JP6013587B2 - Hairdressing composition - Google Patents

Description

  The present invention relates to a hair styling composition that is suitably used for a hair styling agent for shaping hair.

  In order to prepare hair, hair conditioner compositions having various properties such as liquid, gel, cream, and solid are used. Conventionally, a film-forming polymer is often used for imparting hair-styling power, which is a main function, to a hair-styling composition. However, when an effective amount of the film-forming polymer is blended, the initial hair styling power immediately after hair styling is increased, while the hair styling composition composition on the hair becomes unsuitable and unfit, and stickiness occurs. . Moreover, in the hairdressing composition using a film-forming polymer, a film is formed on the surface of the hair after hair styling, derived from the film-forming polymer. For this reason, it is difficult to prepare the hair in a natural state, and when the hair is stimulated with hands or a comb after hair styling, the film peels off from the surface of the hair (so-called flaking occurs), Hair styling power is easily reduced.

  In order to solve such problems, it has been studied to increase the flexibility of a film formed from a film-forming polymer. Patent Document 1 below discusses the use of silicones as a plasticizer in a hairdressing composition containing a film-forming polymer.

  In addition, a method different from the method using a film-forming polymer has been studied, and specifically, it has been studied to impart hair-styling power to a hair-styling composition using a powder.

Patent Document 2 below discloses a hair cosmetic (hairdressing composition) containing 0.1 to 10% by mass of a fine particle powder having a specific surface area of 50 m ² / g or more. In Patent Document 2, by using the specific fine particle powder at a specific content, a good feel can be obtained, an excellent hair styling power can be obtained, and a good feel can be maintained for a long time, and an excellent It describes that hair styling properties can be obtained.

JP 2001-240519 A JP 2003-342130 A

  In the hairdressing composition described in Patent Document 1, the flexibility of the film formed from the film-forming polymer is increased to some extent. As a result, the usability of the hairdressing composition is improved to some extent. However, as the flexibility of the film is improved, there is a problem in that the function of maintaining the hair-styled state for a long time is lowered. That is, when the hair is formulated using the hair styling composition described in Patent Document 1, the hair styling holding power may not be sufficiently high.

  In addition, as described in Patent Document 2, even when hair is stipulated using a hair styling composition containing fine particle powder, the hair styling holding power may not be sufficiently high.

  Furthermore, when the viscosity of the composition is not sufficiently high and the applicability of the composition during hair styling is reduced, or when the storage stability is reduced due to separation of powder and liquid components in the composition There is.

  An object of the present invention is to provide a hair styling composition that is excellent in hair styling holding power, coating properties, and storage stability.

The hairdressing composition according to the present invention includes the following component (A), the following component (B), the component (C) that is a polymer selected from the group consisting of the following component (C1) and the following component (C2). And a content of the component (A) is 0.1% by mass or more and 10% by mass or less.
Component (A): Particles selected from the group consisting of silica, calcium carbonate, magnesium carbonate, hydroxyapatite, titanium oxide, zinc oxide, calcium silicate, magnesium silicate, aluminum silicate, and magnesium hydroxide Component (B) : Clay mineral Component (C1): Polymer obtained using two or more monomers selected from the group consisting of (meth) acrylic acid and (meth) acrylic acid alkyl ester as the essential monomer component (C2): As an essential monomer component, a monomer selected from the group consisting of (meth) acrylic acid and (meth) acrylic acid alkyl ester, (meth) acrylic acid polyoxyethylene alkyl ether, itaconic acid polyoxyethylene alkyl ether, and Mono selected from the group consisting of vinyl neodecanoate Polymers obtained by using the chromatography

  In the hairdressing composition according to the present invention, the total amount of the component (B) and the component (C) is preferably 0.2% by mass or more and 10% by mass or less.

  In the hairdressing composition according to the present invention, the mass ratio of the content of the component (B) and the content of the component (C) is preferably 0.1: 1 to 30: 1.

The hairdressing composition according to the present invention preferably further contains the following component (D).
Component (D): Compound selected from the group consisting of polyoxyalkylene alkyl glucoside and polyoxyalkylene glycerin fatty acid ester

The hairdressing composition according to the present invention preferably further contains the following component (E).
Component (E): Polyethylene glycol

  The hairdressing composition according to the present invention contains specific components (A), (B), and (C), and the content of the component (A) is within a specific range. Is good, and exhibits excellent hair holding ability after hair styling. Furthermore, it exhibits excellent storage stability.

  Hereinafter, the present invention will be described in detail.

  The first polymer is a polymer obtained using two or more monomers selected from the group consisting of (meth) acrylic acid and (meth) acrylic acid alkyl ester as an essential monomer component. A monomer selected from the group consisting of (meth) acrylic acid and (meth) acrylic acid alkyl ester, (meth) acrylic acid polyoxyethylene alkyl ether, itaconic acid poly, as an essential monomer component, the second polymer A polymer obtained by using a monomer selected from the group consisting of oxyethylene alkyl ether and vinyl neodecanoate.

  The hairdressing composition according to the present invention was selected from the group consisting of silica, calcium carbonate, magnesium carbonate, hydroxyapatite, titanium oxide, zinc oxide, calcium silicate, magnesium silicate, aluminum silicate, and magnesium hydroxide. Particles, clay minerals, and a polymer selected from the group consisting of the first polymer and the second polymer.

  In the present specification, the above-mentioned “particles selected from the group consisting of silica, calcium carbonate, magnesium carbonate, hydroxyapatite, titanium oxide, zinc oxide, calcium silicate, magnesium silicate, aluminum silicate, and magnesium hydroxide” May be referred to as “component (A)”. Further, the “clay mineral” may be referred to as “component (B)”. Furthermore, in the present specification, the “polymer selected from the group consisting of the first polymer and the second polymer” may be referred to as “component (C)”. The “first polymer” may be referred to as “component (C1)”, and the “second polymer” may be referred to as “component (C2)”. “(Meth) acrylic acid” means one or both of acrylic acid and methacrylic acid.

  The hairdressing composition according to the present invention preferably further contains a compound selected from the group consisting of polyoxyalkylene alkyl glucoside and polyoxyalkylene glycerin fatty acid ester.

  In the present specification, the “compound selected from the group consisting of polyoxyalkylene alkyl glucoside and polyoxyalkylene glycerin fatty acid ester” may be referred to as “component (D)”. Further, the “polyoxyalkylene alkyl glucoside” may be referred to as “component (D1)”, and the “polyoxyalkylene glycerin fatty acid ester” may be referred to as “component (D2)”.

