JPWO2019155673A1 - Hairdressing composition - Google Patents
Hairdressing composition Download PDFInfo
- Publication number
- JPWO2019155673A1 JPWO2019155673A1 JP2019570287A JP2019570287A JPWO2019155673A1 JP WO2019155673 A1 JPWO2019155673 A1 JP WO2019155673A1 JP 2019570287 A JP2019570287 A JP 2019570287A JP 2019570287 A JP2019570287 A JP 2019570287A JP WO2019155673 A1 JPWO2019155673 A1 JP WO2019155673A1
- Authority
- JP
- Japan
- Prior art keywords
- component
- mass
- curl
- hair styling
- composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
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- 235000019488 nut oil Nutrition 0.000 description 1
- HMMGMWAXVFQUOA-UHFFFAOYSA-N octamethylcyclotetrasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 HMMGMWAXVFQUOA-UHFFFAOYSA-N 0.000 description 1
- CXQXSVUQTKDNFP-UHFFFAOYSA-N octamethyltrisiloxane Chemical compound C[Si](C)(C)O[Si](C)(C)O[Si](C)(C)C CXQXSVUQTKDNFP-UHFFFAOYSA-N 0.000 description 1
- AEIJTFQOBWATKX-UHFFFAOYSA-N octane-1,2-diol Chemical compound CCCCCCC(O)CO AEIJTFQOBWATKX-UHFFFAOYSA-N 0.000 description 1
- 229940073665 octyldodecyl myristate Drugs 0.000 description 1
- 229940049964 oleate Drugs 0.000 description 1
- BARWIPMJPCRCTP-UHFFFAOYSA-N oleic acid oleyl ester Natural products CCCCCCCCC=CCCCCCCCCOC(=O)CCCCCCCC=CCCCCCCCC BARWIPMJPCRCTP-UHFFFAOYSA-N 0.000 description 1
- 229940055577 oleyl alcohol Drugs 0.000 description 1
- XMLQWXUVTXCDDL-UHFFFAOYSA-N oleyl alcohol Natural products CCCCCCC=CCCCCCCCCCCO XMLQWXUVTXCDDL-UHFFFAOYSA-N 0.000 description 1
- BARWIPMJPCRCTP-CLFAGFIQSA-N oleyl oleate Chemical compound CCCCCCCC\C=C/CCCCCCCCOC(=O)CCCCCCC\C=C/CCCCCCCC BARWIPMJPCRCTP-CLFAGFIQSA-N 0.000 description 1
- 239000004006 olive oil Substances 0.000 description 1
- 235000008390 olive oil Nutrition 0.000 description 1
- 239000003346 palm kernel oil Substances 0.000 description 1
- 235000019865 palm kernel oil Nutrition 0.000 description 1
- 239000002540 palm oil Substances 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- XYJRXVWERLGGKC-UHFFFAOYSA-D pentacalcium;hydroxide;triphosphate Chemical compound [OH-].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O XYJRXVWERLGGKC-UHFFFAOYSA-D 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- WCVRQHFDJLLWFE-UHFFFAOYSA-N pentane-1,2-diol Chemical compound CCCC(O)CO WCVRQHFDJLLWFE-UHFFFAOYSA-N 0.000 description 1
- 229940066842 petrolatum Drugs 0.000 description 1
- 235000019271 petrolatum Nutrition 0.000 description 1
- 238000005191 phase separation Methods 0.000 description 1
- 229920000223 polyglycerol Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920000259 polyoxyethylene lauryl ether Polymers 0.000 description 1
- 235000010486 polyoxyethylene sorbitan monolaurate Nutrition 0.000 description 1
- 239000000256 polyoxyethylene sorbitan monolaurate Substances 0.000 description 1
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 description 1
- 239000000244 polyoxyethylene sorbitan monooleate Substances 0.000 description 1
- 235000010483 polyoxyethylene sorbitan monopalmitate Nutrition 0.000 description 1
- 239000000249 polyoxyethylene sorbitan monopalmitate Substances 0.000 description 1
- 235000010989 polyoxyethylene sorbitan monostearate Nutrition 0.000 description 1
- 239000001818 polyoxyethylene sorbitan monostearate Substances 0.000 description 1
- 235000010988 polyoxyethylene sorbitan tristearate Nutrition 0.000 description 1
- 239000001816 polyoxyethylene sorbitan tristearate Substances 0.000 description 1
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 description 1
- 229920000053 polysorbate 80 Polymers 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- NEOZOXKVMDBOSG-UHFFFAOYSA-N propan-2-yl 16-methylheptadecanoate Chemical compound CC(C)CCCCCCCCCCCCCCC(=O)OC(C)C NEOZOXKVMDBOSG-UHFFFAOYSA-N 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000004405 propyl p-hydroxybenzoate Substances 0.000 description 1
- 235000010232 propyl p-hydroxybenzoate Nutrition 0.000 description 1
- 229940026235 propylene glycol monolaurate Drugs 0.000 description 1
- 229940093625 propylene glycol monostearate Drugs 0.000 description 1
- 229960003415 propylparaben Drugs 0.000 description 1
- LKUNXBRZDFMZOK-UHFFFAOYSA-N rac-1-monodecanoylglycerol Chemical compound CCCCCCCCCC(=O)OCC(O)CO LKUNXBRZDFMZOK-UHFFFAOYSA-N 0.000 description 1
- DCBSHORRWZKAKO-UHFFFAOYSA-N rac-1-monomyristoylglycerol Chemical compound CCCCCCCCCCCCCC(=O)OCC(O)CO DCBSHORRWZKAKO-UHFFFAOYSA-N 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000008165 rice bran oil Substances 0.000 description 1
- 239000004170 rice bran wax Substances 0.000 description 1
- 235000019384 rice bran wax Nutrition 0.000 description 1
- 239000003352 sequestering agent Substances 0.000 description 1
- 239000012176 shellac wax Substances 0.000 description 1
- 229940010747 sodium hyaluronate Drugs 0.000 description 1
- YWIVKILSMZOHHF-QJZPQSOGSA-N sodium;(2s,3s,4s,5r,6r)-6-[(2s,3r,4r,5s,6r)-3-acetamido-2-[(2s,3s,4r,5r,6r)-6-[(2r,3r,4r,5s,6r)-3-acetamido-2,5-dihydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-2-carboxy-4,5-dihydroxyoxan-3-yl]oxy-5-hydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-3,4,5-trihydroxyoxane-2- Chemical compound [Na+].CC(=O)N[C@H]1[C@H](O)O[C@H](CO)[C@@H](O)[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@H](O[C@H]2[C@@H]([C@@H](O[C@H]3[C@@H]([C@@H](O)[C@H](O)[C@H](O3)C(O)=O)O)[C@H](O)[C@@H](CO)O2)NC(C)=O)[C@@H](C(O)=O)O1 YWIVKILSMZOHHF-QJZPQSOGSA-N 0.000 description 1
- FWFUWXVFYKCSQA-UHFFFAOYSA-M sodium;2-methyl-2-(prop-2-enoylamino)propane-1-sulfonate Chemical compound [Na+].[O-]S(=O)(=O)CC(C)(C)NC(=O)C=C FWFUWXVFYKCSQA-UHFFFAOYSA-M 0.000 description 1
- 229940035044 sorbitan monolaurate Drugs 0.000 description 1
- 235000011069 sorbitan monooleate Nutrition 0.000 description 1
- 239000001593 sorbitan monooleate Substances 0.000 description 1
- 229940035049 sorbitan monooleate Drugs 0.000 description 1
- 235000011071 sorbitan monopalmitate Nutrition 0.000 description 1
- 239000001570 sorbitan monopalmitate Substances 0.000 description 1
- 229940031953 sorbitan monopalmitate Drugs 0.000 description 1
- 235000011078 sorbitan tristearate Nutrition 0.000 description 1
- 239000001589 sorbitan tristearate Substances 0.000 description 1
- 229960004129 sorbitan tristearate Drugs 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 229940001941 soy protein Drugs 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 239000012177 spermaceti Substances 0.000 description 1
- 229940084106 spermaceti Drugs 0.000 description 1
- 238000013112 stability test Methods 0.000 description 1
- 150000003432 sterols Chemical class 0.000 description 1
- 235000003702 sterols Nutrition 0.000 description 1
- 239000002600 sunflower oil Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- DZKXJUASMGQEMA-UHFFFAOYSA-N tetradecyl tetradecanoate Chemical compound CCCCCCCCCCCCCCOC(=O)CCCCCCCCCCCCC DZKXJUASMGQEMA-UHFFFAOYSA-N 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
- 229940088594 vitamin Drugs 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
- 235000013343 vitamin Nutrition 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring
Abstract
塗布時ののびのよさ、カール再現性、及びカール保持性に優れる整髪剤組成物を提供する。成分(A):25℃で液状の油剤、成分(B):キサンタンガム、成分(C):アクリル酸系増粘剤、及び成分(D):カチオン性皮膜形成ポリマーを含有する整髪剤組成物。成分(D)は、ポリクオタニウム−11であることが好ましい。上記整髪剤組成物は、成分(E):ポリオキシプロピレンソルビットを含むことが好ましい。上記成分(C)はカルボキシビニルポリマー及び/又はアルキル変性カルボキシビニルポリマーであることが好ましい。Provided is a hair styling composition having excellent spreadability during application, curl reproducibility, and curl retention. Ingredient (A): Oil composition which is liquid at 25 ° C, Ingredient (B): Xanthan gum, Ingredient (C): Acrylic acid thickener, and Ingredient (D): Cationic film-forming polymer. Component (D) is preferably polyquaternium-11. The hair styling composition preferably contains component (E): polyoxypropylene sorbit. The component (C) is preferably a carboxyvinyl polymer and / or an alkyl-modified carboxyvinyl polymer.
Description
本発明は、毛髪を整える整髪剤に用いられる整髪剤組成物に関する。 TECHNICAL FIELD The present invention relates to a hairdressing composition used for a hairdressing agent for conditioning hair.
毛髪を整えるために、液状、ジェル状、クリーム状及び固形状等の種々の性状の整髪剤組成物が知られている。従来、整髪剤組成物においては、その主機能である整髪力を発揮するために、皮膜形成ポリマーや室温で固形状のロウ、油脂や炭化水素油が用いられることが多い(例えば、特許文献1、特許文献2)。 Various hair styling compositions, such as liquid, gel, cream, and solid, are known for conditioning hair. BACKGROUND ART Conventionally, in a hairdressing composition, a film-forming polymer, a wax which is solid at room temperature, a fat or oil, or a hydrocarbon oil is often used in order to exert a hairdressing power which is a main function thereof (for example, Patent Document 1). , Patent Document 2).
例えば、特に女性の間で、毛髪に化学反応を用いて人工的なカールを形成させるパーマネントウェーブを施した髪型が好まれることがある。このような髪型に用いられる整髪剤組成物には、パーマネントウェーブ施術後のカールを再現する性質(カール再現性)に優れ、且つ再現したカールを保持する性質(カール保持性)に優れることが求められる。 For example, a permanent wavy hairstyle that uses chemical reactions to form artificial curls in the hair may be preferred, especially among women. The hairdressing composition used for such a hairstyle is required to be excellent in the property of reproducing the curl after the permanent wave treatment (curl reproducibility) and the property of retaining the reproduced curl (curl holding property). Can be
パーマネントウェーブが施された髪型に用いられる整髪剤組成物としては、例えば、カルボキシビニルポリマーと、ビニルピロリドン/N,N−ジメチルアミノエチルメタクリル酸共重合体ジエチル硫酸塩とを含有するクリーム状毛髪化粧料が知られている(例えば、特許文献3)。 As a hairdressing composition used for a hairstyle subjected to permanent waving, for example, a creamy hair cosmetic containing a carboxyvinyl polymer and a vinylpyrrolidone / N, N-dimethylaminoethylmethacrylic acid copolymer diethyl sulfate salt The fee is known (for example, Patent Document 3).
