KR101789397B1

KR101789397B1 - Hair styling composition

Info

Publication number: KR101789397B1
Application number: KR1020157020879A
Authority: KR
Inventors: 노리코 후지이; 마사노리 오카모토; 가즈키 노다
Original assignee: 가부시키가이샤 만다무
Priority date: 2013-03-29
Filing date: 2014-03-27
Publication date: 2017-10-23
Also published as: JPWO2014157564A1; WO2014157564A1; CN105025867A; KR20150103233A; CN105025867B; CN105007887B; JPWO2014157563A1; KR101763501B1; WO2014157563A1; CN105007887A; JP6013587B2; JP6092365B2; KR20150103237A

Abstract

The cleaning agent composition according to the present invention comprises 0.1 mass% or more of particles (component A) selected from the group consisting of silica, calcium carbonate, magnesium carbonate, hydroxyapatite, titanium oxide, zinc oxide, calcium silicate, magnesium silicate, aluminum silicate, (Component C1) obtained by using at least two kinds of monomers selected from the group consisting of a clay mineral (component B), (meth) acrylic acid and (meth) acrylic acid alkyl ester, and (meth) acrylic acid and (Meth) acrylic acid alkyl ester, a polymer obtained by using a monomer selected from the group consisting of (meth) acrylic acid polyoxyethylene alkyl ether, itaconic acid polyoxyethylene alkyl ether and vinyl neodecanoic acid C2)) (component C2).

Description

HAIR STYLING COMPOSITION < RTI ID = 0.0 >

The present invention relates to a stabilizer composition suitably used for a hair conditioner.

To prepare the hair, various constipating agent compositions such as liquid, gel, cream, and solid forms are used. Conventionally, a film-forming polymer is often used to impart a repulsive force, which is a main function, to the cleaning composition. However, when an effective amount of the film-forming polymer is blended, there is a problem in that the initial recovery force immediately after the straightening is increased, while the spreadability and absorbability of the stabilizer composition on the hair is deteriorated or stickiness is generated. Further, in the regular-agent composition using the film-forming polymer, a film is formed on the surface of the hair derived from the film-forming polymer after the treatment. For this reason, it is difficult to tune the hair into a natural state, and when the hair is stimulated with a hand or a comb after the hair is cleaned, the film is peeled off from the surface of the hair (so-called flaking occurs) .

In order to solve such a problem, it has been studied to increase the flexibility of a film formed from a film-forming polymer. Patent Document 1 below discusses the use of silicones as a plasticizer in a stabilizer composition containing a film-forming polymer.

Further, a method different from the method of using a film-forming polymer has been studied, and more specifically, it has been studied to impart a repulsive force to a cleaning agent composition using a powder.

The following Patent Document 2 discloses a hair cosmetic composition (regular composition composition) containing 0.1 to 10% by mass of a particulate powder having a specific surface area of 50 m ² / g or more. In Patent Document 2, it is described that by using a specific particulate powder at the specified content, a good feeling can be obtained, an excellent power can be obtained, a good feel can be maintained for a long time, and excellent retaliation can be obtained.

Japanese Patent Application Laid-Open No. 2001-240519 Japanese Patent Application Laid-Open No. 2003-342130

In the stabilizer composition described in Patent Document 1, the flexibility of the film derived from the film-forming polymer is increased to some extent. As a result, the feeling of use of the stabilizer composition is improved to some extent. However, as the flexibility of the coating increases, there is a problem in that the function of maintaining the state of constant rotation for a long time is deteriorated. That is, when the stabilizer composition described in Patent Document 1 is used for the regular treatment, the regular retention force may not be sufficiently increased.

In addition, as described in Patent Document 2, the regular retention force may not be sufficiently increased even when the composition is regularly cleaned using the anticorrosive composition containing the fine particle powder.

In addition, the viscosity of the composition is not sufficiently increased, the coating property of the composition at the time of purification is lowered, and the powder and the liquid component are separated from each other in the composition, resulting in deterioration of storage stability.

An object of the present invention is to provide a cleaning agent composition which is excellent in regular holding power, coating ability and storage stability.

The cleaning agent composition according to the present invention comprises a component (C) which is a polymer selected from the group consisting of the following component (A), the following component (B), the following component (C1) The content of the component (A) is 0.1% by mass or more and 10% by mass or less.

Component (A): particles selected from the group consisting of silica, calcium carbonate, magnesium carbonate, hydroxyapatite, titanium oxide, zinc oxide, calcium silicate, magnesium silicate, aluminum silicate and magnesium hydroxide

Component (B): Clay mineral

Component (C1): A polymer obtained by using, as an essential monomer component, at least two monomers selected from the group consisting of (meth) acrylic acid and (meth) acrylic acid alkyl ester

Component (C2): As the essential monomer component, a monomer selected from the group consisting of (meth) acrylic acid and (meth) acrylic acid alkyl ester and a monomer selected from the group consisting of (meth) acrylic acid polyoxyethylene alkyl ether, itaconic acid polyoxyethylene alkyl ether and neodecanoic acid A polymer obtained by using a monomer selected from the group consisting of vinyl

In the conditioner composition according to the present invention, it is preferable that the total amount of the content of the component (B) and the content of the component (C) is 0.2% by mass or more and 10% by mass or less.

In the charge stabilizer composition according to the present invention, the mass ratio of the content of the component (B) to the content of the component (C) is preferably 0.1: 1 to 30: 1.

The stabilizer composition according to the present invention preferably further comprises the following component (D).

Component (D): a compound selected from the group consisting of a polyoxyalkylene alkyl glucoside and a polyoxyalkylene glycerin fatty acid ester

The stabilizer composition according to the present invention preferably further comprises the following component (E).

Component (E): Polyethylene glycol

The tablet composition according to the present invention contains specific components (A), (B) and (C), and since the content of the component (A) is within a specific range, the applicability at the time of regularization is good, Exhibits excellent regular holding power. In addition, excellent storage stability is exhibited.

Hereinafter, the present invention will be described in detail.

The first polymer is a polymer obtained by using, as an essential monomer component, at least two monomers selected from the group consisting of (meth) acrylic acid and (meth) acrylic acid alkyl ester. (Meth) acrylic acid alkyl ester, (meth) acrylic acid polyoxyethylene alkyl ether, itaconic acid polyoxyethylene alkyl ether and neodecanoic acid (meth) acrylic acid alkyl ester as the essential monomer component, Vinyl, and the like.

