CN105025867B - Hair mousse composition - Google Patents
Hair mousse composition Download PDFInfo
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- CN105025867B CN105025867B CN201480010908.9A CN201480010908A CN105025867B CN 105025867 B CN105025867 B CN 105025867B CN 201480010908 A CN201480010908 A CN 201480010908A CN 105025867 B CN105025867 B CN 105025867B
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/0241—Containing particulates characterized by their shape and/or structure
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/24—Phosphorous; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/25—Silicon; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/26—Aluminium; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/27—Zinc; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/29—Titanium; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/86—Polyethers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring
Abstract
The present invention provides a kind of hair mousse composition, and it can suppress the generation peeled off when being haircuted and tacky, and can improve power of haircuting at initial stage and confining force of haircuting.The hair mousse composition of the present invention is included：Below the mass % of more than 0.1 mass % 10 particle (composition A) in the group being made up of silica, calcium carbonate, magnesium carbonate, hydroxyapatite, titanium dioxide, zinc oxide, calcium silicates, magnesium silicate, alumina silicate and magnesium hydroxide；With selected from by the polyoxyethylene/polyoxypropylene copolymer that 25 DEG C are liquid and number-average molecular weight is less than more than 10,000 20000 and the compound (composition B) in the group that the polyoxypropylene D-sorbite that 25 DEG C are liquid and number-average molecular weight is less than more than 300 1000 is constituted.
Description
Technical field
The present invention relates to hair mousse composition, it is suitable for the hair mousse arranged to hair.
Background technology
In order to arrange hair, the hair mousse composition of the various characters such as liquid, gel, paste and solid-like is used.With
It is past, in order to assign the power of haircuting as major function to hair mousse composition, use polymer and forms polymer more.Using covering
In the hair mousse composition of film formation polymer, after haircuting, formed and covered on the surface of hair from polymer and forms polymer
Film.Therefore, if mixture polymer and forms polymer is as main composition of haircuting, the power of haircuting at initial stage after just haircuting is improved, but separately
When on the one hand being difficult to arrange hair with natural state, or hair being stimulated with hand or comb etc. after haircuting, cover
Film can be from the sur-face peeling of hair (producing so-called peel off), the problems such as with degraded appearance.
Therefore, a pair method different from the method using polymer and forms polymer is studied, and specifically, have studied
Using powder power of haircuting is assigned to hair mousse composition.
Following Patent Document 1 discloses a kind of hair cosmetic composition (hair mousse composition), its comprising 0.1 mass %~
10 mass % specific surface area is 50m2/ more than g fine-particle powder.The description below has been recorded in patent document 1：By with spy
Fixed above-mentioned content can obtain good sense of touch, can obtain excellent power of haircuting using specific above-mentioned fine-particle powder, and can
So that good sense of touch is long lasting for and can obtain excellent haircuting property again.
Prior art literature
Patent document
Patent document 1：Japanese Unexamined Patent Publication 2003-342130 publications
The content of the invention
The invention problem to be solved
But, as described in patent document 1, haircuted using the hair mousse composition comprising fine-particle powder
When, it can also peel off sometimes.Additionally, there are the present situation for requiring more excellent power of haircuting at initial stage and confining force of haircuting.
It is an object of the invention to provide a kind of generation that can suppress to peel off when being haircuted and tacky and can carry
The hair mousse composition of high power of haircuting at initial stage and confining force of haircuting.
Scheme for solving problem
The hair mousse composition of the present invention is following hair mousse compositions, and it includes following compositions (A) and following compositions
(B), the content of mentioned component (A) is below the mass % of more than 0.1 mass % 10.
Composition (A)：Selected from by silica, calcium carbonate, magnesium carbonate, hydroxyapatite, titanium dioxide, zinc oxide, silicic acid
Particle in the group that calcium, magnesium silicate, alumina silicate and magnesium hydroxide are constituted
Composition (B)：Selected from by be at 25 DEG C liquid and number-average molecular weight be less than more than 10,000 20000 polyoxyethylene/
Poiyoxypropylene copolymer and be the polyoxypropylene D-sorbite that liquid and number-average molecular weight are less than more than 300 1000 at 25 DEG C
Compound in the group of composition
In the hair mousse composition of the present invention, the content of mentioned component (B) be preferably more than 3 mass % 40 mass % with
Under.
The hair mousse composition of the present invention preferably further includes following compositions (C).
Composition (C)：In the group being made up of polyoxyalkylene alkyl glucoside and polyoxyalkylene fatty acid glyceride
Compound
The hair mousse composition of the present invention is preferably further included as selected from by following compositions (D1) and following compositions
(D2) composition (D) of the polymer in the group of composition.
Composition (D1)：Use two kinds in the group being made up of (methyl) acrylic acid and (methyl) alkyl acrylate
Monomer above is used as polymer obtained from necessary monomer component
Composition (D2)：Use the list in the group being made up of (methyl) acrylic acid and (methyl) alkyl acrylate
Body and selected from by (methyl) acrylic acid polyoxyethylene alkyl ether, itaconic acid polyoxyethylene alkyl ether and vinyl neodecanoate group
Into group in monomer be used as polymer obtained from necessary monomer component
The hair mousse composition of the present invention preferably further includes the composition (E) as clay mineral.
In the hair mousse composition of the present invention, the mass ratio of the content and the content of mentioned component (E) of mentioned component (D) is excellent
Elect 1 as：0.1~1：30.
The effect of invention
The hair mousse composition of the present invention includes specific composition (A) and specific composition (B), and then composition (A) contains
Amount in a specific range, therefore can suppress when haircuting the generation peeled off and tacky, and can improve power of haircuting at initial stage
With confining force of haircuting.
Embodiment
Hereinafter, the present invention is described in detail
The hair mousse composition of the present invention is comprised at least：Selected from by silica, calcium carbonate, magnesium carbonate, hydroxyapatite,
Particle in the group that titanium dioxide, zinc oxide, calcium silicates, magnesium silicate, alumina silicate and magnesium hydroxide are constituted；With selected from by 25
DEG C it is polyoxyethylene/polyoxypropylene copolymer that liquid and number-average molecular weight are less than more than 10,000 20000 and at 25 DEG C is
Compound in the group that the polyoxypropylene D-sorbite that liquid and number-average molecular weight are less than more than 300 1000 is constituted.
In this specification, " it is selected from sometimes by above-mentioned by silica, calcium carbonate, magnesium carbonate, hydroxyapatite, titanium dioxide
Particle in the group that titanium, zinc oxide, calcium silicates, magnesium silicate, alumina silicate and magnesium hydroxide are constituted " is referred to as " composition (A) ".Separately
Outside, " it is selected from sometimes by above-mentioned by being polyoxyethylene/poly- that liquid and number-average molecular weight are less than more than 10,000 20000 at 25 DEG C
Oxypropylene copolymer and be the polyoxypropylene D-sorbite group that liquid and number-average molecular weight are less than more than 300 1000 at 25 DEG C
Into group in compound " be referred to as " composition (B) ".In addition, " at 25 DEG C being liquid by above-mentioned sometimes and number-average molecular weight being
Less than more than 10000 20000 polyoxyethylene/polyoxypropylene copolymer " is referred to as " composition (B1) ", sometimes by above-mentioned " at 25 DEG C
The polyoxypropylene D-sorbite for being less than more than 300 1000 for liquid and number-average molecular weight " is referred to as " composition (B2) ".
The hair mousse composition of the present invention is preferably further included and is selected from by polyoxyalkylene alkyl glucoside and polyoxyalkylene
Compound in the group of fatty acid glyceride composition.
In this specification, " it is selected from sometimes by above-mentioned by polyoxyalkylene alkyl glucoside and polyoxyalkylene fatty acid glyceride
Compound in the group of composition " is referred to as " composition (C) ".In addition, above-mentioned " polyoxyalkylene alkyl glucoside " is referred to as into " composition sometimes
(C1) ", above-mentioned " polyoxyalkylene fatty acid glyceride " is referred to as " composition (C2) " sometimes.
The hair mousse composition of the present invention is preferably further included and is selected from by following 1st polymer and following 2nd polymer
Polymer in the group of composition.1st polymer is to use to be selected from by (methyl) acrylic acid and (methyl) alkyl acrylate group
Into group in two or more monomers be used as polymer obtained from necessary monomer component.2nd polymer be use be selected from by
(methyl) acrylic acid and (methyl) alkyl acrylate composition group in monomer and selected from by (methyl) acrylic acid polyoxy second
Monomer in the group of allylic alkylation ether, itaconic acid polyoxyethylene alkyl ether and vinyl neodecanoate composition is used as necessary monomer component
Obtained from polymer.
In this specification, above-mentioned " polymer in the group being made up of the 1st polymer and the 2nd polymer " is claimed sometimes
For " composition (D) ".In addition, above-mentioned " the 1st polymer " is referred to as into " composition (D1) " sometimes, above-mentioned " the 2nd polymer " is claimed sometimes
For " composition (D2) ".In addition, " (methyl) acrylic acid " refers to one or both of acrylic acid and methacrylic acid.
