CN109862868A - Hair styling agent composition - Google Patents

Abstract

The present invention provides a kind of hair styling agent composition, 1) can be realized increases the volume of hair, and 2) forms a plurality of fine, soft fur beam, and 3) gather the high-quality green tea of fine, soft fur beam, and 4) to fine, soft fur Shu Jinhang moulding.Hair styling agent composition according to the present invention, contain silica (ingredient A), selected from being 10000 or more and 20000 polyoxyethylene/polyoxypropylene random copolymers below by number-average molecular weight and number-average molecular weight is the compound (ingredient B) for the group that 300 or more and 1000 polyoxypropylene D-sorbites below form, Crodaret (ingredient C) and (eicosane diacid/tetracosandioic acid) polyglycerol ester (ingredient D), mentioned component A, mentioned component B, the content of mentioned component C and mentioned component D are in a specific range, the content of mentioned component D relative to the content of mentioned component A mass ratio in a specific range.

Description

Hair styling agent composition

Technical field

The present invention relates to a kind of hair styling agent compositions suitable for the hair styling agent arranged to hair.

Background technique

In order to arrange the hair styling agent composition of hair and the various characters such as use liquid, gel, paste and solid-like. In the past, in order to assign the power of haircuting as major function to hair styling agent composition, polymer and forms polymer is used mostly.It is using In the hair styling agent composition of polymer and forms polymer, after haircuting, due to polymer and forms polymer in the surface shape of hair At overlay film.Therefore, if haircuting ingredient as main and cooperating polymer and forms polymer, the initial stage after hair had just been arranged Power of haircuting improves, on the other hand, if exist be difficult to that hair arrange in the state of nature or after haircuting with hand or Comb, which applies hair, stimulates the problems such as then overlay film makes appearance be deteriorated from the sur-face peeling (generating so-called peeling) of hair.

Therefore, the method different from the method for polymer and forms polymer is used is studied, specifically, to using The method that powder assigns power of haircuting to hair styling agent composition is studied.

In following patent documents 1, discloses and specific surface area is contained for 50m with 0.1~10 mass %²/ g's or more is micro- The hair cosmetic composition (hair styling agent composition) of particle powder.In patent document 1, following content is described: by with specific Above-mentioned content can get good sense of touch, can get excellent power of haircuting, and can using specific above-mentioned microparticle powder Continue good sense of touch for a long time, and can get excellent haircuting property again.In patent document 1, it describes as haircuting Power and enable to hand, comb pass through like that compliantly arrange hair content.

In following patent documents 2, a kind of hair styling agent composition is disclosed, is contained: selected from by silica, carbonic acid The group of calcium, magnesium carbonate, hydroxyapatite, titanium oxide, zinc oxide, calcium silicates, magnesium silicate, alumina silicate and magnesium hydroxide composition Particle (ingredient (A)), selected from by number-average molecular weight be 10000 or more and 20000 polyoxyethylene/polyoxypropylenes below it is random Copolymer and number-average molecular weight are the compound of the group of 300 or more and 1000 polyoxypropylene D-sorbite compositions below (ingredient (B)) and acrylic copolymer (ingredient obtained from Diacetone Acrylamide is used as necessary monomer component (C))。

In following patent documents 3, a kind of hair styling agent composition is disclosed, is contained: selected from by silica, carbonic acid The group of calcium, magnesium carbonate, hydroxyapatite, titanium oxide, zinc oxide, calcium silicates, magnesium silicate, alumina silicate and magnesium hydroxide composition Particle (ingredient (A)), ethylene oxide average addition molal quantity be 40~60 Crodaret (ingredient (B1)), Crodaret (ingredient (B2)), trimethyl of the average addition molal quantity of ethylene oxide for 80~120 Glycine and/or SY-P 400 (ingredient (C)) and water (ingredient (D)).

Existing technical literature

Patent document

Patent document 1: Japanese Unexamined Patent Publication 2003-342130 bulletin

Patent document 2:WO2015/174130A1

Patent document 3: Japanese Unexamined Patent Publication 2017-19728 bulletin

Summary of the invention

Problem to be solved by the invention

In recent years, the diversification for form of haircuting continues to develop, and haircuts form and having used has difference according to required The hair styling agent composition for performance of haircuting.

For example, requiring form of haircuting as follows as one of form is haircuted: increase the volume of hair, and 2) formation A plurality of fine, soft fur beam, 3) gather the high-quality green tea of fine, soft fur beam, and 4) to fine, soft fur Shu Jinhang moulding.

Sometimes 1) can not sufficiently be coped with by hair styling agent composition documented by patent document 1 increases the volume of hair Add, 2) a plurality of fine, soft fur beam of formation, 3) gather the high-quality green tea of fine, soft fur beam, 4) to form of haircuting as fine, soft fur Shu Jinhang moulding.

By hair styling agent composition documented by patent document 1 be difficult to play it is above-mentioned 1)~4) whole effects.

In addition, in patent document 2,3, without especially record about play it is above-mentioned 1)~4) whole effects it is interior Hold.The combination for the effect recorded in patent document 2,3 from it is above-mentioned 1)~4) the combination of effect it is different.

The purpose of the present invention is to provide a kind of hair styling agent composition, 1) can be realized increases the volume of hair, and 2) a plurality of fine, soft fur beam of formation, 3) gather the high-quality green tea of fine, soft fur beam, and 4) to fine, soft fur Shu Jinhang moulding.

The method for solving problem

The present invention provides a kind of hair styling agent composition, containing following compositions (A), following compositions (B), following compositions (C) with And following compositions (D), the content of mentioned component (A) is 0.1 mass % or more and 5.0 mass % are hereinafter, mentioned component (B's) contains Amount is 1.0 mass % or more and 10.0 mass % hereinafter, the content of mentioned component (C) is 5.0 mass % or more and 25.0 matter % is measured hereinafter, the content of mentioned component (D) is 5.0 mass % hereinafter, the content of mentioned component (D) is relative to mentioned component (A) Content mass ratio be 0.1 or more.

Ingredient (A): silica

Ingredient (B): selected from random for 10000 or more and 20000 polyoxyethylene/polyoxypropylenes below by number-average molecular weight Copolymer and number-average molecular weight are the compound of the group of 300 or more and 1000 polyoxypropylene D-sorbite compositions below

Ingredient (C): Crodaret

Ingredient (D): (eicosane diacid/tetracosandioic acid) polyglycerol ester

Preferably, hair styling agent composition according to the present invention contains following compositions (E), and the content of mentioned component (E) is 0.05 mass % or more and 2.0 mass % or less.

Ingredient (E): (hydroxy-ethyl acrylate/methoxyethyl acrylate) copolymer

Hair styling agent composition according to the present invention preferably comprises following compositions (F).

