KR101851166B1

KR101851166B1 - Hair styling composition

Info

Publication number: KR101851166B1
Application number: KR1020167022002A
Authority: KR
Inventors: 마사노리 오카모토
Original assignee: 가부시키가이샤 만다무
Priority date: 2014-05-16
Filing date: 2015-03-12
Publication date: 2018-04-24
Also published as: KR20160108475A; CN106102695A; JP6243014B2; WO2015174130A1; CN106102695B; JPWO2015174130A1

Abstract

The present invention provides a regular-care composition that can suppress the generation of flaking and tackiness during regular operation, and can increase the initial repulsive force to make the shape of the head and the regular retention force after the shape is formed. The cleaning agent composition according to the present invention comprises particles (component A) selected from the group consisting of silica, calcium carbonate, magnesium carbonate, hydroxyapatite, titanium oxide, zinc oxide, calcium silicate, magnesium silicate, aluminum silicate, (Component B) selected from the group consisting of a polyoxyethylene / polyoxypropylene random copolymer having a number average molecular weight of 10,000 or more and 20,000 or less and a polyoxypropylene sorbit having a number average molecular weight of 300 or more and 1000 or less, (Component (C)) obtained by using diacetone acrylamide as a specific content.

Description

HAIR STYLING COMPOSITION < RTI ID = 0.0 >

The present invention relates to a stabilizer composition suitably used for a hair conditioner to trim hair.

In order to trim hair, various formulations of stabilizer compositions such as liquid, gel, cream and solid formulations are used. Conventionally, a film-forming polymer is often used to impart a repulsive force, which is a main function, to the cleaning agent composition. In the regular-charge developer composition using the film-forming polymer, a film is formed on the surface of the hair from the film-forming polymer after purification. Therefore, when the film-forming polymer is blended as a main component for stabilizing the hair, it is difficult to arrange the hair in a natural state while the initial repulsive force immediately after the hair straightening becomes high, or when stimulation is applied to the hair with a hand or a comb, There is a problem that the film is peeled off from the surface (so-called flaking occurs) and the appearance is deteriorated.

Therefore, a method different from the method using a film-forming polymer has been studied, and specifically, it has been studied to impart a repulsive force to a regular-agent composition using a powder.

Patent Document 1 below discloses a hair cosmetic composition (composition for a regular developer) containing 0.1 to 10% by mass of fine particle powder having a specific surface area of 50 m 2 / g or more. Patent Document 1 discloses that a good feeling can be obtained by using the specific particulate powder at the above specific content, an excellent repulsive force can be obtained, a good feel can be sustained for a long time, and excellent reverberation can be obtained have. Patent Document 1 discloses that it is possible to smoothly arrange the hair so that a hand or a comb passes as a repulsive force.

Japanese Patent Application Laid-Open No. 2003-342130

However, as described in Patent Document 1, flaking may occur even when the composition is stabilized by using a stabilizer composition containing a fine particle powder. Further, there is a phenomenon that a more excellent initial recovery power and a regular holding power are required.

Regarding the repulsive force, there are several kinds of repulsive force, such as a repulsive force to gently arrange the hair so that a hand or a comb passes through it, and a repulsive force to form the shape of a hair by raising a hair. Patent Document 1 discloses that it is possible to smoothly arrange the hair so that a hand or a comb passes as a repulsive force. The repulsive force described in Patent Document 1 is different from the repulsive force for making the shape of the head by raising the hair.

It is an object of the present invention to provide a regular-care composition which can suppress the occurrence of flaking and tackiness during regular motion, and can increase the initial repulsive force for making the shape of the head and the regular retention force after the shape is formed.

The propellant composition according to the present invention comprises the following component (A), the following component (B), and the following component (C), wherein the content of the component (A) is 0.05 mass% or more and 7.0 mass% , The content of the component (B) is not less than 3.0 mass% and not more than 35.0 mass%, and the content of the component (C) is not less than 0.10 mass% and not more than 3.0 mass%.

Component (A): particles selected from the group consisting of silica, calcium carbonate, magnesium carbonate, hydroxyapatite, titanium oxide, zinc oxide, calcium silicate, magnesium silicate, aluminum silicate and magnesium hydroxide

Component (B): a polyoxyethylene / polyoxypropylene random copolymer having a number average molecular weight of 10000 or more and 20,000 or less, and a polyoxypropylene sorbitol having a number average molecular weight of 300 or more and 1000 or less

Component (C): An acrylic copolymer obtained by using diacetone acrylamide as an essential monomer component

The stabilizer composition according to the present invention preferably further comprises the following component (D).

