KR20150103233A - Hair styling agent composition - Google Patents

Abstract

Provided is a carcass preparation composition capable of suppressing the occurrence of flaking and tackiness when standing still, and also capable of increasing initial repulsive force and regular holding power. The cleaning agent composition according to the present invention is a composition containing 0.1 mass of particles (component A) selected from the group consisting of silica, calcium carbonate, magnesium carbonate, hydroxyapatite, titanium oxide, zinc oxide, calcium silicate, magnesium silicate, aluminum silicate and magnesium hydroxide % Or more and 10 mass% or less; a polyoxyethylene / polyoxypropylene copolymer which is liquid at 25 占 폚 and has a number average molecular weight of 10000 or more and 20,000 or less; and a polyoxyethylene / polyoxypropylene copolymer which is liquid at 25 占 폚 and has a number average molecular weight of 300 to 1000 And sorbitol (component B).

Description

HAIR STYLING AGENT COMPOSITION < RTI ID = 0.0 >

The present invention relates to a stabilizer composition suitably used for a hair conditioner.

To prepare the hair, various constipating agent compositions such as liquid, gel, cream, and solid forms are used. Conventionally, a film-forming polymer is often used to impart a repulsive force, which is a main function, to the cleaning composition. In the regular-solution composition using the film-forming polymer, a film is formed on the surface of the hair derived from the film-forming polymer after the treatment. As a result, when the film-forming polymer is blended as a main stabilizing component, it is difficult to arrange the hair in a natural state while the initial repulsive force immediately after the hair straightening becomes high, or when stimulation is given to the hair with a hand or a comb, There is a problem that the coating is peeled off (so-called flaking occurs) and the appearance is deteriorated.

Accordingly, a method different from the method of using a film-forming polymer has been studied, and specifically, it has been studied to impart a repulsive force to a cleaning agent composition using a powder.

The following Patent Document 1 discloses a hair cosmetic composition (regular composition composition) containing 0.1 to 10% by mass of a particulate powder having a specific surface area of 50 m ² / g or more. Patent Document 1 discloses that by using a specific particulate powder at the specified content, a good feeling can be obtained, an excellent repulsive force can be obtained, a favorable feeling can be maintained for a long time, and excellent reverberation can be obtained.

Japanese Patent Application Laid-Open No. 2003-342130

However, as described in Patent Document 1, flaking may occur even when the charge stabilizer composition containing the fine particle powder is used. In addition, there is a demand for a more excellent initial repulsive force and a regular retention force.

It is an object of the present invention to provide a cleaning agent composition capable of suppressing the occurrence of flaking and tackiness when standing still, and also capable of increasing the initial repulsive force and the regular retention force.

The cleaning agent composition according to the present invention comprises the following components (A) and (B), and the content of the component (A) is 0.1% by mass or more and 10% by mass or less.

Component (A): particles selected from the group consisting of silica, calcium carbonate, magnesium carbonate, hydroxyapatite, titanium oxide, zinc oxide, calcium silicate, magnesium silicate, aluminum silicate and magnesium hydroxide

Component (B): a polyoxyethylene / polyoxypropylene copolymer which is liquid at 25 DEG C and has a number average molecular weight of 10000 to 20000, and polyoxyethylene / polyoxypropylene copolymer which is liquid at 25 DEG C and polyoxypropylene sorbitol having a number average molecular weight of 300 to 1000 Compound selected from the group

In the conditioner composition according to the present invention, the content of the component (B) is preferably 3% by mass or more and 40% by mass or less.

It is preferable that the tablet composition according to the present invention further comprises the following component (C).

Component (C): a compound selected from the group consisting of a polyoxyalkylene alkyl glucoside and a polyoxyalkylene glycerin fatty acid ester

The stabilizer composition according to the present invention preferably further comprises a component (D) which is a polymer selected from the group consisting of the following components (D1) and (D2).

Component (D1): A polymer obtained by using, as an essential monomer component, at least two monomers selected from the group consisting of (meth) acrylic acid and (meth) acrylic acid alkyl ester

Component (D2): As an essential monomer component, a monomer selected from the group consisting of (meth) acrylic acid and (meth) acrylic acid alkyl ester and a monomer selected from the group consisting of (meth) acrylic acid polyoxyethylene alkyl ether, itaconic acid polyoxyethylene alkyl ether and neodecanoic acid A polymer obtained by using a monomer selected from the group consisting of vinyl

It is preferable that the stabilizer composition according to the present invention further comprises a component (E) which is a clay mineral.

In the stabilizer composition according to the present invention, the mass ratio of the content of the component (D) to the content of the component (E) is preferably 1: 0.1 to 1:30.

The present composition contains the specific component (A) and the specific component (B), and since the content of the component (A) is within a specific range, occurrence of flaking and tackiness are suppressed , And the initial repulsive force and the regular retention force can be increased.

Hereinafter, the present invention will be described in detail.

The tablet composition according to the present invention is a tablet composition comprising particles selected from the group consisting of silica, calcium carbonate, magnesium carbonate, hydroxyapatite, titanium oxide, zinc oxide, calcium silicate, magnesium silicate, aluminum silicate and magnesium hydroxide, A polyoxyethylene / polyoxypropylene copolymer having a number average molecular weight of 10,000 or more and 20,000 or less, and a compound selected from the group consisting of polyoxypropylene sorbitol which is liquid at 25 占 폚 and has a number average molecular weight of 300 or more and 1000 or less.

In the present specification, "particles selected from the group consisting of silica, calcium carbonate, magnesium carbonate, hydroxyapatite, titanium oxide, zinc oxide, calcium silicate, magnesium silicate, aluminum silicate and magnesium hydroxide" . The polyoxyethylene / polyoxypropylene copolymer which is liquid at 25 DEG C and has a number average molecular weight of 10000 to 20000, and polyoxyethylene / polyoxypropylene copolymer which is liquid at 25 DEG C and polyoxypropylene sorbitol having a number average molecular weight of 300 to 1000 Is sometimes referred to as " component (B) ". The polyoxyethylene / polyoxypropylene copolymer which is liquid at 25 占 폚 and has a number average molecular weight of 10000 to 20000 is sometimes referred to as "component (B1)". The term "component (B1) Polyoxypropylene sorbitol having an average molecular weight of 300 or more and 1000 or less " may be referred to as " component (B2) ".

Preferably, the orthostatic composition according to the present invention further comprises a compound selected from the group consisting of a polyoxyalkylene alkyl glucoside and a polyoxyalkylene glycerin fatty acid ester.

In the present specification, the " compound selected from the group consisting of polyoxyalkylene alkyl glucoside and polyoxyalkylene glycerin fatty acid ester " is sometimes referred to as " component (C) ". The "polyoxyalkylene alkyl glucoside" may be referred to as "component (C1)" in some cases, and the "polyoxyalkylene glycerin fatty acid ester" may be referred to as "component (C2)" in some cases.