Ingredient (F): clay mineral

Hair styling agent composition according to the present invention preferably comprises following compositions (G).

Ingredient (G): polysaccharide based compound

Invention effect

Hair styling agent composition according to the present invention contains specific ingredient (A), ingredient (B), ingredient (C) and ingredient (D), the content of ingredient (A) is 0.1 mass % or more and 5.0 mass % hereinafter, the content of ingredient (B) is 1.0 mass % or more And 10.0 mass % hereinafter, the content of ingredient (C) is 5.0 mass % or more and 25.0 mass % hereinafter, the content of ingredient (D) is 5.0 mass % therefore can be realized hereinafter, the content of ingredient (D) relative to the mass ratio of the content of ingredient (A) is 0.1 or more 1) increase the volume of hair by (that is, forming the towering hair style containing air), and 2) form a plurality of fine, soft fur beam, 3) make fine, soft fur The high-quality green tea of beam is gathered, and 4) to fine, soft fur Shu Jinhang moulding (that is, be arbitrarily bent to pieces and carry out moulding).In this hair In bright, volume after 1) haircuting can be played and increased, 2) a plurality of fine, soft fur beam of formation, 3) gather the high-quality green tea of fine, soft fur beam, and also it is 4) right As fine, soft fur Shu Jinhang moulding 1)~4 whole effects).As a result, passing through above-mentioned 1)~4) effect shape At form of haircuting in, can haircut well.Related hair styling agent composition according to the present invention, for example, can make Volume increases hair on the whole, and forms a plurality of fine, soft fur beam, and can further be formed and make these fine, soft fur beams Xiang Suiji Direction bending and carry out moulding " as scalded hair " hair style.

Specific embodiment

The present invention is described in detail below.

Hair styling agent composition according to the present invention at least contain silica, selected from by number-average molecular weight be 10000 with Upper and 20000 polyoxyethylene/polyoxypropylene random copolymers below and number-average molecular weight are 300 or more and 1000 below Compound (at least one compound), the Crodaret and (two of the group of polyoxypropylene D-sorbite composition Eicosane diacid/tetracosandioic acid) polyglycerol ester.

In the present specification, above-mentioned " silica " is known as to " ingredient (A) " sometimes.

In the present specification, sometimes by it is above-mentioned " selected from by number-average molecular weight be 10000 or more and 20000 polyoxies below Ethylene/polyoxypropylene random copolymer and number-average molecular weight are 300 or more and 1000 polyoxypropylene D-sorbite groups below At group compound " be known as " ingredient (B) ".

In the present specification, above-mentioned " Crodaret " is known as to " ingredient (C) " sometimes.

In the present specification, above-mentioned " (eicosane diacid/tetracosandioic acid) polyglycerol ester " is known as " ingredient sometimes (D)”。

Hair styling agent composition according to the present invention preferably comprises (hydroxy-ethyl acrylate/methoxyethyl acrylate) copolymerization Object.

In the present specification, be sometimes known as above-mentioned " (hydroxy-ethyl acrylate/methoxyethyl acrylate) copolymer " " at Divide (E) ".

Hair styling agent composition according to the present invention preferably comprises clay mineral.

In the present specification, above-mentioned " clay mineral " is known as to " ingredient (F) " sometimes.

Hair styling agent composition according to the present invention preferably comprises polysaccharide based compound.

In the present specification, above-mentioned " polysaccharide based compound " is known as " ingredient (G) " sometimes.

Hair styling agent composition according to the present invention at least contains ingredient (A), ingredient (B), ingredient (C) and ingredient (D). Hair styling agent composition according to the present invention is preferably also containing the group for selecting free component (E), ingredient (F) and ingredient (G) composition The ingredient (at least one ingredient) of group.Hair styling agent composition according to the present invention preferably comprise select free component (F) and at Divide the ingredient (at least one ingredient) of the group of (G) composition.Hair styling agent composition according to the present invention preferably comprises ingredient (A), the whole of ingredient (B), ingredient (C), ingredient (D), ingredient (E), ingredient (F) and ingredient (G).It is according to the present invention whole Hair agent composition can also contain other compositions.Mentioned component, for example, ingredient (A), ingredient (B), ingredient (C), ingredient (D), at Divide (E), ingredient (F), ingredient (G), other compositions that one kind can be used only respectively, also can be used two or more.

Hereinafter, being illustrated to the details of each ingredient used in hair styling agent composition according to the present invention.

(ingredient (A))

Ingredient (A) is silica (silica).One kind can be used only in ingredient (A), also can be used together two or more.

Ingredient (A) is haircuted ingredient and is functioned as main.Ingredient (A) increases hair volume.

As ingredient (A), known usual silica (silicic acid anhydride) can be used.Above-mentioned silica can be not Silicic acid anhydride (hydrophilic silica) through silicic acid anhydride, is also possible to hydrophobization silicic acid anhydride.In addition, above-mentioned dioxy SiClx can be the silica being surface-treated by amino acid, ester or lecithin etc..In addition, above-mentioned silica can To be so-called easy disintegrating silica dioxide granule.One kind can be used only in above-mentioned silica, also can be used two or more.

Above-mentioned hydrophobization silicic acid anhydride is that silicic acid anhydride (for example, untreated silicic acid anhydride) is obtained through silicic acid anhydride Substance.As the inorganic agent used in silicic acid anhydride, organic silane compound and silicone compounds etc. can be enumerated as. As above-mentioned organic silane compound, methyl trichlorosilane, dimethyldichlorosilane, trim,ethylchlorosilane, pregnancy can be enumerated as Base disilazane, methyl trialkoxysilane, dimethyldialkylammonium oxysilane, trimethylalkyoxys iotalane, ethyl trichlorosilane, Propyltrichlorosilan, hexyl trichlorosilane, chain alkyl trichlorosilane, ethyltrialkoxysilanes, propyl trialkoxy silane, Hexyl trialkoxy silane, chain alkyl trialkoxy silane, methacryl base silane, fluoroalkyl silanes and perfluor alkane Base silane etc..As above-mentioned silicone compounds, dimethyl polysiloxane (silicone oil), methyl phenyl silicone, first can be enumerated as Base hydrogen polysiloxanes and amino modified silicone etc..As the method for above-mentioned silicic acid anhydride, well known method can be used.Make For the method for above-mentioned silicic acid anhydride, liquid phase method, vapor phase method and autoclave method etc. can be enumerated as.

As the preference of above-mentioned hydrophobization silicic acid anhydride, dimethyl siloxane silicic acid anhydride, front three can be enumerated as Radical siloxane base silicic acid anhydride, octyl siloxy group silicic acid anhydride, the silicic acid anhydride and metering system handled through silicone oil Acyl group siloxy group silicic acid anhydride etc..