しかしながら、従来の整髪剤組成物は、カール再現性及びカール保持性について不充分であり、満足のいくものではなかった。また、ロングヘアに対する整髪剤組成物の塗布性を向上させるために、髪への塗布時ののびのよさも求められることがある。 However, the conventional hair styling compositions were not satisfactory in curl reproducibility and curl retention, and were not satisfactory. Further, in order to improve the applicability of the hair styling composition to long hair, good spreadability at the time of application to hair is sometimes required.
従って、本発明の目的は、塗布時ののびのよさ、カール再現性、及びカール保持性に優れる整髪剤組成物を提供することにある。 Accordingly, an object of the present invention is to provide a hairdressing composition that is excellent in spreadability, curl reproducibility, and curl retention during application.
本発明者らは、上記目的を達成するため鋭意検討した結果、成分(A):25℃で液状の油剤、成分(B):キサンタンガム、成分(C):アクリル酸系増粘剤、及び成分(D):カチオン性皮膜形成ポリマーを含有する整髪剤組成物とすることにより、塗布時ののびのよさ、カール再現性、及びカール保持性に優れる整髪剤組成物が得られることを見出した。本発明はこれらの知見に基づいて完成させたものである。 The present inventors have conducted intensive studies to achieve the above object. As a result, component (A): an oil agent liquid at 25 ° C., component (B): xanthan gum, component (C): acrylic acid-based thickener, and component (D): It was found that a hair styling composition containing a cationic film-forming polymer can provide a hair styling composition having excellent spreadability at the time of application, curl reproducibility, and curl retention. The present invention has been completed based on these findings.
すなわち、本発明は、下記成分(A)、下記成分(B)、下記成分(C)、及び下記成分(D)を含有する整髪剤組成物を提供する。
成分(A):25℃で液状の油剤
成分(B):キサンタンガム
成分(C):アクリル酸系増粘剤
成分(D):カチオン性皮膜形成ポリマーThat is, the present invention provides a hairdressing composition comprising the following components (A), (B), (C), and (D).
Component (A): Oil agent liquid at 25 ° C. Component (B): Xanthan gum Component (C): Acrylic acid-based thickener Component (D): Cationic film-forming polymer
上記成分(D)は、ポリクオタニウム−11であることが好ましい。 The component (D) is preferably polyquaternium-11.
上記整髪剤組成物は、下記成分(E)を含むことが好ましい。
成分(E):ポリオキシプロピレンソルビットIt is preferable that the hair styling composition contains the following component (E).
Component (E): polyoxypropylene sorbit
上記成分(C)は、カルボキシビニルポリマー及び/又はアルキル変性カルボキシビニルポリマーであることが好ましい。 The component (C) is preferably a carboxyvinyl polymer and / or an alkyl-modified carboxyvinyl polymer.
本発明の整髪剤組成物は、塗布時ののびのよさ、カール再現性、及びカール保持性に優れる。 The hair styling composition of the present invention is excellent in spreadability, curl reproducibility and curl retention at the time of application.
本発明の整髪剤組成物は、25℃で液状の油剤、キサンタンガム、アクリル酸系増粘剤、及びカチオン性皮膜形成ポリマーを少なくとも含む。なお、本明細書において、上記25℃で液状の油剤を「成分(A)」と称する場合がある。また、キサンタンガムを「成分(B)」と称する場合がある。また、上記アクリル酸系増粘剤を「成分(C)」と称する場合がある。また、上記カチオン性皮膜形成ポリマーを「成分(D)」と称する場合がある。 The hairdressing composition of the present invention contains at least an oil, a xanthan gum, an acrylic acid-based thickener, and a cationic film-forming polymer which are liquid at 25 ° C. In the present specification, the oil agent that is liquid at 25 ° C. may be referred to as “component (A)”. Further, xanthan gum may be referred to as “component (B)”. The acrylic acid-based thickener may be referred to as “component (C)”. Further, the above cationic film-forming polymer may be referred to as “component (D)” in some cases.
すなわち、本発明の整髪剤組成物は、成分(A)、成分(B)、成分(C)、及び成分(D)を少なくとも含有する。本発明の整髪剤組成物は、上記成分(A)〜(D)以外の成分を含んでいてもよい。また、本発明の整髪剤組成物に含まれる各成分、例えば、成分(A)、成分(B)、成分(C)、成分(D)、及び、成分(A)〜(D)以外の成分等の各成分は、それぞれ、1種のみを用いてもよいし、2種以上を用いてもよい。 That is, the hairdressing composition of the present invention contains at least the components (A), (B), (C) and (D). The hairdressing composition of the present invention may contain components other than the components (A) to (D). Further, each component contained in the hairdressing composition of the present invention, for example, component (A), component (B), component (C), component (D), and components other than components (A) to (D) And the like may be used alone or in combination of two or more.
[成分(A)]
成分(A)は、25℃で液状の油剤である。本発明の整髪剤組成物は、成分(A)を含むことにより、毛髪への塗布時(整髪時)ののびのよさに優れ、毛髪の手触りが良くなる。成分(A)は、1種のみを用いてもよく、2種以上を用いてもよい。[Component (A)]
Component (A) is an oil agent that is liquid at 25 ° C. By containing the component (A), the hair styling composition of the present invention has excellent spreadability at the time of application to hair (at the time of hair styling), and improves the feel of hair. As the component (A), only one type may be used, or two or more types may be used.
なお、上記「25℃で液状」とは、特に限定されないが、例えば、半径2cm、高さ7cmのガラスボトルに50gの試料(油剤)を入れ、25℃の温度下、上記ガラスボトルを逆さにした場合に、逆さにした直後より5分間に、試料がガラスボトルから垂れ落ちる性状であることが好ましい。 The “liquid at 25 ° C.” is not particularly limited. For example, 50 g of a sample (oil) is placed in a glass bottle having a radius of 2 cm and a height of 7 cm, and the glass bottle is inverted at a temperature of 25 ° C. In this case, it is preferable that the sample has a property of dripping from the glass bottle for 5 minutes immediately after being inverted.
成分(A)のブルックフィールド型回転粘度計を用いて25℃で測定された粘度ηは、10〜5000mPa・sが好ましく、より好ましくは20〜3000mPa・sである。上記粘度が10mPa・s以上であると、塗布時に剤が手からたれ落ちるのを防ぐことができる。上記粘度が5000mPa・s以下であると、塗布時ののびがより優れる。 The viscosity η of the component (A) measured at 25 ° C. using a Brookfield-type rotational viscometer is preferably from 10 to 5000 mPa · s, more preferably from 20 to 3000 mPa · s. When the viscosity is 10 mPa · s or more, the agent can be prevented from dropping from hands during application. When the viscosity is 5000 mPa · s or less, the spread during coating is more excellent.
成分(A)としては、特に限定されないが、例えば、油脂、炭化水素油、脂肪酸、高級アルコール、エステル油、シリコーン油等が挙げられる。中でも、べたつきのなさ、滑り性、塗布後の手触りのよさにより優れる観点から、エステル油、シリコーン油が好ましく、より好ましくはシリコーン油である。なお、成分(A)には、後述する成分(E)に相当するものは含まれないものとする。 The component (A) is not particularly limited, and examples thereof include fats and oils, hydrocarbon oils, fatty acids, higher alcohols, ester oils, and silicone oils. Among them, ester oils and silicone oils are preferred, and silicone oils are more preferred, from the viewpoints of being less sticky, slippery, and better feel after application. The component (A) does not include a component corresponding to the component (E) described later.
上記油脂としては、例えば、アボカド油、アルガンオイル、オリーブ油、コメヌカ油、ダイズ油、トウモロコシ油、パーム核油、パーム油、ヒマシ油、ブドウ種子油、ククイナッツ油、マカデミアナッツ油、メドウホーム油、ヒマワリ油等が挙げられる。 Examples of the fats and oils include avocado oil, argan oil, olive oil, rice bran oil, soybean oil, corn oil, palm kernel oil, palm oil, castor oil, grape seed oil, kukui nut oil, macadamia nut oil, meadow home oil, sunflower oil And the like.
上記炭化水素油としては、例えば、α−オレフィンオリゴマー、軽質イソパラフィン、軽質流動イソパラフィン、合成スクワラン、植物性スクワラン、スクワラン、流動イソパラフィン、流動パラフィン等が挙げられる。 Examples of the hydrocarbon oil include α-olefin oligomers, light isoparaffin, light liquid isoparaffin, synthetic squalane, vegetable squalane, squalane, liquid isoparaffin, liquid paraffin, and the like.
上記高級アルコールとしては、例えば、ラウリルアルコール、オレイルアルコール等の炭素数6〜20の飽和又は不飽和の直鎖状の1価アルコール;イソステアリルアルコール、ヘキシルデカノール、オクチルドデカノール、デシルテトラデカノール等の炭素数6〜26の飽和又は不飽和の分岐鎖状の1価アルコールが挙げられる。 Examples of the higher alcohol include saturated or unsaturated linear monohydric alcohols having 6 to 20 carbon atoms such as lauryl alcohol and oleyl alcohol; isostearyl alcohol, hexyldecanol, octyldodecanol, decyltetradecanol and the like. A saturated or unsaturated branched monohydric alcohol having 6 to 26 carbon atoms is exemplified.
上記エステル油としては、例えば、オレイン酸エチル、ミリスチン酸イソプロピル、パルミチン酸イソプロピル、ミリスチン酸ミリスチル、パルミチン酸セチル、オレイン酸オレイル、ミリスチン酸オクチルドデシル、オレイン酸オクチルドデシル、イソステアリン酸エチル、イソステアリン酸イソプロピル、イソステアリン酸プロピレングリコール、2−エチルヘキサン酸セチル、2−エチルヘキサン酸セトステアリル、トリ2−エチルヘキサン酸グリセリル、トリ(カプリル酸/カプリン酸)グリセリル、トリイソパルミチン酸グリセリル、テトラ2−エチルヘキサン酸ペンタエリスリトール、アジピン酸ジイソプロピル、オクタン酸イソセチル、オクタン酸イソステアリル、イソステアリン酸イソセチル、イソステアリン酸オクチルドデシル、ジメチルオクタン酸オクチルドデシル、イソノナン酸イソノニル、テトラオクタン酸ペンタエリスリチル、テトライソステアリン酸ペンタエリトリット等が挙げられる。 Examples of the ester oil include ethyl oleate, isopropyl myristate, isopropyl palmitate, myristyl myristate, cetyl palmitate, oleyl oleate, octyl dodecyl myristate, octyl dodecyl oleate, ethyl isostearate, ethyl isostearate, and isopropyl isostearate. Propylene glycol isostearate, cetyl 2-ethylhexanoate, cetostearyl 2-ethylhexanoate, glyceryl tri-2-ethylhexanoate, glyceryl tri (caprylate / caprate), glyceryl triisopalmitate, tetra-2-ethylhexanoate Pentaerythritol, diisopropyl adipate, isocetyl octanoate, isostearyl octanoate, isosetyl isostearate, octyl isostearate Sill, dimethyl octanoic acid octyldodecyl, isononyl isononanoate, tetra octanoate pentaerythrityl tetra isostearate pentaerythritol and the like.
上記シリコーン油としては、例えば、メチルポリシロキサン、高重合メチルポリシロキサン、メチルフェニルポリシロキサン、メチルハイドロジェンポリシロキサン等のストレートシリコーン油;オクタメチルトリシロキサン、デカメチルテトラシロキサン、オクタメチルシクロテトラシロキサン、デカメチルシクロペンタシロキサン、ドデカメチルシクロヘキサシロキサン、メチルシクロポリシロキサン等の環状シリコーン油;アルコール変性シリコーン、アルキル変性シリコーン、アミノ変性シリコーン、エポキシ変性シリコーン等の変性シリコーン油等が挙げられる。 Examples of the silicone oil include straight silicone oils such as methylpolysiloxane, highly polymerized methylpolysiloxane, methylphenylpolysiloxane, and methylhydrogenpolysiloxane; octamethyltrisiloxane, decamethyltetrasiloxane, octamethylcyclotetrasiloxane, Cyclic silicone oils such as decamethylcyclopentasiloxane, dodecamethylcyclohexasiloxane, and methylcyclopolysiloxane; and modified silicone oils such as alcohol-modified silicone, alkyl-modified silicone, amino-modified silicone, and epoxy-modified silicone.