Component (D): a compound selected from the group consisting of a polyoxyalkylene alkyl glucoside, and a polyoxyalkylene glycerin fatty acid ester

The stabilizer composition according to the present invention preferably further comprises the following component (E).

Component (E): Clay mineral

The stabilizer composition according to the present invention preferably further comprises the following component (F).

Component (F): polysaccharide compound

In the charge stabilizer composition according to the present invention, the mass ratio of the content of the component (E) to the content of the component (F) is preferably 2: 1 to 10: 1.

The cleaning agent composition according to the present invention comprises a specific component (A), a specific component (B) and a specific component (C), and further contains components (A), (B) Since the content is within a specific range, it is possible to suppress the occurrence of flaking and tackiness during regular motion, and to improve the initial repulsive force for making the shape of the head and the regular retention force after the shape is formed.

Hereinafter, the present invention will be described in detail.

The tablet composition according to the present invention is a tablet composition comprising particles selected from the group consisting of silica, calcium carbonate, magnesium carbonate, hydroxyapatite, titanium oxide, zinc oxide, calcium silicate, magnesium silicate, aluminum silicate and magnesium hydroxide, A polyoxyethylene / polyoxypropylene random copolymer having a number average molecular weight of 10000 or more and 20,000 or less and a polyoxypropylene sorbit having a number average molecular weight of 300 or more and 1000 or less and a diacetone acrylamide as an essential monomer component Based on the weight of the acrylic copolymer.

In the present specification, "particles selected from the group consisting of silica, calcium carbonate, magnesium carbonate, hydroxyapatite, titanium oxide, zinc oxide, calcium silicate, magnesium silicate, aluminum silicate and magnesium hydroxide" &Quot; The above-mentioned " compound selected from the group consisting of a polyoxyethylene / polyoxypropylene random copolymer having a number average molecular weight of 10,000 or more and 20,000 or less and a polyoxypropylene sorbit having a number average molecular weight of 300 or more and 1000 or less & ) &Quot;. The polyoxyethylene / polyoxypropylene random copolymer having a number average molecular weight of 10000 or more and 20000 or less may be referred to as " component (B1) ", and the term " polyoxy Propylene sorbitol " is sometimes referred to as " component (B2) ". The above-mentioned "acrylic copolymer obtained by using diacetone acrylamide as an essential monomer component" may be referred to as "component (C)".

The orthostructal composition according to the present invention preferably further comprises a compound selected from the group consisting of a polyoxyalkylene alkyl glucoside and a polyoxyalkylene glycerin fatty acid ester.

In the present specification, the " compound selected from the group consisting of polyoxyalkylene alkyl glucoside and polyoxyalkylene glycerin fatty acid ester " is sometimes referred to as " component (D) ". The above "polyoxyalkylene alkyl glucoside" is sometimes referred to as "component (D1)", and the "polyoxyalkylene glycerin fatty acid ester" is sometimes referred to as "component (D2)".

It is preferred that the tablet composition according to the present invention further comprises a clay mineral. In the present specification, the term "clay mineral" is sometimes referred to as "component (E)".

The stabilizer composition according to the present invention preferably further comprises a polysaccharide compound. In the present specification, the "polysaccharide compound" may be referred to as "component (F)".

The tonicity agent composition according to the present invention contains at least the component (A), the component (B) and the component (C). The stabilizer composition according to the present invention preferably further comprises a component (at least one component) selected from the group consisting of component (D), component (E) and component (F). When the component (E) is used, it is preferable to use the component (E) and the component (F) in combination. Among them, the stabilizer composition according to the present invention preferably contains all of the components (A), (B), (C), (D), (E) and (F). The stabilizer composition according to the present invention may further contain other components. (A), the component (B), the component (C), the component (D), the component (E), the component (F) and other components may be used alone , Or two or more of them may be used.

The component (B) is a compound (at least one compound) selected from the group consisting of the component (B1) and the component (B2). The component (D) is a compound (at least one compound) selected from the group consisting of the component (D1) and the component (D2). Each of the above-mentioned components (B1), (B2), (D1) and (D2) may be used alone or two or more thereof may be used.