The hair mousse composition of the present invention can further include polysaccharide based compound., sometimes will be above-mentioned in this specification
" polysaccharide based compound " is referred to as " composition (D ') ".
The hair mousse composition of the present invention preferably further includes clay mineral.In this specification, sometimes by above-mentioned " clay
Mineral " are referred to as " composition (E) ".
That is, hair mousse composition of the invention comprises at least composition (A) and composition (B).The hair mousse composition of the present invention
Preferably further comprising the composition (at least one composition) in the group for selecting free component (C), composition (D) and composition (E) composition.
In the case where using composition (E), preferably by composition (E) with selecting the composition in the group that free component (D) and composition (D ') are constituted
Share.Wherein, hair mousse composition of the invention preferably include whole compositions (A), composition (B), composition (C), composition (D) and
Composition (E).The hair mousse composition of the present invention can further include other compositions.Mentioned component, such as composition (A), composition
(B), composition (C), composition (D), composition (D '), composition (E) and other compositions can be used only a kind respectively, can also use 2 kinds
More than.
It should be noted that mentioned component (B) is the compound in the group for selecting free component (B1) and composition (B2) to constitute
(at least one compound).In addition, mentioned component (C) is the compound in the group for selecting free component (C1) and composition (C2) to constitute
(at least one compound).In addition, mentioned component (D) is the polymer in the group for selecting free component (D1) and composition (D2) to constitute
(at least one polymer).Above-mentioned composition (B1), composition (B2), composition (C1), composition (C2), composition (D1), composition (D2)
1 kind can be used only respectively, two or more can also be used.
Hereinafter, the details of each composition to being used in the hair mousse composition of the present invention is illustrated.
(composition (A))
Mentioned component (A) be selected from by silica, calcium carbonate, magnesium carbonate, hydroxyapatite, titanium dioxide, zinc oxide,
Particle in the group that calcium silicates, magnesium silicate, alumina silicate and magnesium hydroxide are constituted.Mentioned component (A) mainly have suppress it is tacky,
The effect of raising power of haircuting at initial stage and confining force of haircuting.In addition, by using mentioned component (A), polymerizeing with using overlay film formation
The situation of thing is compared, and is easily haircuted again after once haircuting, and can also improve haircuting property again.
As mentioned component (A), wherein, from the aspect of performance of haircuting is improved, it is preferably selected from by silica, carbonic acid
Particle (at least one particle) in the group that magnesium, hydroxyapatite, calcium silicates, magnesium silicate, alumina silicate and magnesium hydroxide are constituted,
It is more preferably selected from the particle (at least one particle) in the group that is made up of silica, magnesium silicate and magnesium hydroxide.It is above-mentioned into
Divide (A) that a kind can be used only, two or more can also be used.
<Silica>
As above-mentioned silica, known usual silica (silicic acid anhydride) can be used.Above-mentioned silica can be with
For the silicic acid anhydride (hydrophilic silica) without silicic acid anhydride, or hydrophobization silicic acid anhydride.In addition, above-mentioned dioxy
SiClx can also be the silica being surface-treated with amino acid, ester or lecithin etc..In addition, above-mentioned silica
It can be so-called easy disintegrating silica dioxide granule.Above-mentioned silica can be used only a kind, can also use two or more.
Above-mentioned hydrophobization silicic acid anhydride is to have carried out the material of silicic acid anhydride to silicic acid anhydride (such as untreated silicic acid anhydride).
As inorganic agent used in silicic acid anhydride, Organosilyl compound and silicone compounds etc. can be enumerated.As upper
Organosilyl compound is stated, methyl trichlorosilane, dimethyldichlorosilane, trim,ethylchlorosilane, hexamethyl can be enumerated
Disilazane, methyl trialkoxysilane, dimethyldialkylammonium TMOS, trimethylalkyoxys iotalane, ethyl trichlorosilane, third
Base trichlorosilane, hexyl trichlorosilane, chain alkyl trichlorosilane, ethyltrialkoxysilanes, propyl trialkoxy silane, oneself
Base trialkoxy silane, chain alkyl trialkoxy silane, methacryl silanes, fluoroalkyl silanes and perfluoroalkyl silanes
Deng.As above-mentioned silicone compounds, dimethyl polysiloxane (silicone oil), methyl phenyl silicone, methyl hydrogen can be enumerated and gathered
Siloxanes and amino modified silicone etc..As the method for above-mentioned silicic acid anhydride, known method can be used.Dredged as above-mentioned
The method of hydration process, can enumerate liquid phase method, vapor phase method and autoclave method etc..
As the preference of above-mentioned hydrophobization silicic acid anhydride, dimethyl silane epoxide SiClx acid anhydrides, trimethyl can be enumerated
Siloxy SiClx acid anhydrides, octyl group siloxy SiClx acid anhydrides, silicone oil processes silicic acid anhydride and methacrylic acid monosilane oxygen
Base SiClx acid anhydrides etc..
Above-mentioned easy disintegrating silica dioxide granule is particle formed by multiple silica primary particle set.As upper
Silica primary particle is stated, is not particularly limited, for example, can enumerate spherical silica particles, flakey silica
Grain and amorphous silica particles etc..Average grain diameter to above-mentioned silica primary particle is not particularly limited.
In addition, above-mentioned easy disintegrating silica dioxide granule can include the composition beyond silica.It is used as above-mentioned dioxy
Composition (hereinafter sometimes referred to " component content ") beyond SiClx, is not particularly limited, for example, can enumerate surfactant, many
First alcohol, higher alcohol, sugar alcohol, silicone oil, chelating agent, antioxidant, plant extracts, pigment, pigment, spices, NMF, vitamin
Class, amino acids and freshener etc..Wherein, preferred amino acid class, silicone oil, vitamins.As above-mentioned amino acids, without spy
Do not limit, two (lauramide glutamine) lysine Na (for example, Asahi Chemical Corp's manufacture, commodity can be enumerated
Name " pellicer "), trimethylglycine and glutamic acid etc..By making above-mentioned easy disintegrating silica dioxide granule include in above-mentioned
Containing composition, component content is discharged if above-mentioned easy disintegrating silica dioxide granule is disintegrated when haircuting, can give play to and include
The corresponding effect of species of composition.For example, by above-mentioned easy disintegrating silica dioxide granule embedded amine groups acids, hair can have been given play to
The damage nursing function of hair.
As the manufacture method of above-mentioned easy disintegrating silica dioxide granule, it is not particularly limited, known side can be used
Method.
The oil absorption of above-mentioned silica is preferably more than 100mL/100g, more preferably more than 150mL/100g, enters one
Step be preferably more than 200mL/100g, preferably below 1000mL/100g, more preferably below 800mL/100g, further it is excellent
Elect below 700mL/100g as.When the oil absorption of above-mentioned silica is more than above-mentioned lower limit and below the above-mentioned upper limit, initial stage is whole
Have an effect, the confining force and haircuting property becomes more preferable again of haircuting.Method of the above-mentioned oil absorption according to described in JIS K5101 is surveyed
It is fixed.
As the commercially available product of above-mentioned silica, for example, it can enumerate the Fuji Silysia as silicic acid anhydride
Chemical societies manufacture trade name " Sylysia 320 ", trade name " Sylysia 310P ", trade name " Sylysia 250 ",
Trade name " Sylysia 250N ", trade name " Sylysia 350 ", trade name " Sylysia 370 ", trade name " Sylysia
380 ", trade name " Sylysia 420 ", trade name " Sylysia 430 ", trade name " Sylysia 440 ", trade name
" Sylysia 450 " and trade name " Sylysia 470 "；The trade name manufactured as the NIPPON AEROSIL societies of silicic acid anhydride
" AEROSIL 50 ", trade name " AEROSIL 90G ", trade name " AEROSIL 130 ", trade name " AEROSIL 150 ", commodity
Name " AEROSIL 200 ", trade name " AEROSIL 300 ", trade name " AEROSIL 380 ", trade name " AEROSIL 200V "
With trade name " AEROSIL OX50 "；As silicic acid anhydride AGC Si-Tech societies manufacture trade name " Sunsphere H-31 ",
Trade name " Sunsphere H-51 ", trade name " Sunsphere H-121 ", trade name " Sunsphere H-201 ", trade name
" Sunsphere H-32 ", trade name " Sunsphere H-52 ", trade name " Sunsphere H-122 ", trade name
" Sunsphere H-33 " and trade name " Sunsphere H-53 "；It is used as the NIPPON of dimethyl silane epoxide SiClx acid anhydrides
Trade name " AEROSIL R972 ", trade name " AEROSIL R974 " and the trade name " AEROSIL of AEROSIL societies manufacture
R9200”；Trade name " the AEROSIL manufactured as the NIPPON AEROSIL societies of trimethylsiloxy SiClx acid anhydrides
RX200 ", trade name " AEROSIL R8200 ", trade name " AEROSIL RX300 " and trade name " AEROSIL R812S "；Make
Trade name " the AEROSIL R805 " manufactured for the NIPPON AEROSIL societies of octyl group siloxy SiClx acid anhydrides；It is used as silicone oil
Handle silicic acid anhydride NIPPON AEROSIL societies manufacture trade name " AEROSIL R202 ", trade name " AEROSIL RY200 ",
Trade name " AEROSIL RY200S " and trade name " AEROSIL RY300 "；It is used as methacrylic acid monosilane epoxide SiClx acid
Trade name " the AEROSIL R711 " of the NIPPON AEROSIL societies manufacture of acid anhydride；It is good as the three of Shang Shu Yang disintegrative silica
It is melted into trade name " the silica beads SB-705 " of society's manufacture；Manufactured as the Suzuki grease society of Shang Shu Yang disintegrative silica
Trade name " God Ball SF-16C ", trade name " God Ball AF-6C " and trade name " God Ball AF-16C " etc..