本発明の整髪剤組成物中の成分(A)の含有量は、特に限定されないが、本発明の整髪剤組成物100質量%に対して、0.5〜20.0質量%が好ましく、より好ましくは2.0〜10.0質量%、さらに好ましくは2.0〜7.0質量%である。成分(A)の含有量が0.5質量%以上であると、整髪時ののびのよさがより優れる。成分(A)の含有量が20.0質量%以下であると、本発明の整髪剤組成物の安定性、カール保持性、及びカールの強さがより優れる。上記成分(A)の含有量は、本発明の整髪剤組成物中の全ての成分(A)の合計の含有量である。 The content of the component (A) in the hairdressing composition of the present invention is not particularly limited, but is preferably 0.5 to 20.0% by mass relative to 100% by mass of the hairdressing composition of the present invention. Preferably it is 2.0 to 10.0% by mass, more preferably 2.0 to 7.0% by mass. When the content of the component (A) is 0.5% by mass or more, stretchability during hair styling is more excellent. When the content of the component (A) is 20.0% by mass or less, the stability, curl retention, and curl strength of the hairdressing composition of the present invention are more excellent. The content of the component (A) is the total content of all the components (A) in the hairdressing composition of the present invention.
[成分(B)]
成分(B)は、キサンタンガムである。本発明の整髪剤組成物は、成分(C)に加えて成分(B)を含むことにより、整髪剤組成物の安定性に優れる。加えて、整髪時ののびのよさ、カール再現性、カールの強さ、及びカール保持性に優れる。成分(B)は、1種のみを用いてもよく、2種以上を用いてもよい。[Component (B)]
Component (B) is xanthan gum. The hairdressing composition of the present invention contains the component (B) in addition to the component (C), whereby the hairdressing composition is excellent in stability. In addition, it has excellent stretchability, curl reproducibility, curl strength, and curl retention during hair styling. As the component (B), only one type may be used, or two or more types may be used.
本発明の整髪剤組成物中の成分(B)の含有量は、特に限定されないが、本発明の整髪剤組成物100質量%に対して、0.01〜1.0質量%が好ましく、より好ましくは0.02〜0.5質量%、さらに好ましくは0.02〜0.2質量%である。成分(B)の含有量が0.01質量%以上であると、整髪剤組成物の安定性、整髪時ののびのよさ、カール再現性、カールの強さ、及びカール保持性がより優れる。成分(B)の含有量が1.0質量%以下であると、整髪剤組成物の安定性及び整髪時ののびのよさがより優れる。また、べたつきがより抑制される。上記成分(B)の含有量は、本発明の整髪剤組成物中の全ての成分(B)の合計の含有量である。 The content of the component (B) in the hair styling composition of the present invention is not particularly limited, but is preferably 0.01 to 1.0% by mass relative to 100% by mass of the hair styling composition of the present invention. Preferably it is 0.02-0.5 mass%, More preferably, it is 0.02-0.2 mass%. When the content of the component (B) is 0.01% by mass or more, the stability of the hair styling composition, good spreadability at the time of hair styling, curl reproducibility, curl strength, and curl retention are more excellent. When the content of the component (B) is 1.0% by mass or less, the stability of the hair styling composition and the stretchability during hair styling are more excellent. In addition, stickiness is further suppressed. The content of the component (B) is the total content of all the components (B) in the hairdressing composition of the present invention.
[成分(C)]
成分(C)は、アクリル酸系増粘剤である。本発明の整髪剤組成物は、成分(C)を含むことにより、整髪剤組成物の安定性に優れる。成分(C)は、1種のみを用いてもよく、2種以上を用いてもよい。[Component (C)]
Component (C) is an acrylic acid-based thickener. The hair styling composition of the present invention is excellent in stability of the hair styling composition by containing the component (C). As the component (C), only one type may be used, or two or more types may be used.
成分(C)は、特に限定されないが、(メタ)アクリル酸モノマー及び/又は(メタ)アクリル酸アルキルモノマーを必須の構成成分として形成されたコポリマー及びクロスポリマーである。具体的には、例えば、カルボキシビニルポリマー;(メタ)アクリル酸アルキルコポリマー;アクリル酸・メタクリル酸アルキルコポリマー;アクリレーツ/メタクリル酸ポリオキシエチレン(20)セチルエーテルコポリマー、アクリレーツ/メタクリル酸ポリオキシエチレン(20)ステアリルエーテルコポリマー、アクリレーツ/メタクリル酸ポリオキシエチレン(25)べへニルエーテルコポリマー等の(メタ)アクリル酸/(メタ)アクリル酸アルキル/(メタ)アクリル酸ポリオキシエチレンアルキルエーテルコポリマー;アクリレーツ/イタコン酸ポリオキシエチレン(20)セチルエーテルコポリマー、アクリレーツ/イタコン酸ポリオキシエチレン(20)ステアリルエーテルコポリマー等の(メタ)アクリル酸/(メタ)アクリル酸アルキル/イタコン酸ポリオキシエチレンアルキルエーテルコポリマー;アクリレーツ/メタクリル酸ポリオキシエチレン(20)ステアリルエーテルクロスポリマー、アクリレーツ/メタクリル酸ポリオキシエチレン(25)べへニルエーテルクロスポリマー等の(メタ)アクリル酸/(メタ)アクリル酸アルキル/(メタ)アクリル酸ポリオキシエチレンアルキルエーテルクロスポリマー;アクリレーツ/ネオデカン酸ビニルクロスポリマー;(アクリロイルジメチルタウリンアンモニウム/VP)コポリマー;(N−ビニルピロリドン−N、N−ジメチルアミノエチルメタクリレート)クロスポリマー(ポリアクリレート−1)等が挙げられる。なお、括弧内の数値は、酸化エチレンの平均付加モル数を表す。 The component (C) is not particularly limited, but is a copolymer or a crosspolymer formed by using a (meth) acrylic acid monomer and / or an alkyl (meth) acrylate monomer as an essential component. Specifically, for example, carboxyvinyl polymer; alkyl (meth) acrylate copolymer; acrylic acid / alkyl methacrylate copolymer; acrylates / polyoxyethylene methacrylate (20) cetyl ether copolymer, acrylates / polyoxyethylene methacrylate (20 ) Stearyl ether copolymers, acrylates / polyoxyethylene methacrylate (25) benzyl ether copolymers, etc. (meth) acrylic acid / alkyl (meth) acrylate / polyoxyethylene alkyl ether copolymer (meth) acrylate; acrylates / itacon (Meth) acrylic acid / (meth) such as polyoxyethylene (20) cetyl ether copolymer, acrylic acid / polyoxyethylene (20) stearyl ether itaconate copolymer, etc. (Meth) acrylic such as alkyl acrylate / polyoxyethylene alkyl ether itaconate copolymer; acrylates / polyoxyethylene methacrylate (20) stearyl ether crosspolymer, acrylates / polyoxyethylene methacrylate (25) benzyl ether crosspolymer, etc. Acid / alkyl (meth) acrylate / polyoxyethylene alkyl ether (meth) acrylate crosspolymer; Acrylates / vinyl neodecanoate crosspolymer; (acryloyldimethyl taurate ammonium / VP) copolymer; (N-vinylpyrrolidone-N, N- Dimethylaminoethyl methacrylate) crosspolymer (polyacrylate-1). The numbers in parentheses represent the average number of moles of ethylene oxide added.
カルボキシビニルポリマーは、アルキル変性カルボキシビニルポリマーであってもよい。カルボキシビニルポリマーは、主としてアクリル酸の重合体であるものをいい、アルキル変性カルボキシビニルポリマーは、主としてアクリル酸とメタクリル酸アルキル(例えば、総炭素数が10〜30(C10〜C30))の共重合体であるものをいう。上記カルボキシビニルポリマーとしては、特に限定されないが、INCI名で「CARBOMER(カルボマー)」と表記される化合物が挙げられる。上記アルキル変性カルボキシビニルポリマーとしては、特に限定されないが、INCI名で「ACRYLATES/C10−30 ALKYL ACRYLATE CROSSPOLYMER((アクリレーツ/アクリル酸アルキル(C10−30))クロスポリマー)」と表記される化合物が挙げられる。 The carboxyvinyl polymer may be an alkyl-modified carboxyvinyl polymer. The carboxyvinyl polymer is mainly a polymer of acrylic acid, and the alkyl-modified carboxyvinyl polymer is mainly a copolymer of acrylic acid and alkyl methacrylate (for example, having a total carbon number of 10 to 30 (C10 to C30)). It refers to what is united. Although it does not specifically limit as said carboxyvinyl polymer, The compound described by INCI name as "CARBOMER (carbomer)" is mentioned. Examples of the alkyl-modified carboxyvinyl polymer include, but are not particularly limited to, compounds represented by the INCI name "ACRYLATES / C10-30 ALKYL ACRYLATE CROSSPOLYMER ((acrylates / alkyl acrylate (C10-30)) crosspolymer)". Can be
成分(C)としては、中でも、整髪剤組成物の安定性がより優れる観点から、カルボキシビニルポリマー、アルキル変性カルボキシビニルポリマーが好ましい。 As the component (C), a carboxyvinyl polymer and an alkyl-modified carboxyvinyl polymer are preferable, from the viewpoint of more excellent stability of the hairdressing composition.
上記カルボキシビニルポリマーの市販品としては、例えば、商品名「Carbopol 934 Polymer」、商品名「Carbopol 940 Polymer」、商品名「Carbopol 941 Polymer」、商品名「Carbopol 980 Polymer」、商品名「Carbopol 981 Polymer」、商品名「Carbopol 1342 Polymer」、商品名「Carbopol 2984 Polymer」、商品名「Carbopol Ultrez 10 Polymer」、商品名「Carbopol ETD 2050 Polymer」(以上、Lubrizol Advanced Materials社製)、商品名「AQUPEC HV−501」、商品名「AQUPEC HV−504」、商品名「AQUPEC HV−505」(以上、住友精化株式会社製)、商品名「ハイビスワコー104」、商品名「ハイビスワコー105」(以上、和光純薬工業株式会社製)等が挙げられる。上記アルキル変性カルボキシビニルポリマーの市販品としては、例えば、商品名「PEMULEN TR−1」、商品名「PEMULEN TR−2」、商品名「Carbopol ETD 2020 Polymer」、商品名「Carbopol ULTREZ 20 Polymer」、商品名「Carbopol ULTREZ 21 Polymer」、商品名「Carbopol SC−200 Polymer」(以上、Lubrizol Advanced Materials社製)等が挙げられる。 Examples of commercially available products of the carboxyvinyl polymer include, for example, “Carbopol 934 Polymer”, trade name “Carbopol 940 Polymer”, trade name “Carbopol 941 Polymer”, trade name “Carbopol 980 Polymer”, trade name “Carbol Polymer 98” "Carbopol 1342 Polymer", trade name "Carbopol 2984 Polymer", trade name "Carbopol Ultrez 10 Polymer", trade name "Carbopol ETD 2050 Polymer" (above, manufactured by LubrizUlAIDValAdaValMedA.P.A.) -501 ", trade name" AQUAPE HV- 04 ", trade name" AQUPEC HV-505 "(above, manufactured by Sumitomo Seika Co., Ltd.), trade name" Hibiswako 104 ", trade name" Hibiswako 105 "(above, manufactured by Wako Pure Chemical Industries, Ltd.) and the like. No. Commercially available products of the alkyl-modified carboxyvinyl polymer include, for example, trade names "PEMULEN TR-1", trade name "PEMULEN TR-2", trade name "Carbopol ETD 2020 Polymer", trade name "Carbopol ULTREZ 20 Polymer", Trade name "Carbopol ULTREZ 21 Polymer" and trade name "Carbopol SC-200 Polymer" (all manufactured by Lubrizol Advanced Materials).