The cleaning agent composition according to the present invention comprises particles selected from the group consisting of silica, calcium carbonate, magnesium carbonate, hydroxyapatite, titanium oxide, zinc oxide, calcium silicate, magnesium silicate, aluminum silicate and magnesium hydroxide, clay minerals, A first polymer and a second polymer selected from the group consisting of the first polymer and the second polymer.

In the present specification, "particles selected from the group consisting of silica, calcium carbonate, magnesium carbonate, hydroxyapatite, titanium oxide, zinc oxide, calcium silicate, magnesium silicate, aluminum silicate and magnesium hydroxide" . Further, the " clay mineral " may be referred to as " component (B) ". In the present specification, the "polymer selected from the group consisting of the first polymer and the second polymer" may be referred to as "component (C)". The "first polymer" may be referred to as "component (C1)" in some cases and the "second polymer" may be referred to as "component (C2)" in some cases. The term "(meth) acrylic acid" means one or both of acrylic acid and methacrylic acid.

Preferably, the orthostatic composition according to the present invention further comprises a compound selected from the group consisting of a polyoxyalkylene alkyl glucoside and a polyoxyalkylene glycerin fatty acid ester.

In the present specification, the " compound selected from the group consisting of polyoxyalkylene alkyl glucoside and polyoxyalkylene glycerin fatty acid ester " is sometimes referred to as " component (D) ". The "polyoxyalkylene alkyl glucoside" may be referred to as "component (D1)" in some cases and the "polyoxyalkylene glycerin fatty acid ester" may be referred to as "component (D2)" in some cases.

It is preferable that the stabilizer composition according to the present invention further comprises polyethylene glycol. In the present specification, the above-mentioned " polyethylene glycol " is sometimes referred to as " component (E) ".

That is, the ortho-drug composition according to the present invention contains at least component (A), component (B) and component (C). It is preferable that the stabilizer composition according to the present invention further comprises a component (at least one component) selected from the group consisting of the component (D) and the component (E). Among them, the stabilizer composition according to the present invention preferably contains both of component (A), component (B), component (C), component (D) and component (E). The tonicity agent composition according to the present invention may further contain other components. The above components, for example, the component (A), the component (B), the component (C), the component (D) and the component (E) or the other components may be used alone or two or more thereof may be used.

The component (C) is a polymer (at least one polymer) selected from the group consisting of the component (C1) and the component (C2). The component (D) is a compound (at least one compound) selected from the group consisting of the component (D1) and the component (D2). The component (C1), the component (C2), the component (D1) and the component (D2) may each be used alone or two or more thereof may be used.

Hereinafter, details of each component used in the cleaning composition of the present invention will be described.

(Component (A))

The component (A) is a particle selected from the group consisting of silica, calcium carbonate, magnesium carbonate, hydroxyapatite, titanium oxide, zinc oxide, calcium silicate, magnesium silicate, aluminum silicate and magnesium hydroxide. The component (A) has a role of mainly suppressing tackiness and enhancing an initial repulsive force and a constant-retention force (in particular, a constant-retention force). The use of the above-mentioned component (A) makes it easier to perform repetitive refinement once the refinement has been performed once, thereby enhancing the reverberation, as compared with the case where the film-forming polymer is used.

The component (A) is preferably at least one member selected from the group consisting of silica, hydroxyapatite, titanium oxide, zinc oxide, calcium silicate, magnesium silicate, aluminum silicate and magnesium hydroxide from the viewpoint of improving the purification performance Particles), and particles (at least one particle) selected from the group consisting of silica and magnesium hydroxide are more preferable. The above-mentioned component (A) may be used alone, or two or more thereof may be used.

As the silica, known silica (silicic anhydride) can be used. The silica may be anhydrous silicic acid (hydrophilic silica) not subjected to hydrophobic treatment, or may be hydrophobic silicic anhydride. The silica may be silica treated with an amino acid, ester, lecithin or the like. Further, the silica may be a so-called collapsible silica particle. The silica may be used alone or in combination of two or more.

The hydrophobic silicic anhydride is a material obtained by subjecting anhydrous silicic acid (for example, anhydrous silicic anhydride) to hydrophobic treatment. Examples of the treatment agent used in the hydrophobic treatment include an organosilyl compound and a silicone compound. Examples of the organosilyl compound include methyltrichlorosilane, dimethyldichlorosilane, trimethylchlorosilane, hexamethyldisilazane, methyltrialkoxysilane, dimethyl dialkoxysilane, trimethylalkoxysilane, ethyltrichlorosilane, propyltrichlorosilane, hexyl Long chain alkyl trichlorosilane, long chain alkyl trichlorosilane, ethyl trialkoxy silane, propyl trialkoxy silane, hexyl trialkoxy silane, long chain alkyl trialkoxy silane, methacryl silane, fluoroalkyl silane and perfluoroalkyl silane . Examples of the silicone compound include dimethylpolysiloxane (silicone oil), methylphenylpolysiloxane, methylhydrogenpolysiloxane and amino-modified silicone. As a method of the hydrophobic treatment, a known method can be employed. Examples of the hydrophobic treatment method include a liquid phase method, a vapor phase method, and an autoclave method.

Preferred examples of the hydrophobic silicic anhydride include dimethylsiloxylated silicic anhydride, trimethylsiloxylated silicic anhydride, octylsiloxylated silicic anhydride, silicon oil-treated silicic anhydride and methacrylosiloxylated silicic anhydride.

The bast / compactible silica particles are particles formed by aggregating a plurality of primary silica particles. Examples of the silica primary particles include, but are not limited to, spherical silica particles, scaly silica particles, and amorphous silica particles. The average particle diameter of the silica primary particles is not particularly limited.

The diblock compacted silica particles may contain components other than silica. The component other than the silica (hereinafter sometimes referred to as "inclusion component") is not particularly limited, and examples thereof include surfactants, polyhydric alcohols, higher alcohols, sugar alcohols, silicone oils, sequestering agents, Plant extracts, dyes, pigments, fragrances, moisturizers, vitamins, amino acids, and refreshing agents. Among them, amino acids, silicone oil and vitamins are preferable. Examples of the amino acids include, but are not limited to, dilauroyl glutamate lysine Na (e.g., trade name " Perichea ", manufactured by Asahi Kasei Chemicals Co., Ltd.), trimethylglycine and glutamic acid. When the biodestructured silica particles contain the inclusion component, the inclusion component is released when the biodisolidized silica particles collapse at the time of purification, and an effect depending on the type of inclusion component is exerted. For example, when the biodisolidized silica particles contain amino acids, the hair-damaging function of the hair is exerted.

