JP2008542401A - Product release system for spraying a cosmetic cosmetic composition containing a cationic polymer - Google Patents

Abstract

  A product release system for spraying a cosmetic composition for hair comprising (a) a pressure-resistant container, (b) a capillary-mounted spray head, and (c) a propellant-containing cosmetic composition, A product release system is described that includes at least one film forming cationic polymer, hair setting cationic polymer, or hair conditioning cationic polymer. Nebulization is performed using the capillary. The capillary preferably has a diameter of 0.1 to 1 mm and a length of 5 to 100 mm. The spray rate is preferably from 0.01 to 5 g / sec. Said composition can be in particular a gel, a wax or an emulsion.

Description

  An object of the present invention is a product release system for spraying a cosmetic composition, comprising a pressure-resistant container, a capillary-mounted spray head, and a propellant-containing cosmetic composition, the composition comprising a film-forming cationic polymer , A hair setting cationic polymer or a system comprising at least one hair conditioning cationic polymer. That is, the object of the present invention is a corresponding method for hair treatment.

  Many hair cosmetic products contain cationic polymers as hair setting or hair conditioning ingredients. In foam form, the cationic polymer provides excellent combing properties to the hair after application to wet hair and provides high holding power on dry hair with an excellent setting effect. In shampoos, permanent liquids, hair styling products and hair colours, cationic polymers are used for the purpose of providing excellent combing properties on wet hair and high retention properties on dry hair. Cationic polymers provide hairstyle persistence and improve hair volume on dry hair. However, until now, cationic polymers have not been used extensively in high viscosity products such as gels, waxes, hair styling creams, or treatments, which, in addition to the composition, And the increase in the difficulty of application as a result meant that the advantage of the cationic polymer could not be fully exhibited on the hair.

  A process for spraying liquid is known from PCT International Publication No. WO 03/051523 A1, which uses a capillary to form a spray. Only applications relating to the spraying of liquid compositions are described. Equipment for spraying liquid products is described in PCT International Publication No. WO 03/051522 A2, which uses a capillary to form a spray. Only the use of a liquid composition for spraying is described, and the liquid composition can be highly viscous, but 5,000 mPa · s is described as the maximum viscosity that can be sprayed.

  Application forms such as hair waxes, styling gels, hair styling creams, or cream-like treatments also provide the beneficial hair setting and hair conditioning properties of the cationic polymer, and have these beneficial properties with the application form There is a need for a product. The object of the present invention is not specifically available as a diffusivity on the hair, volume effect, setting effect and / or hair style persistence, combing properties, hair gloss and / or spray so far It was to further improve the retention properties of conventional hair treatment compositions and / or the hair treated with the composition.

The object of the present invention is a product release system for spraying a cosmetic composition. The product release system includes:
(A) pressure vessel,
(B) Capillary-equipped spray head, and (c) propellant-containing cosmetic composition.

  The spraying is carried out using a capillary, and the composition contains at least one film-forming cationic polymer, hair setting cationic polymer, or hair conditioning cationic polymer.

  The term “spray” is understood to mean releasing the product in the form of dissipative particles. The dissipative particles can have various shapes, consistency, and sizes. The properties of the spray particles can include all properties from micro aerosol sprays to droplets, snow-like drops, solid spray flakes, and spray foam.

  Unless explicitly stated otherwise, the amounts of ingredients (e.g., weight percent) shown below are each based on a base composition that does not include a propellant. The amount of propellant is based on the total composition containing the propellant.

The composition is non-liquid at 25 ° C. and / or has a viscosity above 5,000 mPa · s (HAAKE VT-550 rheometer, specimen SV-DIN, temperature 25 ° C., shear force 12.9 s Preferably measured at ⁻¹ ).

  The consistency-related properties of the compositions used according to the invention are based on a base composition that does not contain a propellant (unless expressly specified otherwise). Non-liquid compositions in the context of the present invention are in particular non-flowable compositions, which can be determined, for example, by not flowing down a glass surface inclined at 45 degrees at a temperature of 25 ° C. The gel composition is characterized in that the memory module G ′ is larger than the lost module G ″ at 25 ° C. when using oscillographic measurement results within the typical measurement range (0.01-40 Hz). .

The viscosity of the composition used is over 5,000 to 100,000 when measured with a HAAKE VT-550 rheometer, specimen SV-DIN, temperature 25 ° C., shear force 12.9 s ^−1. Is preferably 10,000 to 50,000 mPa · s, or very preferably 25,000 to 35,000 mPa · s.

  An aerosol spray can made from metal or plastic can be used as a pressure vessel. Preferred metals are tinplate and aluminum, while the preferred plastic is polyethylene terephthalate.

  A suitable spray system comprising a capillary mounted spray head and using a capillary to form a spray is described in PCT International Publication No. WO 03/051523 A1 and PCT International Publication No. WO 03/051522 A2. Yes. The diameter of the capillary is preferably 0.1 to 1 mm, particularly 0.2 to 0.6 mm, and the length is preferably 5 to 100 mm, particularly 5 to 50 mm. The principle of spraying is described in “Aerosol Europe” Vol. 13, No. 1, 2005, pages 6-11. The present spray system is based on the principle of capillary spray. Replace the conventional swirl nozzle and, if necessary, the capture tube with a capillary. Compared to conventional spray systems, there is no need to swivel the contents of the can while consuming energy and relying on a large amount of propellant, and no need to significantly dilute the product with a solvent. Even with only a small amount of propellant, the product rises above the wall of the intake tube capillary and proceeds in the direction of the outlet opening after the (wider) capillary valve of the spray head. In this scheme, small droplets from the fluid propellant are separated from the surface of the liquid and continue to flow as an aerosol. Since neither a swirl chamber nor a spray nozzle is available to suppress product flow, the energy in the system can be used more efficiently to produce the desired spray. The spray rate can be adjusted by selecting the capillary shape in conjunction with the internal pressure generated by the propellant or propellant mixture. A preferred spray rate is from 0.01058 to 0.5 g / sec, especially from 0.1 to 0.3 g / sec. The size of the spray droplets produced by nebulization can be adjusted by selecting the capillary shape in conjunction with the internal pressure or viscosity of the composition. A suitable capillary atomization system can be obtained with the product called TRUSPRAY® from Boehringer Ingelheim microParts GmbH.

  Preferred droplet size distributions are those with a dv (50) value of up to 100 μm, such as 50-100 μm, particularly preferred are those with a maximum of 90 μm, such as 70-90 μm, and / or dv (90) Size distribution with a maximum value of 160 μm, for example 90-160 μm, particularly preferred is a maximum of 150 μm, for example 115-150 μm. The value of dv (50) or dv (90) gives the maximum diameter that 50% or 90% of all droplets have. The droplet size distribution can be determined, for example, with the help of a particle size measuring unit based on laser beam diffraction, for example a Malvern particle size measuring device. Also preferred are compositions that, when spraying existing capillaries, form a snow-like consistency, flakes, or foam (spray foam).

The propellants used are lower alkanes, especially C3-C5 hydrocarbons such as n-butane, i-butane and propane, or mixtures thereof, as well as F152a (1,1-difluoroethane) or F134 (tetra Dimethyl ethers or fluorohydrocarbons such as fluoroethane), as well as other gaseous propellants exhibiting the pressure under consideration, such as, for example, N ₂ , N ₂ O and CO ₂ , and mixtures of said propellants You can choose from. The propellant is preferably selected from propane, n-butane, isobutane, dimethyl ether, fluorinated hydrocarbons, and mixtures thereof. In addition to this, the propellant content is preferably 15 to 85% by weight, particularly preferably 25 to 75% by weight.

  The composition includes a cosmetically acceptable solvent, preferably an aqueous medium, an alcohol medium, or a hydroalcoholic medium. Lower alcohols having 1 to 4 carbon atoms, such as ethanol and isopropanol, can be included as alcohols, especially as alcohols typically used for cosmetic purposes. The pH of the composition can be in the range of 2.0 to 9.5. A pH in the range of 4-8 is particularly preferred since there are no special application shapes that require other pH values. As an additional cosolvent, an organic solvent or a mixture of solvents having a boiling point of less than 400 ° C. can be contained in an amount of 0.1 to 15% by weight, or preferably 1 to 10% by weight. Particularly suitable as additional co-solvents are unbranched or branched hydrocarbons such as n-pentane, hexane, isopentane and cyclic hydrocarbons such as cyclopentane, cyclohexane. These volatile hydrocarbons can also be used as propellants. Other particularly preferred water-soluble solvents are glycerol, ethylene glycol, propylene glycol in amounts up to 30% by weight.

  The product release system according to the invention can be used in hair treatments. The composition may be applied as a hair care agent such as a leave-on or rinse-off product, such as a hair repair product or hair rinse, or an agent that temporarily reshapes and / or maintains the hairstyle, such as a hair spray, hair Lacquers, hair gels, hair waxes, styling creams, etc., permanent, semi-permanent or temporary hair dyes such as oxidative hair dyes or non-oxidative hair colorants or hair bleaching agents, permanent hair remodeling agents For example, a hair restructuring agent in the form of a weak alkaline or acidic perm or straight perm containing a reducing agent, or a hair stabilizer in the form of a perm stabilizer containing an oxidizing agent. it can.