The stabilizer composition according to the present invention preferably further comprises a polymer selected from the group consisting of the first polymer and the second polymer below. The first polymer is a polymer obtained by using, as an essential monomer component, at least two monomers selected from the group consisting of (meth) acrylic acid and (meth) acrylic acid alkyl ester. The second polymer may contain, as an essential monomer component, a monomer selected from the group consisting of (meth) acrylic acid and (meth) acrylic acid alkyl ester, (meth) acrylic acid polyoxyethylene alkyl ether, itaconic acid polyoxyethylene alkyl ether and vinyl neodecanoate And a polymer obtained by using a monomer selected from the group consisting of

In the present specification, the "polymer selected from the group consisting of the first polymer and the second polymer" may be referred to as "component (D)". The "first polymer" may be referred to as "component (D1)" in some cases, and the "second polymer" may be referred to as "component (D2)" in some cases. The term "(meth) acrylic acid" means one or both of acrylic acid and methacrylic acid.

The tablet composition according to the present invention may further comprise a polysaccharide compound. In the present specification, the "polysaccharide compound" is sometimes referred to as "component (D ')".

It is preferable that the tablet composition according to the present invention further comprises a clay mineral. In the present specification, the term "clay mineral" is sometimes referred to as "component (E)".

That is, the stabilizer composition according to the present invention contains at least the component (A) and the component (B). The stabilizer composition according to the present invention preferably further comprises a component (at least one component) selected from the group consisting of component (C), component (D) and component (E). When the component (E) is used, it is preferable to use the component (E) in combination with the component selected from the group consisting of the component (D) and the component (D '). Among them, the stabilizer composition according to the present invention preferably contains both of component (A), component (B), component (C), component (D) and component (E). The tonicity agent composition according to the present invention may further contain other components. The above components may be used either individually or in combination. For example, the component (A), the component (B), the component (C), the component (D), the component (D ' Or more may be used.

The component (B) is a compound (at least one compound) selected from the group consisting of the component (B1) and the component (B2). The component (C) is a compound (at least one compound) selected from the group consisting of the component (C1) and the component (C2). The component (D) is a polymer (at least one polymer) selected from the group consisting of the component (D1) and the component (D2). The component (B1), the component (B2), the component (C1), the component (C2), the component (D1) and the component (D2) may be used alone or two or more thereof may be used.

Hereinafter, details of each component used in the cleaning composition of the present invention will be described.

(Component (A))

The component (A) is a particle selected from the group consisting of silica, calcium carbonate, magnesium carbonate, hydroxyapatite, titanium oxide, zinc oxide, calcium silicate, magnesium silicate, aluminum silicate and magnesium hydroxide. The component (A) mainly has a role of suppressing tackiness and enhancing the initial repulsive force and the regular retention force. Further, by using the above-mentioned component (A), it is possible to easily perform repetitive refinement once the refinement is once performed, and to improve the reverberation, as compared with the case where the film-forming polymer is used.

Among the above-mentioned components (A), particles selected from the group consisting of silica, magnesium carbonate, hydroxyapatite, calcium silicate, magnesium silicate, aluminum silicate and magnesium hydroxide (at least one particle ), And particles (at least one particle) selected from the group consisting of silica, magnesium silicate and magnesium hydroxide are more preferable. The above-mentioned component (A) may be used alone, or two or more thereof may be used.

<Silica>

As the silica, known silica (silicic anhydride) can be used. The silica may be anhydrous silicic acid (hydrophilic silica) not subjected to hydrophobic treatment, or may be hydrophobic silicic anhydride. The silica may be silica treated with an amino acid, ester, lecithin or the like. Further, the silica may be a so-called collapsible silica particle. The silica may be used alone or in combination of two or more.

The hydrophobic silicic anhydride is a material obtained by subjecting anhydrous silicic acid (for example, anhydrous silicic anhydride) to hydrophobic treatment. Examples of the treatment agent used in the hydrophobic treatment include an organosilyl compound and a silicone compound. Examples of the organosilyl compound include methyltrichlorosilane, dimethyldichlorosilane, trimethylchlorosilane, hexamethyldisilazane, methyltrialkoxysilane, dimethyl dialkoxysilane, trimethylalkoxysilane, ethyltrichlorosilane, propyltrichlorosilane, hexyl Long chain alkyl trichlorosilane, long chain alkyl trichlorosilane, ethyl trialkoxy silane, propyl trialkoxy silane, hexyl trialkoxy silane, long chain alkyl trialkoxy silane, methacryl silane, fluoroalkyl silane and perfluoroalkyl silane . Examples of the silicone compound include dimethylpolysiloxane (silicone oil), methylphenylpolysiloxane, methylhydrogenpolysiloxane and amino-modified silicone. As a method of the hydrophobic treatment, a known method can be employed. Examples of the hydrophobic treatment method include a liquid phase method, a vapor phase method, and an autoclave method.

Preferred examples of the hydrophobic silicic anhydride include dimethylsiloxylated silicic anhydride, trimethylsiloxylated silicic anhydride, octylsiloxylated silicic anhydride, silicon oil-treated silicic anhydride and methacrylosiloxylated silicic anhydride.

The bast / compactible silica particles are particles formed by aggregating a plurality of primary silica particles. Examples of the silica primary particles include, but are not limited to, spherical silica particles, phosphorus-based silica particles, and amorphous silica particles. The average particle diameter of the silica primary particles is not particularly limited.

The diblock compacted silica particles may contain components other than silica. The component other than the silica (hereinafter sometimes referred to as "inclusion component") is not particularly limited, and examples thereof include surfactants, polyhydric alcohols, higher alcohols, sugar alcohols, silicone oils, sequestering agents, Plant extracts, dyes, pigments, fragrances, moisturizers, vitamins, amino acids, and refreshing agents. Among them, amino acids, silicone oil and vitamins are preferable. Examples of the amino acids include, but are not limited to, dilauroyl glutamate lysine Na (e.g., trade name &quot; Perichea &quot;, manufactured by Asahi Kasei Chemicals Co., Ltd.), trimethylglycine and glutamic acid. When the biodestructured silica particles contain the inclusion component, the inclusion component is released when the biodisolidized silica particles collapse at the time of purification, and an effect depending on the type of inclusion component is exerted. For example, when the biodisolidized silica particles contain amino acids, the hair-damaging function of the hair is exerted.

The method for producing the bast / compactible silica particles is not particularly limited, and a known method can be used.

The oil absorption of the silica is preferably 100 mL / 100 g or more, more preferably 150 mL / 100 g or more, further preferably 200 mL / 100 g or more, preferably 1000 mL / 100 g or less, more preferably 800 mL / Is not more than 700 mL / 100 g. When the oil absorption amount of the silica is not less than the lower limit and not more than the upper limit, the initial recovery power, the corrective holding power and the reverberation are further improved. The oil absorption amount is measured in accordance with the method described in JIS K5101.