成分(C)は、特に限定されないが、塩基性物質で中和されているか、又は塩基性物質で中和して用いられてもよい。上記塩基性物質としては、例えば、トリエタノールアミンやモノエタノールアミン等のアルカノールアミン類、アンモニア、水酸化ナトリウムや水酸化カリウム等の無機塩基、アルギニン等の塩基性アミノ酸等が挙げられる。また、上記塩基性物質の添加量は、成分(C)及び上記塩基性物質の種類や成分(C)の使用量に応じて適宜配合すればよい。 The component (C) is not particularly limited, but may be neutralized with a basic substance, or may be used after being neutralized with a basic substance. Examples of the basic substance include alkanolamines such as triethanolamine and monoethanolamine, ammonia, inorganic bases such as sodium hydroxide and potassium hydroxide, and basic amino acids such as arginine. The amount of the basic substance to be added may be appropriately determined according to the type of the component (C) and the basic substance and the amount of the component (C) used.
本発明の整髪剤組成物中の成分(C)の含有量は、特に限定されないが、本発明の整髪剤組成物100質量%に対して、0.1〜2.0質量%が好ましく、より好ましくは0.2〜0.5質量%である。成分(C)の含有量が0.1質量%以上であると、整髪剤組成物の安定性がより優れる。成分(C)の含有量が2.0質量%以下であると、整髪時ののびのよさ、べたつきの抑制性、及び洗い落ちやすさがより優れる。上記成分(C)の含有量は、本発明の整髪剤組成物中の全ての成分(C)の合計の含有量である。 The content of the component (C) in the hair styling composition of the present invention is not particularly limited, but is preferably 0.1 to 2.0% by mass based on 100% by mass of the hair styling composition of the present invention. Preferably it is 0.2-0.5 mass%. When the content of the component (C) is 0.1% by mass or more, the stability of the hairdressing composition is more excellent. When the content of the component (C) is 2.0% by mass or less, the spreadability at the time of hair styling, the property of suppressing stickiness, and the ease of washing off are more excellent. The content of the component (C) is the total content of all the components (C) in the hairdressing composition of the present invention.
[成分(D)]
成分(D)は、カチオン性皮膜形成ポリマーである。本発明の整髪剤組成物は、成分(D)を含むことにより、整髪剤組成物の安定性を維持しつつ、カール再現性、カールの強さ、及びカール保持性に優れる。また、整髪時に引っかかりがないためのびがよく、塗布性に優れる。成分(D)は、1種のみを用いてもよく、2種以上を用いてもよい。[Component (D)]
Component (D) is a cationic film-forming polymer. By containing the component (D), the hair styling composition of the present invention is excellent in curl reproducibility, curl strength, and curl retention while maintaining the stability of the hair styling composition. In addition, the hair does not get caught at the time of hair styling and has good stretchability and is excellent in applicability. As the component (D), only one type may be used, or two or more types may be used.
成分(D)としては、例えば、ビニルピロリドン・N,N−ジメチルアミノエチルメタクリル酸共重合体ジエチル硫酸塩、ビニルピロリドン/ジメチルアミノプロピルメタクリルアミド/メタクリロイルアミノプロピルラウリルジメチルアンモニウムクロリド共重合体、(メタ)アクリル酸アルキルエステル/メタクリロイルオキシエチルトリメチルアンモニウムクロリド共重合体、メタクリル酸ブチル/メタクリル酸2−エトキシエチル/メタクリロイルオキシエチルトリメチルアンモニウムクロリド共重合体、塩化О−[2−ヒドロキシ−3−(トリメチルアンモニオ)プロピル]ヒドロキシエチルセルロース、ビニルイミダゾリウムトリクロライド/ビニルピロリドン共重合体、ヒドロキシエチルセルロース/ジメチルジアリルアンモニウムクロリド、ポリビニルピロリドン/アルキルアミノアクリレート/ビニルカプロラクタム共重合体、塩化メチルビニルイミダゾリウム・ビニルピロリドン共重合体、(ビニルピロリドン/ジメチルアミノプロピルメタクリルアミド/ラウリルジメチルアミノプロピルメタクリルアミド)共重合体等が挙げられる。 As the component (D), for example, vinylpyrrolidone / N, N-dimethylaminoethyl methacrylic acid copolymer diethyl sulfate, vinylpyrrolidone / dimethylaminopropyl methacrylamide / methacryloylaminopropyllauryl dimethylammonium chloride copolymer, ) Acrylic acid alkyl ester / methacryloyloxyethyltrimethylammonium chloride copolymer, butyl methacrylate / 2-ethoxyethyl methacrylate / methacryloyloxyethyltrimethylammonium chloride copolymer, О- [2-hydroxy-3- (trimethylammonium chloride) E) Propyl] hydroxyethyl cellulose, vinyl imidazolium trichloride / vinyl pyrrolidone copolymer, hydroxyethyl cellulose / dimethyl diallyl ammonium Um chloride, polyvinylpyrrolidone / alkylaminoacrylate / vinylcaprolactam copolymer, methylvinylimidazolium chloride / vinylpyrrolidone copolymer, (vinylpyrrolidone / dimethylaminopropylmethacrylamide / lauryldimethylaminopropylmethacrylamide) copolymer and the like. Can be
成分(D)としては、ビニルピロリドンに由来する構成単位を含むポリマー、アンモニウムクロリドを有する単量体に由来する構成単位を含むポリマーが好ましい。中でも、安定性により優れ、カール保持性(特に、塗布乾燥後に手ぐしを通した後のカール保持性)により優れる観点から、より好ましくはビニルピロリドン・N,N−ジメチルアミノエチルメタクリル酸共重合体ジエチル硫酸塩である。 As the component (D), a polymer containing a structural unit derived from vinylpyrrolidone and a polymer containing a structural unit derived from a monomer having ammonium chloride are preferable. Among them, vinylpyrrolidone / N, N-dimethylaminoethyl methacrylic acid copolymer is more preferred from the viewpoint of excellent stability and excellent curl retention (particularly, curl retention after passing through a hand after coating and drying). It is diethyl sulfate.
成分(D)としては、安定性により優れ、カール保持性(特に、整髪後に手ぐしを通した後のカール保持性)により優れる観点から、INCI名で、「POLYQUATERNIUM(ポリクオタニウム)−11」と表記される化合物が好ましい。 Ingredient (D) is referred to as "POLYQUATERNIUM (polyquaternium) -11" under the INCI name from the viewpoint of superior stability and curl retention (particularly curl retention after passing through a handgear after hair styling). Are preferred.
ポリクオタニウム−11の市販品としては、例えば、商品名「H.C.ポリマー1N」、商品名「H.C.ポリマーGMR」(以上、大阪有機工業株式会社製)、商品名「Gafquat 440」、商品名「Gafquat 755N」(以上、Ashland社製)等が挙げられる。 Examples of commercially available products of polyquaternium-11 include, for example, “HC Polymer 1N” (trade name), “HC Polymer GMR” (trade name, manufactured by Osaka Organic Industry Co., Ltd.), “Gafquat 440”, Trade name “Gafquat 755N” (all manufactured by Ashland) and the like.
本発明の整髪剤組成物中の成分(D)の含有量は、特に限定されないが、本発明の整髪剤組成物100質量%に対して、0.2〜3.0質量%が好ましく、より好ましくは0.5〜2.0質量%である。成分(D)の含有量が0.2質量%以上であると、整髪時ののびのよさ、カール再現性及びカール保持性(特に、カール保持性)がより優れる。成分(D)の含有量が3.0質量%以下であると、整髪剤組成物の安定性がより優れる。また、塗布後の毛髪の手触りやべたつきの抑制性等の使用感がより優れる。上記成分(D)の含有量は、本発明の整髪剤組成物中の全ての成分(D)の合計の含有量である。 The content of the component (D) in the hairdressing composition of the present invention is not particularly limited, but is preferably 0.2 to 3.0% by mass based on 100% by mass of the hairdressing composition of the present invention. Preferably it is 0.5-2.0 mass%. When the content of the component (D) is 0.2% by mass or more, stretchability, curl reproducibility, and curl retention (particularly, curl retention) at the time of hair styling are more excellent. When the content of the component (D) is 3.0% by mass or less, the stability of the hairdressing composition is more excellent. In addition, the feeling of use such as the feel of the hair after application and the property of suppressing stickiness are more excellent. The content of the component (D) is the total content of all the components (D) in the hairdressing composition of the present invention.
[水]
本発明の整髪剤組成物は水を含む。上記水は、特に限定されないが、精製水が好ましい。本発明の整髪剤組成物中の水の含有量は、特に限定されないが、本発明の整髪剤組成物100質量%に対して、45.0〜90.0質量%が好ましく、より好ましくは50.0〜85.0質量%である。[water]
The hairdressing composition of the present invention contains water. The water is not particularly limited, but purified water is preferable. The content of water in the hairdressing composition of the present invention is not particularly limited, but is preferably 45.0 to 90.0% by mass, more preferably 50% by mass, relative to 100% by mass of the hairdressing composition of the present invention. 0.0 to 85.0% by mass.
[成分(E)]
本発明の整髪剤組成物は、さらに、ポリオキシプロピレンソルビット(「成分(E)」と称する場合がある)を含むことが好ましい。本発明の整髪剤組成物が成分(E)を含む場合、整髪剤組成物の塗布時ののび、カール再現性、及びカール保持性がより優れる。成分(E)は、1種のみを用いてもよいし、2種以上を用いてもよい。[Component (E)]
The hairdressing composition of the present invention preferably further contains polyoxypropylene sorbite (sometimes referred to as “component (E)”). When the hair styling composition of the present invention contains the component (E), the hair styling composition has more excellent spreadability, curl reproducibility and curl retention at the time of application. As the component (E), only one type may be used, or two or more types may be used.
成分(E)の数平均分子量は、特に限定されないが、300〜1000が好ましく、より好ましくは400〜800である。成分(E)の数平均分子量が300以上であると、カール再現性及びカール保持性がより優れる。成分(E)の数平均分子量が1000以下であると、整髪剤組成物の塗布時ののびがより優れる。 The number average molecular weight of the component (E) is not particularly limited, but is preferably from 300 to 1,000, and more preferably from 400 to 800. When the number average molecular weight of the component (E) is 300 or more, curl reproducibility and curl retention are more excellent. When the number average molecular weight of the component (E) is 1,000 or less, the spread of the hair styling composition upon application is more excellent.
成分(E)のブルックフィールド型回転粘度計を用いて30℃で測定された粘度ηは、整髪剤組成物ののびをより良くし、毛髪への塗布性をより向上させる観点から、1000〜30000mPa・sが好ましく、より好ましくは2000〜20000mPa・sである。 The viscosity η of the component (E) measured at 30 ° C. using a Brookfield-type rotational viscometer is from 1,000 to 30,000 mPa, from the viewpoint of improving the spread of the hair styling composition and improving the applicability to hair. S is preferable, and more preferably 2,000 to 20,000 mPa · s.
成分(E)の市販品としては、例えば、商品名「ニューポール SP−750」、商品名「サンニックス SP−750」(以上、三洋化成工業株式会社製)等が挙げられる。 Examples of commercially available products of the component (E) include “New Pole SP-750” (trade name) and “Sunnics SP-750” (trade name) (manufactured by Sanyo Chemical Industries, Ltd.).
本発明の整髪剤組成物が成分(E)を含有する場合、本発明の整髪剤組成物中の成分(E)の含有量は、特に限定されないが、本発明の整髪剤組成物100質量%に対して、0.3〜5.0質量%が好ましく、より好ましくは0.4〜3.0質量%である。成分(D)の含有量が0.3質量%以上であると、整髪剤組成物の塗布時ののび、カール再現性、及びカール保持性がより優れる。成分(E)の含有量が5.0質量%以下であると、整髪剤組成物の乳化安定性を高めると共に、塗布後のべたつきをより抑制する。上記成分(E)の含有量は、本発明の整髪剤組成物中の全ての成分(E)の合計の含有量である。 When the hair styling composition of the present invention contains the component (E), the content of the component (E) in the hair styling composition of the present invention is not particularly limited, but 100% by mass of the hair styling composition of the present invention. Is preferably 0.3 to 5.0% by mass, more preferably 0.4 to 3.0% by mass. When the content of the component (D) is 0.3% by mass or more, the spread of the hair styling composition, curl reproducibility, and curl retention are more excellent. When the content of the component (E) is 5.0% by mass or less, the emulsification stability of the hair styling composition is increased, and the stickiness after application is further suppressed. The content of the component (E) is the total content of all the components (E) in the hairdressing composition of the present invention.
