CN105209024B - 生物活性剂从聚合物复合颗粒的释放 - Google Patents

生物活性剂从聚合物复合颗粒的释放 Download PDF

Info

Publication number
CN105209024B
CN105209024B CN201480027396.7A CN201480027396A CN105209024B CN 105209024 B CN105209024 B CN 105209024B CN 201480027396 A CN201480027396 A CN 201480027396A CN 105209024 B CN105209024 B CN 105209024B
Authority
CN
China
Prior art keywords
weight
phase
polymer
formula
monomer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN201480027396.7A
Other languages
English (en)
Chinese (zh)
Other versions
CN105209024A (zh
Inventor
H·萨霍亚尼
M·M·卡鲁索戴利
L·E·海因曾
I·A·埃尔赫多科
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
3M Innovative Properties Co
Original Assignee
3M Innovative Properties Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 3M Innovative Properties Co filed Critical 3M Innovative Properties Co
Publication of CN105209024A publication Critical patent/CN105209024A/zh
Application granted granted Critical
Publication of CN105209024B publication Critical patent/CN105209024B/zh
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00—Processes of treating or compounding macromolecular substances
    • C08J3/12—Powdering or granulating
    • C08J3/126—Polymer particles coated by polymer, e.g. core shell structures
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/26—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests in coated particulate form
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/08—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing solids as carriers or diluents
    • A01N25/10—Macromolecular compounds
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/26—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests in coated particulate form
    • A01N25/28—Microcapsules or nanocapsules
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/40—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides
    • A01N47/42—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides containing —N=CX2 groups, e.g. isothiourea
    • A01N47/44—Guanidine; Derivatives thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N51/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds having the sequences of atoms O—N—S, X—O—S, N—N—S, O—N—N or O-halogen, regardless of the number of bonds each atom has and with no atom of these sequences forming part of a heterocyclic ring
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J13/00—Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
    • B01J13/02—Making microcapsules or microballoons
    • B01J13/04—Making microcapsules or microballoons by physical processes, e.g. drying, spraying
    • B01J13/043—Drying and spraying
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/16—Making expandable particles
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/28—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof by elimination of a liquid phase from a macromolecular composition or article, e.g. drying of coagulum
    • C08J9/286—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof by elimination of a liquid phase from a macromolecular composition or article, e.g. drying of coagulum the liquid phase being a solvent for the monomers but not for the resulting macromolecular composition, i.e. macroporous or macroreticular polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/36—After-treatment
    • C08J9/365—Coating
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/36—After-treatment
    • C08J9/40—Impregnation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2201/00—Foams characterised by the foaming process
    • C08J2201/02—Foams characterised by the foaming process characterised by mechanical pre- or post-treatments
    • C08J2201/036—Use of an organic, non-polymeric compound to impregnate, bind or coat a foam, e.g. fatty acid ester
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2201/00—Foams characterised by the foaming process
    • C08J2201/04—Foams characterised by the foaming process characterised by the elimination of a liquid or solid component, e.g. precipitation, leaching out, evaporation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2205/00—Foams characterised by their properties
    • C08J2205/02—Foams characterised by their properties the finished foam itself being a gel or a gel being temporarily formed when processing the foamable composition
    • C08J2205/024—Organogel, i.e. a gel containing an organic composition
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2207/00—Foams characterised by their intended use
    • C08J2207/10—Medical applications, e.g. biocompatible scaffolds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2333/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
    • C08J2333/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters
    • C08J2333/14—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters of esters containing halogen, nitrogen, sulfur, or oxygen atoms in addition to the carboxy oxygen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2347/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds; Derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2400/00—Characterised by the use of unspecified polymers
    • C08J2400/22—Thermoplastic resins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2491/00—Characterised by the use of oils, fats or waxes; Derivatives thereof
    • C08J2491/06—Waxes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Materials Engineering (AREA)
  • Agronomy & Crop Science (AREA)
  • Zoology (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Environmental Sciences (AREA)
  • Dentistry (AREA)
  • Wood Science & Technology (AREA)
  • Toxicology (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Medicinal Preparation (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Bioinformatics & Cheminformatics (AREA)
  • Pharmacology & Pharmacy (AREA)
  • Epidemiology (AREA)
  • Animal Behavior & Ethology (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
CN201480027396.7A 2013-05-17 2014-05-13 生物活性剂从聚合物复合颗粒的释放 Expired - Fee Related CN105209024B (zh)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US201361824412P 2013-05-17 2013-05-17
US61/824,412 2013-05-17
US201461990348P 2014-05-08 2014-05-08
US61/990,348 2014-05-08
PCT/US2014/037799 WO2014186336A1 (en) 2013-05-17 2014-05-13 Release of biologically active agents from polymeric composite particles

Publications (2)