Examples of commercially available products of the silica include commercially available products such as "Silica 320", trade name "Sarisia 310P", trade name "Sarisia 250", trade name "Sarisia 250N", trade name " Quot; Syriacia 350 &quot;, trade name &quot; Syriacia 440 &quot;, trade name &quot; Syriacia 450 &quot;, trade name &quot; Lycia 470 &quot;; AEROSIL 50 ", trade name" AEROSIL 90G ", trade name" AEROSIL 130 ", trade name" AEROSIL 150 ", trade name" AEROSIL 200 ", trade name" AEROSIL 50 "manufactured by Nippon Aerosil Co., 300 ", trade name" Aerosil 380 ", trade name" Aerosil 200V "and trade name" Aerosil OX50 "; And a trade name &quot; Sun Spear H-201 &quot;, trade name &quot; Sun Spear H-51 &quot;, trade name &quot; Sun Spear H- Sun Spear H-52 ", trade name" Sun Spear H-122 ", trade name" Sun Spear H-33 "and trade name" Sun Spear H-53 "; Trade name &quot; Aerosil R972 &quot;, trade name &quot; Aerosil R974 &quot;, trade name &quot; Aerosil R9200 &quot;, manufactured by Nippon Aerosil Co., Ltd., dimethylsiloxylated silicic anhydride, Trade name &quot; Aerosil RX300 &quot;, trade name &quot; Aerosil R812S &quot;, manufactured by Nippon Aerosil Co., Trade name &quot; Aerosil R805 &quot;, manufactured by Nippon Aerosil Co., Ltd., which is octylsiloxylated silicic anhydride; AEROSIL RY200 ", trade name" AEROSIL RY200S "and trade name" AEROSIL RY300 "manufactured by Nippon Aerosil Co., Trade name &quot; Aerosil R711 &quot;, manufactured by Nippon Aerosil Co., Ltd., which is methacrylsiloxylated silicic anhydride; Silica beads SB-705, manufactured by Miyoshi Kasei Co., Ltd., which is a biodossible silica; Trade name &quot; GAGBOL AF-16C &quot;, trade name &quot; GAGBOL AF-16C &quot;, manufactured by SUZUKI YUSHI CHEMICAL CO., LTD.

<Calcium carbonate>

The above-mentioned calcium carbonate is represented, for example, by the INCI name &quot; CALCIUM CARBONATE &quot;. The calcium carbonate may be used alone or in combination of two or more. Commercially available products of the above-mentioned calcium carbonate include, for example, trade name "Kalmar SCS M5", manufactured by SAKAI CHEMICAL INDUSTRIES, LTD .; Manufactured by Shiraishi Calcium Co., Ltd., trade name &quot; FUWALK &quot;, and the like.

<Magnesium carbonate>

The above-mentioned magnesium carbonate is represented, for example, by the INCI name &quot; MAGNESIUM CARBONATE &quot;. The above-mentioned magnesium carbonate may be used alone, or two or more of them may be used. As a commercially available product of the above-mentioned magnesium carbonate, for example, a trade name "hard magnesium carbonate" manufactured by Tomita Seiyaku Co., Ltd. and the like can be mentioned.

&Lt; Hydroxyapatite >

The hydroxyapatite is represented, for example, by the INCI name &quot; HYDROXYAPATITE &quot;. The hydroxyapatite may be used alone or in combination of two or more.

The hydroxyapatite is not particularly limited and includes, for example, spherical hydroxyapatite, plate-shaped hydroxyapatite, and amorphous hydroxyapatite. Among them, spherical hydroxyapatite is preferable from the standpoint of exhibiting high performance of the treatment. HAP-100 ", trade name" HAP-200 "and trade name" HAP-300 "(trade name, manufactured by Daihige Chemical Industries, Ltd.) &Quot; and the like.

<Titanium oxide>

The titanium oxide is represented, for example, by the INCI name &quot; TITANIUM DIOXIDE &quot;. The titanium oxide is not particularly limited and may be, for example, particulate titanium oxide or pigment titanium. The titanium oxide may be used alone or in a combination of two or more. Examples of commercially available titanium oxide include trade name "TTO-55 (A)" and trade name "CR-50" manufactured by Ishihara Sangyo Co.,

<Zinc Oxide>

The zinc oxide is represented, for example, by the INCI name &quot; ZINC OXIDE &quot;. The zinc oxide may be used alone, or two or more zinc oxides may be used. Examples of commercial products of zinc oxide include trade name "FINEX-30S-LP2" manufactured by SAKAI CHEMICAL CO., LTD.

<Calcium silicate>

The calcium silicate is represented, for example, by the INCI name &quot; CALCIUM SILICATE &quot;. The calcium silicate may be used alone or in combination of two or more. Commercially available products of the above calcium silicate include, for example, trade names &quot; Flowlight R &quot; Trade name &quot; Joon Notlite Powder XJ &quot;, trade name &quot; Tobermorite Powder TK &quot;, manufactured by Nihon Insulation Co., Ltd., and the like.

<Magnesium Silicate>

The magnesium silicate is expressed, for example, by the INCI name &quot; MAGNESIUM SILICATE &quot;. The magnesium silicate may be used alone or in combination of two or more. As a commercially available product of the magnesium silicate, for example, a trade name "magnesium silicate (hard)" manufactured by Tomita Seiyaku Co., Ltd. and the like can be mentioned.

<Aluminum silicate>

The aluminum silicate is represented, for example, by the INCI name &quot; ALUMINUM SILICATE &quot;. The aluminum silicate may be used alone, or two or more aluminum silicate may be used. Although aluminum silicate is not particularly limited, synthetic aluminum silicate is preferable. Examples of the synthesis method include a method of adding Na ₂ SiO ₃ to alum and drying the resulting precipitate, a method of producing a silicate sol by electrodialysis to thereby produce a gel, and a method of producing an aqueous solution of an aluminum salt And the like. As a commercially available product of the aluminum silicate, for example, trade name "synthetic aluminum silicate (heavy)" manufactured by Tomita Seiyaku Co., Ltd. and the like can be mentioned.

<Magnesium hydroxide>

The magnesium hydroxide is represented, for example, by the INCI name &quot; MAGNESIUM HYDROXIDE &quot;. The magnesium hydroxide may be used alone or in combination of two or more. As a commercially available product of the above-mentioned magnesium hydroxide, for example, a trade name "magnesium hydroxide (heavy)" manufactured by Tomita Seiyaku Co., Ltd. and the like can be mentioned.

The content of the above-mentioned component (A) in 100% by mass of the antiseptic composition according to the present invention is 0.1% by mass or more, preferably 0.4% by mass or more, more preferably 1% by mass or more and 10% by mass or less, By mass or less, more preferably 5% by mass or less. By setting the content of the component (A) to be equal to or lower than the lower limit described above, the initial repulsive force immediately after the straightening can be further increased, and the repelling holding power can be further enhanced. When the content of the component (A) is not more than the upper limit, the effect of imparting gloss and the cleaning property are further improved. The content of the component (A) is the total amount of the contents of all the components (A) in the tablet composition according to the present invention. The content of the silica in 100 mass% of the inventive tablet composition according to the present invention and the content of the silica selected from the group consisting of calcium carbonate, magnesium carbonate, hydroxyapatite, titanium oxide, zinc oxide, calcium silicate, magnesium silicate, aluminum silicate and magnesium hydroxide The content of the particles (total content) is 0.1% by mass or more, preferably 0.4% by mass or more, more preferably 1% by mass or more and 10% by mass or less, preferably 7% % Or less.

(Component (B))

The component (B) is at least one compound selected from the group consisting of the component (B1) and the component (B2). The component (B) has a role of effectively increasing the initial repulsive force and the regular retention force. Further, by using the above-mentioned component (B), flaking can be suppressed and the above effect can be exerted. The above-mentioned component (B) may be used alone, or two or more thereof may be used. The component (B1) and the component (B2) may be used alone or in a combination of two or more.

