CN105111694B - 可交联组合物、由其可获得的热塑性弹性体以及它们的用途 - Google Patents
可交联组合物、由其可获得的热塑性弹性体以及它们的用途 Download PDFInfo
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- CN105111694B CN105111694B CN201510557995.6A CN201510557995A CN105111694B CN 105111694 B CN105111694 B CN 105111694B CN 201510557995 A CN201510557995 A CN 201510557995A CN 105111694 B CN105111694 B CN 105111694B
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- vinyl acetate
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- olefin
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- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims abstract description 30
- 239000003999 initiator Substances 0.000 claims abstract description 19
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- BJELTSYBAHKXRW-UHFFFAOYSA-N 2,4,6-triallyloxy-1,3,5-triazine Chemical compound C=CCOC1=NC(OCC=C)=NC(OCC=C)=N1 BJELTSYBAHKXRW-UHFFFAOYSA-N 0.000 claims description 5
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- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 4
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- 230000015572 biosynthetic process Effects 0.000 description 1
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- 238000000071 blow moulding Methods 0.000 description 1
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- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 1
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- OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
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- 230000008878 coupling Effects 0.000 description 1
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- 239000011243 crosslinked material Substances 0.000 description 1
- PDXRQENMIVHKPI-UHFFFAOYSA-N cyclohexane-1,1-diol Chemical compound OC1(O)CCCCC1 PDXRQENMIVHKPI-UHFFFAOYSA-N 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000006735 deficit Effects 0.000 description 1
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 1
- 239000012933 diacyl peroxide Substances 0.000 description 1
- 150000001990 dicarboxylic acid derivatives Chemical class 0.000 description 1
- 150000001993 dienes Chemical class 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- DROMNWUQASBTFM-UHFFFAOYSA-N dinonyl benzene-1,2-dicarboxylate Chemical compound CCCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCCC DROMNWUQASBTFM-UHFFFAOYSA-N 0.000 description 1
- MIMDHDXOBDPUQW-UHFFFAOYSA-N dioctyl decanedioate Chemical compound CCCCCCCCOC(=O)CCCCCCCCC(=O)OCCCCCCCC MIMDHDXOBDPUQW-UHFFFAOYSA-N 0.000 description 1
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- PXJJSXABGXMUSU-UHFFFAOYSA-N disulfur dichloride Chemical compound ClSSCl PXJJSXABGXMUSU-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
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- 230000000694 effects Effects 0.000 description 1
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- MEGHWIAOTJPCHQ-UHFFFAOYSA-N ethenyl butanoate Chemical compound CCCC(=O)OC=C MEGHWIAOTJPCHQ-UHFFFAOYSA-N 0.000 description 1
- AFSIMBWBBOJPJG-UHFFFAOYSA-N ethenyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC=C AFSIMBWBBOJPJG-UHFFFAOYSA-N 0.000 description 1
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- 229920006228 ethylene acrylate copolymer Polymers 0.000 description 1
- STVZJERGLQHEKB-UHFFFAOYSA-N ethylene glycol dimethacrylate Substances CC(=C)C(=O)OCCOC(=O)C(C)=C STVZJERGLQHEKB-UHFFFAOYSA-N 0.000 description 1
- 229920006244 ethylene-ethyl acrylate Polymers 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 230000008570 general process Effects 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
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- 239000012943 hotmelt Substances 0.000 description 1
- 229920002681 hypalon Polymers 0.000 description 1
- 150000003949 imides Chemical class 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
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- 238000004898 kneading Methods 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
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- 125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 description 1
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- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- 125000005498 phthalate group Chemical class 0.000 description 1
- XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920001748 polybutylene Polymers 0.000 description 1
- 229920001707 polybutylene terephthalate Polymers 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920002959 polymer blend Polymers 0.000 description 1
