CN105108168A - 一种新型高分子保护剂包覆的纳米银颗粒的制备方法 - Google Patents
一种新型高分子保护剂包覆的纳米银颗粒的制备方法 Download PDFInfo
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- CN105108168A CN105108168A CN201510562354.XA CN201510562354A CN105108168A CN 105108168 A CN105108168 A CN 105108168A CN 201510562354 A CN201510562354 A CN 201510562354A CN 105108168 A CN105108168 A CN 105108168A
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- 238000002360 preparation method Methods 0.000 title claims abstract description 20
- 229920002521 macromolecule Polymers 0.000 title claims abstract description 9
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 title claims description 23
- 239000000243 solution Substances 0.000 claims abstract description 42
- 239000011347 resin Substances 0.000 claims abstract description 26
- 229920005989 resin Polymers 0.000 claims abstract description 26
- 239000003638 chemical reducing agent Substances 0.000 claims abstract description 11
- 239000011259 mixed solution Substances 0.000 claims abstract description 10
- 235000011114 ammonium hydroxide Nutrition 0.000 claims abstract description 9
- 238000006243 chemical reaction Methods 0.000 claims abstract description 8
- 239000003002 pH adjusting agent Substances 0.000 claims abstract description 7
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 19
- 229920000642 polymer Polymers 0.000 claims description 19
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 15
- 229910052709 silver Inorganic materials 0.000 claims description 14
- 239000004332 silver Substances 0.000 claims description 14
- -1 acryl Chemical group 0.000 claims description 13
- NWZSZGALRFJKBT-KNIFDHDWSA-N (2s)-2,6-diaminohexanoic acid;(2s)-2-hydroxybutanedioic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O.NCCCC[C@H](N)C(O)=O NWZSZGALRFJKBT-KNIFDHDWSA-N 0.000 claims description 12
- IKDUDTNKRLTJSI-UHFFFAOYSA-N hydrazine monohydrate Substances O.NN IKDUDTNKRLTJSI-UHFFFAOYSA-N 0.000 claims description 12
- 238000003756 stirring Methods 0.000 claims description 10
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 claims description 8
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 claims description 8
- 239000007864 aqueous solution Substances 0.000 claims description 7
- KWSLGOVYXMQPPX-UHFFFAOYSA-N 5-[3-(trifluoromethyl)phenyl]-2h-tetrazole Chemical compound FC(F)(F)C1=CC=CC(C2=NNN=N2)=C1 KWSLGOVYXMQPPX-UHFFFAOYSA-N 0.000 claims description 4
- 229960005070 ascorbic acid Drugs 0.000 claims description 4
- 235000010323 ascorbic acid Nutrition 0.000 claims description 4
- 239000011668 ascorbic acid Substances 0.000 claims description 4
- 239000002270 dispersing agent Substances 0.000 claims description 4
- 239000011814 protection agent Substances 0.000 claims description 4
- 229910001961 silver nitrate Inorganic materials 0.000 claims description 4
- 239000012279 sodium borohydride Substances 0.000 claims description 4
- 229910000033 sodium borohydride Inorganic materials 0.000 claims description 4
- 229910001379 sodium hypophosphite Inorganic materials 0.000 claims description 4
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 claims description 3
- 229920001577 copolymer Polymers 0.000 claims description 3
- 238000012544 monitoring process Methods 0.000 claims description 3
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 claims description 3
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- 238000011160 research Methods 0.000 abstract description 2
- 150000003839 salts Chemical class 0.000 abstract description 2
- FOIXSVOLVBLSDH-UHFFFAOYSA-N Silver ion Chemical compound [Ag+] FOIXSVOLVBLSDH-UHFFFAOYSA-N 0.000 abstract 5
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 abstract 2
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 abstract 1
- 150000007513 acids Chemical class 0.000 abstract 1
- PLKATZNSTYDYJW-UHFFFAOYSA-N azane silver Chemical compound N.[Ag] PLKATZNSTYDYJW-UHFFFAOYSA-N 0.000 abstract 1
- 229940083025 silver preparation Drugs 0.000 abstract 1
- 239000007788 liquid Substances 0.000 description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
- 239000008367 deionised water Substances 0.000 description 4
