CN105101793A - 农园艺用颗粒剂的制造方法 - Google Patents
农园艺用颗粒剂的制造方法 Download PDFInfo
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- CN105101793A CN105101793A CN201480017763.5A CN201480017763A CN105101793A CN 105101793 A CN105101793 A CN 105101793A CN 201480017763 A CN201480017763 A CN 201480017763A CN 105101793 A CN105101793 A CN 105101793A
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- agricultural
- manufacture method
- horticultural use
- screw rod
- screw
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- WOSNCVAPUOFXEH-UHFFFAOYSA-N thifluzamide Chemical compound S1C(C)=NC(C(F)(F)F)=C1C(=O)NC1=C(Br)C=C(OC(F)(F)F)C=C1Br WOSNCVAPUOFXEH-UHFFFAOYSA-N 0.000 description 1
- VJQYLJSMBWXGDV-UHFFFAOYSA-N tiadinil Chemical compound N1=NSC(C(=O)NC=2C=C(Cl)C(C)=CC=2)=C1C VJQYLJSMBWXGDV-UHFFFAOYSA-N 0.000 description 1
- WPALTCMYPARVNV-UHFFFAOYSA-N tolfenpyrad Chemical compound CCC1=NN(C)C(C(=O)NCC=2C=CC(OC=3C=CC(C)=CC=3)=CC=2)=C1Cl WPALTCMYPARVNV-UHFFFAOYSA-N 0.000 description 1
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Abstract
本发明提供一种农园艺用颗粒剂的制造方法，其特征在于，是使用卧式挤出造粒机将粉末状农药组合物成型为颗粒的农园艺用颗粒剂的制造方法，上述卧式挤出造粒机具有：用于供给上述粉末状农药组合物和水的混炼物的料斗、用于捏合并挤出上述混炼物的螺杆、收纳上述螺杆的螺杆箱、为了将上述经捏合的混炼物成型为束状而设置于远离上述料斗的一侧的与螺杆轴平行的螺杆箱壁的筛网和用于对远离上述料斗的一侧的螺杆的轴承侧的螺杆箱壁进行冷却的冷却机构，上述粉末状农药组合物合计含有20～80重量％的在水温20℃、pH3～9的条件下的水溶解度为4000～500000ppm的成分。
Description
技术领域
本发明涉及一种农园艺用颗粒剂的制造方法。更详细而言，本发明涉及一种稳定地且长时间连续地制造农园艺用颗粒剂的方法。
本申请基于2013年3月26日在日本申请的特愿2013-065229号主张优先权，并将其内容援引于此。
背景技术
通过使用卧式挤出造粒机或前挤出造粒机，将含有农药活性成分的粉末成型为颗粒来制造农园艺用颗粒剂(非专利文献1)。
