JP6192502B2 - Emulsion hair styling composition - Google Patents

Description

  The present invention relates to an emulsified hair composition, which is an emulsified composition and is used in a hair styling agent for shaping hair.

  In order to prepare hair, hair conditioner compositions having various properties such as liquid, gel, cream and solid are known. Conventionally, in a hairdressing composition, a film-forming polymer or a solid oil at room temperature is often used in order to exert the hairstyling power that is its main function (for example, Patent Document 1 and Patent Document 2).

  However, in a hairdressing composition using a film-forming polymer, a film is formed on the surface of the hair after styling due to the film-forming polymer. For this reason, when a film-forming polymer is blended as a main hair styling component, the initial hair styling power immediately after hair styling becomes high, while the hair after hair styling has problems such as no moist feeling, itching and poor touch. In addition, hair styling compositions using hydrocarbon oils, waxes and fats that are solid at room temperature have problems such as poor hair styling composition spreading during hair styling and hair stickiness after hair styling.

JP-A-11-171740 JP-A-10-45546

  An object of the present invention is to provide an excellent hair styling composition that has good spreading at the time of application, is excellent in hair styling power, and has a good feel without itchiness or stickiness after hair styling. is there.

This invention contains the following component (A), the following component (B), the following component (C), and the following component (D), and content of the said component (A) is 3.0-30.0 mass%. There is provided an emulsified hair conditioner composition characterized in that the content of the component (B) is 5.0 to 30.0% by mass.
Component (A): Oil agent liquid at 25 ° C. Component (B): The following component (B1), or the following component (B1) and the following component (B2)
Component (C): Nonionic surfactant Component (D): Water Component (B1): Polyoxyethylene / polyoxypropylene copolymer having a number average molecular weight of 10,000 to 20,000 Component (B2): Number average molecular weight Polyoxypropylene sorbit which is 300-1000

  The component (A) is preferably an oil agent selected from the group consisting of hydrocarbon oils, silicone oils, fatty acid ester oils, higher alcohols, and fats and oils.

The emulsified hair styling composition of the present invention preferably further comprises the following component (E).
Component (E): particles selected from the group consisting of silica, calcium carbonate, magnesium carbonate, hydroxyapatite, titanium oxide, zinc oxide, calcium silicate, magnesium silicate, aluminum silicate, and magnesium hydroxide

  The emulsified hairdressing composition of the present invention contains a specific component, and further, the content of the component (A) and the component (B) is within a specific range, so that the spread during application is good and the usability is excellent. In addition, it has a high function of grouping hair and exhibits excellent hair-styling ability. Furthermore, the hair after styling has no itchiness or stickiness, and the touch of the hair after styling becomes good.

  The emulsified hairdressing composition of the present invention is a liquid oil at 25 ° C .; a polyoxyethylene / polyoxypropylene copolymer having a number average molecular weight of 10,000 to 20,000, or a polyoxy having a number average molecular weight of 10,000 to 20,000. An ethylene / polyoxypropylene copolymer and a polyoxypropylene sorbite having a number average molecular weight of 300 to 1000; a nonionic surfactant; and water are included. The emulsified hair conditioner composition of the present invention is further selected from the group consisting of silica, calcium carbonate, magnesium carbonate, hydroxyapatite, titanium oxide, zinc oxide, calcium silicate, magnesium silicate, aluminum silicate, and magnesium hydroxide. It is preferred that the particles contain particles.

  In the present specification, the “liquid oil at 25 ° C.” is referred to as “component (A)”; the “polyoxyethylene / polyoxypropylene copolymer having a number average molecular weight of 10,000 to 20,000, or a number “Polyoxyethylene / polyoxypropylene copolymer having an average molecular weight of 10,000 to 20,000 and polyoxypropylene sorbit having a number average molecular weight of 300 to 1,000” are referred to as “component (B)”; the above “nonionic surfactant” “Component (C)”; “water” as “component (D)”; “silica, calcium carbonate, magnesium carbonate, hydroxyapatite, titanium oxide, zinc oxide, calcium silicate, magnesium silicate, aluminum silicate” And “particles selected from the group consisting of magnesium hydroxide” and “component (E)”. There is. The “polyoxyethylene / polyoxypropylene copolymer having a number average molecular weight of 10,000 to 20,000” is referred to as “component (B1)”; and the “polyoxypropylene sorbitol having a number average molecular weight of 300 to 1,000” is referred to as “ It may be referred to as “component (B2)”.

  The emulsified hairdressing composition of the present invention comprises a component (A), a component (B), a component (C), and a component (D). The emulsified hair styling composition of the present invention preferably further contains a component (E). The emulsified hairdressing composition of the present invention may contain components (other components) other than the above components (A) to (E). The component (B) is the component (B1), or the component (B1) and the component (B2). In addition, only 1 type is used for each component (for example, component (A) -component (E), component (B1), component (B2), and other components) contained in the emulsified hairdressing composition of the present invention. Or two or more of them may be used.

[Component (A): Liquid oil at 25 ° C.]
The said component (A) is an oil agent. The said component (A) mainly has a role which suppresses the stickiness by a component (B) and improves the touch of the hair after hairdressing. Only 1 type may be used for a component (A), and 2 or more types may be used for it.

  The said component (A) is liquid at 25 degreeC from a viewpoint of suppressing the stickiness of the hair after hairdressing. The above “liquid at 25 ° C.” is not particularly limited, but for example, a 50 g sample (oil) is put into a glass bottle having a radius of 2 cm and a height of 7 cm, and the glass bottle is turned upside down at a temperature of 25 ° C. In this case, it is preferable that the sample hangs down from the glass bottle for 5 minutes immediately after being inverted. When an oil agent that is not liquid at 25 ° C. is used in place of the component (A), the hair after styling becomes sticky.

  The viscosity η measured at 25 ° C. using the Brookfield type rotational viscometer of the component (A) is from 10 to 5000 mPa · s (from 10 mPa · s to 5000 mPa · s from the viewpoint of suppressing the stickiness of the hair after styling. s or less), more preferably 20 to 3000 mPa · s. When an oil agent having a viscosity exceeding 5000 mPa · s is used in place of the component (A), stickiness may occur on the hair after styling.

