CN110913835A - Hair styling composition - Google Patents
Hair styling composition Download PDFInfo
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- CN110913835A CN110913835A CN201880046947.2A CN201880046947A CN110913835A CN 110913835 A CN110913835 A CN 110913835A CN 201880046947 A CN201880046947 A CN 201880046947A CN 110913835 A CN110913835 A CN 110913835A
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- component
- hair styling
- curl
- styling composition
- composition
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring
Abstract
The invention provides a hair styling agent composition which is excellent in the degree of easy-to-push-off during coating, the reproducibility of curling and the retention of curling. The hair styling composition contains component (a): an oil agent which is liquid at 25 ℃, component (B): xanthan gum, component (C): acrylic thickener and component (D): a cationic film-forming polymer. Component (D) is preferably polyquaternium-11. The hair styling composition preferably contains component (E): polyoxypropylene sorbitol. The component (C) is preferably a carboxyvinyl polymer and/or an alkyl-modified carboxyvinyl polymer.
Description
Technical Field
The present invention relates to a hair styling agent composition for a hair styling agent for hair styling.
Background
Hair styling compositions in various forms such as liquid, gel, cream, and solid are known for hair styling. Conventionally, in hair styling compositions, in order to exert hair styling power as a main function thereof, a film-forming polymer, a wax which is solid at room temperature, an oil or fat, and a hydrocarbon oil have been often used (for example, patent documents 1 and 2).
For example, in particular, among women, there are cases where it is desired to apply a hairstyle in which a permanent wave is formed by a chemical reaction to hair. A hair styling agent composition used for such a hairstyle is required to have excellent properties of reproducing a curl formed after a permanent wave is applied (curl reproducibility) and excellent properties of retaining the reproduced curl (curl retention).
As a hair styling composition for styling hair after permanent waving, for example, a cream-like hair cosmetic containing a carboxyvinyl polymer and vinylpyrrolidone/N, N-dimethylaminoethylmethacrylate copolymer diethyl ester sulfate is known (for example, patent document 3).
Documents of the prior art
Patent document
Patent document 1: japanese laid-open patent publication No. 11-171740
Patent document 2: japanese laid-open patent publication No. 10-45546
Patent document 3: japanese laid-open patent publication No. 2002-
Disclosure of Invention
Problems to be solved by the invention
However, the conventional hair styling compositions are unsatisfactory in curl reproducibility and curl retention. In addition, in order to improve the applicability of the hair styling composition to long hair, the degree of easy pushing-off when applying the composition to hair is sometimes required.
Accordingly, an object of the present invention is to provide a hair styling agent composition which is excellent in the degree of easy-to-push-off at the time of application, curl reproducibility, and curl retention.
Means for solving the problems
As a result of intensive studies to achieve the above object, the inventors of the present invention have found that a composition containing the component (a): an oil agent which is liquid at 25 ℃, component (B): xanthan gum, component (C): acrylic thickener and component (D): a hair styling agent composition containing a cationic film-forming polymer, which is excellent in the degree of easiness in pushing off at the time of application, curl reproducibility, and curl retention. The present invention has been completed based on the above findings.
Namely, the present invention provides a hair styling agent composition comprising the following component (a), the following component (B), the following component (C), and the following component (D).
Component (A): oil agent being liquid at 25 DEG C
Component (B): xanthan gum
Component (C): acrylic acid thickening agent
Component (D): cationic film-forming polymer
The component (D) is preferably polyquaternium-11.
The hair styling composition preferably contains the following component (E).
Component (E): polyoxypropylene sorbitol
The component (C) is preferably a carboxyvinyl polymer and/or an alkyl-modified carboxyvinyl polymer.
Effects of the invention
The hair styling agent composition of the present invention is excellent in the degree of easy-open property, curl reproducibility and curl retention property at the time of application.
Detailed Description
The hair styling agent composition of the present invention contains at least an oil agent which is liquid at 25 ℃, xanthan gum, an acrylic thickener, and a cationic film-forming polymer. In the present specification, the oil agent that is liquid at 25 ℃ may be referred to as "component (a)". Further, xanthan gum is sometimes referred to as "component (B)". The acrylic thickener may be referred to as "component (C)". The cationic film-forming polymer may be referred to as "component (D)".
That is, the hair styling composition of the present invention contains at least component (a), component (B), component (C), and component (D). The hair styling composition of the present invention may contain components other than the above components (a) to (D). The hair styling composition of the present invention may contain only one or two or more of each component, for example, components (a), (B), (C), (D), and components other than components (a) to (D).
[ component (A) ]
The component (A) is an oil agent which is liquid at 25 ℃. The hair styling composition of the present invention contains the component (a), and therefore, the hair styling composition is excellent in the degree of easy pushing-off when applied to hair (during hair styling), and the hair feel is good. The component (A) may be used alone or in combination of two or more.
The "liquid at 25 ℃" is not particularly limited, and is preferably, for example, as follows: a glass bottle having a radius of 2cm and a height of 7cm was filled with 50g of a sample (oil solution), and when the glass bottle was inverted at a temperature of 25 ℃ and 5 minutes passed from the inversion, the sample dropped from the glass bottle.
The viscosity η of the component (A) measured at 25 ℃ with a Brookfield rotational viscometer is preferably 10 to 5000 mPas, more preferably 20 to 3000 mPas, and when the viscosity is 10 mPas or more, the hair setting agent can be prevented from dropping from the hands during application, and when the viscosity is 5000 mPas or less, the degree of easy-to-open property during application is more excellent.
