CN105025867A - Hair styling agent composition - Google Patents

Abstract

Provided is a hair styling agent composition with which flaking and stickiness after styling can be inhibited, and with which initial hair-styling properties and hair-style retention properties can be improved. A hair styling agent composition according to the present invention includes: at least 0.1 mass% but not more than 10 mass% of particles (component A) selected from the group consisting of silica, calcium carbonate, magnesium carbonate, hydroxyapatite, titanium oxide, zinc oxide, calcium silicate, magnesium silicate, aluminium silicate, and magnesium hydroxide; and a compound (component B) selected from the group consisting of polyoxyethylene/polyoxypropylene copolymers which are liquid at 25 DEG C, and which have a number average molecular weight in the range 10000 to 20000 inclusive, and polyoxypropylene sorbitol which is liquid at 25 DEG C, and which has a number average molecular weight in the range 300 to 1000 inclusive.

Description

Hair mousse compositions

Technical field

The present invention relates to hair mousse compositions, it is suitable for the hair mousse arranged hair.

Background technology

In order to arrange hair, use hair mousse compositions that is aqueous, the various character such as gel, paste and solid, shaped.In the past, in order to give the power of haircuting as major function to hair mousse compositions, the overlay film that uses formed polymer more.In the hair mousse compositions employing overlay film formation polymer, after haircuting, be derived from overlay film and form polymer and form overlay film on the surface of hair.Therefore, if mixture overlay film forms polymer as composition of mainly haircuting, initial stage after then just haircuting power of haircuting improves, be difficult to but then arrange hair with natural state, or when hair being stimulated with hands or comb etc. after haircuting, overlay film from the sur-face peeling of hair (producing so-called peeling off), can have the problems such as degraded appearance.

Therefore, be studied with the method diverse ways using overlay film to form polymer, specifically, have studied and use powder body to give to hair mousse compositions power of haircuting.

Patent Document 1 discloses a kind of hair cosmetic composition (hair mousse compositions) following, its specific surface area comprising 0.1 quality % ~ 10 quality % is 50m ²the fine-particle powder of/more than g.Following content is described: by using specific above-mentioned fine-particle powder with specific above-mentioned content in patent documentation 1, good sense of touch can be obtained, excellent power of haircuting can be obtained, and good sense of touch can be made to continue for a long time, and excellent haircuting property again can be obtained.

Prior art document

Patent documentation

Patent documentation 1: Japanese Unexamined Patent Publication 2003-342130 publication

Summary of the invention

The problem that invention will solve

But, as recorded in patent documentation 1, when using the hair mousse compositions comprising fine-particle powder to haircut, sometimes also can peel off.In addition, exist and require the more excellent initial stage to haircut power and the present situation of retentivity of haircuting.

The object of the present invention is to provide a kind of can suppress to peel off when haircuting generation and be clamminess and the hair mousse compositions of can haircut at the initial stage of improving power and retentivity of haircuting.

For solving the scheme of problem

Hair mousse compositions of the present invention is following hair mousse compositions, and it comprises following compositions (A) and following compositions (B), and the content of mentioned component (A) is below more than 0.1 quality % 10 quality %.

Composition (A): be selected from the granule in the group be made up of silicon dioxide, calcium carbonate, magnesium carbonate, hydroxyapatite, titanium dioxide, zinc oxide, calcium silicates, magnesium silicate, aluminium silicate and magnesium hydroxide

Composition (B): be selected from by being liquid and number-average molecular weight is the polyoxyethylene/polyoxypropylene copolymer of less than more than 10,000 20000 and the compound in the group that 25 DEG C be liquid state and the polyoxypropylene Sorbitol that number-average molecular weight is less than more than 300 1000 forms at 25 DEG C

In hair mousse compositions of the present invention, the content of mentioned component (B) is preferably below more than 3 quality % 40 quality %.

Hair mousse compositions of the present invention preferably comprises following compositions (C) further.

Composition (C): be selected from the compound in the group be made up of polyoxyalkylene alkyl glucoside and polyoxyalkylene fatty acid glyceride

Hair mousse compositions of the present invention preferably comprises the composition (D) as the polymer be selected from the group that is made up of following compositions (D1) and following compositions (D2) further.

Composition (D1): use the polymer being selected from the two or more monomer in the group be made up of (methyl) acrylic acid and (methyl) alkyl acrylate and obtaining as necessary monomer component

Composition (D2): the polymer that the monomer in using the monomer that is selected from the group be made up of (methyl) acrylic acid and (methyl) alkyl acrylate and being selected from the group that is made up of (methyl) acrylic acid polyoxyethylene alkyl ether, itaconic acid polyoxyethylene alkyl ether and vinyl neodecanoate obtains as necessary monomer component

Hair mousse compositions of the present invention preferably comprises the composition (E) as clay mineral further.

In hair mousse compositions of the present invention, the mass ratio of the content of mentioned component (D) and the content of mentioned component (E) is preferably 1:0.1 ~ 1:30.

The effect of invention

Hair mousse compositions of the present invention comprises specific composition (A) and specific composition (B), and then the content of composition (A) is in specific scope, therefore can suppress the generation of peeling off when haircuting and be clamminess, and can haircut at the initial stage of improving power and retentivity of haircuting.

Detailed description of the invention

Below, the present invention is described in detail

Hair mousse compositions of the present invention at least comprises: be selected from the granule in the group be made up of silicon dioxide, calcium carbonate, magnesium carbonate, hydroxyapatite, titanium dioxide, zinc oxide, calcium silicates, magnesium silicate, aluminium silicate and magnesium hydroxide; Be selected from by being liquid and number-average molecular weight is the polyoxyethylene/polyoxypropylene copolymer of less than more than 10,000 20000 and the compound in the group that 25 DEG C be liquid state and the polyoxypropylene Sorbitol that number-average molecular weight is less than more than 300 1000 forms at 25 DEG C.

In this description, sometimes above-mentioned " being selected from the granule in the group be made up of silicon dioxide, calcium carbonate, magnesium carbonate, hydroxyapatite, titanium dioxide, zinc oxide, calcium silicates, magnesium silicate, aluminium silicate and magnesium hydroxide " is called " composition (A) ".In addition, sometimes above-mentioned " be selected from by be liquid and number-average molecular weight is the polyoxyethylene/polyoxypropylene copolymer of less than more than 10,000 20000 and the compound in the group that 25 DEG C be liquid state and the polyoxypropylene Sorbitol that number-average molecular weight is less than more than 300 1000 forms at 25 DEG C " is called " composition (B) ".In addition, sometimes by above-mentioned " 25 DEG C be liquid and number-average molecular weight be less than more than 10,000 20000 polyoxyethylene/polyoxypropylene copolymer " be called " composition (B1) ", sometimes by above-mentioned " 25 DEG C be liquid state and number-average molecular weight be less than more than 300 1000 polyoxypropylene Sorbitol " be called " composition (B2) ".

Hair mousse compositions of the present invention preferably comprises the compound in the group being selected from and being made up of polyoxyalkylene alkyl glucoside and polyoxyalkylene fatty acid glyceride further.

In this description, sometimes above-mentioned " being selected from the compound in the group be made up of polyoxyalkylene alkyl glucoside and polyoxyalkylene fatty acid glyceride " is called " composition (C) ".In addition, sometimes above-mentioned " polyoxyalkylene alkyl glucoside " is called " composition (C1) ", sometimes above-mentioned " polyoxyalkylene fatty acid glyceride " is called " composition (C2) ".

Hair mousse compositions of the present invention preferably comprises the polymer in the group being selected from and being made up of following 1st polymer and following 2nd polymer further.1st polymer uses the polymer being selected from the two or more monomer in the group be made up of (methyl) acrylic acid and (methyl) alkyl acrylate and obtaining as necessary monomer component.2nd polymer is the polymer that the monomer in using the monomer that is selected from the group be made up of (methyl) acrylic acid and (methyl) alkyl acrylate and being selected from the group that is made up of (methyl) acrylic acid polyoxyethylene alkyl ether, itaconic acid polyoxyethylene alkyl ether and vinyl neodecanoate obtains as necessary monomer component.