As the component (B), either one of the component (B1) and the component (B2) may be used, and the component (B1) and the component (B2) may be used in combination. Above all, from the viewpoint of improving the sustainability of the repulsive force, it is preferable that the component (B1) and the component (B2) are used in combination.

The component (B1) is a polyoxyethylene / polyoxypropylene copolymer. That is, the component (B1) is a copolymer having at least a plurality of oxyethylene units (ethylene oxide units) and a plurality of oxypropylene units (propylene oxide units). The component (B1) may be any of a block copolymer, a random copolymer and an alternate copolymer, and the type of copolymerization in the component (B1) is not particularly limited.

The average addition mole number of oxyethylene added in the component (B1) is not particularly limited, but is preferably 100 or more, more preferably 200 or more, preferably 400 or less, more preferably 350 or less. The average addition mole number of oxypropylene in the component (B1) is not particularly limited, but is preferably 30 or more, particularly preferably 40 or more, preferably 150 or less, particularly preferably 100 or less.

The component (B1) is in a liquid phase at 25 DEG C from the viewpoint of suppressing flaking, from the viewpoint of easy application of a stabilizer, and glaze on hair.

The number average molecular weight of the component (B1) is 10000 or more and 20000 or less. When the number average molecular weight of the component (B1) is less than the lower limit described above, the regularity is lowered. When the number average molecular weight of the component (B1) exceeds the upper limit, the handling property is deteriorated. The number average molecular weight of the component (B1) is preferably 12,000 or more. The number average molecular weight of the component (B1) is preferably 18,000 or less.

The component (B2) is polyoxypropylene sorbitol. The average addition mole number of oxypropylene in the component (B2) is not particularly limited, but is preferably 4 or more, more preferably 8 or more, preferably 15 or less, more preferably 12 or less.

The component (B2) is in a liquid phase at 25 DEG C from the viewpoint of suppressing flaking, from the viewpoint of easiness of application of a stabilizer, and glaze on hair.

The number average molecular weight of the component (B2) is 300 or more and 1000 or less. The number average molecular weight of the component (B2) is preferably 400 or more. The number average molecular weight of the component (B2) is preferably 800 or less.

The component (B) is liquid at 25 占 폚. It is preferable that the component (B) has fluidity at 25 캜. For example, when 50 g of a sample is put in a glass bottle having a radius of 2 cm and a height of 7 cm and the glass bottle is turned upside down at 25 캜, It is preferable that the sample has a property of flowing down from the glass bottle for 5 minutes immediately after the reversal.

Examples of commercially available products of the component (B1) include trade name "Newpol 75H-90000" manufactured by Sanyo Chemical Industries, Ltd. and the like.

Examples of commercially available products of the above-mentioned component (B2) include trade name "Newpol SP-750" and trade name "Sanenix SP-750" manufactured by Sanyo Chemical Industries, Ltd.

The content of the component (B) in 100% by mass of the present composition according to the present invention is preferably 3% by mass or more, more preferably 5% by mass or more, further preferably 8% by mass or more, % Or less, more preferably 30 mass% or less, further preferably 20 mass% or less. When the content of the component (B) is not lower than the lower limit, the repulsive force and the durability thereof are further improved. When the content of the component (B) is not more than the upper limit, the effect of inhibiting tackiness, the spreadability upon application and the absorbency are further improved. The content of the component (B) is the total amount of the components (B) in the tablet composition according to the present invention.

(A): the content of the component (B)) of the content of the component (A) and the content of the component (B) in the regular tablet composition according to the present invention is 1: 0.1 to 1 : 30, more preferably 1: 1 to 1:20, and even more preferably 1: 3 to 1:20. When the content of the component (A) is relatively large, the ability to form rich styling is further improved. When the content of the component (B) is relatively large, the styling property for producing a tight hair is further improved. The content of the particles selected from the group consisting of calcium carbonate, magnesium carbonate, hydroxyapatite, titanium oxide, zinc oxide, calcium silicate, magnesium silicate, aluminum silicate and magnesium hydroxide in the mass ratio of the content of the silica to the content of the component (B) Is preferably 1: 0.1 to 1:30, more preferably 1: 1 to 1:20, and most preferably 1: 3 to 1:20, in terms of the mass ratio of the component (B) Is more preferable.

(Component (C))

The component (C) is at least one compound selected from the group consisting of the component (C1) and the component (C2). By using the above-mentioned component (C), it is possible to further suppress the flaking, improve the cleansing properties after cleansing, and maintain a high initial repulsive force and give a good feeling to the hair after cleansing. In addition, even if hair is sufficiently cleaned, the hair styling composition is imparted to the hair, and the discomfort felt on the hair styling composition is suppressed, and the hair can be straightened in a natural state. The above-mentioned component (C) may be used alone, or two or more thereof may be used. The component (C1) and the component (C2) may be used either singly or in combinations of two or more.

As the component (C), either one of the component (C1) and the component (C2) may be used, and the component (C1) and the component (C2) may be used in combination.

The component (C1) is a polyoxyalkylene alkyl glucoside. Examples of the oxyalkylene group in the component (C1) include an oxyethylene group and an oxypropylene group. The average number of moles of the oxyalkylene group added in the component (C1) is not particularly limited, but is preferably 5 or more, and preferably 40 or less. The number of carbon atoms of the alkyl group in the component (C1) is preferably 1 to 4, more preferably 1 to 3. The alkyl group in the component (C1) is preferably a methyl group or an ethyl group.

The component (C1) is not particularly limited, and examples thereof include polyoxyethylene methyl glucoside, polyoxyethylene ethyl glucoside, polyoxypropylene methyl glucoside and polyoxypropylene ethyl glucoside.

From the standpoint of imparting a better feeling to the hair after regular hair removal while maintaining a high initial repulsive power, the component (C1) is preferably polyoxyethylene methyl glucoside.

The component (C2) is a polyoxyalkylene glycerin fatty acid ester. The number of carbon atoms in the fatty acid in the component (C2) is preferably 8 or more, and preferably 22 or less. Examples of the oxyalkylene group in the component (C2) include an oxyethylene group and an oxypropylene group. The average addition mole number of the oxyalkylene group in the component (C2) is preferably 5 or more, and preferably 40 or less.

The fatty acid in the component (C2) is preferably a branched fatty acid, and the component (C2) is preferably a polyoxyalkylene glycerin branched fatty acid ester .

The number of carbon atoms in the branched fatty acid in the polyoxyalkylene glycerin branched fatty acid ester is preferably 8 or more, and preferably 22 or less, from the viewpoint of imparting a better feeling to hair after regular hair removal while maintaining a high initial repulsive force. Examples of the branched fatty acid in the polyoxyalkylene glycerin branched fatty acid ester include 2-ethylhexanoic acid, isononanoic acid, isopalmitic acid and isostearic acid.

As the polyoxyalkylene glycerin branched fatty acid ester, polyoxyethylene glyceryl isostearate is particularly preferable.

Commercially available products of the above-mentioned component (C1) include, for example, products of Nichichi Co., Ltd .; Trade name &quot; GLUCAM E-10 &quot;, trade name &quot; GLUCAM E-20 &quot; Glucam P-10 &quot; manufactured by Amarac Corporation, and the like.

