keywords
hardenable
amine
open
chain
composition according
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
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CN201480007725.1A
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English (en)
Chinese (zh)
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CN105408385A (zh
Inventor
M.奥泰尔特
D.富克斯曼
E.朗卡贝尔
B.科尔施特鲁克
K.卡恩斯
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Evonik Operations GmbH
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Evonik Degussa GmbH
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Filing date
Publication date
Priority claimed from EP13154220.1A external-priority patent/EP2765162A1/de
Priority claimed from EP13174322.1A external-priority patent/EP2818491A1/de
Priority claimed from EP13179541.1A external-priority patent/EP2835389A1/de
Application filed by Evonik Degussa GmbH filed Critical Evonik Degussa GmbH
Publication of CN105408385A publication Critical patent/CN105408385A/zh
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/50—Amines
    • C08G59/5026—Amines cycloaliphatic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/20—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
    • C08G59/22—Di-epoxy compounds
    • C08G59/24—Di-epoxy compounds carbocyclic
    • C08G59/245—Di-epoxy compounds carbocyclic aromatic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/50—Amines
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/50—Amines
    • C08G59/5006—Amines aliphatic
    • C08G59/502—Polyalkylene polyamines
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/50—Amines
    • C08G59/56—Amines together with other curing agents
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J163/00—Adhesives based on epoxy resins; Adhesives based on derivatives of epoxy resins

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Epoxy Resins (AREA)
  • Adhesives Or Adhesive Processes (AREA)
CN201480007725.1A 2013-02-06 2014-01-15 具有高断裂韧性的可硬化组合物 Active CN105408385B (zh)

Applications Claiming Priority (7)

Application Number Priority Date Filing Date Title
EP13154220.1A EP2765162A1 (de) 2013-02-06 2013-02-06 Härtbare Zusammensetzung mit hoher Bruchzähigkeit
EP13154220.1 2013-02-06
EP13174322.1A EP2818491A1 (de) 2013-06-28 2013-06-28 Härtbare Zusammensetzung mit hoher Bruchzähigkeit
EP13174322.1 2013-06-28
EP13179541.1A EP2835389A1 (de) 2013-08-07 2013-08-07 Härtbare Zusammensetzung mit hoher Bruchzähigkeit
EP13179541.1 2013-08-07
PCT/EP2014/050714 WO2014121987A1 (de) 2013-02-06 2014-01-15 Härtbare zusammensetzung mit hoher bruchzähigkeit

Publications (2)

Publication Number Publication Date
CN105408385A CN105408385A (zh) 2016-03-16
CN105408385B true CN105408385B (zh) 2018-09-18

Family

ID=49989740

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201480007725.1A Active CN105408385B (zh) 2013-02-06 2014-01-15 具有高断裂韧性的可硬化组合物

Country Status (7)

Country Link
US (1) US9994671B2 (enExample)
EP (1) EP2953991B1 (enExample)
JP (1) JP6312711B2 (enExample)
CN (1) CN105408385B (enExample)
ES (1) ES2720798T3 (enExample)
TW (1) TWI620782B (enExample)
WO (1) WO2014121987A1 (enExample)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108603009B (zh) 2016-02-29 2020-10-20 三菱化学株式会社 环氧树脂组合物、成型材料及纤维增强复合材料
HUE048064T2 (hu) 2016-06-23 2020-05-28 Evonik Operations Gmbh Autoklávozott pórusbetonból (AAC) készített megerõsített építõelem
EP3569630B1 (de) 2018-05-17 2022-08-03 Evonik Operations GmbH Schnell härtende epoxysysteme
EP3569629B1 (de) 2018-05-17 2022-07-06 Evonik Operations GmbH Schnell härtende epoxysysteme
US11359048B2 (en) 2018-05-17 2022-06-14 Evonik Operations Gmbh Fast-curing epoxy systems
US11286335B2 (en) 2018-05-17 2022-03-29 Evonik Operations Gmbh Fast-curing epoxy systems

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3261809A (en) 1962-11-02 1966-07-19 American Cyanamid Co Substituted isobiguanide catalysts for epoxy resins
US5618905A (en) 1995-04-11 1997-04-08 Air Products And Chemicals, Inc. Partially methylated polyamines as epoxy curing agents
US5688905A (en) 1995-09-20 1997-11-18 Air Products And Chemicals, Inc. Primary-tertiary diamines mixed with polyamines as epoxy resin hardeners
US5591812A (en) 1996-01-26 1997-01-07 Air Products And Chemicals, Inc. Reactive accelerators for amine cured epoxy resins
US6248204B1 (en) 1999-05-14 2001-06-19 Loctite Corporation Two part, reinforced, room temperature curable thermosetting epoxy resin compositions with improved adhesive strength and fracture toughness
DE10023752B4 (de) 2000-05-15 2004-09-09 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. Verfahren und Vorrichtung zur Bestimmung zumindest eines bruchmechanischen Materialparameters eines Prüfkörpers
DE10231119A1 (de) 2002-07-10 2004-02-05 Degussa Ag Verfahren zur Selektivitätserhöhung der Hydrierung von 4,4'-Diaminodiphenylmethan zu 4,4'-Diaminodicyclohexylmethan in Gegenwart eines N-Alkyl-4,4'-Diaminodiphenylmethans
US20120328811A1 (en) * 2011-06-24 2012-12-27 Air Products And Chemicals, Inc. Epoxy Resin Compositions
EP2546230A1 (de) * 2011-07-15 2013-01-16 Sika Technology AG Emissionsarmer Härter für Epoxidharze
CN102796349B (zh) 2012-08-27 2015-02-18 黑龙江省科学院石油化学研究院 膜状室温固化环氧树脂复合材料垫片及其制备方法
EP2706076B1 (de) 2012-09-07 2014-12-17 Evonik Industries AG Härtbare Zusammensetzungen auf der Basis von Epoxidharzen ohne Benzylalkohol
EP2752437A1 (de) * 2013-01-08 2014-07-09 Sika Technology AG Härter für emissionsarme Epoxidharz-Produkte

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
The effect of alkyl substituents on the properties of cured hydantoin epoxy Resins;Catsiff, E. H.et al;《ACS Symposium Series》;19791231;第115-135页 *

Also Published As

Publication number Publication date
TW201446871A (zh) 2014-12-16
US20150376327A1 (en) 2015-12-31
CN105408385A (zh) 2016-03-16
JP2016507622A (ja) 2016-03-10
JP6312711B2 (ja) 2018-04-18
WO2014121987A1 (de) 2014-08-14
EP2953991B1 (de) 2018-12-26
TWI620782B (zh) 2018-04-11
US9994671B2 (en) 2018-06-12
ES2720798T3 (es) 2019-07-24
EP2953991A1 (de) 2015-12-16

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Address after: Essen, Germany

Patentee after: Evonik Operations Limited

Address before: Essen, Germany

Patentee before: EVONIK DEGUSSA GmbH