In this description, sometimes above-mentioned " being selected from the polymer in the group be made up of the 1st polymer and the 2nd polymer " is called " composition (D) ".In addition, sometimes above-mentioned " the 1st polymer " is called " composition (D1) ", sometimes above-mentioned " the 2nd polymer " is called " composition (D2) ".In addition, " (methyl) acrylic acid " refers to the one or both in acrylic acid and methacrylic acid.

Hair mousse compositions of the present invention can comprise polysaccharide based compound further.In this description, sometimes above-mentioned " polysaccharide based compound " is called " composition (D ') ".

Hair mousse compositions of the present invention preferably comprises clay mineral further.In this description, sometimes above-mentioned " clay mineral " is called " composition (E) ".

That is, hair mousse compositions of the present invention at least comprises composition (A) and composition (B).Hair mousse compositions of the present invention preferably comprises the composition (at least one composition) in the group selecting free component (C), composition (D) and composition (E) to form further.When using composition (E), preferably composition (E) and the composition in the group selecting free component (D) and composition (D ') to form are share.Wherein, hair mousse compositions of the present invention preferably includes whole composition (A), composition (B), composition (C), composition (D) and composition (E).Hair mousse compositions of the present invention can comprise other compositions further.Mentioned component, such as composition (A), composition (B), composition (C), composition (D), composition (D '), composition (E) and other compositions can only use a kind respectively, also can use two or more.

It should be noted that, mentioned component (B) is the compound (at least one compound) in the group selecting free component (B1) and composition (B2) and form.In addition, mentioned component (C) is the compound (at least one compound) in the group selecting free component (C1) and composition (C2) and form.In addition, mentioned component (D) is the polymer (at least one polymer) in the group selecting free component (D1) and composition (D2) and form.Above-mentioned composition (B1), composition (B2), composition (C1), composition (C2), composition (D1), composition (D2) can only use a kind respectively, also can use two or more.

Below, the details of each composition used in hair mousse compositions of the present invention is described.

(composition (A))

Mentioned component (A) is for being selected from the granule in the group that is made up of silicon dioxide, calcium carbonate, magnesium carbonate, hydroxyapatite, titanium dioxide, zinc oxide, calcium silicates, magnesium silicate, aluminium silicate and magnesium hydroxide.Mentioned component (A) mainly has the effect suppressing to be clamminess, the raising initial stage haircuts power and retentivity of haircuting.In addition, by using mentioned component (A), compared with forming the situation of polymer with use overlay film, easily again haircuting after once haircuting, haircuting property again can also be improved.

As mentioned component (A), wherein, from the viewpoint of improving the performance of haircuting, be preferably selected from the granule (at least one granule) in the group be made up of silicon dioxide, magnesium carbonate, hydroxyapatite, calcium silicates, magnesium silicate, aluminium silicate and magnesium hydroxide, be more preferably selected from the granule (at least one granule) in the group be made up of silicon dioxide, magnesium silicate and magnesium hydroxide.Mentioned component (A) can only use a kind, also can use two or more.

< silicon dioxide >

As above-mentioned silicon dioxide, known usual silicon dioxide (silicic acid anhydride) can be used.Above-mentioned silicon dioxide can be the silicic acid anhydride (hydrophilic silicon dioxide) without hydrophobization process, also can be hydrophobization silicic acid anhydride.In addition, above-mentioned silicon dioxide also can for have carried out surface-treated silicon dioxide with aminoacid, ester or lecithin etc.In addition, above-mentioned silicon dioxide also can be so-called easy disintegrating silica dioxide granule.Above-mentioned silicon dioxide can only use a kind, also can use two or more.

Above-mentioned hydrophobization silicic acid anhydride is material silicic acid anhydride (such as untreated silicic acid anhydride) having been carried out to hydrophobization process.As inorganic agent used in hydrophobization process, Organosilyl compound and silicone compounds etc. can be enumerated.As above-mentioned Organosilyl compound, methyl trichlorosilane, dimethyldichlorosilane, trim,ethylchlorosilane, hexamethyldisiloxane, methyl trialkoxysilane, dimethyldialkylammonium TMOS, trimethylalkyoxys iotalane, ethyl trichlorosilane, propyltrichlorosilan, hexyl trichlorosilane, chain alkyl trichlorosilane, ethyltrialkoxysilanes, propyl trialkoxy silane, hexyl trialkoxy silane, chain alkyl trialkoxy silane, methacryl silanes, fluoroalkyl silanes and perfluoroalkyl silanes etc. can be enumerated.As above-mentioned silicone compounds, dimethyl polysiloxane (silicone oil), methyl phenyl silicone, methylhydrogenpolysi,oxane and amino modified silicone etc. can be enumerated.As the method for above-mentioned hydrophobization process, known method can be used.As the method for above-mentioned hydrophobization process, liquid phase method, vapor phase method and autoclave method etc. can be enumerated.

As the preference of above-mentioned hydrophobization silicic acid anhydride, dimethyl silane oxygen base SiClx anhydride, trimethylsiloxy SiClx anhydride, octyl group siloxy SiClx anhydride, silicone oil process silicic acid anhydride and methacrylic acid monosilane oxygen base SiClx anhydride etc. can be enumerated.

The granule that above-mentioned easy disintegrating silica dioxide granule is the set of multiple silicon dioxide primary particle and is formed.As above-mentioned silicon dioxide primary particle, be not particularly limited, such as, can enumerate spherical silica particles, flakey silica dioxide granule and amorphous silica particles etc.The mean diameter of above-mentioned silicon dioxide primary particle is not particularly limited.

In addition, above-mentioned easy disintegrating silica dioxide granule can include the composition beyond silicon dioxide.As the composition (hereinafter sometimes referred to " component content ") beyond above-mentioned silicon dioxide, be not particularly limited, such as, can enumerate surfactant, polyhydric alcohol, higher alcohol, sugar alcohol, silicone oil, chelating agen, antioxidant, plant extract, pigment, pigment, spice, wetting agent, vitamins, amino acids and freshener etc.Wherein, preferred amino acid class, silicone oil, vitamins.As above-mentioned amino acids, be not particularly limited, two (lauramide glutamine) lysine Na (such as, Asahi Chemical Corp's manufacture, trade name " pellicer "), trimethyl glycine and glutamic acid etc. can be enumerated.By making above-mentioned easy disintegrating silica dioxide granule include above-mentioned component content, if the above-mentioned easy disintegrating silica dioxide granule disintegrate when haircuting, discharging component content, the effect corresponding with the kind of component content can have been given play to.Such as, by above-mentioned easy disintegrating silica dioxide granule embedded amine groups acids, the damage nursing function of hair can have been given play to.

As the manufacture method of above-mentioned easy disintegrating silica dioxide granule, be not particularly limited, known method can be used.

The oil absorption of above-mentioned silicon dioxide is preferably more than 100mL/100g, is more preferably more than 150mL/100g, more preferably more than 200mL/100g, is preferably below 1000mL/100g, is more preferably below 800mL/100g, more preferably below 700mL/100g.When the oil absorption of above-mentioned silicon dioxide is below more than above-mentioned lower limit and the above-mentioned upper limit, the initial stage haircut power, haircut retentivity and again haircuting property become better.Above-mentioned oil absorption measures according to the method recorded in JISK5101.