Commercially available products of the above-mentioned component (C2) include, for example, trade names "NOIGEN GIS-125" manufactured by Dai-ichi Kogyo Seiyaku Co., EMALEX GWIS-120 ", trade name" EMALEX GWIS-125 "and trade name" EMALEX GWIS-130 "manufactured by Nihon Emulsion Co., Ltd., and the like.

The content of the component (C) in 100% by mass of the composition of the present invention is preferably 0.5% by mass or more, more preferably 1% by mass or more, preferably 20% by mass or less, % Or less. When the content of the component (C) is not lower than the lower limit, the flaking is further suppressed, the cleansing properties after the cleansing are further improved, and a better feeling is given to the hair after cleansing. When the content of the component (C) is not more than the upper limit, tackiness is further reduced. The content of the component (C) is the total amount of the components (C) in the tablet composition according to the present invention.

The mass ratio of the content of the component (A) to the content of the component (C) (content of the component (A): content of the component (C)) in the regular tablet composition is 1: 0.2 to 1:20 , More preferably from 1: 1 to 1:10. When the content of the component (C) is relatively large, the feeling of hair, the effect of suppressing flaking, and the cleaning property are further improved. Wherein the ratio of the mass ratio of the silica content to the content of the component (C) and the mass ratio of the particles selected from the group consisting of calcium carbonate, magnesium carbonate, hydroxyapatite, titanium oxide, zinc oxide, calcium silicate, magnesium silicate, aluminum silicate and magnesium hydroxide The mass ratio of the content (content of the total) to the content of the component (C) is preferably 1: 0.2 to 1:20, more preferably 1: 1 to 1:10.

(Component (D))

The component (D) is at least one polymer selected from the group consisting of the component (D1) and the component (D2). The use of the component (D) improves the dispersibility of the component (A) because the stabilizer composition is properly thickened, and the stabilizer composition is hardly separated, and the storage stability is further improved . In addition, the regularity is further improved. The above-mentioned component (D) may be used alone, or two or more thereof may be used. The component (D1) and the component (D2) may be used singly or two or more of them may be used.

The monomer component used to obtain the polymer of component (D1) includes at least two monomers selected from the group consisting of (meth) acrylic acid and (meth) acrylic acid alkyl ester. That is, the component (D1) is a polymer containing at least two or more structural units selected from the group consisting of a structural unit derived from (meth) acrylic acid and a structural unit derived from a (meth) acrylic acid alkyl ester. In the present specification, the polymer which can correspond to both the component (D1) and the component (D2) is not the component (D1) but the component (D2).

The above component (D1) is not particularly limited, but "ACRYLATES COPOLYMER (acrylate copolymer)" is used as INCI name (International Cosmetic Ingredient Dictionary and Handbook, 14th edition, Vol. 1, CTFA, 2012, p.60 to 61) Are preferred.

Examples of commercially available products of the above component (D1) include trade name "Acculin 33" and trade name "Aculin 33A", manufactured by Dow Chemical Company; SEPPIC &quot;, trade name &quot; SepiMAX ZEN &quot;, and the like.

The component (D1) is not particularly limited, but it is preferably neutralized with a basic substance or neutralized with a basic substance. Examples of the basic substance include alkanolamines such as triethanolamine and monoethanolamine; Inorganic bases such as ammonia, sodium hydroxide and potassium hydroxide; And basic amino acids such as arginine. The amount of the basic substance to be added is sufficient to neutralize the neutralized component (D1) or to neutralize the component (D1), and the amount of the basic component (D1) and the kind of the basic component ) May be properly blended.

The monomer component used to obtain the polymer of the component (D2) is at least one monomer component (d2a) selected from the group consisting of (meth) acrylic acid and (meth) acrylic acid alkyl ester, At least one monomer component (d2b) selected from the group consisting of ether, itaconic acid polyoxyethylene alkyl ether, and neodecanoic acid vinyl. That is, the component (D2) is a polymer containing at least a constituent unit derived from the monomer component (d2a) and a constituent unit derived from the monomer component (d2b). The monomer component (d2a) and the monomer component (d2b) may be used singly or two or more kinds may be used.

The component (D2) is not particularly limited, but may be selected from among "ACRYLATES / STEARETH-20 METHACRYLATE COPOLYMER (International Cosmetic Ingredient Dictionary and Handbook, 14th Edition, CTFA, 2012, p.66 to 67) (Acrylate / stearate-20 methacrylate) copolymer "); Quot; ACRYLATES / STEARETH-20 METHACRYLATE CROSSPOLYMER (Acrylate / Stearate-20 acrylate) &quot; as the INCI name (International Cosmetic Ingredient Dictionary and Handbook, 14th edition, Vol 1, CTFA, 2012, p.67) Polymer &quot;); "ACRYLATES / BEHENETH-25 METHACRYLATE COPOLYMER (Acrylate / Behen Methacrylate-25)" as INCI name (International Cosmetic Ingredient Dictionary and Handbook, 14th edition, Vol 1, CTFA, 2012, p.57) Compound &quot;); "ACRYLATES / VINYL NEODECANOATE CROSSPOLYMER" (Crosslinked acrylate / neodecanoate) as INCI name (International Cosmetic Ingredient Dictionary and Handbook, 14th edition, Vol. 1, CTFA, 2012, p.68 to 69) &Lt; / RTI &gt; "ACRYLATES / STEARETH-20 ITACONATE COPOLYMER" ("Acrylate / Itaconic Acid-20") copolymer as INCI name (International Cosmetic Ingredient Dictionary and Handbook, 14th Edition, Vol. 1, CTFA, 2012, p.66) ) &Quot; "ACRYLATES / CETETH-20 ITACONATE COPOLYMER (acrylate / itaconate ceteth-20) copolymer" as INCI name (International Cosmetic Ingredient Dictionary and Handbook, 14th edition, Vol. 1, CTFA, 2012, p.60) ) &Quot; and the like are preferable.

Examples of commercially available products of the above-mentioned component (D2) include trade name "Aculyn 22", trade name "Aculyn 88", trade name "Aculyn 28" and trade name "Aculyn 38", manufactured by Dow Chemical Company; Trade name &quot; STRUCTURE 2001 &quot;, trade name &quot; STRUCTURE 3001 &quot;, manufactured by Akzo Nobel.

The component (D2) is not particularly limited, but is preferably neutralized with a basic substance or neutralized with a basic substance. As the basic substance in this case, the above-mentioned basic substance can be mentioned. The amount of the basic substance added is sufficient to neutralize the neutralized component (D2) or to neutralize the component (D2), and the amount of the basic component (D2) ) May be properly blended.

The content of the component (D) in 100% by mass of the composition of the present invention is preferably 0.01% by mass or more, more preferably 0.1% by mass or more, preferably 5% by mass or less, % Or less. When the content of the component (D) is lower than the lower limit described above, the effect of imparting gloss and the storage stability of the stabilizer composition are further improved. When the content of the component (D) is less than the upper limit, the repulsive force is further improved and the feeling of hair is further improved. The content of the component (D) is the total amount of the contents of all the components (D) in the tablet composition according to the present invention. When the component (D ') is used, the content of the component (D) may be 0% by mass (unused) in 100% by mass of the composition of the present invention.

(Component (D '))

The component (D ') is a polysaccharide compound. The use of the component (D ') improves the dispersibility of the component (A) because the stabilizer composition is appropriately thickened, and the stabilizer composition is hardly separated and the storage stability is further improved It becomes. The component (D ') may be used alone or in combination of two or more.