- 229910021641 deionized water Inorganic materials 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- 230000002572 peristaltic effect Effects 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 239000004020 conductor Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 1
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- 230000018109 developmental process Effects 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 1
- JRBPAEWTRLWTQC-UHFFFAOYSA-N dodecylamine Chemical compound CCCCCCCCCCCCN JRBPAEWTRLWTQC-UHFFFAOYSA-N 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 239000000463 material Substances 0.000 description 1
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- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000007634 remodeling Methods 0.000 description 1
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
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CN201510562354.XA CN105108168B (zh) | 2015-09-08 | 2015-09-08 | 一种新型高分子保护剂包覆的纳米银颗粒的制备方法 |
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CN201510562354.XA CN105108168B (zh) | 2015-09-08 | 2015-09-08 | 一种新型高分子保护剂包覆的纳米银颗粒的制备方法 |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106041352A (zh) * | 2016-08-17 | 2016-10-26 | 武汉工程大学 | 一种有机酸银包覆纳米银颗粒及其制备方法和应用 |
CN115338400A (zh) * | 2022-08-18 | 2022-11-15 | 华中科技大学 | 一种稳定的低硼纳米银溶胶及其制备方法 |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2006118010A (ja) * | 2004-10-22 | 2006-05-11 | Toda Kogyo Corp | Agナノ粒子及びその製造方法、Agナノ粒子の分散溶液 |
CN102218541A (zh) * | 2010-04-16 | 2011-10-19 | 上海赛瓦纳米银材料科技有限公司 | 一种水溶性纳米银的新型大规模制备方法 |
CN102294492A (zh) * | 2011-08-04 | 2011-12-28 | 翔瑞(泉州)纳米科技有限公司 | 一种聚合物表面保护单分散纳米银颗粒及制备方法 |
CN102391716A (zh) * | 2011-09-06 | 2012-03-28 | 天津大学 | 柔印纳米银导电墨水及其制备方法 |
CN102935513A (zh) * | 2012-10-17 | 2013-02-20 | 武汉康银高科有限公司 | 一种稳定的纳米银溶胶与制备方法 |
CN103059492A (zh) * | 2012-12-31 | 2013-04-24 | 武汉理工大学 | 一种高Ag含量Ag/PMMA纳米复合材料的制备方法 |
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2015
- 2015-09-08 CN CN201510562354.XA patent/CN105108168B/zh active Active
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2006118010A (ja) * | 2004-10-22 | 2006-05-11 | Toda Kogyo Corp | Agナノ粒子及びその製造方法、Agナノ粒子の分散溶液 |
CN102218541A (zh) * | 2010-04-16 | 2011-10-19 | 上海赛瓦纳米银材料科技有限公司 | 一种水溶性纳米银的新型大规模制备方法 |
CN102294492A (zh) * | 2011-08-04 | 2011-12-28 | 翔瑞(泉州)纳米科技有限公司 | 一种聚合物表面保护单分散纳米银颗粒及制备方法 |
CN102391716A (zh) * | 2011-09-06 | 2012-03-28 | 天津大学 | 柔印纳米银导电墨水及其制备方法 |
CN102935513A (zh) * | 2012-10-17 | 2013-02-20 | 武汉康银高科有限公司 | 一种稳定的纳米银溶胶与制备方法 |
CN103059492A (zh) * | 2012-12-31 | 2013-04-24 | 武汉理工大学 | 一种高Ag含量Ag/PMMA纳米复合材料的制备方法 |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106041352A (zh) * | 2016-08-17 | 2016-10-26 | 武汉工程大学 | 一种有机酸银包覆纳米银颗粒及其制备方法和应用 |
CN106041352B (zh) * | 2016-08-17 | 2018-05-01 | 武汉工程大学 | 一种有机酸银包覆纳米银颗粒及其制备方法和应用 |
CN115338400A (zh) * | 2022-08-18 | 2022-11-15 | 华中科技大学 | 一种稳定的低硼纳米银溶胶及其制备方法 |
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Address after: 266500 Room 241, Qingdao Sino-German Eco-Park Management Committee, 2877 Tuanjie Road, Huangdao District, Qingdao City, Shandong Province Patentee after: Qingdao North Indomac Incubation Co.,Ltd. Address before: 266500 Building 36, 396 Emeishan Road, Huangdao District, Qingdao City, Shandong Province Patentee before: BEIJING INSTITUTE OF GRAPHIC COMMUNICATION QINGDAO RESEARCH INSTITUTE Co.,Ltd. |
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Effective date of registration: 20181221 Address after: 266555 Room 298, Qingdao Sino-German Eco-Park Management Committee, 2877 Tuanjie Road, Huangdao District, Qingdao City, Shandong Province Patentee after: QINGDAO NANOPRIN NEW MATERIAL TECHNOLOGY CO.,LTD. Address before: 266500 Room 241, Qingdao Sino-German Eco-Park Management Committee, 2877 Tuanjie Road, Huangdao District, Qingdao City, Shandong Province Patentee before: Qingdao North Indomac Incubation Co.,Ltd. |
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Effective date of registration: 20231221 Address after: Building 9, No. 16 Chuangxin Avenue, Changzhou Street, Rongchang District, Chongqing, 400000 (self committed) Patentee after: Chongqing Yinghexin Electronic Technology Co.,Ltd. Address before: 266555 Room 298, Qingdao Sino-German Eco-Park Management Committee, 2877 Tuanjie Road, Huangdao District, Qingdao City, Shandong Province Patentee before: QINGDAO NANOPRIN NEW MATERIAL TECHNOLOGY CO.,LTD. |