As the commercially available product of above-mentioned silicon dioxide, such as can enumerate the trade name " Sylysia 320 " that the Fuji Silysia Chemical society as silicic acid anhydride manufactures, trade name " Sylysia 310P ", trade name " Sylysia 250 ", trade name " Sylysia 250N ", trade name " Sylysia 350 ", trade name " Sylysia 370 ", trade name " Sylysia 380 ", trade name " Sylysia 420 ", trade name " Sylysia 430 ", trade name " Sylysia 440 ", trade name " Sylysia 450 " and trade name " Sylysia 470 ", as trade name " AEROSIL50 ", trade name " AEROSIL 90G ", trade name " AEROSIL 130 ", trade name " AEROSIL 150 ", trade name " AEROSIL 200 ", trade name " AEROSIL 300 ", trade name " AEROSIL 380 ", trade name " AEROSIL 200V " and trade name " AEROSIL OX50 " that the NIPPON AEROSIL society of silicic acid anhydride manufactures, as trade name " Sunsphere H-31 ", trade name " Sunsphere H-51 ", trade name " Sunsphere H-121 ", trade name " Sunsphere H-201 ", trade name " Sunsphere H-32 ", trade name " Sunsphere H-52 ", trade name " Sunsphere H-122 ", trade name " Sunsphere H-33 " and trade name " Sunsphere H-53 " that the AGC Si-Tech society of silicic acid anhydride manufactures, as trade name " AEROSIL R972 ", trade name " AEROSIL R974 " and trade name " AEROSIL R9200 " that the NIPPON AEROSIL society of dimethyl silane oxygen base SiClx anhydride manufactures, as trade name " AEROSIL RX200 ", trade name " AEROSIL R8200 ", trade name " AEROSIL RX300 " and trade name " AEROSIL R812S " that the NIPPON AEROSIL society of trimethylsiloxy SiClx anhydride manufactures, as the trade name " AEROSIL R805 " that the NIPPON AEROSIL society of octyl group siloxy SiClx anhydride manufactures, as trade name " AEROSIL R202 ", trade name " AEROSIL RY200 ", trade name " AEROSIL RY200S " and trade name " AEROSIL RY300 " that the NIPPON AEROSIL society of silicone oil process silicic acid anhydride manufactures, as the trade name " AEROSIL R711 " that the NIPPON AEROSIL society of methacrylic acid monosilane oxygen base SiClx anhydride manufactures, the trade name " silica beads SB-705 " of society's manufacture is changed into well as three of Shang Shu Yang disintegrative silicon dioxide, as trade name " God Ball SF-16C ", trade name " God Ball AF-6C " and trade name " God Ball AF-16C " etc. that the Suzuki oils and fats society of Shang Shu Yang disintegrative silicon dioxide manufactures.

< calcium carbonate >

Above-mentioned calcium carbonate such as represents with INCI name " CALCIUM CARBONATE ".Above-mentioned calcium carbonate can only use a kind, also can use two or more.As the commercially available product of above-mentioned calcium carbonate, such as, can enumerate the trade name " Calmaru SCS M5 " that Sakai chemical industry society manufactures; The trade name " FUWACAL " etc. that shiraishi calcium society manufactures.

< magnesium carbonate >

Above-mentioned magnesium carbonate such as represents with INCI name " MAGNESIUM CARBONATE ".Above-mentioned magnesium carbonate can only use a kind, also can use two or more.As the commercially available product of above-mentioned magnesium carbonate, such as, can enumerate the trade name " light magnesium carbonate " etc. that Fu Tian pharmacy society manufactures.

< hydroxyapatite >

Above-mentioned hydroxyapatite such as represents with INCI name " HYDROXYAPATITE ".Above-mentioned hydroxyapatite can only use a kind, also can use two or more.

As above-mentioned hydroxyapatite, be not particularly limited, such as, can enumerate the hydroxyapatite and amorphous hydroxyapatite etc. of spherical hydroxyapatite, lamellar.Wherein, to haircut performance from the viewpoint of having given play to height, preferably spherical hydroxyapatite.As the commercially available product of above-mentioned hydroxyapatite, such as, can enumerate trade name " lamellar HAP ", trade name " spherical HAP ", trade name " HAP-100 ", trade name " HAP-200 " and trade name " HAP-300 " etc. that peaceful Chemical Industries society manufactures.

< titanium dioxide >

Above-mentioned titanium dioxide such as represents with INCI name " TITANIUM DIOXIDE ".Being not particularly limited above-mentioned titanium dioxide, such as, can be fine particulate titanium dioxide, also can be pigment titanium.Above-mentioned titanium dioxide can only use a kind, also can use two or more.As the commercially available product of above-mentioned titanium dioxide, such as, can enumerate stone and originate in the trade name " TTO-55 (A) " and trade name " CR-50 " etc. that industry society manufactures.

< zinc oxide >

Above-mentioned zinc oxide such as represents with INCI name " ZINC OXIDE ".Above-mentioned zinc oxide can only use a kind, also can use two or more.As the commercially available product of above-mentioned zinc oxide, such as, can enumerate the trade name " FINEX-30S-LP2 " etc. that Sakai chemical industry society manufactures.

< calcium silicates >

Above-mentioned calcium silicates such as represents with INCI name " CALCIUM SILICATE ".Above-mentioned calcium silicates can only use a kind, also can use two or more.As the commercially available product of above-mentioned calcium silicates, such as, can enumerate the trade name " FLORITE R " that Fu Tian pharmacy society manufactures; The trade name " eakleite powder X-ray J " that JAPAN INSULATION CO., LTD. manufacture and trade name " tobermorite powder TK " etc.

< magnesium silicate >

Above-mentioned magnesium silicate such as represents with INCI name " MAGNESIUM SILICATE ".Above-mentioned magnesium silicate can only use a kind, also can use two or more.As the commercially available product of above-mentioned magnesium silicate, such as, can enumerate the trade name " magnesium silicate (lightweight) " etc. that Fu Tian pharmacy society manufactures.

< aluminium silicate >

Above-mentioned aluminium silicate such as represents with INCI name " ALUMINUM SILICATE ".Above-mentioned aluminium silicate can only use a kind, also can use two or more.As aluminium silicate, be not particularly limited, preferred synthetic aluminium silicate.As synthetic method, such as, can enumerate: in Alumen, add Na ₂siO ₃and by the method for generated precipitation drying; Make silica sol by electroosmose process, generate the method for gel thus; And in waterglass, add the method for aqueous solution of aluminum salt; Etc..As the commercially available product of above-mentioned aluminium silicate, such as, can enumerate the trade name " synthetic aluminium silicate (heavy) " etc. that Fu Tian pharmacy society manufactures.

< magnesium hydroxide >

Above-mentioned magnesium hydroxide such as represents with INCI name " MAGNESIUM HYDROXIDE ".Above-mentioned magnesium hydroxide can only use a kind, also can use two or more.As the commercially available product of above-mentioned magnesium hydroxide, such as, can enumerate the trade name " magnesium hydroxide (heavy) " etc. that Fu Tian pharmacy society manufactures.

In hair mousse compositions 100 quality % of the present invention, the content of mentioned component (A) is more than 0.1 quality %, is preferably more than 0.4 quality %, is more preferably more than 1 quality %, is below 10 quality %, is preferably below 7 quality %, is more preferably below 5 quality %.Be more than above-mentioned lower limit by the content of mentioned component (A), the initial stage after just haircuting of can improving further haircuts power, and can improve retentivity of haircuting further.Be below the above-mentioned upper limit by the content of mentioned component (A), effect and the washing away property of giving gloss improve further.The content of mentioned component (A) is the total amount of the content of the whole compositions (A) in hair mousse compositions of the present invention.In addition, in hair mousse compositions 100 quality % of the present invention, the content (content of total) of the granule in the group that the content of silicon dioxide and being selected from is made up of calcium carbonate, magnesium carbonate, hydroxyapatite, titanium dioxide, zinc oxide, calcium silicates, magnesium silicate, aluminium silicate and magnesium hydroxide is respectively more than 0.1 quality %, is preferably more than 0.4 quality %, is more preferably more than 1 quality %, is below 10 quality %, is preferably below 7 quality %, is more preferably below 5 quality %.

(composition (B))

Mentioned component (B) is for being selected from least one compound in the group that is made up of mentioned component (B1) and mentioned component (B2).Mentioned component (B) mainly has effective raising initial stage and to haircut power and the effect of retentivity of haircuting.In addition, by using mentioned component (B), can suppress to peel off, given play to above-mentioned effect.Mentioned component (B) can only use a kind, also can use two or more.It should be noted that, mentioned component (B1), mentioned component (B2) also can only use a kind respectively, also can use two or more.