Above-mentioned easy disintegrating silica dioxide granule is multiple silica primary particle set and the particle formed.As Above-mentioned silica primary particle, is not particularly limited, such as can be enumerated as spherical silica particle, flakey silica Particle and amorphous silica particles etc..The average grain diameter of above-mentioned silica primary particle is not particularly limited.

In addition, above-mentioned easy disintegrating silica dioxide granule can within ingredient of the packet other than silica.As above-mentioned Ingredient (hereinafter, sometimes referred to as " insourcing ingredient ") other than silica, is not particularly limited, such as can be enumerated as surface Activating agent, polyalcohol, higher alcohol, sugar alcohol, silicone oil, metal ion chelation agent, antioxidant, plant extract extract, dyestuff, face Material, fragrance, moisturizer, vitamins, amino acids and freshener etc..In these ingredients, preferred amino acid class, silicone oil, Vitamins.It as above-mentioned amino acids, is not particularly limited, two sodium lauroyl glutamate of lysine can be enumerated as (for example, the rising sun Be melted into Chemical Co., Ltd. manufacture, trade name " pellicer "), trimethylglycine and glutamic acid etc..Above-mentioned easy disintegrating Silica dioxide granule states insourcing ingredient by interior wrap, interior if the disintegration of above-mentioned easy disintegrating silica dioxide granule when haircuting to wrap Ingredient is released, to play effect corresponding with the type of insourcing ingredient.For example, above-mentioned easy disintegrating silica dioxide granule is logical Interior packet amino acids are crossed, the damage maintenance function of hair can be played.

It as the manufacturing method of above-mentioned easy disintegrating silica dioxide granule, is not particularly limited, well known side can be used Method.

The oil absorption of ingredient (A) is preferably 100mL/100g or more, more preferably 150mL/100g or more, further preferably For 200mL/100g or more, preferably 1000mL/100g hereinafter, more preferably 800mL/100g is hereinafter, further preferably 700mL/100g or less.If, can in range of the oil absorption of ingredient (A) more than above-mentioned lower limit and below the above-mentioned upper limit Inhibit the reduction of the hair volume as caused by the fat constituent on the hairs such as scalp grease, the reduction of haircuting property, so that haircuting Property (initial haircuting property) and haircuting property is better again.

Above-mentioned oil absorption is based on method documented by JIS K 5101 and is measured.

The average grain diameter (average primary particle diameter) of ingredient (A) is preferably 0.1nm or more, more preferably 5nm or more, preferably 10 μm hereinafter, more preferably 5 μm or less.If the average grain diameter of ingredient (A) is more than above-mentioned lower limit and the above-mentioned upper limit is below In range, then made into when haircuting due to the intermolecular force or the electrostatic adhesive force that work between multiple ingredients (A) (A) is divided to be easy to further mutually each other, the shape that the surface after haircuting as hair is covered more well by a large amount of ingredient (A) State, and further increase haircuting property.

The average grain diameter (average primary particle diameter) of ingredient (A) is volume average particle size.Above-mentioned average grain diameter is able to use base It is measured in the particle size distribution device of laser diffraction.As above-mentioned particle size distribution device, hole field can be enumerated as " LA-920 " etc. of manufacturing company's manufacture.

As the commercially available product of above-mentioned silica, for example, the FUJI SILYSIA chemistry as silicic acid anhydride can be enumerated as Company's manufacture, trade name " SYLYSIA 320 ", trade name " SYLYSIA 310P ", trade name " SYLYSIA 250 ", commodity Name " SYLYSIA 250N ", trade name " SYLYSIA 350 ", trade name " SYLYSIA 370 ", trade name " SYLYSIA 380 ", Trade name " SYLYSIA 420 ", trade name " SYLYSIA 430 ", trade name " SYLYSIA 440 ", trade name " SYLYSIA 450 " and trade name " SYLYSIA 470 "；Japanese AEROSIL company as silicic acid anhydride manufactures, trade name " AEROSIL50 ", trade name " AEROSIL 90G ", trade name " AEROSIL 130 ", trade name " AEROSIL 150 ", commodity Name " AEROSIL 200 ", trade name " AEROSIL 300 ", trade name " AEROSIL 380 ", trade name " AEROSIL 200V " And trade name " AEROSIL OX50 "；AGC Si-Tech company as silicic acid anhydride manufactures, trade name " SUNSPHERE H-31 ", trade name " SUNSPHERE H-51 ", trade name " SUNSPHERE H-121 ", trade name " SUNSPHERE H-201 ", Trade name " SUNSPHERE H-32 ", trade name " SUNSPHERE H-52 ", trade name " SUNSPHERE H-122 ", trade name " SUNSPHERE H-33 " and trade name " SUNSPHERE H-53 "；Japan as dimethyl siloxane silicic acid anhydride That AEROSIL company manufactures, trade name " AEROSIL R972 ", trade name " AEROSIL R974 " and trade name " AEROSIL R9200"；Japanese AEROSIL company as trimethylsiloxane group silicic acid anhydride manufactures, trade name " AEROSIL RX200 ", trade name " AEROSIL R8200 ", trade name " AEROSIL RX300 " and trade name " AEROSIL R812S "； Japanese AEROSIL company as octyl siloxy group silicic acid anhydride manufactures, trade name " AEROSIL R805 "；As warp The Japanese AEROSIL company manufacture of the silicic acid anhydride of silicone oil processing, trade name " AEROSIL R202 ", trade name " AEROSIL RY200 ", trade name " AEROSIL RY200S " and trade name " AEROSIL RY300 "；As methacryl radical siloxane The Japanese AEROSIL company manufacture of base silicic acid anhydride, trade name " AEROSIL R711 "；As above-mentioned easy disintegrating dioxy The three of SiClx are melted into well company's manufacture, trade name " silica beads SB-705 "；As above-mentioned easy disintegrating silica That Suzuki grease company manufactures, trade name " Godd Ball SF-16C ", trade name " Godd Ball AF-6C " and trade name " Godd Ball AF-16C " etc..

From the viewpoint of making hair volume increase, by hair styling agent composition according to the present invention be 100 mass % in terms of, The content of ingredient (A) is 0.1 mass % or more and 5.0 mass % or less.From making the increased viewpoint of hair volume more well Set out, be 100 mass % by hair styling agent composition according to the present invention in terms of, the content of ingredient (A) be preferably 0.5 mass % with On, more preferably 0.8 mass % or more, preferably 4.0 mass % are hereinafter, more preferably 3.0 mass % or less.

(ingredient (B))

Ingredient (B) be selected from by number-average molecular weight be 10000 or more and 20000 polyoxyethylene/polyoxypropylenes below without It advises copolymer and number-average molecular weight is the compound for the group that 300 or more and 1000 polyoxypropylene D-sorbites below form (at least one compound).One kind can be used only in ingredient (B), two or more can also be used in combination.