  Although it does not specifically limit as said component (A), For example, fats and oils, hydrocarbon oil, a fatty acid, a higher alcohol, fatty acid ester oil, silicone oil etc. are mentioned. Of these, hydrocarbon oils, higher alcohols, fatty acid ester oils, silicone oils, and oils and fats are preferable from the viewpoint that after the hair styling, unnatural glare peculiar to the oil agent does not occur and a light finish with a natural texture can be obtained. That is, the component (A) is preferably an oil agent (at least one oil agent) selected from the group consisting of hydrocarbon oils, higher alcohols, fatty acid ester oils, silicone oils, and fats and oils. In addition, the component (B) and the component (C) described later are not included in the component (A).

  Examples of the hydrocarbon oil include α-olefin oligomer, light isoparaffin, light liquid isoparaffin, synthetic squalane, vegetable squalane, squalane, liquid isoparaffin, and liquid paraffin.

  Examples of the higher alcohol include saturated or unsaturated linear monohydric alcohols having 6 to 20 carbon atoms such as lauryl alcohol and oleyl alcohol; isostearyl alcohol, hexyldecanol, octyldodecanol, decyltetradecanol, and the like. And a saturated or unsaturated branched monohydric alcohol having 6 to 26 carbon atoms.

  Examples of the fatty acid ester oil include ethyl oleate, isopropyl myristate, isopropyl palmitate, myristyl myristate, cetyl palmitate, oleyl oleate, octyldodecyl myristate, octyldodecyl oleate, ethyl isostearate, isopropyl isostearate Cetyl 2-ethylhexanoate, cetostearyl 2-ethylhexanoate, glyceryl tri-2-ethylhexanoate, glyceryl triisopalmitate, pentaerythritol tetra-2-ethylhexanoate, isocetyl octoate, isostearyl octoate, isostearic acid Examples include isocetyl, octyldodecyl isostearate, octyldodecyl dimethyloctanoate, and isononyl isononanoate.

  Examples of the silicone oil include straight silicone oils such as methylpolysiloxane, highly polymerized methylpolysiloxane, methylphenylpolysiloxane, and methylhydrogenpolysiloxane; octamethyltrisiloxane, decamethyltetrasiloxane, octamethylcyclotetrasiloxane, Examples include cyclic silicone oils such as decamethylcyclopentasiloxane, dodecamethylcyclohexasiloxane, and methylcyclopolysiloxane; modified silicone oils such as alcohol-modified silicone, alkyl-modified silicone, amino-modified silicone, and epoxy-modified silicone.

  Examples of the fats and oils include avocado oil, argan oil, olive oil, rice bran oil, soybean oil, corn oil, palm kernel oil, palm oil, castor oil, grape seed oil, kukui nut oil, macadamia nut oil, meadow home oil, sunflower oil Etc.

  The content of the component (A) in the emulsified hairdressing composition of the present invention is 3.0 to 30.0% by mass (3.0% by mass or more) with respect to 100% by mass of the emulsified hairdressing composition of the present invention. 30.0 mass% or less), preferably 5.0-25.0 mass%. When the content of the component (A) is 3.0% by mass or more, the stickiness of the hair after styling is suppressed and the touch is improved. Moreover, when the content of the component (A) is 30.0% by mass or less, the hair styling power of the emulsified hair styling composition of the present invention is improved. When content of a component (A) exceeds 30.0 mass%, since hair will become difficult to stick together and the unit of hair will worsen, hairdressing power will become inadequate. Content of the said component (A) is a total amount of content of all the components (A) in the emulsified hairdressing composition of this invention.

[Component (B): Component (B1) or Component (B1) and Component (B2)]
The component (B) is the component (B1), or the component (B1) and the component (B2). That is, the component (B) includes the component (B1) as an essential component and includes the component (B2) as an optional component. The component (B) mainly has a role of imparting hair styling power to the emulsified hair styling composition of the present invention.

  As the component (B), only the component (B1) may be used, or the component (B1) and the component (B2) may be used in combination. In addition, only 1 type may be used for a component (B1) and a component (B2), respectively, and 2 or more types may be used.

(Component (B1): Polyoxyethylene / polyoxypropylene copolymer)
The component (B1) is a polyoxyethylene / polyoxypropylene copolymer. That is, the component (B1) is a copolymer having at least a plurality of oxyethylene units (ethylene oxide units) and a plurality of oxypropylene units (propylene oxide units). The component (B1) may be any of a block copolymer, a random copolymer, and an alternating copolymer, and the form of copolymerization in the component (B1) is not particularly limited.

  The average number of moles of oxyethylene added in the component (B1) is not particularly limited, but it has excellent hair styling power by suppressing stickiness of the emulsified hairdressing composition and having an appropriate viscosity. 100 to 400 are preferable from the viewpoint of exhibiting, more preferably 200 to 350. The average number of moles of oxypropylene added in the component (B1) is not particularly limited, but the hair styling ability is excellent by suppressing stickiness of the emulsified hair styling composition and having an appropriate viscosity. 30 to 150 is preferable, and 40 to 100 is more preferable.

  The number average molecular weight of the said component (B1) is 10,000-20000 (namely, 10,000 or more and 20000 or less), and 12000-18000 are preferable. When the number average molecular weight of the component (B1) is 10,000 or more, the emulsified hair styling composition of the present invention exhibits excellent hair styling properties. Moreover, when the number average molecular weight of a component (B1) is 20000 or less, the emulsifying hairdressing composition of this invention exhibits the applicability | paintability which was excellent.

  The viscosity η measured at 30 ° C. using the Brookfield type rotational viscometer of the component (B1) is 15000 to 50000 mPas from the viewpoint of improving the spread of the emulsified hair styling composition and improving the applicability to hair. -S (15000 mPa * s or more and 50000 mPa * s or less) is preferable, More preferably, it is 23000-43000 mPa * s.