  The hairdressing composition according to the present invention preferably further contains polyethylene glycol. In the present specification, the “polyethylene glycol” may be referred to as “component (E)”.

  That is, the hairdressing composition according to the present invention includes at least a component (A), a component (B), and a component (C). The hairdressing composition according to the present invention preferably further comprises a component (at least one component) selected from the group consisting of component (D) and component (E). Especially, it is preferable that the hairdressing composition which concerns on this invention contains all of a component (A), a component (B), a component (C), a component (D), and a component (E). The hairdressing composition according to the present invention may further contain other components. Only one kind of each of the above components, for example, the component (A), the component (B), the component (C), the component (D), the component (E), and the other component may be used. More than species may be used.

  The component (C) is a polymer (at least one polymer) selected from the group consisting of the component (C1) and the component (C2). The component (D) is a compound (at least one compound) selected from the group consisting of the component (D1) and the component (D2). As for said component (C1), a component (C2), a component (D1), and a component (D2), only 1 type may respectively be used and 2 or more types may be used.

  Hereinafter, the detail of each component used for the hairdressing agent composition which concerns on this invention is demonstrated.

(Ingredient (A))
The component (A) is a particle selected from the group consisting of silica, calcium carbonate, magnesium carbonate, hydroxyapatite, titanium oxide, zinc oxide, calcium silicate, magnesium silicate, aluminum silicate, and magnesium hydroxide. . The component (A) mainly has a role of suppressing stickiness and increasing initial hair styling power and hair styling holding power (particularly hair styling holding power). Further, by using the component (A), it is possible to facilitate hair styling again after hair styling once and to improve re-hair styling, as compared with the case where a film-forming polymer is used.

  As said component (A), from a viewpoint which makes hairdressing performance favorable especially, from the group which consists of a silica, a hydroxyapatite, a titanium oxide, a zinc oxide, a calcium silicate, a magnesium silicate, an aluminum silicate, and magnesium hydroxide. Selected particles (at least one particle) are preferred, and particles (at least one particle) selected from the group consisting of silica and magnesium hydroxide are more preferred. As for the said component (A), only 1 type may be used and 2 or more types may be used.

<Silica>
As the silica, known and commonly used silica (anhydrous silicic acid) can be used. The silica may be silicic anhydride (hydrophilic silica) that has not been hydrophobized or may be hydrophobized silicic anhydride. The silica may be silica that has been surface-treated with an amino acid, an ester, lecithin, or the like. The silica may be so-called easily disintegrating silica particles. As for the said silica, only 1 type may be used and 2 or more types may be used.

  The hydrophobized silicic anhydride is a substance obtained by hydrophobizing silicic anhydride (for example, untreated silicic anhydride). Examples of the treating agent used for the hydrophobizing treatment include organic silyl compounds and silicone compounds. Examples of the organic silyl compound include methyltrichlorosilane, dimethyldichlorosilane, trimethylchlorosilane, hexamethyldisilazane, methyltrialkoxysilane, dimethyldialkoxysilane, trimethylalkoxysilane, ethyltrichlorosilane, propyltrichlorosilane, hexyltrichlorosilane, long Examples include chain alkyltrichlorosilane, ethyltrialkoxysilane, propyltrialkoxysilane, hexyltrialkoxysilane, long chain alkyltrialkoxysilane, methacryl silane, fluoroalkylsilane, and perfluoroalkylsilane. Examples of the silicone compound include dimethylpolysiloxane (silicone oil), methylphenylpolysiloxane, methylhydrogenpolysiloxane, and amino-modified silicone. A publicly known method can be adopted as a method of the above-mentioned hydrophobic treatment. Examples of the hydrophobic treatment method include a liquid phase method, a gas phase method, and an autoclave method.

  Preferred examples of the hydrophobized silicic anhydride include dimethylsiloxylated silicic anhydride, trimethylsiloxylated silicic anhydride, octylsiloxylated silicic anhydride, silicone oil-treated silicic anhydride and methacrylsiloxylated silicic anhydride. Etc.

  The easily disintegratable silica particles are particles formed by aggregating a plurality of silica primary particles. Although it does not specifically limit as said silica primary particle, For example, a spherical silica particle, a scaly silica particle, an amorphous silica particle, etc. are mentioned. The average particle diameter of the silica primary particles is not particularly limited.

  Moreover, the said easily disintegrable silica particle may include components other than a silica. The component other than the silica (hereinafter may be referred to as “encapsulated component”) is not particularly limited, and examples thereof include surfactants, polyhydric alcohols, higher alcohols, sugar alcohols, silicone oils, sequestering agents, Examples include antioxidants, plant extracts, dyes, pigments, fragrances, moisturizers, vitamins, amino acids, and refreshing agents. Of these, amino acids, silicone oils, and vitamins are preferable. Although it does not specifically limit as said amino acids, Dilauroyl glutamate ricin Na (For example, the product name "Perisea" by Asahi Kasei Chemicals Corporation), a trimethylglycine, glutamic acid, etc. are mentioned. When the easily disintegratable silica particles encapsulate the inclusion component, the inclusion component is released when the easily disintegratable silica particles are disintegrated during hair styling, and an effect corresponding to the type of the inclusion component is exhibited. For example, the easily disintegratable silica particles encapsulate amino acids, thereby exhibiting a hair damage care function.

  It does not specifically limit as a manufacturing method of the said easily disintegrating silica particle, A well-known method can be used.

  The silica oil absorption is preferably 100 mL / 100 g or more, more preferably 150 mL / 100 g or more, still more preferably 200 mL / 100 g or more, preferably 1000 mL / 100 g or less, more preferably 800 mL / 100 g or less, more preferably 700 mL / 100 g or less. When the oil absorption amount of the silica is not less than the above lower limit and not more than the above upper limit, the initial hair styling power, the hair styling holding power, and the re-hair styling property are further improved. The oil absorption is measured according to the method described in JIS K5101.