The component (a) is not particularly limited, and examples thereof include fats and oils, hydrocarbon oils, fatty acids, higher alcohols, ester oils, and silicone oils. Among these, ester oils and silicone oils are preferable, and silicone oils are more preferable, from the viewpoint of further improving the degree of stickiness, smoothness, and the feeling after coating. The component (a) does not contain a component corresponding to the component (E) described later.
Examples of the oils and fats include avocado oil, argan oil, olive oil, rice bran oil, soybean oil, corn oil, palm kernel oil, palm oil, castor oil, grape seed oil, macadamia nut oil, meadowfoam seed oil, sunflower seed oil, and the like.
Examples of the hydrocarbon oil include α -olefin oligomer, light isoparaffin, light liquid isoparaffin, synthetic squalane, vegetable squalane, liquid isoparaffin, and liquid paraffin.
Examples of the higher alcohol include saturated or unsaturated straight chain monohydric alcohols having 6 to 20 carbon atoms, such as lauryl alcohol and oleyl alcohol; saturated or unsaturated branched monohydric alcohols having 6 to 26 carbon atoms such as isostearyl alcohol, hexyldecanol, octyldodecanol, decyltetradecanol, and the like.
Examples of the ester oil include ethyl oleate, isopropyl myristate, isopropyl palmitate, myristyl myristate, cetyl palmitate, oleyl oleate, octyldodecyl myristate, octyldodecyl oleate, ethyl isostearate, isopropyl isostearate, propylene glycol isostearate, cetyl 2-ethylhexanoate, cetyl stearate 2-ethylhexanoate, glyceryl tri-2-ethylhexanoate, glyceryl tri (caprylic/capric) ester, glyceryl tri-isopalmitate, pentaerythritol tetra (2-ethylacetate), diisopropyl adipate, isocetyl octanoate, isocetyl isostearate, octyldodecyl dimethyloctanoate, isononyl isononanoate, isopropyl myristate, isopropyl stearate, isopropyl palmitate, isopropyl, Pentaerythritol tetracaprylate, pentaerythritol tetraisostearate, and the like.
Examples of the silicone oil include linear silicone oils such as methyl polysiloxane, highly polymerized methyl polysiloxane, methylphenyl polysiloxane, and methylhydrogen polysiloxane; cyclic silicone oils such as octamethyltrisiloxane, decamethyltetrasiloxane, octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, dodecamethylcyclohexasiloxane, and methylcyclopolysiloxane; modified silicone oils such as alcohol-modified silicone, alkyl-modified silicone, amino-modified silicone, and epoxy-modified silicone.
The content of the component (a) in the hair styling composition of the present invention is not particularly limited, and is preferably 0.5 to 20.0% by mass, more preferably 2.0 to 10.0% by mass, and still more preferably 2.0 to 7.0% by mass, based on 100% by mass of the hair styling composition of the present invention. When the content of the component (a) is 0.5% by mass or more, the degree of easy pushing-off during hair styling is more excellent. When the content of the component (a) is 20.0% by mass or less, the hair styling composition of the present invention is further excellent in stability, curl retention property, and curl strength. The content of the component (a) is the total content of all the components (a) in the hair styling composition of the present invention.
[ component (B) ]
The component (B) is xanthan gum. The hair styling composition of the present invention further contains component (B) in addition to component (C), and therefore, the hair styling composition has excellent stability. In addition, the hair dressing composition is excellent in the degree of easy-open property, curl reproducibility, curl strength and curl retention property. The component (B) may be used alone or in combination of two or more.
The content of the component (B) in the hair styling composition of the present invention is not particularly limited, and is preferably 0.01 to 1.0% by mass, more preferably 0.02 to 0.5% by mass, and still more preferably 0.02 to 0.2% by mass, based on 100% by mass of the hair styling composition of the present invention. When the content of the component (B) is 0.01% by mass or more, the hair styling composition is more excellent in stability, ease of pushing-off during hair styling, curl reproducibility, curl strength, and curl retention. When the content of the component (B) is 1.0% by mass or less, the stability of the hair styling agent composition and the degree of easy pushing-off during hair styling are further excellent. In addition, stickiness is further suppressed. The content of the component (B) is the total content of all the components (B) in the hair styling composition of the present invention.
[ component (C) ]
The component (C) is an acrylic thickener. The hair styling composition of the present invention contains the component (C), and therefore, the hair styling composition has excellent stability. The component (C) may be used alone or in combination of two or more.
The component (C) is not particularly limited, and is a copolymer and a crosslinked polymer containing a (meth) acrylic acid monomer and/or an alkyl (meth) acrylate monomer as an essential constituent component. Specific examples thereof include carboxyvinyl polymers; an alkyl (meth) acrylate copolymer; acrylic acid/alkyl methacrylate copolymers; alkyl (meth) acrylate/(meth) acrylate alkyl ether (meth) acrylate copolymers such as acrylate/polyoxyethylene (20) cetyl ether methacrylate copolymers, acrylate/polyoxyethylene (20) stearyl ether methacrylate copolymers, and acrylate/polyoxyethylene (25) behenyl ether methacrylate copolymers; alkyl (meth) acrylate/polyoxyethylene alkyl itaconate ether copolymers such as acrylate/polyoxyethylene (20) cetyl itaconate ether copolymers and acrylate/polyoxyethylene (20) stearyl itaconate ether copolymers; alkyl (meth) acrylate/(meth) acrylate polyoxyethylene alkyl ether crosspolymers such as acrylate/polyoxyethylene (20) stearyl ether crosspolymers and acrylate/polyoxyethylene (25) behenyl ether crosspolymers; acrylic/vinyl neodecanoate crosslinked polymers; (ammonium acryloyl dimethyl taurate/VP) copolymer; (N-vinylpyrrolidone-N, N-dimethylaminoethylmethacrylate) crosslinked polymer (polyacrylate-1), and the like. In addition, the numerical values in parentheses represent the average addition mole number of ethylene oxide.
