CN106102695A - Hair mousse composition - Google Patents

Hair mousse composition Download PDF

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Publication number
CN106102695A
CN106102695A CN201580012525.XA CN201580012525A CN106102695A CN 106102695 A CN106102695 A CN 106102695A CN 201580012525 A CN201580012525 A CN 201580012525A CN 106102695 A CN106102695 A CN 106102695A
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Prior art keywords
composition
mentioned
hair
mass
mentioned component
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CN201580012525.XA
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CN106102695B (en
Inventor
冈本将典
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Mandom Corp
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Mandom Corp
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    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/0241—Containing particulates characterized by their shape and/or structure
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/24—Phosphorous; Compounds thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/25—Silicon; Compounds thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/26—Aluminium; Compounds thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/27—Zinc; Compounds thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/29—Titanium; Compounds thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • A61K8/8158—Homopolymers or copolymers of amides or imides, e.g. (meth) acrylamide; Compositions of derivatives of such polymers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/86—Polyethers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Cosmetics (AREA)

Abstract

The present invention provides a kind of hair mousse composition, and it can suppress the generation peeled off and tacky when haircuting, and can improve and mould initial stage of hair style and haircut the confining force of haircuting after power and moulding.The hair mousse composition of the present invention comprises composition A, composition B and composition C with specific content, and this composition A is the particle in the group being made up of silica, calcium carbonate, magnesium carbonate, hydroxyapatite, titanium dioxide, zinc oxide, calcium silicates, magnesium silicate, alumina silicate and magnesium hydroxide；This composition B is the compound in the group that the polyoxyethylene/polyoxypropylene random copolymer being less than more than 10,000 20000 and the polyoxypropylene D-sorbite that number-average molecular weight is less than more than 300 1000 form by number-average molecular weight；This composition C is for using DAAM as acrylic acid series copolymer obtained from necessary monomer component.

Description

Hair mousse composition
Technical field
The present invention relates to the hair mousse composition of the hair mousse being suitable for arranging hair.
Background technology
In order to arrange hair, use the hair mousse composition of the various proterties such as aqueous, gel, paste and solid-like.With Past, in order to give the power of haircuting as major function to hair mousse composition, many use overlay films form polymer.Cover employing Film forms in the hair mousse composition of polymer, after haircuting, is derived from overlay film and forms polymer and formed on the surface of hair and cover Film.Therefore, if mixture overlay film forms polymer as composition of mainly haircuting, then the power of haircuting of the initial stage after just haircuting improves, but separately On the one hand, when being difficult to arrange hair with natural state, or with hand or comb etc., hair is stimulated after haircuting, cover Film can have the problems such as degraded appearance from the sur-face peeling (producing so-called peeling) of hair.
Therefore, the method different from the method using overlay film formation polymer is studied, specifically, be have studied Powder is used to give, to hair mousse composition, power of haircuting.
Patent Document 1 discloses a kind of hair cosmetic composition (hair mousse composition) following, its comprise 0.1 mass %～ The specific surface area of 10 mass % is 50m2The fine-particle powder of/more than g.Record the description below in patent document 1: by with spy Fixed above-mentioned content uses specific above-mentioned fine-particle powder, available good sense of touch, can get excellent power of haircuting, and can So that good sense of touch is long lasting for and available excellent haircuting property again.Patent document 1 has been recorded following in Hold: as the power of haircuting, mildly hair can be arranged in the way of hair is by hand or comb.
Prior art literature
Patent document
Patent document 1: Japanese Unexamined Patent Publication 2003-342130 publication
Content of the invention
Invention problem to be solved
But, as described in patent document 1, haircut using the hair mousse composition comprising fine-particle powder When, sometimes also can peel off.Additionally, there are the present situation requiring that the more excellent initial stage haircuts power with confining force of haircuting.
In addition, with regard to the power of haircuting, including mildly arrange hair in the way of hair is by hand or comb haircuts Power and make hair erect or mould the power etc. of haircuting of hair style, the power of haircuting includes some species.Under patent document 1 has been recorded State content: as the power of haircuting, mildly hair can be arranged in the way of hair is by hand or comb.In patent document 1 Record to haircut power from the power of haircuting making hair and erect or mould hair style be different.
It is an object of the invention to provide a kind of hair mousse composition, it can suppress the generation peeled off when haircuting With tacky, and can improve and mould initial stage of hair style and haircut the confining force of haircuting after power and moulding.
For solving the scheme of problem
The hair mousse composition of the present invention comprises following compositions (A), following compositions (B) and following compositions (C), described composition (A) content is below more than 0.05 mass % 7.0 mass %, and the content of described composition (B) is more than 3.0 mass % 35.0 matter Amount below %, the content of described composition (C) is below more than 0.10 mass % 3.0 mass %.
Composition (A): selected from by silica, calcium carbonate, magnesium carbonate, hydroxyapatite, titanium dioxide, zinc oxide, silicic acid Particle in the group of calcium, magnesium silicate, alumina silicate and magnesium hydroxide composition.
Composition (B): selected from by the polyoxyethylene/polyoxypropylene that number-average molecular weight is less than more than 10,000 20000 randomly altogether Polymers and number-average molecular weight are the compound in the group of the polyoxypropylene D-sorbite composition of less than more than 300 1000.
Composition (C): use DAAM as acrylic acid series copolymer obtained from necessary monomer component.
The hair mousse composition of the present invention preferably further comprises following compositions (D).
Composition (D): the change in the group being made up of polyoxyalkylene alkyl glucoside and polyoxyalkylene fatty acid glyceride Compound.
The hair mousse composition of the present invention preferably further comprises following compositions (E).
Composition (E): clay mineral.
The hair mousse composition of the present invention preferably further comprises following compositions (F).
Composition (F): polysaccharide based compound.
In the hair mousse composition of the present invention, the content of described composition (E) is excellent with the mass ratio of the content of described composition (F) Elect 2:1～10:1 as.
The effect of invention
The hair mousse composition of the present invention comprises specific composition (A), specific composition (B) and specific composition (C), enters And each content of composition (A), composition (B) and composition (C) is in the range of specific, therefore can suppress peel off to send out when haircuting Raw and tacky, and can improve and mould initial stage of hair style and haircut the confining force of haircuting after power and moulding.
Detailed description of the invention
Hereinafter, the present invention is described in detail.
The hair mousse composition of the present invention includes at least: selected from by silica, calcium carbonate, magnesium carbonate, hydroxyapatite, Particle in the group of titanium dioxide, zinc oxide, calcium silicates, magnesium silicate, alumina silicate and magnesium hydroxide composition；Selected from by several equal molecules Amount be less than more than 10,000 20000 polyoxyethylene/polyoxypropylene random copolymer and number-average molecular weight be more than 300 1000 Compound in the group of following polyoxypropylene D-sorbite composition；And use DAAM to become as necessary monomer Acrylic acid series copolymer obtained from Fen.
In this specification, sometimes by above-mentioned " selected from by silica, calcium carbonate, magnesium carbonate, hydroxyapatite, titanium dioxide Particle in the group of titanium, zinc oxide, calcium silicates, magnesium silicate, alumina silicate and magnesium hydroxide composition " is referred to as " composition (A) ".In addition, Sometimes by above-mentioned " selected from by the polyoxyethylene/polyoxypropylene random copolymer that number-average molecular weight is less than more than 10,000 20000, With the compound in the group of the polyoxypropylene D-sorbite composition that number-average molecular weight is less than more than 300 1000 " it is referred to as " composition (B)”.Additionally, sometimes by above-mentioned " number-average molecular weight be less than more than 10,000 20000 polyoxyethylene/polyoxypropylene randomly altogether Polymers " is referred to as " composition (B1) ", sometimes by above-mentioned the polyoxypropylene D-sorbite of less than more than 300 1000 " number-average molecular weight be " It is referred to as " composition (B2) ".In addition, sometimes " use DAAM as propylene obtained from necessary monomer component using above-mentioned Acid based copolymer " is referred to as " composition (C) ".