  Examples of commercially available products of the silica include silica silicic acid manufactured by Fuji Silysia Chemical Co., Ltd., trade name “Silisia 320”, trade name “Silisia 310P”, trade name “Silisia 250”, trade name “Silicia 250N”, and products. The name “Siricia 350”, the product name “Silicia 370”, the product name “Silicia 380”, the product name “Silicia 420”, the product name “Silicia 430”, the product name “Silicia 440”, the product name “Silicia 450”, and the product name. “Silicia 470”; manufactured by Nippon Aerosil Co., Ltd., which is silicic anhydride, trade name “AEROSIL 50”, trade name “AEROSIL 90G”, trade name “AEROSIL 130”, trade name “AEROSIL 150”, trade name “AEROSIL 200”, Product name “AEROSIL 300”, Product name “AEROSIL 380”, product name “AEROSIL 200V” and product name “AEROSIL OX50”; product name “Sunsphere H-31”, product name “Sunsphere H-31” manufactured by AGC S-Itech Co., Ltd., which is silicic anhydride. , Trade name "Sunsphere H-121", trade name "Sunsphere H-201", trade name "Sunsphere H-32", trade name "Sunsphere H-52", trade name "Sunsphere H-122" , Trade name "Sunsphere H-33" and trade name "Sunsphere H-53"; dimethylsiloxylated silicic acid manufactured by Nippon Aerosil Co., Ltd., trade name "AEROSIL R972", trade name "AEROSIL R974" and product Name “AEROSIL R9200”; a trimethylsiloxylated silicic anhydride Product name “AEROSIL RX200”, product name “AEROSIL R8200”, product name “AEROSIL RX300” and product name “AEROSIL R812S”; manufactured by Nippon Aerosil Co., Ltd., which is octylsiloxylated silicic acid, R805 "; manufactured by Nippon Aerosil Co., Ltd., a silicone oil-treated silicic acid, trade name" AEROSIL R202 ", trade name" AEROSIL RY200 ", trade name" AEROSIL RY200S "and trade name" AEROSIL RY300 "; methacrylosiloxylated silicic anhydride Product name “AEROSIL R711” manufactured by Nippon Aerosil Co., Ltd. which is an acid; product name “Silica Beads SB-705” manufactured by Miyoshi Kasei Co., Ltd. which is the above-mentioned disintegrating silica; , The trade name of "God Paul SF-16C", include the trade name "God Paul AF-6C" and the trade name of "God Paul AF-16C" and the like.

<Calcium carbonate>
The said calcium carbonate is represented by the INCI name "CALCIUM CARBONATE", for example. As for the said calcium carbonate, only 1 type may be used and 2 or more types may be used. As a commercial item of the said calcium carbonate, Sakai Chemical Industry make, brand name "Karumaru SCS M5"; Shiraishi calcium company make, brand name "Fuwakaru" etc. are mentioned, for example.

<Magnesium carbonate>
The magnesium carbonate is represented by, for example, the INCI name “MAGNESIUM CARBONATE”. As for the said magnesium carbonate, only 1 type may be used and 2 or more types may be used. As a commercial item of the said magnesium carbonate, the Toda Pharmaceutical company make, brand name "light magnesium carbonate" etc. are mentioned, for example.

<Hydroxyapatite>
The hydroxyapatite is represented by, for example, the INCI name “HYDROXYAPATITE”. As for the said hydroxyapatite, only 1 type may be used and 2 or more types may be used.

  The hydroxyapatite is not particularly limited, and examples thereof include spherical hydroxyapatite, plate-like hydroxyapatite, and amorphous hydroxyapatite. Among these, spherical hydroxyapatite is preferable from the viewpoint of exhibiting high hair styling performance. As a commercial item of the said hydroxyapatite, the product name "Plate HAP", the brand name "spherical HAP", the brand name "HAP-100", the brand name "HAP-200" and the brand name made by Taihei Chemical Industry Co., Ltd. "HAP-300" etc. are mentioned.

<Titanium oxide>
The titanium oxide is represented by, for example, the INCI name “TITANIUM DIOXIDE”. The titanium oxide is not particularly limited, and may be fine particle titanium oxide or pigment titanium, for example. As for the said titanium oxide, only 1 type may be used and 2 or more types may be used. As a commercial item of the said titanium oxide, the Ishihara Sangyo company make, brand name "TTO-55 (A)", brand name "CR-50", etc. are mentioned, for example.

<Zinc oxide>
The zinc oxide is represented by, for example, the INCI name “ZINC OXIDE”. As for the said zinc oxide, only 1 type may be used and 2 or more types may be used. As a commercial item of the said zinc oxide, Sakai Chemical Industry Co., Ltd. make, brand name "FINEX-30S-LP2" etc. are mentioned, for example.

<Calcium silicate>
The calcium silicate is represented, for example, by the INCI name “CALCIUM SILICATE”. As for the said calcium silicate, only 1 type may be used and 2 or more types may be used. Examples of the commercially available calcium silicate include Tomita Pharmaceutical Co., Ltd., trade name “FLORITE R”; Nippon Insulation Co., Ltd., trade name “Zonotolite Powder XJ”, and trade name “Tobermorite Powder TK”. .

<Magnesium silicate>
The magnesium silicate is represented by, for example, the INCI name “MAGNESIUM SILICATE”. As for the said magnesium silicate, only 1 type may be used and 2 or more types may be used. As a commercial item of the said magnesium silicate, the Tomita Pharmaceutical company make, brand name "magnesium silicate (light)" etc. are mentioned, for example.

<Aluminum silicate>
The aluminum silicate is represented by, for example, the INCI name “ALUMINUM SILICATE”. As for the said aluminum silicate, only 1 type may be used and 2 or more types may be used. Although it does not specifically limit as an aluminum silicate, A synthetic aluminum silicate is preferable. Examples of the synthesis method include, for example, a method of adding Na ₂ SiO ₃ to alum and drying the generated precipitate, a method of producing a silicate sol by electrodialysis, thereby producing a gel, and an aluminum salt in water glass. The method of adding the aqueous solution of this is mentioned. As a commercial item of the said aluminum silicate, the Tomita Pharmaceutical company make, brand name "synthetic aluminum silicate (heavy)" etc. are mentioned, for example.

<Magnesium hydroxide>
The magnesium hydroxide is represented by, for example, the INCI name “MAGNESIUM HYDROXIDE”. As for the said magnesium hydroxide, only 1 type may be used and 2 or more types may be used. As a commercial item of the said magnesium hydroxide, the Tomita Pharmaceutical company make, brand name "magnesium hydroxide (heavy)" etc. are mentioned, for example.