The carboxyvinyl polymer may be an alkyl-modified carboxyvinyl polymer. The carboxyvinyl polymer is mainly a polymer of acrylic acid, and the alkyl-modified carboxyvinyl polymer is mainly a copolymer of acrylic acid and an alkyl methacrylate (for example, having 10 to 30(C10 to C30) carbon atoms in total). The carboxyvinyl polymer is not particularly limited, and examples thereof include compounds described as "CARBOMER" under the INCI name. The alkyl-modified carboxyvinyl polymer is not particularly limited, and examples thereof include compounds described under the INCI name "ACRYLATES/C10-30 ALKYLACRYLATE CROSSPOLYMER ((acrylates/alkyl acrylates (C10-30)) (crosslinked polymers)".
Among them, a carboxyvinyl polymer and an alkyl-modified carboxyvinyl polymer are preferable as the component (C) from the viewpoint of further improving the stability of the hair styling composition.
Examples of the commercially available products of the carboxyvinyl Polymer include a trade name "Carbopol 934 Polymer", a trade name "Carbopol 940 Polymer", a trade name "Carbopol 941 Polymer", a trade name "Carbopol 980 Polymer", a trade name "Carbopol 981 Polymer", a trade name "Carbopol 1342 Polymer", a trade name "Carbopol 2984 Polymer", a trade name "Carbopol Ultrez 10 Polymer", a trade name "Carbopol ETD 2050 Polymer" (manufactured by Lubrizol Advanced Materials Co., Ltd., supra), a trade name "AQUPEC UPHV-501", a trade name "AQHV-504", a trade name "AQUPHV-505" (manufactured by Sumitomo Seiki Kaisha), a trade name "HIWAKO 104", a trade name "HIWAVIVIS 105" (manufactured by Wako K.K.K.K.). Examples of commercially available products of the above-mentioned alkyl-modified carboxyvinyl Polymer include a product name "PEMULEN TR-1", a product name "PEMULEN TR-2", a product name "Carbopol ETD 2020 Polymer", a product name "Carbopol ULTREZ 20 Polymer", a product name "Carbopol ULTREZ 21 Polymer", and a product name "Carbopol SC-200 Polymer" (manufactured by Lubrizol Advanced Materials Co., Ltd., supra).
The component (C) is not particularly limited, and can be used by neutralizing with an alkaline substance or by neutralizing with an alkaline substance. Examples of the basic substance include alkanolamines such as triethanolamine and monoethanolamine, inorganic bases such as ammonia, sodium hydroxide and potassium hydroxide, and basic amino acids such as arginine. The amount of the basic substance added may be appropriately adjusted depending on the component (C), the kind of the basic substance, and the amount of the component (C) used.
The content of the component (C) in the hair styling composition of the present invention is not particularly limited, and is preferably 0.1 to 2.0% by mass, more preferably 0.2 to 0.5% by mass, based on 100% by mass of the hair styling composition of the present invention. When the content of the component (C) is 0.1% by mass or more, the hair styling composition is more excellent in stability. When the content of the component (C) is 2.0% by mass or less, the degree of easy pushing-off at the time of hair styling, the property of inhibiting stickiness, and the easiness of washing are further excellent. The content of the component (C) is the total content of all the components (C) in the hair styling composition of the present invention.
[ component (D) ]
The component (D) is a cationic film-forming polymer. The hair styling composition of the present invention contains the component (D), and thus has excellent curl reproducibility, curl strength, and curl retention properties while maintaining the stability of the hair styling composition. Further, since hair is not jammed during hair styling, the hair is easily pushed open and has excellent coating properties. The component (D) may be used alone or in combination of two or more.
Examples of the component (D) include vinylpyrrolidone/N, N-dimethylaminoethyl methacrylic acid copolymer diethyl sulfate, vinylpyrrolidone/dimethylaminopropyl methacrylamide/methacryloylaminopropyl lauryl dimethyl ammonium chloride copolymer, alkyl (meth) acrylate/methacryloyloxyethyl trimethyl ammonium chloride copolymer, butyl methacrylate/2-ethoxyethyl methacrylate/methacryloyloxyethyl trimethyl ammonium chloride copolymer, O- [ 2-hydroxy-3- (trimethylammonium) propyl ] hydroxyethyl cellulose chloride, vinylimidazole trichloride/vinylpyrrolidone copolymer, hydroxyethyl cellulose/dimethyldiallyl ammonium chloride, polyvinyl pyrrolidone copolymer, polyvinyl pyrrolidone, Polyvinylpyrrolidone/alkylaminoacrylate/vinylcaprolactam copolymers, chloromethylvinylimidazole/vinylpyrrolidone copolymers, (vinylpyrrolidone/dimethylaminopropyl methacrylamide/lauryldimethylaminopropyl methacrylamide) copolymers, and the like.