Publication Number Publication Date
CN105209024A CN105209024A (zh) 2015-12-30
CN105209024B true CN105209024B (zh) 2018-04-27

Family

ID=50933532

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201480027396.7A Expired - Fee Related CN105209024B (zh) 2013-05-17 2014-05-13 生物活性剂从聚合物复合颗粒的释放

Country Status (6)

Country Link
US (1) US10111424B2 (https=)
EP (1) EP2996682B1 (https=)
JP (1) JP6316944B2 (https=)
KR (1) KR102246242B1 (https=)
CN (1) CN105209024B (https=)
WO (1) WO2014186336A1 (https=)

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2014186328A1 (en) 2013-05-17 2014-11-20 3M Innovative Properties Company Reaction mixture, porous particles and methods of making
WO2016053875A1 (en) 2014-10-01 2016-04-07 3M Innovative Properties Company Medical dressings comprising fluid management articles and methods of using same
WO2016053830A1 (en) * 2014-10-01 2016-04-07 3M Innovative Properties Company Articles including fibrous substrates and porous polymeric particles and methods of making same
JP6732750B2 (ja) * 2014-12-17 2020-07-29 ロレアル 複合粒子及びその調製
FR3030227B1 (fr) * 2014-12-17 2018-01-26 L'oreal Emulsion stabilisees par des particules composites amphiphiles
JP2018500435A (ja) * 2014-12-23 2018-01-11 スリーエム イノベイティブ プロパティズ カンパニー 硬化性及び硬化済みエポキシ樹脂組成物
KR102528690B1 (ko) * 2015-03-06 2023-05-08 쓰리엠 이노베이티브 프로퍼티즈 캄파니 다공성 중합체 입자를 포함하는 조성물 및 접착 용품 및 기재를 코팅하는 방법
US20180057770A1 (en) * 2015-03-23 2018-03-01 3M Innovative Properties Company Polymeric composite particles
WO2017189388A1 (en) * 2016-04-25 2017-11-02 3M Innovative Properties Company Composite particles for curing epoxy resin compositions and curable and cured epoxy resin compositions prepared using the particles
WO2017205636A1 (en) * 2016-05-25 2017-11-30 University Of Florida Research Foundation, Inc. Texturized insecticidal formulation
US10570017B2 (en) * 2017-01-16 2020-02-25 Winsky Technology Hong Kong Limited Yolk-shell-structured material, anode material, anode, battery, and method of forming same
JP6830666B2 (ja) * 2017-09-22 2021-02-17 新中村化学工業株式会社 コアシェル型農薬粒剤組成物及びその製造方法
CN108041674B (zh) * 2017-11-29 2020-12-18 武汉纺织大学 一种高效阻水防渗透胶囊及其制备方法
JP7737226B2 (ja) * 2018-02-06 2025-09-10 ソルベンタム インテレクチュアル プロパティズ カンパニー 多孔質又は中空コアとｐＨ感受性シェルとを有するマイクロカプセル及びその使用
CN113905812A (zh) * 2019-06-04 2022-01-07 3M创新有限公司 具有多孔或中空的芯以及包含在与酸接触时释放气体的组分的壳的微胶囊
WO2022118125A1 (en) 2020-12-04 2022-06-09 3M Innovative Properties Company Ph-sensitive microcapsule for dental use

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5316774A (en) * 1990-06-20 1994-05-31 Advanced Polymer Systems, Inc. Blocked polymeric particles having internal pore networks for delivering active substances to selected environments