  In 100% by mass of the hairdressing composition according to the present invention, the content of the component (A) is 0.1% by mass or more, preferably 0.4% by mass or more, more preferably 1% by mass or more and 10% by mass. Hereinafter, it is preferably 7% by mass or less, more preferably 5% by mass or less. When the content of the component (A) is equal to or higher than the lower limit, the hair styling retention power can be further increased, and stickiness can be further suppressed. When content of the said component (A) is below the said upper limit, storage stability (stability at the time of long-term storage) can be improved further. In addition, the touch after styling becomes even better. The content of the component (A) is the total content of all the components (A) in the hairdressing composition according to the present invention. Further, in 100% by mass of the hairdressing composition according to the present invention, the content of silica, and calcium carbonate, magnesium carbonate, hydroxyapatite, titanium oxide, zinc oxide, calcium silicate, magnesium silicate, aluminum silicate, and The content (total content) of the particles selected from the group consisting of magnesium hydroxide is 0.1% by mass or more, preferably 0.4% by mass or more, more preferably 1% by mass or more and 10% by mass, respectively. % Or less, preferably 7% by mass or less, more preferably 5% by mass or less.

(Ingredient (B))
The component (B) is a clay mineral. By using the component (B), particularly by using the component (B) and the component (C) in combination, the hairdressing composition is appropriately thickened, so that the dispersibility of the component (A) is further increased. It becomes much better and the storage stability becomes much better. In addition, the applicability during hair styling is improved. As for the said component (B), only 1 type may be used and 2 or more types may be used.

  The component (B) may be a natural product or a synthetic product. Although it does not specifically limit as said component (B), For example, kaolin group clay mineral, antigolite group clay mineral, pyrophyllite group clay mineral, mica group clay mineral, smectite group clay mineral, vermiculite group clay mineral, green mud Examples include stone group clay minerals and organically modified clay minerals.

  Examples of the kaolin group clay mineral include kaolin, nacrite, dickite and halosite. Examples of the antigolite group clay mineral include antigolite, amesite, and cronstedite. Examples of the pyrophyllite clay mineral include pyrophyllite and talc (talc). Examples of the mica group clay minerals include illite, sea chlorite, ceradonite, sericite, mica (mica), muscovite, chromium muscovite and biotite. Examples of the smectite clay mineral include bentonite, montmorillonite, beidellite, nontonite, saponite, hectorite, and lucentite. Vermiculite etc. are mentioned as said vermiculite group clay mineral. Examples of the chlorite group clay mineral include chlorite. Examples of the organic modified clay mineral include an organic modified clay mineral obtained by organically modifying a smectite group clay mineral or a vermiculite group clay mineral. A quaternary ammonium salt type cationic surfactant is preferably used for the organic modification treatment. Examples of the quaternary ammonium salt type cationic surfactant include the above alkyltrimethylammonium chloride, dialkyldimethylammonium chloride, and benzalkonium chloride.

  The component (B) is preferably a clay mineral selected from the group consisting of synthetic silicates and derivatives thereof from the viewpoint of further improving the storage stability and feel of use of the hairdressing composition. The above-mentioned synthetic silicate and its derivative are not a silicate mineral mainly composed of magnesium silicate or silicic acid (sodium / magnesium) derived from nature, which contains impurities, but silicic acid obtained by synthesis. Refers to salts and silicate derivatives.

  Examples of the synthetic silicate and its derivatives include, for example, the INCI name (International Cosmetic Indictional Dictionary and Handbook, 14th edition, Volume 2, CTFA, 2012, p. 3076): SODIUM MAGNESIUM SILICATE Acid (sodium / magnesium), INCI name (International Cosmetic Ingredient Dictionary and Handbook, 14th edition, Volume 2, CTFA, 2012, p. 1793): MAGNESIUM FLUOROSILICATE Magnesium fluorosilicate, Internal name Cosmetic Ingred ent Dictionary and Handbook, 14th edition, Volume 2, CTFA, 2012, p. 3076): SODIUM MAGNESIUM FLUOROSILICATE, fluorosilicic acid (sodium / magnesium), INCI name (International Cosmetic Indicient Hidden Dict. 14th edition, 2nd volume, CTFA, 2012, p. 1799): MAGNESIUM POTASSIUM FLUOROSILIC fluorosilicic acid (magnesium / potassium), INCI name (International Cosmetic Ingredient Dictionary and Handbook, 14th edition) Volume, CTFA, 2012, p. 1800): MAGNESIUM SODIUM FLUOROSILICATE, fluorosilicic acid (magnesium / sodium), INCI name (International Cosmetic Ingredient Dictionary and Handbook, 14th edition, Volume 1, CTFA, 20 , P. 156): synthetic aluminum silicate represented by ALUMINUM SILICATE.

  As the component (B), a clay mineral (at least one selected from the group consisting of synthetic silicic acid (sodium / magnesium), fluorosilicic acid (sodium / magnesium), and fluorosilicic acid (sodium / magnesium) is used. Clay minerals) are particularly preferred.

  As a commercial item of the said component (B), the Rockwood company make, brand name "Laponite XLG", brand name "Laponite XL21", etc. are mentioned, for example.

  In 100% by mass of the hairdressing composition according to the present invention, the content of the component (B) is preferably 0.1% by mass or more, more preferably 0.3% by mass or more, and further preferably 0.5% by mass. As mentioned above, Preferably it is 10 mass% or less, More preferably, it is 5 mass% or less, More preferably, it is 3 mass% or less. When the content of the component (B) is at least the above lower limit, the storage stability and coatability of the hairdressing composition are further improved. In addition, the hair styling property is further improved. When the content of the component (B) is not more than the above upper limit, the applicability of the hairdressing agent composition is further improved. The content of the component (B) is the total content of all the components (B) in the hairdressing composition according to the present invention.

(Ingredient (C))
The component (C) is at least one polymer selected from the group consisting of the component (C1) and the component (C2). By using the component (C), the hair styling retention property is further improved. In addition, the hairdressing composition is difficult to separate, and the storage stability is further improved. Further, by using the component (C) and the component (B) in combination, the hairdressing composition is appropriately thickened, so that the dispersibility of the component (A) is further improved and storage stability is improved. Becomes even better. Moreover, as for the said component (C), only 1 type may be used and 2 or more types may be used. In addition, only 1 type may be used for said component (C1) and said component (C2), respectively, and 2 or more types may be used.

  As the component (C), only one of the component (C1) and the component (C2) may be used, or the component (C1) and the component (C2) may be used in combination. .