The component (D) is preferably a polymer containing a structural unit derived from vinylpyrrolidone or a polymer containing a structural unit derived from a monomer having ammonium chloride. Among these, vinylpyrrolidone/N, N-dimethylaminoethylmethacrylate copolymer diethylsulfate is more preferable from the viewpoint of further improving the stability and the curl retention property (particularly, curl retention property after combing with hands after coating and drying).
The component (D) is preferably a compound described by INCI name "POLYQUATERNIUM-11" from the viewpoint of more excellent stability and more excellent curl retention (particularly curl retention after combing with hands after setting hair).
Examples of the commercially available product of the polyquaternium-11 include a product name "h.c. polymer 1N", a product name "h.c. polymer GMR" (manufactured by osaka organic industries, inc.), a product name "Gafquat 440", and a product name "Gafquat 755N" (manufactured by Ashland, inc.).
The content of the component (D) in the hair styling composition of the present invention is not particularly limited, and is preferably 0.2 to 3.0% by mass, more preferably 0.5 to 2.0% by mass, based on 100% by mass of the hair styling composition of the present invention. When the content of the component (D) is 0.2% by mass or more, the degree of easy pushing-off at the time of hair styling, the curl reproducibility, and the curl retention property (particularly, curl retention property) are more excellent. When the content of the component (D) is 3.0% by mass or less, the hair styling composition is more excellent in stability. Further, the coated hair has more excellent feeling in use such as texture and stickiness-inhibiting property. The content of the component (D) is the total content of all the components (D) in the hair styling composition of the present invention.
[ Water ]
The hair styling composition of the present invention contains water. The water is not particularly limited, and is preferably purified water. The content of water in the hair styling composition of the present invention is not particularly limited, and is preferably 45.0 to 90.0% by mass, and more preferably 50.0 to 85.0% by mass, based on 100% by mass of the hair styling composition of the present invention.
[ component (E) ]
The hair styling agent composition of the present invention preferably further contains polyoxypropylene sorbitol (sometimes referred to as "component (E)"). When the hair styling composition of the present invention contains the component (E), the hair styling composition is more excellent in the degree of easy-to-push, the curl reproducibility and the curl retention property at the time of application. The component (E) may be used alone or in combination of two or more.
The number average molecular weight of the component (E) is not particularly limited, but is preferably 300 to 1000, more preferably 400 to 800. When the number average molecular weight of the component (E) is 300 or more, the curl reproducibility and curl retention are further excellent. When the number average molecular weight of the component (E) is 1000 or less, the degree of easy-open upon application of the hair styling agent composition is further excellent.
From the viewpoint of further improving the ease of pushing-off of the hair styling composition and further improving the applicability to hair, the viscosity η of the component (E) measured at 30 ℃ with a brookfield rotational viscometer is preferably 1000 to 30000mPa · s, more preferably 2000 to 20000mPa · s.
Examples of commercially available products of component (E) include the product name "NEWPOL SP-750" and the product name "SANNIXSP-750" (manufactured by Sanyo chemical industries, Ltd.).
When the hair styling composition of the present invention contains the component (E), the content of the component (E) in the hair styling composition of the present invention is not particularly limited, and is preferably 0.3 to 5.0% by mass, and more preferably 0.4 to 3.0% by mass, based on 100% by mass of the hair styling composition of the present invention. When the content of the component (D) is 0.3% by mass or more, the hair styling agent composition is more excellent in the degree of easy-to-push, the curl reproducibility and the curl retention property at the time of application. When the content of the component (E) is 5.0 mass% or less, the emulsion stability of the hair styling agent composition is improved and stickiness after application is further suppressed. The content of the component (E) is the total content of all the components (E) in the hair styling composition of the present invention.
[ other ingredients ]
The hair styling composition of the present invention may contain components (a) to (E) and components (other components) other than water within a range not impairing the effects of the present invention. The other components are not particularly limited, and examples thereof include components generally used in cosmetics and quasi drugs. Specific examples thereof include oils other than the component (a), surfactants (cationic surfactants, anionic surfactants, nonionic surfactants, amphoteric surfactants, etc.); lower alcohols such as ethanol; powder; polyhydric alcohols such as ethylene glycol, diethylene glycol, triethylene glycol, polyethylene glycol, propylene glycol, dipropylene glycol, polypropylene glycol, isoprene glycol, 1, 3-butanediol, 1, 2-pentanediol, 1, 2-hexanediol, 1, 2-octanediol, 1, 2-decanediol, glycerin, diglycerin, and polyglycerin; thickening agents other than the components (B) and (C) such as hydroxymethylcellulose and hydroxypropylmethylcellulose; sugar alcohols such as sorbitol and maltitol; moisturizers such as hyaluronic acid, collagen, panthenol, etc.; preservatives such as methyl paraben, propyl paraben, butyl paraben and benzoate; phosphoric acid and its salts, citric acid and its salts, lactic acid and its salts, sodium hydroxide, triethanolamine and other pH regulators; a fragrance; an ultraviolet absorber; an antioxidant; metal ion chelators (chelators); a film-forming polymer compound other than the component (D); powder; a pigment; a pigment; vitamins; amino acids; an astringent; a whitening agent; an animal or plant extract; an acid; alkali, and the like. The other components may be used alone or in combination of two or more. Further, it is preferable that the hair styling composition of the present invention does not substantially contain an oil other than the component (a), a thickener other than the components (B) and (C), and a film-forming polymer compound other than the component (D) (for example, each is 0.05% by mass or less, particularly 0.01% by mass or less, based on 100% by mass of the hair styling composition of the present invention). In addition, from the viewpoint of further improving the stickiness-suppressing property and the coating property, the content of the lower alcohol is preferably 10% by mass or less based on 100% by mass of the hair styling composition of the present invention.