  The cationic polymer is preferably contained in the composition used according to the invention in an amount of 0.01 to 20% by weight, or 0.05 to 10%, particularly preferably 0.1 to 5% by weight. . The polymer can be a synthetic or natural polymer. The polymer is preferably a hair setting and / or hair conditioning polymer that also forms a film. Natural polymers are also understood to include chemically modified polymers of natural sources. The hair setting polymer exhibits a setting effect on the hair or an effect of maintaining the hair style when used in a 0.01 to 5% aqueous solution, an alcohol solution or a hydroalcoholic solution, or a dispersion. Polymers that can improve curl persistence in the context of waterwaves, in particular hair fixatives in the International Cosmetic Ingredient Dictionary and Handbook (10th edition, 2004) Understand that it is a polymer whose function of Fixatives is shown. The hair conditioning polymer is a polymer capable of exerting a hair conditioning or conditioning effect on the hair when used in a 0.01 to 5% aqueous solution, alcohol solution or hydroalcoholic solution, or dispersion, such as a comb. "Hair Conditioning Agents" in polymers that improve passability or gloss, especially in the "International Cosmetic Ingredient Dictionary and Handbook" (10th edition, 2004) It is understood that this is a polymer whose function is shown. The film-forming polymer is a polymer capable of depositing a polymer film on the hair after drying when used in a 0.01 to 5% aqueous solution, alcohol solution or hydroalcoholic solution, or dispersion, particularly international It is understood as a polymer whose “Film Formers” function is shown in the International Cosmetic Ingredient Dictionary and Handbook (10th edition, 2004). The polymer can be loaded simultaneously with two or three of the properties known as “film formation”, “hair setting” and “hair conditioning”.

  Cationic polymers are polymers that have cationic or amine groups, especially primary, secondary, tertiary, or quaternary amine groups. The cationic charge density is preferably 1 to 7 meq / g.

  Suitable synthetic cationic polymers include dialkylaminoalkyl acrylates, dialkylaminoalkyl methacrylates, monoalkylaminoalkyl acrylates, as well as monoalkylaminoalkyl methacrylates with cyclic groups containing cationic nitrogen, trialkylmethacryloxyalkylammonium , Trialkylacryloxyalkylammonium, dialkyldiallylammonium, and homo- or copolymers derived from at least one of quaternary vinylammonium monomers.

  Suitable cationic polymers preferably contain quaternary amino groups. Cationic polymers can be homo- or copolymers, with the quaternary nitrogen group included in the polymer chain, or preferably as a substituent on one or more monomers. Monomers containing ammonium groups can be copolymerized with non-cationic monomers. Suitable cationic monomers are unsaturated compounds capable of undergoing radical polymerization, and at least one cationic group, in particular ammonium such as, for example, trialkylmethacryloxyalkylammonium, trialkylacryloxyalkylammonium, dialkyldiallylammonium, etc. Provided are substituted vinyl monomers and quaternary vinylammonium monomers having a cyclic cationic nitrogen-containing group such as pyridinium, imidazolium, or quaternary pyrrolidone, for example, alkyl vinyl imidazolium, alkyl vinyl pyridinium, or alkyl vinyl pyrrolidone salts Yes. The alkyl group of these monomers is preferably a lower alkyl group, for example, a C1-C7 alkyl group, particularly preferably a C1-C3 alkyl group.

  Monomers containing ammonium groups can be copolymerized with non-cationic monomers. Suitable comonomers are, for example, acrylamide, methacrylamide, alkyl and dialkyl acrylamide, alkyl and dialkyl methacrylamide, alkyl acrylate, alkyl methacrylate, vinyl caprolactone, vinyl caprolactam, vinyl pyrrolidone, vinyl esters such as vinyl acetate, vinyl alcohol, propylene glycol. Or an ethylene glycol, and the alkyl group of these monomers is preferably a C1-C7 alkyl group, and particularly preferably a C1-C3 alkyl group.

  Suitable polymers having quaternary amino groups are, for example, the CTFA “Cosmetic Ingredient Dictionary”, methylvinylimidazolium chloride / vinylpyrrolidone copolymer (polyquaternium-16), or quaternized vinylpyrrolidone / methacrylic acid. Polymers described under the name polyquaternium such as dimethylaminoethyl copolymer (polyquaternium-11), as well as quaternary silicone polymers or silicone oligomers such as silicone polymers with quaternary end groups (quaternium-80).

Preferred cationic polymers derived from synthesis:
Copolymers derived from poly (dimethyldiallylammonium chloride), acrylamide and dimethyldiallylammonium chloride; quaternary ammonium polymers formed by the reaction of vinyl pyrrolidone and dimethylaminoethyl methacrylate and diethyl sulfate, especially vinyl pyrrolidone / dimethylaminoethyl methacrylate Methosulfate copolymers (eg, Gafquat® 755N, Gafquat® 734); quaternary ammonium polymers derived from methylvinylimidazolium chloride and vinylpyrrolidone (eg, LUVIQUAT®) ) HM550); Polyquaternium-35; Polyquaternium-57; Trimethylammonium ethyl methacrylate Polymers derived from lorides; terpolymers derived from dimethyldiallylammonium chloride, sodium acrylate, and acrylamide (eg, Merquat® Plus 3300); vinyl pyrrolidone, dimethylaminopropyl methacrylamide, and methacryloylamino Copolymers derived from propyl lauryl dimethyl ammonium chloride; terpolymers derived from vinyl pyrrolidone, dimethylaminoethyl methacrylate and vinyl caprolactam (eg Gaffix® VC 713); vinyl pyrrolidone / methacrylamide propyl trimethyl ammonium chloride copolymer ( For example, Gafquat® HS 100); vinyl pyrrolidone and dimethylaminoethyl meta Relate-derived copolymer; vinylpyrrolidone, vinylcaprolactam, and dimethylaminopropylacrylamide-derived copolymer; formed from at least one first type monomer selected from hydroxy acids substituted with at least one quaternary ammonium group Poly or oligoester; dimethylpolysiloxane having a terminal portion substituted with a quaternary ammonium group.

Suitable cationic polymers derived from natural polymers are in particular cationic derivatives of polysaccharides, such as cationic derivatives of cellulose, starch or guar. Furthermore, chitosan and chitosan derivatives are also suitable. The cationic polysaccharide is represented by the following general formula, for example.
G—O—B—N ⁺ R ^a R ^b R ^c X ⁻
G is an anhydroglucose residue, such as starch or cellulose anhydroglucose;
B is a divalent linking group such as alkylene, oxyalkylene, polyoxyalkylene, or hydroxyalkylene;
R ^a , R ^b , and R ^c are, independently of one another, alkyl, aryl, alkylaryl, arylalkyl, alkoxyalkyl, or alkoxyaryl that can have up to 18 carbon (C) atoms. (At this time, the total number of carbon atoms of R ^a , R ^b , and R ^c is preferably at most 20),
X is a conventional counter anion, such as a halide, acetate, phosphate, nitrate, or alkyl sulfate, preferably chloride. The cationic cellulose has an INCI name of, for example, polyquaternium-4, polyquaternium-10, or polyquaternium-24. A suitable cationic guar derivative has, for example, the INCI name guar hydroxypropyltrimonium chloride.

  Particularly preferred cationic active substances are chitosan, chitosan salts and chitosan derivatives. The chitosan that can be used according to the invention can be chitin that is fully or partially deacetylated. As an example, the molecular weight can be distributed over a wide range of 20,000 to 5 million g / mol, for example 30,000 to 70,000 g / mol. However, the molecular weight is preferably more than 100,000 g / mol, particularly preferably 200,000 to 700,000 g / mol. The degree of deacetylation is preferably 10 to 99%, particularly preferably 60 to 99%. A preferred chitosan salt is chitosonium pyrrolidone carboxylate, for example Kytamer® PC having a molecular weight of about 200,000 to 300,000 g / mol and a degree of deacetylation of 70 to 85%. Chitosan derivatives that can be taken into account include quaternized, alkylated, or hydroxyalkylated derivatives such as hydroxyethyl, hydroxypropyl, or hydroxybutyl chitosan. The chitosan or chitosan derivative is preferably present in a neutralized state or in a partially neutralized form. The degree of neutralization, when calculated based on the number of free base groups, is preferably at least 50%, particularly preferably 70-100%. As the neutralizing agent, in principle, any inorganic or organic acid that is compatible as a cosmetic can be used, such as formic acid, tartaric acid, malic acid, lactic acid, citric acid, pyrrolidone carboxylic acid, hydrochloric acid, etc. Pyrrolidone carboxylic acid is particularly preferred.

Preferred cationic polymers derived from natural sources:
Cationic cellulose derivatives derived from hydroxyethylcellulose and diallyldimethylammonium chloride, cationic cellulose derivatives derived from hydroxyethylcellulose and trimethylammonium substituted epoxides, chitosan and salts thereof, hydroxyalkylchitosan and salts thereof, alkylhydroxyalkylchitosan and salts thereof, N- Hydroxyalkyl chitosan alkyl ether.