  The monomer component used to obtain the polymer of component (C1) includes at least two or more monomers selected from the group consisting of (meth) acrylic acid and (meth) acrylic acid alkyl esters. That is, the component (C1) is a polymer including at least two or more structural units selected from the group consisting of structural units derived from (meth) acrylic acid and structural units derived from (meth) acrylic acid alkyl esters. . In this specification, the polymer that can correspond to both the component (C1) and the component (C2) is not the component (C1) but the component (C2).

  Although it does not specifically limit as said component (C1), INCI name (International Cosmetic Ingredient Dictionary and Handbook, 14th edition, Volume 1, CTFA, 2012, p.60-61) "ACRYLATES COPOLYMER ) "Is preferred.

  As a commercial item of the said component (C1), the Dow Chemical company make, brand name "Aculin 33", and brand name "Aculin 33A"; SEPPIC company make, brand name "SepiMAX ZEN" etc. are mentioned, for example.

  The component (C1) is not particularly limited, but is preferably neutralized with a basic substance or used after being neutralized with a basic substance. Examples of the basic substance include alkanolamines such as triethanolamine and monoethanolamine; inorganic basic compounds such as ammonia, sodium hydroxide and potassium hydroxide; basic amino acids such as arginine. The basic substance is added in an amount sufficient to neutralize the component (C1) or an amount sufficient to neutralize the component (C1). ) And the type of the basic substance and the amount of the component (C1) used may be appropriately blended.

  The monomer component used to obtain the polymer of the component (C2) is at least one monomer component (c2a) selected from the group consisting of (meth) acrylic acid and (meth) acrylic acid alkyl ester, and (meth) And at least one monomer component (c2b) selected from the group consisting of polyoxyethylene alkyl ethers of acrylic acid, polyoxyethylene alkyl ethers of itaconate and vinyl neodecanoate. That is, the component (C2) is a polymer including at least a structural unit derived from the monomer component (c2a) and a structural unit derived from the monomer component (c2b). As for the said monomer component (c2a) and the said monomer component (c2b), only 1 type may respectively be used and 2 or more types may be used.

Although it does not specifically limit as said component (C2), INCI name (International Cosmetic Ingredient Dictionary and Handbook, the 14th edition, the 1st volume, CTFA, 2012, p.66-67) "ACRYLATES / STEARETH-20 METHACRYLATE "POLYMER (Acrylates / Stearless Methacrylic Acid-20) Copolymer)";"CIRYLATES" under the INCI name (International Cosmetic Ingredient Dictionary and Handbook, 14th edition, Volume 1, CTFA, 2012, p. 67) / STEARETH-20 METHACRYLATE CROSSPOLYMER (( "CRRYLATES / Stearless Methacrylate-20) Crosspolymer)" and "CIRYLATES / BEHENETH" under the INCI name (International Cosmetic Ingredient Dictionary and Handbook, 14th edition, volume 1, CTFA, 2012, p. 57) -25 METHACRYLATE COPOLYMER ((Acrylates / Behenethmethacrylate Methacrylate-25) Copolymer) ”; INCI name (International Cosmetic Ingredient Dictionary and Handbook, 14th edition, Volume 1, CTFA, 2012, p. 68- 69) “ACRYLATES / VINYL NEODECANOATE CROS POLYMER ((acrylates / vinyl neodecanoate) crosspolymer) "to be the title compound; INCI name (International Cosmetic
Ingredient Dictionary and Handbook, 14th edition, volume 1, CTFA, 2012, p. 66) “ACRYLATES / STEARTH-20 ITACONATE COPOLYMER ((Acrylates / Steares-20 Itaconate Copolymer)”); INCI name (International Cosmetic Ingredient Dictionary and Handbook, Vol. 14, 14th edition) 2012, p. 60), a compound represented by “ACRYLATES / CETETH-20 ITACONATE COPOLYMER ((Acrylates / cetacenic acid ceteth-20) copolymer)” is preferable.

  As a commercial item of the said component (C2), the product made from Dow Chemical Co., Ltd., the brand name "Aculin 22", the brand name "Aculin 88", the brand name "Aculin 28", and the brand name "Aculin 38"; , Trade name “STRUCTURE 2001”, trade name “STRUCTURE 3001”, and the like.

  The component (C2) is not particularly limited, but is preferably neutralized with a basic substance or used after neutralization with a basic substance. Examples of the basic substance in this case include the basic substances described above. The basic substance is added in an amount sufficient to neutralize the component (C2), or an amount sufficient to neutralize the component (C2). ) And the type of the basic substance and the amount of the component (C2) used may be appropriately blended.

  In 100% by mass of the hairdressing composition according to the present invention, the content of the component (C) is preferably 0.01% by mass or more, more preferably 0.1% by mass or more, and preferably 5% by mass or less. Preferably it is 2 mass% or less. When the content of the component (C) is at least the above lower limit, the storage stability and coatability of the hairdressing composition are further improved. When the content of the component (C) is not more than the above upper limit, applicability is further improved and the feel of the hair is further improved. Content of the said component (C) is a total amount of content of all the components (C) in the hairdressing composition which concerns on this invention.

  In 100% by mass of the hairdressing composition according to the present invention, the total content of the component (B) and the content of the component (C) (that is, the total content) is the applicability of the hairdressing composition. From the viewpoint of further improvement, preferably 0.2% by mass or more, more preferably 0.4% by mass or more, still more preferably 0.6% by mass or more, preferably 10% by mass or less, more preferably 8% by mass or less. More preferably, it is 5% by mass or less. When the total content of the component (B) and the component (C) is not less than the lower limit, the stagnation due to the component (A) at the time of application of the hairdressing composition is further suppressed, and the applicability is further improved. improves. Furthermore, since the thixotropic property is imparted to the hairdressing composition, the viscosity is low at the time of application, and even better applicability is exhibited. After application, the viscosity is increased, so that the hairdressing retention is further improved. When the total content of the component (B) and the component (C) is not more than the above upper limit, the storage stability of the hairdressing composition is further improved.

  The mass ratio of the component (B) to the component (C) (content of the component (B): content of the component (C)) is preferably 0.1: 1 to 30: 1. 0.2: 1 to 20: 1 is more preferable, and 0.5: 1 to 10: 1 is still more preferable. When the above mass ratio is satisfied, the separation of the hairdressing composition is more effectively suppressed, and the storage stability of the hairdressing composition (stability during long-term storage), especially the storage stability when stored for a long period of time, is further improved. Even better.

