CN106102695B - Hair styling agent composition - Google Patents

Hair styling agent composition Download PDF

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Publication number
CN106102695B
CN106102695B CN201580012525.XA CN201580012525A CN106102695B CN 106102695 B CN106102695 B CN 106102695B CN 201580012525 A CN201580012525 A CN 201580012525A CN 106102695 B CN106102695 B CN 106102695B
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Prior art keywords
ingredient
mentioned
hair
mass
haircuting
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CN106102695A (en
Inventor
冈本将典
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Mandom Corp
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Mandom Corp
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    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/0241—Containing particulates characterized by their shape and/or structure
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/25—Silicon; Compounds thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/26—Aluminium; Compounds thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/27—Zinc; Compounds thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/29—Titanium; Compounds thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • A61K8/8158—Homopolymers or copolymers of amides or imides, e.g. (meth) acrylamide; Compositions of derivatives of such polymers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/86—Polyethers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring

Abstract

The present invention provides a kind of hair styling agent composition, can inhibit the generation and tacky peeled off when being haircuted, and the initial stage power of haircuting for moulding hair style and the retentivity of haircuting after moulding can be improved.Hair styling agent composition of the invention includes ingredient A, ingredient B and ingredient C with specific content, and ingredient A is the particle in the group being made of silica, calcium carbonate, magnesium carbonate, hydroxyapatite, titanium dioxide, zinc oxide, calcium silicates, magnesium silicate, alumina silicate and magnesium hydroxide；Ingredient B is selected from being 10000 or more 20000 polyoxyethylene/polyoxypropylene random copolymers below by number-average molecular weight and number-average molecular weight is the compound in group that 300 or more 1000 polyoxypropylene D-sorbites below form；Ingredient C is to use Diacetone Acrylamide as acrylic acid series copolymer obtained from necessary monomer component.

Description

Hair styling agent composition
Technical field
The present invention relates to the hair styling agent compositions suitable for the hair styling agent arranged to hair.
Background technique
In order to arrange hair, the hair styling agent composition of the various characters such as liquid, gel, paste and solid-like is used.With It is past, in order to assign the power of haircuting as major function to hair styling agent composition, use polymer and forms polymer more.It is covered having used Film is formed in the hair styling agent composition of polymer, after haircuting, is formed and is covered on the surface of hair from polymer and forms polymer Film.Therefore, if mixed polymer and forms polymer is as ingredient of mainly haircuting, the initial stage power of haircuting after just haircuting is improved, but another When on the one hand being difficult to arrange hair with natural state, or being stimulated with hand or comb etc. hair after haircuting, cover Film can have the problems such as appearance variation from the sur-face peeling (generating so-called peeling) of hair.
Therefore, the method different from the method for polymer and forms polymer is used is studied, specifically, having studied Power of haircuting is assigned to hair styling agent composition using powder.
The following patent document 1 discloses a kind of hair cosmetic composition (hair styling agent composition), it includes 0.1 mass %~ The specific surface area of 10 mass % is 50m2The fine-particle powder of/g or more.Following the description is described in patent document 1: by with spy Fixed above-mentioned content can be obtained good sense of touch, excellent power of haircuting can be obtained, and can using specific above-mentioned fine-particle powder So that good sense of touch is long lasting for and can be obtained excellent haircuting property again.It is described in following in patent document 1 Hold: as power of haircuting, mildly hair can be arranged in such a way that hair is by hand or comb.
Existing technical literature
Patent document
Patent document 1: Japanese Unexamined Patent Publication 2003-342130 bulletin
Summary of the invention
Subject to be solved by the invention
But as recorded in patent document 1, haircut using the hair styling agent composition comprising fine-particle powder When, it can also peel off sometimes.Additionally, there are the statuses for requiring superior initial stage power of haircuting and retentivity of haircuting.
In addition, about power of haircuting, including mildly haircuting to what hair was arranged in such a way that hair is by hand or comb Power and hair is made to erect or mould the power of haircuting etc. of hair style, power of haircuting includes several species.It describes down in patent document 1 It states content: as power of haircuting, mildly hair can be arranged in such a way that hair is by hand or comb.In patent document 1 The power of haircuting of record is different with the power of haircuting for making hair erect or mould hair style.
The purpose of the present invention is to provide a kind of hair styling agent compositions, can inhibit the generation peeled off when being haircuted With it is tacky, and the initial stage power of haircuting for moulding hair style and the retentivity of haircuting after moulding can be improved.
Solution for solving the problem
Hair styling agent composition of the invention includes following compositions (A), following compositions (B) and following compositions (C), the ingredient (A) content is 0.05 mass % or more, 7.0 mass % hereinafter, the content of the ingredient (B) is 3.0 mass % or more, 35.0 matter % is measured hereinafter, the content of the ingredient (C) is 0.10 mass % or more, 3.0 mass % or less.
Ingredient (A): selected from by silica, calcium carbonate, magnesium carbonate, hydroxyapatite, titanium dioxide, zinc oxide, silicic acid The particle in group that calcium, magnesium silicate, alumina silicate and magnesium hydroxide form.
Ingredient (B): selected from randomly total for 10000 or more 20000 polyoxyethylene/polyoxypropylenes below by number-average molecular weight Polymers and number-average molecular weight are the compound in the group of 300 or more 1000 polyoxypropylene D-sorbite compositions below.
Ingredient (C): use Diacetone Acrylamide as acrylic acid series copolymer obtained from necessary monomer component.
Hair styling agent composition of the invention preferably further includes following compositions (D).
Ingredient (D): the change in the group being made of polyoxyalkylene alkyl glucoside and polyoxyalkylene fatty acid glyceride Close object.
Hair styling agent composition of the invention preferably further includes following compositions (E).
Ingredient (E): clay mineral.
Hair styling agent composition of the invention preferably further includes following compositions (F).
Ingredient (F): polysaccharide based compound.
In hair styling agent composition of the invention, the mass ratio of the content and the content of the ingredient (F) of the ingredient (E) is excellent It is selected as 2:1~10:1.
The effect of invention
Hair styling agent composition of the invention includes specific ingredient (A), specific ingredient (B) and specific ingredient (C), into And each content of ingredient (A), ingredient (B) and ingredient (C) is in a specific range, therefore can inhibit the hair of peeling when haircuting It is raw and tacky, and the initial stage power of haircuting for moulding hair style and the retentivity of haircuting after moulding can be improved.
Specific embodiment
Hereinafter, the present invention will be described in detail.
Hair styling agent composition of the invention includes at least: selected from by silica, calcium carbonate, magnesium carbonate, hydroxyapatite, The particle in group that titanium dioxide, zinc oxide, calcium silicates, magnesium silicate, alumina silicate and magnesium hydroxide form；Selected from by the equal molecule of number Amount is 10000 or more 20000 polyoxyethylene/polyoxypropylene random copolymers below and number-average molecular weight is 300 or more 1000 Compound in the group of polyoxypropylene D-sorbite composition below；And use Diacetone Acrylamide as necessary monomer at Acrylic acid series copolymer obtained from point.
In this specification, sometimes by above-mentioned " selected from by silica, calcium carbonate, magnesium carbonate, hydroxyapatite, titanium dioxide The particle in group that titanium, zinc oxide, calcium silicates, magnesium silicate, alumina silicate and magnesium hydroxide form " is known as " ingredient (A) ".In addition, Sometimes by it is above-mentioned " selected from by number-average molecular weight be 10000 or more 20000 polyoxyethylene/polyoxypropylene random copolymers below, It is the compound in the group of 300 or more 1000 polyoxypropylene D-sorbite compositions below with number-average molecular weight " it is known as " ingredient (B)".In addition, sometimes by it is above-mentioned " number-average molecular weight be 10000 or more 20000 polyoxyethylene/polyoxypropylenes below randomly altogether Polymers " is known as " ingredient (B1) ", sometimes by above-mentioned " number-average molecular weight is 300 or more 1000 polyoxypropylene D-sorbites below " Referred to as " ingredient (B2) ".In addition, " using Diacetone Acrylamide as propylene obtained from necessary monomer component for above-mentioned sometimes Sour based copolymer " is known as " ingredient (C) ".