[その他の成分]
本発明の整髪剤組成物は、本発明の効果を損なわない範囲内で、成分(A)〜(E)及び水以外の成分(その他の成分)を含んでいてもよい。上記その他の成分しては、特に限定されず、例えば、化粧品や医薬部外品に通常用いられる成分等が挙げられる。具体的には、例えば、成分(A)以外の油剤、界面活性剤(カチオン性界面活性剤、アニオン性界面活性剤、ノニオン性界面活性剤、両性界面活性剤等);エタノール等の低級アルコール;粉体;エチレングリコール、ジエチレングリコール、トリエチレングリコール、ポリエチレングリコール、プロピレングリコール、ジプロピレングリコール、ポリプロピレングリコール、イソプレングリコール、1,3−ブチレングリコール、1,2−ブタンジオール、1,2−ペンタンジオール、1,2−ヘキサンジオール、1,2−オクタンジオール、1,2−デカンジオール、グリセリン、ジグリセリン、ポリグリセリン等の多価アルコール;ヒドロキシメチルセルロース、ヒドロキシプロピルメチルセルロース等の成分(B)及び(C)以外の増粘剤;ソルビトール、マルチトール等の糖アルコール;ヒアルロン酸、コラーゲン、パントテニルアルコール等の保湿剤;メチルパラベン、プロピルパラベン、ブチルパラベン、安息香酸塩等の防腐剤;リン酸及びその塩類、クエン酸及びその塩類、乳酸及びその塩類、水酸化ナトリウム、トリエタノールアミン等のpH調整剤;香料;紫外線吸収剤;酸化防止剤;金属イオン封鎖剤(キレート剤);成分(D)以外の皮膜形成性高分子化合物;粉体;色素;顔料;ビタミン類;アミノ酸類;収斂剤;美白剤;動植物抽出物;酸;アルカリ等が挙げられる。上記その他の成分は、1種のみを用いてもよいし、2種以上を用いてもよい。なお、成分(A)以外の油剤、成分(B)及び(C)以外の増粘剤、並びに成分(D)以外の皮膜形成性高分子化合物は、それぞれ、実質的に含有しないこと(例えば、本発明の整髪剤組成物100質量%に対してそれぞれ、0.05質量%以下、特に0.01質量%以下)が好ましい。また、低級アルコールの含有量は、べたつきの抑制性及び塗布性により優れる観点から、本発明の整髪剤組成物100質量%に対して、10質量%以下であることが好ましい。[Other ingredients]
The hairdressing composition of the present invention may contain components (A) to (E) and components (other components) other than water as long as the effects of the present invention are not impaired. The other components are not particularly limited, and include, for example, components commonly used in cosmetics and quasi-drugs. Specifically, for example, oils other than component (A), surfactants (cationic surfactant, anionic surfactant, nonionic surfactant, amphoteric surfactant, etc.); lower alcohols such as ethanol; Powder; ethylene glycol, diethylene glycol, triethylene glycol, polyethylene glycol, propylene glycol, dipropylene glycol, polypropylene glycol, isoprene glycol, 1,3-butylene glycol, 1,2-butanediol, 1,2-pentanediol, Polyhydric alcohols such as 1,2-hexanediol, 1,2-octanediol, 1,2-decanediol, glycerin, diglycerin and polyglycerin; other than components (B) and (C) such as hydroxymethylcellulose and hydroxypropylmethylcellulose of Viscosity agents; sugar alcohols such as sorbitol and maltitol; humectants such as hyaluronic acid, collagen, pantothenyl alcohol; preservatives such as methylparaben, propylparaben, butylparaben, benzoate; phosphoric acid and salts thereof, citric acid and PH adjusters such as salts thereof, lactic acid and salts thereof, sodium hydroxide, triethanolamine, etc .; fragrances; ultraviolet absorbers; antioxidants; sequestering agents (chelating agents); high film-forming properties other than component (D) Molecular compounds; powders; pigments; pigments; vitamins; amino acids; astringents; whitening agents; As the other components, only one kind may be used, or two or more kinds may be used. The oil agent other than the component (A), the thickener other than the components (B) and (C), and the film-forming polymer compound other than the component (D) are each substantially free from (for example, 0.05% by mass or less, particularly preferably 0.01% by mass or less, based on 100% by mass of the hairdressing composition of the present invention. Further, the content of the lower alcohol is preferably 10% by mass or less based on 100% by mass of the hair styling composition of the present invention, from the viewpoint of suppressing stickiness and improving coatability.
本発明の整髪剤組成物は、特に限定されないが、本発明の整髪剤組成物を乳化剤型にする観点から、界面活性剤を含有することが好ましい。中でも、ノニオン性界面活性剤が好ましい。上記界面活性剤(特に、ノニオン性界面活性剤)は、1種のみを用いてもよいし、2種以上を用いてもよい。 The hair styling composition of the present invention is not particularly limited, but preferably contains a surfactant from the viewpoint of converting the hair styling composition of the present invention into an emulsifier type. Among them, a nonionic surfactant is preferable. As the surfactant (particularly, a nonionic surfactant), only one kind may be used, or two or more kinds may be used.
上記ノニオン性界面活性剤としては、特に限定されないが、例えば、ソルビタン脂肪酸エステル、グリセリン脂肪酸エステル、及びこれらのアルキレンオキシド付加物、ポリオキシアルキレンアルキルエーテル、ポリオキシアルキレン脂肪酸エステル、ポリオキシアルキレンアルキルフェノール、ポリオキシエチレンソルビット脂肪酸エステル、ポリオキシエチレンアルキルフェニルホルムアルデヒド縮合物、ポリオキシエチレンステロール及びその誘導体、ポリオキシエチレンラノリン及びその誘導体、ポリオキシエチレンミツロウ誘導体、シュガーエステル類、ポリオキシエチレン硬化ヒマシ油、ポリオキシエチレンヒマシ油等が挙げられる。 The nonionic surfactant is not particularly limited, for example, sorbitan fatty acid ester, glycerin fatty acid ester, and their alkylene oxide adducts, polyoxyalkylene alkyl ether, polyoxyalkylene fatty acid ester, polyoxyalkylene alkyl phenol, polyoxyalkylene Oxyethylene sorbite fatty acid ester, polyoxyethylene alkylphenyl formaldehyde condensate, polyoxyethylene sterol and its derivatives, polyoxyethylene lanolin and its derivatives, polyoxyethylene beeswax derivatives, sugar esters, polyoxyethylene hydrogenated castor oil, polyoxy And ethylene castor oil.
ソルビタン脂肪酸エステルとしては、例えば、モノオレイン酸ソルビタン、モノステアリン酸ソルビタン、モノイソステアリン酸ソルビタン、モノパルミチン酸ソルビタン、モノラウリン酸ソルビタン、トリオレイン酸ソルビタン、トリステアリン酸ソルビタン、セスキステアリン酸ソルビタン、セスキオレイン酸ソルビタン、セスキイソステアリン酸ソルビタン、ヤシ油脂肪酸ソルビタン等が挙げられる。また、ソルビタン脂肪酸エステルのアルキレンオキシド付加物としては、モノラウリン酸ポリオキシエチレンソルビタン、モノパルミチン酸ポリオキシエチレンソルビタン、モノステアリン酸ポリオキシエチレンソルビタン、モノオレイン酸ポリオキシエチレンソルビタン、モノイソステアリン酸ポリオキシエチレンソルビタン、モノヤシ油脂肪酸ポリオキシエチレンソルビタン、トリステアリン酸ポリオキシエチレンソルビタン、トリオレイン酸ポリオキシエチレンソルビタン等が挙げられる。 Examples of sorbitan fatty acid esters include sorbitan monooleate, sorbitan monostearate, sorbitan monoisostearate, sorbitan monopalmitate, sorbitan monolaurate, sorbitan trioleate, sorbitan tristearate, sorbitan sesquistearate, sesquioleate Sorbitan, sorbitan sesquiisostearate, sorbitan coconut oil fatty acid, and the like. Examples of alkylene oxide adducts of sorbitan fatty acid esters include polyoxyethylene sorbitan monolaurate, polyoxyethylene sorbitan monopalmitate, polyoxyethylene sorbitan monostearate, polyoxyethylene sorbitan monooleate, and polyoxyethylene monoisostearate. Sorbitan, mono-coconut oil fatty acid polyoxyethylene sorbitan, polyoxyethylene sorbitan tristearate, polyoxyethylene sorbitan trioleate, and the like.
グリセリン脂肪酸エステルは、モノグリセリン脂肪酸エステル及びポリグリセリン脂肪酸エステルのいずれも含む。モノグリセリン脂肪酸エステルとしては、例えば、モノカプリル酸グリセリル、モノカプリン酸グリセリル、モノラウリン酸グリセリル、モノミリスチン酸グリセリル、モノパルミチン酸グリセリル、モノステアリン酸グリセリル、モノイソステアリン酸グリセリル、モノベヘン酸グリセリル、モノオレイン酸グリセリル、モノエルカ酸グリセリル、セスキオレイン酸グリセリル、ジステアリン酸グリセリル、ジイソステアリン酸グリセリル、ジアラキン酸グリセリル等が挙げられる。上記ポリグリセリン脂肪酸エステルとしては、例えば、モノカプリル酸ジグリセリル、モノカプリル酸デカグリセリル、モノカプリン酸ヘキサグリセリル、モノラウリン酸テトラグリセリル、モノラウリン酸ヘキサグリセリル、モノラウリン酸デカグリセリル、モノラウリン酸ポリ(4〜10)グリセリル、モノミリスチン酸デカグリセリル、モノステアリン酸デカグリセリル、モノイソステアリン酸デカグリセリル、モノステアリン酸ポリ(2〜10)グリセリル、モノオレイン酸ジグリセリル、モノオレイン酸ヘキサグリセリル、セスキオレイン酸ジグリセリル、ジイソステアリン酸ポリ(2〜10)グリセリル、ジステアリン酸ポリ(6〜10)グリセリル、トリイソステアリン酸ジグリセリル、トリステアリン酸ポリ(10)グリセリル等の上記モノグリセリン脂肪酸エステルの重合度2〜10のポリグリセリン脂肪酸エステル等が挙げられる。また、グリセリン脂肪酸エステルのアルキレンオキシド付加物としては、モノステアリン酸ポリオキシエチレングリセリル、モノオレイン酸ポリオキシエチレングリセリル等が挙げられる。 Glycerin fatty acid esters include both monoglycerin fatty acid esters and polyglycerin fatty acid esters. Examples of the monoglycerin fatty acid ester include glyceryl monocaprylate, glyceryl monocaprate, glyceryl monolaurate, glyceryl monomyristate, glyceryl monopalmitate, glyceryl monostearate, glyceryl monoisostearate, glyceryl monobehenate, and monooleic acid. Glyceryl, glyceryl monoerucate, glyceryl sesquioleate, glyceryl distearate, glyceryl diisostearate, glyceryl diarachiate and the like can be mentioned. Examples of the polyglycerin fatty acid ester include diglyceryl monocaprylate, decaglyceryl monocaprylate, hexaglyceryl monocaprate, tetraglyceryl monolaurate, hexaglyceryl monolaurate, decaglyceryl monolaurate, polylaurate mono (4-10) ) Glyceryl, decaglyceryl monomyristate, decaglyceryl monostearate, decaglyceryl monoisostearate, poly (2-10) glyceryl monostearate, diglyceryl monooleate, hexaglyceryl monooleate, diglyceryl sesquioleate, Poly (2-10) glyceryl diisostearate, poly (6-10) glyceryl distearate, diglyceryl triisostearate, poly (10) glyceryl tristearate Polyglycerol fatty acid esters having a degree of polymerization of 2 to 10 of the monoglycerol fatty acid esters such as Le like. Examples of the alkylene oxide adduct of glycerin fatty acid ester include polyoxyethylene glyceryl monostearate and polyoxyethylene glyceryl monooleate.