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- 229920006324 polyoxymethylene Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- FBCQUCJYYPMKRO-UHFFFAOYSA-N prop-2-enyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC=C FBCQUCJYYPMKRO-UHFFFAOYSA-N 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
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- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 230000035882 stress Effects 0.000 description 1
- YPMOSINXXHVZIL-UHFFFAOYSA-N sulfanylideneantimony Chemical compound [Sb]=S YPMOSINXXHVZIL-UHFFFAOYSA-N 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 239000012815 thermoplastic material Substances 0.000 description 1
- 229920006346 thermoplastic polyester elastomer Polymers 0.000 description 1
- 229920005992 thermoplastic resin Polymers 0.000 description 1
- 229920006342 thermoplastic vulcanizate Polymers 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- KUAZQDVKQLNFPE-UHFFFAOYSA-N thiram Chemical compound CN(C)C(=S)SSC(=S)N(C)C KUAZQDVKQLNFPE-UHFFFAOYSA-N 0.000 description 1
- 229960002447 thiram Drugs 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- 125000005591 trimellitate group Chemical group 0.000 description 1
- WVPGXJOLGGFBCR-UHFFFAOYSA-N trioctyl phosphate Chemical class CCCCCCCCOP(=O)(OCCCCCCCC)OCCCCCCCC WVPGXJOLGGFBCR-UHFFFAOYSA-N 0.000 description 1
- 235000013799 ultramarine blue Nutrition 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 150000003751 zinc Chemical class 0.000 description 1
- 239000011667 zinc carbonate Substances 0.000 description 1
- 235000004416 zinc carbonate Nutrition 0.000 description 1
- 229910000010 zinc carbonate Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L31/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid; Compositions of derivatives of such polymers
- C08L31/02—Homopolymers or copolymers of esters of monocarboxylic acids
- C08L31/04—Homopolymers or copolymers of vinyl acetate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
- C08L67/025—Polyesters derived from dicarboxylic acids and dihydroxy compounds containing polyether sequences
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
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| DE102008012516A DE102008012516A1 (de) | 2008-03-04 | 2008-03-04 | Vernetzbare Zusammensetzungen, daraus erhältliche thermoplastische Elastomere und deren Verwendung |
| DE102008012516.4 | 2008-03-04 | ||
| CN200910126034A CN101525471A (zh) | 2008-03-04 | 2009-03-02 | 可交联组合物、由其可获得的热塑性弹性体以及它们的用途 |
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| CN200910126034A Division CN101525471A (zh) | 2008-03-04 | 2009-03-02 | 可交联组合物、由其可获得的热塑性弹性体以及它们的用途 |
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| CN105111694A CN105111694A (zh) | 2015-12-02 |
| CN105111694B true CN105111694B (zh) | 2018-09-14 |
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| CN201510557995.6A Expired - Fee Related CN105111694B (zh) | 2008-03-04 | 2009-03-02 | 可交联组合物、由其可获得的热塑性弹性体以及它们的用途 |
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| CN200910126034A Pending CN101525471A (zh) | 2008-03-04 | 2009-03-02 | 可交联组合物、由其可获得的热塑性弹性体以及它们的用途 |
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| JP (1) | JP5770416B2 (enExample) |
| CN (2) | CN101525471A (enExample) |
| BR (2) | BRPI0900686B1 (enExample) |
| CA (1) | CA2656482C (enExample) |
| DE (1) | DE102008012516A1 (enExample) |
| MX (1) | MX2009002086A (enExample) |
Families Citing this family (23)
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| EP2336229A1 (de) * | 2009-12-21 | 2011-06-22 | LANXESS Deutschland GmbH | Flammgeschützte Polymerzusammensetzungen |
| DE202009019165U1 (de) | 2009-12-22 | 2017-05-15 | Veritas Ag | Fluidleitung |
| CN102753614A (zh) * | 2010-02-08 | 2012-10-24 | 日本化成株式会社 | 交联性弹性体用交联剂及其应用 |
| US8178647B2 (en) | 2010-08-25 | 2012-05-15 | Eastman Chemical Company | Copolyester ether elastomer compositions and methods of making copolyester ether elastomer compositions |
| CN101948599B (zh) * | 2010-10-12 | 2012-08-22 | 上海交通大学 | 一种热塑性弹性体的制备方法 |
| CN102329483B (zh) * | 2011-09-26 | 2012-11-21 | 上海交通大学 | 聚丁二酸丁二醇酯/乙烯－醋酸乙烯酯共混材料制备方法 |
| US9388296B2 (en) | 2012-06-04 | 2016-07-12 | National Institute Of Clean-And-Low-Carbon Energy | Crosslinked polyethylene composition having improved processability |
| WO2013185302A1 (zh) * | 2012-06-13 | 2013-12-19 | 北京低碳清洁能源研究所 | 一种交联聚乙烯组合物 |