The method for producing the bast / compactible silica particles is not particularly limited and a known method may be used.

The oil absorption of the silica is preferably 100 mL / 100 g or more, more preferably 150 mL / 100 g or more, further preferably 200 mL / 100 g or more, preferably 1000 mL / 100 g or less, more preferably 800 mL / Is not more than 700 mL / 100 g. When the oil absorption amount of the silica is not less than the lower limit and not more than the upper limit, the initial recovery power, the corrective holding power and the reverberation are further improved. The oil absorption amount is measured in accordance with the method described in JIS K5101.

Examples of commercially available products of the silica include commercially available products such as "Silica 320", trade name "Sarisia 310P", trade name "Sarisia 250", trade name "Sarisia 250N", trade name " Quot; Syriacia 350 ", trade name " Syriacia 440 ", trade name " Syriacia 450 ", trade name " Lycia 470 "; AEROSIL 50 ", trade name" AEROSIL 90G ", trade name" AEROSIL 130 ", trade name" AEROSIL 150 ", trade name" AEROSIL 200 ", trade name" AEROSIL 50 "manufactured by Nippon Aerosil Co., 300 ", trade name" Aerosil 380 ", trade name" Aerosil 200V "and trade name" Aerosil OX50 "; And a trade name " Sun Spear H-201 ", trade name " Sun Spear H-51 ", trade name " Sun Spear H- Sun Spear H-52 ", trade name" Sun Spear H-122 ", trade name" Sun Spear H-33 "and trade name" Sun Spear H-53 "; Trade name " Aerosil R972 ", trade name " Aerosil R974 ", trade name " Aerosil R9200 ", manufactured by Nippon Aerosil Co., Ltd., dimethylsiloxylated silicic anhydride, Trade name " Aerosil RX300 ", trade name " Aerosil R812S ", manufactured by Nippon Aerosil Co., Trade name " Aerosil R805 ", manufactured by Nippon Aerosil Co., Ltd., which is octylsiloxylated silicic anhydride; AEROSIL RY200 ", trade name" AEROSIL RY200S "and trade name" AEROSIL RY300 "manufactured by Nippon Aerosil Co., Trade name " Aerosil R711 ", manufactured by Nippon Aerosil Co., Ltd., which is methacrylsiloxylated silicic anhydride; Silica beads SB-705, manufactured by Miyoshi Kasei Co., Ltd., which is a biodossible silica; Gadolve SF-16C ", trade name " Gut Ball AF-6C ", trade name " Gut Ball AF-16C ", manufactured by Suzuki Yushi Co.,

The above-mentioned calcium carbonate is represented, for example, by the INCI name " CALCIUM CARBONATE ". The calcium carbonate may be used alone or in combination of two or more. Commercially available products of the above-mentioned calcium carbonate include, for example, trade name "Kalmar SCS M5", manufactured by SAKAI CHEMICAL INDUSTRIES, LTD .; Manufactured by Shiraishi Calcium Co., Ltd., trade name " FUWALK ", and the like.

The above-mentioned magnesium carbonate is represented, for example, by the INCI name " MAGNESIUM CARBONATE ". The above-mentioned magnesium carbonate may be used alone, or two or more of them may be used. As a commercially available product of the above-mentioned magnesium carbonate, for example, a trade name "hard magnesium carbonate" manufactured by Tomita Seiyaku Co., Ltd. and the like can be mentioned.

&Lt; Hydroxyapatite >

The hydroxyapatite is represented, for example, by the INCI name " HYDROXYAPATITE ". The hydroxyapatite may be used alone or in combination of two or more.

The hydroxyapatite is not particularly limited and includes, for example, spherical hydroxyapatite, plate-shaped hydroxyapatite, and amorphous hydroxyapatite. Among them, spherical hydroxyapatite is preferable from the standpoint of exhibiting high performance of the treatment. HAP-100 ", trade name" HAP-200 "and trade name" HAP-300 "(trade name, manufactured by Daihige Chemical Industries, Ltd.) &Quot; and the like.

The titanium oxide is represented, for example, by the INCI name " TITANIUM DIOXIDE ". The titanium oxide is not particularly limited and may be, for example, particulate titanium oxide or pigment titanium. The titanium oxide may be used alone or in a combination of two or more. Examples of commercially available titanium oxide include trade name "TTO-55 (A)" and trade name "CR-50" manufactured by Ishihara Sangyo Co.,

The zinc oxide is represented, for example, by the INCI name " ZINC OXIDE ". The zinc oxide may be used alone, or two or more zinc oxides may be used. Examples of commercial products of zinc oxide include trade name "FINEX-30S-LP2" manufactured by SAKAI CHEMICAL CO., LTD.

The calcium silicate is represented, for example, by the INCI name " CALCIUM SILICATE ". The calcium silicate may be used alone or in combination of two or more. Commercially available products of the above calcium silicate include, for example, trade names " Flowlight R " Trade name " Joon Notlite Powder XJ ", trade name " Tobermorite Powder TK ", manufactured by Nihon Insulation Co., Ltd., and the like.

The magnesium silicate is expressed, for example, by the INCI name " MAGNESIUM SILICATE ". The magnesium silicate may be used alone or in combination of two or more. As a commercially available product of the magnesium silicate, for example, a trade name "magnesium silicate (hard)" manufactured by Tomita Seiyaku Co., Ltd. and the like can be mentioned.

The aluminum silicate is represented, for example, by the INCI name " ALUMINUM SILICATE ". The aluminum silicate may be used alone, or two or more aluminum silicate may be used. Although aluminum silicate is not particularly limited, synthetic aluminum silicate is preferable. Examples of the synthesis method include a method of adding Na ₂ SiO ₃ to alum and drying the resulting precipitate, a method of producing a silicate sol by electrodialysis to thereby produce a gel, and a method of producing an aqueous solution of an aluminum salt And the like. As a commercially available product of the aluminum silicate, for example, trade name "synthetic aluminum silicate (heavy)" manufactured by Tomita Seiyaku Co., Ltd. and the like can be mentioned.