  As a commercial item of the said component (B1), the Sanyo Chemical Industries Co., Ltd. make, brand name "New Paul 75H-90000" etc. are mentioned, for example.

(Component (B2): polyoxypropylene sorbit)
The component (B2) is polyoxypropylene sorbit. Only 1 type may be used for a component (B2), and 2 or more types may be used for it.

  The average number of moles of oxypropylene added in the component (B2) is not particularly limited, but the hair styling ability is excellent by suppressing stickiness of the emulsified hair styling composition and having an appropriate viscosity. From the viewpoint of exhibiting, it is preferably 4 or more, more preferably 8 or more, preferably 15 or less, more preferably 12 or less.

  The number average molecular weight of the component (B2) improves the spread of the emulsified hairdressing composition, improves the coatability to the hair, suppresses stickiness of the emulsified hairdressing composition, and the emulsified hairdressing composition From the viewpoint of exhibiting excellent hair styling power by having an appropriate viscosity, it is 300 or more and 1000 or less. The number average molecular weight of the component (B2) is preferably 400 or more. The number average molecular weight of the component (B2) is preferably 800 or less.

  The viscosity η measured at 30 ° C. using the Brookfield type rotational viscometer of the above component (B2) is 8000-30000 mPas from the viewpoint of improving the spreading of the emulsified hair styling composition and improving the applicability to hair. -S (8000 mPa * s or more and 30000 mPa * s or less) is preferable, More preferably, it is 12000-22000 mPa * s.

  As a commercial item of the said component (B2), the Sanyo Chemical Industries Co., Ltd. make, brand name "New Paul SP-750", brand name "Sanix SP-750", etc. are mentioned, for example.

  The content of the component (B) in the emulsified hairdressing composition of the present invention is 5.0 to 30.0% by mass (5.0% by mass or more) with respect to 100% by mass of the emulsified hairdressing composition of the present invention. 30.0% by mass or less), preferably 6.0 to 25.0% by mass. When the content of the component (B) is 5.0% by mass or more, the hair styling power of the emulsified hair styling composition of the present invention is increased. Moreover, stickiness is suppressed because content of a component (B) is 30.0 mass% or less. When content of a component (B) exceeds 30.0 mass%, even if a component (A) is mix | blended, it will become impossible to suppress stickiness. Content of the said component (B) is a total amount of content of all the components (B) in the emulsified hairdressing composition of this invention.

  Although content of the component (B1) in the component (B) in the emulsified hairdressing composition of this invention is not specifically limited, From a viewpoint of improving hairdressing power, it is 60 with respect to 100 mass% of components (B). 0.0-100 mass% is preferable, More preferably, it is 70.0-95.0 mass%.

[Component (C): Nonionic surfactant]
The component (C) is a nonionic surfactant. The said component (C) mainly has the role which makes the emulsified hairdressing composition of this invention an emulsifier type | mold, and provides the refreshing touch at the time of application | coating. Only 1 type may be used for a component (C), and 2 or more types may be used for it.

  Although the said component (C) is not specifically limited, For example, glycerin fatty acid ester, polyglycerin fatty acid ester, ethylene oxide condensate of glycerin fatty acid ester, polyethylene glycol fatty acid ester, propylene glycol fatty acid ester, sorbitan fatty acid ester, sorbitan fatty acid ester Examples include ethylene oxide condensate, polyoxyalkylene alkyl ether, polyoxyethylene hydrogenated castor oil, polyoxyethylene castor oil, and polyoxyethylene lanolin.

  More specifically, for example, glyceryl monocaprylate, glyceryl monocaprate, glyceryl monolaurate, glyceryl monomyristate, glyceryl monopalmitate, glyceryl monostearate, glyceryl monoisostearate, glyceryl monobehenate, glyceryl monooleate Glyceryl fatty acid esters such as glyceryl monoerucate, glyceryl sesquioleate, glyceryl distearate, glyceryl diisostearate, glyceryl diarachiate; diglyceryl monocaprylate, decaglyceryl monocaprylate, hexaglyceryl monocaprate, tetraglyceryl monolaurate, Hexaglyceryl monolaurate, decaglyceryl monolaurate, poly (4-10) glyceryl monolaurate, monomyris Decaglyceryl acid, decaglyceryl monostearate, decaglyceryl monoisostearate, poly (2-10) glyceryl monostearate, diglyceryl monooleate, hexaglyceryl monooleate, diglyceryl sesquioleate, poly (diisostearate poly ( 2-10) polyglyceryl fatty acid ester having a polymerization degree of 2-10, such as glyceryl fatty acid ester described above, such as glyceryl, poly (6-10) glyceryl distearate, diglyceryl triisostearate, poly (10) glyceryl tristearate; mono Ethylene oxide condensate of glycerin fatty acid esters such as polyoxyethylene glyceryl stearate and polyoxyethylene glyceryl monooleate; polyethylene glycol monooleate, polystearate monostearate Polyethylene glycol fatty acid esters such as ethylene glycol and polyethylene glycol monolaurate; Propylene glycol fatty acid esters such as propylene glycol monostearate, propylene glycol monolaurate and propylene glycol monooleate; sorbitan monooleate, sorbitan monostearate, monoisostearic acid Sorbitan fatty acid esters such as sorbitan, sorbitan monopalmitate, sorbitan monolaurate, sorbitan trioleate, sorbitan tristearate, sorbitan sesquistearate, sorbitan sesquioleate, sorbitan sesquiisostearate, coconut oil fatty acid sorbitan; polyoxymonolaurate Ethylene sorbitan, polyoxyethylene monopalmitate Sorbitan, polyoxyethylene sorbitan monostearate, polyoxyethylene sorbitan monooleate, polyoxyethylene sorbitan monoisostearate, monooxy oil fatty acid polyoxyethylene sorbitan, polyoxyethylene sorbitan tristearate, polyoxyethylene sorbitan trioleate Ethylene oxide condensates of sorbitan fatty acid esters such as: polyoxyethylene lauryl ether, polyoxyethylene cetyl ether, polyoxyethylene stearyl ether, polyoxyethylene oleyl ether, polyoxyethylene polyoxypropylene lauryl ether, polyoxypropylene cetyl ether, Polyoxypropylene isocetyl ether, polyoxypropylene stearyl ether, polyoxy Such as polyoxyalkylene alkyl ethers such as B pyrene oleyl ether and the like.