The hair styling composition of the present invention is not particularly limited, and preferably contains a surfactant from the viewpoint of preparing the hair styling composition of the present invention into an emulsion form. Among them, nonionic surfactants are preferable. The surfactant (particularly, nonionic surfactant) may be used alone or in combination of two or more.
The nonionic surfactant is not particularly limited, and examples thereof include sorbitan fatty acid esters, glycerin fatty acid esters, and alkylene oxide adducts thereof, polyoxyalkylene alkyl ethers, polyoxyalkylene fatty acid esters, polyoxyalkylene alkylphenols, polyoxyethylene sorbitol fatty acid esters, polyoxyethylene alkylphenyl formaldehyde condensates, polyoxyethylene sterols and derivatives thereof, polyoxyethylene lanolin and derivatives thereof, polyoxyethylene beeswax derivatives, sugar esters, polyoxyethylene hydrogenated castor oil, and polyoxyethylene castor oil.
Examples of the sorbitan fatty acid ester include sorbitan monooleate, sorbitan monostearate, sorbitan monoisostearate, sorbitan monopalmitate, sorbitan monolaurate, sorbitan trioleate, sorbitan tristearate, sorbitan sesquistearate, sorbitan sesquioleate, sorbitan sesquiisostearate, and sorbitan coconut oil fatty acid ester. Examples of the alkylene oxide adduct of a sorbitan fatty acid ester include polyoxyethylene sorbitan monolaurate, polyoxyethylene sorbitan monopalmitate, polyoxyethylene sorbitan monostearate, polyoxyethylene sorbitan monooleate, polyoxyethylene sorbitan monoisostearate, polyoxyethylene sorbitan monolocofatty acid ester, polyoxyethylene sorbitan tristearate, and polyoxyethylene sorbitan trioleate.
The glycerin fatty acid ester includes any one of a monoglyceride and a polyglycerin fatty acid ester. Examples of the monoglyceride fatty acid ester include glyceryl monocaprylate, glyceryl monocaprate, glyceryl monolaurate, glyceryl monomyristate, glyceryl monopalmitate, glyceryl monostearate, glyceryl monoisostearate, glyceryl monobehenate, glyceryl monooleate, glyceryl monocerucate, glyceryl sesquioleate, glyceryl distearate, glyceryl diisostearate, and glyceryl dianhydronate. Examples of the polyglycerin fatty acid ester include polyglycerin fatty acid esters having a polymerization degree of 2 to 10 such as a monoglyceride of a fatty acid ester of a monoglyceride of a fatty acid having a polymerization degree of 2 to 10, such as diglycerol monocaprylate, decaglycerol monocaprylate, hexaglycerol monolaurate, decaglycerol monolaurate, poly (4 to 10) glycerol monolaurate, decaglycerol monomyristate, decaglycerol monostearate, decaglycerol monoisostearate, poly (2 to 10) glycerol monostearate, diglycerol monooleate, hexaglycerol monooleate, diglycerol sesquioleate, poly (2 to 10) glycerol diisostearate, poly (6 to 10) glycerol distearate, diglycerol triisostearate, and poly (10) glycerol tristearate. Examples of the alkylene oxide adduct of a glycerin fatty acid ester include polyoxyethylene glyceryl monostearate and polyoxyethylene glyceryl monooleate.
Examples of the polyoxyalkylene alkyl ether include polyoxyethylene lauryl ether, polyoxyethylene cetyl ether, polyoxyethylene stearyl ether, polyoxyethylene oleyl ether, polyoxyethylene polyoxypropylene lauryl ether, polyoxypropylene cetyl ether, polyoxypropylene isohexadecyl ether, polyoxypropylene stearyl ether, and polyoxypropylene oleyl ether.
Examples of the polyoxyalkylene fatty acid ester include polyethylene glycol fatty acid esters such as polyethylene glycol monooleate, polyethylene glycol monostearate, polyethylene glycol distearate and polyethylene glycol monolaurate; propylene glycol fatty acid esters such as propylene glycol monostearate, propylene glycol monolaurate and propylene glycol monooleate.
When the hair styling composition of the present invention contains a surfactant, the content of the surfactant (particularly, nonionic surfactant) in the hair styling composition of the present invention is not particularly limited, and is preferably 2.0 to 6.0% by mass, more preferably 2.5 to 5.0% by mass, based on 100% by mass of the hair styling composition of the present invention, from the viewpoint of stability of the hair styling composition. The content of the surfactant is the total content of all surfactants in the hair styling composition of the present invention.