Hair styling agent composition of the invention preferably further includes selected from by polyoxyalkylene alkyl glucoside and polyoxyalkylene Compound in the group of fatty acid glyceride composition.
In this specification, sometimes by above-mentioned " selected from by polyoxyalkylene alkyl glucoside and polyoxyalkylene fatty acid glyceride Compound in the group of composition " is known as " ingredient (D) ".In addition, above-mentioned " polyoxyalkylene alkyl glucoside " is known as " ingredient sometimes (D1) " above-mentioned " polyoxyalkylene fatty acid glyceride ", is known as " ingredient (D2) " sometimes.
Hair styling agent composition of the invention preferably further includes clay mineral.In this specification, sometimes by above-mentioned " clay Mineral " are known as " ingredient (E) ".
Hair styling agent composition of the invention preferably further includes polysaccharide based compound.It, sometimes will be above-mentioned in this specification " polysaccharide based compound " is known as " ingredient (F) ".
Hair styling agent composition of the invention includes at least ingredient (A), ingredient (B) and ingredient (C).Hair styling agent group of the invention Close object preferably further include select free component (D), ingredient (E) and ingredient (F) composition group in ingredient (at least one at Point).Using ingredient (E), preferably ingredient (E) and ingredient (F) are shared.Wherein, hair styling agent of the invention combination Object preferably comprises whole components (A), ingredient (B), ingredient (C), ingredient (D), ingredient (E) and ingredient (F).Hair styling agent of the invention Composition can further include other ingredients.Mentioned component may be used alone or in combination of two or more respectively.
It should be noted that mentioned component (B) is the compound in the group for selecting free component (B1) and ingredient (B2) to form (at least one compound).In addition, mentioned component (D) is the compound in the group for selecting free component (D1) and ingredient (D2) to form (at least one compound).Above-mentioned ingredient (B1), ingredient (B2), ingredient (D1), ingredient (D2) can be used only a kind respectively, Also two or more can be used.
Hereinafter, being illustrated to the details of each ingredient used in hair styling agent composition of the invention.
(ingredient (A))
Mentioned component (A) be selected from by silica, calcium carbonate, magnesium carbonate, hydroxyapatite, titanium dioxide, zinc oxide, The particle (at least one particle) in group that calcium silicates, magnesium silicate, alumina silicate and magnesium hydroxide form.Mentioned component (A) is main Have the function of inhibiting tacky, improve the initial stage power of haircuting for moulding hair style and the retentivity of haircuting after moulding.In addition, by using Mentioned component (A) is easy to haircut again after once haircuting, can also improve haircuting property again.It should be noted that above-mentioned Ingredient (A) preferably except with the particle in addition to ingredient (E) comparable ingredient.
As mentioned component (A), in above-mentioned particle, examined in terms of the performance of haircuting that hair style is moulded in further improvement Consider, is preferably selected from and is made of silica, magnesium carbonate, hydroxyapatite, calcium silicates, magnesium silicate, alumina silicate and magnesium hydroxide Particle (at least one particle) in group, being more preferably selected from the group being made of silica, magnesium silicate and magnesium hydroxide Grain (at least one particle).Mentioned component (A) may be used alone or in combination of two or more.
<silica>
As above-mentioned silica, known usual silica (silicic acid anhydride) can be used.Above-mentioned silica can be with For the silicic acid anhydride (hydrophilic silica) without silicic acid anhydride, or hydrophobization silicic acid anhydride.In addition, above-mentioned dioxy SiClx may be the silica being surface-treated with amino acid, ester or lecithin etc..In addition, above-mentioned silica It can be so-called easy disintegrating silica dioxide granule.Above-mentioned silica may be used alone or in combination of two or more.
Above-mentioned hydrophobization silicic acid anhydride is to have carried out the substance of silicic acid anhydride to silicic acid anhydride (such as untreated silicic acid anhydride). As inorganic agent used in silicic acid anhydride, Organosilyl compound and silicone compounds etc. can be enumerated.As upper Organosilyl compound is stated, methyl trichlorosilane, dimethyldichlorosilane, trim,ethylchlorosilane, hexamethyl can be enumerated Disilazane, methyl trialkoxysilane, dimethyldialkylammonium oxysilane, trimethylalkyoxys iotalane, ethyl trichlorosilane, third Base trichlorosilane, hexyl trichlorosilane, chain alkyl trichlorosilane, ethyltrialkoxysilanes, propyl trialkoxy silane, oneself Base trialkoxy silane, chain alkyl trialkoxy silane, methacryl silanes, fluoroalkyl silanes and perfluoroalkyl silanes Deng.As above-mentioned silicone compounds, it is poly- that dimethyl polysiloxane (silicone oil), methyl phenyl silicone, methyl hydrogen can be enumerated Siloxanes and amino modified silicone etc..As the method for above-mentioned silicic acid anhydride, well known method can be used.It is dredged as above-mentioned The method of hydration process can enumerate liquid phase method, vapor phase method and autoclave method etc..
As the preference of above-mentioned hydrophobization silicic acid anhydride, dimethyl silane oxygroup SiClx acid anhydrides, trimethyl can be enumerated Siloxy SiClx acid anhydrides, octyl siloxy SiClx acid anhydrides, silicone oil processes silicic acid anhydride and methacrylic acid monosilane oxygen Base SiClx acid anhydrides etc..
Above-mentioned easy disintegrating silica dioxide granule is multiple silica primary particle set and the particle formed.As upper Silica primary particle is stated, is not particularly limited, for example, spherical silica particles, flakey silica Grain and amorphous silica particles etc..The average grain diameter of above-mentioned silica primary particle is not particularly limited.
In addition, above-mentioned easy disintegrating silica dioxide granule can include the ingredient other than silica.As above-mentioned dioxy Ingredient (hereinafter sometimes referred to " component content ") other than SiClx, is not particularly limited, for example, surfactant, more First alcohol, higher alcohol, sugar alcohol, silicone oil, chelating agent, antioxidant, plant extracts, pigment, pigment, fragrance, moisturizer, vitamin Class, amino acids and freshener etc..Wherein, preferred amino acid class, silicone oil, vitamins.As above-mentioned amino acids, without spy Do not limit, can enumerate two (lauramide glutamine) lysine Na (such as Asahi Chemical Corp manufacture, commodity Name " pellicer "), trimethylglycine and glutamic acid etc..By including above-mentioned easy disintegrating silica dioxide granule in above-mentioned Containing ingredient, component content is released if the disintegration of above-mentioned easy disintegrating silica dioxide granule when haircuting, can play and include The corresponding effect of the type of ingredient.For example, hair can be played by above-mentioned easy disintegrating silica dioxide granule embedded amine groups acids The damage nursing function of hair.
It as the manufacturing method of above-mentioned easy disintegrating silica dioxide granule, is not particularly limited, well known side can be used Method.
The oil absorption of above-mentioned silica is preferably 100mL/100g or more, more preferably 150mL/100g or more, into one Step is preferably 200mL/100g or more, preferably 1000mL/100g or less, is more preferably 800mL/100g or less, is further excellent It is selected as 700mL/100g or less.When the oil absorption of above-mentioned silica is above-mentioned lower limit or more and the above-mentioned upper limit or less, hair is moulded The retentivity and haircuting property becomes more preferable again of haircuting of the initial stage power of haircuting of type, the hair of institute's moulding.Above-mentioned oil absorption is according to JIS The method recorded in K5101 is measured.