The hair mousse composition of the present invention preferably further comprises selected from by polyoxyalkylene alkyl glucoside and polyoxyalkylene Compound in the group of fatty acid glyceride composition.
In this specification, sometimes by above-mentioned " selected from by polyoxyalkylene alkyl glucoside and polyoxyalkylene fatty acid glyceride Compound in the group of composition " is referred to as " composition (D) ".In addition, sometimes above-mentioned " polyoxyalkylene alkyl glucoside " is referred to as " composition (D1) ", sometimes above-mentioned " polyoxyalkylene fatty acid glyceride " is referred to as " composition (D2) ".
The hair mousse composition of the present invention preferably further comprises clay mineral.In this specification, sometimes by above-mentioned " clay Mineral " are referred to as " composition (E) ".
The hair mousse composition of the present invention preferably further comprises polysaccharide based compound.In this specification, sometimes by above-mentioned " polysaccharide based compound " is referred to as " composition (F) ".
The hair mousse composition of the present invention is including at least composition (A), composition (B) and composition (C).The hair mousse group of the present invention Compound preferably further comprises to select free component (D), composition (E), and (at least one becomes with the composition in the group that composition (F) forms Point).In the case of using composition (E), preferably composition (E) is shared with composition (F).Wherein, the hair mousse combination of the present invention Thing preferably comprises whole composition (A), composition (B), composition (C), composition (D), composition (E) and composition (F).The hair mousse of the present invention Composition can comprise other compositions further.Mentioned component can only use a kind respectively, it is possible to use two or more.
It should be noted that mentioned component (B) is the compound in the group selecting free component (B1) and composition (B2) to form (at least one compound).In addition, mentioned component (D) is the compound in the group selecting free component (D1) and composition (D2) to form (at least one compound).Above-mentioned composition (B1), composition (B2), composition (D1), composition (D2) can only use a kind respectively, Also can be used two or more.
Hereinafter, the details of each composition using in the hair mousse composition of the present invention is illustrated.
(composition (A))
Mentioned component (A) for selected from by silica, calcium carbonate, magnesium carbonate, hydroxyapatite, titanium dioxide, zinc oxide, Particle (at least one particle) in the group of calcium silicates, magnesium silicate, alumina silicate and magnesium hydroxide composition.Mentioned component (A) is main Have that suppression is tacky, improve and mould initial stage of hair style and haircut the effect of the confining force of haircuting after power and moulding.In addition, by using Mentioned component (A), easily haircuts after once haircuting again, can also improve haircuting property again.It should be noted that it is above-mentioned Composition (A) is preferably the particle in addition to the composition suitable with composition (E).
As mentioned component (A), in above-mentioned particle, from further improve mould hair style performance of haircuting in terms of examine Consider, be preferably selected from being made up of silica, magnesium carbonate, hydroxyapatite, calcium silicates, magnesium silicate, alumina silicate and magnesium hydroxide Particle in group (at least one particle), be more preferably selected from the group being made up of silica, magnesium silicate and magnesium hydroxide Grain (at least one particle).Mentioned component (A) can only use a kind, it is possible to use two or more.
<silica>
As above-mentioned silica, it is possible to use known usual silica (silicic acid anhydride).Above-mentioned silica is permissible For the silicic acid anhydride (hydrophilic silica) that processes without hydrophobization or hydrophobization silicic acid anhydride.In addition, above-mentioned dioxy SiClx also can be for having carried out the silica of surface treatment with amino acid, ester or lecithin etc..In addition, above-mentioned silica is also So-called easy disintegrating silica dioxide granule can be.Above-mentioned silica can only use a kind, it is possible to use two or more.
Above-mentioned hydrophobization silicic acid anhydride for having carried out the material that hydrophobization is processed to silicic acid anhydride (for example untreated silicic acid anhydride). Inorganic agent used in processing as hydrophobization, can enumerate Organosilyl compound and silicone compounds etc..As upper State Organosilyl compound, methyl trichlorosilane, dimethyldichlorosilane, trim,ethylchlorosilane, hexamethyl can be enumerated Disilazane, methyl trialkoxysilane, dimethyldialkylammonium TMOS, trimethylalkyoxys iotalane, ethyl trichlorosilane, third Base trichlorosilane, hexyl trichlorosilane, chain alkyl trichlorosilane, ethyltrialkoxysilanes, propyl trialkoxy silane, oneself Base trialkoxy silane, chain alkyl trialkoxy silane, methacryl silanes, fluoroalkyl silanes and perfluoroalkyl silanes Deng.As above-mentioned silicone compounds, can enumerate dimethyl polysiloxane (silicone oil), methyl phenyl silicone, methyl hydrogen gather Siloxanes and amino modified silicone etc..The method processing as above-mentioned hydrophobization, it is possible to use known method.Dredge as above-mentioned The method of hydration process, can enumerate liquid phase method, vapor phase method and autoclave method etc..
As the preference of above-mentioned hydrophobization silicic acid anhydride, dimethyl silane epoxide SiClx acid anhydrides, trimethyl can be enumerated Siloxy SiClx acid anhydrides, octyl group siloxy SiClx acid anhydrides, silicone oil process silicic acid anhydride and methacrylic acid monosilane oxygen Base SiClx acid anhydrides etc..
Above-mentioned easy disintegrating silica dioxide granule is multiple silica primary particle set and the particle that formed.As upper State silica primary particle, be not particularly limited, for example, can enumerate spherical silica particles, flakey silica Grain and amorphous silica particles etc..The average grain diameter of above-mentioned silica primary particle is not particularly limited.
In addition, above-mentioned easy disintegrating silica dioxide granule can include silica beyond composition.As above-mentioned dioxy Composition (hereinafter sometimes referred to " component content ") beyond SiClx, is not particularly limited, for example, can enumerate surfactant, many Unit's alcohol, higher alcohol, sugar alcohol, silicone oil, chelating agent, antioxidant, plant extracts, pigment, pigment, spices, NMF, vitamin Class, amino acids and freshener etc..Wherein, preferred amino acid class, silicone oil, vitamins.As above-mentioned amino acids, there is no spy Do not limit, two (lauramide glutamine) lysine Na (for example, Asahi Chemical Corp's manufacture, commodity can be enumerated Name " pellicer "), trimethylglycine and glutamic acid etc..Above-mentioned interior by making above-mentioned easy disintegrating silica dioxide granule include Containing composition, if the above-mentioned easy disintegrating silica dioxide granule disintegration when haircuting, discharge component content, can give play to and include The corresponding effect of species of composition.For example, by above-mentioned easy disintegrating silica dioxide granule embedded amine groups acids, hair can have been given play to The damage nursing function sent out.
It as the manufacture method of above-mentioned easy disintegrating silica dioxide granule, is not particularly limited, it is possible to use known side Method.
The oil absorption of above-mentioned silica is preferably more than 100mL/100g, more preferably more than 150mL/100g, enters one Step is preferably more than 200mL/100g, preferably below 1000mL/100g, more preferably below 800mL/100g, excellent further Elect below 700mL/100g as.When the oil absorption of above-mentioned silica is below more than above-mentioned lower limit and the above-mentioned upper limit, moulds and send out The initial stage of type haircut power, institute's moulding hair haircut confining force and again haircuting property become more preferable.Above-mentioned oil absorption is according to JIS Method described in K5101 is measured.