Examples of the powder include silica, talc, mica, calcium carbonate, magnesium carbonate, hydroxyapatite, titanium oxide, zinc oxide, calcium silicate, magnesium silicate, aluminum silicate, and magnesium hydroxide. When the hair styling composition of the present invention contains a powder, stickiness is further suppressed, and the effect after hair styling becomes light. Among the above powders, silica, magnesium silicate, and magnesium hydroxide are preferable from the viewpoint of more excellent suppression of stickiness and hair styling ability. The silica may be anhydrous silicic acid (hydrophilic silica) which has not been subjected to hydrophobization treatment, or may be hydrophobized anhydrous silicic acid. The silica may be surface-treated with an amino acid, an ester, lecithin, or the like. The silica may be so-called easily disintegrable silica particles. The powder may be used alone or in combination of two or more.
The hair styling agent composition of the present invention preferably contains substantially no oil agent which is solid at 25 ℃ and is selected from the group consisting of hydrocarbon oils, waxes, and oils and fats. In the present specification, the phrase "solid at 25 ℃ means that, for example, a sample (oil) flowing in an amount of 50g is dissolved by heating in a glass bottle having a radius of 2cm and a height of 7cm, and the sample does not drip from the glass bottle when 5 minutes has elapsed since the inversion after the glass bottle is cooled to 25 ℃. Hereinafter, the "oil agent which is solid at 25 ℃ and is selected from the group consisting of hydrocarbon oils, waxes, and oils" may be referred to as "specific oil agent which is solid at 25 ℃. Examples of the specific oil agent which is solid at 25 ℃ include carnauba wax, candelilla wax, beeswax, rice bran wax, shellac wax, spermaceti wax, lanolin, ceresin (ceresin), paraffin wax, microcrystalline wax, polyethylene powder, polyethylene wax, vaseline, hydrogenated castor oil, and wood wax.
In the present specification, "substantially not contained" means "not actively contained", and does not exclude that a trace amount of the component contained in other compounding ingredients is inevitably contained. More specifically, for example, the content of the specific oil agent which is solid at 25 ℃ (particularly the specific oil agent which is solid at 25 ℃) in the hair styling composition of the present invention is preferably 0.05% by mass or less (that is, 0 to 0.05% by mass), and more preferably 0.01% by mass or less, based on 100% by mass of the hair styling composition of the present invention. When the hair styling composition does not substantially contain a specific oil agent which is solid at 25 ℃, the hair styling composition is more excellent in the degree of easy-to-push-off during hair styling, and can further suppress stickiness of hair after hair styling.
The formulation of the hair styling composition of the present invention is not particularly limited, and examples thereof include lotions, creams, and the like. Among them, a fluid emulsion is preferable. The hair styling composition of the present invention is an emulsified composition. By using the emulsion composition, a moist touch can be imparted during application.
The viscosity of the hair styling composition of the present invention at 25 ℃ is not particularly limited, and is preferably 500 to 100000mPa · s, and more preferably 1000 to 30000mPa · s, from the viewpoint of coating properties and good affinity for hair. For example, the above viscosity was measured using a viscometer with a No.4 spindle at a rotation speed of 6rpm for 1 minute. As the viscometer, a TV-22 type viscometer manufactured by Toyobo industries Co., Ltd can be used.
The hair styling composition of the present invention is not particularly limited, and can be produced by a known or customary method. For example, the hair styling composition of the present invention can be produced by mixing the above-mentioned components and emulsifying by a forward emulsification method, a phase inversion emulsification method, or the like using a homomixer. The mixing and emulsification may be performed separately or simultaneously.
The hair styling composition of the present invention is a hair styling composition containing water and an oil agent [ component (a) ], and the hair styling composition containing water and component (a) is thickened and stabilized in an emulsified state by blending xanthan gum [ component (B) ] and an acrylic thickener [ component (C) ]. In particular, by using the component (B) as a substance which exerts a thickening effect in addition to the component (C), the curl reproducibility after coating is excellent and the curl retainability is relatively excellent in addition to the stability. Further, stickiness of the hair styling agent can be suppressed. In addition, in such a hair styling agent composition, the degree of easy-open at the time of application is excellent by blending the component (a). Further, by blending a cationic film-forming polymer [ component (D) ] (particularly polyquaternium-11) in a large amount of a polymer (setting polymer) imparting hair styling properties, the hair styling composition can maintain stability and can form a film having excellent curl reproducibility. Further, since the hair is not caught even by hand combing in a dry state and is not easily deformed even by touching, the degree of easy pushing-off at the time of coating is more excellent and the curl retention is also excellent. In general, since the component (C) is anionic, when the component (D) is used in combination with the component (C), a block is formed or the viscosity of the hair styling composition is lowered, whereby it is predicted that the stability is lowered. However, surprisingly, in the hair styling agent composition of the present invention, the component (D) can form a relatively soft film after application while maintaining the stability and viscosity of the hair styling agent composition, thereby exerting an effect of making the curl reproducibility and curl retention excellent.
Further, by blending polyoxypropylene sorbitol [ component (E) ] in the hair styling composition of the present invention, the hair styling composition is imparted with adhesiveness, and the degree of easy pushing-off, curl reproducibility and curl retention at the time of application are further excellent.
Examples
The present invention will be described in more detail below with reference to examples, but the present invention is not limited to these examples. The amounts listed in the table are amounts of each component (i.e., amounts of effective components in each raw material) and are expressed as "% by mass" unless otherwise specified. In addition, "-" in the amounts blended in the tables means that the component was not blended.
Examples 1 to 7 and comparative examples 1 to 8
Using the components (a) to (E), water and other components) described in the table, samples of examples and comparative examples were prepared according to a conventional method, hair styling agent compositions were prepared, and the following evaluations were performed. The results are shown in the table. Further, the hair styling composition having the evaluation result of stability of x was not subjected to other evaluations.