  In one embodiment, the composition according to the invention is a gel, and at least one thickener or gel former is preferably 0.01-20% by weight, or 0.1-10% by weight, 0.5. It is contained in an amount of ˜8% by weight, or particularly preferably 1 to 5% by weight. Substances for which the function of “Viscosity Increasing Agent” is shown in the International Cosmetic Ingredient Dictionary and Handbook (10th edition, 2004) are essentially suitable. The thickener or gel-based formulation is preferably a thickening polymer, at least one first type monomer selected from acrylic acid and methacrylic acid, and an ester of acrylic acid and ethoxylated fatty alcohol A copolymer derived from at least one second type monomer selected from: cross-linked polyacrylic acid; at least one first type monomer selected from acrylic acid and methacrylic acid; and acrylic acid and C10 to C30 A crosslinked copolymer derived from at least one second type monomer selected from esters with alcohol; at least one first type monomer selected from acrylic acid and methacrylic acid; and itaconic acid and ethoxylated fat COPO derived from at least one second type monomer selected from esters with aliphatic alcohols At least one first type monomer selected from acrylic acid and methacrylic acid; at least one second type monomer selected from esters of itaconic acid and ethoxylated C10-C30 alcohol; and A copolymer derived from a third type of monomer selected from C1-C4 aminoalkyl acrylate; a copolymer derived from two or more monomers selected from acrylic acid, methacrylic acid, acrylic ester, and methacrylic ester; vinylpyrrolidone And copolymers derived from ammonium acryloyl dimethyl taurate; copolymers derived from monomers selected from ammonium acryloyl dimethyl taurate and esters of methacrylic acid and ethoxylated fatty alcohols; hydroxyethyl cellulose; hydroxy Hydroxypropyl guar; Glyceryl polyacrylate; Glyceryl polymethacrylate; Copolymer derived from at least one C2, C3, or C4 alkylene and styrene; Polyurethane; Hydroxypropyl starch phosphate; Polyacrylamide; Maleic anhydride and methyl Copolymer decadiene derived from vinyl ether; locust bean gum; guar gum; xanthan; dehydroxanthan; carrageenan; caraya gum; hydrolyzed corn starch; copolymer derived from polyethylene oxide, aliphatic alcohol and saturated methylene diphenyl diisocyanate (eg PEG-150) / Stearyl alcohol / SMDI copolymer) is particularly preferred.

  In certain additional embodiments, the composition is waxy and at least one wax that is solid at 25 ° C is preferably 10-80 wt%, especially 20-60 wt%, or 25-50 wt%. In addition, other water-insoluble substances that are liquid at room temperature are included if necessary. The waxy viscosity is preferably a penetration value (scale 0.1 mm, test weight 100 g, test time 5 seconds, test temperature 25 ° C., according to DIN 51 579), preferably 2 to 70, or especially 3 to 40. And / or the composition is soluble and has a freezing point above 25 ° C., or preferably in the range of 30 ° C. to 70 ° C., or particularly preferably in the range of 40 ° C. to 55 ° C. It is preferable to have a freezing point.

  In principle, any wax known in the prior art can be used as wax or waxy material. The waxes include animal, plant, and synthetic waxes, microcrystalline wax, macrocrystalline wax, solid paraffin, petroleum jelly, petroleum jelly, ground wax, montan wax, Fischer-Tropsch wax, polyolefin wax such as polybutene, beeswax, wool Wax and its derivatives, such as wool wax alcohol, candelilla wax, olive wax, carnauba wax, Japanese wax, apple wax, hardened oil, fatty acid ester, fatty acid glyceride, silicone wax or hydrophilic having a freezing point above 40 ° C Wax, for example, high molecular weight polyethylene glycol wax having a molecular weight of 800 to 20,000, preferably 2,000 to 10,000 g / mol. The freezing point of the wax or waxy substance is above 25 ° C, or preferably above 40 ° C or 55 ° C. The penetration value (0.1 mm, 100 g, 5 seconds, 25 ° C., according to DIN 51 579) is preferably in the range from 2 to 70, or in particular from 3 to 40.

  In another embodiment, the composition is preferably emulsion-like and the consistency is cream-like. The emulsion can be a water-in-oil emulsion, an oil-in-water emulsion, a microemulsion, or a higher emulsion. Preferably, in addition to water, at least one hydrophobic oil that is liquid at room temperature (25 ° C.) and at least one emulsifier are included. The oil content is preferably 1 to 20% by weight, or in particular 2 to 10% by weight. The content of the emulsifier is preferably 0.01 to 30% by weight, or in particular 0.1 to 20% by weight, or 0.5 to 10% by weight.

  Suitable liquid hydrophobic oils have a melting point of less than 25 ° C. and the melting point is preferably more than 250 ° C., or more particularly more than 300 ° C. Volatile oils can also be used. In principle, any oil generally known to those skilled in the art can be used. Suitable oils are vegetable or animal oils, mineral oils (liquid paraffin), silicone oils or mixtures thereof. Hydrocarbon oils such as paraffin or oils derived from isoparaffin oil, squalane, fatty acids and polyols, especially triglycerides, are suitable. Suitable vegetable oils are, for example, sunflower oil, coconut oil, castor oil, lanolin oil, jojoba oil, corn oil, soybean oil.

Suitable emulsifiers can include nonionic, anionic, cationic, or bipolar surfactants. Suitable nonionic surfactants are, for example,
-Ethoxylated fatty alcohols, fatty acids, fatty acid glycerides or alkylphenols, in particular 2-30 moles of ethylene oxide and / or 1-5 moles of propylene oxide, C8-C22 fatty alcohol, C12-C22 fatty alcohol, or , Products added to alkylphenols having 8 to 15 carbon (C) atoms in the alkyl group-C12 to C22 fatty acid mono- and diesters of products obtained by adding 1 to 30 moles of ethylene oxide to glycerol -5 Products of 60 moles of ethylene oxide added to castor oil or hydrogenated castor oil-fatty acid sugar esters, in particular esters formed from sucrose and one or two C8-C22 fatty acids, INCI name: sucrose cocoate, sucrose dilaurate , Scroll Distearate, sucrose laurate, sucrose myristate, sucrose oleate, sucrose palmitate, sucrose ricinoleate, sucrose stearate-sorbitan, one, two or three C8-C22 fatty acids, and one of 4-20 Esters derived from two degrees of ethoxylation-polyglyceryl fatty acid esters, in particular, polyglyceryl fatty acid esters derived from polyglycerols having 1, 2 or more C8-C22 fatty acids and 2-20 glyceryl units-C8-C22 Alkyl glucosides, alkyl oligoglucosides, and alkyl polyglucosides having an alkyl group of, for example, decyl glucoside or lauryl glucoside

  Suitable anionic surfactants include, for example, salts and esters of carboxylic acids, alkyl ether sulfates and alkyl sulfates, fatty alcohol ether sulfates, sulfonic acids and salts thereof (eg sulfosuccinate or fatty acid isethionate), phosphate esters. And salts thereof, acylamino acids and salts thereof. A comprehensive description of these anionic surfactants can be found in the publication “FIEDLER-Lexikon der Hilfsstoffe [FIEDLER-Dictionary of Adjuvants]” Volume 1, 5th Edition (2002), 97. Page 102, the publication explicitly mentions the above. Preferred surfactants are mono-, di- and / or triesters of the product phosphoric acid obtained by adding 2-30 moles of ethylene oxide to a C8-C22 aliphatic alcohol.

  Suitable amphoteric surfactants are, for example, derivatives of aliphatic quaternary ammonium, phosphonium and sulfonium compounds represented by the following formula:

式中Ｒ１は、８〜１８個の炭素（Ｃ）原子、エチレンオキシド単位、０〜約１０個のエチレンオキシド単位及び０〜１個のグリセロール単位を有する直鎖又は分枝鎖アルキル、アルケニル、又はヒドロキシアルキル基を表しており、ＹはＮ、Ｐ、又は、Ｓ含有基であり、Ｒ２は、１〜３個の炭素（Ｃ）原子を有するアルキル又はモノヒドロキシアルキル基であり、Ｙがイオウ原子である場合のｘ＋ｙの合計は２であり、Ｙが窒素原子又はリン原子である場合のｘ＋ｙの合計は３であり、Ｒ３は、１〜４個の炭素（Ｃ）原子を有するアルキレン又はヒドロキシアルキレン基であり、Ｚ^(-)は、カルボキシレート基、サルフェート基、ホスホネート基、又は、ホスフェート基を表している。ベタインのようなその他の両性界面活性剤も好適である。ベタインの例としては、Ｃ８〜Ｃ１８アルキルベタイン、例えば、ココジメチルカルボキシメチルベタイン、ラウリルジメチルカルボキシメチルベタイン、ラウリルジメチル−α−カルボキシエチルベタイン、セチルジメチルカルボキシメチルベタイン、オレイルジメチル−γ−カルボキシプロピルベタイン、及び、ラウリル−ビス−（２−ヒドロキシプロピル）−α−カルボキシエチルベタイン；Ｃ８〜１８スルホベタイン、例えば、ココジメチルスルホプロピルベタイン、ステアリルジメチルスルホプロピルベタイン、ラウリルジメチルスルホエチルベタイン、ラウリル−ビス−（２−ヒドロキシエチル）スルホプロピルベタイン；イミダゾール、Ｃ８〜１８アルキルジメチルアンモニウムアセテート、Ｃ８〜１８アルキルジメチルカルボニルメチルアンモニウム塩、及び、Ｃ８〜１８脂肪酸アルキルアミドベタインのカルボキシル誘導体、例えば、ヤシ脂肪酸アミドプロピルベタイン及びＮ−ヤシ脂肪酸アミドエチル−Ｎ−［２−（カルボキシメトキシ）エチル］グリセロール（ＣＴＦＡ名：ココアンホカルボキシグリシネート）が挙げられる。