一般地，卧式挤出造粒机为如下装置：具有用于供给粉末的料斗、螺杆箱、在螺杆箱内旋转而用于对供给的粉末进行捏合并挤出的至少1根螺杆、以及为了将经捏合的粉末成型为束状而设置于远离料斗的一侧的与螺杆轴平行的螺杆箱壁的筛网；该装置以使制冷剂流入螺杆轴的内腔、料斗侧的与螺杆轴平行的螺杆箱壁的内腔而能够控制螺杆和螺杆箱的温度的方式形成。
连续实施造粒时，发生造粒机的筛网的堵塞和局部造粒物的排出。这些是由于造粒机的排出特性和由连续运转产生的摩擦热，由摩擦热而导致筛网的温度上升，因此筛网干燥，发生堵塞。
造粒时的挤出压力高时，即使发生筛网堵塞，通过来自内侧的压力而要消除堵塞的力起作用，从而能够长时间运转。
但是，农药活性成分或载体是水溶性成分时，混炼物的温度高时水溶性成分溶解于添加水中，相对于固体成分的水的比率变高，造粒时的挤出压力降低。
现有技术文献
非专利文献
非专利文献1:“MOSPIRAN颗粒可溶性粉剂”农业时代，第193号，2012年，38～42页
发明内容
因此，对于以往的农园艺用颗粒剂的制造方法，在卧式挤出造粒机中，如果要长时间连续地将含有大量的水溶解度高的成分的农药组合物成型为颗粒，则有时筛网堵塞。另外，有时从筛网挤出的线束彼此熔合形成线球状的块。
因此，本发明的课题在于提供使用含有大量的水溶解度高的成分的农药组合物，稳定且长时间连续地制造农园艺用颗粒剂的方法。
本发明人为了解决上述课题进行研究，结果完成了包含以下方式的本发明。
〔1〕一种农园艺用颗粒剂的制造方法，其特征在于，是使用卧式挤出造粒机将粉末状农药组合物成型为颗粒的农园艺用颗粒剂的制造方法，上述卧式挤出造粒机具有：
用于供给上述粉末状农药组合物和水的混炼物的料斗，
用于捏合并挤出上述混炼物的螺杆，
收纳上述螺杆的螺杆箱，
为了将上述经捏合的混炼物成型为束状而设置于远离上述料斗的一侧的与螺杆轴平行的螺杆箱壁的筛网，
用于对远离上述料斗的一侧的螺杆的轴承侧的螺杆箱壁进行冷却的冷却机构，
上述粉末状农药组合物合计含有20～80重量％的在水温20℃、pH3～9的条件下的水溶解度为4000～500000ppm的成分。
〔2〕根据〔1〕所述的农园艺用颗粒剂的制造方法，其中，上述冷却机构为点式冷却器(スポットクーラー)。
〔3〕根据〔2〕所述的农园艺用颗粒剂的制造方法，其特征在于，用上述点式冷却器吹送的空气的温度为0～25℃。
〔4〕根据〔1〕～〔3〕中任一项所述的农园艺用颗粒剂的制造方法，其特征在于，上述粉末状农药组合物含有在水温20℃、pH3～9的条件下的水溶解度为4000～500000ppm的农药活性成分。
〔5〕根据〔4〕所述的农园艺用颗粒剂的制造方法，其特征在于，上述农药活性成分为新烟碱系杀虫成分。
〔6〕根据〔5〕所述的农园艺用颗粒剂的制造方法，其特征在于，上述新烟碱系杀虫成分为啶虫脒、呋虫胺或噻虫嗪。
〔7〕根据〔1〕～〔6〕中任一项所述的农园艺用颗粒剂的制造方法，其特征在于，上述粉末状农药组合物含有在水温20℃、pH3～9的条件下的水溶解度为4000～500000ppm的载体。
〔8〕根据〔6〕所述的农园艺用颗粒剂的制造方法，其特征在于，上述载体为卤化金属盐、碳酸金属盐、硫酸金属盐、铵盐、脲、单糖类、二糖类、或多糖类。
根据本发明的方法，在农园艺用颗粒剂的制造中，即使农药组合物含有大量的水溶解度高的成分时从筛网挤出的线束彼此也不熔合，且不会使筛网堵塞，能够长期间连续地制造农园艺用颗粒剂。
附图说明
图1是在本发明的一个实施方式的制造方法中使用的卧式挤出造粒机的侧视透视图。
图2是在本发明的一个实施方式的制造方法中使用的卧式挤出造粒机的俯视透视图。
图3是表示颗粒剂制造设备的一个实施方式的图。
具体实施方式
参照附图对本发明的一个实施方式进行说明。但是，本发明不限定于在此说明的实施方式，在不违背本发明的主旨的范围内，也包含对构成进行修正、追加或省略而成的构成。