As the commercially available product of above-mentioned silica, for example, the Fuji Silysia as silicic acid anhydride Chemical society manufacture trade name " Sylysia 320 ", trade name " Sylysia 310P ", trade name " Sylysia 250 ", Trade name " Sylysia 250N ", trade name " Sylysia 350 ", trade name " Sylysia 370 ", trade name " Sylysia 380 ", trade name " Sylysia 420 ", trade name " Sylysia 430 ", trade name " Sylysia 440 ", trade name " Sylysia 450 " and trade name " Sylysia 470 "；The trade name that NIPPON AEROSIL society as silicic acid anhydride manufactures " AEROSIL50 ", trade name " AEROSIL 90G ", trade name " AEROSIL 130 ", trade name " AEROSIL 150 ", commodity Name " AEROSIL 200 ", trade name " AEROSIL 300 ", trade name " AEROSIL 380 ", trade name " AEROSIL 200V " With trade name " AEROSIL OX50 "；The trade name " Sunsphere H-31 " of AGC Si-Tech society manufacture as silicic acid anhydride, Trade name " Sunsphere H-51 ", trade name " Sunsphere H-121 ", trade name " Sunsphere H-201 ", trade name " Sunsphere H-32 ", trade name " Sunsphere H-52 ", trade name " Sunsphere H-122 ", trade name " Sunsphere H-33 " and trade name " Sunsphere H-53 "；NIPPON as dimethyl silane oxygroup SiClx acid anhydrides Trade name " AEROSIL R972 ", trade name " AEROSIL R974 " and the trade name " AEROSIL of AEROSIL society manufacture R9200"；Trade name " the AEROSIL that NIPPON AEROSIL society as trimethylsiloxy SiClx acid anhydrides manufactures RX200 ", trade name " AEROSIL R8200 ", trade name " AEROSIL RX300 " and trade name " AEROSIL R812S "；Make The trade name " AEROSIL R805 " manufactured for the NIPPON AEROSIL society of octyl siloxy SiClx acid anhydrides；As silicone oil Handle silicic acid anhydride NIPPON AEROSIL society manufacture trade name " AEROSIL R202 ", trade name " AEROSIL RY200 ", Trade name " AEROSIL RY200S " and trade name " AEROSIL RY300 "；As methacrylic acid siloxy SiClx acid The trade name " AEROSIL R711 " of the NIPPON AEROSIL society manufacture of acid anhydride；Three as Shang Shu Yang disintegration silica are good It is melted into the trade name " silica beads SB-705 " of society's manufacture；Suzuki grease society as Shang Shu Yang disintegration silica manufactures Trade name " God Ball SF-16C ", trade name " God Ball AF-6C " and trade name " God Ball AF-16C " etc..
<calcium carbonate>
Above-mentioned calcium carbonate is for example indicated with INCI " CALCIUM CARBONATE ".Above-mentioned calcium carbonate can be used only 1 Kind, two or more also can be used.As the commercially available product of above-mentioned calcium carbonate, for example, the quotient of Sakai chemical industry corporation manufacture The name of an article " Calmaru SCS M5 "；The trade name " FUWACAL " etc. of shiraishi calcium society manufacture.
<magnesium carbonate>
Above-mentioned magnesium carbonate is for example indicated with INCI " MAGNESIUM CARBONATE ".Above-mentioned magnesium carbonate can be used only 1 Kind, two or more also can be used.As the commercially available product of above-mentioned magnesium carbonate, for example, the commodity of Fu Tian pharmacy society manufacture Name " light magnesium carbonate " etc..
<hydroxyapatite>
Above-mentioned hydroxyapatite is for example indicated with INCI " HYDROXYAPATITE ".Above-mentioned hydroxyapatite can only make With a kind, two or more also can be used.
It as above-mentioned hydroxyapatite, is not particularly limited, for example, the hydroxyl of spherical hydroxyapatite, sheet Base apatite and amorphous hydroxyapatite etc..Wherein, it haircuts from the aspect of performance from playing the height for moulding hair style, It is preferred that spherical hydroxyapatite.As the commercially available product of above-mentioned hydroxyapatite, for example, peaceful Chemical Industries society system Trade name " sheet HAP ", trade name " spherical HAP ", trade name " HAP-100 ", trade name " HAP-200 " and the trade name made " HAP-300 " etc..
<titanium dioxide>
Above-mentioned titanium dioxide is for example indicated with INCI " TITANIUM DIOXIDE ".It is not special to above-mentioned titanium dioxide It limits, such as can be fine particulate titanium dioxide, or pigment titanium.Above-mentioned titanium dioxide can be used only a kind, can also make Use two or more.As the commercially available product of above-mentioned titanium dioxide, for example, stone originates in the trade name " TTO-55 of industry society manufacture And trade name " CR-50 " etc. (A) ".
<zinc oxide>
Above-mentioned zinc oxide is for example indicated with INCI " ZINC OXIDE ".Above-mentioned zinc oxide can be used only a kind, can also be with Use two or more.As the commercially available product of above-mentioned zinc oxide, for example, the trade name of Sakai chemical industry corporation manufacture " FINEX-30S-LP2 " etc..
<calcium silicates>
Above-mentioned calcium silicates is for example indicated with INCI " CALCIUM SILICATE ".Above-mentioned calcium silicates can be used only a kind, Also two or more can be used.As the commercially available product of above-mentioned calcium silicates, for example, the trade name of Fu Tian pharmacy society manufacture "FLORITE R"；The trade name " eakleite powder X-ray J " and trade name " snow of JAPAN INSULATION CO., LTD. manufacture Silico-calcium stone powder TK " etc..
<magnesium silicate>
Above-mentioned magnesium silicate is for example indicated with INCI " MAGNESIUM SILICATE ".Above-mentioned magnesium silicate can be used only 1 Kind, two or more also can be used.As the commercially available product of above-mentioned magnesium silicate, for example, the commodity of Fu Tian pharmacy society manufacture Name " magnesium silicate (lightweight) " etc..
<alumina silicate>
Above-mentioned alumina silicate is for example indicated with INCI " ALUMINUM SILICATE ".Above-mentioned alumina silicate can be used only 1 Kind, two or more also can be used.It as alumina silicate, is not particularly limited, preferably synthetic alumina silicate.As synthetic method, such as It can enumerate: Na being added into alum2SiO3And the method that precipitating generated is dry；It is molten that silicic acid is made by electroosmose process Glue, the method for thus generating gel；And the method that the aqueous solution of aluminium salt is added into waterglass；Etc..As above-mentioned silicic acid The commercially available product of aluminium, for example, the trade name " synthetic aluminium silicate (heavy) " of Fu Tian pharmacy society manufacture and trade name " synthesis Alumina silicate (lightweight) " etc..
<magnesium hydroxide>
Above-mentioned magnesium hydroxide is for example indicated with INCI " MAGNESIUM HYDROXIDE ".Above-mentioned magnesium hydroxide can be only Using a kind, two or more also can be used.As the commercially available product of above-mentioned magnesium hydroxide, for example, Fu Tian pharmacy society manufactures Trade name " magnesium hydroxide (heavy) " etc..
In 100 mass % of hair styling agent composition of the invention, the content of mentioned component (A) be 0.05 mass % or more, Preferably 0.07 mass % or more, more preferably 0.10 mass % or more, be 7.0 mass % or less, preferably 5.0 mass % with Under, more preferably 4.0 mass % or less.It is above-mentioned lower limit or more by the content of mentioned component (A), can be further improved modeling The initial stage power of haircuting of hair style is made, and can be further improved the retentivity of haircuting after moulding, and then hair can be further suppressed It is viscous.Content by mentioned component (A) is the above-mentioned upper limit hereinafter, preventing the effect peeled off, the effect for assigning gloss and washing away property It further increases.The content of mentioned component (A) is the total of the content of the whole components (A) in hair styling agent composition of the invention Amount.