The magnesium hydroxide is represented, for example, by the INCI name " MAGNESIUM HYDROXIDE ". The magnesium hydroxide may be used alone or in combination of two or more. As a commercially available product of the above-mentioned magnesium hydroxide, for example, a trade name "magnesium hydroxide (heavy)" manufactured by Tomita Seiyaku Co., Ltd. and the like can be mentioned.

The content of the component (A) in the 100% by mass composition of the present composition according to the present invention is 0.1% by mass or more, preferably 0.4% by mass or more, more preferably 1% by mass or more and 10% 7% by mass or less, and more preferably 5% by mass or less. When the content of the component (A) is not less than the lower limit, the regular holding power can be further increased, and the tackiness can further be suppressed. When the content of the component (A) is not more than the upper limit, the storage stability (stability in long-term storage) can be further improved. In addition, the feeling after normal treatment is further improved. The content of the component (A) is the total amount of the contents of all the components (A) in the tablet composition according to the present invention. The content of the silica in the 100% by mass of the inventive tablet composition according to the present invention is not particularly limited and may be selected from the group consisting of calcium carbonate, magnesium carbonate, hydroxyapatite, titanium oxide, zinc oxide, calcium silicate, magnesium silicate, aluminum silicate, The content (total content) of the selected particles is 0.1 mass% or more, preferably 0.4 mass% or more, more preferably 1 mass% or more and 10 mass% or less, preferably 7 mass% or less, % Or less.

(Component (B))

The component (B) is a clay mineral. By using the above-mentioned component (B), the components of the component (B) and the component (C) are used in combination to increase the viscosity of the stabilizer composition appropriately. Thus, the dispersibility of the component (A) And it becomes better than this. In addition, the applicability at the time of regularization is improved. The above-mentioned component (B) may be used alone, or two or more thereof may be used.

The component (B) may be a natural product or a compound. Examples of the component (B) include, but are not limited to, kaolin clay minerals, antigorite clay minerals, pyrophyllite clay minerals, mica clay minerals, smectite clay minerals, vermiculite clay minerals, Clay minerals and organic modified clay minerals.

Examples of the kaolin clay minerals include kaolin, nacrite, dickite, and halloysite. Examples of the above-mentioned antigorite clay minerals include antigorite, imidesite and kronostate. Examples of the pyrophyllite clay minerals include pyrophyllite and talc (talc). Examples of the mica clay minerals include ilite, seaweed, seladonite, selissite, mica (mica), muscovite, chromite muscovite and biotite. Examples of the smectite clay minerals include bentonite, montmorillonite, beidellite, nontonite, saponite, hectorite and lucentite. Examples of the vermiculite clay minerals include vermiculite and the like. Examples of the chlorite-based clay minerals include chlorite (chlorite) and the like. Examples of the organically modified clay minerals include organic modified clay minerals obtained by organic modification treatment of smectite clay minerals or vermiculite clay minerals. For the organic modification treatment, a quaternary ammonium salt type cationic surfactant is suitably used. Examples of the quaternary ammonium salt type cationic surfactant include alkyl trimethylammonium chloride, dialkyldimethylammonium chloride, and benzalkonium chloride.

From the viewpoint of further improving the storage stability and feeling of use of the regular-charge composition, the component (B) is preferably a clay mineral selected from the group consisting of a synthetic silicate and a derivative thereof. The synthetic silicate and derivative thereof refer not to a silicate mineral mainly composed of magnesium silicate or silicate (sodium / magnesium) derived from naturally occurring impurities, but also to silicates and silicate derivatives obtained by synthesis.

Examples of the synthetic silicate and derivatives thereof include synthetic silicate (sodium / aluminum silicate) represented by INCI name (International Cosmetic Ingredient Dictionary and Handbook, 14th Edition, CTFA, 2012, p.3076) Magnesium fluoride, INCI name (International Cosmetic Ingredient Dictionary and Handbook, 14th Edition, Volume 2, CTFA, 2012, p.1793): Magnesium fluorosilicate, INCI name (MAGNESIUM FLUOROSILICATE) (Sodium / Magnesium), INCI (International Cosmetic Ingredient Dictionary and Handbook, 14th edition, 2nd edition, CTFA, 2012, p.3076): SODIUM MAGNESIUM FLUOROSILICATE (International Cosmetic Ingredient Dictionary and Handbook, 14th Edition, Vol. 2, CTFA, 2012, p. 1799): MAGNESIUM POTASSIUM FLUOROSILICATE, fluorosilicic acid (magnesium / potassium) p.1800): Marked as MAGNESIUM SODIUM FLUOROSILICATE Synthetic aluminosilicates such as fluorosilicic acid (magnesium / sodium), INCI name (International Cosmetic Ingredient Dictionary and Handbook, 14th edition, Vol. 1, CTFA, 2012, page 156): ALUMINUM SILICATE have.

As the component (B), clay minerals (at least one clay mineral) selected from the group consisting of synthetic silicate (sodium / magnesium), fluorosilicic acid (sodium / magnesium) and fluorosilicic acid (sodium / magnesium) desirable.

Examples of commercially available products of the above component (B) include trade name "Laponite XLG" and trade name "Laponite XL21" manufactured by Lockwood Co., Ltd.

The content of the component (B) is preferably 0.1% by mass or more, more preferably 0.3% by mass or more, still more preferably 0.5% by mass or more, and preferably 10% by mass or more, in the 100% By mass or less, more preferably 5% by mass or less, further preferably 3% by mass or less. When the content of the component (B) is lower than the lower limit described above, the storage stabilizer composition and the coating property of the regular-cleansing composition are further improved. In addition, the regularity is further improved. When the content of the component (B) is not more than the upper limit, the applicability of the stabilizing agent is further improved. The content of the component (B) is the total amount of the components (B) in the tablet composition according to the present invention.

(Component (C))

The component (C) is at least one polymer selected from the group consisting of the component (C1) and the component (C2). By the use of the above-mentioned component (C), the steady-state retainability is further improved. Further, the stabilizer composition is hardly separated, and the storage stability is further improved. Further, since the stabilizer composition is appropriately thickened by using the component (C) and the component (B) in combination, the dispersibility of the component (A) becomes better and the storage stability is further improved. The component (C) may be used alone or in combination of two or more. The component (C1) and the component (C2) may be used either singly or in combinations of two or more.