  Although content of the component (C) in the emulsified hairdressing composition of this invention is not specifically limited, From a viewpoint of the emulsification effect, it is 0.30-6 with respect to 100 mass% of emulsified hairdressing composition of this invention. 0.0 mass% is preferable, More preferably, it is 0.50-5.0 mass%. Content of the said component (C) is a total amount of content of all the components (C) in the emulsified hairdressing composition of this invention.

[Component (D): Water]
The component (D) is water. The water is not particularly limited, but purified water is preferable. Since the emulsified hair styling composition of the present invention is an emulsified composition containing water, it becomes fresh and suppresses stickiness. The content of water in the emulsified hairdressing composition of the present invention is not particularly limited, but from the viewpoint of freshness and stickiness suppression, the emulsified hairdressing composition of the present invention is based on 100% by mass of the emulsified hairdressing composition. 30.0-85.0 mass% is preferable, More preferably, it is 40.0-80.0 mass%, More preferably, it is 50.0-75.0 mass%.

[Component (E): Particles selected from the group consisting of silica, calcium carbonate, magnesium carbonate, hydroxyapatite, titanium oxide, zinc oxide, calcium silicate, magnesium silicate, aluminum silicate, and magnesium hydroxide]
The component (E) is at least one selected from the group consisting of silica, calcium carbonate, magnesium carbonate, hydroxyapatite, titanium oxide, zinc oxide, calcium silicate, magnesium silicate, aluminum silicate, and magnesium hydroxide. Particles. The component (E) is preferable because the stickiness-inhibiting effect is further improved, and the hair finish is light after hair styling. As for the said component (E), only 1 type may be used and 2 or more types may be used.

  Among the above components (E), silica, magnesium silicate, and magnesium hydroxide are more preferable from the viewpoint of having a stickiness-inhibiting effect and hair-styling ability.

<Silica>
As the silica, known and commonly used silica (anhydrous silicic acid) can be used. The silica may be silicic anhydride (hydrophilic silica) that has not been hydrophobized or may be hydrophobized silicic anhydride. Further, the silica may be silica surface-treated with amino acid, ester, lecithin or the like. The silica may be so-called easily disintegrating silica particles. As for the said silica, only 1 type may be used and 2 or more types may be used.

  The hydrophobized silicic anhydride is a substance obtained by hydrophobizing silicic anhydride (for example, untreated silicic anhydride). Examples of the treating agent used for the hydrophobizing treatment include organic silyl compounds and silicone compounds. Examples of the organic silyl compound include methyltrichlorosilane, dimethyldichlorosilane, trimethylchlorosilane, hexamethyldisilazane, methyltrialkoxysilane, dimethyldialkoxysilane, trimethylalkoxysilane, ethyltrichlorosilane, propyltrichlorosilane, hexyltrichlorosilane, long Examples include chain alkyltrichlorosilane, ethyltrialkoxysilane, propyltrialkoxysilane, hexyltrialkoxysilane, long chain alkyltrialkoxysilane, methacryl silane, fluoroalkylsilane, and perfluoroalkylsilane. Examples of the silicone compound include dimethylpolysiloxane (silicone oil), methylphenylpolysiloxane, methylhydrogenpolysiloxane, and amino-modified silicone. The method for the hydrophobic treatment is not particularly limited, and a known method can be used. Examples of the hydrophobic treatment method include a liquid phase method, a gas phase method, and an autoclave method.

  Preferred examples of the hydrophobic silicic anhydride include dimethylsiloxylated silicic anhydride, trimethylsiloxylated silicic anhydride, octylsiloxylated silicic anhydride, silicone oil treated silicic anhydride and methacrylsiloxylated silicic anhydride. Etc.

  The easily disintegratable silica particles are particles formed by aggregating a plurality of silica primary particles. Although it does not specifically limit as said silica primary particle, For example, a spherical silica particle, a scaly silica particle, an amorphous silica particle, etc. are mentioned. The average particle diameter of the silica primary particles is not particularly limited.

  Moreover, the said easily disintegrable silica particle may include components other than a silica. The component other than the silica (hereinafter may be referred to as “encapsulated component”) is not particularly limited, and examples thereof include surfactants, polyhydric alcohols, higher alcohols, sugar alcohols, silicone oils, sequestering agents, Examples include antioxidants, plant extracts, dyes, pigments, fragrances, moisturizers, vitamins, amino acids, and refreshing agents. Of these, amino acids, silicone oils, and vitamins are preferable. Although it does not specifically limit as said amino acids, Dilauroyl glutamate ricin Na (For example, Asahi Kasei Chemicals make, brand name "Perisea"), a trimethylglycine, glutamic acid, etc. are mentioned. When the easily disintegratable silica particles encapsulate the inclusion component, the inclusion component is released when the easily disintegratable silica particles are disintegrated during hair styling, and an effect corresponding to the type of the inclusion component is exhibited. For example, the easily disintegratable silica particles encapsulate amino acids, thereby exhibiting a hair damage care function.

  It does not specifically limit as a manufacturing method of the said easily disintegrating silica particle, A well-known method can be used.

  The silica oil absorption is preferably 100 mL / 100 g or more, more preferably 150 mL / 100 g or more, still more preferably 200 mL / 100 g or more, preferably 1000 mL / 100 g or less, more preferably 800 mL / 100 g or less, more preferably 700 mL / 100 g or less. When the oil absorption amount of the silica is not less than the above lower limit and not more than the above upper limit, the initial hair styling power, the hair styling holding power and the re-hair styling property are further improved. The oil absorption is measured according to the method described in JIS K5101.