As mentioned component (B), only can use any one in mentioned component (B1) and mentioned component (B2), also can share mentioned component (B1) and mentioned component (B2).Wherein, from the aspect that the persistence of the power of haircuting improves, preferably share mentioned component (B1) and mentioned component (B2).

Mentioned component (B1) is polyoxyethylene/polyoxypropylene copolymer.That is, mentioned component (B1) is the copolymer at least with more than 2 ethylene oxide units (ethylene oxide unit) and more than 2 propylene oxide units (propylene oxide unit).Mentioned component (B1) can be any one in block copolymer, random copolymer and alternate copolymer, is not particularly limited the copolymerization mode in mentioned component (B1).

The average addition molal quantity of the ethylene oxide in mentioned component (B1) is not particularly limited, is preferably more than 100, is more preferably more than 200, be preferably less than 400, be more preferably less than 350.The average addition molal quantity of the propylene oxide in mentioned component (B1) is not particularly limited, is preferably more than 30, is particularly preferably more than 40, be preferably less than 150, be particularly preferably less than 100.

From the coating easiness of the aspect suppressing to peel off, hair mousse, give the aspect of gloss to hair, mentioned component (B1) be liquid state at 25 DEG C.

The number-average molecular weight of mentioned component (B1) is less than more than 10,000 20000.The number-average molecular weight of mentioned component (B1) is less than above-mentioned in limited time lower, and haircuting property reduces.The number-average molecular weight of mentioned component (B1) exceedes above-mentioned in limited time upper, and treatability is deteriorated.The number-average molecular weight of mentioned component (B1) is preferably more than 12000.The number-average molecular weight of mentioned component (B1) is preferably less than 18000.

Mentioned component (B2) is polyoxypropylene Sorbitol.The average addition molal quantity of the propylene oxide in mentioned component (B2) is not particularly limited, is preferably more than 4, is more preferably more than 8, be preferably less than 15, be more preferably less than 12.

From the coating easiness of the aspect suppressing to peel off, hair mousse, give the aspect of gloss to hair, mentioned component (B2) be liquid state at 25 DEG C.

The number-average molecular weight of mentioned component (B2) is less than more than 300 1000.The number-average molecular weight of mentioned component (B2) is preferably more than 400.The number-average molecular weight of mentioned component (B2) is preferably less than 800.

Mentioned component (B) is liquid at 25 DEG C.Mentioned component (B) preferably has mobility at 25 DEG C, such as preferably there is following character: loaded by 50g sample in the vial of radius 2cm, height 7cm, when being put upside down by above-mentioned vial at the temperature of 25 DEG C, when putting upside down latter 5 minutes, sample drips from vial.

As the commercially available product of mentioned component (B1), such as, can enumerate the trade name " Newpol 75H-90000 " etc. that Sanyo changes into the manufacture of industrial society.

As the commercially available product of mentioned component (B2), such as, can enumerate Sanyo and change into the trade name " Newpol SP-750 " and trade name " Sannix SP-750 " etc. that industrial society manufactures.

In hair mousse compositions 100 quality % of the present invention, the content of mentioned component (B) is preferably more than 3 quality %, is more preferably more than 5 quality %, more preferably more than 8 quality %, is preferably below 40 quality %, is more preferably below 30 quality %, more preferably below 20 quality %.When the content of mentioned component (B) is more than above-mentioned lower limit, power of haircuting and persistence thereof become better.When the content of mentioned component (B) is below the above-mentioned upper limit, the ductility when inhibition be clamminess, coating and amalgamation become better.The content of mentioned component (B) is the total amount of the content of the whole compositions (B) in hair mousse compositions of the present invention.

In hair mousse compositions of the present invention, the mass ratio (content of mentioned component (A): the content of mentioned component (B)) of the content of mentioned component (A) and the content of mentioned component (B) is preferably 1:0.1 ~ 1:30, is more preferably 1:1 ~ 1:20, more preferably 1:3 ~ 1:20.When the content of mentioned component (A) is relatively many, the Forming ability of soft moulding becomes better.When the content of mentioned component (B) is relatively many, makes the formative nature sending out stream closely and become better.The content (content of total) of granule in the group that the mass ratio of the content of the content of silicon dioxide and mentioned component (B) and being selected from is made up of calcium carbonate, magnesium carbonate, hydroxyapatite, titanium dioxide, zinc oxide, calcium silicates, magnesium silicate, aluminium silicate and magnesium hydroxide is preferably 1:0.1 ~ 1:30 respectively with the mass ratio of the content of mentioned component (B), is more preferably 1:1 ~ 1:20, more preferably 1:3 ~ 1:20.

(composition (C))

Mentioned component (C) is for being selected from least one compound in the group that is made up of mentioned component (C1) and mentioned component (C2).By using mentioned component (C), can suppress further to peel off, and the washing away property after haircuting can be improved, and can haircut while power and give good feel to the hair after haircuting maintaining the high initial stage.In addition, even if giving hair mousse compositions, hair to hair by under the state of fully haircuting, hair mousse compositions also can be suppressed to adhere to the sense of discomfort brought, can haircut with natural state.Mentioned component (C) can only use a kind, also can use two or more.It should be noted that, mentioned component (C1), mentioned component (C2) also can only use a kind respectively, can also use two or more.

As mentioned component (C), can only use in mentioned component (C1) and mentioned component (C2) any one, also mentioned component (C1) and mentioned component (C2) can be share.

Mentioned component (C1) is polyoxyalkylene alkyl glucoside.As the oxyalkylene alkyl in mentioned component (C1), oxyethylene group and oxypropylene group etc. can be enumerated.The average addition molal quantity of the oxyalkylene alkyl in mentioned component (C1) is not particularly limited, is preferably more than 5, is preferably less than 40.The carbon number of the alkyl in mentioned component (C1) is preferably 1 ~ 4, is more preferably 1 ~ 3.Alkyl in mentioned component (C1) is preferably methyl or ethyl.

As mentioned component (C1), be not particularly limited, Glucam E-10, polyoxyethylene ethyl cyclophosphadenosine glycoside, PP 25 and polyoxypropylene ethyl cyclophosphadenosine glycoside etc. can be enumerated.

From the viewpoint of haircuting while power and give better feel to hair after haircuting maintaining the high initial stage, mentioned component (C1) is Glucam E-10 preferably.

Mentioned component (C2) is polyoxyalkylene fatty acid glyceride.The carbon number of the fatty acid in mentioned component (C2) is preferably more than 8, is preferably less than 22.As the oxyalkylene alkyl in mentioned component (C2), oxyethylene group and oxypropylene group etc. can be enumerated.The average addition molal quantity of the oxyalkylene alkyl in mentioned component (C2) is preferably more than 5, is preferably less than 40.

From the viewpoint of haircuting while power and give better feel to hair after haircuting maintaining the high initial stage, fatty acid in mentioned component (C2) is preferably branched chain fatty acid, and mentioned component (C2) is preferably polyoxyalkylene glycerol side chain fatty acid ester.

From the viewpoint of haircuting while power and give better feel to hair after haircuting maintaining the high initial stage, the carbon number of the branched chain fatty acid in above-mentioned polyoxyalkylene glycerol side chain fatty acid ester is preferably more than 8, preferably less than 22.As the branched chain fatty acid in above-mentioned polyoxyalkylene glycerol side chain fatty acid ester, 2 ethyl hexanoic acid, different n-nonanoic acid, different Palmic acid and isostearic acid etc. can be enumerated.

As above-mentioned polyoxyalkylene glycerol side chain fatty acid ester, particularly preferably isostearic acid polyoxyethylene glyceride.

As the commercially available product of mentioned component (C1), such as, can enumerate the trade name " MACBIOBRIDE MG-10P " that You society manufactures; The trade name " GLUCAM E-10 " that Noveon society manufactures and trade name " GLUCAM E-20 "; The trade name " GLUCAM P-10 " etc. that Amerchol society manufactures.