As the component (C), either the component (C1) or the component (C2) may be used alone, or the component (C1) and the component (C2) may be used in combination.

The monomer component used for obtaining the polymer of the component (C1) includes at least two or more monomers selected from the group consisting of (meth) acrylic acid and (meth) acrylic acid alkyl ester. That is, the component (C1) is a polymer containing at least two or more structural units selected from the group consisting of a structural unit derived from (meth) acrylic acid and a structural unit derived from a (meth) acrylic acid alkyl ester. In the present specification, the polymer which may correspond to both of the component (C1) and the component (C2) is not the component (C1) but the component (C2).

As the component (C1), there is no particular limitation, but "ACRYLATES COPOLYMER (acrylate copolymer)" is used as the INCI name (International Cosmetic Ingredient Dictionary and Handbook, 14th Edition, CTFA, 2012, p.60 to 61) Are preferred.

Commercially available products of the above-mentioned component (C1) include, for example, trade name "Acculin 33" and trade name "Aculin 33A", manufactured by Dow Chemical Company; SepiMAX ZEN "manufactured by SEPPIC, and the like.

The component (C1) is not particularly limited, but is preferably neutralized with a basic substance or neutralized with a basic substance. Examples of the basic substance include alkanolamines such as triethanolamine and monoethanolamine; Inorganic base compounds such as ammonia, sodium hydroxide and potassium hydroxide; And basic amino acids such as arginine. The amount of the basic substance added is sufficient to neutralize the neutralized component (C1) or sufficient to neutralize the component (C1), and the amount of the basic component (C1) and the kind of the basic component ) May be properly blended.

The monomer component used to obtain the polymer of component (C2) is at least one monomer component (c2a) selected from the group consisting of (meth) acrylic acid and (meth) acrylic acid alkyl ester, At least one monomer component (c2b) selected from the group consisting of ether, itaconic acid polyoxyethylene alkyl ether and neodecanoic acid vinyl. That is, the component (C2) is a polymer containing at least a constituent unit derived from the monomer component (c2a) and a constituent unit derived from the monomer component (c2b). The monomer component (c2a) and the monomer component (c2b) may be used singly or two or more kinds may be used.

The above component (C2) is not particularly limited, but may be an "ACRYLATES / STEARETH-20 METHACRYLATE COPOLYMER (International Cosmetic Ingredient Dictionary and Handbook, 14th Edition, CTFA, 2012, p.66 to 67) (Acrylate / stearate-20 methacrylate) copolymer "); Quot; ACRYLATES / STEARETH-20 METHACRYLATE CROSSPOLYMER (Acrylate / Stearate-20 acrylate) " as the INCI name (International Cosmetic Ingredient Dictionary and Handbook, 14th edition, Vol 1, CTFA, 2012, p.67) Polymer ") " "ACRYLATES / BEHENETH-25 METHACRYLATE COPOLYMER (Acrylate / Behen Methacrylate-25)" as INCI name (International Cosmetic Ingredient Dictionary and Handbook, 14th edition, Vol 1, CTFA, 2012, p.57) Compound "); "ACRYLATES / VINYL NEODECANOATE CROSSPOLYMER" (Crosslinked acrylate / neodecanoate) as INCI name (International Cosmetic Ingredient Dictionary and Handbook, 14th edition, Vol. 1, CTFA, 2012, p.68 to 69) &Lt; / RTI > "ACRYLATES / STEARETH-20 ITACONATE COPOLYMER" ("Acrylate / Itaconic Acid-20") copolymer as INCI name (International Cosmetic Ingredient Dictionary and Handbook, 14th Edition, Vol. 1, CTFA, 2012, p.66) ) &Quot; "ACRYLATES / CETETH-20 ITACONATE COPOLYMER (acrylate / itaconate ceteth-20) copolymer" as INCI name (International Cosmetic Ingredient Dictionary and Handbook, 14th edition, Vol. 1, CTFA, 2012, p.60) ) &Quot; and the like are preferable.

Examples of commercial products of the above component (C2) include trade name "Aculyn 22", trade name "Aculyn 88", trade name "Aculyn 28" and trade name "Aculyn 38", manufactured by Dow Chemical Company; Trade name " STRUCTURE 2001 ", trade name " STRUCTURE 3001 ", manufactured by Akzo Nobel.

The component (C2) is not particularly limited, but is preferably neutralized with a basic substance or neutralized with a basic substance. As the basic substance in this case, the above-mentioned basic substance can be mentioned. The amount of the basic substance added is sufficient to neutralize the neutralized component (C2) or to neutralize the component (C2), and the amount of the basic component (C2) ) May be properly blended.

The content of the component (C) in 100% by mass of the inventive composition according to the present invention is preferably 0.01% by mass or more, more preferably 0.1% by mass or more, preferably 5% by mass or less, % Or less. When the content of the component (C) is lower than the lower limit described above, the storage stabilizer composition and coating property of the regular-charge composition are further improved. When the content of the component (C) is not more than the upper limit, the coatability is further improved and the feeling of hair is further improved. The content of the component (C) is the total amount of the components (C) in the tablet composition according to the present invention.

The total amount (that is, the total content) of the content of the component (B) and the content of the component (C) in 100% by mass of the composition of the present invention is, from the viewpoint of further improving the applicability of the stabilizer composition, Preferably not less than 0.2 mass%, more preferably not less than 0.4 mass%, further preferably not less than 0.6 mass%, preferably not more than 10 mass%, more preferably not more than 8 mass%, further preferably not more than 5 mass% Or less. When the total content of the component (B) and the component (C) is not lower than the lower limit described above, the varnish stain caused by the component (A) at the time of applying the stabilizer composition is further suppressed, and the coating property is further improved. In addition, since the stabilizer composition is imparted with thixotropic properties, the viscosity is low at the time of coating, and furthermore, the coating property is further improved, and after coating, the viscosity is increased, and the constant holding property is further improved. When the total amount of the content of the component (B) and the content of the component (C) is not more than the upper limit, the storage stability of the stabilizer composition is further improved.