(ingredient (B))
Mentioned component (B) is selected from least one of the group being made of mentioned component (B1) and mentioned component (B2) chemical combination Object.Mentioned component (B) mainly has the function of effectively improving the retentivity of haircuting after moulding.In addition, by using mentioned component (B), it can inhibit to peel off, play said effect.In addition, can be imparted luster to the hair by using mentioned component (B). Mentioned component (B) may be used alone or in combination of two or more.It should be noted that mentioned component (B1), mentioned component (B2) it also may be used alone or in combination of two or more respectively.
As mentioned component (B), any one in mentioned component (B1) and mentioned component (B2) can be used only, it can also To share mentioned component (B1) and mentioned component (B2).Wherein, can further inhibit from while retentivity is haircuted in raising Tacky aspect is set out, preferred component (B2).
Mentioned component (B1) is polyoxyethylene/polyoxypropylene random copolymer.That is, mentioned component (B1) is at least to have 2 The copolymer of a above ethylene oxide unit (ethylene oxide unit) and 2 or more propylene oxide unit (propylene oxide unit). Copolymerization mode in mentioned component (B1) is the mode of random copolymer.
The average addition molal quantity of ethylene oxide in mentioned component (B1) is not particularly limited, and preferably 100 or more, more Preferably 200 or more, preferably 400 or less, 350 or less are more preferably.To being averaged for the propylene oxide in mentioned component (B1) Addition molal quantity is not particularly limited, preferably 30 or more, particularly preferably 40 or more, preferably 150 or less, particularly preferably 100 or less.
In terms of peeling off from inhibition, the coating easiness of hair styling agent, gloss aspect, mentioned component are assigned to hair (B1) preferably 25 DEG C be liquid.
The number-average molecular weight of mentioned component (B1) is 10000 or more 20000 or less.The number-average molecular weight of mentioned component (B1) When less than above-mentioned lower limit, the initial stage power of haircuting of hair style is moulded and retentivity reduction of haircuting.The number-average molecular weight of mentioned component (B1) When more than the above-mentioned upper limit, treatability is deteriorated.The number-average molecular weight of mentioned component (B1) is preferably 12000 or more.Mentioned component (B1) number-average molecular weight is preferably 18000 or less.
Mentioned component (B2) is polyoxypropylene D-sorbite.It rubs to the average addition of the propylene oxide in mentioned component (B2) You are not particularly limited number, and preferably 4 or more, more preferably 8 or more, preferably 15 or less, more preferably 12 or less.
In terms of peeling off from inhibition, the coating easiness of hair styling agent, gloss aspect, mentioned component are assigned to hair (B2) preferably 25 DEG C be liquid.
The number-average molecular weight of mentioned component (B2) is 300 or more 1000 or less.The number-average molecular weight of mentioned component (B2) is small When above-mentioned lower limit, the initial stage power of haircuting of hair style is moulded and retentivity reduction of haircuting.The number-average molecular weight of mentioned component (B2) is super When crossing the above-mentioned upper limit, tacky, treatability variation is generated.The number-average molecular weight of mentioned component (B2) is preferably 400 or more.It is above-mentioned at The number-average molecular weight for dividing (B2) is preferably 800 or less.
Mentioned component (B) is preferably liquid at 25 DEG C.Mentioned component (B) preferably has mobility at 25 DEG C, such as preferably With following characters: 50g sample is fitted into the vial of radius 2cm, height 7cm, 25 DEG C at a temperature of by above-mentioned glass When bottle is reverse, sample slides from vial when 5 minutes after overturning.
As the commercially available product of mentioned component (B1), for example, the trade name of chemical conversion industry society, Sanyo manufacture " Newpol 75H-90000 " etc..
As the commercially available product of mentioned component (B2), for example, the trade name of chemical conversion industry society, Sanyo manufacture " Newpol SP-750 " and trade name " Sannix SP-750 " etc..
In 100 mass % of hair styling agent composition of the invention, the content of mentioned component (B) is 3.0 mass % or more, excellent Be selected as 5.0 mass % or more, more preferably 8.0 mass % or more, be 35.0 mass % or less, preferably 30.0 mass % with Under, more preferably 23.0 mass % or less.When the content of mentioned component (B) is above-mentioned lower limit or more, the initial stage for moulding hair style is whole Having an effect becomes more preferably with the retentivity of haircuting after moulding, can further assign hair better gloss.Mentioned component (B's) contains Amount be the above-mentioned upper limit below when, tacky inhibitory effect, coating when ductility and amalgamation become more preferable.Mentioned component (B) Content be hair styling agent composition of the invention in whole components (B) content total amount.
In hair styling agent composition of the invention, the mass ratio of the content of the content and mentioned component (B) of mentioned component (A) (content of mentioned component (A): the content of mentioned component (B)) is preferably 1:0.1~1:30, more preferably 1:1~1:20, into one Step is preferably 1:3~1:20.When the content of mentioned component (A) is relatively more, the initial stage power of haircuting and tacky suppression of hair style are moulded Effect processed becomes more preferable.When the content of mentioned component (B) is relatively more, the gloss of haircut retentivity and hair after moulding becomes More preferably.
(ingredient (C))
Mentioned component (C) is to use Diacetone Acrylamide as acrylic copolymer obtained from necessary monomer component Object.Mentioned component (C) can further use other monomers other than Diacetone Acrylamide together with Diacetone Acrylamide Ingredient obtains as monomer component.Other monomer component conducts can be enumerated selected from by (methyl) acryllic acid and (first Base) acrylic acid acid esters composition group in monomer (at least one monomer) etc..Mentioned component (C), which mainly effectively improves, to be moulded The effect of the initial stage power of haircuting of hair style.In particular, being used together mentioned component (C) with mentioned component (A) and mentioned component (B) When, greatly contribute to the state for erecting it while arranging to hair and keeping erected hair.Mentioned component (C) it may be used alone or in combination of two or more.
Monomer component for obtaining mentioned component (C) includes at least Diacetone Acrylamide.For obtaining mentioned component (C) monomer component preferably further includes in the group being made of (methyl) acryllic acid and (methyl) acrylic acid acid esters Monomer (at least one monomer).That is, mentioned component (C) is the copolymerization including at least the structural unit from Diacetone Acrylamide Object.Mentioned component (C) is preferably further comprising selected from by the structural unit from (methyl) acryllic acid and from (methyl) third Structural unit in the group of the structural unit composition of olefin(e) acid acid esters.
As the concrete example of mentioned component (C), for example, with INCI (international cosmetic raw material dictionary and handbooks (International Cosmetic Ingredient Dictionary and Handbook), the 15th edition, volume 1,2014 Year, page 66): acrylic acid (ester) class/diacetone acrylamide that ACRYLATES/DIACETONEACRYLAMIDE COPOLYMER is indicated Amide copolymer etc..
Acrylic acid series copolymer as above-mentioned (C) ingredient can be sodium salt, ammonium salt, triethanolamine salt, 2- amino -2- first Base -1- propylate or 2- amino-2-methyl -1,3- propylene glycol salt etc..
The concrete example of copolymer as the form with mentioned component (C) comparable salt, for example, as 2- ammonia Base-2- methyl-1-propylate with INCI (international cosmetic raw material dictionary and handbook, the 15th edition, volume 1,2014,212 Page): acrylic acid (ester) class/diacetone acrylamide that AMP-ACRYLATES/DIACETONEACRYLAMIDE COPOLYMER is indicated Amide AMP salt (acrylic acid (ester) class/biacetone acrylamide copolymer AMP salt)；As 2- amino-2-methyl -1,3- the third two Alkoxide with INCI (international cosmetic raw material dictionary and handbooks, the 15th edition, volume 1,2014, page 214): AMPD- Acrylic acid (ester) class/biacetone acrylamide copolymer that ACRYLATES/DIACETONEACRYLAMIDECOPOLYMER is indicated AMPD salt etc..