Family Cites Families (57)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3890269A (en) 1972-08-11 1975-06-17 Stauffer Chemical Co Process for preparing aminofunctional polysiloxane polymers
US3921636A (en) 1973-01-15 1975-11-25 Alza Corp Novel drug delivery device
US4743545A (en) 1984-08-09 1988-05-10 Torobin Leonard B Hollow porous microspheres containing biocatalyst
US4303736A (en) 1979-07-20 1981-12-01 Leonard Torobin Hollow plastic microspheres
JPH0699244B2 (ja) 1985-04-10 1994-12-07 日本ペイント株式会社 抗有害生物性を有する微小樹脂粒子
US4661577A (en) 1985-10-01 1987-04-28 General Electric Company Aminofunctional polysiloxanes
US4690825A (en) 1985-10-04 1987-09-01 Advanced Polymer Systems, Inc. Method for delivering an active ingredient by controlled time release utilizing a novel delivery vehicle which can be prepared by a process utilizing the active ingredient as a porogen
US5214119A (en) 1986-06-20 1993-05-25 Minnesota Mining And Manufacturing Company Block copolymer, method of making the same, dimaine precursors of the same, method of making such diamines and end products comprising the block copolymer
US5512650A (en) 1986-06-20 1996-04-30 Minnesota Mining And Manufacturing Company Block copolymer, method of making the same, diamine precursors of the same, method of making such diamines and end products comprising the block copolymer
US4855144A (en) 1987-10-23 1989-08-08 Advanced Polymer Systems Synthetic melanin aggregates
US4806360A (en) * 1987-10-23 1989-02-21 Advanced Polymer Systems Synthetic melanin aggregates
US5026890A (en) 1988-05-20 1991-06-25 General Electric Company Method and intermediates for preparation of bis(aminoalkyl)polydiorganosiloxanes
US5045569A (en) 1988-11-30 1991-09-03 Minnesota Mining And Manufacturing Company Hollow acrylate polymer microspheres
US5888930A (en) 1989-03-27 1999-03-30 Bend Research, Inc. Asymmetric microporous beads for controlled release
US5292835A (en) 1990-05-16 1994-03-08 Basf Aktiengesellschaft Microcapsules
US5190775A (en) 1991-05-29 1993-03-02 Balchem Corporation Encapsulated bioactive substances
JP2684130B2 (ja) 1991-08-15 1997-12-03 信越化学工業株式会社 アミノ基含有ポリシロキサンの製造方法
US5508341A (en) 1993-07-08 1996-04-16 Regents Of The University Of California Organic aerogel microspheres and fabrication method therefor
JPH0753835A (ja) 1993-08-10 1995-02-28 Takeda Chem Ind Ltd 有効成分を含有するコアポリマー、コアシェルポリマーおよびそれらの製造法
US5554686A (en) 1993-08-20 1996-09-10 Minnesota Mining And Manufacturing Company Room temperature curable silane-terminated polyurethane dispersions
US6441118B2 (en) 1996-04-25 2002-08-27 3M Innovative Properties Company Polydiorganosiloxane oligourea segmented copolymers and a process for making same
US6355759B1 (en) 1996-04-25 2002-03-12 3M Innovative Properties Company Polydiorganosiloxane polyurea segmented copolymers and a process for making same
US6407195B2 (en) 1996-04-25 2002-06-18 3M Innovative Properties Company Tackified polydiorganosiloxane oligourea segmented copolymers and a process for making same
AU6909396A (en) 1996-04-25 1997-11-12 Minnesota Mining And Manufacturing Company Silicone compositions containing a silicone-urea segmented copolymer
US6846893B1 (en) 1996-10-23 2005-01-25 Minnesota Mining And Manufacturing Company Polymer mixtures containing polydiorganosiloxane urea-containing components
US5972363A (en) 1997-04-11 1999-10-26 Rohm And Haas Company Use of an encapsulated bioactive composition
US7354596B1 (en) 1998-05-01 2008-04-08 3M Innovative Properties Company Anti-microbial agent delivery system
US6406719B1 (en) 1998-05-13 2002-06-18 Microbiological Research Authority Encapsulation of bioactive agents
PL351487A1 (en) 1999-03-02 2003-04-22 Liposome Co Inc Encapsulation of bioactive complexes in liposomes
JP2000302606A (ja) 1999-04-15 2000-10-31 Novartis Ag 固体農薬のマイクロカプセル、その製造方法及び施用方法
WO2001046290A1 (en) 1999-12-20 2001-06-28 3M Innovative Properties Company Ambient-temperature-stable, one-part curable epoxy adhesive
DE60103858T2 (de) 2000-01-28 2005-06-30 3M Innovative Properties Co., Saint Paul Durch extrusion verbundenes laminat von elastischem material und vlies
US6720007B2 (en) 2000-10-25 2004-04-13 Tufts University Polymeric microspheres
US6906157B2 (en) 2002-04-09 2005-06-14 Eastman Kodak Company Polymer particle stabilized by dispersant and method of preparation
US6936644B2 (en) 2002-10-16 2005-08-30 Cookson Electronics, Inc. Releasable microcapsule and adhesive curing system using the same
US6835397B2 (en) 2002-12-23 2004-12-28 Balchem Corporation Controlled release encapsulated bioactive substances
DE10326575A1 (de) 2003-06-12 2005-01-20 Wacker-Chemie Gmbh Organopolysiloxan/Polyharnstoff/Polyurethan-Blockcopolymere
US20050202096A1 (en) 2004-03-09 2005-09-15 Jun Li Microcapsules for encapsulation of bioactive substances
KR101205481B1 (ko) 2005-06-17 2012-11-27 오스트레일리언뉴클리어사이언스앤드테크놀로지오거나이제이션 방출 가능한 도펀트를 함유한 입자
NZ565013A (en) 2005-06-17 2010-02-26 Australian Nuclear Science Tec Particles having hydrophobic material therein
KR101331818B1 (ko) 2005-10-20 2013-11-22 마쓰모토유시세이야쿠 가부시키가이샤 열팽창성 미소구 및 그 제조방법
US7371464B2 (en) 2005-12-23 2008-05-13 3M Innovative Properties Company Adhesive compositions
US7501184B2 (en) 2005-12-23 2009-03-10 3M Innovative Properties Company Polydiorganosiloxane polyoxamide copolymers
BRPI0712183A2 (pt) 2006-06-08 2012-01-17 3M Innovative Properties Co microesferas poliméricas e métodos de preparo de microesferas poliméricas
AU2008213911A1 (en) 2007-02-09 2008-08-14 Newsouth Innovations Pty Limited Hollow microparticles
US8710111B2 (en) 2007-11-09 2014-04-29 3M Innovative Properties Company Porous polymeric resins
IE20080211A1 (en) 2008-03-20 2009-11-25 Nat Univ Ireland Biodegradable nanoshells for delivery of therapeutic and/or imaging molecules
US9125872B2 (en) 2009-10-13 2015-09-08 Yosry A. Attia Polyethylene glycol aerogels for targeted delivery of pharmaceutical drubs
JP5991983B2 (ja) 2010-12-13 2016-09-14 スリーエム イノベイティブ プロパティズ カンパニー 乾燥した表面改質ナノカルサイト
WO2012134679A2 (en) 2011-03-07 2012-10-04 3M Innovative Properties Company Hollow microspheres
JP6083936B2 (ja) * 2011-03-11 2017-02-22 大阪ガスケミカル株式会社 徐放性粒子の製造方法
EP2696855B1 (en) 2011-04-13 2021-06-02 The Trustees Of The University Of Pennsylvania Coated mesoporous nanoparticles
CN104093754B (zh) 2011-11-21 2017-06-23 3M创新有限公司 用于储存并递送活性剂的聚合物粒子
AR090901A1 (es) 2012-04-30 2014-12-17 Dow Agrosciences Llc Formulaciones para el tratamiento de semillas
WO2014186328A1 (en) 2013-05-17 2014-11-20 3M Innovative Properties Company Reaction mixture, porous particles and methods of making
EP2886620B1 (en) 2013-12-18 2019-11-27 3M Innovative Properties Company Post-curable pressure-sensitive adhesive
US10413881B2 (en) 2013-12-18 2019-09-17 3M Innovative Properties Company Porous articles for separation