The mass ratio of the component (B) to the component (C) (the content of the component (B): the content of the component (C)) is preferably from 0.1: 1 to 30: 1, more preferably from 0.2: 1 to 20: , More preferably from 0.5: 1 to 10: 1. When the mass ratio is satisfied, separation of the stabilizer composition is more effectively suppressed, and the storage stability of the stabilizer composition (stability in long-term storage), particularly storage stability in storage for a long period of time, is further improved.

(Component (D))

The component (D) is at least one compound selected from the group consisting of the component (D1) and the component (D2). By using the above-mentioned component (D), flaking can be further suppressed, the cleansing properties after purification can be improved, and a good feeling can be given to the hair after hair growth while maintaining a high initial repulsive force. In addition, even when the hair care composition is applied to the hair and the hair is sufficiently cleaned, it is possible to suppress the discomfort with which the hair care composition is adhered, and the hair treatment can be performed in a natural state. The above-mentioned component (D) may be used alone, or two or more thereof may be used. The component (D1) and the component (D2) may be used singly or two or more of them may be used.

As the component (D), either one of the component (D1) and the component (D2) may be used, and the component (D1) and the component (D2) may be used in combination.

The component (D1) is a polyoxyalkylene alkyl glucoside. Examples of the oxyalkylene group in the component (D1) include an oxyethylene group and an oxypropylene group. The average molar number of addition of the oxyalkylene group in the component (D1) is not particularly limited, but is preferably 5 or more, and preferably 40 or less. The number of carbon atoms of the alkyl group in the component (D1) is preferably 1 to 4, more preferably 1 to 3. The alkyl group in the above-mentioned component (D1) is preferably a methyl group or an ethyl group.

The component (D1) is not particularly limited, and examples thereof include polyoxyethylene methyl glucoside, polyoxyethylene ethyl glucoside, polyoxypropylene methyl glucoside, and polyoxypropylene ethyl glucoside.

From the standpoint of imparting a better feeling to the hair after regular hair removal while maintaining a high initial repulsive force, the component (D1) is preferably polyoxyethylene methyl glucoside.

The component (D2) is a polyoxyalkylene glycerin fatty acid ester. The number of carbon atoms of the fatty acid in the component (D2) is preferably 8 or more, and preferably 22 or less. Examples of the oxyalkylene group in the component (D2) include an oxyethylene group and an oxypropylene group. The average number of moles of the oxyalkylene group added in the component (D2) is preferably 5 or more, and preferably 40 or less.

The fatty acid in the component (D2) is preferably a branched fatty acid, and the component (D2) is preferably a branched polyoxyalkylene glycerin fatty acid ester .

The number of carbon atoms of the branched fatty acid in the polyoxyalkylene glycerin branched fatty acid ester is preferably 8 or more, and preferably 16 or less, from the viewpoint of imparting a better feeling to hair after regular hair removal while maintaining a high initial repulsive force. Examples of the branched fatty acid in the polyoxyalkylene glycerin branched fatty acid ester include 2-ethylhexanoic acid, isononanoic acid, isopalmitic acid and isostearic acid.

As the polyoxyalkylene glycerin branched fatty acid ester, polyoxyethylene glyceryl isostearate is particularly preferable.

Commercially available products of the above-mentioned component (D1) include, for example, Nippon Petrochemical Co., Ltd .; Trade name " Glukam E-10 ", trade name " Glukam E-20 ", manufactured by Noveon; Glucam P-10 " manufactured by Amarac Corporation, and the like.

As a commercially available product of the above-mentioned component (D2), for example, trade name "NOIGEN GIS-125" manufactured by Dai-ichi Kogyo Seiyaku Co., EMALEX GWIS-120 ", trade name" EMALEX GWIS-125 "and trade name" EMALEX GWIS-130 "manufactured by Nihon Emulsion Co., Ltd., and the like.

The content of the component (D) in 100% by mass of the composition of the present invention is preferably 0.5% by mass or more, more preferably 1% by mass or more, preferably 20% by mass or less, % Or less. When the content of the component (D) is not lower than the lower limit described above, the flaking is further suppressed, the cleaning property after the cleaning treatment is further improved, and a better feeling is given to the hair after the hair treatment. When the content of the component (D) is less than the upper limit, the tackiness is further reduced. The content of the component (D) is the total amount of the contents of all the components (D) in the tablet composition according to the present invention.

The mass ratio of the content of the component (A) to the content of the component (D) (the content of the component (A): the content of the component (D)) in the regular tablet composition is 1: 0.2 to 1:20 , More preferably from 1: 1 to 1:10. When the content of the component (A) is relatively large, the repulsive force is further improved. When the content of the component (D) is relatively large, the feel of the hair and the cleanability at the time of curing of the corrective agent are further improved. The ratio of the mass ratio of the silica content to the content of the component (D) and the mass ratio of the particles selected from the group consisting of calcium carbonate, magnesium carbonate, hydroxyapatite, titanium oxide, zinc oxide, calcium silicate, magnesium silicate, aluminum silicate and magnesium hydroxide The mass ratio of the content (content of the total) to the content of the component (D) is preferably 1: 0.2 to 1:20, and more preferably 1: 1 to 1:10.

(Component (E))

The component (E) is polyethylene glycol. By using the above-mentioned component (E), it is possible to impart a good feeling to the hair after the treatment, while maintaining high regularity. The component (E) may be used alone, or two or more thereof may be used.

The number average molecular weight of the component (E) is preferably 800 or more, more preferably 900 or more, preferably 2,000 or less, more preferably 1,700 or more, in view of further enhancing the effect of imparting a good feel to the hair Or less.

The content of the component (E) in the 100 percent by mass of the inventive cleaning agent composition is 0.3 mass% or more, preferably 0.5 mass% or more, more preferably 1 mass% or more, and preferably 15 mass% And more preferably 10 mass% or less. When the content of the component (E) is lower than the lower limit, the effect of imparting a good feel to the hair is further improved. When the content of the component (E) is not more than the upper limit, the regularity is further improved. The content of the component (E) is the sum of the contents of all the components (E) in the stabilizer composition according to the present invention.

(Other components)

The stabilizer composition according to the present invention is not particularly limited, but preferably contains water. The water is not particularly limited as long as it is water used in cosmetics, but purified water is preferable. The content of water in the 100% by mass composition of the present composition according to the present invention is preferably 30% by mass or more, more preferably 40% by mass or more, preferably 95% by mass or less, and still more preferably 90% by mass or less.