As the commercially available product of mentioned component (C2), such as, can enumerate the trade name " Noigen GIS-125 " that the first industrial pharmaceutical society manufactures; The trade name " EMALEX GWIS-115 " that NIHON EMULSION society manufactures, trade name " EMALEX GWIS-120 ", trade name " EMALEX GWIS-125 " and trade name " EMALEXGWIS-130 " etc.

In hair mousse compositions 100 quality % of the present invention, the content of mentioned component (C) is preferably more than 0.5 quality %, is more preferably more than 1 quality %, is preferably below 20 quality %, is more preferably below 10 quality %.When the content of mentioned component (C) is more than above-mentioned lower limit, can suppress further to peel off, and the washing away property after haircuting becomes better, and better feel can be given to the hair after haircuting.When the content of mentioned component (C) is below the above-mentioned upper limit, is clamminess and is alleviated further.The content of mentioned component (C) is the total amount of the content of the whole compositions (C) in hair mousse compositions of the present invention.

In above-mentioned hair mousse compositions, the mass ratio (content of mentioned component (A): the content of mentioned component (C)) of the content of mentioned component (A) and the content of mentioned component (C) is preferably 1:0.2 ~ 1:20, is more preferably 1:1 ~ 1:10.If the content of mentioned component (C) is relatively many, then hair feel, peel off inhibition, washing away property becomes better.The content (content of total) of granule in the group that the mass ratio of the content of the content of silicon dioxide and mentioned component (C) and being selected from is made up of calcium carbonate, magnesium carbonate, hydroxyapatite, titanium dioxide, zinc oxide, calcium silicates, magnesium silicate, aluminium silicate and magnesium hydroxide is preferably 1:0.2 ~ 1:20 respectively with the mass ratio of the content of mentioned component (C), is more preferably 1:1 ~ 1:10.

(composition (D))

Mentioned component (D) is for being selected from least one polymer in the group that is made up of mentioned component (D1) and mentioned component (D2).By use mentioned component (D), hair mousse compositions appropriateness thickening, therefore the dispersibility of mentioned component (A) becomes better, so hair mousse compositions become be difficult to be separated, storage stability becomes better.In addition, haircuting property becomes better.Mentioned component (D) can only use a kind, also can use two or more.It should be noted that, mentioned component (D1), mentioned component (D2) also can only use a kind respectively, also can use two or more.

Monomer component for the polymer obtaining mentioned component (D1) at least comprises the two or more monomer in the group being selected from and being made up of (methyl) acrylic acid and (methyl) alkyl acrylate.That is, mentioned component (D1) at least comprises the polymer be selected from by from the two or more construction units in (methyl) acrylic acid construction unit and the group that forms from the construction unit of (methyl) alkyl acrylate.It should be noted that, in this description, mentioned component (D1) can be equivalent to and mentioned component (D2) both polymer are not composition (D1) but composition (D2).

As mentioned component (D1), be not particularly limited, preferably with INCI name (international cosmetic raw material dictionary and handbook, 14th edition, 1st volume, CTFA, 2012, p.60 ~ 61) compound of " ACRYLATES COPOLYMER (acrylic acid (ester) analog copolymer) " is expressed as.

As the commercially available product of mentioned component (D1), such as, can enumerate trade name " Aculyn 33 " and the trade name " Aculyn 33A " of DOW Chemical society manufacture; The trade name " SepiMAX ZEN " etc. that SEPPIC society manufactures.

Mentioned component (D1) is not particularly limited, has preferably carried out neutralization with alkaline matter or with in alkaline matter and rear use.As above-mentioned alkaline matter, such as, can enumerate the alkanol such as triethanolamine and monoethanolamine amine; The inorganic bases such as ammonia, sodium hydroxide and potassium hydroxide; The basic amino acids etc. such as arginine.In addition, the addition of above-mentioned alkaline matter be composition (D1) after reaching fully neutralization amount or in and mentioned component (D1) measure fully, as long as according to mentioned component (D1) and the kind of above-mentioned alkaline matter and the suitable mixture of consumption of mentioned component (D1).

At least one monomer component (d2b) at least comprising at least one monomer component (d2a) in the group being selected from and being made up of (methyl) acrylic acid and (methyl) alkyl acrylate for the monomer component of the polymer obtaining mentioned component (D2) and being selected from the group that is made up of (methyl) acrylic acid polyoxyethylene alkyl ether, itaconic acid polyoxyethylene alkyl ether and vinyl neodecanoate.That is, mentioned component (D2) is the polymer at least comprised from the construction unit of above-mentioned monomer component (d2a) and the construction unit from above-mentioned monomer component (d2b).Above-mentioned monomer component (d2a), above-mentioned monomer component (d2b) can only use a kind respectively, also can use two or more.

As mentioned component (D2), be not particularly limited, preferably with INCI name (international cosmetic raw material dictionary and handbook, 14th edition, 1st volume, CTFA, 2012, p.66 ~ 67) compound of " ACRYLATES/STEARETH-20METHACRYLATE COPOLYMER (acrylic acid (ester) class/stereth-20 methacrylate copolymer) " is expressed as; With INCI name (international cosmetic raw material dictionary and handbook, 14th edition, 1st volume, CTFA, 2012, p.67) be expressed as the compound of " ACRYLATES/STEARETH-20METHACRYLATECROSSPOLYMER (acrylic acid (ester) class/stereth-20 Methacrylate Crosspolymer) "; With INCI name (international cosmetic raw material dictionary and handbook, 14th edition, 1st volume, CTFA, 2012, p.57) be expressed as the compound of " ACRYLATES/BEHENETH-25METHACRYLATE COPOLYMER (acrylic acid (ester) class/behenyl alcohol polyethers-25 methacrylate copolymer) "; With INCI name (international cosmetic raw material dictionary and handbook, 14th edition, 1st volume, CTFA, 2012, p.68 ~ 69) compound of " ACRYLATES/VINYLNEODECANOATE CROSSPOLYMER (acrylic acid (ester) class/vinyl neodecanoate cross linked polymer) " is expressed as; With INCI name (international cosmetic raw material dictionary and handbook, 14th edition, 1st volume, CTFA, 2012, p.66) be expressed as the compound of " ACRYLATES/STEARETH-20ITACONATE COPOLYMER (acrylic acid (ester) class/stereth-20 itaconate copolymeric) "; With INCI name (international cosmetic raw material dictionary and handbook, 14th edition, 1st volume, CTFA, 2012, p.60) be expressed as the compound etc. of " ACRYLATES/CETETH-20ITACONATECOPOLYMER (acrylic acid (ester) class/ceteth-20 itaconate copolymeric) ".

As the commercially available product of mentioned component (D2), such as, can enumerate trade name " Aculyn 22 ", trade name " Aculyn 88 ", trade name " Aculyn 28 " and trade name " Aculyn 38 " that DOW Chemical society manufactures; The trade name " STRUCTURE 2001 " that Akzo Nobel society manufactures and trade name " STRUCTURE 3001 " etc.

Mentioned component (D2) is not particularly limited, has preferably carried out neutralization with alkaline matter or with in alkaline matter and rear use.As alkaline matter now, above-mentioned alkaline matter can be enumerated.In addition, the addition of above-mentioned alkaline matter be composition (D2) after reaching fully neutralization amount or in and mentioned component (D2) measure fully, as long as according to mentioned component (D2) and the kind of above-mentioned alkaline matter and the suitable mixture of consumption of mentioned component (D2).

In hair mousse compositions 100 quality % of the present invention, the content of mentioned component (D) is preferably more than 0.01 quality %, is more preferably more than 0.1 quality %, is preferably below 5 quality %, is more preferably below 2 quality %.When the content of mentioned component (D) is more than above-mentioned lower limit, the imparting effect of gloss and the storage stability of hair mousse compositions become better.When the content of mentioned component (D) is below the above-mentioned upper limit, power of haircuting improves further, and the feel of hair becomes better.The content of mentioned component (D) is the total amount of the content of the whole compositions (D) in hair mousse compositions of the present invention.It should be noted that, when using mentioned component (D '), particularly in hair mousse compositions 100 quality % of the present invention, the content of mentioned component (D) can be 0 quality % (use).