As the commercially available product of mentioned component (C), for example, total as acrylic acid (ester) class/Diacetone Acrylamide The trade name " Plascize L-53 " of the mutual induction chemical industry corporation manufacture of polymers；As acrylic acid (ester) class/diacetone acrylamide acyl The trade name of the mutual induction chemical industry corporation manufacture of amine AMP salt (acrylic acid (ester) class/biacetone acrylamide copolymer AMP salt) “Plascize L-3200B”、“Plascize L-6010”、“Plascize L-6330”、“Plascize L-7400B”、 "Plascize L-9400B","Plascize L-9909"；As acrylic acid (ester) class/biacetone acrylamide copolymer The trade name " Plascize L-1260 " of the mutual induction chemical industry corporation manufacture of AMPD salt, " Plascize L-53D " etc..
In 100 mass % of hair styling agent composition of the invention, the content of mentioned component (C) be 0.10 mass % or more, Preferably 0.30 mass % or more, more preferably 0.40 mass % or more, be 3.0 mass % or less, preferably 2.0 mass % with Under, more preferably 1.8 mass % or less.When the content of mentioned component (C) is above-mentioned lower limit or more, the initial stage for moulding hair style haircuts Power becomes more preferable.Content by mentioned component (C) is the above-mentioned upper limit hereinafter, haircuting property becomes the effect for more preferably preventing from peeling off again Fruit, washing away property further increase.The content of mentioned component (C) is the whole components (C) in hair styling agent composition of the invention The total amount of content.
In hair styling agent composition of the invention, the mass ratio of the content of the content and mentioned component (C) of mentioned component (B) (content of mentioned component (B): the content of mentioned component (C)) is preferably 5:1~70:1, more preferably 6:1~60:1.It is above-mentioned at When dividing the content of (B) relatively more, the gloss of retentivity of haircuting, the effect for preventing peeling, washing away property and hair after moulding becomes It obtains more preferably.When the content of mentioned component (C) is relatively more, moulds the initial stage power of haircuting of hair style and tacky effect is inhibited to become more It is good.
(ingredient (D))
Mentioned component (D) is selected from least one of the group being made of mentioned component (D1) and mentioned component (D2) chemical combination Object.By using mentioned component (D), peeling can be further suppressed, and the washing away property after haircuting can be improved, and can be with Good feel is assigned to the hair after haircuting while maintaining to mould the initial stage power of haircuting of hair style.Mentioned component (D) can be with Using only a kind, two or more also can be used.It should be noted that mentioned component (D1), mentioned component (D2) also respectively can be with Using only a kind, two or more can also be used.
As mentioned component (D), any one in mentioned component (D1) and mentioned component (D2) can be used only, it can also Mentioned component (D1) and mentioned component (D2) to be shared.
Mentioned component (D1) is polyoxyalkylene alkyl glucoside.It, can be with as the oxyalkylene alkyl in mentioned component (D1) Enumerate oxyethylene group and oxypropylene group etc..Do not have to the average addition molal quantity of the oxyalkylene alkyl in mentioned component (D1) It is particularly limited to, preferably 5 or more, preferably 40 or less.The carbon atom number of alkyl in mentioned component (D1) is preferably 1~4, more Preferably 1~3.Alkyl in mentioned component (D1) is preferably methyl or ethyl.
It as mentioned component (D1), is not particularly limited, Glucam E-10, polyoxyethylene ethyl can be enumerated Glucoside, PP 25 and polyoxypropylene ethyl cyclophosphadenosine glycoside etc..
Better feel is assigned to the hair after haircuting from while maintaining to mould the initial stage power of haircuting of hair style higher From the aspect of, mentioned component (D1) preferably comprises polyoxyalkylene methyl glucosamine, preferably comprises PP 25.
Mentioned component (D2) is polyoxyalkylene fatty acid glyceride.The carbon atom number of fatty acid in mentioned component (D2) is excellent It is selected as 8 or more, preferably 22 or less.As the oxyalkylene alkyl in mentioned component (D2), oxyethylene group and oxygen can be enumerated Change acrylic etc..The average addition molal quantity of oxyalkylene alkyl in mentioned component (D2) is preferably 5 or more, preferably 40 with Under.
In terms of assigning better feel to the hair after haircuting while maintaining and moulding the initial stage power of haircuting of hair style Consider, the fatty acid in mentioned component (D2) is preferably branched chain fatty acid, and mentioned component (D2) is preferably polyoxyalkylene glycerol branch Chain fatty acid ester.
Better feel is assigned to the hair after haircuting from while maintaining to mould the initial stage power of haircuting of hair style higher From the aspect of, the carbon atom number of the branched chain fatty acid in above-mentioned polyoxyalkylene glycerol side chain fatty acid ester is preferably 8 or more, excellent It is selected as 22 or less.As the branched chain fatty acid in above-mentioned polyoxyalkylene glycerol side chain fatty acid ester, can enumerate 2 ethyl hexanoic acid, Isononanoic acid, different palmitinic acid and isostearic acid etc..
As above-mentioned polyoxyalkylene glycerol side chain fatty acid ester, particularly preferred isostearic acid polyoxyethylene glyceride.
As the commercially available product of mentioned component (D1), for example, the trade name " MACBIOBRIDE of You society manufacture MG-10P"；The trade name " GLUCAM E-10 " and trade name " GLUCAM E-20 " of Noveon society manufacture；The manufacture of Amerchol society Trade name " GLUCAM P-10 " etc..
As the commercially available product of mentioned component (D2), for example, the trade name of the first industrial pharmaceutical society manufacture "Noigen GIS-125"；The trade name " EMALEX GWIS-115 " of NIHON EMULSION society manufacture, trade name " EMALEX GWIS-120 ", trade name " EMALEX GWIS-125 " and trade name " EMALEXGWIS-130 " etc..
In 100 mass % of hair styling agent composition of the invention, the content of mentioned component (D) be preferably 0.5 mass % with Upper, more preferably 1.0 mass % or more, preferably 20.0 mass % or less, more preferably 10.0 mass % or less.Mentioned component (D) when content is above-mentioned lower limit or more, peeling can be further suppressed, and the washing away property after haircuting becomes more preferably, and can To assign better feel to the hair after haircuting.It is tacky further when the content of mentioned component (D) is the above-mentioned upper limit or less Mitigate.The content of mentioned component (D) is the total amount of the content of the whole components (D) in hair styling agent composition of the invention.
In above-mentioned hair styling agent composition, the mass ratio of the content and the content of mentioned component (D) of mentioned component (A) is (above-mentioned The content of ingredient (A): the content of mentioned component (D)) it is preferably 1:0.2~1:20, more preferably 1:1~1:10.If it is above-mentioned at The content of point (D) is relatively more, then the feel of hair, peel off inhibitory effect, washing away property becomes more preferable.
(ingredient (E))
Mentioned component (E) is clay mineral.By using mentioned component (E), moulds the initial stage power of haircuting of hair style and haircut The storage stability of agent composition becomes more preferable.Mentioned component (E) may be used alone or in combination of two or more.
Mentioned component (E) can be natural goods, or synthetic.As mentioned component (E), it is not particularly limited, For example, kaolin group's clay mineral, antigorite race clay mineral, pyrophyllite race clay mineral, Mica Group clay pit Object, smectite clay mineral, vermiculite race clay mineral, chlorite race clay mineral and organo-clay mineral etc..