The component (D ') is not particularly limited, but polysaccharides and modified polysaccharides (for example, alkyl modified polysaccharides and the like) are preferable, and examples thereof include alginic acid, carrageenan, agar, perselen, guar gum, Polysaccharide-derived polysaccharide compounds such as konjac mannan, tamarind gum, tara gum, dextrin, starch, locust bean gum, gum arabic, ghatti gum, karaya gum, tragacanth gum, arabinogalactan, pectin and quince; Animal-derived polysaccharide compounds such as chitosan and hyaluronic acid; Polysaccharide-derived polysaccharide compounds such as curdlan, xanthan gum, gellan gum, cyclodextrin, dextran, pullulan and hyaluronic acid; Non-ionic cellulose such as microcrystalline cellulose, methylcellulose, ethylcellulose, hydroxymethylcellulose, hydroxyethylcellulose, hydroxypropylcellulose and hydroxypropylmethylcellulose; Anionic cellulose such as carboxymethylcellulose; Cationized cellulose such as O- [2-hydroxy-3- (trimethylammonio) propyl] hydroxyethylcellulose chloride; And cationized guar gum such as O- [2-hydroxy-3- (trimethylammonio) propyl] guar gum chloride.

As the component (D '), a compound (at least one compound) selected from the group consisting of xanthan gum, guar gum, tamarind gum and gellan gum is preferable.

Examples of commercially available products of the above component (D ') include trade name "Eco Gum T", trade name "Keldent" and trade name "Monat Gum", manufactured by Dainippon Sumitomo Seiyaku Co., Manufactured by Nippon Kagaku Kogyo Co., Ltd., trade name &quot; Ingel Guar gum CS &quot;; Manufactured by DSP Gokyo Food &amp; Chemical Co., Ltd .; trade name "Glyroid 6C"; CP Kelco U.S., Inc., Gellan Surname. , &Quot; Kerkogel &quot;, and the like.

The content of the component (D ') in 100% by mass of the inventive cleaning agent composition is preferably 0.01% by mass or more, more preferably 0.1% by mass or more, preferably 5% by mass or less, % Or less. When the content of the component (D ') is lower than the lower limit described above, the storage stability of the stabilizer composition is further improved. When the content of the component (D ') is less than the upper limit, the stickiness is further improved. The content of the component (D ') is the total amount of the contents of all the components (D') in the stabilizer composition according to the present invention. When the component (D) is used, the content of the component (D ') may be 0 mass% (unused) in 100 mass% of the composition of the present invention.

(Component (E))

The component (E) is a clay mineral. By the use of the above-mentioned component (E), the shelf stability and the storage stability of the stabilizer composition are further improved. The component (E) may be used alone, or two or more thereof may be used.

The component (E) may be a natural product or a compound. Examples of the component (E) include, but are not limited to, kaolin clay minerals, antigorite clay minerals, pyrophyllite clay minerals, mica clay minerals, smectite clay minerals, vermiculite clay minerals, Clay minerals and organic modified clay minerals.

Examples of the kaolin clay minerals include kaolin, nacrite, dickite, and halloysite. Examples of the above-mentioned antigorite clay minerals include antigorite, imidesite and kronostate. Examples of the pyrophyllite clay minerals include pyrophyllite and talc (talc). Examples of the mica clay minerals include ilite, seaweed, seladonite, selissite, mica (mica), muscovite, chromite muscovite and biotite. Examples of the smectite clay minerals include bentonite, montmorillonite, beidellite, nontonite, saponite, hectorite and lucentite. Examples of the vermiculite clay minerals include vermiculite and the like. Examples of the chlorite-based clay minerals include chlorite (chlorite) and the like. Examples of the organically modified clay minerals include organic modified clay minerals obtained by organic modification treatment of smectite clay minerals or vermiculite clay minerals. For the organic modification treatment, a quaternary ammonium salt type cationic surfactant is suitably used. Examples of the quaternary ammonium salt type cationic surfactant include alkyl trimethylammonium chloride, dialkyldimethylammonium chloride, and benzalkonium chloride.

From the viewpoint of further improving storage stability and feeling, the component (E) is preferably a clay mineral selected from the group consisting of a synthetic silicate and a derivative thereof. The synthetic silicate and derivative thereof refer not to a silicate mineral mainly composed of magnesium silicate or silicate (sodium / magnesium) derived from naturally occurring impurities, but also to silicates and silicate derivatives obtained by synthesis.

Examples of the synthetic silicate and derivatives thereof include synthetic silicate (sodium / aluminum silicate) represented by INCI name (International Cosmetic Ingredient Dictionary and Handbook, 14th Edition, CTFA, 2012, p.3076) Magnesium fluoride, INCI name (International Cosmetic Ingredient Dictionary and Handbook, 14th Edition, Volume 2, CTFA, 2012, p.1793): Magnesium fluorosilicate, INCI name (MAGNESIUM FLUOROSILICATE) (Sodium / Magnesium), INCI (International Cosmetic Ingredient Dictionary and Handbook, 14th edition, 2nd edition, CTFA, 2012, p.3076): SODIUM MAGNESIUM FLUOROSILICATE (International Cosmetic Ingredient Dictionary and Handbook, 14th Edition, Vol. 2, CTFA, 2012, p. 1799): MAGNESIUM POTASSIUM FLUOROSILICATE, fluorosilicic acid (magnesium / potassium) p.1800): Marked as MAGNESIUM SODIUM FLUOROSILICATE Synthetic aluminosilicates such as fluorosilicic acid (magnesium / sodium), INCI name (International Cosmetic Ingredient Dictionary and Handbook, 14th edition, Vol. 1, CTFA, 2012, page 156): ALUMINUM SILICATE have.

As the component (E), clay minerals (at least one clay mineral) selected from the group consisting of synthetic silicic acid (sodium / magnesium), fluorosilicic acid (sodium / magnesium) and fluorosilicic acid (sodium / magnesium) desirable.

Commercially available products of the above component (E) include, for example, trade name "Laponite XLG" and trade name "Laponite XL21" manufactured by Roquewood.

The content of the component (E) in 100% by mass of the inventive purifier composition is preferably 0.1% by mass or more, more preferably 0.3% by mass or more, still more preferably 0.5% by mass or more, % Or less, more preferably 5 mass% or less, further preferably 3 mass% or less. When the content of the component (E) is lower than the lower limit described above, the regularity is further improved. When the content of the component (E) is not more than the upper limit, the preservative stability of the anticorrosive composition is further improved.

From the standpoint of further increasing the storage stability of the stabilizer composition by further increasing the viscosity of the stabilizer composition to an appropriate level, the stabilizer composition according to the present invention preferably contains the component (D) and the component (E) . The dispersion stability of the component (A) is further increased by the combined use of the component (D) and the component (E), and the purification developer composition is more difficult to be separated. Further, since the stabilizer composition exhibits good thixotropic properties, the applicability of the stabilizer composition is improved.

The ratio of the mass ratio of the component (D) to the component (E) (the content of the component (D): the content of the component (E)) in the case of using the component (D) 0.1 to 1:30, more preferably 1: 0.2 to 1:20, and still more preferably 1: 0.5 to 1:10. When the mass ratio is satisfied, the preservative stability of the anticorrosive composition, particularly the storage stability when stored for a long period of time, is further improved.