<Calcium carbonate>
For example with INCI, " CALCIUM CARBONATE " are represented above-mentioned calcium carbonate.Above-mentioned calcium carbonate can be used only 1
Kind, two or more can also be used.As the commercially available product of above-mentioned calcium carbonate, for example, it can enumerate the business of Sakai chemical industry society manufacture
The name of an article " Calmaru SCS M5 "；Trade name " FUWACAL " of shiraishi calcium society manufacture etc..
<Magnesium carbonate>
For example with INCI, " MAGNESIUM CARBONATE " are represented above-mentioned magnesium carbonate.Above-mentioned magnesium carbonate can be used only 1
Kind, two or more can also be used.As the commercially available product of above-mentioned magnesium carbonate, for example, it can enumerate the commodity of Fu Tian pharmacy society manufacture
Name " light magnesium carbonate " etc..
<Hydroxyapatite>
Above-mentioned hydroxyapatite is for example represented with INCI " HYDROXYAPATITE ".Above-mentioned hydroxyapatite can only make
With a kind, two or more can also be used.
As above-mentioned hydroxyapatite, it is not particularly limited, for example, can enumerates spherical hydroxyapatite, the hydroxyl of sheet
Base apatite and amorphous hydroxyapatite etc..Wherein, it is preferably spherical from the aspect of high performance of haircuting has been given play to
Hydroxyapatite.As the commercially available product of above-mentioned hydroxyapatite, for example, it can enumerate the trade name of peaceful Chemical Industries society manufacture
" sheet HAP ", trade name " spherical HAP ", trade name " HAP-100 ", trade name " HAP-200 " and trade name " HAP-300 " etc..
<Titanium dioxide>
For example with INCI, " TITANIUM DIOXIDE " are represented above-mentioned titanium dioxide.It is not special to above-mentioned titanium dioxide
Limit, for example, can be fine particulate titanium dioxide, or pigment titanium.Above-mentioned titanium dioxide can be used only a kind, can also make
Use two or more.As the commercially available product of above-mentioned titanium dioxide, for example, it can enumerate the trade name " TTO-55 that stone originates in the manufacture of industry society
" and trade name " CR-50 " etc. (A).
<Zinc oxide>
For example with INCI, " ZINC OXIDE " are represented above-mentioned zinc oxide.Above-mentioned zinc oxide can be used only a kind, can also
Use two or more.As the commercially available product of above-mentioned zinc oxide, for example, it can enumerate the trade name of Sakai chemical industry society manufacture
" FINEX-30S-LP2 " etc..
<Calcium silicates>
For example with INCI, " CALCIUM SILICATE " are represented above-mentioned calcium silicates.Above-mentioned calcium silicates can be used only a kind,
Two or more can also be used.As the commercially available product of above-mentioned calcium silicates, for example, it can enumerate the trade name of Fu Tian pharmacy society manufacture
“FLORITE R”；Trade name " eakleite powder X-ray J " and the trade name " snow of JAPAN INSULATION CO., LTD. manufactures
Silico-calcium stone powder TK " etc..
<Magnesium silicate>
For example with INCI, " MAGNESIUM SILICATE " are represented above-mentioned magnesium silicate.Above-mentioned magnesium silicate can be used only 1
Kind, two or more can also be used.As the commercially available product of above-mentioned magnesium silicate, for example, it can enumerate the commodity of Fu Tian pharmacy society manufacture
Name " magnesium silicate (lightweight) " etc..
<Alumina silicate>
For example with INCI, " ALUMINUM SILICATE " are represented above-mentioned alumina silicate.Above-mentioned alumina silicate can be used only 1
Kind, two or more can also be used.As alumina silicate, it is not particularly limited, preferably synthetic alumina silicate.As synthetic method, for example
It can enumerate：Na is added into alum2SiO3And precipitate dry method by what is generated；Silicic acid is made by electroosmose process molten
Glue, the method for thus generating gel；And the method that the aqueous solution of aluminium salt is added into waterglass；Etc..It is used as above-mentioned silicic acid
The commercially available product of aluminium, such as the trade name " synthetic aluminium silicate (heavy) " that can enumerate the manufacture of Fu Tian pharmacy society.
<Magnesium hydroxide>
For example with INCI, " MAGNESIUM HYDROXIDE " are represented above-mentioned magnesium hydroxide.Above-mentioned magnesium hydroxide can be only
Using a kind, two or more can also be used.As the commercially available product of above-mentioned magnesium hydroxide, for example, it can enumerate the manufacture of Fu Tian pharmacy society
Trade name " magnesium hydroxide (heavy) " etc..
In the mass % of hair mousse composition 100 of the present invention, the content of mentioned component (A) is more than 0.1 mass %, excellent
Elect as more than 0.4 mass %, more preferably more than 1 mass %, be below 10 mass %, be preferably below 7 mass %, more preferably
For below 5 mass %.It is first after just haircuting more than above-mentioned lower limit, can further to improve by the content of mentioned component (A)
Phase power of haircuting, and can further improve confining force of haircuting.Content by mentioned component (A) is below the above-mentioned upper limit, to assign
The effect and washing away property of gloss is given further to improve.The content of mentioned component (A) is complete in the hair mousse composition of the present invention
The total amount of the content of portion's composition (A).In addition, in the mass % of hair mousse composition 100 of the present invention, the content of silica,
And selected from by calcium carbonate, magnesium carbonate, hydroxyapatite, titanium dioxide, zinc oxide, calcium silicates, magnesium silicate, alumina silicate and hydrogen
The content (total content) of particle in the group of magnesia composition is respectively more than 0.1 mass %, be preferably 0.4 mass % with
Upper, more preferably more than 1 mass %, is below 10 mass %, is preferably below 7 mass %, more preferably below 5 mass %.
(composition (B))
Mentioned component (B) is selected from least one of the group being made up of mentioned component (B1) and mentioned component (B2) chemical combination
Thing.Mentioned component (B) mainly effectively improves the effect of power of haircuting at initial stage and confining force of haircuting.In addition, by using above-mentioned
Composition (B), can suppress to peel off, give play to the effect above.Mentioned component (B) can be used only a kind, can also use 2 kinds with
On.It should be noted that mentioned component (B1), mentioned component (B2) also respectively can be used only a kind, can also use 2 kinds with
On.
As mentioned component (B), any one in mentioned component (B1) and mentioned component (B2) can be used only, also may be used
To share mentioned component (B1) and mentioned component (B2).Wherein, the aspect improved from the continuation of power of haircuting, it is preferably suitable
Mentioned component (B1) and mentioned component (B2).
Mentioned component (B1) is polyoxyethylene/polyoxypropylene copolymer.That is, mentioned component (B1) be at least have 2 with
The copolymer of upper ethylene oxide unit (ethylene oxide unit) and more than 2 propylene oxide units (propylene oxide unit).It is above-mentioned
Composition (B1) can be any of block copolymer, random copolymer and alternate copolymer, in mentioned component (B1)
Copolymerization mode is not particularly limited.
The average addition molal quantity of ethylene oxide in mentioned component (B1) is not particularly limited, preferably more than 100,
More preferably more than 200, preferably less than 400, less than 350 are more preferably.To the flat of the propylene oxide in mentioned component (B1)
Equal addition molal quantity is not particularly limited, preferably more than 30, particularly preferably more than 40, preferably less than 150, particularly preferably
For less than 100.
From suppress peel off in terms of, the coating easiness of hair mousse, to hair imparting gloss aspect, mentioned component
(B1) it is liquid at 25 DEG C.
The number-average molecular weight of mentioned component (B1) is less than more than 10,000 20000.The number-average molecular weight of mentioned component (B1)
During less than above-mentioned lower limit, haircuting property reduction.When the number-average molecular weight of mentioned component (B1) exceedes the above-mentioned upper limit, treatability is deteriorated.