Wherein R1 is a linear or branched alkyl, alkenyl, or hydroxyalkyl having 8 to 18 carbon (C) atoms, ethylene oxide units, 0 to about 10 ethylene oxide units, and 0 to 1 glycerol units. Y represents a group containing N, P or S, R2 is an alkyl or monohydroxyalkyl group having 1 to 3 carbon (C) atoms, and Y is a sulfur atom The sum of x + y in the case is 2, the sum of x + y in the case where Y is a nitrogen atom or a phosphorus atom is 3, and R3 is an alkylene or hydroxyalkylene group having 1 to 4 carbon (C) atoms. Yes, Z ^(-) represents a carboxylate group, a sulfate group, a phosphonate group, or a phosphate group. Other amphoteric surfactants such as betaine are also suitable. Examples of betaines include C8-C18 alkylbetaines such as cocodimethylcarboxymethylbetaine, lauryldimethylcarboxymethylbetaine, lauryldimethyl-α-carboxyethylbetaine, cetyldimethylcarboxymethylbetaine, oleyldimethyl-γ-carboxypropylbetaine, And lauryl-bis- (2-hydroxypropyl) -α-carboxyethylbetaine; C8-18 sulfobetaines such as cocodimethylsulfopropylbetaine, stearyldimethylsulfopropylbetaine, lauryldimethylsulfoethylbetaine, lauryl-bis- ( 2-hydroxyethyl) sulfopropylbetaine; imidazole, C8-18 alkyldimethylammonium acetate, C8-18 alkyldimethylcarbo And methyl derivatives of C8-18 fatty acid alkylamide betaines, such as coconut fatty acid amidopropyl betaine and N-coconut fatty acid amidoethyl-N- [2- (carboxymethoxy) ethyl] glycerol (CTFA name: Cocoampho) Carboxyglycinate).

Suitable cationic surfactants include amino groups or quaternized hydrophilic ammonium groups that have a positive charge in solution and can be represented by the following general formula.
N ⁽⁺⁾ R ¹ R ² R ³ R ⁴ X ^(-)
In the formula, R1 to R4 are independently of each other an aliphatic group having 1 to 22 carbon (C) atoms, an aromatic group, an alkoxy group, a polyoxyalkylene group, an alkylamide group, a hydroxyalkyl group, an aryl group. Or an alkaryl group, wherein at least one radical has at least 6, preferably at least 8 carbon (C) atoms, and X ⁻ is an anion, such as halide, acetate, phosphate, nitrate, Or, it is an alkyl sulfate, but is preferably chloride. In addition to carbon and hydrogen atoms, aliphatic groups can also include bridging compounds or other groups such as additional amino groups. Examples of suitable cationic surfactants are alkyldimethylbenzylammonium salts, chlorides or bromides of alkyltrimethylammonium salts, such as cetyltrimethylammonium chloride or bromide, tetradecyltrimethylammonium chloride or bromide, alkyldimethylhydroxyethylammonium chloride or Bromide, dialkyldimethylammonium chloride or bromide, alkylpyridinium salts such as lauryl or cetylpyridinium chloride, alkylamidoethyltrimethylammonium ether sulfate, and compounds having cationic properties such as amine oxides such as alkylmethylamine oxide or alkyl Aminoethyldimethylamine oxide. Particularly preferred are C8-22 alkyldimethylbenzylammonium compounds, C8-22 alkyltrimethylammonium compounds, especially cetyltrimethylammonium chloride, C8-22 alkyldimethylhydroxyethylammonium compounds, di- (C8-22 alkyl) -dimethyl. Ammonium compounds, C8-22 alkylpyridinium salts, C8-22 alkylamidoethyltrimethylammonium ether sulfate, C8-22 alkylmethylamine oxide, and C8-22 alkylaminoethyldimethylamine oxide.

  The cosmetic composition used according to the invention may also include at least one additional active cosmetic ingredient or additive for the hair or skin / scalp. This active ingredient or additive includes, for example, hair conditioning substances, hair setting substances, silicone compounds, photoprotective substances, preservatives, pigments, direct osmotic hair dyes, particulate substances, oxidizing agents, reducing agents, and oxidizing agents. It can be selected from hair dye precursor products. The active ingredients and additives are contained in an amount of 0.01 to 20% by weight, or in particular 0.05 to 10 or 0.1 to 5% by weight, depending on the type and purpose of use. Is preferred.

  In one embodiment, the agent as a hair conditioning or hair setting additive according to the present invention comprises 0.01 to 20% by weight of at least one polymer having an anionic group or anionizable group, or 0.05 to 10 wt%, with 0.1 to 5 wt% being particularly preferred. Anionizable groups can be deprotonated using, for example, organic amines or typical bases such as alkali or alkaline earth hydroxides such as carboxylic acid groups, sulfonic acid groups, or phosphate groups. It is understood that it is such an acidic group. The anionic polymer can be partially or completely neutralized with an alkaline neutralizer. 50% to 100%, particularly preferably 70% to 100%, of the above-mentioned agents that neutralize acidic groups in the polymer are preferred. Organic or inorganic bases can be used as neutralizing agents. Specific examples of bases are aminoalkanols such as, for example, aminomethylpropanol (AMP), triethanolamine, or monoethanolamine, and in particular ammonia, NaOH, and KOH.

  The anionic polymer can be a homopolymer or copolymer having acidic group-containing monomer units derived from natural or synthetic sources and, if necessary, can be polymerized with a comonomer that does not contain acidic groups. Possible acidic groups are sulfonic acid groups, phosphoric acid groups and carboxylic acid groups, among which carboxylic acid groups are preferred. Suitable acidic group-containing monomers are, for example, acrylic acid, methacrylic acid, crotonic acid, maleic acid, and maleic anhydride, in particular C1-C7 alkyl monoesters of maleic acid, and aldehyde carboxylic acids or ketocarboxylic acids. . Comonomers not substituted with acidic groups are, for example, acrylamide, methacrylamide, alkyl and dialkyl acrylamide, alkyl and dialkyl methacrylamide, alkyl acrylate, alkyl methacrylate, vinyl caprolactone, vinyl pyrrolidone, vinyl ester, vinyl alcohol, propylene glycol, or , Ethylene glycol, amine-substituted vinyl monomers such as dialkylaminoalkyl acrylates, dialkylaminoalkyl methacrylates, monoalkylaminoalkyl acrylates, and monoalkylaminoalkyl methacrylates, where the alkyl groups of these monomers are C1-C7 An alkyl group is preferred, and a C1-C-alkyl group is particularly preferred.

  Suitable polymers having acidic groups are in particular acrylic acid or methacrylic acid homopolymers, acrylic acid or methacrylic acid esters, acrylamides, methacrylamides and copolymers of acrylic acid or methacrylic acid with monomers selected from vinylpyrrolidone, croton Acid homopolymers and copolymers of crotonic acid with monomers selected from vinyl esters, acrylic or methacrylic esters, acrylamides and methacrylamides that are non-cross-linked or cross-linked with polyfunctional agents. A suitable natural polymer is, for example, shellac.

Preferred polymers having acidic groups are
Terpolymers derived from acrylic acid, alkyl acrylates and N-alkyl acrylamides (INCI name: acrylate / acrylamide copolymers), in particular terpolymers derived from acrylic acid, ethyl acrylate and N-tert-butyl acrylamide; Cross-linked vinyl acetate / crotonic acid copolymer (INCI name: VA / crotonate copolymer); at least one selected from one or more C1-C5 alkyl acrylates, in particular C2-C4 alkyl acrylates, and acrylic acid or methacrylic acid Copolymers derived from monomers (INCI name: acrylate copolymers), for example terpolymers derived from tert-butyl acrylate, ethyl acrylate and methacrylic acid; sodium polystyrene sulfonate; Ruacetylene / crotonic acid / vinyl alkanoate copolymers such as copolymers derived from vinyl acetate, crotonic acid and vinyl propionate; copolymers derived from vinyl acetate, crotonic acid and vinyl neodecanoate (INCI name: VA / Crotonate / vinyl propionate copolymer, VA / crotonate / vinyl neodecanoate copolymer): aminomethyl propanol acrylate copolymer; vinyl pyrrolidone and acrylic acid and methacrylic acid, if necessary, acrylic ester and methacrylic Copolymer derived from at least one further monomer selected from acid esters; copolymer derived from methyl vinyl ether and monoalkyl maleate (INCI name: PVM / MA copoly) In addition to allyl methacrylate and acrylic acid and methacrylic acid, if necessary, from at least one further monomer selected from acrylic acid ester and methacrylic acid ester Aminomethylpropanol salt of a copolymer of; a crosslinked copolymer derived from ethyl acrylate and methacrylic acid; a copolymer derived from vinyl acetate, mono-N-butyl maleate, and isobornyl acrylate; acrylic acid and methacrylic acid, and as required A copolymer derived from two or more monomers selected from acrylic acid esters and methacrylic acid esters; octylacrylamide, and acrylic acid esters if necessary in addition to acrylic acid and methacrylic acid And a copolymer derived from at least one monomer selected from methacrylic acid esters; polyesters derived from diglycol, cyclohexanedimethanol, isophthalic acid, and sulfoisophthalic acid, wherein the alkyl group of the polymer is generally 1, 2, 3, Alternatively, it preferably has 4 carbon (C) atoms.