Ingredient (B) plays the role of gathering the high-quality green tea of fine, soft fur beam.Ingredient (B) be formed with by ingredient (C) it is a plurality of In the state of fine, soft fur beam, gather the high-quality green tea of fine, soft fur beam.By using ingredient (B), can impart luster to the hair.In addition, logical It crosses using ingredient (B), is able to suppress peeling and plays said effect.

In the present specification, " number-average molecular weight is 10000 or more and 20000 polyoxyethylene below/poly- by above-mentioned sometimes Oxypropylene random copolymer " is known as " ingredient (B1) ".

In the present specification, sometimes by it is above-mentioned " number-average molecular weight be 300 or more and 1000 polyoxypropylene sorboses below Alcohol " is known as " ingredient (B2) ".

Thus, ingredient (B) is the compound (at least oneization for the group for selecting free component (B1) and ingredient (B2) to form Close object).One kind can be used only in ingredient (B1) and ingredient (B2) respectively, also can be used two or more.

Ingredient (B1) is that at least have multiple ethylene oxide units (ethylene oxide unit) and (oxidation third of multiple oxypropylene units Alkene unit) copolymer.Copolymerization form in ingredient (B1) is the form of random copolymer.

Average addition molal quantity in ingredient (B1), ethylene oxide does not have specific limitation, preferably 100 or more, more preferably It is 200 or more, preferably 400 hereinafter, more preferably 350 or less.Average addition molal quantity in ingredient (B1), oxypropylene does not have It is particularly limited to, preferably 30 or more, more preferably 40 or more, preferably 150 hereinafter, more preferably 100 or less.

From the viewpoint of further increasing the effect for gathering the high-quality green tea of fine, soft fur beam, preferred component (B1) is at 25 DEG C Liquid.

The number-average molecular weight of ingredient (B1) is 10000 or more and 20000 or less.If the number-average molecular weight of ingredient (B1) is insufficient Above-mentioned lower limit, the then effect for gathering the high-quality green tea of fine, soft fur beam reduce.If the number-average molecular weight of ingredient (B1) is more than the above-mentioned upper limit, Operability is deteriorated.The number-average molecular weight of ingredient (B1) is preferably 12000 or more.The number-average molecular weight of ingredient (B1) is preferably 18000 or less.

As the commercially available product of ingredient (B1), such as the manufacture of chemical conversion industry company, Sanyo, trade name " NEWPOL can be enumerated as 75H-90000 " etc..

Ingredient (B2) is polyoxypropylene D-sorbite.Average addition molal quantity in ingredient (B2), oxypropylene is without spy It does not limit, preferably 4 or more, more preferably 8 or more, preferably 15 hereinafter, more preferably 12 or less.

From the viewpoint of further increasing the effect for gathering the high-quality green tea of fine, soft fur beam, preferred component (B2) is at 25 DEG C Liquid.

The number-average molecular weight of ingredient (B2) is 300 or more and 1000 or less.If in the number-average molecular weight deficiency of ingredient (B2) Lower limit is stated, then the effect for gathering the high-quality green tea of fine, soft fur beam reduces.If the number-average molecular weight of ingredient (B2) is more than the above-mentioned upper limit, become Obtain tacky, operability variation.The number-average molecular weight of ingredient (B2) is preferably 400 or more.The number-average molecular weight of ingredient (B2) is preferred It is 800 or less.

As the commercially available product of ingredient (B2), such as the manufacture of chemical conversion industry company, Sanyo, trade name " NEWPOL can be enumerated as SP-750 " and trade name " SANNIX SP-750 " etc..

Preferred component (B) is in a liquid state at 25 DEG C.Preferred component (B) has mobility at 25 DEG C, such as preferably has Following character: radius be 2cm, highly be 7cm vial in put into the sample of 50g, 25 DEG C at a temperature of, will be above-mentioned In the inverted situation of vial, 5 minutes from after rigid be inverted, sample is dripped from vial.

From the viewpoint of gathering the high-quality green tea of fine, soft fur beam, with hair styling agent composition according to the present invention for 100 matter Measure % meter, the content of ingredient (B) is 1.0 mass % or more, preferably 2.0 mass % or more, more preferably 3.0 mass % with On.From the sight for inhibiting the hair after haircuting to become weight and inhibit the effect to form fine, soft fur beam, reduce the increased effect of hair volume Point, be 100 mass % by hair styling agent composition according to the present invention in terms of, the content of ingredient (B) is 10.0 mass % hereinafter, excellent 9.0 mass % are selected as hereinafter, more preferably 8.0 mass % or less.

(ingredient (C))

Ingredient (C) is Crodaret.One kind can be used only in ingredient (C), two or more can also be used in combination.

Ingredient (C) plays the role of forming a plurality of fine, soft fur beam.

From the viewpoint of being effectively formed a plurality of fine, soft fur beam, ingredient (C) preferably comprises the average addition mole of ethylene oxide The Crodaret that number is 40~60 preferably comprises the polyoxy that the average addition molal quantity of ethylene oxide is 80~120 Ethylene hydrogenation castor oil, the further preferably average addition molal quantity of ethylene oxide be 40~60 Crodaret and The Crodaret that the average addition molal quantity of ethylene oxide is 80~120.

In the present specification, sometimes by it is above-mentioned " the average addition molal quantity of ethylene oxide be 40~60 it is polyethylene glycol hydrogenated Castor oil " is known as " ingredient (C1) ".

In the present specification, sometimes by it is above-mentioned " the average addition molal quantity of ethylene oxide be 80~120 it is polyethylene glycol hydrogenated Castor oil " is known as " ingredient (C2) ".

Thus, ingredient (C) preferably comprises ingredient (C1), preferably comprises ingredient (C2).Ingredient (C) preferably comprise selected from by Divide the Crodaret (at least one Crodaret) of the group of (C1) and ingredient (C2) composition. Ingredient (C) further preferably ingredient (C1) and ingredient (C2).One kind can be used only in ingredient (C1) and ingredient (C2) respectively, It can be used two or more.

By using ingredient (C1) and ingredient (C2), while sufficiently improving the characteristic for gathering hair each other, into one Step, which improves, inhibits effect that is tacky, hardening.

From the viewpoint of being effectively formed a plurality of fine, soft fur beam, the average of ethylene oxide (ethylene oxide) in ingredient (C1) adds It is preferably 40 or more at molal quantity, more preferably 45 or more, preferably 60 hereinafter, more preferably 55 or less.

From the viewpoint of being effectively formed a plurality of fine, soft fur beam, the HLB (Hydrophile-Lipophile of ingredient (C1) Balance) value is preferably 11.5 or more, and preferably 14.8 or less.