Hereinafter, the details of each component used in the composition for purification agent according to the present invention will be described.

(Component (A))

The component (A) is particles (at least one particle) selected from the group consisting of silica, calcium carbonate, magnesium carbonate, hydroxyapatite, titanium oxide, zinc oxide, calcium silicate, magnesium silicate, aluminum silicate and magnesium hydroxide . The component (A) has a role of suppressing tackiness and enhancing the initial repulsive force for making the head shape and the regular retention force after the shape is formed. Further, by using the above-mentioned component (A), it is possible to facilitate the regular repetition after the once-outgoing, and to improve the retaliation. The component (A) is preferably particles other than the component corresponding to the component (E).

Among the above-mentioned particles, as the component (A), silica, magnesium carbonate, hydroxyapatite, calcium silicate, magnesium silicate, aluminum silicate, and magnesium hydroxide are preferably used as the component (A) (At least one particle) are preferable, and particles (at least one particle) selected from the group consisting of silica, magnesium silicate, and magnesium hydroxide are more preferable. The component (A) may be used alone or in combination of two or more.

As the silica, known silica (silicic anhydride) can be used. The silica may be anhydrous silicic acid (hydrophilic silica) not subjected to hydrophobic treatment, or may be hydrophobic silicic anhydride. The silica may be silica surface-treated with amino acid, ester, lecithin or the like. The silica may be a so-called disintegrable silica particle. The silica may be used alone or in combination of two or more.

The hydrophobic silicic anhydride is a material obtained by subjecting anhydrous silicic acid (for example, anhydrous silicic anhydride) to hydrophobic treatment. Examples of the treatment agent used in the hydrophobic treatment include an organosilyl compound and a silicone compound. Examples of the organosilyl compound include methyltrichlorosilane, dimethyldichlorosilane, trimethylchlorosilane, hexamethyldisilazane, methyltrialkoxysilane, dimethyldialkoxysilane, trimethylalkoxysilane, ethyltrichlorosilane, propyltrichlorosilane, Hexyl trichlorosilane, long-chain alkyltrichlorosilane, ethyltrialkoxysilane, propyltrialkoxysilane, hexyltrialkoxysilane, long-chain alkyltrialkoxysilane, methacrylsilane, fluoroalkylsilane and perfluoroalkylsilane. have. Examples of the silicone compound include dimethylpolysiloxane (silicone oil), methylphenylpolysiloxane, methylhydrogenpolysiloxane and amino-modified silicone. A known method may be employed as the method of the hydrophobic treatment. Examples of the hydrophobic treatment method include a liquid phase method, a vapor phase method and an autoclave method.

Preferable examples of the hydrophobic silicic anhydride include dimethylsiloxylated silicic anhydride, trimethylsiloxylated silicic anhydride, octylsiloxylated silicic anhydride, silicon oil-treated silicic anhydride and methacrylosiloxylated silicic anhydride.

The bibulous compacted silica particles are particles formed by aggregating a plurality of primary silica particles. Examples of the silica primary particles include, but are not limited to, spherical silica particles, scaly silica particles, and amorphous silica particles. The average particle diameter of the silica primary particles is not particularly limited.

The diblock compacted silica particles may contain components other than silica. Examples of the component other than the silica (hereinafter sometimes referred to as a " contained component ") include, but are not limited to, surfactants, polyhydric alcohols, higher alcohols, sugar alcohols, silicone oils, Antioxidants, plant extracts, dyes, pigments, fragrances, moisturizers, vitamins, amino acids and refreshing agents. Among them, amino acids, silicone oil and vitamins are preferable. Examples of the amino acids include, but are not limited to, dilauroyl glutamate lysine Na (for example, trade name "Pellicer" available from Asahi Chemical Industry Co., Ltd.), trimethylglycine and glutamic acid. When the biodestructured silica particles contain the inclusion component, the inclusion component is released when the biodisolidized silica particles collapse at the time of purification, and an effect depending on the type of inclusion component is exerted. For example, when the biodisolidized silica particles contain amino acids, the damage-care function of the hair is exerted.

The method for producing the bast / compactible silica particles is not particularly limited and a known method can be used.

