CN105268992A - 一种网状的二维片状银粉及其液相合成方法 - Google Patents
一种网状的二维片状银粉及其液相合成方法 Download PDFInfo
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- CN105268992A CN105268992A CN201510809407.3A CN201510809407A CN105268992A CN 105268992 A CN105268992 A CN 105268992A CN 201510809407 A CN201510809407 A CN 201510809407A CN 105268992 A CN105268992 A CN 105268992A
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- silver powder
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- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 title claims abstract description 65
- 239000007791 liquid phase Substances 0.000 title claims description 19
- 238000001308 synthesis method Methods 0.000 title 1
- 238000000034 method Methods 0.000 claims abstract description 30
- 239000011347 resin Substances 0.000 claims abstract description 19
- 229920005989 resin Polymers 0.000 claims abstract description 19
- 239000002245 particle Substances 0.000 claims abstract description 10
- 239000002105 nanoparticle Substances 0.000 claims abstract description 6
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 4
- 239000000463 material Substances 0.000 claims abstract description 4
- 239000000243 solution Substances 0.000 claims description 71
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 claims description 36
- 230000003647 oxidation Effects 0.000 claims description 22
- 238000007254 oxidation reaction Methods 0.000 claims description 22
- 239000008367 deionised water Substances 0.000 claims description 21
- 229910021641 deionized water Inorganic materials 0.000 claims description 21
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 21
- 230000015572 biosynthetic process Effects 0.000 claims description 19
- 229960005070 ascorbic acid Drugs 0.000 claims description 18
- 235000010323 ascorbic acid Nutrition 0.000 claims description 18
- 239000011668 ascorbic acid Substances 0.000 claims description 18
- 239000011790 ferrous sulphate Substances 0.000 claims description 17
- 235000003891 ferrous sulphate Nutrition 0.000 claims description 17
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 claims description 17
- 229910000359 iron(II) sulfate Inorganic materials 0.000 claims description 17
- 238000003786 synthesis reaction Methods 0.000 claims description 17
- PXIPVTKHYLBLMZ-UHFFFAOYSA-N Sodium azide Chemical compound [Na+].[N-]=[N+]=[N-] PXIPVTKHYLBLMZ-UHFFFAOYSA-N 0.000 claims description 14
- 239000003638 chemical reducing agent Substances 0.000 claims description 13
- GGCZERPQGJTIQP-UHFFFAOYSA-N sodium;9,10-dioxoanthracene-2-sulfonic acid Chemical compound [Na+].C1=CC=C2C(=O)C3=CC(S(=O)(=O)O)=CC=C3C(=O)C2=C1 GGCZERPQGJTIQP-UHFFFAOYSA-N 0.000 claims description 12
- FOIXSVOLVBLSDH-UHFFFAOYSA-N Silver ion Chemical compound [Ag+] FOIXSVOLVBLSDH-UHFFFAOYSA-N 0.000 claims description 11
- 239000011259 mixed solution Substances 0.000 claims description 9
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 7
- 238000006243 chemical reaction Methods 0.000 claims description 7
- JUINSXZKUKVTMD-UHFFFAOYSA-N hydrogen azide Chemical compound N=[N+]=[N-] JUINSXZKUKVTMD-UHFFFAOYSA-N 0.000 claims description 7
- 238000002156 mixing Methods 0.000 claims description 7
- 229910017604 nitric acid Inorganic materials 0.000 claims description 7
- 238000002360 preparation method Methods 0.000 claims description 7
- 239000012266 salt solution Substances 0.000 claims description 7
- 238000003756 stirring Methods 0.000 claims description 7
- 238000005406 washing Methods 0.000 claims description 7
- 238000005303 weighing Methods 0.000 claims description 7
- 229920002521 macromolecule Polymers 0.000 claims description 4
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 claims description 4
- 238000007711 solidification Methods 0.000 claims description 4
- 230000008023 solidification Effects 0.000 claims description 4
- 238000001723 curing Methods 0.000 claims description 3
- 230000003014 reinforcing effect Effects 0.000 claims description 3
- 239000011859 microparticle Substances 0.000 claims description 2
- 229910001961 silver nitrate Inorganic materials 0.000 claims description 2
- 239000012074 organic phase Substances 0.000 abstract description 2
- 229910052709 silver Inorganic materials 0.000 abstract description 2
- 239000004332 silver Substances 0.000 abstract description 2
- 239000010408 film Substances 0.000 description 7
- 238000010438 heat treatment Methods 0.000 description 6
- 238000001035 drying Methods 0.000 description 5
- 239000002002 slurry Substances 0.000 description 5
- 239000002253 acid Substances 0.000 description 3
- 125000000852 azido group Chemical group *N=[N+]=[N-] 0.000 description 3
- 238000000498 ball milling Methods 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 239000012752 auxiliary agent Substances 0.000 description 2