(composition (D '))

Mentioned component (D ') be polysaccharide based compound.By using mentioned component (D '), the thickening of hair mousse compositions appropriateness, therefore the dispersibility of mentioned component (A) becomes better, and then hair mousse compositions becomes and is difficult to be separated, and storage stability becomes better.Mentioned component (D ') can only use a kind, also can use two or more.

As mentioned component (D '), be not particularly limited, preferred polysaccharide, modification of polysaccharides (such as alkyl-modified polysaccharide etc.) etc., such as, can enumerate alginic acid, carrageenan, agar, pharselan, guar gum, Fructus cydoniae oblongae seed, Konjaku plucosidopolyose, tamarind gum, tara gum, dextrin, starch, locust bean gum, arabic gum, gum ghatti, POLY-karaya, Tragacanth, arabinogalactan, pectin with the polysaccharide based compound of the plant origins such as Fructus cydoniae oblongae; The polysaccharide based compound of the animal origin such as chitosan and hyaluronic acid; The polysaccharide based compound that curdlan, xanthan gum, gellan gum, cyclodextrin, dextran, amylopectin and hyaluronic acid etc. are microbe-derived; The non-ionic cellulose elements such as microcrystalline Cellulose, methylcellulose, ethyl cellulose, hydroxy methocel, hydroxyethyl-cellulose, hydroxypropyl cellulose and hydroxypropyl emthylcellulose; The anionic cellulose elements such as carboxymethyl cellulose; The Poise C-80Ms such as chlorination O-[2-hydroxyl-3-(trimethyl ammonium) propyl group] hydroxyethyl-cellulose; The cationized guar glue etc. such as chlorination O-[2-hydroxyl-3-(trimethyl ammonium) propyl group] guar gum.

As mentioned component (D '), wherein, be preferably selected from the compound (at least one compound) in the group be made up of xanthan gum, guar gum, tamarind gum and gellan gum.

As the commercially available product of mentioned component (D '), such as, can enumerate trade name " ECHO GUM T ", trade name " ケ Le デ Application ト " and trade name " モ ナ ー ト ガ system " that the large SUMITOMO CHEMICAL pharmacy society as xanthan gum manufactures; As the trade name " Inagel guar gum CS " that the Yi Na food industry society of guar gum manufactures; As the trade name " GLYLOID 6C " that the DSPGOKYO FOOD & CHEMICAL Co., Ltd. of tamarind gum manufactures; As the trade name " Kelcogel " etc. that the CP Kelco U.S. of gellan gum, Inc. manufacture.

In hair mousse compositions 100 quality % of the present invention, the content of mentioned component (D ') is preferably more than 0.01 quality %, is more preferably more than 0.1 quality %, is preferably below 5 quality %, is more preferably below 2 quality %.When the content of mentioned component (D ') is more than above-mentioned lower limit, the storage stability of hair mousse compositions becomes better.When the content of mentioned component (D ') is below the above-mentioned upper limit, is clamminess and becomes better.The content of mentioned component (D ') is the total amount of the content of whole compositions in hair mousse compositions of the present invention (D ').It should be noted that, when using mentioned component (D), particularly in hair mousse compositions 100 quality % of the present invention, the content of mentioned component (D ') can be 0 quality % (use).

(composition (E))

Mentioned component (E) is clay mineral.By using mentioned component (E), the storage stability of power of haircuting and hair mousse compositions becomes better.Mentioned component (E) can only use a kind, also can use two or more.

Mentioned component (E) can be natural goods, also can be synthetic.As mentioned component (E), be not particularly limited, such as, can enumerate kaolin group's clay mineral, antigorite race clay mineral, pyrophyllite race clay mineral, Mica Group clay mineral, smectite clay mineral, Vermiculitum race clay mineral, chlorite race clay mineral and organo-clay mineral etc.

As above-mentioned kaolin group clay mineral, Kaolin, nacrite, dickite and halloysite etc. can be enumerated.As above-mentioned antigorite race clay mineral, antigorite, pictoamesite and cronstedtite etc. can be enumerated.As above-mentioned pyrophyllite race clay mineral, pyrophyllite and Talcum (Talcum) etc. can be enumerated.As above-mentioned Mica Group clay mineral, illite, glauconite, seladonit, sericite, Muscovitum (Muscovitum), white mica, fuchsite and biotite etc. can be enumerated.As above-mentioned smectite clay mineral, bentonite, montorillonite clay, beidellite, nontronite, saponite, Strese Hofmann's hectorite. (Hectorite) and synthetic li-montmorillonite (Lucentite) etc. can be enumerated.As above-mentioned Vermiculitum race clay mineral, Vermiculitum etc. can be enumerated.As above-mentioned chlorite race clay mineral, chlorite (chlorite) etc. can be enumerated.As above-mentioned organo-clay mineral, smectite clay mineral or Vermiculitum race clay mineral etc. can be enumerated and carried out the organo-clay mineral etc. of organically-modified process.Be suitable for using quaternary ammonium salt cationic surfactant in organically-modified process.As above-mentioned quaternary ammonium salt cationic surfactant, abovementioned alkyl trimethyl ammonium chloride, dialkyl dimethyl ammonium chloride and benzalkonium chloride etc. can be enumerated.

From the viewpoint of improving storage stability and use sense further, mentioned component (E) is preferably selected from the clay mineral in the group be made up of synthetic silicate and derivant thereof.Above-mentioned synthetic silicate and derivant thereof are not take the magnesium silicate of the natural origin containing many impurity or silicic acid (sodium/magnesium) etc. as the silicate mineral of main component, but by synthesizing the silicate and silicate derivative that obtain.

As above-mentioned synthetic silicate and derivant thereof, such as can enumerate with INCI name (international cosmetic raw material dictionary and handbook (International Cosmetic Ingredient Dictionary and Handbook), 14th edition, 2nd volume, CTFA, 2012, p.3076): the synthetic silicic acid (sodium/magnesium) that SODIUM MAGNESIUM SILICATE (sodium magnesium silicate) represents, with INCI name (international cosmetic raw material dictionary and hands volume, 14th edition, 2nd volume, CTFA, 2012, p.1793): the magnesium fluosilicate that MAGNESIUM FLUOROSILICATE (magnesium fluosilicate) represents, with INCI name (international cosmetic raw material dictionary and hands volume, 14th edition, 2nd volume, CTFA, 2012, p.3076): the hexafluosilicic acid (sodium/magnesium) that SODIUMMAGNESIUM FLUOROSILICATE (magnesium fluosilicate sodium) represents, with INCI name (international cosmetic raw material dictionary and hands volume, 14th edition, 2nd volume, CTFA, 2012, p.1799): the hexafluosilicic acid (magnesium/potassium) that MAGNESIUMPOTASSIUM FLUOROSILICATE (potassium fluosilicate magnesium) represents, with INCI name (international cosmetic raw material dictionary and hands volume, 14th edition, 2nd volume, CTFA, 2012, p.1800): the hexafluosilicic acid (magnesium/sodium) that MAGNESIUMSODIUM FLUOROSILICATE (prodan magnesium) represents, with INCI name (international cosmetic raw material dictionary and hands volume, 14th edition, 1st volume, CTFA, 2012, p.156): the synthetic aluminium silicate etc. that ALUMINUMSILICATE (aluminium silicate) represents.

As mentioned component (E), wherein, the clay mineral (at least one clay mineral) in the group be made up of synthetic silicic acid (sodium/magnesium), hexafluosilicic acid (sodium/magnesium) and hexafluosilicic acid (sodium/magnesium) is particularly preferably selected from.

As the commercially available product of mentioned component (E), such as, can enumerate trade name " LAPONITE XLG " and trade name " LAPONITE XL21 " etc. that Rockwood society manufactures.

In hair mousse compositions 100 quality % of the present invention, the content of mentioned component (E) is preferably more than 0.1 quality %, is more preferably more than 0.3 quality %, more preferably more than 0.5 quality %, is preferably below 10 quality %, is more preferably below 5 quality %, more preferably below 3 quality %.When the content of mentioned component (E) is more than above-mentioned lower limit, haircuting property becomes better.When the content of mentioned component (E) is below the above-mentioned upper limit, the storage stability of hair mousse compositions becomes better.