  In one embodiment, the agent as a hair conditioning or hair setting additive according to the present invention is preferably 0.01 to 20% by weight of at least one zwitterionic and / or amphoteric polymer, or 0.0. It is contained in an amount of 05 to 10% by weight, or particularly preferably 0.1 to 5% by weight. The zwitterionic polymer simultaneously has at least one anionic charge and at least one cationic charge. The amphoteric polymer exhibits at least one acidic group (for example, a carboxylic acid group or a sulfonic acid group) and at least one alkaline group (for example, an amino group). Acidic groups can be deprotonated using, for example, organic amines or typical bases such as alkali or alkaline earth hydroxides.

Preferred zwitterionic or amphoteric polymers are
Alkyl acrylamide, alkylaminoalkyl methacrylate, and copolymers formed from acrylic acid and methacrylic acid and, if necessary, two or more monomers derived from their esters, in particular octylacrylamide, acrylic acid, butylaminoethyl A copolymer derived from methacrylate, methyl methacrylate and hydroxypropyl methacrylate (INCI name: octylacrylamide / acrylate / butylaminoethyl methacrylate copolymer); at least one first type monomer having a quaternary amino group and an acidic group A copolymer formed from at least one second type monomer having: fatty alcohol acrylate, alkylamine oxide methacrylate, and acrylic acid and Copolymers derived from at least one monomer selected from acrylic acid esters and methacrylic acid esters, in particular lauric acrylate, stearyl acrylate, ethylamine oxide methacrylate, and acrylic acid and methacrylic acid, if necessary, in addition to crylic acid In addition, if necessary, a copolymer derived from at least one monomer selected from those esters; a copolymer derived from at least one monomer selected from methacryloylethylbetaine and acrylic acid and methacrylic acid ester; acrylic acid, Copolymer derived from methyl acrylate and methacrylamidopropyltrimethylammonium chloride (INCI name: Polyquaternium-47); A copolymer derived from muchloride and acrylate, or a copolymer derived from acrylamide, acrylamidopropyltrimethylammonium chloride, 2-amidopropylacrylamidesulfonate and dimethylaminopropylamine (INCI name: polyquaternium-43); quaternary chronoyl betaine, Or it is the oligomer or polymer which can be produced | generated from a quaternary crotonoyl betaine ester.

  In one embodiment, the agent of the present invention comprises 0.01 to 15 wt%, or preferably 0.5 to 10 wt%, of at least one synthetic or natural nonionic film-forming polymer.

  Suitable synthetic nonionic polymers include vinyl lactams such as vinyl pyrrolidone or vinyl caprolactam; vinyl esters such as vinyl acetate; vinyl alcohol, vinyl formamide, acrylamide, methacrylamide, alkyl acrylamide, dialkyl acrylamide, alkyl methacrylamide, A homo- or copolymer derived from at least one of dialkylmethacrylamide, alkylacrylate, alkylmethacrylate, alkylmaleimide, such as ethylmaleimide or hydroxyethylmaleimide, and an alkylene glycol, such as propylene or ethylene glycol, The alkyl and / or alkylene group of the monomer is preferably a C1-C7 alkyl group, , Particularly preferred are C1~C3 alkyl group.

  Suitable homopolymers are, for example, vinylcaprolactam, vinylpyrrolidone, or N-vinylformamide homopolymer. Further suitable synthetic nonionic polymers are, for example, polyacrylamide, polyethylene glycol / polypropylene glycol copolymers, vinyl pyrrolidone and vinyl acetate derived copolymelides, vinyl pyrrolidone, vinyl acetate and vinyl propionate terpolymers, polyacrylamide Polyvinyl alcohol and polyethylene glycol / polypropylene glycol copolymers; Suitable natural film-forming polymers are especially saccharide-based polymers, preferably glucans such as cellulose and its derivatives. Suitable derivatives are in particular derivatives having alkyl and / or hydroxyalkyl substituents, said alkyl group having for example 1 to 20 or preferably 1 to 4 carbon (C) atoms. For example, hydroxyalkyl cellulose. Preferred nonionic polymers are polyvinyl pyrrolidone, polyvinyl caprolactam, vinyl pyrrolidone / vinyl acetate copolymer, polyvinyl alcohol, isobutylene / ethyl maleimide / hydroxyethyl maleimide copolymer; copolymers derived from vinyl pyrrolidone, vinyl acetate, and vinyl propionate. .

In one embodiment, the agent as a hair conditioning additive according to the invention preferably comprises at least one silicone compound, preferably 0.01 to 15% by weight, or particularly preferably 0.1 to 5% by weight. Included in quantity. Silicone compounds include volatile and non-volatile silicones and silicones that are soluble and insoluble in the agent. One embodiment, 0.001 m viscosity at 25 ° C. ² / sec (1,000cSt) ~2m ² / sec (2,000,000cSt), or, preferably 0.01 m ² / s (10,000 cSt) It is a high molecular weight silicone that is ˜1.8 m ² / sec (1,800,0000 cSt) or 0.1 m ² / sec (100,000 cSt) to 1.5 m ² / sec (1,500,000 cSt). Silicone compounds include polyalkyl and polyaryl siloxanes, especially those having methyl, ethyl, propyl, phenyl, methylphenyl, and phenylmethyl groups. Polydimethylsiloxane, polydiethylsiloxane, and polymethylphenylsiloxane are preferred. Also preferred are arylated silicones that provide gloss with a refractive index of at least 1.46 or at least 1.52. Examples of the silicone compound include, among others, the INCI names cyclomethicone, dimethicone, dimethiconol, dimethicone copolyol, phenyltrimethicone, amodimethicone, trimethylsilylamodimethicone, stearylsiloxysilicate, polymethylsilsesquioxane, and dimethicone crosspolymer. There are certain substances. Also suitable are silicone resins and silicone elastomers, which are highly crosslinked siloxanes. Preferred silicones include cyclic dimethylsiloxane, linear polydimethylsiloxane, block polymers derived from polydimethylsiloxane and polyethylene oxide and / or polypropylene oxide, polydimethylsiloxane having terminal or side chain polyethylene oxide or polypropylene oxide radicals, terminal hydroxyl groups. Polydimethylsiloxane, phenyl substituted polydimethylsiloxane, silicone emulsion, silicone elastomer, silicone wax, silicone gum, amino substituted silicone, and silicone substituted with quaternary ammonium groups.

  In one embodiment, the agent according to the invention is preferably 0.01 to 10% by weight, or 0.1 to 5% by weight, or particularly preferably 0.2 to 2% by weight, of a photoprotective substance. Is included in the amount. Examples of the photoprotective substance include all the photoprotective substances described in European Patent No. 1,084,696. 4-Methoxycinnamic acid-2-ethylhexyl ester, methylmethoxycinnamate, 2-hydroxy-4-methoxybenzophenone-5-sulfonic acid, and polyethoxylated p-aminobenzoate are preferred.

  In one embodiment, the agent according to the invention comprises betaine; panthenol; panthenyl ethyl ether; sorbitol; protein hydrolysate; plant extract; AB block copolymer derived from alkyl acrylate and alkyl methacrylate; AB block copolymer derived from acrylonitrile; ABA block copolymer derived from lactide and ethylene oxide; ABA block copolymer derived from caprolactone and ethylene oxide; alkylene or alkadiene compound; A- derived from styrene and alkyl methacrylate B-C block copolymer; ABC block copolymer derived from acrylic acid, styrene and alkyl methacrylate; star block copolymer; hyperbranched polymer; dendri -Essentially conductive 3,4-polyethylenedioxythiophene; and at least one hair conditioning additive selected from essentially conductive polyaniline is 0.01-20, particularly preferably 0.05. To 10 or, in particular, preferably 0.1 to 5% by weight.

  In one embodiment, the agent according to the invention comprises 0.01 to 5, or particularly preferably 0.05 to 1% by weight of at least one preservative. Suitable preservatives are those listed as having the function of “Preservatives” in the 10th edition of the “International Cosmetic Ingredient Dictionary and Handbook”, for example phenoxyethanol, benzyl Paraben, butylparaben, ethylparaben, isobutylparaben, isopropylparaben, methylparaben, propylparaben, iodopropynylbutylcarbamate, methyldibromoglutaronitrile, and DMDM hydantoin.

  Certain embodiments of the invention relate to hair conditioning agents. Hair conditioning agents are, for example, conditioners, treatments, hair repair products, rinses and the like. Cationic or amine substitution includes at least one hair conditioning agent component selected from the silicone compounds, cationic or amine substituted surfactants, and cationic or amine substituted polymers. The hair conditioning agent can be used in an amount of 0.01 to 10.0% by weight, or especially 0.01 to 5.0% by weight, based on the final product. The hair conditioning agent according to the present invention can be applied to dry, moist or wet hair and then remain in the hair, or it can be rinsed off after a suitable period of action. The duration of action varies with the type of hair. In principle, a duration of action of 0.5 to 30 minutes, in particular 0.5 to 10 minutes and preferably 1 to 5 minutes can be envisaged.