As the commercially available product of ingredient (C1), such as the manufacture of green wood oil rouge industrial group, trade name can be enumerated as " Blaunon RCW-50 " (average addition molal quantity of ethylene oxide: 50)；Japanese Emulsion company manufacture, trade name " EMALEX HC-50 " (average addition molal quantity of ethylene oxide: 50)；The manufacture of green wood oil rouge industrial group, trade name " Blaunon RCW-40 " (average addition molal quantity of ethylene oxide: 40)；The manufacture of green wood oil rouge industrial group, trade name " Blaunon RCW-60 " (the average addition molal quantity of ethylene oxide: 60) etc..

From the viewpoint of being effectively formed a plurality of fine, soft fur beam, the average of ethylene oxide (ethylene oxide) in ingredient (C2) adds It is preferably 80 or more, more preferably 90 or more, preferably 120 hereinafter, more preferably 110 or less at molal quantity.

From the viewpoint of being effectively formed a plurality of fine, soft fur beam, the HLB value of ingredient (C2) is preferably 15.0 or more, preferably 17.0 or less.

As the commercially available product of ingredient (C2), such as the manufacture of green wood oil rouge industrial group, trade name can be enumerated as " Blaunon RCW-100 " (average addition molal quantity of ethylene oxide: 100)；Japanese Emulsion company manufacture, trade name " EMALEX HC-100 " (average addition molal quantity of ethylene oxide: 100)；The manufacture of green wood oil rouge industrial group, trade name " Blaunon RCW-100 " (the average addition molal quantity of ethylene oxide: 100), the manufacture of green wood oil rouge industrial group, trade name " Blaunon RCW-80 " (the average addition molal quantity of ethylene oxide: 80) etc..

From the viewpoint of forming a plurality of fine, soft fur beam, be 100 mass % by hair styling agent composition according to the present invention in terms of, The content of ingredient (C) is preferably 5.0 mass % or more and 25.0 mass % or less.From the viewpoint for being effectively formed a plurality of fine, soft fur beam Set out, be 100 mass % by hair styling agent composition according to the present invention in terms of, the content of ingredient (C) be preferably 6.0 mass % with On, more preferably 8.0 mass % or more, preferably 20.0 mass % are hereinafter, more preferably 16.0 mass % or less.

(ingredient (D))

Ingredient (D) is (eicosane diacid/tetracosandioic acid) polyglycerol ester.One kind can be used only in ingredient (D), can also be with It is two or more to be used in combination.

Ingredient (D) plays the effect to fine, soft fur Shu Jinhang moulding, specifically, playing is bent pieces to arbitrary direction And moulding is carried out, and keep the effect of the shape.

As long as the glyceryl quantity in ingredient (D) is 2 or more, it is not particularly limited.Above-mentioned glyceryl quantity is 2 More than, preferably 3 or more, more preferably 5 or more, preferably 12 hereinafter, more preferably 10 or less.

As ingredient (D), (eicosane diacid/tetracosandioic acid) two glyceride, (eicosane diacid/14 can be enumerated as Docosandioic acid) glyceryl ester, (eicosane diacid/tetracosandioic acid) four glyceride, (eicosane diacid/tetracosandioic acid) five glycerol Ester, (eicosane diacid/tetracosandioic acid) six glyceride, (eicosane diacid/tetracosandioic acid) seven glyceride, (eicosane two Acid/tetracosandioic acid) eight glyceride, (eicosane diacid/tetracosandioic acid) nine glyceride, (eicosane diacid/tetradecane two Acid) ten glyceride, (eicosane diacid/tetracosandioic acid) ten monoglyceryl esters and (eicosane diacid/tetracosandioic acid) 12 Glyceride etc..Also (eicosane diacid/tetracosandioic acid) polyglycerol ester in addition to this can be used.Ingredient (D) is preferably (two Eicosane diacid/tetracosandioic acid) ten glyceride [20 carbon of Natrulon H-10, two acid esters/14 carbon, two acid esters].

As ingredient (D), commercially available product can be used.As the commercially available product of ingredient (D), Neosolue-Aqua can be enumerated as (trade name, (eicosane diacid/tetracosandioic acid) ten glyceride, Japan refine company manufacture) etc..

It hardens from the viewpoint of inhibiting hair to be hardened to improving the feel of hair, with hair styling agent according to the present invention Composition is 100 mass % meter, and the content of ingredient (D) is 5.0 mass % hereinafter, preferably 4.0 mass % are hereinafter, more preferably 3.5 mass % or less.

From the viewpoint of to fine, soft fur Shu Jinhang moulding, the mass ratio of the content of ingredient (D) relative to the content of ingredient (A) (content of content/ingredient (A) of ingredient (D)) is 0.1 or more.From the viewpoint of effectively to fine, soft fur Shu Jinhang moulding, on Stating mass ratio (content of content/ingredient (A) of ingredient (D)) is preferably 0.15 or more, and more preferably 0.2 or more.

(ingredient (E))

Ingredient (E) is (hydroxy-ethyl acrylate/methoxyethyl acrylate) copolymer.One kind can be used only in ingredient (E), It two or more can also be used in combination.

Ingredient (E) facilitates effectively to fine, soft fur Shu Jinhang moulding.

As (hydroxy-ethyl acrylate/methoxyethyl acrylate) copolymer of ingredient (E), it is also known as acrylic acid hydroxyl second Ester methoxyethyl acrylate copolymer.Ingredient (E) is from the structural unit of hydroxy-ethyl acrylate and from third Copolymer of the structural unit of olefin(e) acid methoxy acrylate as necessary structural unit.Ingredient (E) is, for example, with INCl: HYDROXYETHYL ACRYLATE/METHOXYETHYL ACRYLATE COPOLYMER (hydroxy-ethyl acrylate/acrylic acid methoxy Base methacrylate copolymers) indicate compound.

In order to effectively play the fiting effect of ingredient (E), the number-average molecular weight of ingredient (E) is preferably 5500 or more, excellent It is selected as 50000 or less.

As the commercially available product of ingredient (E), trade name " the Plascize L- of mutual induction chemical industrial company manufacture can be enumerated as 2200 " etc..

From the viewpoint of effectively to fine, soft fur Shu Jinhang moulding, with hair styling agent composition according to the present invention be 100 Quality % meter, the content of ingredient (E) is preferably 0.05 mass % or more, more preferably 0.08 mass % or more, further preferably For 0.2 weight % or more.It hardens from the viewpoint of inhibiting hair to be hardened to improving the feel of hair, with involved in the present invention Hair styling agent composition be 100 mass % meter, the content of ingredient (E) is preferably 2.0 mass % hereinafter, more preferably 1.5 matter % is measured hereinafter, further preferably 1.2 mass % or less.