(Component (D))
The component (D) is at least one compound selected from the group consisting of the component (D1) and the component (D2). By using the component (D), flaking can be further suppressed, washing off after hair styling is improved, and good hair feel can be imparted to the hair after styling while maintaining high initial hair styling power. Moreover, even if the hair-styling composition is applied to the hair and the hair is sufficiently hair-styled, the sense of discomfort to which the hair-styling composition is attached is suppressed, and hair can be styled in a natural state. As for the said component (D), only 1 type may be used and 2 or more types may be used. In addition, only 1 type may be used for said component (D1) and said component (D2), respectively, and 2 or more types may be used.

  As the component (D), only one of the component (D1) and the component (D2) may be used, and the component (D1) and the component (D2) may be used in combination. .

  The component (D1) is a polyoxyalkylene alkyl glucoside. Examples of the oxyalkylene group in the component (D1) include an oxyethylene group and an oxypropylene group. The average addition mole number of the oxyalkylene group in the component (D1) is not particularly limited, but is preferably 5 or more, and preferably 40 or less. Preferably carbon number of the alkyl group in the said component (D1) is 1-4, More preferably, it is 1-3. The alkyl group in the component (D1) is preferably a methyl group or an ethyl group.

  Although it does not specifically limit as said component (D1), Polyoxyethylene methyl glucoside, polyoxyethylene ethyl glucoside, polyoxypropylene methyl glucoside, polyoxypropylene ethyl glucoside, etc. are mentioned.

  From the viewpoint of imparting a better feel to the hair after styling while maintaining high initial hair styling power, the component (D1) is preferably polyoxyethylene methyl glucoside.

  The component (D2) is a polyoxyalkylene glycerin fatty acid ester. The number of carbon atoms of the fatty acid in the component (D2) is preferably 8 or more, and preferably 22 or less. Examples of the oxyalkylene group in the component (D2) include an oxyethylene group and an oxypropylene group. The average added mole number of the oxyalkylene group in the component (D2) is preferably 5 or more, and preferably 40 or less.

  From the viewpoint of imparting a better touch to the hair after styling while maintaining high initial hair styling power, the fatty acid in the component (D2) is preferably a branched fatty acid, and the component (D2) is a polyoxyalkylene. It is preferably a glycerin branched fatty acid ester.

  From the viewpoint of imparting a better touch to the hair after styling while maintaining high initial hair styling power, the number of carbon atoms of the branched fatty acid in the polyoxyalkylene glycerin branched fatty acid ester is preferably 8 or more, and preferably 16 or less. . Examples of the branched fatty acid in the polyoxyalkylene glycerin branched fatty acid ester include 2-ethylhexanoic acid, isononanoic acid, isopalmitic acid, and isostearic acid.

  As the polyoxyalkylene glycerin branched fatty acid ester, polyoxyethylene glyceryl isostearate is particularly preferable.

  As a commercial item of the said component (D1), the product name "Macbio Obride MG-10P" made by NOF Corporation; the product name "Glucam E-10" and the brand name "Glucam E-20" made by Noveon, for example. A product name “Glucam P-10” manufactured by Amacol Corporation.

  As a commercial item of the said component (D2), Daiichi Kogyo Seiyaku Co., Ltd. make, brand name "Neugen GIS-125"; Nihon Emulsion company make, brand name "EMALEX GWIS-115", brand name "EMALEX GWIS-120", for example. ", Trade name" EMALEX GWIS-125 ", trade name" EMALEX GWIS-130 ", and the like.

  In 100% by mass of the hairdressing composition according to the present invention, the content of the component (D) is preferably 0.5% by mass or more, more preferably 1% by mass or more, preferably 20% by mass or less, more preferably. It is 10 mass% or less. When the content of the component (D) is not less than the above lower limit, flaking is further suppressed, washing off after hair styling is further improved, and better touch is imparted to the hair after hair styling. The When the content of the component (D) is not more than the above upper limit, stickiness is further reduced. Content of the said component (D) is a total amount of content of all the components (D) in the hairdressing agent composition which concerns on this invention.

  In the hairdressing composition, the mass ratio of the content of the component (A) to the content of the component (D) (content of the component (A): content of the component (D)) is 1 : 0.2 to 1:20 is preferable, and 1: 1 to 1:10 is more preferable. When the content of the component (A) is relatively increased, the hair styling power is further improved. When content of the said component (D) becomes relatively large, the touch of hair and the wash-off property at the time of the hair-washing of a hairdressing agent will become still better. Mass ratio of content of silica and content of component (D), calcium carbonate, magnesium carbonate, hydroxyapatite, titanium oxide, zinc oxide, calcium silicate, magnesium silicate, aluminum silicate, and water The mass ratio of the content (total content) of the particles selected from the group consisting of magnesium oxide and the content of the component (D) is 1: 0.2 to 1:20, respectively. Preferably, it is 1: 1 to 1:10.

(Ingredient (E))
The component (E) is polyethylene glycol. By using the component (E), it is possible to impart a good touch to the hair after styling while maintaining high hair styling properties. As for the said component (E), only 1 type may be used and 2 or more types may be used.

  From the viewpoint of further enhancing the effect of imparting a good touch to the hair, the number average molecular weight of the component (E) is preferably 800 or more, more preferably 900 or more, preferably 2000 or less, more preferably 1700 or less. is there.

  In 100% by mass of the hairdressing composition according to the present invention, the content of the component (E) is 0.3% by mass or more, preferably 0.5% by mass or more, more preferably 1% by mass or more, preferably mass. It is 15% or less, more preferably 10% by mass or less. When the content of the component (E) is not less than the above lower limit, the effect of imparting a good touch to the hair is further improved. Hair content improves further because content of the said component (E) is below the said upper limit. Content of the said component (E) is a total amount of content of all the components (E) in the hairdressing composition which concerns on this invention.

(Other ingredients)
The hairdressing composition according to the present invention is not particularly limited, but preferably contains water. Although the said water will not be specifically limited if it is the water used for cosmetics, Purified water is preferable. In 100% by mass of the hairdressing composition according to the present invention, the content of water is preferably 30% by mass or more, more preferably 40% by mass or more, preferably 95% by mass or less, more preferably 90% by mass or less. .