  Examples of the commercially available silica include, for example, silica silicic acid manufactured by Fuji Silysia Chemical Co., Ltd., trade name “Silisia 320”, trade name “Silisia 310P”, trade name “Silicia 250”, trade name “Silicia 250N”, Product name “Siricia 350”, product name “Sylithia 370”, product name “Sylithia 380”, product name “Sylithia 420”, product name “Siricia 430”, product name “Siricia 440”, product name “Siricia 450”, and product Product name “AerOSIL 50”, product name “AEROSIL 90G”, product name “AEROSIL 130”, product name “AEROSIL 150”, product name “AEROSIL 200” manufactured by Nippon Aerosil Co., Ltd., which is silicic anhydride. ", Product name" AEROSIL 300 ”, trade name“ AEROSIL 380 ”, trade name“ AEROSIL 200V ”, and trade name“ AEROSIL OX50 ”; manufactured by AGC S-Itech Co., Ltd., which is silicic anhydride, trade name“ Sunsphere H-31 ”, trade name“ Sance ” Fair name H-51, trade name "Sunsphere H-121", trade name "Sunsphere H-201", trade name "Sunsphere H-32", trade name "Sunsphere H-52", trade name "Sance Fair H-122 ”, trade name“ Sunsphere H-33 ”and trade name“ Sunsphere H-53 ”; Nippon Aerosil Co., Ltd., which is dimethylsiloxylated silicic acid, trade name“ AEROSIL R972 ”, trade name “AEROSIL R974” and trade name “AEROSIL R9200”; trimethylsiloxyl Nippon Aerosil Co., Ltd. which is silicic anhydride, trade name “AEROSIL RX200”, trade name “AEROSIL R8200”, trade name “AEROSIL RX300” and trade name “AEROSIL R812S”; Nippon Aerosil which is octylsiloxylated silicic anhydride Product name “AEROSIL R805” manufactured by Nippon Aerosil Co., Ltd., a silicone oil-treated silicic acid product, product name “AEROSIL R202”, product name “AEROSIL RY200”, product name “AEROSIL RY200S” and product name “AEROSIL” “RY300”; Nippon Aerosil Co., Ltd., which is methacrylsiloxylated silicic anhydride, trade name “AEROSIL R711”; Miyoshi Kasei Co., Ltd., trade name “Silica Bee” SB-705 "; the above-mentioned easily disintegrating silica manufactured by Suzuki Oil & Fats Co., Ltd., trade name" God Ball SF-16C ", trade name" God Ball AF-6C ", trade name" God Ball AF-16C ", etc. Can be mentioned.

<Calcium carbonate>
The said calcium carbonate is represented by the INCI name "CALCIUM CARBONATE", for example. As for the said calcium carbonate, only 1 type may be used and 2 or more types may be used.
As a commercial item of the said calcium carbonate, Sakai Chemical Industry Co., Ltd. product name "Karumaru SCS M5"; Shiraishi Calcium Co., Ltd. product name "Fuwakal" etc. are mentioned, for example.

<Magnesium carbonate>
The magnesium carbonate is represented by, for example, the INCI name “MAGNESIUM CARBONATE”. As for the said magnesium carbonate, only 1 type may be used and 2 or more types may be used.
As a commercial item of the said magnesium carbonate, the Tomita Pharmaceutical Co., Ltd. make, brand name "light magnesium carbonate" etc. are mentioned, for example.

<Hydroxyapatite>
The hydroxyapatite is represented by, for example, the INCI name “HYDROXYAPATITE”. As for the said hydroxyapatite, only 1 type may be used and 2 or more types may be used.
The hydroxyapatite is not particularly limited, and examples thereof include spherical hydroxyapatite, plate-like hydroxyapatite, and amorphous hydroxyapatite. Among these, spherical hydroxyapatite is preferable from the viewpoint of high hair styling performance.
As a commercial item of the said hydroxyapatite, brand name "plate-shaped HAP", brand name "spherical HAP", brand name "HAP-100", brand name "HAP-200", brand name "HAP-300" ( All of them are manufactured by Taihei Chemical Industry Co., Ltd.).

<Titanium oxide>
The titanium oxide is represented by, for example, the INCI name “TITANIUM DIOXIDE”. The titanium oxide is not particularly limited, and may be fine particle titanium oxide or pigment titanium, for example. As for the said titanium oxide, only 1 type may be used and 2 or more types may be used.
As a commercial item of the said titanium oxide, Ishihara Sangyo Co., Ltd. make, brand name "TTO-55 (A)", brand name "CR-50", etc. are mentioned, for example.

<Zinc oxide>
The zinc oxide is represented by, for example, the INCI name “ZINC OXIDE”. As for the said zinc oxide, only 1 type may be used and 2 or more types may be used.
As a commercial item of the said zinc oxide, Sakai Chemical Industry Co., Ltd. make, brand name "FINEX-30S-LP2" etc. are mentioned, for example.

<Calcium silicate>
The calcium silicate is represented, for example, by the INCI name “CALCIUM SILICATE”. As for the said calcium silicate, only 1 type may be used and 2 or more types may be used.
Commercially available products of the above calcium silicate include, for example, Tomita Pharmaceutical Co., Ltd., trade name “Calcium Silicate Fluorite R”; Nippon Insulation Co., Ltd., trade name “Zonotolite Powder XJ”, trade name “Tobermorite Powder TK”. Or the like.

<Magnesium silicate>
The magnesium silicate is represented by, for example, the INCI name “MAGNESIUM SILICATE”. As for the said magnesium silicate, only 1 type may be used and 2 or more types may be used.
As a commercial item of the said magnesium silicate, the Tomita Pharmaceutical Co., Ltd. make, brand name "magnesium silicate (light)" etc. are mentioned, for example.