(ingredient (F))

Ingredient (F) is clay mineral.By using ingredient (F), so that carrying out the initial stage power of haircuting of plastotype to hair, haircuting The storage stability of agent composition becomes more good.One kind can be used only in ingredient (F), also can be used two or more.

Ingredient (F) can be natural goods, be also possible to synthetic.It as ingredient (F), is not particularly limited, such as can arrange It lifts and is taken off for kaolin group's clay mineral, antigorite race clay mineral, pyrophyllite race clay mineral, Mica Group clay mineral, illiteracy Stone race clay mineral, vermiculite race clay mineral, chlorite race clay mineral and organo-clay mineral etc..

As above-mentioned kaolin group's clay mineral, kaolin, nacrite, dickite and galapectite etc. can be enumerated as. As above-mentioned antigorite race clay mineral, antigorite, pictoamesite, cronstedtite etc. can be enumerated as.As above-mentioned pyrophyllite Race's clay mineral can be enumerated as pyrophyllite and talcum (Talc) etc..As above-mentioned Mica Group clay mineral, Erie can be enumerated as Stone, glauconite, celadonite, sericite, mica (Mica), muscovite, fuchsite and biotite etc..It is viscous as montmorillonite race Native mineral can be enumerated as bentonite, montmorillonite, beidellite, nontronite, saponite, hectorite and synthetic li-montmorillonite etc..Make For above-mentioned vermiculite race clay mineral, vermiculite etc. can be enumerated as.As above-mentioned chlorite race clay mineral, chlorite can be enumerated as (Chlorite) etc..As above-mentioned organo-clay mineral, smectite clays mineral or vermiculite race clay pit can be enumerated as Object etc. is through organo-clay mineral etc. made of organically-modified processing., it is preferable to use quaternary in organically-modified processing Cationic surfactant.As above-mentioned quaternary ammonium salt cationic surfactant, abovementioned alkyl trimethyl ammonia chloride can be enumerated as Ammonium, dialkyl dimethyl ammonium chloride and benzalkonium chloride etc..

From the viewpoint of making storage stability, use feeling more good, ingredient (F) is preferably selected from by synthetic silicic acid The clay mineral of the group of salt and its derivative composition.Above-mentioned synthetic silicate and its derivative refer to, not containing many miscellaneous Matter from natural with silicate minerals as main component such as magnesium silicate, silicic acid (sodium/magnesium), but obtained by synthesis Silicate and silicate derivative.

As above-mentioned synthetic silicate and its derivative, such as INCl (International can be enumerated as Cosmetic Ingredient Dictionary and Handbook, the 14th edition, volume 2,2012, p.3076): Synthetic silicic acid represented by SODIUM MAGNESIUM SILICATE (sodium magnesium silicate) (sodium/magnesium), INCl (International Cosmetic Ingredient Dictionary and Handbook, the 14th edition, volume 2,2012 Year, p.1793): magnesium fluosilicate represented by MAGNESIUM FLUOROSILICATE (magnesium fluosilicate), INCl (International Cosmetic Ingredient Dictionary and Handbook, the 14th edition, volume 2,2012 Year, p.3076): fluosilicic acid (sodium/magnesium) represented by SODIUM MAGNESIUM FLUOROSILICATE (magnesium fluosilicate sodium), INCl (International Cosmetic Ingredient Dictionary and Handbook, the 14th edition, the 2nd Volume, 2012, p.1799): fluorine silicon represented by MAGNESIUM POTASSIUM FLUOROSILICATE (potassium fluosilicate magnesium) Sour (magnesium/potassium), INCl (International Cosmetic Ingredient Dictionary and Handbook, the 14 editions, volume 2,2012, p.1800): represented by MAGNESIUM SODIUM FLUOROSILICATE (prodan magnesium) Fluosilicic acid (magnesium/sodium), INCl (International Cosmetic Ingredient Dictionary and Handbook, the 14th edition, volume 1,2012, p.156): synthetic silicic acid represented by ALUMINUM SILICATE (alumina silicate) Aluminium etc..

As ingredient (F), in clay mineral, particularly preferably selected from by synthetic silicic acid (sodium/magnesium), fluosilicic acid (sodium/ Magnesium) and fluosilicic acid (sodium/magnesium) composition group clay mineral (at least one clay mineral).

As the commercially available product of ingredient (F), such as the trade name " Laponite of Rockwood company manufacture can be enumerated as XLG " and trade name " Laponite XL21 " etc..

By hair styling agent composition according to the present invention be 100 mass % in terms of, the content of ingredient (F) is preferably 0.1 matter Measure % or more, more preferably 0.3 mass % or more, further preferably 0.5 mass % or more, preferably 10.0 mass % with Under, more preferably 5.0 mass % are hereinafter, further preferably 3.0 mass % or less.When the content of ingredient (F) is above-mentioned lower limit When above, storage stability and haircuting property become more good.When the content of ingredient (F) is the above-mentioned upper limit or less, haircut The storage stability of agent composition becomes more good.

(ingredient (G))

Ingredient (G) is polysaccharide based compound.By using ingredient (G), keep hair styling agent composition according to the present invention suitable Degree ground thickening, therefore the dispersibility of ingredient (A) becomes more good, and then hair styling agent composition according to the present invention becomes not It is easily separated and storage stability is made to become more good.One kind can be used only in ingredient (G), also can be used two or more.

It as ingredient (G), is not particularly limited, preferably polysaccharide, modification of polysaccharides (for example, alkyl-modified polysaccharide etc.) etc., Such as can be enumerated as alginic acid, carragheen, agar, furcellaran, guar gum, Wen Quince seed glue, konjacmannan, tamarind gum, Tara gum, dextrin, starch, locust bean gum, gum arabic, ghatti gum, karaya gum, bassora gum, arabinogalactan Sugar, pectin Yi are Ji Wen Quince (marmelo) etc. derives from the polysaccharide based compound of plant；Chitosan and hyaluronic acid etc. derive from The polysaccharide based compound of animal；Curdlan (Curdlan), xanthan gum, gellan gum, cyclodextrin, glucan, pulullan polysaccharide with And hyaluronic acid etc. derives from the polysaccharide based compound of microorganism；Microcrystalline cellulose, methylcellulose, ethyl cellulose, hydroxyl first The non-ionic celluloses such as base cellulose, hydroxyethyl cellulose, hydroxypropyl cellulose and hydroxypropyl methyl cellulose element；Carboxymethyl The anionic celluloses such as cellulose element；The cations such as chlorination O- [2- hydroxyl -3- (trimethyl ammonium) propyl] hydroxyethyl cellulose Cellulose；Cationizations guar gums such as chlorination O- [2- hydroxyl -3- (trimethyl ammonium) propyl] guar gum etc..

As ingredient (G), in polysaccharide based compound, it is preferably selected from by xanthan gum, guar gum, tamarind gum and knot The compound (at least one compound) of the group of cold glue composition.