The oil absorption of the silica is preferably 100 mL / 100 g or more, more preferably 150 mL / 100 g or more, further preferably 200 mL / 100 g or more, preferably 1000 mL / 100 g or less, more preferably 800 mL / Preferably 700 mL / 100 g or less. When the amount of oil absorption of the silica is not less than the lower limit and not more than the upper limit, the initial repulsive force for making the shape of the head, the regular retentive force and the reverberation of the head made of the shape are further improved. The oil absorption amount is measured in accordance with the method described in JIS K5101.

Examples of commercially available products of the silica include Syylsia 320, Silysia 310P, Silysia 250, Silysia 250N, and Silysia 250N manufactured by Fuji Silysia Kagaku Co., Quot; Silicia 420 ", trade name " Silicia 430 ", trade name " Silicia 440 ", trade name " Silicia 420 ", trade name " Silicia 350 ", trade name " Silicia 370 ", trade name & And trade name " Silysia 470 "; AEROSIL 300 ", trade name" AEROSIL 380 ", trade name" AEROSIL 150 ", trade name" AEROSIL 150 ", trade name" AEROSIL 200 ", trade name" AEROSIL 300 " Trade name " AEROSIL 200V " and trade name " AEROSIL OX50 "; (Trade name " Sun Spare H-201 ", trade name " Sun Spare H-201 ", trade name " Sun Spare H- Sun Spare H-32 ", trade name" Sun Spare H-52 ", trade name" Sun Spare H-122 ", trade name" Sun Spare H-33 " Trade name " AEROSIL R972 ", trade name " AEROSIL R974 ", trade name " AEROSIL R9200 ", manufactured by Nippon Aerosil Co., Ltd., dimethylsiloxylated silicic anhydride; Trade name "AEROSIL R8200", trade name "AEROSIL RX300" and trade name "AEROSIL R812S" manufactured by Nippon Aerosil Co., Trade name " AEROSIL R805 ", manufactured by Nippon Aerosil Co., Ltd., which is octylsiloxylated silicic anhydride; AEROSIL RY200 ", trade name" AEROSIL RY200S "and trade name" AEROSIL RY300 "manufactured by Nippon Aerosil Co., Trade name " AEROSIL R711 ", manufactured by Nippon Aerosil Co., Ltd., which is methacrylsiloxylated silicic anhydride; SILICA BEADS SB-705, manufactured by Miyoshi Kasei Co., Ltd., which is a biodossible silica; "GODD BALL SF-16C", trade name "GAGBOL AF-6C" and trade name "GAGBOL AF-16C" manufactured by SUZUKI YASE INC.

The above-mentioned calcium carbonate is indicated, for example, by the INCI name " CALCIUM CARBONATE ". The calcium carbonate may be used alone or in combination of two or more. Commercially available products of the above-mentioned calcium carbonate include, for example, "Calmaru SCS M5" manufactured by Sakai Kagaku Kogyo Co., Ltd.; Quot; FUWACAL ", manufactured by Shiraishi Calcium Co., Ltd., and the like.

The above-mentioned magnesium carbonate is represented, for example, by INCI name " MAGNESIUM CARBONATE ". The above-mentioned magnesium carbonate may be used singly or two or more kinds may be used. Commercially available products of the above-mentioned magnesium carbonate include, for example, "hard magnesium carbonate" manufactured by Tomita Seiyaku Co., Ltd. and the like.

&Lt; Hydroxyapatite >

The hydroxyapatite is represented, for example, by the INCI name " HYDROXYAPATITE ". The hydroxyapatite may be used alone or in combination of two or more.

The hydroxyapatite is not particularly limited and includes, for example, spherical hydroxyapatite, plate-shaped hydroxyapatite, and amorphous hydroxyapatite. Among them, spherical hydroxyapatite is preferable from the viewpoint of exhibiting high performance of cleaning which forms a hair shape. Examples of commercially available products of hydroxyapatite include HAP-100, HAP-200, HAP-200 and HAP-100, which are manufactured by Daihigakakusan Co., -300 " and the like.

The titanium oxide is represented by, for example, INCI name " TITANIUM DIOXIDE ". The titanium oxide is not particularly limited and may be, for example, fine titanium oxide or pigment titanium. The above-mentioned titanium oxide may be used alone, or two or more kinds may be used. Examples of commercially available titanium oxide include trade name "TTO-55 (A)" and trade name "CR-50" manufactured by Ishihara Sangyo Co.,

The zinc oxide is represented, for example, by the INCI name " ZINC OXIDE ". The zinc oxide may be used singly or two or more kinds may be used. As a commercially available product of zinc oxide, for example, trade name "FINEX-30S-LP2" manufactured by Sakai Chemical Industry Co., Ltd. and the like can be mentioned.