The number-average molecular weight of mentioned component (B1) is preferably more than 12000.The number-average molecular weight of mentioned component (B1) be preferably 18000 with
Under.
Mentioned component (B2) is polyoxypropylene D-sorbite.Average addition to the propylene oxide in mentioned component (B2) rubs
You are not particularly limited number, and preferably more than 4, more preferably more than 8, preferably less than 15, more preferably less than 12.
From suppress peel off in terms of, the coating easiness of hair mousse, to hair imparting gloss aspect, mentioned component
(B2) it is liquid at 25 DEG C.
The number-average molecular weight of mentioned component (B2) is less than more than 300 1000.The number-average molecular weight of mentioned component (B2) is excellent
Elect more than 400 as.The number-average molecular weight of mentioned component (B2) is preferably less than 800.
Mentioned component (B) is liquid at 25 DEG C.Mentioned component (B) preferably has mobility at 25 DEG C, for example, preferably have
Following characters：50g samples are fitted into radius 2cm, height 7cm vial, above-mentioned vial run at a temperature of 25 DEG C
When, sample is dripped from vial when 5 minutes after overturning.
As mentioned component (B1) commercially available product, for example, it can enumerate the trade name of chemical conversion industry society of Sanyo manufacture
" Newpol 75H-90000 " etc..
As mentioned component (B2) commercially available product, for example, it can enumerate the trade name of chemical conversion industry society of Sanyo manufacture
" Newpol SP-750 " and trade name " Sannix SP-750 " etc..
In the mass % of hair mousse composition 100 of the present invention, the content of mentioned component (B) is preferably more than 3 mass %,
More preferably more than 5 mass %, more preferably more than 8 mass %, more preferably preferably below 40 mass %, 30 matter
Measure below %, more preferably below 20 mass %.The content of mentioned component (B) be above-mentioned lower limit more than when, power of haircuting and
Its continuation becomes more preferable.When the content of mentioned component (B) is below the above-mentioned upper limit, prolonging when tacky inhibition, coating
Malleability and amalgamation become more preferable.The content of mentioned component (B) is whole compositions (B) in the hair mousse composition of the present invention
The total amount of content.
In the hair mousse composition of the present invention, the mass ratio of the content of mentioned component (A) and the content of mentioned component (B)
(the content of mentioned component (A)：The content of mentioned component (B)) it is preferably 1：0.1~1：30th, it is more preferably 1：1~1：20th, one is entered
Step is preferably 1：3~1：20.When the content of mentioned component (A) is relatively more, the Forming ability of soft moulding becomes more preferable.It is above-mentioned
When the content of composition (B) is relatively more, making the formative nature of closely hair stream becomes more preferable.The content of silica with it is above-mentioned into
Divide the mass ratio of the content of (B) and selected from by calcium carbonate, magnesium carbonate, hydroxyapatite, titanium dioxide, zinc oxide, silicic acid
The content (total content) of particle in the group that calcium, magnesium silicate, alumina silicate and magnesium hydroxide are constituted and mentioned component (B)
The mass ratio of content is respectively preferably 1：0.1~1：30th, it is more preferably 1：1~1：20th, it is more preferably 1：3~1：20.
(composition (C))
Mentioned component (C) is selected from least one of the group being made up of mentioned component (C1) and mentioned component (C2) chemical combination
Thing.It by using mentioned component (C), can further suppress to peel off, and can improve the washing away property after haircuting, and can be with
While high power of haircuting at initial stage is maintained to haircuting after hair assign good feel.In addition, whole even in being assigned to hair
In the state of hair agent composition, hair are fully haircuted, the sense of discomfort that hair mousse composition sclerozone comes can also be suppressed, can
Haircuted with natural state.Mentioned component (C) can be used only a kind, can also use two or more.It should be noted that
Mentioned component (C1), mentioned component (C2) can also be used only a kind respectively, can also use two or more.
As mentioned component (C), any one in mentioned component (C1) and mentioned component (C2) can be used only, also may be used
So that mentioned component (C1) and mentioned component (C2) to be shared.
Mentioned component (C1) is polyoxyalkylene alkyl glucoside., can be with as the oxyalkylene alkyl in mentioned component (C1)
Enumerate oxyethylene group and oxypropylene group etc..Do not have to the average addition molal quantity of the oxyalkylene alkyl in mentioned component (C1)
It is particularly limited to, preferably more than 5, preferably less than 40.The carbon number of alkyl in mentioned component (C1) is preferably 1~4, more
Preferably 1~3.Alkyl in mentioned component (C1) is preferably methyl or ethyl.
As mentioned component (C1), it is not particularly limited, Glucam E-10, polyoxyethylene ethyl can be enumerated
Glucoside, PP 25 and polyoxypropylene ethyl cyclophosphadenosine glycoside etc..
Hair after while high power of haircuting at initial stage is maintained to haircuting is assigned from the aspect of more preferable feel, above-mentioned
Composition (C1) is preferably Glucam E-10.
Mentioned component (C2) is polyoxyalkylene fatty acid glyceride.The carbon number of aliphatic acid in mentioned component (C2) is excellent
Elect more than 8 as, be preferably less than 22.As the oxyalkylene alkyl in mentioned component (C2), oxyethylene group and oxygen can be enumerated
Change acrylic etc..The average addition molal quantity of oxyalkylene alkyl in mentioned component (C2) is preferably more than 5, be preferably 40 with
Under.
Hair after while high power of haircuting at initial stage is maintained to haircuting is assigned from the aspect of more preferable feel, above-mentioned
Aliphatic acid in composition (C2) is preferably branched chain fatty acid, and mentioned component (C2) is preferably polyoxyalkylene glycerine branched chain fatty acid
Ester.
Hair after while high power of haircuting at initial stage is maintained to haircuting is assigned from the aspect of more preferable feel, above-mentioned
The carbon number of branched chain fatty acid in polyoxyalkylene glycerine side chain fatty acid ester is preferably more than 8, is preferably less than 22.As
Branched chain fatty acid in above-mentioned polyoxyalkylene glycerine side chain fatty acid ester, can enumerate 2 ethyl hexanoic acid, different n-nonanoic acid, different palmitic acid
With isostearic acid etc..
It is used as above-mentioned polyoxyalkylene glycerine side chain fatty acid ester, particularly preferred isostearic acid polyoxyethylene glyceride.
As mentioned component (C1) commercially available product, for example, it can enumerate the trade name " MACBIOBRIDE of You societies manufacture
MG-10P”；Trade name " GLUCAM E-10 " and trade name " the GLUCAM E-20 " of Noveon societies manufacture；Amerchol societies manufacture
Trade name " GLUCAM P-10 " etc..
As mentioned component (C2) commercially available product, for example, it can enumerate the trade name of the first industrial pharmaceutical society manufacture
“Noigen GIS-125”；Trade name " EMALEX GWIS-115 ", the trade name " EMALEX of NIHON EMULSION societies manufacture
GWIS-120 ", trade name " EMALEX GWIS-125 " and trade name " EMALEX GWIS-130 " etc..
In the mass % of hair mousse composition 100 of the present invention, the content of mentioned component (C) be preferably 0.5 mass % with
Upper, more preferably more than 1 mass %, more preferably preferably below 20 mass %, below 10 mass %.Mentioned component (C)
When content is more than above-mentioned lower limit, it can further suppress to peel off, and the washing away property after haircuting becomes more preferable, and can be to whole
Hair after hair assigns more preferable feel.It is tacky further to be mitigated when the content of mentioned component (C) is below the above-mentioned upper limit.
The content of mentioned component (C) for the present invention hair mousse composition in whole compositions (C) content total amount.
In above-mentioned hair mousse composition, the mass ratio of the content and the content of mentioned component (C) of mentioned component (A) is (above-mentioned
The content of composition (A)：The content of mentioned component (C)) it is preferably 1：0.2~1：20th, it is more preferably 1：1~1：10.If it is above-mentioned into
The content of point (C) is relatively more, then the feel of hair, peel off inhibition, washing away property and become more preferable.The content of silica with
The mass ratio of the content of mentioned component (C) and selected from by calcium carbonate, magnesium carbonate, hydroxyapatite, titanium dioxide, zinc oxide,
The content (total content) and mentioned component of particle in the group that calcium silicates, magnesium silicate, alumina silicate and magnesium hydroxide are constituted
(C) mass ratio of content is respectively preferably 1：0.2~1：20th, it is more preferably 1：1~1：10.
(composition (D))
Mentioned component (D) is selected from the polymerization of at least one of group being made up of mentioned component (D1) and mentioned component (D2)
Thing.By using mentioned component (D), hair mousse composition is moderately thickened, therefore the dispersiveness of mentioned component (A) becomes more preferable,
And then hair mousse composition becomes to be difficult to separate, storage stability becomes more preferable.In addition, haircuting property becomes more preferable.Mentioned component
(D) a kind can be used only, two or more can also be used.It should be noted that mentioned component (D1), mentioned component (D2) also divide
1 kind can be used only, two or more can also be used.