<Aluminum silicate>
The aluminum silicate is represented by, for example, the INCI name “ALUMINUM SILICATE”. As for the said aluminum silicate, only 1 type may be used and 2 or more types may be used. Although it does not specifically limit as an aluminum silicate, A synthetic aluminum silicate is preferable. Synthetic methods include, for example, a method of adding Na ₂ SiO ₃ to alum and drying the generated precipitate, a method of forming a silicate sol by electrodialysis, and generating a gel by this, or an aluminum salt in water glass A method of adding an aqueous solution of
As a commercial item of the said aluminum silicate, the Tomita Pharmaceutical Co., Ltd. make, brand name "synthetic aluminum silicate (heavy)" etc. are mentioned, for example.

<Magnesium hydroxide>
The magnesium hydroxide is represented by, for example, the INCI name “MAGNESIUM HYDROXIDE”. As for the said magnesium hydroxide, only 1 type may be used and 2 or more types may be used.
As a commercial item of the said magnesium hydroxide, the Tomita Pharmaceutical Co., Ltd. make, brand name "magnesium hydroxide (heavy)" etc. are mentioned, for example.

  Although content of the component (E) in the emulsified hairdressing composition of this invention is not specifically limited, 0.02-3.0 mass% is preferable with respect to 100 mass% of emulsified hairdressing composition of this invention. More preferably, it is 0.05-2.0 mass%. When the content of the component (E) is 0.02% by mass or more, the stickiness of the hair after styling is further suppressed. Moreover, when content of a component (E) is 3.0 mass% or less, the hair-styling power of the emulsified hair-styling composition of this invention becomes still higher. If the content of the component (E) exceeds 3.0% by mass, the hair after styling may become dry, and the unity may be reduced, and the styling power may be reduced. Content of the said component (E) is a total amount of content of all the components (E) in the emulsified hair-styling composition of this invention.

[Other ingredients]
The emulsified hairdressing composition of the present invention may contain components (other components) other than the components (A) to (E). Examples of other components include surfactants other than component (C) (cationic surfactants, anionic surfactants, amphoteric surfactants, etc.); powders other than component (E); ethylene glycol , Diethylene glycol, triethylene glycol, polyethylene glycol, propylene glycol, dipropylene glycol, polypropylene glycol, isoprene glycol, 1,3-butylene glycol, 1,2-butanediol, 1,2-pentanediol, 1,2-hexanediol , 1,2-octanediol, 1,2-decanediol, polyhydric alcohols such as glycerin, diglycerin and polyglycerin; carboxyvinyl polymer, acrylic acid / alkyl methacrylate copolymer, hydroxymethylcellulose, hydroxypropylmethyl Water-soluble thickeners such as loin and xanthan gum; sugar alcohols such as sorbitol and maltitol; moisturizers such as hyaluronic acid, collagen and pantothenyl alcohol; preservatives such as methylparaben, propylparaben, butylparaben and benzoate; ethanol PH adjusting agents such as phosphoric acid and its salts, citric acid and its salts, lactic acid and its salts, sodium hydroxide and triethanolamine; fragrances; ultraviolet absorbers; dyes; inorganic pigments; antioxidants; Vitamins; animal and plant extracts; sequestering agents and the like. Among these, polyethylene glycol, carboxyvinyl polymer, and acrylic acid / alkyl methacrylate copolymer are preferable. Only 1 type may be used for the said other component, and 2 or more types may be used for it.

  The emulsified hair styling composition of the present invention preferably contains substantially no film-forming polymer. Examples of the film-forming polymer include polyvinyl pyrrolidone, vinyl pyrrolidone / vinyl acetate copolymer, vinyl pyrrolidone / methacrylamide / vinyl imidazole copolymer, (meth) acrylic acid alkyl copolymer, (meth) acrylic acid / ( (Meth) alkyl acrylate copolymer, acrylic resin alkanolamine, vinylpyrrolidone / N, N-dimethylaminoethyl methacrylic acid copolymer diethyl sulfate, N-methacryloyloxyethyl N, N-dimethylammonium-α-N-methyl Carboxybetaine / methacrylic acid alkyl ester copolymer, N, N dimethyl-N- (2-methacryloyloxyethyl) amine = N-oxide / methacrylic acid alkyl ester copolymer, and the like.

  In the present specification, “substantially does not contain” a film-forming polymer means “does not actively contain” a film-forming polymer, and a trace amount contained in other compounding components. It is not excluded that the film-forming polymer is inevitably included. More specifically, the content of the film-forming polymer (particularly, the film-forming polymer exemplified above) in the emulsified hairdressing composition of the present invention is based on 100% by mass of the emulsified hairstyling composition of the present invention. It is preferable that it is 0.01 mass% or less (namely, 0-0.01 mass%), More preferably, it is 0.005 mass% or less. When a film-forming polymer is contained in the hairdressing composition, the moist feeling of the hair after hairdressing may be reduced, or itching may occur and the touch may be deteriorated.

  It is preferable that the emulsified hairdressing composition of the present invention is solid at 25 ° C. and does not substantially contain an oil selected from the group consisting of hydrocarbon oils, waxes, and fats and oils. In the present specification, “solid form at 25 ° C.” means, for example, a 50 g sample (oil agent) heated and dissolved in a glass bottle having a radius of 2 cm and a height of 7 cm, cooled to 25 ° C. When the glass bottle is inverted, it means that the sample does not sag from the glass bottle for 5 minutes immediately after being inverted. Hereinafter, the “oil agent selected from the group consisting of hydrocarbon oils, waxes, and fats and oils that are solid at 25 ° C.” may be referred to as “specific oil agent that is solid at 25 ° C.”. Examples of the above-mentioned specific oil solid at 25 ° C. include carnauba wax, candelilla wax, beeswax, rice bran wax, shellac wax, whale wax, lanolin, ceresin, paraffin, microcrystalline wax, polyethylene powder, polyethylene wax, petrolatum, hydrogenated castor oil. And owls.