- 230000005611 electricity Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000005693 optoelectronics Effects 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 241000276425 Xiphophorus maculatus Species 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 239000007772 electrode material Substances 0.000 description 1
- 239000012776 electronic material Substances 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000007667 floating Methods 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 238000013035 low temperature curing Methods 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 230000008054 signal transmission Effects 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
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- Manufacture Of Metal Powder And Suspensions Thereof (AREA)
Abstract
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Priority Applications (1)
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CN201510809407.3A CN105268992B (zh) | 2015-11-20 | 2015-11-20 | 一种网状的二维片状银粉及其液相合成方法 |
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CN201510809407.3A CN105268992B (zh) | 2015-11-20 | 2015-11-20 | 一种网状的二维片状银粉及其液相合成方法 |
Publications (2)
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CN105268992A true CN105268992A (zh) | 2016-01-27 |
CN105268992B CN105268992B (zh) | 2018-07-31 |
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Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105913897A (zh) * | 2016-06-01 | 2016-08-31 | 江苏泓源光电科技股份有限公司 | 一种低银含量的晶体硅太阳能电池银浆及其制备方法 |
CN106409379A (zh) * | 2016-07-21 | 2017-02-15 | 江苏国瓷泓源光电科技有限公司 | 一种晶体硅太阳能电池背电极用低串阻银浆及其制备方法 |
CN107633960A (zh) * | 2017-09-11 | 2018-01-26 | 大连大学 | 一种片状铁成网状分布强化的银基电触头材料及其制备方法 |
CN108555312A (zh) * | 2018-04-19 | 2018-09-21 | 湖南省国银新材料有限公司 | 一种片状银粉的制备方法 |
CN110860698A (zh) * | 2019-11-12 | 2020-03-06 | 广东羚光新材料股份有限公司 | 一种网状银粉及其制备方法和应用 |
CN113245554A (zh) * | 2021-04-21 | 2021-08-13 | 中山大学 | 一种银多孔材料及其制备方法 |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101569935A (zh) * | 2009-06-05 | 2009-11-04 | 中国乐凯胶片集团公司 | 一种片状微米银粉的制备方法 |
CN101708555A (zh) * | 2009-11-26 | 2010-05-19 | 上海大学 | 一种片状银粉的制备方法 |
KR20130004064A (ko) * | 2011-06-30 | 2013-01-09 | 미쓰이 긴조꾸 고교 가부시키가이샤 | 소결형 도전성 페이스트용 은분 |
CN102974839A (zh) * | 2012-12-04 | 2013-03-20 | 中山大学 | 化学沉积法制备纳米厚度片状银粉的方法 |
CN104470656A (zh) * | 2012-07-18 | 2015-03-25 | 福田金属箔粉工业株式会社 | 极薄小薄片状银粉及其制造方法 |
CN104690286A (zh) * | 2013-12-10 | 2015-06-10 | 上海拓引数码技术有限公司 | 片状和球状混合银粉及其制备方法 |
-
2015
- 2015-11-20 CN CN201510809407.3A patent/CN105268992B/zh active Active
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101569935A (zh) * | 2009-06-05 | 2009-11-04 | 中国乐凯胶片集团公司 | 一种片状微米银粉的制备方法 |
CN101708555A (zh) * | 2009-11-26 | 2010-05-19 | 上海大学 | 一种片状银粉的制备方法 |
KR20130004064A (ko) * | 2011-06-30 | 2013-01-09 | 미쓰이 긴조꾸 고교 가부시키가이샤 | 소결형 도전성 페이스트용 은분 |
CN104470656A (zh) * | 2012-07-18 | 2015-03-25 | 福田金属箔粉工业株式会社 | 极薄小薄片状银粉及其制造方法 |
CN102974839A (zh) * | 2012-12-04 | 2013-03-20 | 中山大学 | 化学沉积法制备纳米厚度片状银粉的方法 |
CN104690286A (zh) * | 2013-12-10 | 2015-06-10 | 上海拓引数码技术有限公司 | 片状和球状混合银粉及其制备方法 |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105913897A (zh) * | 2016-06-01 | 2016-08-31 | 江苏泓源光电科技股份有限公司 | 一种低银含量的晶体硅太阳能电池银浆及其制备方法 |
CN106409379A (zh) * | 2016-07-21 | 2017-02-15 | 江苏国瓷泓源光电科技有限公司 | 一种晶体硅太阳能电池背电极用低串阻银浆及其制备方法 |
CN107633960A (zh) * | 2017-09-11 | 2018-01-26 | 大连大学 | 一种片状铁成网状分布强化的银基电触头材料及其制备方法 |
CN108555312A (zh) * | 2018-04-19 | 2018-09-21 | 湖南省国银新材料有限公司 | 一种片状银粉的制备方法 |
CN110860698A (zh) * | 2019-11-12 | 2020-03-06 | 广东羚光新材料股份有限公司 | 一种网状银粉及其制备方法和应用 |
CN110860698B (zh) * | 2019-11-12 | 2022-09-13 | 广东羚光新材料股份有限公司 | 一种网状银粉及其制备方法和应用 |
CN113245554A (zh) * | 2021-04-21 | 2021-08-13 | 中山大学 | 一种银多孔材料及其制备方法 |
CN113245554B (zh) * | 2021-04-21 | 2022-07-12 | 中山大学 | 一种银多孔材料及其制备方法 |
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CN105268992B (zh) | 2018-07-31 |
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Address after: 316022 No. 1, Haida South Road, Lincheng street, Dinghai District, Zhoushan, Zhejiang Patentee after: Zhejiang Ocean University Country or region after: China Address before: 316022 No. 1, Haida South Road, Lincheng street, Dinghai District, Zhoushan, Zhejiang Patentee before: ZHEJIANG OCEAN University Country or region before: China |
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Effective date of registration: 20240511 Address after: Room 203, Building 2, Northwest District, Nanocity, No. 99 Jinjihu Avenue, Suzhou Industrial Park, Suzhou City, Jiangsu Province, 215100 Patentee after: Suzhou Hongpai Technology Co.,Ltd. Country or region after: China Address before: 316022 No. 1, Haida South Road, Lincheng street, Dinghai District, Zhoushan, Zhejiang Patentee before: Zhejiang Ocean University Country or region before: China |