From the viewpoint of making the further appropriate thickening of hair mousse compositions, improve further the storage stability of hair mousse compositions, hair mousse compositions of the present invention preferably comprises mentioned component (D) and mentioned component (E).By share mentioned component (D) and mentioned component (E), the dispersion stabilization of mentioned component (A) improves further, and the separation of hair mousse compositions becomes and is more difficult to occur.In addition, hair mousse compositions demonstrates good thixotropy, and therefore the coating of hair mousse compositions improves.

When share mentioned component (D) with mentioned component (E), mentioned component (D) is preferably 1:0.1 ~ 1:30 with the mass ratio (content of mentioned component (D): the content of mentioned component (E)) of mentioned component (E), is more preferably 1:0.2 ~ 1:20, more preferably 1:0.5 ~ 1:10.If meet above-mentioned mass ratio, then the storage stability of hair mousse compositions, storage stability when particularly preserving for a long time become better.

When share mentioned component (D) with mentioned component (E), the total amount of the content of mentioned component (D) and the content of mentioned component (E) is preferably more than 0.2 quality %, is more preferably more than 0.4 quality %, more preferably more than 0.6 quality %, is preferably below 10 quality %, is more preferably below 8 quality %, more preferably below 5 quality %.If in the scope of above-mentioned total amount, then the storage stability of hair mousse compositions, storage stability when particularly preserving for a long time become better.

(other compositions)

Hair mousse compositions of the present invention is not particularly limited, preferably comprises water.As long as in above-mentioned water cosmetics, water used is just not particularly limited, preferred pure water.In hair mousse compositions 100 quality % of the present invention, the content of water is preferably more than 30 quality %, is more preferably more than 40 quality %, is preferably below 95 quality %, is more preferably below 90 quality %.

In addition, hair mousse compositions of the present invention is not particularly limited, preferably comprises the lower alcohol (particularly ethanol) that carbon number is 2 ~ 5.In hair mousse compositions 100 quality % of the present invention, the content of lower alcohol (particularly ethanol) is preferably more than 2 quality %, is more preferably more than 5 quality %, is preferably below 50 quality %, is more preferably below 30 quality %.

Concerning hair mousse compositions of the present invention, also can comprise the surfactants such as such as non-ionic surface active agent, cationic surfactant and amphoteric surfactant in the scope not suppressing effect of the present invention; The polyhydric alcohol such as glycerol, 1,3 butylene glycol, propylene glycol, 1,2-butanediol, 1,2-pentanediol, 1,2-hexanediol, 1,2-ethohexadiol, 1,2-decanediol; The carbon numbers such as lauryl alcohol, myristyl alcohol, hexadecanol, stearyl alcohol, isooctadecanol, cetearyl alcohol and oily enol are the higher alcohol of 12 ~ 18; The sugar alcohols such as Sorbitol, maltose alcohol and trehalose; Silicone oil; Chelating agen; Antioxidant; Plant extract; Color element; Pigment; PH adjusting agent; Spice; Antiseptic; Solvent etc.

(other details of hair mousse compositions)

Being not particularly limited the character of hair mousse compositions of the present invention, can be any one in aqueous, gel, paste and solid, shaped.Above-mentioned hair mousse compositions is preferably aqueous or gel.In general, if use granule in aqueous or gelatinous hair mousse compositions, then the mobility of hair mousse compositions is high, the tendency that the dispersibility therefore with granule reduces.Its result, in above-mentioned aqueous or gelatinous hair mousse compositions, has initial stage power of haircuting and easily reduces with retentivity of haircuting, easily produces the tendency being clamminess and peeling off.On the other hand, by adopting the above-mentioned composition in hair mousse compositions of the present invention, even if aqueous or gelatinous hair mousse compositions, also can suppress the generation of peeling off and being clamminess, and can haircut at the initial stage of improving power and retentivity of haircuting.

The viscosity of 25 DEG C of above-mentioned hair mousse compositions is preferably more than 1000mPas, is more preferably more than 2000mPas, is preferably below 100000mPas, is more preferably below 50000mPas.When above-mentioned viscosity is below more than above-mentioned lower limit and the above-mentioned upper limit, coating improves further, and then the generation of peeling off and being clamminess is inhibited further, and the initial stage haircuts, power and retentivity of haircuting improve further.In above-mentioned hair mousse compositions, above-mentioned viscosity is below the above-mentioned upper limit, even if mobility is high, also can suppresses the generation of peeling off and be clamminess, and can haircut at the initial stage of improving power and retentivity of haircuting.

Above-mentioned viscosity utilizes viscometer, uses No.4 rotor to measure with rotary speed 12rpm, the rotational time condition of 1 minute.As above-mentioned viscometer, the TV-22 type viscometer that Dong Ji industry society manufactures can be used.

The manufacture method of hair mousse compositions of the present invention is not particularly limited, as the manufacture method of hair mousse compositions of the present invention, the manufacture method of known hair mousse compositions can be used.As the manufacture method of hair mousse compositions of the present invention, be not particularly limited, such as can enumerate following method: after utilizing dispersing mixer to stir composition (A) and water (also having composition (E) as required), be replaced with arm mixer and stir other compositions of mixture and homogenization.

Hair mousse compositions of the present invention at least comprises composition (A) and composition (B) as main composition of haircuting.Only utilize to produce time composition (B) and be clamminess, on the other hand, by share composition (A) and composition (B), can while suppressing to be clamminess the initial stage after just haircuting of improving to haircut power, and can retentivity of haircuting be improved.In addition, by being used in 25 DEG C for liquid composition and composition (B), the generation of peeling off (phenomenon seeming hair is attached with white powder or overlay film) can be suppressed when haircuting.Thus, if use hair mousse compositions of the present invention, can not only haircut well, and the state for extended periods of haircuting can be made to continue well.

In addition, by compounding ingredients (C), power of haircuting and the inhibition of peeling off improve further, and then give the effect of gloss to the hair after haircuting and washing away property improves.

In addition, by compounding ingredients (D) and composition (E), hair mousse compositions is by appropriate thickening, and the coating of hair mousse compositions improves.In addition, by making the mix ratio of composition (D) and composition (E) be specific preferable range, composition (A) becomes and is difficult to sedimentation or gathering, and the storage stability (stability during long-term preservation) of hair mousse compositions improves.

Hair mousse compositions of the present invention is not particularly limited, such as, can uses with the form be filled in container.

As said vesse, bottle container, can container and tubular container etc. can be enumerated.Said vesse is preferably bottle container or tubular container.

(embodiment)

Below, embodiment is enumerated and comparative example is specifically described the present invention.The present invention is not limited only to following embodiment.

Following compositions is employed in embodiment and comparative example.

(composition (A))

Trade name " Sylysia 320 ": silicon dioxide, Fuji Silysia Chemical society manufacture

Trade name " AEROSIL 200 ": silicon dioxide, NIPPON AEROSIL society manufacture

Trade name " spherical HAP ": hydroxyapatite (peaceful Chemical Industries society manufactures)

Trade name " FLORITE R ": calcium silicates (manufacture of Fu Tian pharmacy society)

Trade name " synthetic aluminium silicate (heavy) ": aluminium silicate (manufacture of Fu Tian pharmacy society)

Trade name " magnesium hydroxide (heavy) ": magnesium hydroxide (manufacture of Fu Tian pharmacy society)

(composition (B))

Trade name " Newpol 75H-90000 ": polyoxyethylene polyoxypropylene glycol ether, Sanyo change into the manufacture of industrial society, number-average molecular weight 14000, liquid state

Trade name " Newpol SP-750 ": polyoxypropylene Sorbitol, Sanyo change into the manufacture of industrial society, number-average molecular weight 690, liquid state

Trade name " Newpol 50HB-55 ": polyoxyethylene polyoxypropylene butyl ether, Sanyo change into the manufacture of industrial society, number-average molecular weight 300, liquid state

(composition (C))