As the commercially available product of ingredient (G), for example, can be enumerated as xanthan gum big SUMITOMO CHEMICAL drugmaker manufacture Trade name " Echogum T ", trade name " Keldent " and trade name " Monat Gum "；Her that food work as guar gum The trade name " Inagel guar gum CS " of industry company manufacture；DSP GOKYO FOOD&CHEMICAL as tamarind gum Co., the trade name " Glyloid 6C " of Ltd. manufacture；The trade name of CP Kelco U.S., Inc. manufacture as gellan gum " Kelcogel " etc..

By hair styling agent composition according to the present invention be 100 mass % in terms of, the content of ingredient (G) is preferably 0.01 matter % or more is measured, more preferably 0.05 mass % or more, preferably 5.0 mass % are hereinafter, more preferably 2.0 mass % or less.When When the content of ingredient (G) is above-mentioned lower limit or more, the storage stability of hair styling agent composition becomes more good.As ingredient (G) Content be the above-mentioned upper limit below when, further suppress tacky.The content of ingredient (G) is hair styling agent combination according to the present invention The total amount of the content of whole ingredients (G) in object.

Stablize from the preservation for viscosifying hair styling agent composition further moderately and further increase hair styling agent composition From the perspective of property, hair styling agent composition according to the present invention preferably comprises ingredient (F) and ingredient (G).Pass through using ingredient (F) and ingredient (G), the dispersion stabilization of ingredient (A) is further increased, is not readily separated hair styling agent composition more.Further Ground, hair styling agent composition shows good thixotropy, therefore the coating of hair styling agent composition improves.

In the case where using ingredient (F) and ingredient (G), the quality of the content of ingredient (F) relative to the content of ingredient (G) Be preferably 1.0 or more than (content of content/ingredient (G) of ingredient (F)), more preferably 2.0 or more, preferably 10.0 hereinafter, More preferably 8.0 or less.If meeting the range of above-mentioned mass ratio, can further suppress it is tacky so that hair styling agent combine The storage stability of object, especially long-term keeping when storage stability become more good.

In the case where using ingredient (F) and ingredient (G), with hair styling agent composition according to the present invention for 100 matter % meter is measured, the total amount of the content of the content and ingredient (G) of ingredient (F) is preferably 0.3 mass % or more, more preferably 0.4 matter % or more is measured, preferably 5.0 mass % are hereinafter, more preferably 4.0 mass % or less.If in the range of above-mentioned total amount, Can further suppress it is tacky so that the storage stability of hair styling agent composition, especially long-term keeping when preservation stablize Property become more good.

(other compositions)

Hair styling agent composition according to the present invention preferably comprises water.Above-mentioned water is preferably Purified Water.Involved by the present invention And hair styling agent composition be 100 mass % meter, the content of water is preferably 30.0 mass % or more, more preferably 40.0 mass % More than, preferably less than 84.9 mass %, more preferably 83.0 mass % hereinafter, further preferably 80.0 mass % or less.

In addition, hair styling agent composition according to the present invention, although being not particularly limited, from improve anti-corrosion ability, Improve coating when ductility, reduce it is tacky from the perspective of, preferably comprise carbon atom number be 2~5 lower alcohol (especially second Alcohol).By hair styling agent composition according to the present invention be 100 mass % in terms of, the content of lower alcohol (especially ethyl alcohol) is preferably 2.0 mass % or more, more preferably 5.0 mass % or more, preferably 50.0 mass % hereinafter, more preferably 30.0 mass % with Under.

Hair styling agent composition according to the present invention can contain in a range that does not hinder the effect of the present invention: for example, The surfactants such as nonionic surfactant, cationic surfactant and amphoteric surfactant；Glycerol, 1,3- fourth two The polyalcohols such as alcohol, propylene glycol, 1,2- butanediol, 1,2- pentanediol, 1,2- hexylene glycol, 1,2- ethohexadiol, Decane-1,2-diol；Laurel The carbon atom numbers such as alcohol, myristyl alcohol, cetanol, stearyl alcohol, isooctadecanol, cetostearyl alcohol and oleyl alcohol be 12~18 it is advanced Alcohol；The sugar alcohols such as D-sorbite, maltitol and trehalose；Silicone oil；Metal ion chelation agent；Antioxidant；Plant mentions Take object；Dyestuff；Pigment；PH adjusting agent；Fragrance；Preservative；Solvent etc..

(other details of hair styling agent composition)

The character of hair styling agent composition according to the present invention is not particularly limited, can for liquid, gel, paste with And solid-like is any.Above-mentioned hair styling agent composition is preferably liquid or gel.

Viscosity at 25 DEG C of above-mentioned hair styling agent composition is preferably 1000mPas or more, more preferably 2000mPas More than, preferably 100000mPas is hereinafter, more preferably 50000mPas or less.When above-mentioned viscosity is more than above-mentioned lower limit And when below the above-mentioned upper limit, coating is further increased, and then is further inhibited tacky.

Using viscosimeter and No.4 rotor is used, is come under conditions of rotation speed is 12rpm, rotational time is 1 minute Measure above-mentioned viscosity.As above-mentioned viscosimeter, the TV-22 type viscosimeter of Dong Ji industry companies manufacture can be used.

The manufacturing method of hair styling agent composition according to the present invention is not particularly limited, as according to the present invention whole The manufacturing method for sending out agent composition, can be used the manufacturing method of well known hair styling agent composition.As according to the present invention The manufacturing method of hair styling agent composition, such as following method can be enumerated as: by ingredient (A) and water (further addition as needed Ingredient (F)) be stirred using dispersator after, be changed to paddle stirrer cooperate while being stirred other at Divide and homogenizes.

Hair styling agent composition according to the present invention haircuts ingredient and at least contains ingredient (A), ingredient as main (B), ingredient (C) and ingredient (D).By cooperating mentioned component (A)~(D) with specified amount, it can be realized following effect: 1) making The volume of hair increases, and 2) forms a plurality of fine, soft fur beam, and 3) gather the high-quality green tea of fine, soft fur beam, and 4) fine, soft fur Shu Jinhang is made Type.In the present invention, a plurality of fine, soft fur beam can play 1) that volume increases after haircuting, 2) is formed, 3) keep the high-quality green tea of fine, soft fur beam poly- Hold together, and 4) to as fine, soft fur Shu Jinhang moulding 1)~4) whole effects.As a result, can haircut well to want Ask it is above-mentioned 1)~4) effect form of haircuting.

Play 1)~4) effect haircut form be, for example, keep curved fine, soft fur Shu Chaoxiang random direction have body The hair style of long-pending hair style, the curly hair style as scalding hair.

It further, can be effectively to fine, soft fur Shu Jinhang moulding by gradation composition (E).