As the commercially available product of above-mentioned silica, for example, can enumerate the Fuji Silysia as silicic acid anhydride Chemical society manufacture trade name " Sylysia 320 ", trade name " Sylysia 310P ", trade name " Sylysia 250 ", Trade name " Sylysia 250N ", trade name " Sylysia 350 ", trade name " Sylysia 370 ", trade name " Sylysia 380 ", trade name " Sylysia 420 ", trade name " Sylysia 430 ", trade name " Sylysia 440 ", trade name " Sylysia 450 " and trade name " Sylysia 470 "；The trade name manufacturing as the NIPPON AEROSIL society of silicic acid anhydride " AEROSIL50 ", trade name " AEROSIL 90G ", trade name " AEROSIL 130 ", trade name " AEROSIL 150 ", commodity Name " AEROSIL 200 ", trade name " AEROSIL 300 ", trade name " AEROSIL 380 ", trade name " AEROSIL 200V " With trade name " AEROSIL OX50 "；The trade name " Sunsphere H-31 " that manufactures as the AGC Si-Tech society of silicic acid anhydride, Trade name " Sunsphere H-51 ", trade name " Sunsphere H-121 ", trade name " Sunsphere H-201 ", trade name " Sunsphere H-32 ", trade name " Sunsphere H-52 ", trade name " Sunsphere H-122 ", trade name " Sunsphere H-33 " and trade name " Sunsphere H-53 "；NIPPON as dimethyl silane epoxide SiClx acid anhydrides Trade name " AEROSIL R972 ", trade name " AEROSIL R974 " and the trade name " AEROSIL that AEROSIL society manufactures R9200”；Trade name " the AEROSIL manufacturing as the NIPPON AEROSIL society of trimethylsiloxy SiClx acid anhydrides RX200 ", trade name " AEROSIL R8200 ", trade name " AEROSIL RX300 " and trade name " AEROSIL R812S "；Make The trade name " AEROSIL R805 " manufacturing for the NIPPON AEROSIL society of octyl group siloxy SiClx acid anhydrides；As silicone oil Process trade name " AEROSIL R202 ", trade name " AEROSIL RY200 " that the NIPPON AEROSIL society of silicic acid anhydride manufactures, Trade name " AEROSIL RY200S " and trade name " AEROSIL RY300 "；As the acid of methacrylic acid monosilane epoxide SiClx The trade name " AEROSIL R711 " that the NIPPON AEROSIL society of acid anhydride manufactures；As above-mentioned disintegrative silica three are good The trade name " silica beads SB-705 " that chemical conversion society manufactures；Suzuki grease society as above-mentioned disintegrative silica manufactures Trade name " God Ball SF-16C ", trade name " God Ball AF-6C " and trade name " God Ball AF-16C " etc..
<calcium carbonate>
Above-mentioned calcium carbonate for example represents with INCI name " CALCIUM CARBONATE ".Above-mentioned calcium carbonate can only use 1 Kind, it is possible to use two or more.As the commercially available product of above-mentioned calcium carbonate, for example, can enumerate the business that chemical industry society manufactures The name of an article " Calmaru SCS M5 "；The trade name " FUWACAL " etc. that shiraishi calcium society manufactures.
<magnesium carbonate>
Above-mentioned magnesium carbonate for example represents with INCI name " MAGNESIUM CARBONATE ".Above-mentioned magnesium carbonate can only use 1 Kind, it is possible to use two or more.As the commercially available product of above-mentioned magnesium carbonate, for example, can enumerate the commodity that Fu Tian pharmacy society manufactures Name " light magnesium carbonate " etc..
<hydroxyapatite>
Above-mentioned hydroxyapatite for example represents with INCI name " HYDROXYAPATITE ".Above-mentioned hydroxyapatite can only make With a kind, it is possible to use two or more.
It as above-mentioned hydroxyapatite, is not particularly limited, for example, can enumerate spherical hydroxyapatite, the hydroxyl of sheet Base apatite and amorphous hydroxyapatite etc..Wherein, haircut from the aspect of performance from having given play to the height moulding hair style, Preferably spherical hydroxyapatite.As the commercially available product of above-mentioned hydroxyapatite, for example, can enumerate peaceful Chemical Industries society system Trade name " sheet HAP ", trade name " spherical HAP ", trade name " HAP-100 ", trade name " HAP-200 " and the trade name made " HAP-300 " etc..
<titanium dioxide>
Above-mentioned titanium dioxide for example represents with INCI name " TITANIUM DIOXIDE ".To above-mentioned titanium dioxide not especially Limit, for example, can be fine particulate titanium dioxide or pigment titanium.Above-mentioned titanium dioxide can only use a kind, it is possible to so that Use two or more.As the commercially available product of above-mentioned titanium dioxide, for example, can enumerate stone and originate in the trade name " TTO-55 that industry society manufactures " and trade name " CR-50 " etc. (A).
<zinc oxide>
Above-mentioned zinc oxide for example represents with INCI name " ZINC OXIDE ".Above-mentioned zinc oxide can only use a kind, it is also possible to Use two or more.As the commercially available product of above-mentioned zinc oxide, for example, can enumerate the trade name that chemical industry society manufactures " FINEX-30S-LP2 " etc..
<calcium silicates>
Above-mentioned calcium silicates for example represents with INCI name " CALCIUM SILICATE ".Above-mentioned calcium silicates can only use a kind, Also can be used two or more.As the commercially available product of above-mentioned calcium silicates, for example, can enumerate the trade name that Fu Tian pharmacy society manufactures “FLORITE R”；Trade name " eakleite powder X-ray J " and trade name that JAPAN INSULATION CO., LTD. manufacture " are avenged Silicoglaserite powder TK " etc..
<magnesium silicate>
Above-mentioned magnesium silicate for example represents with INCI name " MAGNESIUM SILICATE ".Above-mentioned magnesium silicate can only use 1 Kind, it is possible to use two or more.As the commercially available product of above-mentioned magnesium silicate, for example, can enumerate the commodity that Fu Tian pharmacy society manufactures Name " magnesium silicate (lightweight) " etc..
<alumina silicate>
Above-mentioned alumina silicate for example represents with INCI name " ALUMINUM SILICATE ".Above-mentioned alumina silicate can only use 1 Kind, it is possible to use two or more.It as alumina silicate, is not particularly limited, preferably synthetic alumina silicate.As synthetic method, such as Can enumerate: in alum, add Na2SiO3And precipitated, by generate, the method being dried；Make silicic acid by electroosmose process molten Glue, thus generates the method for gel；And in waterglass, add the method for the aqueous solution of aluminium salt；Etc..As above-mentioned silicic acid The commercially available product of aluminium, for example, can enumerate the trade name " synthetic aluminium silicate (heavy) " that Fu Tian pharmacy society manufactures and trade name " synthesizes Alumina silicate (lightweight) " etc..
<magnesium hydroxide>
Above-mentioned magnesium hydroxide for example represents with INCI name " MAGNESIUM HYDROXIDE ".Above-mentioned magnesium hydroxide can be only Use a kind, it is possible to use two or more.As the commercially available product of above-mentioned magnesium hydroxide, for example, can enumerate Fu Tian pharmacy society and manufacture Trade name " magnesium hydroxide (heavy) " etc..
In hair mousse composition 100 mass % of the present invention, the content of mentioned component (A) be more than 0.05 mass %, Be preferably more than 0.07 mass %, more than more preferably 0.10 mass %, be below 7.0 mass %, be preferably 5.0 mass % with Under, below more preferably 4.0 mass %.Content by mentioned component (A) is more than above-mentioned lower limit, can improve further and mould Make initial stage of hair style to haircut power, and the confining force of haircuting after moulding can being improved further, and then can suppress further to send out Viscous.Content by mentioned component (A) is below the above-mentioned upper limit, prevents the effect peeled off, the effect giving gloss and washing away property Improve further.The content of mentioned component (A) is the total of the content of the whole compositions (A) in the hair mousse composition of the present invention Amount.