Trade name " Noigen GIS-125 ": isostearic acid polyoxyethylene glyceride, the first industrial pharmaceutical society manufacture

Trade name " MACBIOBRIDE MG-10P ": PP 25, You society manufacture

(composition (D))

Trade name " Aculyn 22 ": alkyl acrylate alkyl methacrylate methacrylic acid polyoxyethylene stearyl base ether (20E.O.) copolymer emulsion, the manufacture of DOW Chemical society, 30 quality % aqueous solutions

Trade name " Aculyn 28 ": alkyl acrylate alkyl methacrylate methacrylic acid polyoxyethylene docosyl ether (25E.O.) copolymer emulsion, the manufacture of DOW Chemical society, 20 quality % aqueous solutions

Trade name " Aculyn 33A ": alkyl acrylate copolymer emulsion, the manufacture of DOW Chemical society, 28 quality % aqueous solutions

Trade name " Aculyn 38 ": alkyl acrylate vinyl neodecanoate cross linked polymer, the manufacture of DOW Chemical society, 29 quality % aqueous solutions

(composition (D '))

Trade name " ECHO GUM T ": xanthan gum, large SUMITOMO CHEMICAL pharmacy society manufacture

(composition (E))

Trade name " LAPONITE XL21 ": hexafluosilicic acid (sodium/magnesium), Rockwood society manufacture

Trade name " LAPONITE XLG ": synthetic silicic acid (sodium/magnesium), Rockwood society manufacture

(embodiment 1 ~ 44 and comparative example 1 ~ 13)

Compounding ingredients (mixture unit is quality %) shown in following table 1 ~ 8 of mixture, prepares hair mousse compositions.The character of the hair mousse compositions obtained in embodiment 1 ~ 44 is gel.It should be noted that, the blend amount in table represents with actual blend amount (blend amount of commodity).

Obtained hair mousse compositions is filled in plastic container, obtains hair mousse.

(test example 1: the evaluation of being clamminess)

Above-mentioned hair mousse compositions is applied on the hair of wig (exercise anthropometric dummy: YUKARI Japan society manufactures) by 20 professional judging panels equably, along wig shape from front to back combing hair to implement to haircut, answer afterwards with or without being clamminess.According to above-mentioned answer, evaluate being clamminess according to following benchmark.

The metewand > that < is clamminess

Zero (fairly good): answer without being clamminess for more than 16 in 20

△ (well): answer without being clamminess for 10 ~ 15 in 20

× (bad): answer without being clamminess for less than 9 in 20

(test example 2: initial stage haircut the evaluation of power)

Above-mentioned hair mousse compositions is applied on the hair of wig (exercise anthropometric dummy: YUKARI Japan society manufactures) by 20 professional judging panels equably, along wig shape from front to back combing hair to implement to haircut, answer afterwards and to haircut power with or without the initial stage.It should be noted that, when the shape of the hair arranged obviously is kept, be evaluated as and there is the initial stage haircut power.According to above-mentioned answer, according to following benchmark, the initial stage power of haircuting is evaluated.

The < initial stage haircuts the metewand > of power

Zero (fairly good): answer and have the initial stage to haircut power for more than 16 in 20

△ (well): in 20,10 ~ 15 answers have the initial stage to haircut power

× (bad): answer and have the initial stage to haircut power for less than 9 in 20

(test example 3: the evaluation of retentivity of haircuting)

20 professional judging panels observed the hair implementing the wig of haircuting after above-mentioned test example 2 evaluation of power (initial stage haircut) after 6 hours, answered with or without retentivity of haircuting.It should be noted that, the carrying out of test example 2 haircut after hair shape when being continued to keep, be judged to be that there is retentivity of haircuting.According to above-mentioned answer, according to following benchmark, retentivity of haircuting is evaluated.

< haircuts the metewand > of retentivity

Zero (fairly good): in 20, more than 16 answers have retentivity of haircuting

△ (well): in 20,10 ~ 15 answers have retentivity of haircuting

× (bad): in 20, less than 9 answers have retentivity of haircuting

(test example 4: the evaluation of peeling off)

20 professional judging panels after above-mentioned test example 3 (evaluation of retentivity of haircuting) with finger tip by the hair of wig from continuous 5 combing of the root of hair to sending out a tip, answer with or without peeling off.It should be noted that, when seeming hair to be attached with white lead, be judged to peel off.According to above-mentioned answer, evaluate peeling off according to following benchmark.

The metewand > that < peels off

Zero (fairly good): answer without peeling off for more than 16 in 20

△ (well): answer without peeling off for 10 ~ 15 in 20

× (bad): answer without peeling off for less than 9 in 20

(test example 5: the evaluation of washing away property)

20 professional judging panels use shampoo (trade name " LUCIDOshampoo ", Man Dan society manufacture) with the hair of warm water cleaning wig, to carry out drying afterwards above-mentioned test example 4 (evaluation of peeling off) afterwards, whether well answer washing away property.It should be noted that, when hair during hair washing is without rough sense and sticky feeling, be evaluated as washing away property good.According to above-mentioned answer, according to following benchmark, washing away property is evaluated.

The metewand > of washing away property of <

Zero (fairly good): in 20, more than 16 washing away property of answer are good

△ (well): in 20,10 ~ 15 washing away property of answer are good

× (bad): in 20, less than 9 washing away property of answer are good

(test example 6: the evaluation of gloss)

The hair that 20 professional judging panels answer wig after above-mentioned test example 2 evaluation of power (initial stage haircut) has tarnish.According to above-mentioned answer, according to following benchmark, gloss is evaluated.

The metewand > of the gloss of < hair

Zero (fairly good): answer glossy for more than 16 in 20

△ (well): in 20,10 ~ 15 answers are glossy

× (bad): in 20, less than 9 answers are glossy

Show the result in following table 1 ~ 8.Compounding ingredients in each embodiment of table 1 ~ 8 and each comparative example add up to 100 quality %.

[table 1]

[table 2]

[table 3]

[table 4]

[table 5]

[table 6]

[table 7]

[table 8]

Claims (6)

1. a hair mousse compositions, it comprises following compositions A and following compositions B,

The content of described composition A is below more than 0.1 quality % 10 quality %,

Composition A: be selected from the granule in the group be made up of silicon dioxide, calcium carbonate, magnesium carbonate, hydroxyapatite, titanium dioxide, zinc oxide, calcium silicates, magnesium silicate, aluminium silicate and magnesium hydroxide;

Composition B: be selected from by being liquid and number-average molecular weight is the polyoxyethylene/polyoxypropylene copolymer of less than more than 10,000 20000 and the compound in the group that 25 DEG C be liquid state and the polyoxypropylene Sorbitol that number-average molecular weight is less than more than 300 1000 forms at 25 DEG C.

2. hair mousse compositions as claimed in claim 1, wherein, the content of described composition B is below more than 3 quality % 40 quality %.

3. hair mousse compositions as claimed in claim 1 or 2, it comprises following compositions C further,

Composition C: be selected from the compound in the group be made up of polyoxyalkylene alkyl glucoside and polyoxyalkylene fatty acid glyceride.

4. the hair mousse compositions according to any one of claims 1 to 3, it comprises the components D as the polymer be selected from the group that is made up of following compositions D1 and following compositions D2 further,

Components D 1: use the polymer being selected from the two or more monomer in the group be made up of (methyl) acrylic acid and (methyl) alkyl acrylate and obtaining as necessary monomer component;

Components D 2: the polymer that the monomer in using the monomer that is selected from the group be made up of (methyl) acrylic acid and (methyl) alkyl acrylate and being selected from the group that is made up of (methyl) acrylic acid polyoxyethylene alkyl ether, itaconic acid polyoxyethylene alkyl ether and vinyl neodecanoate obtains as necessary monomer component.

5. the hair mousse compositions according to any one of Claims 1 to 4, it comprises the composition E as clay mineral further.

6. hair mousse compositions as claimed in claim 4, it comprises the composition E as clay mineral further,

The mass ratio of the content of described components D and the content of described composition E is 1:0.1 ~ 1:30.