The monomer component of polymer for obtaining mentioned component (D1) comprise at least be selected from by (methyl) acrylic acid and
Two or more monomers in the group of (methyl) alkyl acrylate composition.That is, mentioned component (D1) be comprise at least be selected from by
Two kinds in the group of construction unit from (methyl) acrylic acid and the construction unit composition from (methyl) alkyl acrylate
The polymer of above construction unit.It should be noted that in this specification, can be equivalent to mentioned component (D1) and mentioned component
Both (D2) polymer is not composition (D1) but composition (D2).
As mentioned component (D1), be not particularly limited, preferably with INCI (international cosmetic raw material dictionary and handbook,
14th edition, volume 1, CTFA, 2012, p.60~61) it is expressed as " ACRYLATES COPOLYMER (acrylic acid (ester) class copolymerization
Thing) " compound.
As mentioned component (D1) commercially available product, for example, it can enumerate the trade name " Aculyn of DOW Chemical society manufacture
33 " and trade name " Aculyn 33A "；Trade name " SepiMAX ZEN " etc. of SEPPIC societies manufacture.
Mentioned component (D1) is not particularly limited, has preferably been carried out neutralizing or with alkaline matter with alkaline matter
Used with after.As above-mentioned alkaline matter, the ethyl alcohol amine such as can enumerate triethanolamine and MEA；Ammonia, hydroxide
The inorganic base such as sodium and potassium hydroxide；Basic amino acids such as arginine etc..In addition, the addition of above-mentioned alkaline matter is abundant to reach
The amount of composition (D1) after neutralization or sufficiently measured for neutralizing mentioned component (D1), as long as according to mentioned component (D1)
With the appropriate mixture of consumption of the species and mentioned component (D1) of above-mentioned alkaline matter.
The monomer component of polymer for obtaining mentioned component (D2), which is comprised at least, to be selected from by (methyl) acrylic acid and (first
Base) alkyl acrylate composition at least one of group monomer component (d2a) and selected from by (methyl) acrylic acid polyoxyethylene
At least one of the group of alkyl ether, itaconic acid polyoxyethylene alkyl ether and vinyl neodecanoate composition monomer component (d2b).
That is, mentioned component (D2) is including at least the construction unit from above-mentioned monomer component (d2a) and from above-mentioned monomer component
(d2b) polymer of construction unit.Above-mentioned monomer component (d2a), above-mentioned monomer component (d2b) can be used only a kind respectively,
Two or more can also be used.
As mentioned component (D2), be not particularly limited, preferably with INCI (international cosmetic raw material dictionary and handbook,
14th edition, volume 1, CTFA, 2012, p.66~67) it is expressed as " ACRYLATES/STEARETH-20METHACRYLATE
COPOLYMER (acrylic acid (ester) class/methacrylate copolymer of stereth -20) " compound；With INCI (states
Border cosmetic material dictionary and handbook, the 14th edition, volume 1, CTFA, 2012, p.67) it is expressed as " ACRYLATES/
STEARETH-20METHACRYLATE CROSSPOLYMER (hand over by acrylic acid (ester) class/methacrylate of stereth -20
Linked polymer) " compound；With INCI (international cosmetic raw material dictionary and handbooks, the 14th edition, volume 1, CTFA, 2012
Year, p.57) it is expressed as " ACRYLATES/BEHENETH-25METHACRYLATE COPOLYMER (acrylic acid (ester) class/behenyls
The methacrylate copolymer of alcohol polyethers -25) " compound；With INCI (international cosmetic raw material dictionary and handbooks, the 14th
Version, volume 1, CTFA, 2012, p.68~69) it is expressed as " ACRYLATES/VINYL NEODECANOATE
CROSSPOLYMER (acrylic acid (ester) class/vinyl neodecanoate cross-linked polymer) " compound；(made up the world with INCI
Product raw material dictionary and handbook, the 14th edition, volume 1, CTFA, 2012, p.66) it is expressed as " ACRYLATES/STEARETH-
20ITACONATE COPOLYMER (acrylic acid (ester) class/itaconate copolymeric of stereth -20) " compound；With
INCI (international cosmetic raw material dictionary and handbook, the 14th edition, volume 1, CTFA, 2012, p.60) be expressed as
" (acrylic acid (ester) class/itaconate of ceteth -20 is total to ACRYLATES/CETETH-20ITACONATE COPOLYMER
Polymers) " compound etc..
As mentioned component (D2) commercially available product, for example, it can enumerate the trade name " Aculyn of DOW Chemical society manufacture
22 ", trade name " Aculyn 88 ", trade name " Aculyn 28 " and trade name " Aculyn 38 "；The manufacture of Akzo Nobel societies
Trade name " STRUCTURE 2001 " and trade name " STRUCTURE 3001 " etc..
Mentioned component (D2) is not particularly limited, has preferably been carried out neutralizing or with alkaline matter with alkaline matter
Used with after.As alkaline matter now, above-mentioned alkaline matter can be enumerated.In addition, the addition of above-mentioned alkaline matter
To reach the amount of the composition (D2) after fully neutralizing or sufficiently being measured for neutralizing mentioned component (D2), as long as according to upper
State the appropriate mixture of consumption of the species and mentioned component (D2) of composition (D2) and above-mentioned alkaline matter.
In the mass % of hair mousse composition 100 of the present invention, the content of mentioned component (D) be preferably 0.01 mass % with
Upper, more preferably more than 0.1 mass %, more preferably preferably below 5 mass %, below 2 mass %.Mentioned component (D)
When content is more than above-mentioned lower limit, assigning the effect of gloss and the storage stability of hair mousse composition becomes more preferable.It is above-mentioned into
When dividing the content of (D) for below the above-mentioned upper limit, power of haircuting is further improved, and the feel of hair becomes more preferable.Mentioned component (D)
Content for the present invention hair mousse composition in whole compositions (D) content total amount.It should be noted that using above-mentioned
In the case of composition (D '), particularly in the mass % of hair mousse composition 100 of the present invention, the content of mentioned component (D) can
Think 0 mass % (unused).
(composition (D '))
Mentioned component (D ') is polysaccharide based compound.By using mentioned component (D '), hair mousse composition is moderately thickened,
Therefore the dispersiveness of mentioned component (A) becomes more preferable, and then hair mousse composition becomes to be difficult to separate, and storage stability becomes more
It is good.Mentioned component (D ') can be used only a kind, can also use two or more.
As mentioned component (D '), it is not particularly limited, preferred polysaccharide, modification of polysaccharides (such as alkyl-modified polysaccharide)
Deng can for example enumerate alginic acid, carragheen, agar, pharselan, guar gum, Wen Quinces seed, konjac glucomannan, tamarind
Glue, tara gum, dextrin, starch, locust bean gum, Arabic gum, ghatti gum, Karaya Gum, bassora gum, arabinogalactan
Sugar, pectin are He the polysaccharide based compound of the plant origin such as Wen Quince；The polysaccharide system chemical combination of the animal origin such as chitosan and hyaluronic acid
Thing；Microbe-derived many such as curdlan, xanthans, gellan gum, cyclodextrin, dextran, amylopectin and hyaluronic acid
Sugared based compound；Microcrystalline cellulose, methylcellulose, ethyl cellulose, hydroxymethyl cellulose, hydroxyethyl cellulose, hydroxypropyl
The non-ionic cellulose such as cellulose and hydroxypropyl methyl cellulose element；The anionic celluloses such as carboxymethyl cellulose element；Chlorination O-
The cationized celluloses such as [2- hydroxyls -3- (trimethyl ammonium) propyl group] hydroxyethyl cellulose；Chlorination O- [2- hydroxyl -3- (front threes
Base ammonium) propyl group] the cationized guar glue such as guar gum etc..
As mentioned component (D '), wherein, it is preferably selected from being made up of xanthans, guar gum, tamarind gum and gellan gum
Group in compound (at least one compound).
As mentioned component (D ') commercially available product, for example, it can enumerate the big SUMITOMO CHEMICAL pharmacy society manufacture as xanthans
Trade name " ECHO GUM T ", trade name " ケ Le デ Application ト " and trade name " モ ナ ー ト ガ system "；As guar gum she
Trade name " the Inagel guar gum CS " of that food industry society manufacture；It is used as the DSP GOKYO FOOD＆ of tamarind gum
Trade name " the GLYLOID 6C " of CHEMICAL Co., Ltd. manufactures；It is used as CP Kelco U.S., the Inc. manufactures of gellan gum
Trade name " Kelcogel " etc..
In the mass % of hair mousse composition 100 of the present invention, the content of mentioned component (D ') is preferably 0.01 mass %
Above, more preferably more than 0.1 mass %, more preferably preferably below 5 mass %, below 2 mass %.Mentioned component (D ')
Content to be more than above-mentioned lower limit when, the storage stability of hair mousse composition becomes more preferable.The content of mentioned component (D ') is
It is tacky to become more preferable when below the above-mentioned upper limit.The content of mentioned component (D ') is the whole in the hair mousse composition of the present invention
The total amount of the content of composition (D ').It should be noted that in the case where using mentioned component (D), particularly the present invention's
In the mass % of hair mousse composition 100, the content of mentioned component (D ') can be 0 mass % (unused).