(composition (B))
Mentioned component (B) is at least one chemical combination in the group being made up of mentioned component (B1) and mentioned component (B2) Thing.Mentioned component (B) mainly has the effect of the confining force of haircuting after effectively improving moulding.In addition, by using mentioned component (B), can suppress to peel off, give play to the effect above.Additionally, by using mentioned component (B), gloss can be given to hair. Mentioned component (B) can only use a kind, it is possible to use two or more.It should be noted that mentioned component (B1), mentioned component (B2) also a kind can only be used respectively, it is possible to use two or more.
As mentioned component (B), can only use any one in mentioned component (B1) and mentioned component (B2), it is possible to To share mentioned component (B1) and mentioned component (B2).Wherein, can further suppress from while confining force is haircuted in raising Tacky aspect is set out, preferred component (B2).
Mentioned component (B1) is polyoxyethylene/polyoxypropylene random copolymer.That is, mentioned component (B1) is at least to have 2 Individual above ethylene oxide unit (ethylene oxide unit) and the copolymer of more than 2 propylene oxide units (propylene oxide unit). Copolymerization mode in mentioned component (B1) is the mode of random copolymer.
The average addition molal quantity of the ethylene oxide in mentioned component (B1) is not particularly limited, and preferably more than 100, more It is preferably more than 200, preferably less than 400, more preferably less than 350.Average to the propylene oxide in mentioned component (B1) Addition molal quantity is not particularly limited, preferably more than 30, particularly preferably more than 40, preferably less than 150, particularly preferably Less than 100.
In terms of suppression peeling, the coating easiness of hair mousse, the aspect giving gloss to hair, mentioned component (B1) preferably 25 DEG C be liquid.
The number-average molecular weight of mentioned component (B1) is less than more than 10,000 20000.The number-average molecular weight of mentioned component (B1) During less than above-mentioned lower limit, the initial stage moulding hair style haircuts power and confining force reduction of haircuting.The number-average molecular weight of mentioned component (B1) When exceeding the above-mentioned upper limit, treatability is deteriorated.The number-average molecular weight of mentioned component (B1) is preferably more than 12000.Mentioned component (B1) number-average molecular weight is preferably less than 18000.
Mentioned component (B2) is polyoxypropylene D-sorbite.Average addition to the propylene oxide in mentioned component (B2) rubs You are not particularly limited number, and preferably more than 4, more preferably more than 8, preferably less than 15, more preferably less than 12.
In terms of suppression peeling, the coating easiness of hair mousse, the aspect giving gloss to hair, mentioned component (B2) preferably 25 DEG C be liquid.
The number-average molecular weight of mentioned component (B2) is less than more than 300 1000.The number-average molecular weight of mentioned component (B2) is little When above-mentioned lower limit, the initial stage moulding hair style haircuts power and confining force reduction of haircuting.The number-average molecular weight of mentioned component (B2) surpasses When crossing the above-mentioned upper limit, producing tacky, treatability is deteriorated.The number-average molecular weight of mentioned component (B2) is preferably more than 400.Above-mentioned one-tenth The number-average molecular weight dividing (B2) is preferably less than 800.
Mentioned component (B) preferably 25 DEG C be liquid.Mentioned component (B) preferably has mobility at 25 DEG C, for example preferably There is following proterties: 50g sample is loaded in the vial of radius 2cm, highly 7cm, by above-mentioned glass at a temperature of 25 DEG C When bottle is reverse, when reverse latter 5 minutes, sample is from vial landing.
As the commercially available product of mentioned component (B1), for example, can enumerate the trade name that chemical conversion industry society of Sanyo manufactures " Newpol 75H-90000 " etc..
As the commercially available product of mentioned component (B2), for example, can enumerate the trade name that chemical conversion industry society of Sanyo manufactures " Newpol SP-750 " and trade name " Sannix SP-750 " etc..
In hair mousse composition 100 mass % of the present invention, the content of mentioned component (B) is more than 3.0 mass %, excellent Elect more than more than 5.0 mass %, more preferably 8.0 mass % as, be below 35.0 mass %, be preferably 30.0 mass % with Under, below more preferably 23.0 mass %.When the content of mentioned component (B) is more than above-mentioned lower limit, the initial stage moulding hair style is whole Have an effect and the confining force of haircuting after moulding becomes more preferable, can give hair more preferable gloss further.Mentioned component (B) contains Amount is for when below the above-mentioned upper limit, and ductility and amalgamation when tacky inhibition, coating become more preferable.Mentioned component (B) Content be the present invention hair mousse composition in the total amount of content of whole compositions (B).
In the hair mousse composition of the present invention, the mass ratio of the content of the content of mentioned component (A) and mentioned component (B) (content of mentioned component (A): the content of mentioned component (B)) is preferably 1:0.1～1:30, more preferably 1:1～1:20, enters one Step is preferably 1:3～1:20.When the content of mentioned component (A) is relatively many, moulds initial stage of hair style and haircut power and tacky pressing down Effect processed becomes more preferable.When the content of mentioned component (B) is relatively many, the gloss of haircut confining force and hair after moulding becomes More preferably.
(composition (C))
Mentioned component (C) is for using DAAM as acrylic copolymer obtained from necessary monomer component Thing.Mentioned component (C) together can use other monomers beyond DAAM further with DAAM Composition is used as monomer component and obtains.Other monomer component conducts, can enumerate selected from by (methyl) acryllic acid and (first Base) acrylic acid acid esters composition group in monomer (at least one monomer) etc..Mentioned component (C) mainly has to effectively improve to be moulded The initial stage of hair style haircuts the effect of power.Particularly, with mentioned component (A) and mentioned component (B) mentioned component used along (C) When, go far towards to make it erect while arranging hair and keep the state of erected hair.Mentioned component (C) a kind can only be used, it is possible to use two or more.
Monomer component for obtaining mentioned component (C) includes at least DAAM.For obtaining mentioned component (C) monomer component preferably further comprises in the group being made up of (methyl) acryllic acid and (methyl) acrylic acid acid esters Monomer (at least one monomer).That is, mentioned component (C) is the copolymerization including at least the construction unit from DAAM Thing.Mentioned component (C) preferably further comprises selected from by the construction unit from (methyl) acryllic acid with from (methyl) third Construction unit in the group of the construction unit composition of olefin(e) acid acid esters.
As the concrete example of mentioned component (C), for example, can enumerate with INCI name (international cosmetic raw material dictionary and handbook (International Cosmetic Ingredient Dictionary and Handbook), the 15th edition, volume 1,2014 Year, page 66): acrylic acid (ester) class/diacetone acrylamide that ACRYLATES/DIACETONEACRYLAMIDE COPOLYMER represents Amide copolymer etc..
Acrylic acid series copolymer as above-mentioned (C) composition can be sodium salt, ammonium salt, triethanolamine salt, 2-amino-2-first Base-1-propylate or 2-amino-2-methyl-1,3-propane diols salt etc..
As the concrete example of copolymer of the form of the salt suitable with mentioned component (C), for example, can enumerate as 2-ammonia Base-2-methyl isophthalic acid-propylate with INCI name (international cosmetic raw material dictionary and handbook, the 15th edition, volume 1,2014,212 Page): acrylic acid (ester) class/diacetone acrylamide that AMP-ACRYLATES/DIACETONEACRYLAMIDE COPOLYMER represents Acid amides AMP salt (acrylic acid (ester) class/biacetone acrylamide copolymer AMP salt)；As 2-amino-2-methyl-1,3-the third two Alkoxide with INCI name (international cosmetic raw material dictionary and handbook, the 15th edition, volume 1,2014, page 214): AMPD- Acrylic acid (ester) class/biacetone acrylamide copolymer that ACRYLATES/DIACETONEACRYLAMIDECOPOLYMER represents AMPD salt etc..