  In the present specification, “substantially does not contain” the solid specific oil agent at 25 ° C. means “does not actively contain” the solid specific oil agent at 25 ° C., It is not excluded to the extent that a small amount of a specific oil agent unavoidably contained at 25 ° C. contained in other blending components. More specifically, the content of the specific oil agent solid at 25 ° C. (particularly, the specific oil agent solid at 25 ° C. exemplified above) in the emulsified hairdressing composition of the present invention is determined by the emulsified hairstyling of the present invention. It is preferable that it is 0.05 mass% or less (namely, 0-0.05 mass%) with respect to 100 mass% of agent composition, More preferably, it is 0.01 mass% or less. When the hairdressing composition contains a solid specific oil at 25 ° C., the hairdressing composition at the time of hairstyling may deteriorate and the hair may become sticky after hairdressing.

[Production method, use, properties, etc. of emulsified hairdressing composition of the present invention]
The manufacturing method of the emulsified hair conditioner composition of this invention is not specifically limited, A well-known manufacturing method can be used. For example, the emulsified hair styling composition of the present invention can be produced by mixing the above-mentioned components and emulsifying by a phase inversion emulsification method using a homomixer. Moreover, mixing and emulsification may be performed separately or simultaneously. More specifically, for example, the heated mixture of the component (B) and the component (D) was added to the heated mixture of the component (A) and the component (C) while stirring with a homomixer, and then cooled to obtain. It can manufacture by adding a component (E) to an emulsion.

  The dosage form of the emulsified hairdressing composition of the present invention is not particularly limited, and examples thereof include emulsions and creams. Among these, an emulsion is preferable. The emulsified hairdressing composition of the present invention is an emulsified composition. By being an emulsified composition, a fresh touch can be imparted at the time of application.

  The viscosity at 25 ° C. of the emulsified hairdressing composition of the present invention is preferably 2000 to 30000 mPa · s, more preferably 4000 to 15000 mPa · s, from the viewpoints of applicability and non-stickiness. The above viscosity was measured using a viscometer, No. 4 rotor or no. The measurement is performed under the conditions of a rotation speed of 12 rpm and a rotation time of 1 minute using 3 rotors. A TV-22 type viscometer manufactured by Toki Sangyo Co., Ltd. can be used as the viscometer.

The emulsified hair styling composition of the present invention is characterized in that the component (B) is used as a main hair styling component in an emulsifier type. Since it is used as a main hair styling component, the emulsified hair styling composition of the present invention contains a relatively large amount of the component (B). Since the component (B) has a viscous property, the hair is tightly gathered and exhibits high hair styling power. On the other hand, since it does not solidify like a film-forming polymer and does not become hard after coating, there is no itchiness after hair styling as in the case of using a film-forming polymer, and the touch of hair after styling becomes good. In addition, the component (B) has good stretchability during hair styling, excellent coatability, and less stickiness after hair styling compared to solid hair styling components.
Furthermore, since component (B) has relatively high hydrophilicity, it exists in the matrix phase (outer phase) in the emulsification system. For this reason, the emulsified hair styling composition of the present invention exhibits a hair styling effect relatively quickly after application, so that it can be fastened (that is, it can quickly bundle hair bundles and form a desired wave), Usability is further improved. On the other hand, when a lipophilic hair styling component such as a liquid oil is used, the hair styling component is present in the particle phase (inner phase) in the emulsification system, so that the onset of the hair styling effect is slower than in the present invention. Become.
In addition, the emulsified hair styling composition of the present invention using component (B) is particularly excellent in storage stability.

Moreover, in the emulsified hairdressing composition of the present invention, by using a specific amount of the component (A), the stickiness after hairstyling caused by using a relatively large amount of the component (B) is suppressed, It is compatible with no stickiness. Ingredient (A) inhibits the hairs from sticking to each other, thereby imparting a certain degree of smoothness to the hair after styling and improving the touch. Moreover, the hair-styling power is further improved by a synergistic effect with the component (B).
Furthermore, when the component (E) is used, the effect of suppressing stickiness after styling is further improved. In addition, the hair styling power is further improved.

  The emulsified hair conditioner composition of the present invention is used as a hair conditioner for preparing hair. Among them, since it has high hair-styling ability and can adjust hair with a soft and smooth feel, it is preferably used as a hair-styling agent for middle hair, long hair, and permanent hair.

  Hereinafter, the present invention will be specifically described with reference to Examples and Comparative Examples. The present invention is not limited only to the following examples.

  In the examples and comparative examples, the following components were used.

(Ingredient (A))
Liquid paraffin: Trade name “CARNATION”, manufactured by Sonneborn Inc. Isononyl isononanoate: Trade name “Saracos 99”, Nisshin Oillio Group Co., Ltd. Methylphenylpolysiloxane: Trade name “KF-56A”, manufactured by Shin-Etsu Chemical Co., Ltd., Diphenylsiloxyphenyl trimethicone (oil agent other than component (A) (specific oil agent solid at 25 ° C.))
Vaseline: trade name “WHITE PROTOPET 1S”, manufactured by Sonneborn Inc. Candelilla wax: trade name “refined candelilla wax R-2CG”, manufactured by Mitsuba Trading Co., Ltd. (component (B))
Polyoxyethylene polyoxypropylene hexylene glycol ether: trade name “New Paul 75H-90000”, manufactured by Sanyo Chemical Industries, Ltd., number average molecular weight 14000
Polyoxypropylene sorbit: trade name “Sanix SP-750”, manufactured by Sanyo Chemical Industries, Ltd., number average molecular weight 690, viscosity (30 ° C.) 12000-22000 mPa · s
(Ingredient (C))
Sorbitan monostearate: trade name “SS-10V”, manufactured by Nippon Surfactant Co., Ltd. Polyoxyethylene cetyl ether: trade name “Brownon CH-320L”, manufactured by Koyo Fine Chemical Co., Ltd. (component (D))
Purified water (component (E))
Silica: Trade name “Silicia 320”, manufactured by Fuji Silysia Chemical Ltd. (Other)
Carboxyvinyl polymer: Trade name “Hibiswako 104”, Wako Pure Chemical Industries, Ltd. Triethanolamine: Trade name “TEA-99”, Japan Chemtech Co., Ltd.