(composition (E))
Mentioned component (E) is clay mineral.By using mentioned component (E), the preservation of power of haircuting and hair mousse composition
Stability becomes more preferable.Mentioned component (E) can be used only a kind, can also use two or more.
Mentioned component (E) can be natural goods, or synthetic.As mentioned component (E), it is not particularly limited,
Kaolin group's clay mineral, antigorite race clay mineral, pyrophyllite race clay mineral, Mica Group clay pit can for example be enumerated
Thing, smectite clay mineral, vermiculite race clay mineral, chlorite race clay mineral and organo-clay mineral etc..
As above-mentioned kaolin group's clay mineral, kaolin, nacrite, dickite and halloysite etc. can be enumerated.Make
For above-mentioned antigorite race clay mineral, antigorite, pictoamesite and cronstedtite etc. can be enumerated.It is used as above-mentioned pyrophyllite race
Clay mineral, can enumerate pyrophyllite and talcum (talcum) etc..As above-mentioned Mica Group clay mineral, can enumerate illite,
Glauconite, seladonit, sericite, mica (mica), muscovite, fuchsite and biotite etc..It is viscous as above-mentioned smectite race
Native mineral, can enumerate bentonite, montmorillonite, beidellite, nontronite, saponite, hectorite (Hectorite) and synthesis lithium and cover
De- stone (Lucentite) etc..As above-mentioned vermiculite race clay mineral, vermiculite etc. can be enumerated.It is used as above-mentioned chlorite race clay
Mineral, can enumerate chlorite (chlorite) etc..As above-mentioned organo-clay mineral, smectite clay can be enumerated
Mineral or vermiculite race clay mineral etc. have carried out organo-clay mineral of organically-modified processing etc..Fitted in organically-modified processing
Preferably use quaternary ammonium salt cationic surfactant.As above-mentioned quaternary ammonium salt cationic surfactant, it can enumerate above-mentioned
Alkyl trimethyl ammonium chloride, dialkyl dimethyl ammonium chloride and benzalkonium chloride etc..
From the aspect of further improvement storage stability and use feeling, mentioned component (E) is preferably selected from by synthesizing
Clay mineral in the group of silicate and its derivative composition.Above-mentioned synthetic silicate and its derivative are not with containing many
Magnesium silicate or silicic acid (sodium/magnesium) of the natural origin of impurity etc. are the silicate mineral of main component, but are obtained by synthesis
Silicate and silicate derivative.
As above-mentioned synthetic silicate and its derivative, for example, it can enumerate with INCI (international cosmetic raw material dictionaries
With handbook (International Cosmetic Ingredient Dictionary and Handbook), the 14th edition, the 2nd
Volume, CTFA, 2012, p.3076)：SODIUM MAGNESIUM SILICATE (sodium magnesium silicate) represent synthetic silicic acid (sodium/
Magnesium), volume 2, CTFA, 2012, p.1793 with INCI (international cosmetic raw material dictionary and handbooks, the 14th edition)：
MAGNESIUM FLUOROSILICATE (magnesium fluosilicate) represent magnesium fluosilicate, with INCI (international cosmetic raw material dictionaries
And handbook, the 14th edition, volume 2, CTFA, 2012, p.3076)：SODIUM MAGNESIUM FLUOROSILICATE (fluorine silicon
Sour magnesium sodium) represent fluosilicic acid (sodium/magnesium), with INCI (international cosmetic raw material dictionary and handbook, the 14th edition, volume 2,
CTFA, 2012, p.1799)：The fluorine silicon that MAGNESIUM POTASSIUM FLUOROSILICATE (potassium fluosilicate magnesium) are represented
Volume 2, CTFA, 2012, p.1800 sour (magnesium/potassium), with INCI (international cosmetic raw material dictionary and handbooks, the 14th edition)：
MAGNESIUM SODIUM FLUOROSILICATE (prodan magnesium) represent fluosilicic acid (magnesium/sodium), with INCI (worlds
Cosmetic material dictionary and handbook, the 14th edition, volume 1, CTFA, 2012, p.156)：ALUMINUM SILICATE (silicic acid
Aluminium) synthetic aluminium silicate etc. that represents.
As mentioned component (E), wherein, particularly preferably be selected from by synthetic silicic acid (sodium/magnesium), fluosilicic acid (sodium/magnesium) and
Clay mineral (at least one clay mineral) in the group of fluosilicic acid (sodium/magnesium) composition.
As mentioned component (E) commercially available product, for example, it can enumerate the trade name " LAPONITE of Rockwood societies manufacture
XLG " and trade name " LAPONITE XL21 " etc..
In the mass % of hair mousse composition 100 of the present invention, the content of mentioned component (E) be preferably 0.1 mass % with
Upper, more preferably more than 0.3 mass %, more preferably more than 0.5 mass %, preferably below 10 mass %, more preferably
For below 5 mass %, more preferably below 3 mass %.When the content of mentioned component (E) is more than above-mentioned lower limit, haircut
Property becomes more preferable.When the content of mentioned component (E) is below the above-mentioned upper limit, the storage stability of hair mousse composition becomes more
It is good.
From make hair mousse composition further moderately thickening, further improve hair mousse composition storage stability side
Face considers that hair mousse composition of the invention preferably comprises mentioned component (D) and mentioned component (E).By sharing mentioned component
(D) with mentioned component (E), the dispersion stabilization of mentioned component (A) is further improved, and the separation of hair mousse composition becomes increasingly difficult to
To occur.In addition, hair mousse composition shows good thixotropy, therefore the coating of hair mousse composition is improved.
In the case where sharing mentioned component (D) and mentioned component (E), the quality of mentioned component (D) and mentioned component (E)
Than (the content of mentioned component (D)：The content of mentioned component (E)) it is preferably 1：0.1~1：30th, it is more preferably 1：0.2~1：20、
More preferably 1：0.5~1：10.If meeting above-mentioned mass ratio, the storage stability of hair mousse composition, particularly length
Storage stability when time preserves becomes more preferable.
In the case where sharing mentioned component (D) and mentioned component (E), content and the mentioned component (E) of mentioned component (D)
Content total amount be preferably more than 0.2 mass %, more preferably more than 0.4 mass %, more preferably 0.6 mass % with
On, preferably below 10 mass %, more preferably below 8 mass %, more preferably below 5 mass %.If above-mentioned total
In the range of amount, then the storage stability of hair mousse composition, the storage stability being particularly when preserving for a long time become more preferable.
(other compositions)
The hair mousse composition of the present invention is not particularly limited, water is preferably comprised.As long as institute in above-mentioned water cosmetics
Water is just not particularly limited, preferably pure water.In the mass % of hair mousse composition 100 of the present invention, the content of water is excellent
Elect as more than 30 mass %, more preferably more than 40 mass %, preferably below 95 mass %, more preferably 90 mass % with
Under.
In addition, to the present invention hair mousse composition be not particularly limited, preferably comprise carbon number for 2~5 it is rudimentary
Alcohol (particularly ethanol).In the mass % of hair mousse composition 100 of the present invention, the content of lower alcohol (particularly ethanol) is preferred
For more than 2 mass %, more preferably more than 5 mass %, more preferably preferably below 50 mass %, below 30 mass %.
, can also be in the range of the effect of the present invention not be suppressed comprising for example for the hair mousse composition of the present invention
The surfactants such as nonionic surfactant, cationic surfactant and amphoteric surfactant；Glycerine, 1,3- fourths two
The polyalcohols such as alcohol, propane diols, 1,2- butanediols, 1,2- pentanediols, 1,2- hexylene glycols, 1,2- ethohexadiols, Decane-1,2-diol；Bay
The height that the carbon numbers such as alcohol, myristyl alcohol, hexadecanol, stearyl alcohol, isooctadecanol, cetostearyl alcohol and oily enol are 12~18
Level alcohol；The sugar alcohols such as D-sorbite, maltitol and trehalose；Silicone oil；Chelating agent；Antioxidant；Plant extracts；Pigment；Face
Material；PH adjusting agent；Spices；Preservative；Solvent etc..
(other details of hair mousse composition)
Character to the hair mousse composition of the present invention is not particularly limited, and can be liquid, gel, paste and solid
Any of shape.Above-mentioned hair mousse composition is preferably liquid or gel.In general, in liquid or gelatinous haircut
If using particle in agent composition, the mobility of hair mousse composition is high, therefore the tendency of the dispersiveness reduction with particle.