As the commercially available product of mentioned component (C), for example, can enumerate as acrylic acid (ester) class/DAAM common The trade name " Plascize L-53 " that the mutual induction chemical industry society of polymers manufactures；As acrylic acid (ester) class/diacetone acrylamide acyl The trade name that the mutual induction chemical industry society of amine AMP salt (acrylic acid (ester) class/biacetone acrylamide copolymer AMP salt) manufactures “Plascize L-3200B”、“Plascize L-6010”、“Plascize L-6330”、“Plascize L-7400B”、 “Plascize L-9400B”、“Plascize L-9909”；As acrylic acid (ester) class/biacetone acrylamide copolymer Trade name " Plascize L-1260 " that the mutual induction chemical industry society of AMPD salt manufactures, " Plascize L-53D " etc..
In hair mousse composition 100 mass % of the present invention, the content of mentioned component (C) be more than 0.10 mass %, Be preferably more than 0.30 mass %, more than more preferably 0.40 mass %, be below 3.0 mass %, be preferably 2.0 mass % with Under, below more preferably 1.8 mass %.When the content of mentioned component (C) is more than above-mentioned lower limit, the initial stage moulding hair style haircuts Power becomes more preferable.Content by mentioned component (C) is below the above-mentioned upper limit, then haircuting property becomes more preferable, prevents the effect peeled off Really, washing away property improves further.The content of mentioned component (C) is the whole compositions (C) in the hair mousse composition of the present invention The total amount of content.
In the hair mousse composition of the present invention, the mass ratio of the content of the content of mentioned component (B) and mentioned component (C) (content of mentioned component (B): the content of mentioned component (C)) is preferably 5:1～70:1, more preferably 6:1～60:1.Above-mentioned one-tenth When dividing the content of (B) relatively many, the confining force of haircuting after moulding, the gloss change preventing the effect peeled off, washing away property and hair Obtain more preferably.When the content of mentioned component (C) is relatively many, moulds initial stage of hair style and haircut power and suppress tacky effect to become more Good.
(composition (D))
Mentioned component (D) is at least one chemical combination in the group being made up of mentioned component (D1) and mentioned component (D2) Thing.By using mentioned component (D), can suppress further to peel off, and the washing away property after haircuting can be improved, and permissible Maintain mould initial stage of hair style haircut power while give good feel to the hair after haircuting.Mentioned component (D) is permissible Only use a kind, it is possible to use two or more.It should be noted that mentioned component (D1), mentioned component (D2) are also permissible respectively Only use a kind, can also be used two or more.
As mentioned component (D), can only use in mentioned component (D1) and mentioned component (D2) any one, it is possible to To share mentioned component (D1) and mentioned component (D2).
Mentioned component (D1) is polyoxyalkylene alkyl glucoside.As the oxyalkylene alkyl in mentioned component (D1), permissible Enumerate oxyethylene group and oxypropylene group etc..The average addition molal quantity of the oxyalkylene alkyl in mentioned component (D1) is not had It is particularly limited to, preferably more than 5, preferably less than 40.The carbon number of the alkyl in mentioned component (D1) is preferably 1～4, more It is preferably 1～3.Alkyl in mentioned component (D1) is preferably methyl or ethyl.
It as mentioned component (D1), is not particularly limited, Glucam E-10, polyoxyethylene ethyl can be enumerated Glucoside, PP 25 and polyoxypropylene ethyl cyclophosphadenosine glycoside etc..
From maintain higher mould initial stage of hair style haircut power while give more preferable feel to the hair after haircuting From the aspect of, mentioned component (D1) preferably comprises polyoxyalkylene methyl glucosamine, preferably comprises PP 25.
Mentioned component (D2) is polyoxyalkylene fatty acid glyceride.The carbon number of the aliphatic acid in mentioned component (D2) is excellent Elect more than 8 as, be preferably less than 22.As the oxyalkylene alkyl in mentioned component (D2), oxyethylene group and oxygen can be enumerated Change acrylic etc..The average addition molal quantity of the oxyalkylene alkyl in mentioned component (D2) is preferably more than 5, be preferably 40 with Under.
From maintain mould initial stage of hair style haircut power while the hair after haircuting given more preferable feel in terms of Considering, the aliphatic acid in mentioned component (D2) is preferably branched chain fatty acid, and mentioned component (D2) is preferably polyoxyalkylene glycerine and props up Chain fatty acid ester.
From maintain higher mould initial stage of hair style haircut power while give more preferable feel to the hair after haircuting From the aspect of, the carbon number of the branched chain fatty acid in above-mentioned polyoxyalkylene glycerine side chain fatty acid ester is preferably more than 8, excellent Elect less than 22 as.As the branched chain fatty acid in above-mentioned polyoxyalkylene glycerine side chain fatty acid ester, can enumerate 2 ethyl hexanoic acid, Different n-nonanoic acid, different palmitic acid and isostearic acid etc..
As above-mentioned polyoxyalkylene glycerine side chain fatty acid ester, particularly preferred isostearic acid polyoxyethylene glyceride.
As the commercially available product of mentioned component (D1), for example, can enumerate the trade name " MACBIOBRIDE that You society manufactures MG-10P”；The trade name " GLUCAM E-10 " of Noveon society manufacture and trade name " GLUCAM E-20 "；Amerchol society manufactures Trade name " GLUCAM P-10 " etc..
As the commercially available product of mentioned component (D2), for example, can enumerate the trade name that the first industrial pharmaceutical society manufactures “Noigen GIS-125”；Trade name " EMALEX GWIS-115 " that NIHON EMULSION society manufactures, trade name " EMALEX GWIS-120 ", trade name " EMALEX GWIS-125 " and trade name " EMALEXGWIS-130 " etc..
In hair mousse composition 100 mass % of the present invention, the content of mentioned component (D) be preferably 0.5 mass % with Above, it more than more preferably 1.0 mass %, is preferably below below 20.0 mass %, more preferably 10.0 mass %.Mentioned component (D) when content is more than above-mentioned lower limit, can suppress further to peel off, and the washing away property after haircuting becomes more preferable, and can To give more preferable feel to the hair after haircuting.When the content of mentioned component (D) is below the above-mentioned upper limit, tacky by further Mitigate.The content of mentioned component (D) is the total amount of the content of the whole compositions (D) in the hair mousse composition of the present invention.
In above-mentioned hair mousse composition, the content of mentioned component (A) is (above-mentioned with the mass ratio of the content of mentioned component (D) The content of composition (A): the content of mentioned component (D)) it is preferably 1:0.2～1:20, more preferably 1:1～1:10.If above-mentioned one-tenth The content of point (D) is relatively many, then hair feel, peel off inhibition, washing away property becomes more preferable.
(composition (E))
Mentioned component (E) is clay mineral.By using mentioned component (E), mould initial stage of hair style and haircut power and haircuting The storage stability of agent composition becomes more preferable.Mentioned component (E) can only use a kind, it is possible to use two or more.
Mentioned component (E) can be natural goods or synthetic.It as mentioned component (E), is not particularly limited, For example can enumerate kaolin group's clay mineral, antigorite race clay mineral, pyrophyllite race clay mineral, Mica Group clay pit Thing, smectite clay mineral, vermiculite race clay mineral, chlorite race clay mineral and organo-clay mineral etc..