本发明的农园艺用颗粒剂的制造方法包括使用卧式挤出造粒机1将粉末状农药组合物和水的混炼物2成型为颗粒剂。
上述粉末状农药组合物合计含有10～90重量％的水溶解度4000～500000ppm(水温20℃、pH3～9)的成分，优选含有20～80重量％，更优选含有25～65重量％。
对于上述粉末状农药组合物，可含有水溶解度4000～500000ppm(水温20℃、pH3～9)的农药活性成分作为上述水溶解度4000～500000ppm(水温20℃、pH3～9)的成分。作为这样的农药活性成分，例如，可举出1-萘乙酸钠、MDBA钾盐、啶虫脒、双胍辛胺乙酸盐、双胍辛胺苯磺酸盐、烟碱硫磷(Imicyafos)、草甘膦铵盐、草甘膦异丙胺盐、草铵膦、草铵膦P钠盐、呋虫胺、环丙氨嗪、丁酰肼、噻虫嗪、特糠酯酮(Tefuryltrione)、苯唑草酮、嘧舒藩(Pyrimisulfan)、氟吡磺隆、氟啶虫酰胺、毫姆拉斯如富隆(ホムラスルフロン)、硝磺草酮、甲霜灵、甲霜灵M、碘甲烷、嗪吡嘧磺隆(Metazosulfuron)等。这些活性成分可以单独使用或混合几种使用。
而且，这些活性成分之中，优选新烟碱系杀虫成分，更优选啶虫脒、呋虫胺和噻虫嗪。
上述粉末状农药组合物可含有水溶解度4000～500000ppm(水温20℃、pH3～9)的载体作为上述水溶解度4000～500000ppm(水温20℃、pH3～9)的成分。作为这样的载体，优选无机盐类和糖类。
作为无机盐类，例如可例示卤化金属盐(例如：氯化钾、氯化钠、氯化钙等)、碳酸金属盐(例如：碳酸钠、碳酸铝等)、硫酸金属盐(例：硫酸钠、硫酸镁、硫酸铜等)、铵盐(例如：氯化铵、硫酸铵、硝酸铵等)、脲等。
作为糖类，可例示单糖类(例如：葡萄糖、半乳糖等)、二糖类(例如：蔗糖、乳糖、白糖等)、多糖类(例如：淀粉等)等，优选为二糖类，特别优选乳糖。
这些无机盐或糖类可以单独使用，也可以混合多种使用。
上述粉末状农药组合物可以进一步含有其它原体。作为这样的原体，例如，可举出四唑嘧磺隆、灭螨醌、嘧菌酯、阿维菌素、吲唑磺菌胺、甲草胺、异噻菌胺、稻瘟灵、艾分卡巴腙(Ipfencarbazone)、烟碱硫磷(Imicyafos)、吡虫啉、亚胺唑、三嗪茚草胺(Indaziflam)、茚草酮、茚虫威、茚虫威MP、烯效唑P、戊草丹、噻唑菌胺、吲唑酯、乙虫腈、乙螨唑、醚菊酯、草酮、丙炔草酮、嗪草酮、喹酸、肟醚菌胺、硫线磷、唑草胺、环丙酰菌胺、苄草隆、醚菌酯、噻虫胺、环虫酰肼、稗草胺、氯虫苯甲酰胺、溴虫腈、氯酞酰亚胺(Chlorphthalim)、氰霜唑、腈吡螨酯、双氯氰菌胺、二氰蒽醌、氟硫草定、苯醚甲环唑、环氟菌胺、丁氟螨酯、硅氟唑、异戊乙净、噻吩草胺P、烯酰吗啉、氟硅菊酯、乙基多杀菌素、多杀菌素、螺螨酯、螺虫乙酯、螺甲螨酯、杀草隆、噻酰菌胺、溴氟唑菌、戊唑醇、虫酰肼、异丁乙氧喹啉(Tebufloquin)、抗倒酯、肟菌酯、唑虫酰胺、氟乐灵、氟酰脲、多效唑、氯吡嘧磺隆、联苯肼酯、联苯菊酯、吡蚜酮、唑菌胺酯、双唑草腈、吡草醚、皮里奥芬(Pyriofenone，ピリオフェノン)、哒螨灵、三氟甲吡醚、环酯草醚、稗草畏、吡氟喹虫唑(Pyrifluquinazon)、吡丙醚、吡菌苯威、嘧啶硫蕃(Pyrimisulfan)、嘧草醚、氰菌胺、嘧菌腙、咪唑菌酮、四唑酰草胺、胺苯吡菌酮、腈苯唑、环酰菌胺、丁草胺、抑草磷、噻嗪酮、呋吡菌胺、嘧螨酯、氟吡菌胺、氟吡菌酰胺、氟唑菌酰胺、咯菌腈、氟吡磺隆、氟替尼(Flutianil，フルチアニル)、氟酰胺、氟虫脲、氟虫双酰胺、氟胺草唑、呋嘧醇、丙草胺、苄草丹、氟啶虫酰胺、霜霉威盐酸盐、茉莉酮、丙嗪嘧磺隆、溴丁酰草胺、五氟磺草胺、戊菌隆、苄嘧磺隆、双环磺草酮、苯噻菌胺、灭草丹、吡噻菌胺、二甲戊乐灵、环戊草酮、氟唑菌苯胺、呋草黄、啶酰菌胺、双炔酰菌胺、腈菌唑、密灭汀、2-甲-4-氯丙酸P异丙胺盐、四聚乙醛、甲氧虫酰肼、叶菌唑、苯氧菌胺、异丙甲草胺、S-异丙甲草胺、苯噻草胺、灭锈胺、虱螨脲、林皮没丁(Lepimectin)、EPN、IBP、MPP(倍硫磷)、PAP(稻丰散)、1-甲基环丙烯等。