The stabilizer composition according to the present invention is not particularly limited, but it preferably contains a lower alcohol having 2 to 5 carbon atoms (particularly, ethanol). The content of the lower alcohol (particularly, ethanol) in the 100% by mass composition of the present composition according to the present invention is preferably 2% by mass or more, more preferably 5% by mass or more, and further preferably 50% Is not more than 30% by mass.

The cleaning agent composition according to the present invention can contain, for example, a surfactant such as a nonionic surfactant, a cationic surfactant, and an amphoteric surfactant within a range that does not impair the effect of the present invention; Polyhydric alcohols such as glycerin, 1,3-butylene glycol, propylene glycol, 1,2-butanediol, 1,2-pentanediol, 1,2-hexanediol, ; Higher alcohols having 12 to 18 carbon atoms such as lauryl alcohol, myristyl alcohol, cetyl alcohol, stearyl alcohol, isostearyl alcohol, cetostearyl alcohol and oleyl alcohol; Sugar alcohols such as sorbitol, maltitol and trehalose; Polysaccharide compounds such as xanthan gum, carrageenan, guar gum and gellan gum; Silicone oil; Metal ion sequestrants; Antioxidants; Plant extracts; dyes; Pigments; pH adjusters; Spices; antiseptic; A solvent, and the like.

(Other details of the stabilizer composition)

The properties of the tablet composition according to the present invention are not particularly limited, and examples thereof include a liquid, a gel, a cream, and a solid. Particularly, it is preferable that the stabilizer composition is liquid or gel-like.

The viscosity of the stabilizer composition at 25 ° C is preferably 1000 mPa · s or more, more preferably 2000 mPa · s or more, preferably 100000 mPa · s or less, and furthermore preferably 50000 mPa · s or less. When the viscosity is not less than the lower limit and not more than the upper limit, the coating property is further increased, the occurrence of flaking and tackiness are further suppressed, and the initial repulsive force and the regular retention force are further increased. In the above-described stabilizer composition, since the viscosity is not more than the upper limit, generation of flaking and tackiness can be suppressed even when fluidity is high, and the initial recovery power and the regular holding power can be increased.

The viscosity was measured using a viscometer at a rotational speed of 12 rpm and a rotation time of 1 minute using a No. 4 rotor. As the above-mentioned viscometer, a TV-22 type viscometer manufactured by Ohshiku Co., Ltd. can be used.

The method for producing the stabilizer composition according to the present invention is not particularly limited, and a known method for producing the stabilizer composition can be used as the method for producing the stabilizer composition according to the present invention. The method for producing the stabilizer composition according to the present invention is not particularly limited. For example, after stirring the components (A), (C) and water with a dispenser, the components are mixed with a paddle mixer, And a method of homogenization.

The detergent composition according to the present invention contains at least the component (A), the component (B) and the component (C). By the component (A), the composition of the present invention exhibits excellent regular retention ability. Further, the component (A) alone solves the problem that the coated hair is burnt to improve the coatability. It is also presumed that the combination of the component (B) and the component (C) forms a crosslinked structure of the component (B) and the component (C), and the stabilizer composition is appropriately thickened. In addition, the stabilizer composition exhibits thixotropic properties, and the viscosity decreases under shear stress. As a result, the component (A) precipitates or becomes difficult to agglomerate or harden, and the storage stability when the stabilizer composition is stored for a long period of time is improved. In addition, the coating property is improved. This effect is further improved by setting the blending ratio of the component (B) and the component (C) within a specific preferable range. It is also presumed that the component (C) exhibits the effect of retaining water by the combined use of the component (B) and the component (C), and it is possible to inhibit the separation of the stabilizer composition The storage stability is further improved.

Further, by blending the component (D), the repulsive power and the effect of suppressing flaking can be further improved, the effect of imparting luster to the hair after the treatment, and the cleaning property are improved.

The stabilizer composition according to the present invention preferably further comprises component (E). By using the component (E), it is possible to impart a good feeling to the hair after the treatment, while maintaining high regularity. In addition, tackiness occurs only with the component (E), while using the component (A) and the component (E) in combination, it is possible to exhibit the above effect while suppressing tackiness.

As described above, the use of the tablet composition according to the present invention enables not only good treatment but also a satisfactory long-term sustained state of the treatment. The stabilizer composition of the present invention is also excellent in storage stability.

The stabilizer composition according to the present invention is not particularly limited, but can be used in the form filled in a container, for example.

Examples of the container include a bottle container, a self-container, and a tube container. The container is preferably a bottle container or a tube container.

Hereinafter, the present invention will be specifically described with reference to examples and comparative examples. The present invention is not limited to the following embodiments.

(Example)

In the Examples and Comparative Examples, the following components were used.

(Component (A))

Silicia 320 ": Silica, manufactured by Fuji Silysia Chemical Co., Ltd.

Aerosil 200: Silica, manufactured by Nippon Aerosil Co., Ltd.

&Quot; Conformational HAP ": Hydroxyapatite (manufactured by Daihei Chemical Industry Co., Ltd.)

Trade name " Flowlight R ": calcium silicate (manufactured by Tomita Seiyaku Co., Ltd.)

Synthetic aluminum silicate (heavy) ": Silicate aluminum (manufactured by Tomita Seiyaku Co., Ltd.)

Magnesium hydroxide (heavy): Magnesium hydroxide (manufactured by Tomita Seiyaku Co., Ltd.)

(Component (B))

Trade name " Laponite XL21 ": fluorosilicic acid (sodium / magnesium), manufactured by Rockwood

Product name "Laponite XLG": Synthetic silicate (sodium / magnesium), manufactured by Roquewood Co.