As above-mentioned kaolin group's clay mineral, kaolin, nacrite, dickite and halloysite etc. can be enumerated.Make For above-mentioned antigorite race clay mineral, antigorite, pictoamesite and cronstedtite etc. can be enumerated.As above-mentioned pyrophyllite race Clay mineral can enumerate pyrophyllite and talcum (talcum) etc..As above-mentioned Mica Group clay mineral, can enumerate illite, Glauconite, seladonit, sericite, mica (mica), muscovite, fuchsite and biotite etc..It is viscous as above-mentioned smectite race Native mineral can enumerate bentonite, montmorillonite, beidellite, nontronite, saponite, hectorite (Hectorite) and synthesis lithium and cover De- stone (Lucentite) etc..As above-mentioned vermiculite race clay mineral, vermiculite etc. can be enumerated.As above-mentioned chlorite race clay Mineral can enumerate chlorite (chlorite) etc..As above-mentioned organo-clay mineral, smectite clay can be enumerated Mineral or vermiculite race clay mineral etc. have carried out organo-clay mineral of organically-modified processing etc..It is fitted in organically-modified processing Preferably use quaternary ammonium salt cationic surfactant.As above-mentioned quaternary ammonium salt cationic surfactant, can enumerate above-mentioned Alkyl trimethyl ammonium chloride, dialkyl dimethyl ammonium chloride and benzalkonium chloride etc..
From the aspect of further improvement storage stability and use feeling, mentioned component (E) is preferably selected from by synthesizing Clay mineral in the group of silicate and its derivative composition.Above-mentioned synthetic silicate and its derivative are not containing many The silicate minerals as main component such as the natural magnesium silicate or silicic acid (sodium/magnesium) of impurity, but obtained by synthesis Silicate and silicate derivative.
As above-mentioned synthetic silicate and its derivative, for example, with INCI (international cosmetic raw material dictionaries And handbook, the 14th edition, volume 2,2012, page 3076): what SODIUM MAGNESIUM SILICATE (sodium magnesium silicate) was indicated Synthetic silicic acid (sodium/magnesium), with INCI (international cosmetic raw material dictionary and handbook, the 14th edition, volume 2,2012,1793 Page): MAGNESIUM FLUOROSILICATE (magnesium fluosilicate) indicate magnesium fluosilicate, with INCI (international cosmetic raw materials Dictionary and handbook, the 14th edition, volume 2,2012, page 3076): SODIUMMAGNESIUM FLUOROSILICATE (fluosilicic acid Magnesium sodium) indicate fluosilicic acid (sodium/magnesium), with INCI (international cosmetic raw material dictionary and handbook, the 14th edition, volume 2,2012 Year, page 1799): the fluosilicic acid (magnesium/potassium) of MAGNESIUMPOTASSIUM FLUOROSILICATE (potassium fluosilicate magnesium) expression, With INCI (international cosmetic raw material dictionary and handbooks, the 14th edition, volume 2,2012, page 1800): MAGNESIUM SODIUMFLUOROSILICATE (prodan magnesium) indicate fluosilicic acid (magnesium/sodium), with INCI (international cosmetic raw material words Allusion quotation and handbook, the 14th edition, volume 1,2012, page 156): the synthetic aluminium silicate that ALUMINUM SILICATE (alumina silicate) is indicated Deng.
As mentioned component (E), in clay mineral, particularly preferably selected from by synthetic silicic acid (sodium/magnesium), fluosilicic acid (sodium/ Magnesium) and fluosilicic acid (sodium/magnesium) composition group in clay mineral (at least one clay mineral).
As the commercially available product of mentioned component (E), for example, the trade name " synthetic soapstone of Rockwood society manufacture XLG " and trade name " synthetic soapstone XL21 " etc..
In 100 mass % of hair styling agent composition of the invention, the content of mentioned component (E) be preferably 0.10 mass % with Upper, more preferably 0.30 mass % or more, further preferably 0.50 mass % or more, preferably 10.0 mass % or less, more Preferably 5.0 mass % or less, further preferably 3.0 mass % or less.The content of mentioned component (E) is above-mentioned lower limit or more When, storage stability and haircuting property become more preferable.When the content of mentioned component (E) is the above-mentioned upper limit or less, hair styling agent composition Storage stability become more preferable.
(ingredient (F))
Mentioned component (F) is polysaccharide based compound.By using mentioned component (F), hair styling agent composition is moderately thickened, because The dispersibility of this mentioned component (A) becomes more preferably, and then hair styling agent composition becomes difficult to separate, and storage stability becomes more It is good.Mentioned component (F) may be used alone or in combination of two or more.
It as mentioned component (F), is not particularly limited, preferred polysaccharide, modification of polysaccharides (such as alkyl-modified polysaccharide etc.) etc., For example, alginic acid, carragheen, agar, furcellaran, guar gum, Wen Quince seed, konjac glucomannan, tamarind gum, tower Draw glue, dextrin, starch, locust bean gum, Arabic gum, ghatti gum, Karaya Gum, bassora gum, arabogalactan, pectin The polysaccharide based compound of the plant origins such as He Wen Quince；The polysaccharide based compound of the animal origins such as chitosan and hyaluronic acid；It can obtain The microbe-derived polysaccharide system chemical combination such as right glue, xanthan gum, gellan gum, cyclodextrin, dextran, amylopectin and hyaluronic acid Object；Microcrystalline cellulose, methylcellulose, ethyl cellulose, hydroxymethyl cellulose, hydroxyethyl cellulose, hydroxypropyl cellulose and The non-ionic celluloses such as hydroxypropyl methyl cellulose element；The anionic celluloses such as carboxymethyl cellulose element；Chlorination O- [2- hydroxyl- 3- (trimethyl ammonium) propyl] cationized celluloses such as hydroxyethyl cellulose；Chlorination O- [2- hydroxyl -3- (trimethyl ammonium) Propyl] the cationized guars glue such as guar gum etc..
As mentioned component (F), in polysaccharide based compound, be preferably selected from by xanthan gum, guar gum, tamarind gum and Compound (at least one compound) in the group of gellan gum composition.
As the commercially available product of mentioned component (F), for example, the big SUMITOMO CHEMICAL pharmacy society as xanthan gum manufactures Trade name " ECHO GUM T ", trade name " ケ Le デ Application ト " and trade name " モ ナ ー ト ガ system "；As guar gum she The trade name " Inagel guar gum CS " of that food industry society manufacture；DSPGOKYO FOOD& as tamarind gum The trade name " GLYLOID 6C " of CHEMICAL Co., Ltd. manufacture；CP Kelco U.S., Inc. manufacture as gellan gum Trade name " Kelcogel " etc..
In 100 mass % of hair styling agent composition of the invention, the content of mentioned component (F) be preferably 0.01 mass % with Upper, more preferably 0.10 mass % or more, preferably 5.0 mass % or less, more preferably 2.0 mass % or less.Mentioned component (F) when content is above-mentioned lower limit or more, the storage stability of hair styling agent composition becomes more preferable.The content of mentioned component (F) It is tacky to be suppressed more when for below the above-mentioned upper limit.The content of mentioned component (F) is in hair styling agent composition of the invention The total amount of the content of whole components (F).
From make hair styling agent composition further moderately thicken, further increase hair styling agent composition storage stability side Face considers that hair styling agent composition of the invention preferably comprises mentioned component (E) and mentioned component (F).By sharing mentioned component (E) it is further increased with mentioned component (F), the dispersion stabilization of mentioned component (A), the separation of hair styling agent composition becomes increasingly difficult to To occur.In addition, hair styling agent composition shows good thixotropy, therefore the coating of hair styling agent composition improves.
In the case where sharing mentioned component (E) and mentioned component (F), the quality of mentioned component (E) and mentioned component (F) It is preferably 2:1~10:1, more preferably 2.5:1~8:1 than (content of mentioned component (E): the content of mentioned component (F)).If Meet above-mentioned mass ratio, then it is tacky to be suppressed more, and then the storage stability of hair styling agent composition, particularly long-time are protected Storage stability when depositing becomes more preferable.
In the case where sharing mentioned component (E) and mentioned component (F), the content and mentioned component (F) of mentioned component (E) Content total amount be preferably 0.30 mass % or more, more preferably 0.40 mass % or more, preferably 5.0 mass % or less, More preferably 4.0 mass % or less.If it is tacky to be suppressed more in the range of above-mentioned total amount, and then hair styling agent combines The storage stability when storage stability of object, particularly for a long time preservation becomes more preferable.