When the component (D) and the component (E) are used in combination, the total amount of the content of the component (D) and the content of the component (E) is preferably 0.2% by mass or more, more preferably 0.4% More preferably not less than 0.6% by mass, preferably not more than 10% by mass, more preferably not more than 8% by mass, further preferably not more than 5% by mass. When the total amount is within the above range, the preservative stability of the composition, particularly the storage stability when stored for a long period of time, is further improved.

(Other components)

The stabilizer composition according to the present invention is not particularly limited, but preferably contains water. The water is not particularly limited as long as it is water used in cosmetics, but purified water is preferable. The content of water in 100% by mass of the inventive purifier composition is preferably 30% by mass or more, more preferably 40% by mass or more, preferably 95% by mass or less, and still more preferably 90% by mass or less.

The stabilizer composition according to the present invention is not particularly limited, but it preferably contains a lower alcohol having 2 to 5 carbon atoms (particularly, ethanol). The content of the lower alcohol (particularly, ethanol) in 100% by mass of the purifier composition according to the present invention is preferably 2% by mass or more, more preferably 5% by mass or more, and preferably 50% by mass or less, 30% by mass or less.

The cleaning agent composition according to the present invention may contain, for example, a surfactant such as a nonionic surfactant, a cationic surfactant and an amphoteric surfactant within a range that does not impair the effect of the present invention; Polyhydric alcohols such as glycerin, 1,3-butylene glycol, propylene glycol, 1,2-butanediol, 1,2-pentanediol, 1,2-hexanediol, ; Higher alcohols having 12 to 18 carbon atoms such as lauryl alcohol, myristyl alcohol, cetyl alcohol, stearyl alcohol, isostearyl alcohol, cetostearyl alcohol and oleyl alcohol; Sugar alcohols such as sorbitol, maltitol and trehalose; Silicone oil; Metal ion sequestrants; Antioxidants; Plant extracts; dyes; Pigments; pH adjusters; Spices; antiseptic; A solvent, and the like.

(Other details of the stabilizer composition)

The shape of the stabilizer composition according to the present invention is not particularly limited, but may be any of liquid, gel, cream, and solid. It is preferable that the tablet composition is liquid or gel-like. Generally, when the particles are used in the liquid developer composition on a liquid or gel basis, since the flowability of the stabilizer composition is high, the dispersibility of the particles tends to be lowered. As a result, in the above liquid or gel-type stabilizer composition, the initial repulsive force and the regular retention force are likely to be lowered, and tackiness and flaking tend to occur easily. On the other hand, by employing the above-mentioned composition in the cleaning agent composition according to the present invention, it is possible to suppress the occurrence of flaking and tackiness even in a liquid or gel conditioner composition, and to improve the initial repulsive force and corrective holding power.

The viscosity of the stabilizer composition at 25 ° C is preferably 1000 mPa · s or more, more preferably 2000 mPa · s or more, preferably 100000 mPa · s or less, and furthermore preferably 50000 mPa · s or less. When the viscosity is not less than the lower limit and not more than the upper limit, the coating property is further increased, the occurrence of flaking and tackiness are further suppressed, and the initial repulsive force and the regular retention force are further increased. In the above-described stabilizer composition, since the viscosity is not more than the upper limit, generation of flaking and tackiness can be suppressed even when fluidity is high, and the initial recovery power and the regular holding power can be increased.

The viscosity was measured using a viscometer at a rotational speed of 12 rpm and a rotation time of 1 minute using a No. 4 rotor. As the above-mentioned viscometer, a TV-22 type viscometer manufactured by Ohshiku Co., Ltd. can be used.

The method for producing the stabilizer composition according to the present invention is not particularly limited, and a known method for producing the stabilizer composition can be used as the method for producing the stabilizer composition according to the present invention. The method for producing the stabilizer composition according to the present invention is not particularly limited. For example, the component (A) and water (component (E), if necessary) are stirred with a dispenser and then exchanged with a paddle mixer And mixing and homogenizing the other components while stirring.

The ortho-drug composition according to the present invention contains at least a component (A) and a component (B) as main purification components. By using the component (A) and the component (B) in combination, the initial repulsive force immediately after the straightening can be increased while the stickiness is suppressed, and the constant retention force can be increased. Further, by using the component (B) which is a liquid component at 25 占 폚, it is possible to suppress the occurrence of flaking (a phenomenon in which white powder or a film appears to adhere on the hair) upon correcting. Thereby, the use of the tablet composition according to the present invention makes it possible not only to satisfactorily stabilize the hair, but also to maintain the hair straightening state for a long period of time.

In addition, by blending the component (C), the repulsive force and the suppressing effect of flaking can be further improved, and the effect of imparting luster to the hair after the cleansing and cleansing properties are improved.

Further, by blending the component (D) and the component (E), the stabilizer composition is appropriately thickened, and the applicability of the stabilizer composition is improved. Further, by setting the compounding ratio of the component (D) and the component (E) to a specific preferable range, the component (A) precipitates or becomes difficult to agglomerate or become difficult to achieve the storage stability .

The stabilizer composition according to the present invention is not particularly limited, but can be used in the form filled in a container, for example.

Examples of the container include a bottle container, a self-container, and a tube container. The container is preferably a bottle container or a tube container.

(Example)

Hereinafter, the present invention will be specifically described with reference to examples and comparative examples. The present invention is not limited to the following embodiments.

In the Examples and Comparative Examples, the following components were used.

(Component (A))

Silicia 320 ": Silica, manufactured by Fuji Silysia Chemical Co., Ltd.

Aerosil 200: Silica, manufactured by Nippon Aerosil Co., Ltd.

&Quot; Conformational HAP &quot;: Hydroxyapatite (manufactured by Daihei Chemical Industry Co., Ltd.)

Trade name &quot; Flowlight R &quot;: calcium silicate (manufactured by Tomita Seiyaku Co., Ltd.)

Synthetic aluminum silicate (heavy) ": Silicate aluminum (manufactured by Tomita Seiyaku Co., Ltd.)

Magnesium hydroxide (heavy): Magnesium hydroxide (manufactured by Tomita Seiyaku Co., Ltd.)

(Component (B))

Trade name &quot; Newpol 75H-90000 &quot;: polyoxyethylene polyoxypropylene hexylene glycol ether, manufactured by Sanyo Chemical Industries, Ltd., number average molecular weight 14000,

Trade name &quot; Newpol SP-750 &quot;: polyoxypropylene sorbitol, manufactured by Sanyo Chemical Industries, Ltd., number average molecular weight 690,

Trade name &quot; Newpol 50HB-55 &quot;: polyoxyethylene polyoxypropylene butyl ether, manufactured by Sanyo Chemical Industries, Ltd., number average molecular weight 300,

(Component (C))

Trade name &quot; Noigen GIS-125 &quot;: polyoxyethylene glyceryl isostearate, manufactured by Dai-ichi Kogyo Seiyaku Co.,

Trade name &quot; Macbio Ride MG-10P &quot;: polyoxypropylene methyl glucoside,

(Component (D))

Acrylic acid alkyl acrylate / alkyl methacrylate / methacrylic acid polyoxyethylene stearyl ether (20E. O.) copolymer emulsion, manufactured by Dow Chemical Co., a 30% by mass aqueous solution

Acrylic acid alkyl acrylate, alkyl methacrylate, polyoxyethylene behenyl ether methacrylate (25E. O.) copolymer emulsion, manufactured by Dow Chemical Company, 20% by mass aqueous solution

Trade name &quot; Acculin 33A &quot;: Acrylic acid alkyl copolymer emulsion, manufactured by Dow Chemical Company, 28 mass% aqueous solution

Trade name &quot; Aculin 38 &quot;: acrylic acid alkyl neodecanoate vinyl crosspolymer, manufactured by Dow Chemical Company, 29 mass% aqueous solution

(Component (D '))

"Eco Gum T": xanthan gum, manufactured by Dainippon Sumitomo Seiyako Co., Ltd.