这些之中，优选吡虫啉、噻唑菌胺、醚菌酯、噻虫胺、环氟菌胺、乙基多杀菌素、多杀菌素、虫酰肼、联苯菊酯、吡菌苯威、嘧螨酯、氟替尼、氟虫双酰胺、氟胺草唑等。
上述粉末状农药组合物可以使用粘土等这样的在水中不溶的载体。
本发明的制造方法中，在上述粉末状农药组合物中添加的水的量可以根据粉末状农药组合物的成分、量等而适当地调整，但优选为5～25重量％。
上述粉末状农药组合物通过合成农药活性成分等各个成分，对上述各个成分采用公知的方法进行精制、干燥，接下来根据需要进行混合并粉碎而得到。例如，对于图3所示的制造设备，在混合槽A中添加农药活性成分、载体、表面活性剂、展开剂等任意成分并在混合槽A中混合。利用螺旋送料器B对得到的混合物进行流量调整并供给连续式混炼机C。另外，同时利用定量泵D对水进行流量调整并供给连续式混炼器C。在连续式混炼机C内对混合物和水进行捏合，得到农药组合物和水的混炼物2。
本发明中使用的卧式挤出造粒机1(图1、图2)具有：用于供给粉末状农药组合物和水的混炼物2的料斗4、用于捏合并挤出上述混炼物2的螺杆6、收纳上述螺杆6的螺杆箱5、为了将经捏合的混炼物成型为束状而设置于远离上述料斗4的一侧的与螺杆轴平行的螺杆箱壁53的筛网7、以及用于对远离料斗4的一侧的螺杆的轴承侧的螺杆箱壁54进行冷却的冷却机构8。筛网7的温度优选为40～60℃。
另外，本发明中使用的卧式挤出造粒机1可以使制冷剂流过螺杆轴的内腔、料斗侧的与螺杆轴平行的螺杆箱壁52的内腔，从而能够控制螺杆6和螺杆箱5的温度。制冷剂通常采用水。流过螺杆轴的冷却水的温度优选为5～25℃。流过料斗侧的与螺杆轴平行的螺杆箱壁52的内腔的冷却水的温度优选为5～25℃。温度的测定可利用红外线传感器等进行测定。
在图1和图2所示的本发明的一个实施方式中，冷却机构8为送风机，向远离料斗4的一侧的螺杆的轴承侧的螺杆箱壁54吹送冷却用空气9。吹送的空气的温度优选为0～25℃。
刚从筛网7挤出后的束状成型物的温度优选为35～60℃。如图3所示，束状成型物用流动层干燥机E进行干燥。在流动干燥期间束状成型物被切短，成为颗粒。用圆形振动筛G对得到的颗粒进行分级，调整为规定大小的颗粒。
实施例
以下示出实施例和比较例，更详细地说明本发明。
比较例
在含有作为农药活性成分的啶虫脒20重量％、乳糖45重量％的粉末状的农药组合物中加入规定量的水进行捏合，利用卧式挤出造粒机，以约155kg-wet/小时开始连续生产颗粒直径0.7mmφ的束状的造粒湿品。
对于卧式挤出造粒机而言，2根螺杆可在螺杆箱内旋转并混炼，具备用于对螺杆的轴和料斗侧的与螺杆轴平行的螺杆箱的温度进行调整的水冷功能(水温20℃、pH3～9)和用于对从筛网挤出的造粒湿品进行冷却的送风机。
用设定温度65℃的送风干燥机(未图示)对得到的造粒湿品连续进行干燥而制成表观比重0.544～0.593、颗粒直径0.7mmφ的颗粒剂。刚开始生产后的造粒湿品的温度为40℃。
从开始连续生产经过24小时时，靠近料斗的一侧的筛网堵塞，从远离料斗的一侧的筛网挤出的线束凝结为线球状。此时的造粒湿品的温度超过64℃。
实施例
在含有作为农药活性成分的啶虫脒20重量％、乳糖45重量％的粉末状的农药组合物中加入规定量的水进行捏合，利用卧式挤出造粒机1，以约155kg-wet/小时开始连续生产颗粒直径0.7mmφ的束状的造粒湿品3。