[ test example 1: evaluation of stability
The hair styling compositions obtained in examples and comparative examples were visually checked for the state thereof, and the emulsified state was judged according to the following criteria.
< evaluation criteria for stability >
○ (good) the mixture was uniformly mixed, and formation of lumps and phase separation were not observed
X 1 (poor): separation was observed
X 2 (poor): formation of lumps was observed
[ test example 2: evaluation of degree of easy-to-push-off at the time of coating ]
The hair styling composition was uniformly applied to the hair of a wig (practice manikin, manufactured by YUKARI JAPAN) after permanent waving, and the degree of easiness of being pushed off the hair was answered by 10 panelists. Based on the above-mentioned answer, the degree of easy-open was evaluated according to the following criteria.
< evaluation criteria for degree of easy-to-push-off during coating >
○ good 8 or more out of 10 answers no jamming and good degree of easy pushing open
△ (used) among 10, 5 to 7 answers are no jamming and good in pushing-off easiness
X (bad): out of 10, 4 or less were answered as no jamming and good pushing-off
[ test example 3: evaluation of curl reproducibility
The hair condition of the wig to which the hair styling composition was applied was answered by 10 panelists to determine the degree of good reproducibility of the curl as in test example 2. From the above responses, the reproducibility of curl was evaluated according to the following criteria.
< evaluation criteria for curl reproducibility >
○ good 8 or more out of 10 answers are good reproducibility of curl
△ (used) among 10, 5 to 7 answers were good in curl reproducibility
X (bad): among 10, 4 or less answers are good reproducibility of curl
[ test example 4: evaluation of curl Strength
The hair of the wig to which the hair styling composition was applied was lightly held and touched with the palm of 10 panelists to answer the curl strength as in test example 2. Based on the above responses, the strength of curl was evaluated according to the following criteria.
○ (good). more than 8 of 10 answered as higher curl strength
△ (used) 5-7 of the 10 respond to higher curl strength
X (bad): among 10, 4 or less answers are higher in curl strength
[ test example 5: evaluation of curl Retention after drying (curl Retention (1))
The hair of the wig coated with the hair styling composition in the same manner as in test example 2 was left in the room for 6 hours. Thereafter, 10 panelists lightly hold and touch the wig hair with the palm of the hand to answer the curl retention after drying. Based on the above-mentioned responses, curl retention (1) was evaluated according to the following criteria.
< evaluation criteria for curl Retention (1) >
○ good 8 or more out of 10 answered as strength of curl
△ (used) among 10, 5 to 7 answers to the strength of the curl
X (bad): among 10, 4 or less answers were to maintain the strength of curl
[ test example 6: evaluation of curl Retention (2)) when combing by hand after drying
After combing the hair of the wig evaluated in test example 5 with a hand 5 times by 10 panelists, the hair of the wig was lightly held and touched with the palm, and the curl retention after combing with a hand was answered. Based on the above-mentioned responses, the curl retention property (2) was evaluated in accordance with the following criteria. In test example 5, the case where the evaluation result of the curl retention property (1) was x was not evaluated.
< evaluation criteria for curl Retention (2) >
○ (good). more than 8 of 10 answered as higher curl strength
△ (used) 5-7 of the 10 respond to higher curl strength
X (bad): among 10, 4 or less answers are higher in curl strength
TABLE 1
TABLE 2
The hair styling agent composition (example) of the present invention is excellent in stability, degree of easy-open upon application, curl reproducibility, and curl retention. On the other hand, when the component (a) is not contained (comparative example 1), the degree of easy-open at the time of coating is low. In the case where the component (C) was not contained (comparative example 2), separation was observed in the stability test. When the component (D) is not contained (comparative example 3), the curl retention is poor. In the case of using carrageenan instead of the component (B) (comparative example 4), the curl reproducibility was poor. When another film-forming polymer was used in place of the component (D) (comparative examples 5 to 8), the degree of easy-to-push during coating and the curl retention during manual combing after drying were poor.
The details of each component described in the table are as follows.
< ingredient (A) >
Dimethylpolysiloxane (350 cs): trade name "KF 96-350 CS" (manufactured by shin-Etsu chemical Co., Ltd.)
Dimethylpolysiloxane (100 cs): trade name "SH 200C FLUID 100 CS" (manufactured by Torredo Corning Co., Ltd.)
Cetyl 2-ethylhexanoate: trade name "CIO-N" (manufactured by Nippon surfactant industries Co., Ltd.)
< ingredient (B) >
Xanthan gum: trade name "Echogum T" (manufactured by Sumitomo pharmaceutical Co., Ltd., Japan)
< ingredient (C) >
Carboxyvinyl polymer: under the trade name "Carbopol 980 Polymer" (manufactured by Lubrizol advanced materials Co., Ltd.)
Alkyl-modified carboxyvinyl polymer: trade name "PEMULEN TR-1" (manufactured by Lubrizol advanced materials Co., Ltd.)