(other ingredients)
Hair styling agent composition of the invention is not particularly limited, water is preferably comprised.Above-mentioned water is not particularly limited, can be with Use the preferred pure water such as water used in cosmetic preparation etc..In 100 mass % of hair styling agent composition of the invention, the content of water Preferably 30 mass % or more, more preferably 40 mass % or more, preferably 95 mass % or less, more preferably 90 mass % with Under.
In addition, hair styling agent composition of the invention is not particularly limited, preferably comprise carbon atom number be 2~5 it is rudimentary Alcohol (especially ethyl alcohol).In 100 mass % of hair styling agent composition of the invention, the content of lower alcohol (especially ethyl alcohol) is preferred For 2.0 mass % or more, more preferably 5.0 mass % or more, preferably 50.0 mass % or less, more preferably 30.0 mass % Below.
For hair styling agent composition of the invention, can also in the range of not inhibiting effect of the invention including, for example, The surfactants such as nonionic surfactant, cationic surfactant and amphoteric surfactant；Glycerol, 1,3- fourth two The polyalcohols such as alcohol, propylene glycol, 1,2- butanediol, 1,2- pentanediol, 1,2- hexylene glycol, 1,2- ethohexadiol, Decane-1,2-diol；Laurel The height that the carbon atom numbers such as the pure and mild oily enol of alcohol, myristyl alcohol, hexadecanol, stearyl alcohol, isooctadecanol, cetearyl alcohol are 12~18 Grade alcohol；The sugar alcohols such as D-sorbite, maltitol and trehalose；Silicone oil；Chelating agent；Antioxidant；Plant extracts；Pigment；Face Material；PH adjusting agent；Fragrance；Preservative；Solvent etc..
(other details of hair styling agent composition)
The character of hair styling agent composition of the invention is not particularly limited, can be liquid, gel, paste and solid Any one of shape.Above-mentioned hair styling agent composition is preferably liquid or gel.In general, it in liquid or gelatinous haircuts If using particle in agent composition, the mobility of hair styling agent composition is high, therefore the tendency that the dispersibility with particle reduces. As a result, in above-mentioned liquid or gelatinous hair styling agent composition, after there is the initial stage power of haircuting and moulding for moulding hair style Retentivity of haircuting is easily reduced, is easy to produce tendency that is tacky and peeling off.In contrast, by using hair styling agent group of the invention Close the above-mentioned composition in object, even liquid or gelatinous hair styling agent composition can also inhibit the generation peeled off and tacky, And the initial stage power of haircuting for moulding hair style and the retentivity of haircuting after moulding can be improved.
25 DEG C of viscosity of above-mentioned hair styling agent composition be preferably 1000mPas or more, more preferably 2000mPas with On, preferably 100000mPas or less, more preferably 50000mPas or less.Above-mentioned viscosity is more than above-mentioned lower limit and upper When stating the upper limit or less, coating is further increased, so the generation peeled off and it is tacky be further inhibited, and mould hair style Initial stage power of haircuting and moulding after retentivity of haircuting further increase.In above-mentioned hair styling agent composition, above-mentioned viscosity is above-mentioned The upper limit hereinafter, even if mobility is high, can also inhibit the generation peeled off and tacky, and can be improved mould hair style initial stage it is whole It has an effect and the retentivity of haircuting after moulding.
Above-mentioned viscosity be using viscosimeter, using No.4 rotor with 1 minute rotation speed 12rpm, rotational time condition It is measured.As above-mentioned viscosimeter, the TV-22 type viscosimeter of Dong Ji industry society manufacture can be used.
The manufacturing method of hair styling agent composition of the invention is not particularly limited, as hair styling agent composition of the invention Manufacturing method, the manufacturing method of well known hair styling agent composition can be used.System as hair styling agent composition of the invention Method is made, for example, following methods: (there are also ingredient (E)) to utilize dispersing mixer as needed by ingredient (A) and water After stirring, it is replaced with arm mixer and Hun Peis while stirring and other ingredients and homogenize.
In the case where hair styling agent composition of the invention, the generation and tacky peeled off can be inhibited when being haircuted, And the initial stage power of haircuting for moulding hair style and the retentivity of haircuting after moulding can be improved.
It should be noted that above-mentioned " moulding hair style " is not particularly limited in this specification, e.g. hair is instigated to erect Deng relatively hard place combing hair.
Hair styling agent composition of the invention includes at least ingredient (A), ingredient (B) and ingredient (C) and haircuts into as main Point.For mentioned component (B), do up and keep the excellent effect of hair, though after haircuting by long-time the case where Under, also it is able to suppress that topknot scatters, the hair style of institute's moulding is destroyed.In addition, it is also excellent to restrain the effect peeled off.On the other hand, For ingredient (C), the excellent effect of hardness is assigned to hair, such as the power for erecting hair is excellent.In addition, for ingredient (A) for, while having the effect of the above-mentioned effect for doing up and keeping hair and hardness is assigned to hair, and have and inhibit hair It glues, inhibit unnatural gloss and assign the effect of natural appearance.
Therefore, by sharing ingredient (A), ingredient (B) and ingredient (C), tacky and unnatural gloss can inhibited The initial stage power of haircuting for moulding hair style is improved simultaneously, and the retentivity of haircuting after moulding can be improved.Especially it is possible to arrange head Hair erects it well, and can keep the hair for arranging and erecting well.In addition, can press down when being haircuted System peels off the generation of (seeming the phenomenon that white powder or overlay film are attached on hair).
In addition, the inhibitory effect of power of haircuting and peeling is further increased by compounding ingredients (D), so to haircuting after Hair assign gloss effect and washing away property improve.
In addition, moderately being thickened by compounding ingredients (E) and ingredient (F), hair styling agent composition, the painting of hair styling agent composition Cloth improves.In addition, the specific preferred scope of mix ratio by making ingredient (E) Yu ingredient (F), ingredient (A) become difficult to The storage stability (stability when long-term preservation) of sedimentation or aggregation, hair styling agent composition improves.
Hair styling agent composition of the invention is not particularly limited, such as can be used in the form of being filled in container.
As said vesse, bottle container, can container and tubular container etc. can be enumerated.Said vesse is preferably bottle container or pipe Container.
Embodiment
In the following, enumerating embodiment and comparative example the present invention to be specifically described.The present invention is not limited only to reality below Apply example.
Following compositions have been used in embodiment and comparative example.
(ingredient (A))
Trade name " Sylysia 320 ": silica (manufacture of Fuji Silysia Chemical society)
Trade name " AEROSIL 200 ": silica (manufacture of NIPPON AEROSIL society)
Trade name " spherical HAP ": hydroxyapatite (peaceful Chemical Industries society manufacture)
Trade name " FLORITE R ": calcium silicates (manufacture of Fu Tian pharmacy society)
Trade name " synthetic aluminium silicate (heavy) ": alumina silicate (manufacture of Fu Tian pharmacy society)
Trade name " magnesium hydroxide (heavy) ": magnesium hydroxide (manufacture of Fu Tian pharmacy society)
(ingredient (B))
Trade name " Newpol 75H-90000 ": polyoxyethylene polyoxypropylene hexylene glycol ether, chemical conversion industry society, Sanyo manufacture, Number-average molecular weight 14000, liquid
Trade name " Newpol SP-750 ": polyoxypropylene D-sorbite, the manufacture of chemical conversion industry society, Sanyo, number-average molecular weight 690, liquid
(the polyoxyethylene/polyoxypropylene copolymer (ingredient (B ')) other than ingredient (B)
Trade name " Newpol 50HB-55 ": polyoxyethylene polyoxypropylene butyl ether, the manufacture of chemical conversion industry society, Sanyo, number are divided equally Son amount 300, liquid
(ingredient (C))
Trade name " Plascize L-6330 ", 30 mass % of purity, the manufacture of mutual induction chemical industry corporation
Trade name " Plascize L-53 ", 50 mass % of purity, the manufacture of mutual induction chemical industry corporation
Trade name " Plascize L-53D ", 50 mass % of purity, the manufacture of mutual induction chemical industry corporation
(ingredient (D))
Trade name " Noigen GIS-125 ": isostearic acid polyoxyethylene glyceride, the manufacture of the first industrial pharmaceutical society
Trade name " MACBIOBRIDE MG-10P ": PP 25, the manufacture of You society
(ingredient (E))
Trade name " synthetic soapstone XL21 ": fluosilicic acid (sodium/magnesium), the manufacture of Rockwood society
Trade name " synthetic soapstone XLG ": synthetic silicic acid (sodium/magnesium), the manufacture of Rockwood society
(ingredient (F))
Trade name " ECHO GUM T ": xanthan gum, the manufacture of big SUMITOMO CHEMICAL pharmacy society
(other)
Ethyl alcohol
2-amino-2-methyl-1-propanol
Pure water
(embodiment 1~17 and the Comparative Examples 1 to 5)
Mixed following table 1, compounding ingredients shown in 2 (mixed unit is quality %), prepare hair styling agent composition.Embodiment The character of hair styling agent composition obtained in 1~17 is gel.It should be noted that the blend amount in table is by with purity meter Blend amount indicate.