ポリオキシアルキレンアルキルエーテルとしては、例えば、ポリオキシエチレンラウリルエーテル、ポリオキシエチレンセチルエーテル、ポリオキシエチレンステアリルエーテル、ポリオキシエチレンオレイルエーテル、ポリオキシエチレンポリオキシプロピレンラウリルエーテル、ポリオキシプロピレンセチルエーテル、ポリオキシプロピレンイソセチルエーテル、ポリオキシプロピレンステアリルエーテル、ポリオキシプロピレンオレイルエーテル等が挙げられる。 As the polyoxyalkylene alkyl ether, for example, polyoxyethylene lauryl ether, polyoxyethylene cetyl ether, polyoxyethylene stearyl ether, polyoxyethylene oleyl ether, polyoxyethylene polyoxypropylene lauryl ether, polyoxypropylene cetyl ether, polyoxyethylene Oxypropylene isocetyl ether, polyoxypropylene stearyl ether, polyoxypropylene oleyl ether and the like can be mentioned.
ポリオキシアルキレン脂肪酸エステルとしては、例えば、モノオレイン酸ポリエチレングリコール、モノステアリン酸ポリエチレングリコール、ジステアリン酸ポリエチレングリコール、モノラウリン酸ポリエチレングリコール等のポリエチレングリコール脂肪酸エステル;モノステアリン酸プロピレングリコール、モノラウリン酸プロピレングリコール、モノオレイン酸プロピレングリコール等のプロピレングリコール脂肪酸エステル等が挙げられる。 Polyoxyalkylene fatty acid esters include, for example, polyethylene glycol fatty acid esters such as polyethylene glycol monooleate, polyethylene glycol monostearate, polyethylene glycol distearate and polyethylene glycol monolaurate; propylene glycol monostearate, propylene glycol monolaurate, And propylene glycol fatty acid esters such as propylene glycol oleate.
本発明の整髪剤組成物が界面活性剤を含有する場合、本発明の整髪剤組成物中の界面活性剤(特に、ノニオン性界面活性剤)の含有量は、特に限定されないが、整髪剤組成物の安定性の観点から、本発明の整髪剤組成物100質量%に対して、2.0〜6.0質量%が好ましく、より好ましくは2.5〜5.0質量%である。上記界面活性剤の含有量は、本発明の整髪剤組成物中の全ての界面活性剤の合計の含有量である。 When the hair styling composition of the present invention contains a surfactant, the content of the surfactant (especially, a nonionic surfactant) in the hair styling composition of the present invention is not particularly limited. From the viewpoint of the stability of the product, the content is preferably 2.0 to 6.0% by mass, more preferably 2.5 to 5.0% by mass, based on 100% by mass of the hairdressing composition of the present invention. The content of the surfactant is the total content of all the surfactants in the hairdressing composition of the present invention.
上記粉体としては、例えば、シリカ、タルク、マイカ、炭酸カルシウム、炭酸マグネシウム、ヒドロキシアパタイト、酸化チタン、酸化亜鉛、ケイ酸カルシウム、ケイ酸マグネシウム、ケイ酸アルミニウム、水酸化マグネシウム等が挙げられる。本発明の整髪剤組成物が粉体を含むと、べたつきがより抑制され、さらに、整髪後の仕上がりが軽い仕上がりとなる。上記粉体としては、中でも、べたつきの抑制性により優れ、整髪力を有する観点から、シリカ、ケイ酸マグネシウム、水酸化マグネシウムが好ましい。上記シリカは、疎水化処理されていない無水ケイ酸(親水性のシリカ)であってもよいし、疎水化無水ケイ酸であってもよい。また、上記シリカは、アミノ酸、エステル、レシチン等で表面処理されたシリカであってもよい。また、上記シリカは、所謂、易崩壊性シリカ粒子であってもよい。上記粉体は、1種のみを用いてもよいし、2種以上を用いてもよい。 Examples of the powder include silica, talc, mica, calcium carbonate, magnesium carbonate, hydroxyapatite, titanium oxide, zinc oxide, calcium silicate, magnesium silicate, aluminum silicate, magnesium hydroxide and the like. When the hair styling composition of the present invention contains powder, stickiness is further suppressed, and the finish after hair styling becomes a light finish. Among these powders, silica, magnesium silicate, and magnesium hydroxide are preferable, from the viewpoint of excellent tackiness and hair styling. The silica may be silicic anhydride that has not been subjected to hydrophobic treatment (hydrophilic silica) or may be hydrophobic silicic anhydride. Further, the silica may be a silica surface-treated with an amino acid, an ester, a lecithin or the like. Further, the silica may be so-called easily collapsible silica particles. As the powder, only one kind may be used, or two or more kinds may be used.
本発明の整髪剤組成物は、25℃で固形状であり、且つ、炭化水素油、ロウ類、及び油脂からなる群より選ばれた油剤を実質的に含有しないことが好ましい。なお、本明細書において、「25℃で固形状」とは、例えば、半径2cm、高さ7cmのガラスボトルに50gの試料(油剤)を加熱溶解して流し込み、25℃まで冷却した後、上記ガラスボトルを逆さにした場合に、逆さにした直後より5分間、試料がガラスボトルから垂れ落ちないことを意味する。以下、上記「25℃で固形状であり、且つ、炭化水素油、ロウ類、及び油脂からなる群より選ばれた油剤」を、「25℃で固形状の特定油剤」と称する場合がある。上記25℃で固形状の特定油剤としては、例えば、カルナウバロウ、キャンデリラロウ、ミツロウ、コメヌカロウ、セラックロウ、鯨ロウ、ラノリン、セレシン、パラフィン、マイクロクリスタリンワックス、ポリエチレン末、ポリエチレンワックス、ワセリン、硬化ヒマシ油、モクロウ等が挙げられる。 It is preferable that the hairdressing composition of the present invention is solid at 25 ° C. and does not substantially contain an oil selected from the group consisting of hydrocarbon oils, waxes, and fats and oils. In the present specification, “solid at 25 ° C.” means, for example, 50 g of a sample (oil) is heated and melted and poured into a glass bottle having a radius of 2 cm and a height of 7 cm. When the glass bottle is inverted, it means that the sample does not hang down from the glass bottle for 5 minutes immediately after the inversion. Hereinafter, the above “oil agent that is solid at 25 ° C. and is selected from the group consisting of hydrocarbon oils, waxes, and fats and oils” may be referred to as “specific oil agent that is solid at 25 ° C.”. Specific oils which are solid at 25 ° C. include, for example, carnauba wax, candelilla wax, beeswax, rice bran wax, shellac wax, spermaceti, lanolin, ceresin, paraffin, microcrystalline wax, polyethylene powder, polyethylene wax, petrolatum, hydrogenated castor oil And mokuro.
なお、本明細書において、「実質的に含有しない」とは、「能動的に含有させることはしない」という意味であり、他の配合成分中に含まれる微量の該当成分が不可避的に含まれることまでを除外するものではない。より具体的には、例えば、本発明の整髪剤組成物中の25℃で固形状の特定油剤(特に、上記に例示した25℃で固形状の特定油剤)の含有量は、本発明の整髪剤組成物100質量%に対して、0.05質量%以下(即ち、0〜.05質量%)であることが好ましく、より好ましくは0.01質量%以下である。整髪剤組成物が25℃で固形状の特定油剤を実質的に含有しない場合、整髪時の整髪剤組成物ののびがより優れ、整髪後の毛髪のべたつきをより抑制することができる。 In the present specification, “substantially not contained” means “not actively contained”, and a trace amount of the corresponding component contained in other compounding components is inevitably contained. It does not exclude things. More specifically, for example, the content of the specific oil agent that is solid at 25 ° C. (particularly, the specific oil agent that is solid at 25 ° C. as exemplified above) in the hairdressing composition of the present invention, The amount is preferably 0.05% by mass or less (that is, 0 to 0.05% by mass) with respect to 100% by mass of the agent composition, and more preferably 0.01% by mass or less. When the hair styling composition does not substantially contain the specific oil at 25 ° C., the hair styling composition at the time of hair styling is more excellent in spreadability, and the stickiness of the hair after the hair styling can be further suppressed.
本発明の整髪剤組成物の剤型は、特に限定されないが、例えば、乳液、クリーム等が挙げられる。中でも、流動性を有する乳液が好ましい。本発明の整髪剤組成物は、乳化した組成物である。乳化組成物であることにより、塗布時にみずみずしい感触を付与することができる。 The dosage form of the hairdressing composition of the present invention is not particularly limited, and examples thereof include an emulsion and a cream. Among them, an emulsion having fluidity is preferred. The hairdressing composition of the present invention is an emulsified composition. By being an emulsion composition, a fresh feeling can be imparted at the time of application.
本発明の整髪剤組成物の25℃における粘度は、特に限定されないが、塗布性、髪へのなじみの良さの観点から、500〜100000mPa・sが好ましく、より好ましくは1000〜30000mPa・sである。上記粘度は、例えば、粘度計を用いて、No.4ローターを使用して回転速度6rpm、回転時間1分間の条件で測定される。上記粘度計としては、東機産業株式会社製、TV−22型粘度計を使用することができる。 The viscosity at 25 ° C. of the hairdressing composition of the present invention is not particularly limited, but is preferably 500 to 100,000 mPa · s, more preferably 1,000 to 30,000 mPa · s, from the viewpoint of applicability and good fit to hair. . For example, the above viscosity was measured using a viscometer. The measurement is performed under the conditions of a rotation speed of 6 rpm and a rotation time of 1 minute using a 4-rotor. As the viscometer, a TV-22 viscometer manufactured by Toki Sangyo Co., Ltd. can be used.
本発明の整髪剤組成物は、特に限定されず、公知乃至慣用の方法により製造することができる。例えば、本発明の整髪剤組成物は、上記の各成分を混合し、ホモミキサーを用いた順相乳化法、転相乳化法等により乳化することにより製造できる。また、混合と乳化は別々に行っても同時に行ってもよい。 The hairdressing composition of the present invention is not particularly limited, and can be produced by a known or common method. For example, the hairdressing composition of the present invention can be produced by mixing the above components and emulsifying the mixture by a normal phase emulsification method, a phase inversion emulsification method or the like using a homomixer. Mixing and emulsification may be performed separately or simultaneously.