The calcium silicate is indicated, for example, by the INCI name " CALCIUM SILICATE ". The calcium silicate may be used either singly or in combination of two or more. As a commercially available product of the above calcium silicate, for example, trade name "FLORITE R" manufactured by Tomita Seiyaku Co., Ltd.; Trade name " Xonotlite Powder XJ ", trade name " Tobermorite Powder TK ", manufactured by Nihon Insulation Co., Ltd., and the like.

The magnesium silicate is indicated, for example, by the INCI name " MAGNESIUM SILICATE ". The magnesium silicate may be used alone, or two or more magnesium silicate may be used. Examples of the commercially available magnesium silicate include trade name "magnesium silicate (hard)" manufactured by Tomita Seiyaku Co., Ltd., and the like.

The aluminum silicate is indicated, for example, by the INCI name " ALUMINUM SILICATE ". The aluminum silicate may be used alone, or two or more aluminum silicate may be used. The aluminum silicate is not particularly limited, but synthetic aluminum silicate is preferable. Examples of the synthesis method include a method of adding Na ₂ SiO ₃ to alum and drying the resulting precipitate or a method of producing a silicate sol by electrodialysis to thereby form a gel, And a method of adding an aqueous solution of an aluminum salt. Examples of commercially available products of the aluminum silicate include trade name "synthetic aluminum silicate (heavy)" and trade name "synthetic aluminum silicate (hard)" manufactured by Tomita Seiyaku Co.,

The magnesium hydroxide is represented, for example, by the INCI name " MAGNESIUM HYDROXIDE ". The magnesium hydroxide may be used alone or in combination of two or more. Examples of commercially available products of the above-mentioned magnesium hydroxide include trade name "magnesium hydroxide (heavy)" manufactured by Tomita Seiyaku Co., Ltd. and the like.

The content of the component (A) in the 100% by weight of the present composition according to the present invention is 0.05% by mass or more, preferably 0.07% by mass or more, more preferably 0.10% by mass or more and 7.0% Is 5.0 mass% or less, and more preferably 4.0 mass% or less. Since the content of the component (A) is lower than the lower limit, it is possible to further increase the initial repulsive force for making the shape of the head, further improve the constant-holding power after the shape is formed, and furthermore, have. When the content of the component (A) is not more than the upper limit, the effect of preventing flaking, the effect of imparting gloss and the cleaning property are further improved. The content of the component (A) is the total amount of the contents of all the components (A) in the tablet composition according to the present invention.

(Component (B))

The component (B) is at least one compound selected from the group consisting of the component (B1) and the component (B2). The component (B) has a role of effectively increasing the regular holding power after the shape is formed. By using the above-mentioned component (B), flaking can be suppressed and the above effect can be exerted. Further, by using the above-mentioned component (B), it is possible to impart shine to the hair. The component (B) may be used alone or in combination of two or more. The component (B1) and the component (B2) may be used alone or in a combination of two or more.

As the component (B), either one of the component (B1) and the component (B2) may be used, and the component (B1) and the component (B2) may be used in combination. Among them, the component (B2) is preferable from the viewpoint of further restraining the stickiness while increasing the regular retention force.

The component (B1) is a polyoxyethylene / polyoxypropylene random copolymer. That is, the component (B1) is a copolymer having at least a plurality of oxyethylene units (ethylene oxide units) and a plurality of oxypropylene units (propylene oxide units). The type of copolymerization in the component (B1) is in the form of a random copolymer.

The average addition mole number of oxyethylene in the component (B1) is not particularly limited, but is preferably 100 or more, more preferably 200 or more, preferably 400 or less, more preferably 350 or less. The average addition mole number of oxypropylene in the component (B1) is not particularly limited, but is preferably 30 or more, particularly preferably 40 or more, preferably 150 or less, particularly preferably 100 or less.

The component (B1) is preferably in a liquid phase at 25 DEG C from the viewpoint of suppressing flaking, from the viewpoint of easiness of application of a stabilizer, and glaze on hair.