Further, by gradation composition (F) and ingredient (G), viscosify hair styling agent composition moderately, raising is haircuted The coating of agent composition.Further, by the way that the match ratio of ingredient (F) and ingredient (G) is set as specific preferred scope It is interior, so that ingredient (A) is not susceptible to sedimentation, agglutination, to improve the storage stability of hair styling agent composition (when long-term keeping Stability).

Hair styling agent composition according to the present invention, is particularly limited to, such as can be made in the form of being filled in container With.

As said vesse, flask, tank container, tubular container etc. can be enumerated as.In said vesse, preferably Flask or tubular container.

Embodiment

Hereinafter, enumerating embodiment and the present invention is specifically described in comparative example.The present invention is not limited in following Embodiment.

(ingredient (A))

Trade name " SYLYSIA 320 ": silica 1 (manufacture of FUJI SILYSIA chemical company)

Trade name " AEROSIL 300 ": silica 2 (Japanese AEROSIL company manufacture)

(ingredient (B))

Trade name " NEWPOL SP-750 ": polyoxypropylene D-sorbite, the manufacture of chemical conversion industry company, Sanyo, the equal molecule of number Amount is 690, liquid

Trade name " NEWPOL 75H-90000 ": polyoxyethylene polyoxypropylene hexylene glycol ether (300E.O.) (75P.O.), three It foreignizes into industrial group to manufacture, number-average molecular weight 14000, liquid

(ingredient (C))

Crodaret (100E.O.): the manufacture of green wood oil rouge industrial group, trade name " Blaunon RCW- 100 ", the average addition molal quantity of ethylene oxide is 100, PEG-100 rilanit special

Crodaret (60E.O.): the manufacture of green wood oil rouge industrial group, trade name " Blaunon RCW- 60 ", the average addition molal quantity of ethylene oxide is 60, PEG-60 rilanit special

Crodaret (50E.O.): the manufacture of green wood oil rouge industrial group, trade name " Blaunon RCW- 50 ", the average addition molal quantity of ethylene oxide is 50, PEG-50 rilanit special

(ingredient (D))

20 carbon of Natrulon H-10, two acid esters/14 carbon, two acid esters: trade name " Neosolue-Aqua ", Japan refine company Manufacture

(ingredient (E))

(hydroxy-ethyl acrylate/methoxyethyl acrylate) copolymer: trade name " Plascize L-2200 ", mutual induction Learn industrial group's manufacture.

(ingredient (F))

Fluosilicic acid (sodium/magnesium): the manufacture of Rockwood company, trade name " Laponite XL21 "

(ingredient (G))

Xanthan gum: big SUMITOMO CHEMICAL drugmaker manufacture, trade name " Echogum T "

(other compositions)

Glycerol

Dipropylene glycol

Ethyl alcohol

Purified Water

(embodiment 1~11 and comparative example 1~5)

Cooperate gradation composition shown in following tables 1, table 2 (unit of fit is quality %), prepares hair styling agent composition.? The character of hair styling agent composition obtained in embodiment 1~11 is gel.In addition, indicating table with the use level of pure component In use level.

(evaluation)

Obtained hair styling agent composition is uniformly coated to wig (the practice manikin: YUKARI of moderate-length JAPAN company manufacture) hair on, the hair from being combed upward the root of hair to high-quality green tea.Later, holding hair keeps its curved Song simultaneously carries out moulding and implements after haircuting, and observes hair, and the determinating reference carried out based on evaluation 1~4 below To be evaluated.In addition, carrying out the judgement of evaluation 1~4 after just haircuting and after 2 hours.By 5 specialty evaluation persons into Row evaluation.

(evaluation 1: the increased evaluation of volume)

[the increased determinating reference of volume]

Zero (fairly good): pieces is erected from root, forms the hair style that volume obviously increases on the whole

△ (good): pieces is slightly erected from root, forms the slightly increased hair style of volume on the whole

× (bad): pieces is not erected from root, and volume absolutely not increases on the whole

(evaluation 2: the evaluation of the formative of fine, soft fur beam)

[determinating reference of the formative of fine, soft fur beam]

Zero (fairly good): fine, soft fur beam has been formed uniformly it

△ (good): fine, soft fur beam and pieces thicker to a certain degree are formed with

× (bad): fine, soft fur beam is not formed

(evaluation 3: the evaluation of the high-quality green tea of fine, soft fur beam gathered)

[criterion of the high-quality green tea of fine, soft fur beam gathered]

Zero (fairly good): the high-quality green tea of fine, soft fur beam is ideally gathered

△ (good): gathering for the high-quality green tea of fine, soft fur beam is slightly weak

× (bad): the high-quality green tea of fine, soft fur beam is not gathered, and high-quality green tea scatters

(evaluation 4: the evaluation of the moulding power of fine, soft fur beam)

[determinating reference of the moulding power of fine, soft fur beam]

Zero (fairly good): the basic hair style kept after moulding, moulding power are strong

△ (good): the hair style after moulding is slightly collapsed, and moulding power is slightly weak

× (bad): before the moulding of pieces is almost back to haircuting, moulding power is insufficient

Show the result in following tables 1, table 2.

Table 1

Table 2

Claims (4)

1. a kind of hair styling agent composition, containing following compositions A, following compositions B, following compositions C and following compositions D,

The content of the ingredient A be 0.1 mass % or more and 5.0 mass % hereinafter,

The content of the ingredient B be 1.0 mass % or more and 10.0 mass % hereinafter,

The content of the ingredient C be 5.0 mass % or more and 25.0 mass % hereinafter,

The content of the ingredient D be 5.0 mass % hereinafter,

The content of the ingredient D is 0.1 or more relative to the mass ratio of the content of the ingredient A,

Ingredient A: silica,

Ingredient B: being selected from by number-average molecular weight is 10000 or more and 20000 polyoxyethylene/polyoxypropylene random copolymers below And number-average molecular weight is the compound of the group of 300 or more and 1000 polyoxypropylene D-sorbite compositions below,

Ingredient C: Crodaret,

Ingredient D:(eicosane diacid/tetracosandioic acid) polyglycerol ester.

2. hair styling agent composition according to claim 1, which is characterized in that the hair styling agent composition contains following compositions E,

The content of the ingredient E be 0.05 mass % or more and 2.0 mass % hereinafter,

Ingredient E:(hydroxy-ethyl acrylate/methoxyethyl acrylate) copolymer.

3. hair styling agent composition according to claim 1 or 2, which is characterized in that under the hair styling agent composition also contains Ingredient F is stated,

Ingredient F: clay mineral.

4. hair styling agent composition described in any one of claim 1 to 3, which is characterized in that the hair styling agent composition Also contain following compositions G,

Ingredient G: polysaccharide based compound.