As a result, in above-mentioned liquid or gelatinous hair mousse composition, be easily reduced with power of haircuting at initial stage and confining force of haircuting,
Easily produce tendency that is tacky and peeling off.On the other hand, by using the above-mentioned composition in the hair mousse composition of the present invention, i.e.,
It is liquid or gelatinous hair mousse composition, the generation and tacky peeled off can also be suppressed, and it is whole to improve initial stage
Have an effect and haircut confining force.
25 DEG C of viscosity of above-mentioned hair mousse composition be preferably more than 1000mPas, more preferably 2000mPas with
On, preferably below 100000mPas, more preferably below 50000mPas.Above-mentioned viscosity is more than above-mentioned lower limit and upper
When stating below the upper limit, coating is further improved, so the generation peeled off and it is tacky be further inhibited, and initial stage haircuts
Power and confining force of haircuting further are improved.In above-mentioned hair mousse composition, above-mentioned viscosity is below the above-mentioned upper limit, even if mobility
Height, can also suppress the generation and tacky peeled off, and can improve power of haircuting at initial stage and confining force of haircuting.
Above-mentioned viscosity is with rotary speed 12rpm, the rotational time condition of 1 minute using viscosimeter, using No.4 rotors
Determined.As above-mentioned viscosimeter, the TV-22 type viscosimeters that Dong Ji industries society can be used to manufacture.
Manufacture method to the hair mousse composition of the present invention is not particularly limited, and is used as the hair mousse composition of the present invention
Manufacture method, the manufacture method of known hair mousse composition can be used.It is used as the system of the hair mousse composition of the present invention
Method is made, is not particularly limited, for example, can enumerate following methods：By composition (A) and water (also having composition (E) as needed) profit
After being stirred with dispersing mixer, it is replaced with arm mixer and stirs while mixture other compositions and homogenizing.
The hair mousse composition of the present invention comprises at least composition (A) and composition (B) as main composition of haircuting.Merely with
Can be produced during composition (B) it is tacky, on the other hand, by sharing composition (A) and composition (B), can suppress it is tacky while carry
It is high just haircut after power of haircuting at initial stage, and confining force of haircuting can be improved.In addition, by using in the composition that 25 DEG C are liquid
I.e. composition (B), can suppress to peel off the generation of (seeming to be attached with the phenomenon of white powder or overlay film on hair) when haircuting.
Thus, if using the hair mousse composition of the present invention, can not only haircut well, and the state for extended periods haircuted can be made
Continue well.
In addition, by compounding ingredients (C), the inhibition of power of haircuting and peeling is further improved, so to haircuting after
Hair assign gloss effect and washing away property improve.
In addition, by compounding ingredients (D) and composition (E), hair mousse composition is moderately thickened, the painting of hair mousse composition
Cloth is improved.In addition, being specific preferred scope by making the mix ratio of composition (D) and composition (E), composition (A) becomes to be difficult to
Sedimentation is assembled, and the storage stability (stability during long-term preservation) of hair mousse composition is improved.
The hair mousse composition of the present invention is not particularly limited, for example, can be used with the form being filled in container.
As said vesse, bottle container, can container and tubular container etc. can be enumerated.Said vesse is preferably bottle container or pipe
Container.
(embodiment)
Below, embodiment and comparative example is enumerated the present invention is specifically described.The present invention is not limited only to following reality
Apply example.
Following compositions have been used in embodiment and comparative example.
(composition (A))
Trade name " Sylysia 320 "：Silica, the manufacture of Fuji Silysia Chemical societies
Trade name " AEROSIL 200 "：Silica, the manufacture of NIPPON AEROSIL societies
Trade name " spherical HAP "：Hydroxyapatite (peaceful Chemical Industries society manufacture)
Trade name " FLORITE R "：Calcium silicates (manufacture of Fu Tian pharmacy society)
Trade name " synthetic aluminium silicate (heavy) "：Alumina silicate (manufacture of Fu Tian pharmacy society)
Trade name " magnesium hydroxide (heavy) "：Magnesium hydroxide (manufacture of Fu Tian pharmacy society)
(composition (B))
Trade name " Newpol 75H-90000 "：Polyoxyethylene diethanol amine fatty acid ester ether, chemical conversion industry society of Sanyo manufacture,
Number-average molecular weight 14000, liquid
Trade name " Newpol SP-750 "：Polyoxypropylene D-sorbite, the manufacture of chemical conversion industry society of Sanyo, number-average molecular weight
690th, liquid
Trade name " Newpol 50HB-55 "：Polyoxyethylene polyoxypropylene butyl ether, the manufacture of chemical conversion industry society of Sanyo, number are divided equally
Son amount 300, liquid
(composition (C))
Trade name " Noigen GIS-125 "：Isostearic acid polyoxyethylene glyceride, the manufacture of the first industrial pharmaceutical society
Trade name " MACBIOBRIDE MG-10P "：PP 25, the manufacture of You societies
(composition (D))
Trade name " Aculyn 22 "：Alkyl acrylate alkyl methacrylate methacrylic acid polyoxyethylene
Stearyl ether (20E.O.) copolymer emulsion, the manufacture of DOW Chemical society, the 30 mass % aqueous solution
Trade name " Aculyn 28 "：Alkyl acrylate alkyl methacrylate methacrylic acid polyoxyethylene
Docosyl ether (25E.O.) copolymer emulsion, the manufacture of DOW Chemical society, the 20 mass % aqueous solution
Trade name " Aculyn 33A "：Alkyl acrylate copolymer emulsion, the manufacture of DOW Chemical society, 28 mass % are water-soluble
Liquid
Trade name " Aculyn 38 "：Alkyl acrylate vinyl neodecanoate cross-linked polymer, DOW Chemical society system
Make, the 29 mass % aqueous solution
(composition (D '))
Trade name " ECHO GUM T "：Xanthans, the manufacture of big SUMITOMO CHEMICAL pharmacy society
(composition (E))
Trade name " LAPONITE XL21 "：Fluosilicic acid (sodium/magnesium), the manufacture of Rockwood societies
Trade name " LAPONITE XLG "：Synthetic silicic acid (sodium/magnesium), the manufacture of Rockwood societies
(embodiment 1~44 and comparative example 1~13)
Compounding ingredients (mixture unit is quality %) shown in mixture table 1 below~8, prepare hair mousse composition.Implement
The character of the hair mousse composition obtained in example 1~44 is gel.It should be noted that the blend amount in table is with actual mixed
Dosage (blend amounts of commodity) is represented.
Resulting hair mousse composition is filled to plastic container, hair mousse is obtained.
(test example 1：Tacky evaluation)
Above-mentioned hair mousse composition is equably applied to wig (exercise manikin by 20 professional judging panels：YUKARI
Japan societies manufacture) hair on, along wig shape from front to back combing hair to implement to haircut, afterwards answer whether there is hair
It is viscous.According to above-mentioned answer, evaluated according to following benchmark tacky.
<Tacky metewand>
Zero (fairly good)：Answered in 20 without tacky for more than 16
△ (good)：Answered in 20 without tacky for 10~15
× (bad)：Answered in 20 without tacky for less than 9
(test example 2：Initial stage power of haircuting evaluation)
Above-mentioned hair mousse composition is equably applied to wig (exercise manikin by 20 professional judging panels：YUKARI
Japan societies manufacture) hair on, along wig shape from front to back combing hair to implement to haircut, afterwards answer whether there is just
Phase power of haircuting.It should be noted that when the shape of the hair arranged is substantially kept, being evaluated as with power of haircuting at initial stage.Root
According to above-mentioned answer, power of haircuting at initial stage is evaluated according to following benchmark.
<Initial stage power of haircuting metewand>
Zero (fairly good)：More than 16 answers have power of haircuting at initial stage in 20
△ (good)：10~15 answers have power of haircuting at initial stage in 20
× (bad)：Less than 9 answers have power of haircuting at initial stage in 20
(test example 3：Haircut the evaluation of confining force)
20 professional judging panels haircuted after above-mentioned test example 2 evaluation of power of haircuting (initial stage) after 6 hours to implementing
The hair of wig observed, answer whether there is confining force of haircuting.It should be noted that after being haircuted of test example 2
In the case that hair shape is by lasting holding, it is determined as that there is confining force of haircuting.According to above-mentioned answer, according to following benchmark to whole
Hair confining force is evaluated.
<Haircut the metewand of confining force>
Zero (fairly good)：Answered in 20 with confining force of haircuting for more than 16
△ (good)：Answered in 20 with confining force of haircuting for 10~15
× (bad)：Answered in 20 with confining force of haircuting for less than 9
(test example 4：The evaluation of peeling)
20 professional judging panels after above-mentioned test example 3 (evaluation for confining force of haircuting) with finger tip by the hair of wig from hair
Continuous 5 combing in root to the tip is sent out, answer whether there is peeling.It should be noted that seeming to be attached with the feelings of white powder on hair
Under condition, it is determined as there is peeling.According to above-mentioned answer, peeling is evaluated according to following benchmark.