对于卧式挤出造粒机1(图1、图2)而言，2根螺杆6可以在螺杆箱内旋转并混炼，具备用于对螺杆6的轴和料斗4侧的与螺杆轴平行的螺杆箱52的温度进行调整的水冷功能(水温20℃、pH3～9)和用于对从筛网7挤出的造粒湿品3进行冷却的送风机(未图示)。而且，实施例中使用的卧式挤出造粒机1具备冷却机构8(点式冷却器)，利用该冷却机构8对远离料斗4的一侧的螺杆轴承侧螺杆箱壁54吹送约15℃的冷却用空气9。
用设定温度65℃的送风干燥机(未图示)对得到的造粒湿品3进行连续干燥而制成表观比重0.544～0.593、颗粒直径0.7mmφ的颗粒剂。刚开始生产后的造粒湿品3的温度为40℃。
即使从开始连续生产经过48小时，筛网也不堵塞，能够稳定地生产束状的造粒湿品3。此时的造粒湿品3的温度为45℃，筛网7的温度约为50℃。
符号说明
1：卧式挤出造粒机
2：混炼物
3：造粒湿品
4：料斗
5：螺杆箱
52：料斗侧的与螺杆轴平行的螺杆箱壁
53：远离料斗的一侧的与螺杆轴平行的螺杆箱壁
54：远离料斗的一侧的螺杆的轴承侧的螺杆箱壁
6：螺杆
7：筛网
8：冷却机构(点式冷却器)
9：冷却用空气
Claims (8)
1.一种农园艺用颗粒剂的制造方法，其特征在于，是使用卧式挤出造粒机将粉末状农药组合物成型为颗粒的农园艺用颗粒剂的制造方法，所述卧式挤出造粒机具有：
用于供给所述粉末状农药组合物和水的混炼物的料斗；
用于捏合并挤出所述混炼物的螺杆；
收纳所述螺杆的螺杆箱；
为了将所述经捏合的混炼物成型为束状而设置于远离所述料斗的一侧的与螺杆轴平行的螺杆箱壁的筛网；
用于对远离所述料斗的一侧的螺杆的轴承侧的螺杆箱壁进行冷却的冷却机构，
所述粉末状农药组合物合计含有20～80重量％的在水温20℃、pH3～9的条件下的水溶解度为4000～500000ppm的成分。
2.根据权利要求1所述的农园艺用颗粒剂的制造方法，其中，所述冷却机构为点式冷却器。
3.根据权利要求2所述的农园艺用颗粒剂的制造方法，其特征在于，用所述点式冷却器吹送的空气的温度为0～25℃。
4.根据权利要求1～3中任一项所述的农园艺用颗粒剂的制造方法，其特征在于，所述粉末状农药组合物含有在水温20℃、pH3～9的条件下的水溶解度为4000～500000ppm的农药活性成分。
5.根据权利要求4所述的农园艺用颗粒剂的制造方法，其特征在于，所述农药活性成分为新烟碱系杀虫成分。
6.根据权利要求5所述的农园艺用颗粒剂的制造方法，其特征在于，所述新烟碱系杀虫成分为啶虫脒、呋虫胺或噻虫嗪。
7.根据权利要求1～6中任一项所述的农园艺用颗粒剂的制造方法，其特征在于，所述粉末状农药组合物含有在水温20℃、pH3～9的条件下的水溶解度为4000～500000ppm的载体。
8.根据权利要求6所述的农园艺用颗粒剂的制造方法，其特征在于，所述载体为卤化金属盐、碳酸金属盐、硫酸金属盐、铵盐、脲、单糖类、二糖类或多糖类。
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| CN1093641A (zh) * | 1993-04-16 | 1994-10-19 | 杨木苍 | 塑胶挤出急速冷却切割制粒法 |
| US5680812A (en) | 1995-01-23 | 1997-10-28 | Linsgeseder; Helmut | Apparatus and method for the extraction of vegetable oils |