As above-mentioned kaolin group clay mineral, kaolin, nacrite, dickite and halloysite etc. can be enumerated.Make For above-mentioned antigorite race clay mineral, antigorite, pictoamesite and cronstedtite etc. can be enumerated.As above-mentioned pyrophyllite race Clay mineral, can enumerate pyrophyllite and talcum (talcum) etc..As above-mentioned Mica Group clay mineral, can enumerate illite, Glauconite, seladonit, sericite, mica (mica), muscovite, fuchsite and biotite etc..Glue as above-mentioned smectite race Soil mineral, can enumerate bentonite, montmorillonite, beidellite, nontronite, saponite, hectorite (Hectorite) and synthesis lithium and cover De-stone (Lucentite) etc..As above-mentioned vermiculite race clay mineral, vermiculite etc. can be enumerated.As above-mentioned chlorite race clay Mineral, can enumerate chlorite (chlorite) etc..As above-mentioned organo-clay mineral, smectite clay can be enumerated Mineral or vermiculite race clay mineral etc. have carried out the organo-clay mineral etc. of organically-modified process.Organically-modified process is fitted Preferably use quaternary ammonium salt cationic surfactant.As above-mentioned quaternary ammonium salt cationic surfactant, can enumerate above-mentioned Alkyl trimethyl ammonium chloride, dialkyl dimethyl ammonium chloride and benzalkonium chloride etc..
From the aspect of improving storage stability and use feeling further, mentioned component (E) is preferably selected from by synthesizing Clay mineral in the group of silicate and derivative composition thereof.Above-mentioned synthetic silicate and derivative thereof are not with containing much The silicate mineral that the magnesium silicate of the natural origin of impurity or silicic acid (sodium/magnesium) etc. are main component, but obtained by synthesis Silicate and silicate derivative.
As above-mentioned synthetic silicate and derivative thereof, for example, can enumerate with INCI name (international cosmetic raw material dictionary And handbook, the 14th edition, volume 2,2012, page 3076): SODIUM MAGNESIUM SILICATE (sodium magnesium silicate) represents Synthetic silicic acid (sodium/magnesium), with INCI name (international cosmetic raw material dictionary and handbook, the 14th edition, volume 2,2012,1793 Page): magnesium fluosilicate that MAGNESIUM FLUOROSILICATE (magnesium fluosilicate) represents, with INCI name (international cosmetic raw material Dictionary and handbook, the 14th edition, volume 2,2012, page 3076): SODIUMMAGNESIUM FLUOROSILICATE (fluosilicic acid Magnesium sodium) represent fluosilicic acid (sodium/magnesium), with INCI name (international cosmetic raw material dictionary and handbook, the 14th edition, volume 2,2012 Year, page 1799): fluosilicic acid (magnesium/potassium) that MAGNESIUMPOTASSIUM FLUOROSILICATE (potassium fluosilicate magnesium) represents, With INCI name (international cosmetic raw material dictionary and handbook, the 14th edition, volume 2,2012, page 1800): MAGNESIUM Fluosilicic acid (magnesium/sodium) that SODIUMFLUOROSILICATE (prodan magnesium) represents, with INCI name (international cosmetic raw material word Allusion quotation and handbook, the 14th edition, volume 1,2012, page 156): the synthetic aluminium silicate that ALUMINUM SILICATE (alumina silicate) represents Deng.
As mentioned component (E), in clay mineral, particularly preferably selected from by synthetic silicic acid (sodium/magnesium), fluosilicic acid (sodium/ Magnesium) and the group that forms of fluosilicic acid (sodium/magnesium) in clay mineral (at least one clay mineral).
As the commercially available product of mentioned component (E), for example, can enumerate the trade name " LAPONITE that Rockwood society manufactures XLG " and trade name " LAPONITE XL21 " etc..
In hair mousse composition 100 mass % of the present invention, the content of mentioned component (E) be preferably 0.10 mass % with Above, it is more preferably more than more than 0.30 mass %, more preferably 0.50 mass %, below preferably 10.0 mass %, more It is preferably below below 5.0 mass %, more preferably 3.0 mass %.The content of mentioned component (E) is more than above-mentioned lower limit When, storage stability and haircuting property become more preferable.When the content of mentioned component (E) is below the above-mentioned upper limit, hair mousse composition Storage stability become more preferable.
(composition (F))
Mentioned component (F) is polysaccharide based compound.By using mentioned component (F), the appropriateness thickening of hair mousse composition, because of The dispersiveness of this mentioned component (A) becomes more preferable, and then hair mousse composition becomes to be difficult to separate, and storage stability becomes more Good.Mentioned component (F) can only use a kind, it is possible to use two or more.
It as mentioned component (F), is not particularly limited, preferred polysaccharide, modification of polysaccharides (such as alkyl-modified polysaccharide etc.) etc., For example can enumerate alginic acid, carragheen, agar, furcellaran, guar gum, seed, konjac glucomannan, tamarind gum, tower Draw glue, dextrin, starch, locust bean gum, Arabic gum, ghatti gum, Karaya Gum, bassora gum, arabogalactan, pectin With the polysaccharide based compound waiting plant origin；The polysaccharide based compound of the animal origin such as shitosan and hyaluronic acid；Can obtain The microbe-derived polysaccharide system chemical combination such as right glue, xanthans, gellan gum, cyclodextrin, dextran, amylopectin and hyaluronic acid Thing；Microcrystalline cellulose, methylcellulose, ethyl cellulose, hydroxymethyl cellulose, hydroxyethyl cellulose, hydroxypropyl cellulose and The non-ionic cellulose elements such as hydroxypropyl methyl cellulose；The anionic cellulose elements such as carboxymethylcellulose calcium；Chlorination O-[2-hydroxyl- 3-(trimethyl ammonium) propyl group] cationized cellulose such as hydroxyethyl cellulose；Chlorination O-[2-hydroxyl-3-(trimethyl ammonium) Propyl group] the cationized guar glue etc. such as guar gum.
As mentioned component (F), in polysaccharide based compound, be preferably selected from by xanthans, guar gum, tamarind gum and Compound (at least one compound) in the group of gellan gum composition.
As the commercially available product of mentioned component (F), for example, can enumerate the big SUMITOMO CHEMICAL pharmacy society as xanthans and manufacture Trade name " ECHO GUM T ", trade name " ケ Le デ Application ト " and trade name " モ Na ト ガ system "；As she of guar gum The trade name " Inagel guar gum CS " that food industry society manufactures；DSPGOKYO FOOD& as tamarind gum The trade name " GLYLOID 6C " that CHEMICAL Co., Ltd. manufacture；As the CP Kelco U.S. of gellan gum, Inc. manufactures Trade name " Kelcogel " etc..
In hair mousse composition 100 mass % of the present invention, the content of mentioned component (F) be preferably 0.01 mass % with Above, more than more preferably 0.10 mass %, below preferably 5.0 mass %, below more preferably 2.0 mass %.Mentioned component (F), when content is more than above-mentioned lower limit, the storage stability of hair mousse composition becomes more preferable.The content of mentioned component (F) It for when below the above-mentioned upper limit, tacky is suppressed more.The content of mentioned component (F) is in the hair mousse composition of the present invention The total amount of the content of whole compositions (F).
From the side making the appropriateness thickening further of hair mousse composition, the further storage stability of raising hair mousse composition Face considers, the hair mousse composition of the present invention preferably comprises mentioned component (E) and mentioned component (F).By sharing mentioned component (E) with mentioned component (F), the dispersion stabilization of mentioned component (A) improves further, and the separation of hair mousse composition becomes increasingly difficult to To occur.Additionally, hair mousse composition demonstrates good thixotropy, therefore the coating of hair mousse composition improves.
In the case of sharing mentioned component (E) with mentioned component (F), the quality of mentioned component (E) and mentioned component (F) It is preferably 2:1～10:1, more preferably 2.5:1～8:1 than (content of mentioned component (E): the content of mentioned component (F)).If Meet above-mentioned mass ratio, then tacky be suppressed more, so hair mousse composition storage stability, particularly protect for a long time Storage stability when depositing becomes more preferable.
In the case of sharing mentioned component (E) with mentioned component (F), the content of mentioned component (E) and mentioned component (F) The total amount of content be preferably more than more than 0.30 mass %, more preferably 0.40 mass %, below preferably 5.0 mass %, Below more preferably 4.0 mass %.It if in the range of above-mentioned total amount, then tacky is suppressed more, and then hair mousse combination The storage stability when storage stability of thing, particularly for a long time preservation becomes more preferable.