< ingredient (D) >
Component (D-1): trade name "H.C. Polymer 1N" (manufactured by Osaka organic industries Co., Ltd., vinylpyrrolidone/N, N-dimethylaminoethylmethacrylate copolymer diethyl ester sulfate, polyquaternium-11)
Component (D-2): trade name "H.C. Polymer GMR" (manufactured by Osaka organic industries Co., Ltd., vinylpyrrolidone/N, N-dimethylaminoethylmethacrylate copolymer diethyl ester sulfate, polyquaternium-11)
< ingredient (E) >
Polyoxypropylene sorbitol: trade name "SANNIX SP-750" (manufactured by Sanyo chemical industries Co., Ltd., number average molecular weight 690)
< other ingredients >
Carrageenin: trade name "GENUVISCO PJ-JPE" (manufactured by TRICIRCULA CO., LTD.)
(alkyl acrylate/diacetone acrylamide) copolymer: the trade name "Plaszize L-6345U" (manufactured by Nippon chemical Co., Ltd., anionic film-forming polymer, acrylic resin alkanolamine solution)
(hydroxyethyl acrylate/methoxyethyl acrylate) copolymer: the trade name "Plasize L-2200" (manufactured by International chemical industries, Ltd., nonionic skin-forming polymer, hydroxyethyl acrylate/methoxyethyl acrylate copolymer solution)
(Ethyl betaine methacrylate/acrylate) copolymer having a trade name of "YUKAFORMER 301" (purity: 30%), manufactured by Mitsubishi chemical corporation, amphoteric coating-forming polymer, N-methacryloyloxyethyl-N, N-dimethylammonium- α -N-carboxybetaine/alkyl methacrylate copolymer solution)
Polyvinyl pyrrolidone: trade name "PVP K-90" (nonionic film-forming polymer, available from ISP Co.)
Sorbitan stearate: trade name "SS-10V" (sorbitan monostearate, manufactured by Nippon surfactant industries Co., Ltd.)
Ceteth-20: the trade name "BLAUNON CH-320L" (polyoxyethylene cetyl ether, manufactured by JIAO Fine chemical Co., Ltd.)
Further, formulation examples of the hair styling composition of the present invention are shown below.
(formulation example 1: Hair cream)
(formulation example 2: Hair cream)
Claims (4)
1. A hair styling agent composition characterized by comprising the following component (A), the following component (B), the following component (C) and the following component (D),
component (A): an oil agent which is liquid at 25 ℃,
component (B): a xanthan gum,
component (C): an acrylic acid-based thickener, which is a mixture of,
component (D): a cationic film-forming polymer.
2. The hair styling composition according to claim 1, wherein the ingredient (D) is polyquaternium-11.
3. The hair styling agent composition according to claim 1 or 2, characterized in that the hair styling agent composition contains the following ingredient (E),
component (E): polyoxypropylene sorbitol.
4. The hair styling agent composition according to any one of claims 1 to 3, wherein the component (C) is a carboxyvinyl polymer and/or an alkyl-modified carboxyvinyl polymer.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2018-021576 | 2018-02-09 | ||
| JP2018021576 | 2018-02-09 | ||
| PCT/JP2018/034171 WO2019155673A1 (en) | 2018-02-09 | 2018-09-14 | Hairdressing agent composition |
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| CN110913835A true CN110913835A (en) | 2020-03-24 |
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| JP (1) | JP6965372B2 (en) |
| CN (1) | CN110913835A (en) |
| WO (1) | WO2019155673A1 (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2003292422A (en) * | 2002-04-01 | 2003-10-15 | Noevir Co Ltd | Hair cosmetic |
| JP2010189311A (en) * | 2009-02-18 | 2010-09-02 | Arimino Kagaku Kk | Cosmetic for hair |
| CN106102695A (en) * | 2014-05-16 | 2016-11-09 | 株式会社漫丹 | Hair mousse composition |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2806274B1 (en) * | 2000-03-14 | 2002-09-20 | Oreal | BALL APPLICATOR CONTAINING A HAIR COMPOSITION |
| DE10237257A1 (en) * | 2001-08-17 | 2003-05-08 | Nat Starch Chem Invest | Use of xanthan gum as a hair fixative |
| DE102004042848A1 (en) * | 2004-09-04 | 2006-03-09 | Wella Ag | Hair treatment composition containing a polymer combination |
| DE102005028382A1 (en) * | 2005-06-20 | 2006-12-28 | Wella Aktiengesellschaft | Product release system to atomize cosmetic composition for hair, has pressure-resistant packaging, spray head containing capillary, and propellant-containing cosmetic composition having hair-setting, or hair-conditioning cationic polymer |
| JP2007320872A (en) * | 2006-05-31 | 2007-12-13 | Mandom Corp | Hair cosmetic product |
| JP5197837B2 (en) * | 2010-12-08 | 2013-05-15 | 株式会社 資生堂 | Gel hair cosmetic |
-
2018
- 2018-09-14 WO PCT/JP2018/034171 patent/WO2019155673A1/en active Application Filing
- 2018-09-14 JP JP2019570287A patent/JP6965372B2/en active Active
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Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2003292422A (en) * | 2002-04-01 | 2003-10-15 | Noevir Co Ltd | Hair cosmetic |
| JP2010189311A (en) * | 2009-02-18 | 2010-09-02 | Arimino Kagaku Kk | Cosmetic for hair |
| CN106102695A (en) * | 2014-05-16 | 2016-11-09 | 株式会社漫丹 | Hair mousse composition |
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| Publication number | Publication date |
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| JPWO2019155673A1 (en) | 2020-04-02 |
| JP6965372B2 (en) | 2021-11-10 |
| WO2019155673A1 (en) | 2019-08-15 |
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