| FR2995716B1 (fr) * | 2012-09-17 | 2014-09-05 | Silec Cable | Procede de fabrication d'un cable de transport d'energie electrique et cable fabrique par un tel procede |
| US20140079898A1 (en) * | 2012-09-18 | 2014-03-20 | Ticona Llc | Polymer Articles Made From a Blend of a Copolyester Elastomer and an Alpha-Olefin Vinyl Acetate Copolymer |
| EP2810986B1 (de) | 2013-06-05 | 2017-04-19 | Carl Freudenberg KG | Thermoplastische Elastomerzusammensetzung und deren Verwendung |
| WO2015160592A1 (en) | 2014-04-17 | 2015-10-22 | Ticona Llc | Elastomeric composition having oil resistance |
| DE102015007200A1 (de) | 2015-05-26 | 2016-12-01 | Kraiburg Tpe Gmbh & Co. Kg | Härteeinstellung von thermoplastischen Elastomerzusammensetzungen durch Kombination von Thermoplasten und thermoplastischen Elastomeren |
| WO2017021800A1 (en) * | 2015-08-04 | 2017-02-09 | Aei Compounds Ltd. | Oil and mud resistant sheathing composition |
| CA3007349C (en) | 2015-08-24 | 2023-10-10 | Aei Compounds Ltd. | Thermoset insulation composition |
| CA3018896C (en) | 2017-03-01 | 2020-11-17 | Aei Compounds Ltd. | Cable sheathing composition |
| WO2018160460A1 (en) | 2017-03-01 | 2018-09-07 | Aei Compounds Ltd. | Wire sheathing and insulation compositions |
| CN110515168A (zh) * | 2019-08-30 | 2019-11-29 | 江苏中天科技股份有限公司 | 易剥离干式光纤微管和全干式微束光缆 |
| JP7432809B2 (ja) * | 2019-11-11 | 2024-02-19 | 東ソー株式会社 | 射出成形用樹脂組成物および射出成形体 |
| CN111961267A (zh) * | 2020-09-04 | 2020-11-20 | 石家庄硕若科技有限公司 | 一种耐高温的橡胶粉制作工艺 |
| CN113831855B (zh) * | 2021-09-26 | 2023-03-10 | 保定乐凯新材料股份有限公司 | 适应pla基材低温裱磁的热转移型磁条制备方法及应用 |
| KR102352074B1 (ko) * | 2021-11-08 | 2022-01-18 | 정준호 | 플랜지 접합용 가스켓 |
| CN118791796A (zh) * | 2023-04-14 | 2024-10-18 | 中国石油天然气股份有限公司 | 新型交联抗冲聚丙烯及其制备方法与应用 |
Family Cites Families (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4322575A (en) * | 1978-12-13 | 1982-03-30 | Raychem Limited | Flame retardant compositions |
| JPS63120750A (ja) * | 1986-11-11 | 1988-05-25 | Du Pont Mitsui Polychem Co Ltd | 耐熱性に優れたキャップライナ− |
| US4981908A (en) | 1988-02-02 | 1991-01-01 | E. I. Du Pont De Nemours And Company | Thermoplastic elastomer blends |
| DE3815946A1 (de) | 1988-05-10 | 1989-11-23 | Bayer Ag | Loesungspolymerisation zur herstellung von gelfreien ethylen/vinylacetat-copolymerisaten |
| DE3825450C2 (de) | 1988-07-27 | 1997-07-10 | Bayer Ag | Verfahren zur Herstellung von Ethylen/Vinylacetat-Copolymerisaten mit verringerter Klebeneigung |
| DE4123963A1 (de) | 1991-07-19 | 1993-01-21 | Buna Ag | Schlagzaehe polyamid-formmassen |
| DE4113291A1 (de) | 1991-04-24 | 1992-10-29 | Bayer Ag | Herstellung von ethylen-vinylacetat-copolymeren |
| DE4425944C2 (de) | 1994-07-21 | 2002-08-01 | Wacker Chemie Gmbh | Thermoplastische Elastomerzusammensetzung |
| BE1010792A3 (nl) | 1996-12-06 | 1999-02-02 | Dsm Nv | Copolyester elastomeer. |
| DE10017149A1 (de) | 1999-04-06 | 2000-11-02 | Yokohama Rubber Co Ltd | Thermoplastische Elastomerzusammensetzung und Gelenkmanschette daraus |
| JP2000351889A (ja) * | 1999-04-06 | 2000-12-19 | Yokohama Rubber Co Ltd:The | 熱可塑性エラストマー組成物及びそれを使用したジョイントブーツ |
| NL1012561C2 (nl) | 1999-07-09 | 2001-01-10 | Dsm Nv | Thermoplastisch blokcopolyesterelastomeer. |
| JP4057365B2 (ja) * | 2002-07-23 | 2008-03-05 | リケンテクノス株式会社 | 光ファイバ被覆用難燃性樹脂組成物および光ファイバコード又は光ケーブル |
| EP1767577A4 (en) | 2004-06-30 | 2009-12-16 | Zeon Corp | THERMOPLASTIC ELASTOMER COMPOSITION AND FORM PART THEREOF |
| DE502005004671D1 (de) | 2005-12-23 | 2008-08-21 | Ems Chemie Ag | Polyamid-EVA Mischungen |
| US20080161438A1 (en) * | 2006-12-28 | 2008-07-03 | Xingwang Wang | Composition comprising copolyetherester elastomer |
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2008
- 2008-03-04 DE DE102008012516A patent/DE102008012516A1/de not_active Withdrawn
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- 2009-02-26 BR BRPI0900769-5A patent/BRPI0900769B1/pt not_active IP Right Cessation
- 2009-02-27 CA CA2656482A patent/CA2656482C/en not_active Expired - Fee Related
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|---|---|
| CA2656482A1 (en) | 2009-09-04 |
| BRPI0900686A2 (pt) | 2010-05-04 |
| BRPI0900769B1 (pt) | 2019-04-24 |
| CA2656482C (en) | 2016-08-02 |
| JP2009209370A (ja) | 2009-09-17 |
| US20090227725A1 (en) | 2009-09-10 |
| CN101525471A (zh) | 2009-09-09 |
| JP5770416B2 (ja) | 2015-08-26 |
| US7943694B2 (en) | 2011-05-17 |
| BRPI0900769A2 (pt) | 2010-04-06 |
| BRPI0900686B1 (pt) | 2019-04-24 |
| DE102008012516A1 (de) | 2009-09-10 |
| MX2009002086A (es) | 2009-09-28 |
| CN105111694A (zh) | 2015-12-02 |
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