本発明の整髪剤組成物は、水及び油剤[成分(A)]を含む整髪剤組成物であり、これにキサンタンガム[成分(B)]及びアクリル酸系増粘剤[成分(C)]を配合することで、水及び成分(A)を含む整髪剤組成物を増粘させて乳化状態を安定化している。特に、成分(C)に加えて、増粘作用を発揮する物質として成分(B)を用いることにより、安定性に加え、塗布後のカール再現性に優れ、カール保持性にも比較的優れる。さらに、剤のべたつきを抑えることができる。また、このような整髪剤組成物において、成分(A)が配合されていることにより塗布時ののびのよさに優れる。さらに、これに、数ある整髪性を付与するポリマー(セットポリマー)の中でも、カチオン性皮膜形成ポリマー[成分(D)](特に、ポリクオタニウム−11)を配合することで、整髪剤組成物の安定性を維持しつつ、皮膜形成することでカール再現性に優れる。また、乾燥状態で手ぐしを通しても引っかからず触ってもくずれにくいため、塗布時ののびのよさにより優れ、またカール保持性にも優れる。成分(D)は、通常、成分(C)がアニオン性であることから、成分(C)と組み合わせて用いる場合は塊状物を形成したり、整髪剤組成物の粘度が低下したりすることで、安定性が低下すると予測されていた。しかしながら、驚くべきことに、本発明の整髪剤組成物において成分(D)は、整髪剤組成物の安定性及び粘度を維持しながら、塗布後は比較的柔軟な皮膜を形成することができ、これによりカール再現性及びカール保持性に優れるという作用を発揮する。 The hair styling composition of the present invention is a hair styling composition containing water and an oil agent [Component (A)], and comprises a xanthan gum [Component (B)] and an acrylic acid-based thickener [Component (C)]. By blending, the hairdressing composition containing water and the component (A) is thickened to stabilize the emulsified state. In particular, by using the component (B) as a substance exhibiting a thickening effect in addition to the component (C), the curl reproducibility after application and the curl retention are relatively excellent in addition to stability. Further, stickiness of the agent can be suppressed. In addition, in such a hairdressing composition, since the component (A) is blended, it is excellent in spreadability at the time of application. Furthermore, by blending a cationic film-forming polymer [component (D)] (particularly, polyquaternium-11) among various polymers (set polymers) for imparting hair styling properties, the hair styling composition can be stabilized. Excellent curl reproducibility by forming a film while maintaining the properties. In addition, since it is hard to be broken when touched without passing through a hand glove in a dry state, it is excellent in spreadability at the time of application and excellent in curl retention. Component (D) is generally anionic, and therefore, when used in combination with component (C), forms a lump or reduces the viscosity of the hair styling composition. It was predicted that the stability would decrease. However, surprisingly, in the hairdressing composition of the present invention, the component (D) can form a relatively soft film after application while maintaining the stability and viscosity of the hairdressing composition, Thereby, an effect of being excellent in curl reproducibility and curl retention is exhibited.
また、本発明の整髪剤組成物にポリオキシプロピレンソルビット[成分(E)]を配合することにより、整髪剤組成物に粘着性を付与し、塗布時ののび、カール再現性、及びカール保持性により優れる。 In addition, by blending polyoxypropylene sorbit [component (E)] with the hair styling composition of the present invention, the hair styling composition is imparted with tackiness, and can be spread, curl reproducibility, and curl retention during application. Better.
以下に、実施例に基づいて本発明をより詳細に説明するが、本発明はこれらの実施例にのみ限定されるものではない。なお、表に記載の配合量は、各成分の配合量(すなわち、各原料中の有効成分の配合量)であり、特記しない限り「質量%」で表す。また、表中の配合量における「−」は、その成分を配合していないことを示す。 Hereinafter, the present invention will be described in more detail with reference to Examples, but the present invention is not limited to only these Examples. In addition, the compounding amount described in the table is the compounding amount of each component (that is, the compounding amount of the active ingredient in each raw material), and is represented by “% by mass” unless otherwise specified. In addition, "-" in the blending amount in the table indicates that the component is not blended.
実施例1〜7、比較例1〜8
表に記した各成分(成分(A)〜(E)、水、及びその他の成分)を用い、実施例及び比較例の各試料を常法に準じて整髪剤組成物を調製し、下記評価を行った。結果をそれぞれ表に示した。なお、安定性の評価結果が×であった整髪剤組成物についてはその他の評価を行っていない。Examples 1 to 7, Comparative Examples 1 to 8
Using each component (components (A) to (E), water, and other components) described in the table, a hairdressing composition was prepared from each sample of Examples and Comparative Examples according to a conventional method, and evaluated as follows. Was done. The results are shown in the table. In addition, other evaluations were not performed on the hair styling composition whose stability evaluation result was x.
[試験例1:安定性の評価]
実施例及び比較例で得られた各整髪剤組成物について、目視でその状態を確認し、乳化状態を下記の判定基準で判定した。
<安定性の評価基準>
○(良好):均一に混合しており、塊状物の形成や相分離が確認されない
×1(不良):分離が認められる
×2(不良):塊状物の形成が認められる[Test Example 1: Evaluation of stability]
About each hairdressing composition obtained in the Example and the comparative example, the state was confirmed visually, and the emulsified state was determined according to the following criteria.
<Evaluation criteria for stability>
((Good): homogeneously mixed, no formation of lumps or phase separation
X1 (poor): separation is observed x2 (poor): lump formation is observed
[試験例2:塗布時ののびの評価]
専門パネル10名が、上記整髪剤組成物を、パーマをかけたヘアウィッグ(レッスンマネキン:株式会社ユーカリジャパン製)の毛髪に均一に塗布した際の、毛髪上でののびのよさを回答した。上記回答から、下記の基準でのびを評価した。
<塗布時ののびの評価基準>
○(良好):10名中8名以上が、引っかかりがなくのびがよいと回答
△(使用可能):10名中5〜7名が、引っかかりがなくのびがよいと回答
×(不良):10名中4名以下が、引っかかりがなくのびがよいと回答[Test Example 2: Evaluation of spread during application]
Ten expert panels answered that the hair styling composition was spread evenly on the hair of a hair wig (lesson mannequin: manufactured by Eucalyptus Japan Co., Ltd.) with a perm applied. Based on the above answers, the following criteria were used to evaluate growth.
<Evaluation criteria for spread during application>
((Good): 8 or more of 10 persons answered that there was no snagging and good spread △ (usable): 5 to 7 persons out of 10 answered that there was no snagging and good spread × (poor): 10 4 or less of the respondents answered that they were comfortable without snagging
[試験例3:カール再現性の評価]
専門パネル10名が、試験例2と同様に整髪剤組成物を塗布したヘアウィッグの毛髪の状態について、カールの再現性のよさを回答した。上記回答から、下記の基準でカールの再現性を評価した。
<カール再現性の評価基準>
○(良好):10名中8名以上が、カールの再現性がよいと回答
△(実用可能):10名中5〜7名が、カールの再現性がよいと回答
×(不良):10名中4名以下が、カールの再現性がよいと回答[Test Example 3: Evaluation of curl reproducibility]
Ten expert panels answered the reproducibility of the curl of the hair condition of the hair wig to which the hair styling composition was applied in the same manner as in Test Example 2. Based on the above answer, the curl reproducibility was evaluated according to the following criteria.
<Evaluation criteria for curl reproducibility>
((Good): 8 or more of 10 persons answered that curl reproducibility was good △ (practical): 5 to 7 persons of 10 persons answered that curl reproducibility was good × (poor): 10 Less than 4 of the respondents said curl reproducibility was good
[試験例4:カールの強さの評価]
専門パネル10名が、試験例2と同様に整髪剤組成物を塗布したヘアウィッグの毛髪を、手のひらで軽く握って触ることで、カールの強さを回答した。上記回答から、下記の基準でカールの強さを評価した。
○(良好):10名中8名以上が、カールの強度が高いと回答
△(使用可能):10名中5〜7名が、カールの強度が高いと回答
×(不良):10名中4名以下が、カールの強度が高いと回答[Test Example 4: Evaluation of curl strength]
Ten professional panels answered the strength of the curl by lightly holding and touching the hair of the hair wig coated with the hair styling composition in the same manner as in Test Example 2. Based on the above answer, the curl strength was evaluated based on the following criteria.
((Good): 8 or more out of 10 answered that curl strength was high △ (usable): 5 to 7 out of 10 answered that curl strength was high × (bad): out of 10 Less than 4 people report high curl strength
[試験例5:乾燥後のカールの保持性(カール保持性(1))の評価]
試験例2と同様に整髪剤組成物を塗布したヘアウィッグの毛髪を、6時間室内で放置する。専門パネル10名が、その後ヘアウィッグの毛髪を、手のひらで軽く握って触ることで乾燥後のカールの保持性を回答した。上記回答から、下記の基準でカール保持性(1)を評価した。
<カール保持性(1)の評価基準>
○(良好):10名中8名以上が、カールの強度が保持されていると回答
△(使用可能):10名中5〜7名が、カールの強度が保持されていると回答
×(不良):10名中4名以下が、カールの強度が保持されていると高いと回答[Test Example 5: Evaluation of curl retention after drying (curl retention (1))]
The hair of the hair wig to which the hair styling composition has been applied in the same manner as in Test Example 2 is left indoors for 6 hours. Ten specialized panels then responded to the curl retention after drying by lightly gripping and touching the hair of the hair wig. Based on the above answer, curl retention (1) was evaluated according to the following criteria.
<Evaluation criteria for curl retention (1)>
((Good): 8 or more out of 10 persons answered that curl strength was maintained △ (usable): 5 to 7 out of 10 persons answered that curl strength was maintained × ( Poor): 4 or less out of 10 responded that curl strength was high if maintained
[試験例6:乾燥後に手ぐしを通したときのカールの保持性(カール保持性(2))の評価]
専門パネル10名が、試験例5で評価した後のヘアウィッグの毛髪に手ぐしを5回通した後、ヘアウィッグの毛髪を手のひらで軽く握って触ることで、手ぐし後のカールの保持性を回答した。上記回答から、下記の基準でカール保持性(2)を評価した。なお、試験例5においてカール保持性(1)の評価結果が×のものについては評価を行わなかった。
<カール保持性(2)の評価基準>
○(良好):10名中8名以上が、カールの強度が保持されていると回答
△(使用可能):10名中5〜7名が、カールの強度が高いと回答
×(不良):10名中4名以下が、カールの強度が高いと回答[Test Example 6: Evaluation of curl retention (curl retention (2)) when passed through a handgear after drying]
Ten expert panels passed the hand wig five times through the hair of the hair wig evaluated in Test Example 5, and then gently grasped and touched the hair of the hair wig to maintain the curl retention after the hand wig. Was answered. Based on the above answer, curl retention (2) was evaluated according to the following criteria. Note that, in Test Example 5, the evaluation result of the curl retention (1) was x, and the evaluation was not performed.
<Evaluation criteria for curl retention (2)>
((Good): 8 or more of 10 persons answered that curl strength was maintained △ (usable): 5 to 7 out of 10 persons answered that curl strength was high × (poor): Less than 4 out of 10 responded that curl strength was high
本発明の整髪剤組成物(実施例)は、安定性、塗布時ののびのよさ、カール再現性、及びカール保持性に優れていた。一方、成分(A)を含まない場合(比較例1)、塗布時ののびのよさに劣っていた。成分(C)を含まない場合(比較例2)、安定性試験において分離が認められた。成分(D)を含まない場合(比較例3)、カール保持性に劣っていた。成分(B)の代わりにカラギーナンを用いた場合(比較例4)、カール再現性に劣っていた。成分(D)の代わりに他の皮膜形成ポリマーを用いた場合(比較例5〜8)、塗布時ののびのよさ及び乾燥後に手ぐしを通したときのカールの保持性に劣っていた。 The hairdressing composition of the present invention (Example) was excellent in stability, spreadability upon application, curl reproducibility, and curl retention. On the other hand, when component (A) was not contained (Comparative Example 1), the spreadability at the time of coating was poor. When component (C) was not contained (Comparative Example 2), separation was observed in the stability test. When no component (D) was contained (Comparative Example 3), the curl retention was poor. When carrageenan was used instead of the component (B) (Comparative Example 4), the curl reproducibility was poor. When another film-forming polymer was used instead of the component (D) (Comparative Examples 5 to 8), it was inferior in spreadability at the time of coating and curl retention when passed through a hand glove after drying.
表に記載の各成分の詳細は、以下の通りである。 The details of each component described in the table are as follows.