(other compositions)
The hair mousse composition of the present invention is not particularly limited, preferably comprises water.Above-mentioned water is not particularly limited, permissible The preferred pure water such as water used in use cosmetic preparation etc..In hair mousse composition 100 mass % of the present invention, the content of water Be preferably more than 30 mass %, more than more preferably 40 mass %, below preferably 95 mass %, more preferably 90 mass % with Under.
In addition, the hair mousse composition of the present invention is not particularly limited, preferably comprise carbon number be 2～5 rudimentary Alcohol (particularly ethanol).In hair mousse composition 100 mass % of the present invention, the content of lower alcohol (particularly ethanol) is preferred It is more than more than 2.0 mass %, more preferably 5.0 mass %, below preferably 50.0 mass %, be more preferably 30.0 mass % Below.
For the hair mousse composition of the present invention, it is also possible to comprise for example in the range of not suppressing the effect of the present invention The surfactants such as nonionic surfactant, cationic surfactant and amphoteric surfactant；Glycerine, 1,3-fourth two The polyalcohols such as alcohol, propane diols, 1,2-butanediol, 1,2-pentanediol, 1,2-hexylene glycol, 1,2-ethohexadiol, Decane-1,2-diol；Bay The carbon numbers such as alcohol, myristyl alcohol, hexadecanol, stearyl alcohol, isooctadecanol, cetostearyl alcohol and oil enol are the height of 12～18 Level alcohol；The sugar alcohols such as D-sorbite, maltitol and trehalose；Silicone oil；Chelating agent；Antioxidant；Plant extracts；Pigment；Face Material；PH adjusting agent；Spices；Preservative；Solvent etc..
(other details of hair mousse composition)
The proterties of the hair mousse composition of the present invention is not particularly limited, can be aqueous, gel, paste and solid Any one in shape.Above-mentioned hair mousse composition is preferably aqueous or gel.In general, haircut aqueous or gelatinous If using particle in agent composition, then the mobility of hair mousse composition is high, therefore has the tendency that the dispersiveness of particle reduces. Its result, in above-mentioned aqueous or gelatinous hair mousse composition, has and moulds initial stage of hair style and haircut after power and moulding Confining force of haircuting is easily reduced, easily produces tendency that is tacky and that peel off.On the other hand, by using the hair mousse group of the present invention Above-mentioned composition in compound, even aqueous or gelatinous hair mousse composition, it is also possible to the generation and tacky that suppression is peeled off, And can improve and mould initial stage of hair style and haircut the confining force of haircuting after power and moulding.
The viscosity of 25 DEG C of above-mentioned hair mousse composition be preferably more than 1000mPa s, more preferably 2000mPa s with On, preferably below 100000mPa s, more preferably below 50000mPa s.Above-mentioned viscosity is more than above-mentioned lower limit and upper When stating below the upper limit, coating improves further, and then the generation peeled off and tacky be inhibited further, and moulds hair style The initial stage confining force of haircuting after power and moulding of haircuting improve further.In above-mentioned hair mousse composition, above-mentioned viscosity is above-mentioned Below the upper limit, even if mobility is high, it is also possible to the generation and tacky that suppression is peeled off, and can improve that to mould initial stage of hair style whole Have an effect and the confining force of haircuting after moulding.
Above-mentioned viscosity is to utilize viscosimeter, use No.4 rotor with rotary speed 12rpm, the rotational time condition of 1 minute Measured.As above-mentioned viscosimeter, it is possible to use the TV-22 type viscosimeter that Dong Ji industry society manufactures.
The manufacture method of the hair mousse composition of the present invention is not particularly limited, as the hair mousse composition of the present invention Manufacture method, it is possible to use the manufacture method of known hair mousse composition.System as the hair mousse composition of the present invention Make method, for example, can enumerate following method: composition (A) and water (also having composition (E) as required) are utilized dispersing mixer It after stirring, is replaced with arm mixer and stirs other compositions of mixture and homogenize.
In the case of the hair mousse composition of the present invention, the generation and tacky peeled off can be suppressed when haircuting, And can improve and mould initial stage of hair style and haircut the confining force of haircuting after power and moulding.
It should be noted that in this specification, above-mentioned " moulding hair style " is not particularly limited, and e.g. instigates hair to erect Etc. harder ground combing hair.
The hair mousse composition of the present invention is haircuted into as main with composition (C) including at least composition (A), composition (B) Point.For mentioned component (B), do up and keep the excellent effect of hair, even if through long situation after haircuting Under, it is also possible to suppression topknot scatters, the hair style of institute's moulding is destroyed.In addition, it is also excellent to restrain the effect peeled off.On the other hand, For composition (C), giving the excellent effect of hardness to hair, the power for example making hair erect is excellent.In addition, for composition (A), for, there is above-mentioned effect and the effect to hair imparting hardness doing up and keeping hair simultaneously, and there is suppression Glue, suppress factitious gloss and the effect that gives natural outward appearance.
Therefore, by sharing composition (A), composition (B) and composition (C), can be at the tacky and factitious gloss of suppression Improve simultaneously and mould initial stage of hair style and haircut power, and the confining force of haircuting after moulding can be improved.Especially it is possible to arrangement head Sending out makes it erect well, and can keep the hair that arranges and erect well.In addition, can press down when haircuting System peels off the generation of (seeming to be attached with on hair the phenomenon of white powder or overlay film).
Additionally, pass through compounding ingredients (D), the inhibition of power of haircuting and peeling improves further, so to haircuting after Hair give the effect of gloss and washing away property improves.
Additionally, pass through compounding ingredients (E) and composition (F), hair mousse composition is by appropriateness thickening, the painting of hair mousse composition Cloth improves.In addition, by making composition (E) be specific preferred scope with the mix ratio of composition (F), composition (A) becomes to be difficult to Sedimentation or gathering, the storage stability (stability during long-term preservation) of hair mousse composition improves.
The hair mousse composition of the present invention is not particularly limited, for example, can use with the form being filled in container.
As said vesse, bottle container, can container and tubular container etc. can be enumerated.Said vesse is preferably bottle container or pipe Container.
Embodiment
Below, enumerate embodiment and the present invention is specifically described by comparative example.The present invention is not limited only to following reality Execute example.
Employ following compositions in embodiment and comparative example.
(composition (A))
Trade name " Sylysia 320 ": silica (Fuji Silysia Chemical society manufacture)
Trade name " AEROSIL 200 ": silica (NIPPON AEROSIL society manufacture)
Trade name " spherical HAP ": hydroxyapatite (peaceful Chemical Industries society manufactures)
Trade name " FLORITE R ": calcium silicates (Fu Tian pharmacy society manufacture)
Trade name " synthetic aluminium silicate (heavy) ": alumina silicate (Fu Tian pharmacy society manufacture)
Trade name " magnesium hydroxide (heavy) ": magnesium hydroxide (Fu Tian pharmacy society manufacture)
(composition (B))
Trade name " Newpol 75H-90000 ": polyoxyethylene polyoxypropylene hexylene glycol ether, Sanyo chemical conversion industry society manufacture, Number-average molecular weight the 14000th, liquid
Trade name " Newpol SP-750 ": polyoxypropylene D-sorbite, the manufacture of chemical conversion industry society of Sanyo, number-average molecular weight 690th, liquid
(the polyoxyethylene/polyoxypropylene copolymer (composition (B ')) beyond composition (B)
Trade name " Newpol 50HB-55 ": polyoxyethylene polyoxypropylene butyl ether, chemical conversion industry society of Sanyo manufacture, count and divide equally Son amount the 300th, liquid
(composition (C))
Trade name " Plascize L-6330 ", purity 30 mass %, mutual induction chemical industry society manufacture
Trade name " Plascize L-53 ", purity 50 mass %, mutual induction chemical industry society manufacture
Trade name " Plascize L-53D ", purity 50 mass %, mutual induction chemical industry society manufacture
(composition (D))
Trade name " Noigen GIS-125 ": isostearic acid polyoxyethylene glyceride, the first industrial pharmaceutical society manufacture
Trade name " MACBIOBRIDE MG-10P ": PP 25, You society manufacture
(composition (E))
Trade name " LAPONITE XL21 ": fluosilicic acid (sodium/magnesium), Rockwood society manufacture
Trade name " LAPONITE XLG ": synthetic silicic acid (sodium/magnesium), Rockwood society manufacture
(composition (F))
Trade name " ECHO GUM T ": xanthans, big SUMITOMO CHEMICAL pharmacy society manufacture
(other)
Ethanol
2-amino-2-methyl-1-propanol
Pure water
(embodiment 1～17 and comparative example 1～5)
Mixture table 1 below, the compounding ingredients (mixture unit is quality %) shown in 2, prepare hair mousse composition.Embodiment The proterties of the hair mousse composition obtaining in 1～17 is gel.It should be noted that the blend amount in table is by with purity meter Blend amount represent.