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5316774A (en) * 1990-06-20 1994-05-31 Advanced Polymer Systems, Inc. Blocked polymeric particles having internal pore networks for delivering active substances to selected environments

Also Published As

Publication number Publication date
US10111424B2 (en) 2018-10-30
JP2016523833A (ja) 2016-08-12
KR20160010506A (ko) 2016-01-27
WO2014186336A1 (en) 2014-11-20
EP2996682A1 (en) 2016-03-23
US20160088836A1 (en) 2016-03-31
JP6316944B2 (ja) 2018-04-25
EP2996682B1 (en) 2018-07-04
KR102246242B1 (ko) 2021-04-28
CN105209024A (zh) 2015-12-30

Similar Documents

Publication Publication Date Title
CN105209024B (zh) 生物活性剂从聚合物复合颗粒的释放
Hwang et al. Preparation and characterization of melamine-formaldehyde resin microcapsules containing fragrant oil
CN107108913A (zh) 可固化的和固化的环氧树脂组合物
CN104093754B (zh) 用于储存并递送活性剂的聚合物粒子
CN105228820B (zh) 反应混合物、多孔粒子以及制备方法
JP5317181B2 (ja) ポリウレタン粒子及びポリウレタン粒子群の製造方法
CN103429078B (zh) 缓释粒子及其制造方法
US20070286959A1 (en) Coating resins and coating with multiple crosslink functionalities crosslink
CN106795692B (zh) 包括纤维基底和多孔聚合物粒子的制品及其制备方法
CN102480939A (zh) 缓释性颗粒及其制造方法
Zhang et al. Tunable thermal, mechanical, and controlled-release properties of epoxy phenolic novolac resin microcapsules mediated by diamine crosslinkers
Bansal et al. Self-assembled nanostructures from amphiphilic sucrose-soyates for solubilizing hydrophobic guest molecules
JP6355486B2 (ja) 徐放性粒子、その製造方法、成形材料および成形品
CN112313259B (zh) 官能化的多壁核壳颗粒
US20190262490A1 (en) Composite particles, dispersion liquid, film, deodorizing material, wet wiper, and spray
WO2013083693A1 (de) Komposite und beschichtungsstoffe mit in biologischem hüllmaterial inkludierten wirkstoffen
Hwang et al. Fabrication of hollow silica particles using copolymeric spheres prepared in supercritical carbon dioxide
WO2015030213A1 (ja) 徐放性粒子、その製造方法、成形材料および成形品
CN105636684B (zh) 用于制备优选水溶性活性剂的浓缩物的方法
Rodrigues et al. Technologies for producing microcapsules with added value

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20180427

CF01 Termination of patent right due to non-payment of annual fee