<成分(A)>
ジメチルポリシロキサン(350cs):商品名「KF96−350CS」(信越化学工業株式会社製)
ジメチルポリシロキサン(100cs):商品名「SH200 C FLUID 100CS」(東レ・ダウコーニング株式会社製)
2−エチルヘキサン酸セチル:商品名「CIO−N」(日本サーファクタント工業株式会社製)
<成分(B)>
キサンタンガム:商品名「エコーガムT」(大日本住友製薬株式会社製)
<成分(C)>
カルボキシビニルポリマー:商品名「Carbopol 980 Polymer」(Lubrizol Advanced Materials社製)
アルキル変性カルボキシビニルポリマー:商品名「PEMULEN TR−1」(Lubrizol Advanced Materials社製)
<成分(D)>
成分(D−1):商品名「H.C.ポリマー1N」(大阪有機工業株式会社製、ビニルピロリドン・N,N−ジメチルアミノエチルメタクリル酸共重合体ジエチル硫酸塩、ポリクオタニウム−11)
成分(D−2):商品名「H.C.ポリマーGMR」(大阪有機工業株式会社製、ビニルピロリドン・N,N−ジメチルアミノエチルメタクリル酸共重合体ジエチル硫酸塩、ポリクオタニウム−11)
<成分(E)>
ポリオキシプロピレンソルビット:商品名「サンニックス SP−750」(三洋化成工業株式会社製、数平均分子量690)
<その他の成分>
カラギーナン:商品名「GENUVISCO PJ−JPE」(三晶株式会社製)
(アクリル酸アルキル/ジアセトンアクリルアミド)コポリマー:商品名「プラスサイズL−6345U」(互応化学工業株式会社製、アニオン性皮膜形成ポリマー、アクリル樹脂アルカノールアミン液)
(アクリル酸ヒドロキシエチル/アクリル酸メトキシエチル)コポリマー:商品名「プラスサイズL−2200」(互応化学工業株式会社製、ノニオン性皮膜形成ポリマー、アクリル酸ヒドロキシエチル・アクリル酸メトキシエチル共重合体液)
(メタクリル酸エチルベタイン / アクリレーツ)コポリマー:商品名「ユカフォーマー 301」(純分30%)、三菱ケミカル株式会社製、両性皮膜形成ポリマー、N−メタクリロイルオキシエチル−N,N−ジメチルアンモニウム−α−N−カルボキシベタイン・メタクリル酸アルキルエステル共重合体液)
ポリビニルピロリドン:商品名「PVP K−90」(ISP社製、ノニオン性皮膜形成ポリマー)
ステアリン酸ソルビタン:商品名「SS−10V」(日本サーファクタント工業株式会社製、モノステアリン酸ソルビタン)
セテス−20:商品名「ブラウノン CH−320L」(交洋ファインケミカル株式会社製、ポリオキシエチレンセチルエーテル)<Component (A)>
Dimethyl polysiloxane (350cs): trade name "KF96-350CS" (manufactured by Shin-Etsu Chemical Co., Ltd.)
Dimethylpolysiloxane (100cs): trade name "SH200 C FLUID 100CS" (manufactured by Dow Corning Toray)
Cetyl 2-ethylhexanoate: Trade name "CIO-N" (manufactured by Nippon Surfactant Industries, Ltd.)
<Component (B)>
Xanthan gum: Trade name "Echo gum T" (manufactured by Dainippon Sumitomo Pharma Co., Ltd.)
<Component (C)>
Carboxyvinyl polymer: trade name “Carbopol 980 Polymer” (manufactured by Lubrizol Advanced Materials)
Alkyl-modified carboxyvinyl polymer: trade name "PEMULEN TR-1" (manufactured by Lubrizol Advanced Materials)
<Component (D)>
Component (D-1): trade name "HC Polymer 1N" (manufactured by Osaka Organic Industry Co., Ltd., vinylpyrrolidone / N, N-dimethylaminoethyl methacrylic acid copolymer diethyl sulfate, polyquaternium-11)
Component (D-2): trade name "HC Polymer GMR" (manufactured by Osaka Organic Industry Co., Ltd., vinylpyrrolidone / N, N-dimethylaminoethyl methacrylic acid copolymer diethyl sulfate, polyquaternium-11)
<Component (E)>
Polyoxypropylene sorbit: trade name "Sunnics SP-750" (manufactured by Sanyo Chemical Industries, Ltd., number average molecular weight 690)
<Other ingredients>
Carrageenan: trade name "GENUVISCO PJ-JPE" (manufactured by Sanshin Co., Ltd.)
(Alkyl acrylate / diacetone acrylamide) copolymer: trade name “Plus size L-6345U” (manufactured by Yoyo Chemical Industry Co., Ltd., anionic film-forming polymer, acrylic resin alkanolamine liquid)
(Hydroxyethyl acrylate / methoxyethyl acrylate) copolymer: Trade name "Plus Size L-2200" (manufactured by Yoyo Chemical Industry Co., Ltd., nonionic film-forming polymer, hydroxyethyl acrylate / methoxyethyl acrylate copolymer solution)
(Ethyl betaine methacrylate / Acrylates) Copolymer: trade name “Yukaformer 301” (30% pure), manufactured by Mitsubishi Chemical Corporation, amphoteric film-forming polymer, N-methacryloyloxyethyl-N, N-dimethylammonium-α-N -Carboxybetaine-alkyl methacrylate copolymer solution)
Polyvinylpyrrolidone: trade name "PVP K-90" (a nonionic film-forming polymer manufactured by ISP)
Sorbitan stearate: trade name "SS-10V" (Sorbitan monostearate, manufactured by Nippon Surfactant Industries, Ltd.)
Ceteth-20: trade name "Brownon CH-320L" (manufactured by Koyo Fine Chemical Co., Ltd., polyoxyethylene cetyl ether)
さらに、以下に、本発明の整髪剤組成物の処方例を示す。 Furthermore, below, the formulation example of the hairdressing composition of this invention is shown.
(処方例1:ヘアミルク)
ジメチルポリシロキサン(350cs) 1.5質量%
アルガンオイル 1.0質量%
ジグリセリン 5.0質量%
マルチトール 2.0質量%
ステアリン酸ソルビタン 1.0質量%
ポリオキシエチレンセチルエーテル 2.0質量%
カルボキシビニルポリマー 0.2質量%
キサンタンガム 0.05質量%
ポリクオタニウム−11 1.0質量%
ポリオキシプロピレンソルビット 1.0質量%
エタノール 5.0質量%
トリエタノールアミン 0.2質量%
パントテニルアルコール 0.5質量%
EDTA−2Na 0.05質量%
ヒアルロン酸ナトリウム 0.005質量%
香料 適 量
精製水 残 部(Prescription example 1: Hair milk)
1.5 mass% of dimethylpolysiloxane (350cs)
Argan oil 1.0% by mass
Diglycerin 5.0% by mass
Maltitol 2.0% by mass
Sorbitan stearate 1.0% by mass
2.0% by mass of polyoxyethylene cetyl ether
Carboxyvinyl polymer 0.2% by mass
Xanthan gum 0.05% by mass
1.0% by mass of polyquaternium-11
Polyoxypropylene sorbit 1.0% by mass
5.0% by mass of ethanol
0.2% by mass of triethanolamine
Pantothenyl alcohol 0.5% by mass
EDTA-2Na 0.05% by mass
Sodium hyaluronate 0.005% by mass
Perfume Appropriate amount of purified water Remainder
(処方例2:ヘアミルク)
ジメチルポリシロキサン(100cs) 1.0質量%
2−エチルヘキサン酸セチル 0.5質量%
グリセリン 5.0質量%
1,3−ブチレングリコール 2.0質量%
ステアリン酸ソルビタン 1.5質量%
ポリオキシエチレンセチルエーテル 1.5質量%
アルキル変性カルボキシビニルポリマー 0.25質量%
キサンタンガム 0.03質量%
ポリクオタニウム−11 1.0質量%
エタノール 3.0質量%
トリエタノールアミン 0.25質量%
パントテニルアルコール 0.5質量%
加水分解ダイズタンパク 0.5質量%
EDTA−2Na 0.05質量%
香料 適 量
精製水 残 部(Prescription example 2: Hair milk)
Dimethylpolysiloxane (100cs) 1.0% by mass
Cetyl 2-ethylhexanoate 0.5% by mass
Glycerin 5.0% by mass
1,3-butylene glycol 2.0% by mass
Sorbitan stearate 1.5% by mass
1.5% by mass of polyoxyethylene cetyl ether
0.25% by mass of alkyl-modified carboxyvinyl polymer
Xanthan gum 0.03% by mass
1.0% by mass of polyquaternium-11
Ethanol 3.0% by mass
0.25% by mass of triethanolamine
Pantothenyl alcohol 0.5% by mass
Hydrolyzed soy protein 0.5% by mass
EDTA-2Na 0.05% by mass
Perfume Appropriate amount of purified water Remainder
Claims (4)
成分(A):25℃で液状の油剤
成分(B):キサンタンガム
成分(C):アクリル酸系増粘剤
成分(D):カチオン性皮膜形成ポリマーA hairdressing composition comprising the following components (A), (B), (C), and (D).
Component (A): Oil agent liquid at 25 ° C. Component (B): Xanthan gum Component (C): Acrylic acid-based thickener Component (D): Cationic film-forming polymer
成分(E):ポリオキシプロピレンソルビットThe hairdressing composition according to claim 1 or 2, comprising the following component (E).
Component (E): polyoxypropylene sorbit
Applications Claiming Priority (3)
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JP2018021576 | 2018-02-09 | ||
JP2018021576 | 2018-02-09 | ||
PCT/JP2018/034171 WO2019155673A1 (en) | 2018-02-09 | 2018-09-14 | Hairdressing agent composition |
Publications (2)
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JP6965372B2 JP6965372B2 (en) | 2021-11-10 |
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Citations (9)
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JP2001294517A (en) * | 2000-03-14 | 2001-10-23 | L'oreal Sa | Roll-on applicator containing hair composition |
JP2003073237A (en) * | 2001-08-17 | 2003-03-12 | Natl Starch & Chem Investment Holding Corp | Use of xanthan gum as hair-fixing agent |
JP2003292422A (en) * | 2002-04-01 | 2003-10-15 | Noevir Co Ltd | Hair cosmetic |
JP2006070030A (en) * | 2004-09-04 | 2006-03-16 | Wella Ag | Hair treatment comprising combination of polymer |
JP2007320872A (en) * | 2006-05-31 | 2007-12-13 | Mandom Corp | Hair cosmetic product |
JP2008542401A (en) * | 2005-06-20 | 2008-11-27 | ザ プロクター アンド ギャンブル カンパニー | Product release system for spraying a cosmetic cosmetic composition containing a cationic polymer |
JP2010189311A (en) * | 2009-02-18 | 2010-09-02 | Arimino Kagaku Kk | Cosmetic for hair |
JP2012136514A (en) * | 2010-12-08 | 2012-07-19 | Shiseido Co Ltd | Gel hair cosmetic |
WO2015174130A1 (en) * | 2014-05-16 | 2015-11-19 | 株式会社マンダム | Hair styling composition |
-
2018
- 2018-09-14 WO PCT/JP2018/034171 patent/WO2019155673A1/en active Application Filing
- 2018-09-14 CN CN201880046947.2A patent/CN110913835A/en active Pending
- 2018-09-14 JP JP2019570287A patent/JP6965372B2/en active Active
Patent Citations (9)
Publication number | Priority date | Publication date | Assignee | Title |
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JP2001294517A (en) * | 2000-03-14 | 2001-10-23 | L'oreal Sa | Roll-on applicator containing hair composition |
JP2003073237A (en) * | 2001-08-17 | 2003-03-12 | Natl Starch & Chem Investment Holding Corp | Use of xanthan gum as hair-fixing agent |
JP2003292422A (en) * | 2002-04-01 | 2003-10-15 | Noevir Co Ltd | Hair cosmetic |
JP2006070030A (en) * | 2004-09-04 | 2006-03-16 | Wella Ag | Hair treatment comprising combination of polymer |
JP2008542401A (en) * | 2005-06-20 | 2008-11-27 | ザ プロクター アンド ギャンブル カンパニー | Product release system for spraying a cosmetic cosmetic composition containing a cationic polymer |
JP2007320872A (en) * | 2006-05-31 | 2007-12-13 | Mandom Corp | Hair cosmetic product |
JP2010189311A (en) * | 2009-02-18 | 2010-09-02 | Arimino Kagaku Kk | Cosmetic for hair |
JP2012136514A (en) * | 2010-12-08 | 2012-07-19 | Shiseido Co Ltd | Gel hair cosmetic |
WO2015174130A1 (en) * | 2014-05-16 | 2015-11-19 | 株式会社マンダム | Hair styling composition |
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CN110913835A (en) | 2020-03-24 |
JP6965372B2 (en) | 2021-11-10 |
WO2019155673A1 (en) | 2019-08-15 |
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