Fill obtained hair mousse composition to plastic container, obtain hair mousse.
(test example 1: tacky evaluation)
20 specialty judging panel above-mentioned hair mousse composition is applied to equably bob wig (exercise manikin: YUKARI Japan society manufactures) hair on, upwards make hair erect to implement to haircut from the root of hair of hair, contact afterwards erects Hair, answer have or not tacky.According to above-mentioned answer, evaluate to tacky according to following benchmark.
<tacky metewand>
Zero (fairly good): answer without tacky for more than 16 in 20
△ (well): answer without tacky for 10～15 in 20
× (bad): answer without tacky for less than 9 in 20
(test example 2: initial stage haircut the evaluation of power (erecting power))
20 specialty judging panel above-mentioned hair mousse composition is applied to equably bob wig (exercise manikin: YUKARI Japan society manufactures) hair on, upwards make hair erect to implement to haircut from the root of hair of hair, answer afterwards and have or not Initial stage haircuts power.During it should be noted that the shape of the hair being arranged substantially is kept, it is determined that haircut power for having the initial stage. According to above-mentioned answer, according to following benchmark, the initial stage power of haircuting is evaluated.
The metewand of power<initial stage haircut>
Zero (fairly good): answer and have the initial stage to haircut power for more than 16 in 20
△ (well): 10～15 answers in 20 have the initial stage to haircut power
× (bad): answer and have the initial stage to haircut power for less than 9 in 20
(test example 3: the evaluation of confining force of haircuting)
20 specialty judging panels haircuted to implementing after above-mentioned test example 2 evaluation of power (initial stage haircut) after 6 hours The hair of wig observe, answer and have or not the confining force of haircuting after erecting.It should be noted that the carrying out of test example 2 In the case that hair shape after haircuting persistently is kept, it is determined that for having confining force of haircuting.According to above-mentioned answer, according to following Confining force of haircuting is evaluated by benchmark.
<metewand of confining force of haircuting>
Zero (fairly good): more than 16 answers in 20 have confining force of haircuting
△ (well): 10～15 answers in 20 have confining force of haircuting
× (bad): less than 9 answers in 20 have confining force of haircuting
(test example 4: the evaluation of peeling)
20 specialty judging panel after above-mentioned test example 3 (evaluation of confining force of haircuting) with finger tip by the hair of wig from hair Continuous 5 combing of root to send out a tip, answer have or not peeling.It should be noted that seem to be attached with on hair the feelings of white powder Under condition, it is determined that for there being peeling.According to above-mentioned answer, according to following benchmark, peeling is evaluated.
<metewand of peeling>
Zero (fairly good): answer without peeling off for more than 16 in 20
△ (well): answer without peeling off for 10～15 in 20
× (bad): answer without peeling off for less than 9 in 20
(test example 5: the evaluation of washing away property)
20 specialty judging panels use shampoo (trade name afterwards above-mentioned test example 4 (evaluation of peeling) " LUCIDOshampoo ", Man Dan society manufacture) with warm water clean wig hair, be dried afterwards, answer washing away property whether good Good.It in the case of it should be noted that hair during hair washing is without rough sense and sticky feeling, is evaluated as washing away property good.According to above-mentioned Answer, according to following benchmark, washing away property is evaluated.
<metewand of washing away property>
Zero (fairly good): in 20, more than 16 washing away property of answer are good
△ (well): in 20,10～15 washing away property of answer are good
× (bad): in 20, less than 9 washing away property of answer are good
(test example 6: the evaluation of gloss)
The hair that 20 specialty judging panels answer wig after above-mentioned test example 2 evaluation of power (initial stage haircut) has unglazed Pool.According to above-mentioned answer, according to following benchmark, gloss is evaluated.
<metewand of the gloss of hair>
Zero (fairly good): answer glossy for more than 16 in 20
△ (well): in 20,10～15 answers are glossy
× (bad): answer glossy for less than 9 in 20
(test example 7: the evaluation of storage stability)
Fill each hair mousse composition immediately after preparation to clear glass container, preserve in the thermostat of 40 DEG C 4 week.The outward appearance and proterties of each hair mousse composition after preservation is observed, is evaluated according to following benchmark.
<metewand of storage stability (appearance character)>
Zero (quite good): the rising of the dehydration to composition unconfirmed and viscosity
△ (well): slightly confirm the dehydration of composition or the rising of viscosity
× (bad): clearly confirm the dehydration of composition or the rising of viscosity
Show the result in following table the 1st, 2.Table the 1st, 2 each embodiment and each comparative example in the adding up to of compounding ingredients 100 mass %.
[table 1]
[table 2]

Claims (5)

1. a hair mousse composition, it comprises following compositions A, following compositions B and following compositions C,
The content of described composition A is below more than 0.05 mass % 7.0 mass %,
The content of described composition B is below more than 3.0 mass % 35.0 mass %,
The content of described composition C is below more than 0.10 mass % 3.0 mass %,
Composition A: selected from by silica, calcium carbonate, magnesium carbonate, hydroxyapatite, titanium dioxide, zinc oxide, calcium silicates, silicic acid Particle in the group of magnesium, alumina silicate and magnesium hydroxide composition,
Composition B: selected from by the polyoxyethylene/polyoxypropylene random copolymer that number-average molecular weight is less than more than 10,000 20000, With the compound in the group of polyoxypropylene D-sorbite that number-average molecular weight is less than more than 300 1000 composition,
Composition C: use DAAM as acrylic acid series copolymer obtained from necessary monomer component.
2. hair mousse composition as claimed in claim 1, it comprises following compositions D further,
Components D: the compound in the group being made up of polyoxyalkylene alkyl glucoside and polyoxyalkylene fatty acid glyceride.
3. hair mousse composition as claimed in claim 1 or 2, it comprises following compositions E further,
Composition E: clay mineral.
4. the hair mousse composition as according to any one of claims 1 to 3, it comprises following compositions F further,
Composition F: polysaccharide based compound.
5. hair mousse composition as claimed in claim 3, it comprises following compositions F further,
The content of described composition E is 2:1～10:1 with the mass ratio of the content of described composition F,
Composition F: polysaccharide based compound.
CN201580012525.XA 2014-05-16 2015-03-12 Hair styling agent composition Expired - Fee Related CN106102695B (en)

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CN110167520A (en) * 2017-04-27 2019-08-23 株式会社漫丹 Hair styling agent composition
CN110831572A (en) * 2017-09-26 2020-02-21 株式会社漫丹 Composition for hair treatment and spray cosmetic for hair treatment
CN110913835A (en) * 2018-02-09 2020-03-24 株式会社漫丹 Hair styling composition

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