In addition to the cationic surfactant, other suitable cationic or amino-substituted surfactants, R1-NH- (CH ₂₎ expression of n-NR2 R3,
_{Or, R1-NH- (CH 2)} n-N + R2R3R4 X -
Is a surfactant of the formula

Wherein R1 is an acyl or alkyl residue having 8 to 24 carbon (C) atoms, said residue can be branched or straight chain, saturated or unsaturated, whereby acyl and And / or the alkyl residue may include one or more OH groups, and R2, R3, and R4, independently of one another, are hydrogen, alkyl having 1 to 6 carbon (C) atoms, alkyl, Or an alkoxyalkyl residue, which can be the same or different saturated or unsaturated and can be substituted with one or more hydroxy groups, and X ⁻ is an anion, in particular a halogen. An ion or a compound of the general formula RSO ₃ ^— , wherein R is a saturated or unsaturated alkyl residue having 1 to 4 carbon (C) atoms, and n is 1 to 10, Preferably the integer of 2-5 is meant.

The active hair conditioning compound is preferably an amidoamine and / or a quaternized amidoamine of the above formula, wherein R1 is branched or straight chain having 8 to 24 carbon (C) atoms, A saturated or unsaturated acyl residue that can contain at least one PH group. Preference is given to said amines and / or quaternized amines, wherein at least one of the residues R2, R3 and R4 means a residue according to the general formula CH ₂ CH ₂ OR5, Can mean an alkyl residue having 1 to 4 carbon (C) atoms, hydroxyethyl, or H. Optionally, suitable amines or amidoamines that can be quaternized are in particular those whose INCI names are ricinolamidopropylbetaine, ricinolamidopropyldimethylamine, ricinolamidopropyldimethyllactate, sinolamidopropylethyldimonium ethosulphate, ricinolamide Propyltrimonium chloride, ricinolamidopropyltrimonium methosulfate, cocamidopropyl betaine, cocamidopropyldimethylamine, cocamidopropylethyldimonium etosulphate, cocamidopropyltrimonium chloride, behenamidopropyldimethylamine, isostearylamide Propyldimethylamine, stearylamidopropyldimethylamine, quaternium-33, undecylenamidopropyltri It is those that are methosulfate.

  In a preferred embodiment, the agent according to the invention contains at least one pigment. The pigment can be a colored pigment that provides a coloring effect on the product mass or hair, or the pigment can be a gloss enhancing pigment that provides a gloss effect on the product or hair. The coloring or gloss effect in the hair is preferably temporary, i.e. the effect remains until the next wash of the hair and can be removed by washing the hair with a typical shampoo. The pigment does not dissolve in the product mass and can be contained in an amount of 0.01 to 25% by weight, with 5 to 15% being particularly preferred. The preferred particle size is 1 to 200 μm, especially 3 to 150 μm and particularly preferably 10 to 100 μm. The pigment is a colorant that is substantially insoluble in the application medium and can be inorganic or organic. Inorganic-organic mixed pigments are also possible. Inorganic pigments are preferred. The advantage of inorganic pigments is exceptional resistance to light, climate and temperature. The inorganic pigment can be a natural source pigment, for example, a pigment made from chalk, ocher, amber, green clay, burnt senna, or graphite. The pigment may be a white pigment such as titanium dioxide or zinc oxide, a black pigment such as black iron oxide, a colored pigment such as ultramarine or red iron oxide, a gloss pigment, a metal effect pigment, a pearl luster pigment, and a fluorescent pigment. Alternatively, it can be a phosphorescent pigment, and at least one pigment is preferably a colored non-white pigment. Metal oxides, metal hydroxides, and metal oxide hydrates, mixed phase pigments, sulfur-containing silicates, metal sulfides, complex metal cyanides, metal sulfates, metal chromates, metal borate, and metals The product itself (bronze pigment) is suitable. Titanium dioxide (CI 77891), black iron oxide (CI 77499), yellow iron oxide (CI 77492), red and brown iron oxide (CI 77491), manganese violet (CI 77742), ultramarine (sodium aluminum sulfosilicate, CI 77007, pigment blue 29), Particularly suitable are chromium oxide hydrate (CI 77289), bitumen (ferric ferrocyanide, CI 77510) and carmine (cochineal).

  Metal oxides or metal oxychlorides such as titanium dioxide or bismuth oxychloride and, if necessary, additional color donors such as iron oxide, bitumen, ultramarine, carmine (in this case the color Particularly preferred are mica-based pearlescent pigments and colored pigments, which can be determined by varying the thickness of These types of pigments are, for example, by German Merck, Rona®, Colorona®, Dichrona®, and Timiron. It is sold under the trade name (registered trademark).

  Organic pigments are, for example, the natural pigment Sepia, Garcinia Cambodia, Bone Block, Bandai Brown, Indigo, Chlorophyll, and other plant pigments. Synthetic organic pigments are, for example, azo pigments, anthraquinods, indigoids, and dioxazine, quinacridone, phthalocyanine, isoindolinone, perylene, perinone, metal complexes, alkali blue, and diketopyrrolopyrrole pigments.

  In one embodiment, the agent according to the invention comprises 0.01 to 10, or particularly preferably 0.05 to 5% by weight of at least one particulate material. Suitable materials are, for example, materials that are solid and particulate at room temperature (25 ° C.). Silica, silicates, aluminates, alumina, mica, salts, especially inorganic metal salts, metal oxides such as titanium dioxide, minerals and polymer particles are somewhat suitable. The particles are present in the agent in an undissolved form, preferably in a steadily dispersed form, and are deposited on the hair in solid form after application to the hair and after evaporation of the solvent. be able to. Steady dispersion can be achieved by providing a composition with a yield point high enough to completely prevent solid particle settlement. A sufficient yield point can be achieved by using an appropriate amount of an appropriate gel former. Preferred particulate materials are silica (silica gel, silicon dioxide) and metal salts, especially inorganic metal salts, in which case silica is particularly preferred. Metal salts are, for example, alkali or alkaline earth halides, such as sodium chloride or potassium chloride, and alkali or alkaline earth sulfates, such as sodium sulfate or magnesium sulfate.

  Additional embodiments relate to agents that permanently remodel hair. Said substance contains at least one reducing agent, in particular a mercapto compound which reduces keratin, preferably in an amount of 0.5 to 15% by weight. The permanent agent is preferably present as an aqueous alkaline (pH = 5-10) preparation, and the preparation contains, for example, cysteine, cysteamine, N-acetyl-L-cysteine as mercapto compounds that reduce keratin. , Mercaptocarboxylic acids such as mercaptoacetic acid or thiolactic acid, or salts of mercaptocarboxylic acid such as ammonium and guanidine salts of mercaptoacetic acid or thiolactic acid. The required alkalinity is achieved by adding ammonia, organic amines, ammonium and alkali carbonates or bicarbonates. Neutral or acidic (pH = 4.5-7) hair remodeling agents with an effective content of sulfite or mercaptocarboxylate in an aqueous medium can also be considered. In the first case, sodium or ammonium sulfite, or a salt of sulfuric acid with an organic amine, such as monoethanolamine and guanidine, can be used at a concentration of about 2 to 12% by weight (calculated as SO2). . In the latter case, mercaptoacetic acid monoglycol ester or glycerol ester is used in particular at a concentration of about 5-50% by weight (corresponding to a content of 2-16% by weight of mercaptoacetic acid). The agent for permanently reconstituting hair according to the present invention may also include a mixture of the above keratin reducing compounds. For the post-oxidation treatment, it is possible to use the stabilizer according to the invention, which contains at least one oxidizing agent. Examples of oxidants that can be used in one of these types of stabilizers are sodium and potassium bromate, sodium perborate, urea peroxide, and hydrogen peroxide. The concentration of the oxidizing agent can be about 0.5 to 10% by weight. Both the agent for permanently reconstituting hair according to the present invention and the stabilizer according to the present invention should be present in emulsion or thickened form on an aqueous basis, in particular as a cream, gel or paste. Can do.

  The composition used according to the invention further comprises any additive commonly used for hair treatment agents, such as perfume oils; opacifiers such as ethylene glycol distearate, styrene / PVP copolymers or polystyrene; humectants; brighteners Product dyes; antioxidants can all be included, preferably in an amount of 0.01 to 10% by weight, in which case the total amount preferably does not exceed 10% by weight.

The object of the present invention is also a method of hair treatment,
-Providing a product release system according to the invention,
-The product release system sprays the composition contained therein onto the hair; and
-The sprayed composition is washed away from the hair after the period of action or remains in the hair.

  Also, especially if the product has a snow-like consistency, or if the product is in flakes or foams, instead of spraying directly on the hair, the product is applied by hand or by an application device such as a comb or Place on brush and place in hair.

  The product according to the invention is characterized by its special application with the special aerosol spray system used according to the invention, with excellent hairstyle persistence with high retention and excellent dispensing power in combination with hair gloss and , Limited by the application. A further advantage of the product according to the invention is that different spray properties can be precisely adjusted simply by changing the propellant, propellant composition or propellant pressure, It was not accepted for active ingredient compositions. The spray characteristics include all characteristics from micro aerosol atomized spray and snow-like drops to spray flakes and spray foam.

  The following examples will provide an illustration of further objects of the invention.

  In the following examples, the individual active ingredient compositions are filled in a pressure-resistant aerosol can with the propellant indicated separately and, for example, under the trade name TRUSPRAY, Boehringer Ingelheim Micro A capillary spray system available from Boehringer Ingelheim microParts GmbH was installed.