Obtained hair styling agent composition is filled to plastic container, hair styling agent is obtained.
(test example 1: tacky evaluation)
20 professional judging panels above-mentioned hair styling agent composition is equably applied to bob wig (practice manikin: YUKARI Japan society manufacture) hair on, from the root of hair of hair upwards erect hair with implement haircut, later contact erect Hair, answer whether there is or not tacky.According to above-mentioned answer, evaluate according to following benchmark tacky.
<tacky evaluation criteria>
Zero (fairly good): it is answered without tacky for 16 or more in 20
△ (good): it is answered without tacky for 10~15 in 20
× (bad): it is answered without tacky for 9 or less in 20
(test example 2: the evaluation of initial stage power of haircuting (erecting power))
20 professional judging panels above-mentioned hair styling agent composition is equably applied to bob wig (practice manikin: YUKARI Japan society manufacture) hair on, from the root of hair of hair upwards erect hair with implement haircut, answer later whether there is or not Initial stage power of haircuting.It should be noted that being determined as when the shape of the hair arranged is obviously kept with initial stage power of haircuting. According to above-mentioned answer, initial stage power of haircuting is evaluated according to following benchmark.
<evaluation criteria of initial stage power of haircuting>
Zero (fairly good): 16 or more answers have initial stage power of haircuting in 20
△ (good): 10~15 answers have initial stage power of haircuting in 20
× (bad): 9 or less answers have initial stage power of haircuting in 20
(test example 3: the evaluation for retentivity of haircuting)
20 professional judging panels haircut after 6 hours to implementing after above-mentioned test example 2 (evaluation of initial stage power of haircuting) The hair of wig observed, answer that whether there is or not the retentivities of haircuting after standing.It should be noted that the progress of test example 2 In the case that hair shape after haircuting is by lasting holding, it is determined as that there is retentivity of haircuting.According to above-mentioned answer, according to following Benchmark evaluates retentivity of haircuting.
<evaluation criteria for retentivity of haircuting>
Zero (fairly good): it is answered with retentivity of haircuting for 16 or more in 20
△ (good): it is answered with retentivity of haircuting for 10~15 in 20
× (bad): it is answered with retentivity of haircuting for 9 or less in 20
(test example 4: the evaluation of peeling)
20 professional judging panels after above-mentioned test example 3 (evaluation for retentivity of haircuting) with finger tip by the hair of wig from hair Continuous 5 combing in root to the tip is sent out, answer that whether there is or not peelings.It should be noted that seeming the feelings for being attached with white powder on hair Under condition, it is determined as there is peeling.According to above-mentioned answer, peeling is evaluated according to following benchmark.
<evaluation criteria of peeling>
Zero (fairly good): it is answered without peeling for 16 or more in 20
△ (good): it is answered without peeling for 10~15 in 20
× (bad): it is answered without peeling for 9 or less in 20
(test example 5: the evaluation of washing away property)
20 professional judging panels use shampoo (trade name in above-mentioned test example 4 (evaluation of peeling) afterwards The manufacture of " LUCIDOshampoo ", Man Dan society) with the hair of warm water cleaning wig, it is dried later, whether good answers washing away property It is good.It should be noted that it is good to be evaluated as washing away property in the case that hair when hair washing is without rough sense and sticky feeling.According to above-mentioned It answers, washing away property is evaluated according to following benchmark.
<evaluation criteria of washing away property>
Zero (fairly good): 16 or more washing away property of answer are good in 20
△ (good): 10~15 washing away property of answer are good in 20
× (bad): 9 or less washing away property of answer are good in 20
(test example 6: the evaluation of gloss)
The hair that 20 professional judging panels answer wig after above-mentioned test example 2 (evaluation of initial stage power of haircuting) has unglazed Pool.According to above-mentioned answer, gloss is evaluated according to following benchmark.
<evaluation criteria of the gloss of hair>
Zero (fairly good): in 20 16 or more answer it is glossy
△ (good): 10~15 answers are glossy in 20
× (bad): in 20 9 or less answer it is glossy
(test example 7: the evaluation of storage stability)
Each hair styling agent composition immediately after preparation is filled into transparent glass container, is saved in 40 DEG C of thermostat 4 week.The appearance and character of each hair styling agent composition after preservation are observed, evaluated according to following benchmark.
<evaluation criteria of storage stability (appearance character)>
Zero (quite good): the dehydration of composition and the rising of viscosity are not confirmed
△ (good): the dehydration of composition or the rising of viscosity are slightly confirmed
× (bad): the dehydration of composition or the rising of viscosity are clearly confirmed
Show the result in following tables 1,2.Each embodiment of table 1,2 and adding up to for the compounding ingredients in each comparative example 100 mass %.
[table 1]
[table 2]

Claims (3)

1. a kind of hair styling agent composition, it includes following compositions A, following compositions B, following compositions C, following compositions E and it is following at Divide F,
The content of the ingredient A be 0.05 mass % or more, 7.0 mass % hereinafter,
The content of the ingredient B be 3.0 mass % or more, 35.0 mass % hereinafter,
The content of the ingredient C be 0.10 mass % or more, 3.0 mass % hereinafter,
Ingredient A: selected from by silica, calcium carbonate, magnesium carbonate, hydroxyapatite, titanium dioxide, zinc oxide, calcium silicates, silicic acid Particle in the group of magnesium, alumina silicate and magnesium hydroxide composition,
Ingredient B: selected from by number-average molecular weight be 10000 or more 20000 polyoxyethylene/polyoxypropylene random copolymers below, It is the compound in the group of 300 or more 1000 polyoxypropylene D-sorbite compositions below with number-average molecular weight,
Ingredient C: using Diacetone Acrylamide as acrylic acid series copolymer obtained from necessary monomer component,
Ingredient E: clay mineral,
Ingredient F: polysaccharide based compound.
2. hair styling agent composition as described in claim 1, further includes following compositions D,
Ingredient D: the compound in the group being made of polyoxyalkylene alkyl glucoside and polyoxyalkylene fatty acid glyceride.
3. hair styling agent composition as claimed in claim 1 or 2,
The mass ratio of the content of the ingredient E and the content of the ingredient F is 2:1~10:1.
CN201580012525.XA 2014-05-16 2015-03-12 Hair styling agent composition Expired - Fee Related CN106102695B (en)

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CN109862868A (en) * 2017-03-30 2019-06-07 株式会社漫丹 Hair styling agent composition
JP6784834B2 (en) * 2017-04-27 2020-11-11 株式会社マンダム Hair styling composition
WO2019064851A1 (en) * 2017-09-26 2019-04-04 株式会社マンダム Composition for hair treatment and mist cosmetic for hair treatment
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