| JP3988842B2 (ja) * | 1997-03-03 | 2007-10-10 | クミアイ化学工業株式会社 | 粒状農薬製剤の製造法 |
| US6752943B1 (en) * | 2002-12-31 | 2004-06-22 | United Phosphorus, Ltd. | Apparatus and process for granulating dry powder materials |
| CA2497332A1 (en) * | 2004-02-19 | 2005-08-19 | Dai-Ichi Kogyo Seiyaku Co., Ltd. | Water soluble nonionic alkylene oxide resin and production process therefor |
| US7591974B2 (en) * | 2006-01-25 | 2009-09-22 | Absorbent Technologies, Inc. | Methods for producing superabsorbent polymers for use in agricultural applications |
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| JP2013000940A (ja) * | 2011-06-14 | 2013-01-07 | Takahama Industry Co Ltd | 木質ペレット製造用の押出成形機 |
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| CN2063846U (zh) * | 1989-07-07 | 1990-10-17 | 化学工业部化工机械研究院 | 有剪切捏和件的单螺杆挤出造粒机 |
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| CN101669974A (zh) * | 2009-10-15 | 2010-03-17 | 江阴天江药业有限公司 | 熔融挤压法制备中药配方颗粒 |
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| PL2979547T3 (pl) | 2017-12-29 |
| KR101755140B1 (ko) | 2017-07-06 |
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| JPWO2014157028A1 (ja) | 2017-02-16 |
| US20160050913A1 (en) | 2016-02-25 |
| BR112015024357A2 (pt) | 2017-07-18 |
| BR112015024357B1 (pt) | 2021-01-12 |
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| NZ711533A (en) | 2016-05-27 |
| CN105101793B (zh) | 2017-04-19 |
| IL241717B (en) | 2018-01-31 |
| AU2014246011B2 (en) | 2016-10-13 |
| TWI608798B (zh) | 2017-12-21 |
| EP2979547A4 (en) | 2016-10-05 |
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