  (Example 1): Solid microemulsion

稠度：半透明の固体マイクロエマルション

Consistency: Translucent solid microemulsion

Spray characteristics:
1-1: Fine dry aerosol spray 1-2: Fine wet aerosol spray 1-3: Snow-like droplet structure 1-4: Spray foam 1-5: Ultra fine dry aerosol

  Field tests were performed on mannequin hair. In one-side comparison, the left side of the mannequin hair was treated with an aerosol-using substance 1-1, and the right side was treated with a highly viscous active ingredient composition containing no propellant. Those using aerosols were easier to dispense, applied very accurately, and easier to spread in the hair than pure active ingredients. Hair treated with an aerosol-use substance was greatly improved in gloss and hairstyle sustainability significantly compared to hair treated with pure active ingredients.

  (Example 2): Hair styling gel

稠度：高粘度透明ゲル

Consistency: High viscosity transparent gel

Spray characteristics:
2-1: Snow-like spray 2-2: Snow-like spray 2-3: Wet aerosol spray 2-4: Spray foam 2-5: Droplet (snow-like)

  (Example 3): Hair styling cream

稠度：高粘度クリーム

Consistency: high viscosity cream

Spray characteristics:
2-1: Micro aerosol spray 2-2: Wet aerosol spray 2-3: Spray foam 2-4: Micro aerosol spray 2-5: Micro aerosol spray

  (Example 4): Hair styling wax

稠度：ペースト状ワックス

Consistency: Paste wax

  Example 5: Emulsion-like creamy hair restoration product / treatment

稠度：高粘度クリーム

Consistency: high viscosity cream

Spray characteristics:
5-1: Snow-like spray 5-2: Snow-like spray 5-3: Wet aerosol spray 5-4: Spray foam 5-5: Spray foam

  (Example 6): Hair Balsam

稠度：粘性ヘアミルク

Consistency: viscous hair milk

Spray characteristics:
6-1: Snow-like spray 6-2: Snow-like spray 6-3: Wet aerosol spray 6-4: Spray foam 6-5: Spray foam

Claims (28)