  Moreover, although the hairdressing composition which concerns on this invention is not specifically limited, It is preferable that a C2-C5 lower alcohol (especially ethanol) is included. In 100% by mass of the hairdressing composition according to the present invention, the content of the lower alcohol (particularly ethanol) is preferably 2% by mass or more, more preferably 5% by mass or more, preferably 50% by mass or less, more preferably. 30% by mass or less.

  In the range which does not inhibit the effect of the present invention, for example, a surfactant such as a nonionic surfactant, a cationic surfactant and an amphoteric surfactant; glycerin, 1,3-butylene glycol Polyhydric alcohols such as propylene glycol, 1,2-butanediol, 1,2-pentanediol, 1,2-hexanediol, 1,2-octanediol, 1,2-decanediol; lauryl alcohol, myristyl alcohol, C12-18 higher alcohols such as cetyl alcohol, stearyl alcohol, isostearyl alcohol, cetostearyl alcohol and oleyl alcohol; sugar alcohols such as sorbitol, maltitol and trehalose; polysaccharides such as xanthan gum, carrageenan, guar gum and gellan gum Compound; silicone oil; sequestrants, antioxidants, plant extracts; dyes; pigments; pH adjusting agents; perfumes; may contain a solvent such as, preservatives.

(Other details of hairdressing composition)
The property of the hairdressing composition according to the present invention is not particularly limited, and examples thereof include liquid, gel, cream, and solid. In particular, the hair styling composition is preferably liquid or gel.

  The viscosity at 25 ° C. of the hairdressing composition is preferably 1000 mPa · s or more, more preferably 2000 mPa · s or more, preferably 100,000 mPa · s or less, more preferably 50000 mPa · s or less. When the viscosity is not less than the above lower limit and not more than the above upper limit, applicability is further enhanced, flaking and stickiness are further suppressed, and initial hair styling power and hair styling holding power are further enhanced. In the hair styling composition, even if the viscosity is not more than the above upper limit and the fluidity is high, the occurrence of flaking and stickiness can be suppressed, and the initial hair styling power and hair styling holding power can be increased.

  The above viscosity was measured using a viscometer, No. It is measured under the conditions of a rotation speed of 12 rpm and a rotation time of 1 minute using a 4-rotor. A TV-22 type viscometer manufactured by Toki Sangyo Co., Ltd. can be used as the viscometer.

  The manufacturing method of the hairdressing composition which concerns on this invention is not specifically limited, As a manufacturing method of the hairdressing composition which concerns on this invention, the manufacturing method of a well-known hairdressing composition can be used. Although it does not specifically limit as a manufacturing method of the hairdressing agent composition which concerns on this invention, For example, after stirring a component (A), a component (C), and water with a disper mixer, changing to a paddle mixer, other The method of mix | blending and homogenizing an ingredient is mentioned.

  The hairdressing composition according to the present invention includes at least a component (A), a component (B), and a component (C). By the component (A), the hairdressing composition according to the present invention exhibits excellent hair holding ability. Furthermore, only the component (A) solves the problem that the applied hair is stagnated and improves applicability. Furthermore, it is presumed that the combined use of component (B) and component (C) results in the formation of a crosslinked structure of component (B) and component (C), but the hairdressing composition is moderately thickened. . In addition, the hairdressing composition exhibits thixotropic properties, and the viscosity decreases under shear stress. Thereby, a component (A) becomes difficult to settle or aggregate, and the storage stability when a hairdressing composition is stored for a long period of time improves. In addition, applicability is improved. The said effect is further improved by making the compounding ratio of a component (B) and a component (C) into a specific preferable range. Furthermore, it is presumed that the combined use of the component (B) and the component (C) causes the component (C) to exhibit an effect of retaining water, but separation of the hairdressing composition (liquid component separation) And storage stability is further improved.

  Furthermore, by mix | blending a component (D), the hair-styling force and the inhibitory effect of flaking improve further, Furthermore, the effect which gives the hair after hair-setting and the wash-off property improve.

  The hairdressing composition according to the present invention preferably further comprises a component (E). By using the component (E), it is possible to impart a good touch to the hair after styling while maintaining high hair styling properties. In addition, stickiness arises only with a component (E), but the said effect can be exhibited, suppressing stickiness, by using a component (A) and a component (E) together.

  As described above, when the hairdressing composition according to the present invention is used, not only hair can be properly sculpted, but the state of shampooing can be favorably sustained for a long period of time. Furthermore, the hairdressing composition of the present invention is excellent in storage stability.

  Although the hairdressing composition which concerns on this invention is not specifically limited, For example, it can be used with the form with which the container was filled.

  Examples of the container include a bottle container, a jar container, and a tube container. The container is preferably a bottle container or a tube container.

  Hereinafter, the present invention will be specifically described with reference to Examples and Comparative Examples. The present invention is not limited only to the following examples.

(Example)
The following components were used in Examples , Reference Examples and Comparative Examples.

(Ingredient (A))
Product name “Silysia 320”: Silica, manufactured by Fuji Silysia Chemical Co., Ltd. Product name “Aerosil 200”: Silica, manufactured by Nippon Aerosil Co., Ltd. Product name “Spherical HAP”: Hydroxyapatite (manufactured by Taihei Chemical Industrial Co., Ltd.)
Product name "FLORITE R": calcium silicate (manufactured by Tomita Pharmaceutical)
Product name "Synthetic aluminum silicate (heavy)": Aluminum silicate (manufactured by Tomita Pharmaceutical)
Product name "Magnesium hydroxide (heavy)": Magnesium hydroxide (Tonda Pharmaceutical)

(Ingredient (B))
Product name “Laponite XL21”: fluorosilicic acid (sodium / magnesium), manufactured by Rockwood Corporation Product name “Laponite XLG”: synthetic silicic acid (sodium / magnesium), manufactured by Rockwood Corporation

(Ingredient (C))
Product name “Aculin 22”: alkyl acrylate, alkyl methacrylate, polyoxyethylene stearyl ether (20EO) copolymer emulsion, 30% by weight aqueous solution manufactured by Dow Chemical Co., Ltd. Product name “Aculin 28”: Acrylic Alkyl acid / alkyl methacrylate / polyoxyethylene behenyl ether (25EO) copolymer emulsion, manufactured by Dow Chemical Co., Ltd., 20% by mass aqueous solution Product name “Aculin 33A”: alkyl acrylate copolymer emulsion, Dow 28% by mass aqueous solution manufactured by Chemical Co., Ltd. Trade name “Aculin 38”: alkyl acrylate / vinyl neodecanoate cross polymer, 29% by mass aqueous solution manufactured by Dow Chemical