(Examples 1 to 10)
The blending ingredients shown in Table 1 below were blended to prepare an emulsified hair conditioner composition. Specifically, the heated mixture of component (B), component (D) and carboxyvinyl polymer is added to the heated mixture of component (A) and component (C) while stirring with a homomixer, and triethanolamine is used. After neutralization, the mixture was cooled and component (E) was added to the resulting emulsion to prepare an emulsified hairdressing composition. The properties of the obtained emulsified hairdressing composition were emulsions. In addition, the compounding quantity in a table | surface was shown with the amount of active ingredients (The compounding quantity of each component, a compounding unit is the mass%).

(Comparative Examples 1-5)
In the same manner as in the Examples, the components shown in Table 2 below were blended (the blending unit was mass%) to prepare an emulsified hair styling composition.

  The emulsified hairdressing composition obtained in Examples and Comparative Examples was filled in a plastic container to obtain a hairdressing agent.

(Test Example 1: Evaluation of spread)
10 professional panelists answered that the above emulsified hair styling composition was applied evenly to the hair of a medium hair wig (Lesson Mannequin: Eucalyptus Japan Co., Ltd.) with perm. did. From the above answers, the following criteria were used to evaluate the spread.
<Evaluation criteria for Nobi>
○ (Good): 8 or more out of 10 responded that the spread was good. △ (Inadequate): 5-7 out of 10 responded that the spread was good. × (Bad): 4 or less out of 10 , Answer is good

(Test Example 2: Evaluation of hair styling power)
10 professional panels applied the emulsified hair styling composition in Test Example 1 above to the permeated medium hair wig (Lesson Mannequin: manufactured by Eucalyptus Japan Co., Ltd.), and then emulsified hair styling so that the hair is lifted from below. The presence or absence of hair-styling power when the hair-dressing composition was squeezed into hair was answered. In addition, it was determined that there was a hairstyling ability when a beautiful wave was created by incorporating the emulsified hairdressing composition, and the wave persisted after 6 hours. From the above answers, hair styling power was evaluated according to the following criteria.
<Evaluation criteria for hair styling power>
○ (Good): 8 or more out of 10 responded that they have hair styling ability △ (Inadequate): 5 to 7 out of 10 responded that they had hair styling ability × (Poor): 4 out of 10 persons The following responded that there is hair styling power

(Test Example 3: Touch evaluation)
Ten professional panels answered that the hair feels right after styling in Test Example 2 (no itchiness or stickiness). From the above answers, the touch was evaluated according to the following criteria.
<Evaluation criteria for touch>
○ (Good): 8 or more out of 10 responded that the touch was good △ (Insufficient): 5-7 out of 10 responded that the touch was good × (Poor): 4 or less out of 10 , The feel is good

(Test Example 4: Evaluation of speed of habiting)
Ten expert panels answered the speed of kinking when the hair was adjusted in Test Example 2 above. In addition, compared with the case where the hair wax of the following prescription was similarly used for hair shaping, it was determined that the habit was fast when the hair wax could be equalized or faster than the hair wax. From the above answers, the speed of habiting was evaluated according to the following criteria.
<Prescription of hair wax>
Candelilla wax 5.0% by mass
Paraffin wax 11.0% by mass
High melting point microcrystalline wax 4.0% by mass
Liquid paraffin 8.0% by mass
Squalane 8.0% by mass
Polyoxyethylene (10) oleyl alcohol ether 5.0% by mass
Stearyl alcohol 0.5% by mass
1,3-butylene glycol 5.0% by mass
Carboxyvinyl polymer 0.3% by mass
Triethanolamine 0.3% by mass
Purified water 52.9% by mass
Total 100.0% by mass
<Evaluation criteria for speed of habit>
○ (Good): 8 or more out of 10 responded that the clinging was fast △ (Inadequate): 5-7 out of 10 responded that the clinging was fast × (Bad): 4 out of 10 The following is a quick answer

  The results are shown in Tables 1-2 below.

A prescription example is shown below.
(Prescription example)
Liquid paraffin 3.0% by mass
Methylphenylpolysiloxane 3.0% by mass
Methyl polysiloxane (350cs) 1.0 mass%
Isononyl isononanoate 3.0% by mass
Argan oil 1.0% by mass
Polyoxyethylene polyoxypropylene hexylene glycol ether (300EO) (75PO) 20.0 mass%
Sorbitan monostearate 2.0% by mass
Polyoxyethylene cetyl ether (20E.O.) 2.0 mass%
Silica 0.2% by mass
Carboxyvinyl polymer 0.2% by mass
Triethanolamine 0.2% by mass
Polyethylene glycol 400 7.0% by mass
1,3-butylene glycol 5.0% by mass
Ethanol 5.0% by mass
Edetic acid disodium 0.05 mass%
Methylparaben 0.8% by mass
Perfume appropriate amount Purified water balance 100% by mass

Claims (2)

Following components (A), comprising the following components (B), the following components (C), under Symbol Component (D), and the following component (E),
The content of the component (A) is 3.0 to 30.0% by mass,
Content of the said component (B) is 5.0-30.0 mass%, The emulsified hair-styling composition characterized by the above-mentioned.
Component (A): Oil agent liquid at 25 ° C. Component (B): The following component (B1), or the following component (B1) and the following component (B2)
Component (C): Nonionic surfactant (however, polyoxyethylene / polyoxypropylene copolymer is excluded as a nonionic surfactant, and polyoxypropylene sorbit is excluded as a nonionic surfactant)
Ingredient (D): Water
Component (E): Particle component (B1) selected from the group consisting of silica, calcium carbonate, magnesium carbonate, hydroxyapatite, titanium oxide, zinc oxide, calcium silicate, magnesium silicate, aluminum silicate, and magnesium hydroxide : Polyoxyethylene / polyoxypropylene copolymer having a number average molecular weight of 10,000 to 20,000 Component (B2): Polyoxypropylene sorbit having a number average molecular weight of 300 to 1,000   The emulsified hair conditioner composition according to claim 1, wherein the component (A) is an oil agent selected from the group consisting of hydrocarbon oil, silicone oil, fatty acid ester oil, higher alcohol, and fats and oils.