(Component (C))

Acrylic acid alkyl acrylate / alkyl methacrylate / methacrylic acid polyoxyethylene stearyl ether (20E. O.) copolymer emulsion, manufactured by Dow Chemical Co., a 30% by mass aqueous solution

Acrylic acid alkyl acrylate, alkyl methacrylate, polyoxyethylene behenyl ether methacrylate (25E. O.) copolymer emulsion, manufactured by Dow Chemical Company, 20% by mass aqueous solution

Trade name " Acculin 33A ": Acrylic acid alkyl copolymer emulsion, manufactured by Dow Chemical Company, 28 mass% aqueous solution

Trade name " Aculin 38 ": acrylic acid alkyl neodecanoate vinyl crosspolymer, manufactured by Dow Chemical Company, 29 mass% aqueous solution

(Component (D))

Trade name " Noigen GIS-125 ": polyoxyethylene glyceryl isostearate, manufactured by Dai-ichi Kogyo Seiyaku Co.,

Trade name " Macbio Ride MG-10P ": polyoxypropylene methyl glucoside,

(Component (E))

Trade name " PEG # 1000 ": polyethylene glycol 1000, manufactured by Lion Corporation

(Examples 1 to 42 and Comparative Examples 1 to 9)

The formulation ingredients shown in Tables 1 to 6 below were blended (the mixing unit was% by mass) to prepare a stabilizer composition. The properties of the tonicity compositions obtained in Examples 1 to 42 were all in the form of gels. The blending amount in the table is expressed by the actual blending amount (blending amount of the product).

The obtained tonicity composition was filled in a plastic container.

(Test Example 1: Evaluation of storage stability)

The clarifying composition was filled in a transparent glass container having a volume of 60 mL and stored for 1 month in a thermostatic chamber maintained at 40 캜. After the storage for 1 month, the stabilizer composition in the transparent glass container was visually observed to evaluate "storage stability" according to the following evaluation criteria.

○ (very good): no occurrence of agglomerates or sediments, or separation of the stabilizer composition.

? (Good): At least one change in the occurrence of agglomerates or sediments and separation of the stabilizer composition appears to be slight

X (defective): at least one of the occurrence of agglomerates or sediments and the separation of the stabilizer composition becomes apparent

(Test Example 2: evaluation of application property)

Twenty professional panels were uniformly applied to the hair of a wig (lesson mannequin: manufactured by Yukari JAPAN Co., Ltd.) and the hair was flattened from the front to the back so as to follow the shape of the wig, I replied. Further, when the user did not feel a hanging or buzzing at the time of correcting, it was judged that the application was easy. From the answers, the applicability was evaluated based on the following criteria.

&Lt; Evaluation criteria of application &

○ (very good): More than 16 out of 20 is easy to apply Answer

△ (good): 10 to 15 out of 20 responded that it is easy to apply

× (bad): Less than nine out of 20 answered that it is easy to apply

(Test Example 3: evaluation of retention force)

20 professional panelists observed the hair of the wig after the lapse of 6 hours after the test Example 2 (evaluation of the applicability), and the wig of the wig was observed to answer whether or not there was a constant holding force. In addition, it was judged that the shape of the regular hair of Test Example 2 was continuously held and that the hair holding ability was maintained. From the answers, the regular retention force was evaluated based on the following criteria.

○ (very good): More than 16 out of 20 respondents said that they had regular maintenance

△ (Good): 10 to 15 out of 20 respondents answered that they had a positive remedy

× (bad): Less than nine out of 20 responded

The results are shown in Tables 1 to 6 below. The total of the blending components in each of Examples and Comparative Examples shown in Tables 1 to 6 is 100% by mass.

The following components were evaluated for flaking and cleaning properties with respect to the components of the stabilizer compositions obtained in Example 1, Example 20, Example 22, and Example 41. [

(Test Example 4: evaluation of flaking)

After 20 professional panels, the hair of the wig was combed with the tips of the hair from the roots of the hair to the ends of the hair five times successively after the test Example 3 (evaluation of the regular holding power). Further, in the case where white powder appeared to be attached on the hair, it was judged that there was flaking. From the answers, flaking was evaluated based on the following criteria.

○ (very good): More than 16 out of 20 responded that there is no play king

△ (Good): 10 to 15 out of 20 responded that there was no play king

× (bad): Less than 9 out of 20 answered that there is no play king

(Test Example 5: evaluation of cleaning property)

After 20 professional panels, the hair of the wig was shaved with lukewarm water using shampoo (trade name "Lucido shampoo", manufactured by Mandamusa Co., Ltd.) after the above Test Example 4 (evaluation of the flaking), then dried, ). In addition, when there was no discoloration or stickiness of the hair at the time of shaving, it was judged that the cleaning property was good. From the answers, cleaning properties were evaluated according to the following criteria.

&Lt; Evaluation Criteria of Cleanliness &

○ (very good): More than 16 out of 20 responded well

△ (Good): 10 to 15 out of 20 people answered that they had good cleanliness

× (bad): Less than nine out of 20 answered that they are clean

As a result of the evaluation, the evaluations of both the flaking and cleaning properties of the tonicity adjusting composition obtained in Example 1 and Example 22 were "? (Very good). &Quot; On the other hand, in the compositions of the present composition obtained in Example 20 and Example 41, the evaluation results of both the flaking and cleaning properties were "? (Good)".

Claims

A component C which is a polymer selected from the group consisting of the following component A, the following component B, the following component C1 and the following component C2, and a polyoxyalkylene glycerin branched fatty acid ester,
Wherein the content of the component A is 0.1% by mass or more and 7% by mass or less.
Component A: particles selected from the group consisting of silica, calcium carbonate, magnesium carbonate, hydroxyapatite, titanium oxide, zinc oxide, calcium silicate, magnesium silicate, aluminum silicate and magnesium hydroxide
Component B: Clay Minerals
Component C1: a polymer obtained by using, as an essential monomer component, two or more monomers selected from the group consisting of (meth) acrylic acid and (meth) acrylic acid alkyl ester
Component C2: As the essential monomer component, a monomer selected from the group consisting of (meth) acrylic acid and (meth) acrylic acid alkyl ester and a monomer selected from the group consisting of (meth) acrylic acid polyoxyethylene alkyl ether, itaconic acid polyoxyethylene alkyl ether and neodecanoyl vinyl ether A polymer obtained by using a monomer selected from the group consisting of

The cleaning agent composition according to claim 1, wherein the total amount of the component B and the component C is 0.2 mass% or more and 10 mass% or less.

The cleaning agent composition according to claim 1 or 2, wherein the mass ratio of the content of the component B to the content of the component C is 0.1: 1 to 30: 1.

3. The stabilizer composition according to claim 1 or 2, further comprising the following component (E).
Component E: Polyethylene glycol

4. The stabilizer composition according to claim 3, further comprising the following component (E).
Component E: Polyethylene glycol