(Component (D))
Product name “Neugen GIS-125”: Polyoxyethylene glyceryl isostearate, manufactured by Daiichi Kogyo Seiyaku Co., Ltd. Product name “Macbiobride MG-10P”: Polyoxypropylene methyl glucoside, manufactured by NOF Corporation

(Ingredient (E))
Product name “PEG # 1000”: Polyethylene glycol 1000, manufactured by Lion Corporation

(Examples 1 to 19, Reference Example 20, Examples 21 to 40, Reference Example 41, Example 42, and Comparative Examples 1 to 9)
Blending ingredients shown in Tables 1 to 6 below were blended (the blending unit was mass%) to prepare a hairdressing composition. The properties of the hairdressing composition obtained in Examples 1 to 19, Reference Example 20, Examples 21 to 40, Reference Example 41 and Example 42 were all gel-like. In addition, the compounding quantity in a table | surface was shown by the actual compounding quantity (composition quantity of goods).

  The obtained hairdressing composition was filled in a plastic container.

(Test Example 1: Evaluation of storage stability)
The hair styling composition was filled in a transparent glass container having a volume of 60 mL and stored for 1 month in a thermostat kept at 40 ° C. The hair styling composition in the transparent glass container after storage for 1 month was visually observed, and “storage stability” was evaluated according to the following evaluation criteria.

<Evaluation criteria for storage stability>
○ (Remarkably good): Generation of aggregates and sediments and separation of hairdressing composition are not observed. Δ (Good): Out of generation of aggregates and sediments and separation of hairdressing composition. A slight change in at least one of X is observed. × (Poor): At least one change among the generation of aggregates and sediments and the separation of the hairdressing composition is clearly observed.

(Test Example 2: Evaluation of applicability)
20 professional panelists apply the above hairdressing composition uniformly onto the hair of the wig (Lesson Mannequin: Eucalyptus Japan), and styling the hair so that the hair is stroked from front to back along the shape of the wig. After applying, it answered the ease of application. In addition, it was determined that it was easy to apply when it was not caught or itchy during hair styling. From the above answers, applicability was evaluated according to the following criteria.

<Evaluation criteria for applicability>
○ (Remarkably good): 16 or more out of 20 responded that it was easy to apply △ (Good): 10-15 out of 20 responded that it was easy to apply × (defect): 9 or less out of 20 Reply that it is easy to apply

(Test Example 3: Evaluation of hair holding ability)
Twenty professional panels observed the hair of the wig subjected to hair styling after 6 hours after the test example 2 (applicability evaluation), and answered the presence or absence of hair styling retention power. In addition, it was determined that the hair having the hair shape of Test Example 2 in which the shape of the hair was kept is held. Based on the above answers, hair holding ability was evaluated according to the following criteria.

<Evaluation criteria for hair styling retention power>
○ (Remarkably good): More than 16 out of 20 responded that they have hair styling retention △ (Good): 10 to 15 out of 20 responded that they had hair styling retention × (Poor): Out of 20 Nine or less responded that they have hair styling retention

The results are shown in Tables 1 to 6 below. The sum total of the compounding component in each Example , each reference example, and each comparative example of Tables 1-6 is 100 mass%.

In addition, about the hairdressing composition obtained in Example 1, Reference Example 20, Example 22, and Reference Example 41, the following flaking and washing-off evaluation were also performed.

(Test Example 4: Evaluation of flaking)
Twenty expert panels combed the hair of the wig from the root of the hair to the tip of the hair with the fingertips five times after the above Test Example 3 (evaluation of hair holding ability), and answered the presence or absence of flaking. In addition, when it appeared that white powder had adhered on the hair, it determined with there being flaking. From the above answers, flaking was evaluated according to the following criteria.

<Evaluation criteria for flaking>
○ (Remarkably good): More than 16 out of 20 responded that there was no flaking △ (Good): 10-15 out of 20 responded that there was no flaking × (Poor): 9 out of 20 The following responded that there was no flaking

(Test Example 5: Evaluation of washing off)
After 20 specialist panels, after the above test example 4 (evaluation of flaking), the hair of the wig was shampooed using a shampoo (trade name “Lucido Shampoo”, manufactured by Mandom Co., Ltd.), washed with warm water, and then dried. The answer was good or bad. In addition, when there was no squeaky feeling or sticky feeling at the time of shampooing, it was determined that washing off was good. From the above answers, wash-off was evaluated according to the following criteria.

<Evaluation criteria for wash-off>
○ (Remarkably good): More than 16 out of 20 responded that the wash-off was good. △ (Good): 10-15 out of 20 answered that the wash-out was good. × (Bad): 9 out of 20 The following are good to wash off

As a result of the evaluation, the hairdressing composition obtained in Example 1 and Example 22 was evaluated as “◯ (very good)” for both flaking and washing-off. On the other hand, the hairdressing composition obtained in Reference Example 20 and Reference Example 41 had an evaluation result of “Δ (good)” for both flaking and washing-off.

Claims (4)

The following component A, the following component B, the component C which is a polymer selected from the group consisting of the following component C1 and the following component C2 , and a polyoxyalkylene glycerin branched fatty acid ester ,
A hair styling composition, wherein the content of component A is 0.1% by mass or more and 10% by mass or less.
Component A: Particles selected from the group consisting of silica, calcium carbonate, magnesium carbonate, hydroxyapatite, titanium oxide, zinc oxide, calcium silicate, magnesium silicate, aluminum silicate, and magnesium hydroxide Component B: Clay mineral Component C1: Polymer obtained by using two or more monomers selected from the group consisting of (meth) acrylic acid and (meth) acrylic acid alkyl ester as essential monomer components Component C2: As essential monomer components (meth ) Selected from the group consisting of acrylic acid and (meth) acrylic acid alkyl ester, and selected from the group consisting of (meth) acrylic acid polyoxyethylene alkyl ether, itaconic acid polyoxyethylene alkyl ether, and vinyl neodecanoate Obtained with The polymer   The hairdressing composition according to claim 1, wherein the total content of the component B and the content of the component C is 0.2% by mass or more and 10% by mass or less.   The hairdressing composition according to claim 1 or 2, wherein a mass ratio of the content of the component B and the content of the component C is 0.1: 1 to 30: 1. Furthermore, the hairdressing composition of any one of Claims 1-3 containing the following component E.
Component E: Polyethylene glycol