<The metewand of peeling>
Zero (fairly good)：No peeling is answered in 20 for more than 16
△ (good)：Answered in 20 without peeling for 10~15
× (bad)：Answered in 20 without peeling for less than 9
(test example 5：The evaluation of washing away property)
20 professional judging panels use shampoo (trade name " LUCIDO afterwards in above-mentioned test example 4 (evaluation of peeling)
Shampoo ", the manufacture of Man Dan societies) with the hair of warm water cleaning wig, it is dried afterwards, whether good answers washing away property.Need
Illustrate, in the case that hair during hair washing is without rough sense and sticky feeling, be evaluated as washing away property good.According to above-mentioned answer, press
Washing away property is evaluated according to following benchmark.
<The metewand of washing away property>
Zero (fairly good)：More than 16 washing away property of answer are good in 20
△ (good)：10~15 washing away property of answer are good in 20
× (bad)：Less than 9 washing away property of answer are good in 20
(test example 6：The evaluation of gloss)
The hair that 20 professional judging panels answer wig after above-mentioned test example 2 evaluation of power of haircuting (initial stage) has unglazed
Pool.According to above-mentioned answer, gloss is evaluated according to following benchmark.
<The metewand of the gloss of hair>
Zero (fairly good)：Answer glossy for more than 16 in 20
△ (good)：10~15 answers are glossy in 20
× (bad)：Answer glossy for less than 9 in 20
Show the result in following tables 1~8.Each embodiment of table 1~8 and adding up to for the compounding ingredients in each comparative example
100 mass %.
[table 1]
[table 2]
[table 3]
[table 4]
[table 5]
[table 6]
[table 7]
[table 8]
Claims (3)
1. a kind of hair mousse composition, it includes following compositions A, following compositions B and following compositions E,
The content of the composition A is below the mass % of more than 0.1 mass % 10,
The content of the composition B is below the mass % of more than 3 mass % 40,
Composition A：Selected from by silica, calcium carbonate, magnesium carbonate, hydroxyapatite, titanium dioxide, zinc oxide, calcium silicates, silicic acid
Particle in the group of magnesium, alumina silicate and magnesium hydroxide composition；
Composition B：Selected from by being polyoxyethylene/polyoxy third that liquid and number-average molecular weight are less than more than 10,000 20000 at 25 DEG C
Alkene copolymer and be that the polyoxypropylene D-sorbite that liquid and number-average molecular weight are less than more than 300 1000 is constituted at 25 DEG C
Compound in group；
Composition E：Clay mineral.
2. hair mousse composition as claimed in claim 1, it further includes following compositions C,
Composition C：Compound in the group being made up of polyoxyalkylene alkyl glucoside and polyoxyalkylene fatty acid glyceride.
3. hair mousse composition as claimed in claim 1 or 2, it is further comprised as selected from by following compositions D1, following
The composition of components D 2 and the polymer in the group of following D ' compositions,
Components D 1：Using two or more in the group being made up of (methyl) acrylic acid and (methyl) alkyl acrylate
Monomer is used as polymer obtained from necessary monomer component；
Components D 2：Use the monomer in the group being made up of (methyl) acrylic acid and (methyl) alkyl acrylate and choosing
Freely in the group of (methyl) acrylic acid polyoxyethylene alkyl ether, itaconic acid polyoxyethylene alkyl ether and vinyl neodecanoate composition
Monomer be used as polymer obtained from necessary monomer component；
D’：Polysaccharide based compound.
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| Application Number | Priority Date | Filing Date | Title |
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| JP2013073966 | 2013-03-29 | ||
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| JP2013-073966 | 2013-03-29 | ||
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| JP2013163394 | 2013-08-06 | ||
| JP2013-163394 | 2013-08-06 | ||
| JP2013163393 | 2013-08-06 | ||
| JP2013-163393 | 2013-08-06 | ||
| PCT/JP2014/058985 WO2014157563A1 (en) | 2013-03-29 | 2014-03-27 | Hair styling agent composition |
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| CN105025867B true CN105025867B (en) | 2017-08-04 |
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| CN201480010908.9A Active CN105025867B (en) | 2013-03-29 | 2014-03-27 | Hair mousse composition |
| CN201480011124.8A Expired - Fee Related CN105007887B (en) | 2013-03-29 | 2014-03-27 | Hair mousse composition |
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| JP (2) | JP6092365B2 (en) |
| KR (2) | KR101789397B1 (en) |
| CN (2) | CN105025867B (en) |
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| JP6150714B2 (en) * | 2013-11-19 | 2017-06-21 | 株式会社マンダム | Emulsion hair styling composition |
| JP6192502B2 (en) * | 2013-11-19 | 2017-09-06 | 株式会社マンダム | Emulsion hair styling composition |
| CN105792803A (en) * | 2014-03-28 | 2016-07-20 | 株式会社漫丹 | Hair styling product composition |
| KR101851166B1 (en) * | 2014-05-16 | 2018-04-24 | 가부시키가이샤 만다무 | Hair styling composition |
| JP6628487B2 (en) * | 2015-03-31 | 2020-01-08 | 株式会社マンダム | Hair styling composition |
| JP7045130B2 (en) * | 2015-12-15 | 2022-03-31 | 株式会社ミルボン | Hair treatment agent, hair treatment method |
| JP6723772B2 (en) * | 2016-03-10 | 2020-07-15 | ジャパンコーティングレジン株式会社 | Hairdressing composition |
| JP6723771B2 (en) * | 2016-03-10 | 2020-07-15 | ジャパンコーティングレジン株式会社 | Acrylic resin emulsion for hairdressing agent and method for producing the same, and hairdressing agent and method for producing the same |
| JP6679169B2 (en) * | 2016-05-20 | 2020-04-15 | 株式会社マンダム | Hairdressing composition |
| JP6662547B2 (en) * | 2016-05-20 | 2020-03-11 | 株式会社マンダム | Hairdressing composition |
| CN109890353B (en) | 2016-11-08 | 2022-05-31 | 株式会社资生堂 | Cosmetic composition |
| JP6784834B2 (en) * | 2017-04-27 | 2020-11-11 | 株式会社マンダム | Hair styling composition |
| JP7178684B2 (en) * | 2018-02-23 | 2022-11-28 | ホーユー株式会社 | hair styling composition |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA1155992A (en) * | 1979-09-17 | 1983-10-25 | Jean Dupre | Thickening agent for aqueous compositions |
| JP2000204025A (en) * | 1999-01-11 | 2000-07-25 | Kose Corp | Foamy hair-dressing preparation |
| JP2000256139A (en) * | 1999-03-10 | 2000-09-19 | Kose Corp | Hair cosmetic |
| JP2002220315A (en) * | 2001-01-24 | 2002-08-09 | Shiseido Co Ltd | Gel type composition |
| JP2002275039A (en) * | 2001-03-21 | 2002-09-25 | Nonogawa Shoji Kk | Hair dressing composition |
| JP2003342130A (en) * | 2002-05-30 | 2003-12-03 | Shiseido Co Ltd | Hair cosmetic |
| JP4532814B2 (en) * | 2002-08-06 | 2010-08-25 | 花王株式会社 | Hair cosmetics |
| JP4709965B2 (en) * | 2003-09-11 | 2011-06-29 | 株式会社アリミノ | Aqueous hair conditioner |
| JP2007320872A (en) * | 2006-05-31 | 2007-12-13 | Mandom Corp | Hair cosmetic product |
| CN101500532B (en) * | 2006-08-16 | 2014-12-10 | 荷兰联合利华有限公司 | Hair treatment composition |
| JP5574621B2 (en) * | 2009-05-21 | 2014-08-20 | 株式会社マンダム | Hairdressing cosmetics |
| JP5328032B2 (en) * | 2009-08-12 | 2013-10-30 | 株式会社マンダム | Cleaning composition |
| WO2011025025A1 (en) * | 2009-08-31 | 2011-03-03 | 株式会社資生堂 | Cosmetic preparation for hair styling |
| US20130164246A1 (en) * | 2010-06-25 | 2013-06-27 | Shiseido Company, Ltd. | Hair Styling Cosmetic Composition |
| JP5823114B2 (en) * | 2010-11-11 | 2015-11-25 | 株式会社マンダム | Gel hair styling composition |
| JP5794776B2 (en) * | 2010-12-15 | 2015-10-14 | 株式会社マンダム | Foam hair conditioner |
| JP5837330B2 (en) * | 2011-05-23 | 2015-12-24 | 株式会社マンダム | Viscous composition |
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| WO2014157564A1 (en) | 2014-10-02 |
| KR20150103233A (en) | 2015-09-09 |
| KR101789397B1 (en) | 2017-10-23 |
| JPWO2014157564A1 (en) | 2017-02-16 |
| KR101763501B1 (en) | 2017-07-31 |
| CN105007887A (en) | 2015-10-28 |
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| JPWO2014157563A1 (en) | 2017-02-16 |
| JP6013587B2 (en) | 2016-10-25 |
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