(Component (E))

Trade name &quot; Laponite XL21 &quot;: fluorosilicic acid (sodium / magnesium), manufactured by Rockwood

Product name "Laponite XLG": Synthetic silicate (sodium / magnesium), manufactured by Roquewood Co.

(Examples 1 to 44 and Comparative Examples 1 to 13)

The formulation ingredients shown in Tables 1 to 8 below were blended (the mixing unit was% by mass) to prepare a stabilizer composition. The characteristics of the tonicity compositions of Examples 1 to 44 were all in the form of gel. The blending amount in the table is expressed by the actual blending amount (blending amount of the product).

The obtained tonicity agent composition was charged into a plastic container to obtain a correcting agent.

(Test Example 1: Evaluation of stickiness)

Twenty professional panels were uniformly applied to the hair of a wig (lesson mannequin: manufactured by Yukari Japan) and the hair was flattened from the front to the back so as to conform to the shape of the wig, . From the answers, stickiness was evaluated based on the following criteria.

<Evaluation criteria of stickiness>

○ (very good): More than 16 out of 20 responded that they are not sticky

△ (Good): 10 to 15 out of 20 responded that they are not sticky

× (bad): Less than 9 out of 20 responded that they are not sticky

(Test Example 2: Evaluation of initial repulsive force)

Twenty professional panels were uniformly applied to the hair of the wig (lesson mannequin: manufactured by Yukari JAPAN Co., Ltd.) and the hair was flattened from the front to the back so as to conform to the shape of the wig, . Further, it was judged that there was an initial repulsive force that the shape of the hair that had been constantly held was kept firm. From the answer, the initial repulsive force was evaluated based on the following criteria.

<Evaluation Criteria of Initial Power>

○ (very good): More than 16 out of 20 responded that they had early recovery power

△ (good): 10 to 15 out of 20 responded that they had early reproductive power

× (bad): Less than nine out of 20 responded that they had early recovery power

(Test Example 3: evaluation of retention force)

Twenty professional panelists observed the hair of the wig after the elapse of 6 hours from Test Example 2 (evaluation of the initial repulsive force), and the hair of the wig was observed to answer whether or not there was a constant retention force. Further, it was judged that there was a regular holding power in the case where the shape of the regular hair of Test Example 2 was continuously maintained. From the answers, the regular retention force was evaluated based on the following criteria.

<Criteria for Evaluation of Retention Force>

○ (very good): More than 16 out of 20 respondents said that they had regular maintenance

△ (Good): 10 to 15 out of 20 respondents answered that they had a positive remedy

× (bad): Less than nine out of 20 responded

(Test Example 4: evaluation of flaking)

After 20 professional panels, the hair of the wig was combed with the fingertips from the root of the hair to the end of the hair five times successively after the test Example 3 (evaluation of the regular holding power), and replied whether or not flaking was performed. Further, in the case where white powder appeared to be attached on the hair, it was judged that there was flaking. From the answers, flaking was evaluated based on the following criteria.

<Evaluation criteria of flaking>

○ (very good): More than 16 out of 20 responded that there is no play king

△ (Good): 10 to 15 out of 20 responded that there was no play king

× (bad): Less than 9 out of 20 answered that there is no play king

(Test Example 5: evaluation of cleaning property)

After 20 professional panels, the hair of the wig was shaved with lukewarm water using shampoo (trade name "Lucido shampoo", manufactured by Mandamusa Co., Ltd.) after the above Test Example 4 (evaluation of the flaking), and the hair was dried, ). Further, when there was no discoloration or stickiness of the hair at the time of hair frying, it was judged that the cleaning property was good. From the answers, cleaning properties were evaluated according to the following criteria.

&Lt; Evaluation Criteria of Cleanliness &

○ (very good): More than 16 out of 20 responded well

△ (Good): 10 to 15 out of 20 people answered that they had good cleanliness

× (bad): Less than nine out of 20 answered that they are clean

(Test Example 6: Evaluation of glossiness)

20 professional panel members replied that the hair of the wig was glazed after the above Test Example 2 (evaluation of the initial repulsive force). From the answer, the gloss was evaluated according to the following criteria.

&Lt; Evaluation standard of shine of hair >

○ (very good): More than 16 out of 20 responded that there was gloss

△ (Good): 10 to 15 out of 20 people answered that there was gloss

× (bad): Less than nine out of 20 answered with gloss

The results are shown in Tables 1 to 8 below. The total of the blending components in each of Examples and Comparative Examples shown in Tables 1 to 8 is 100% by mass.

Claims (6)

Which comprises the following component A and the following component B,
Wherein the content of the component A is 0.1 mass% or more and 10 mass% or less.
Component A: particles selected from the group consisting of silica, calcium carbonate, magnesium carbonate, hydroxyapatite, titanium oxide, zinc oxide, calcium silicate, magnesium silicate, aluminum silicate and magnesium hydroxide
Component B: a polyoxyethylene / polyoxypropylene copolymer which is liquid at 25 占 폚 and has a number average molecular weight of 10000 to 20000, and polyoxyethylene / polyoxypropylene copolymer which is liquid at 25 占 폚 and polyoxypropylene sorbitol having a number average molecular weight of 300 to 1000 The selected compound The cleaning agent composition according to claim 1, wherein the content of the component B is 3 mass% or more and 40 mass% or less. 3. The stabilizer composition according to claim 1 or 2, further comprising the following component (C).
Component C: a compound selected from the group consisting of a polyoxyalkylene alkyl glucoside and a polyoxyalkylene glycerin fatty acid ester 4. The stabilizing agent composition according to any one of claims 1 to 3, further comprising a component D which is a polymer selected from the group consisting of the following components D1 and D2.
Component D1: A polymer obtained by using, as an essential monomer component, two or more monomers selected from the group consisting of (meth) acrylic acid and (meth) acrylic acid alkyl ester
Component D2: As the essential monomer component, a monomer selected from the group consisting of (meth) acrylic acid and (meth) acrylic acid alkyl ester and a monomer selected from the group consisting of (meth) acrylic acid polyoxyethylene alkyl ether, itaconic acid polyoxyethylene alkyl ether and neodecanoyl vinyl ether A polymer obtained by using a monomer selected from the group consisting of 5. The stabilizer composition according to any one of claims 1 to 4, further comprising component E being a clay mineral. 5. The composition of claim 4 further comprising component E being a clay mineral,
Wherein the mass ratio of the content of the component D to the content of the component E is 1: 0.1 to 1:30.