A product release system for spraying a cosmetic composition for hair,
(A) pressure vessel,
(B) a capillary-mounted spray head, and
(C) a propellant-containing cosmetic composition, which is nebulized using the capillary, and in which the film-forming cationic polymer, hair-setting cationic polymer, or hair-conditioning cationic polymer is added A product release system comprising at least one of   The product release system according to claim 1, wherein the capillary has a diameter of 0.1 to 1 mm and a length of 5 to 100 mm.   The product release system according to claim 1 or 2, wherein the spray rate is 0.01 to 5 g / sec.   4. The product release system according to any one of claims 1 to 3, wherein the propellant is selected from propane, butane, dimethyl ether, fluorinated hydrocarbons, and mixtures thereof.   The cationic polymer is a dialkylaminoalkyl acrylate, a dialkylaminoalkyl methacrylate, a monoalkylaminoalkyl acrylate, a monoalkylaminoalkyl methacrylate having a cyclic group containing cationic nitrogen, a trialkylmethacryloxyalkylammonium, 5. A product according to any one of claims 1 to 4 selected from homo- or copolymers composed of at least one of the monomers alkyl acryloxyalkyl ammonium, dialkyl diallylammonium and quaternary vinyl ammonium monomers. Extrusion system.   The cationic polymer is derived from hydroxyethylcellulose and diallyldimethylammonium chloride; a cationic cellulose derivative derived from hydroxyethylcellulose and trimethylammonium substituted epoxide; poly (dimethyldiallylammonium chloride); acrylamide and dimethyldiallylammonium chloride Copolymer; Quaternary ammonium polymer formed by reaction of diethyl sulfate with a copolymer derived from vinylpyrrolidone and dimethylaminoethyl methacrylate; Quaternary ammonium polymer derived from methylvinylimidazolium chloride and vinylpyrrolidone; Polyquaternium-35; Trimethylammoniumethyl Polymer derived from methacrylate chloride; Quaternium-57; dimethylpolysiloxane end-substituted with quaternary ammonium groups; copolymers derived from vinylpyrrolidone, dimethylaminopropylmethacrylamide and methacryloylaminopropyllauryldimethylammonium chloride; chitosan and its salts; hydroxyalkylchitosan and its salts Alkyl hydroxyalkyl chitosan and salts thereof; N-hydroxyalkyl chitosan alkyl ether; copolymer derived from vinyl caprolactam, vinyl pyrrolidone and dimethylaminoethyl methacrylate; copolymer derived from vinyl pyrrolidone and dimethylaminoethyl methacrylate; and vinyl pyrrolidone , Vinylcaprolactam and dimethylaminopropylacrylamide derived copolymers; 6. The method according to any one of claims 1 to 5, which is also selected from poly or oligoesters composed of at least one first type monomer selected from hydroxycarboxylic acids substituted with one quaternary ammonium group. Product release system as described in the paragraph.   The product release system according to any one of claims 1 to 6, wherein the composition is a gel, a wax or an emulsion.   9. A product release system according to claim 8, wherein the gel-type composition comprises at least one thickener or gel former in an amount of 0.01 to 20% by weight.   The thickener or gel former is at least one first type monomer selected from acrylic acid and methacrylic acid, and at least one selected from esters of acrylic acid and ethoxylated fatty alcohols. A copolymer derived from a second type of monomer; cross-linked polyacrylic acid; at least one first type monomer selected from acrylic acid and methacrylic acid, and an ester of acrylic acid with a C10-C30 alcohol. A cross-linked copolymer derived from at least one second type monomer; selected from at least one first type monomer selected from acrylic acid and methacrylic acid, and an ester of itaconic acid and an ethoxylated fatty alcohol Copolymer derived from at least one second type of monomer; acrylic acid and methacrylate At least one first type monomer selected from oxalic acid; at least one second type monomer selected from esters of itaconic acid and ethoxylated C10-C30 alcohol; and C1-C4 aminoalkyl A copolymer derived from a third type of monomer selected from acrylates; a copolymer derived from two or more monomers selected from acrylic acid, methacrylic acid, acrylic esters and methacrylic esters; vinylpyrrolidone and ammonium acryloyl Copolymers derived from dimethyl taurate; copolymers derived from monomers selected from ammonium acryloyl dimethyl taurate and esters of methacrylic acid and ethoxylated fatty alcohols; hydroxyethyl cellulose; hydroxypropyl cellulose Hydroxypropyl guar; Glyceryl polyacrylate; Glyceryl polymethacrylate; Copolymer derived from at least one C2, C3, or C4 alkylene and styrene; Polyurethane; Hydroxypropyl starch phosphate; Polyacrylamide; Maleic anhydride and methyl vinyl ether Copolymer of decadiene; locust bean gum; guar gum; xanthan; dehydroxanthan; carrageenan; caraya gum; hydrolyzed corn starch; polyethylene oxide, aliphatic alcohol, and a copolymer derived from saturated methylene diphenyl diisocyanate. 9. The product release system of claim 8, wherein   8. The product release system according to claim 7, wherein the waxy composition comprises at least one wax that is solid at 25 [deg.] C. in an amount of 10 to 80% by weight.   The wax is paraffin wax, polyolefin wax, wool wax, wool wax alcohol, candelilla wax, olive wax, carnauba wax, Japanese wax, apple wax, hardened oil, fatty acid ester, fatty acid glyceride, fatty acid triglyceride, polyethylene glycol wax, and 11. A product release system according to claim 10 selected from silicone waxes.   The emulsion-type composition is a water-in-oil type, an oil-in-water type, or a microemulsion, and the emulsion-type composition contains at least one emulsifier in an amount of 0.1 to 30% by weight and at least 1 8. The product release system according to claim 7, wherein the two oils are in an amount of 1 to 20% by weight and contain water.   13. The oil of claim 12, wherein the oil is selected from silicone oil, mineral oil, isoparaffin oil, paraffin oil, squalane, sunflower seed oil, coconut oil, castor oil, lanolin oil, jojoba oil, corn oil, and soybean oil. Product release system.   The emulsifier is a product obtained by adding 2 to 30 moles of ethylene oxide and / or 1 to 5 moles of propylene oxide to a C8 to C22 aliphatic alcohol, 2 to 30 moles of ethylene oxide and / or 1 to 5 moles of propylene oxide. Of C12 to C22 fatty acids, 2 to 30 moles of ethylene oxide and / or 1 to 5 moles of propylene oxide were added to alkylphenols having 8 to 15 carbon (C) atoms in the alkyl group. Products, C12-C22 fatty acid monoesters and diesters of products with 1-30 moles of ethylene oxide added to glycerol, products with 5-60 moles of ethylene oxide added to castor oil or hydrogenated castor oil, 2-30 Moles of ethylene oxide to C8-C22 aliphatic alcohols Mono-, di- or triesters of phosphoric acid with added products, esters of saccharose and one or two C8-C22 fatty acids, sorbitan, one, two or three C8-C22 fatty acids And an ester derived from one degree of ethoxylation of 4-20, one, two or more C8-C22 fatty acids, and a polyglycerol-derived polyglyceryl fatty acid ester having 2-20 glyceryl units, alkyl Glycoside, C8-22 alkyldimethylbenzylammonium compound, C8-22 alkyltrimethylammonium compound, C8-22 alkyldimethylhydroxyethylammonium compound, di- (C8-22 alkyl) -dimethylammonium compound, C8-22 alkylpyridinium salt, C8 ~ 22 alkyl Bromide trimethyl ammonium ether sulfates, C8～22 alkyl methyl amine oxide, C8～22 alkyl aminoethyl dimethyl amine oxides, amidoamines, and are selected from quaternized amidoamine, product release system according to claim 12 or 13.   The composition includes a hair conditioning material, a hair setting material, a silicone compound, a photoprotective material, a preservative, a pigment, a direct osmotic hair dye, a particulate material, an oxidizing agent, a reducing agent, and an oxidative hair dye precursor. 15. Product release system according to any one of the preceding claims, comprising at least one additional active ingredient or additive selected from the product.   16. A product release system according to claim 15, wherein the active ingredient or additive is included in an amount of 0.01 to 20% by weight.   A nonionic polymer is included as a hair conditioning or hair setting material, the polymer being polyvinyl pyrrolidone, polyvinyl caprolactam, vinyl pyrrolidone / vinyl acetate copolymer, polyvinyl alcohol, isobutylene / ethyl maleimide / hydroxyethyl maleimide copolymer; vinyl pyrrolidone, 17. Product release system according to claim 15 or 16, selected from vinyl acetate and copolymers derived from vinyl propionate.   An anionic polymer is included as a hair conditioning or hair setting material, and the polymer is a terpolymer derived from acrylic acid, ethyl acrylate, and N-tert-butylacrylamide; a crosslinked or non-crosslinked vinyl acetate / crotonic acid copolymer; Terpolymer derived from tert-butyl acrylate, ethyl acrylate and methacrylic acid; sodium polystyrene sulfonate; copolymer derived from vinyl acetate, crotonic acid and vinyl propionate; vinyl acetate, crotonic acid and vinyl neodecano Amine-derived copolymer; aminomethylpropanol acrylate copolymer; vinyl pyrrolidone, and acrylic acid, methacrylic acid, acrylic ester, and methacrylic ester A copolymer derived from at least one additional monomer; a copolymer derived from methyl vinyl ether and a monoalkyl maleate; allyl methacrylate and acrylic acid, methacrylic acid, acrylic acid ester and methacrylic acid ester Aminomethylpropanol salt of a copolymer derived from at least one additional monomer; a cross-linked copolymer derived from ethyl acrylate and methacrylic acid; a copolymer derived from vinyl acetate, mono-n-butyl maleate and isobornyl acrylate; acrylic acid Copolymers derived from two or more monomers selected from methacrylic acid, acrylic acid esters and methacrylic acid esters; octylacrylamide and acrylic acid, methacrylic acid, acrylic acid 17. Copolymer derived from at least one monomer selected from esters and methacrylic acid esters; selected from polyesters derived from diglycol, cyclohexanedimethanol, isophthalic acid and sulfoisophthalic acid. Product release system.   A zwitterionic or amphoteric polymer is included as a hair conditioning or hair setting material, the polymer being a copolymer derived from octylacrylamide, acrylic acid, butylaminoethyl methacrylate, methyl methacrylate, and hydroxypropyl methacrylate; lauryl acrylate, Stearyl acrylate, ethylamine oxide methacrylate, and a copolymer derived from at least one monomer selected from acrylic acid, methacrylic acid, acrylic ester, and methacrylic ester; methacryloyl ethyl betaine, and methacrylic acid, and methacrylic ester A copolymer derived from at least one monomer selected from: acrylic acid, methyl acrylate, and methacrylamide Pills trimethylammonium chloride derived copolymers; quaternary crotonic betaine, or is selected from the generation, oligomeric or polymeric quaternary croton betaine esters, product release system according to claim 15 or 16.   At least one silicone compound, said silicone compound comprising a cyclic dimethylsiloxane, a linear polydimethylsiloxane, a polydimethylsiloxane and a block polymer derived from polyethylene oxide and / or polypropylene oxide, a terminal or side chain polyethylene oxide or polypropylene Polydimethylsiloxanes with oxide radicals, polydimethylsiloxanes with terminal hydroxyl groups, phenyl substituted polydimethylsiloxanes, silicone emulsions, silicone elastomers, silicone waxes, silicone gums, amino substituted silicones, and one or more quaternary ammonium 20. A product release system according to any one of claims 15 to 19, selected from silicones substituted with groups.   At least one photoprotective substance, which is 4-methoxycinnamic acid-2-ethylhexyl ester, methylmethoxycinnamate, 2-hydroxy-4-methoxybenzophenone-5-sulfonic acid 21. A product release system according to any one of claims 15-20, selected from polyethoxylated p-aminobenzoates.   Active ingredients and additives are included, the active ingredients and additives being betaine; panthenol; panthenyl ethyl ether; sorbitol; protein hydrolysate; plant extract; AB from alkyl acrylate and alkyl methacrylate A block copolymer; an AB block copolymer derived from alkyl methacrylate and acrylonitrile; an ABA block copolymer derived from lactide and ethylene oxide; an ABA block copolymer derived from caprolactone and ethylene oxide; an alkylene or alkadiene compound, styrene, and ABC block copolymer derived from alkyl methacrylate; ABC block copolymer derived from acrylic acid, styrene, and alkyl methacrylate; star block copolymer; hyperbranched Rimmer; dendrimers; intrinsically conductive 3,4-polyethylenedioxythiophene; and is selected from the intrinsically conductive polyaniline, product release system according to any one of claims 15 to 21.   At least one pigment is included, the pigment comprising titanium dioxide (CI 77891), black iron oxide (CI 77499), yellow iron oxide (CI 77492), red and brown iron oxide (CI 77491), manganese violet (CI 77742), ultra Metal oxides or metal oxychlorides such as marine (CI77007), chromium oxide hydrate (CI77289), bitumen (CI77510), bismuth oxychloride (CI77163), carmine (cochineal), titanium dioxide or bismuth oxychloride, and , If necessary, selected from mica-based pearlescent and colored pigments coated with additional color-donating substances such as iron oxide, bitumen, ultramarine or carmine, varying the thickness of the layers The color is determined accordingly. 22 product release system according to any one of.   At least one particulate material, wherein the particulate material is selected from silica, silicate, aluminate, alumina, mica, insoluble metal salt, metal oxide, mineral, and insoluble polymer particles. Item 24. The product release system according to any one of Items 15 to 23. The composition is a gel, and the composition includes
(A) derived from at least one first type monomer selected from acrylic acid and methacrylic acid, and at least one second type monomer selected from esters of acrylic acid and ethoxylated fatty alcohols A copolymer of: cross-linked polyacrylic acid; at least one first type monomer selected from acrylic acid and methacrylic acid; and at least one second selected from esters of acrylic acid and C10-C30 alcohols A cross-linked copolymer derived from a monomer of the type; at least one first type of monomer selected from acrylic acid and methacrylic acid; and at least one second selected from esters of itaconic acid and ethoxylated fatty alcohols A copolymer derived from a monomer of the type; selected from acrylic acid and methacrylic acid At least one first type monomer, at least one second type monomer selected from esters of itaconic acid and ethoxylated C10-C30 alcohols, and a first selected from C1-C4 aminoalkyl acrylates. A copolymer derived from three types of monomers; a copolymer derived from two or more monomers selected from acrylic acid, methacrylic acid, an acrylate ester, and a methacrylic acid ester; a copolymer derived from vinylpyrrolidone and ammonium acryloyldimethyltaurate A copolymer derived from a monomer selected from ammonium acryloyldimethyl taurate and an ester of methacrylic acid and an ethoxylated fatty alcohol; hydroxyethyl cellulose; hydroxypropyl cellulose; hydroxypropyl group; -Glyceryl polyacrylate; Glyceryl polymethacrylate; Copolymer derived from at least one C2, C3 or C4 alkylene and styrene; Polyurethane; Hydroxypropyl starch phosphate; Polyacrylamide; Cross linked with decadiene derived from maleic anhydride and methyl vinyl ether At least one thickening polymer selected from copolymers derived from polyethylene oxide, aliphatic alcohols, and saturated methylene diphenyl diisocyanates; locust bean gum; guar gum; xanthan; dehydroxanthan; carrageenan; 0.1 to 10% by weight, and
(B) 0.1-5% by weight of at least one film-forming cationic polymer, hair setting cationic polymer or hair conditioning cationic polymer selected from the cationic polymers according to claim 6
The product release system of claim 1, which is included. The composition is in the form of an O / W emulsion, a W / O emulsion, or a microemulsion,
(A) Silicone oil, mineral oil, isoparaffin oil, paraffin oil, squalane, vegetable oil, paraffin wax, polyolefin wax, wool wax, wool wax alcohol, candelilla wax, olive wax, carnauba wax, Japanese wax, apple wax, hardened oil, fatty acid 1 to 20% by weight of at least one oil or wax selected from esters, fatty acid glycerides, fatty acid triglycerides, polyethylene glycol waxes, and silicone waxes,
(B) 0.01-30% by weight of at least one emulsifier, and
(C) 0.01 to 20% by weight of at least one film-forming cationic polymer selected from the cationic polymers according to claim 6, a hair setting cationic polymer, or a hair conditioning cationic polymer
The product release system of claim 1, which is included.   Use of the product release system according to any one of claims 1 to 26 for hair treatment purposes. A hair treatment method,
-Providing a product release system according to any one of claims 1 to 26;
-The product release system sprays the composition contained therein onto the hair; and
-Method of washing the composition off the hair after it has been active or leaving it in the hair.