The number average molecular weight of the component (B1) is 10000 or more and 20000 or less. When the number average molecular weight of the component (B1) is less than the lower limit described above, the initial repulsive force and the regular retention force for making the shape of the head become lower. When the number average molecular weight of the component (B1) exceeds the upper limit, the handling property is deteriorated. The number average molecular weight of the component (B1) is preferably 12,000 or more. The number average molecular weight of the component (B1) is preferably 18,000 or less.

The component (B2) is polyoxypropylene sorbit. The average addition mole number of oxypropylene in the component (B2) is not particularly limited, but is preferably 4 or more, more preferably 8 or more, preferably 15 or less, more preferably 12 or less.

The component (B2) is preferably in a liquid phase at 25 DEG C from the viewpoint of suppressing flaking, from the viewpoint of easiness of application of a stabilizer, and glaze on hair.

The number average molecular weight of the component (B2) is 300 or more and 1000 or less. When the number average molecular weight of the component (B2) is less than the lower limit described above, the initial repulsive force and the regular retention force for making the shape of the head are lowered. When the number average molecular weight of the component (B2) exceeds the upper limit, tackiness occurs and the handling property is deteriorated. The number average molecular weight of the component (B2) is preferably 400 or more. The number average molecular weight of the component (B2) is preferably 800 or less.

The component (B) is preferably liquid at 25 占 폚. It is preferable that the component (B) has fluidity at 25 DEG C. For example, when 50 g of sample is put into a glass bottle having a radius of 2 cm and a height of 7 cm and the glass bottle is inverted at a temperature of 25 DEG C, It is preferable that the sample has a property of flowing down from the glass bottle immediately after inverted for 5 minutes.

Examples of commercially available products of the above-mentioned component (B1) include trade name "NEWPOL 75H-90000" manufactured by Sanyo Chemical Industries, Ltd. and the like.

Examples of commercially available products of the component (B2) include trade name "Newpol SP-750" and trade name "SANNIX SP-750" manufactured by Sanyo Chemical Industries, Ltd. and the like.

The content of the component (B) in 100% by mass of the composition of the present invention is 3.0% by mass or more, preferably 5.0% by mass or more, more preferably 8.0% by mass or more and 35.0% by mass or less, Is not more than 30.0 mass%, more preferably not more than 23.0 mass%. When the content of the component (B) is at least the lower limit, the initial repulsive force for making the shape of the head and the regular holding power after the shape are formed can be further improved, and the hair can be further improved in glossiness. When the content of the component (B) is not more than the upper limit, the effect of inhibiting tackiness, the spreadability upon application and the absorbency are further improved. The content of the component (B) is the total amount of the components (B) in the tablet composition according to the present invention.

(A): the content of the component (B)) of the content of the component (A) and the content of the component (B) in the regular tablet composition according to the present invention is 1: 0.1 More preferably 1: 1 to 1:20, and still more preferably 1: 3 to 1:20. When the content of the component (A) is relatively large, the initial repulsive force for making the shape of the head and the effect of suppressing stickiness are further improved. When the content of the component (B) is relatively large, the regular holding power and the shine of the hair after the shape is formed are further improved.

(Component (C))

The component (C) is an acrylic copolymer obtained by using diacetone acrylamide as an essential monomer component. The component (C) may be obtained by further using a monomer component other than diacetone acrylamide together with diacetone acrylamide as a monomer component. Examples of the other monomer component include monomers (at least one monomer) selected from the group consisting of (meth) acrylic acid and (meth) acrylic acid ester. The component (C) has a role of effectively raising the initial repulsive force to make the shape of the head. In particular, the use of the component (C) together with the component (A) and the component (B) contributes greatly to keeping the hair gathered and maintaining the condition of the hair standing. As the component (C), only one kind may be used, or two or more kinds may be used.

The monomer component used to obtain the component (C) comprises at least diacetone acrylamide. The monomer component used for obtaining the component (C) preferably further comprises a monomer (at least one monomer) selected from the group consisting of (meth) acrylic acid and (meth) acrylic acid ester. That is, the component (C) is a copolymer containing at least a structural unit derived from diacetone acrylamide. The component (C) preferably further comprises a structural unit selected from the group consisting of a structural unit derived from (meth) acrylic acid and a structural unit derived from a (meth) acrylic acid ester.

Specific examples of the above-mentioned component (C) include, for example, INCI (International Cosmetic Ingredient Dictionary and Handbook, 15th Edition, Vol 1, 2014, p.66): ACRYLATES / DIACETONEACRYLAMIDE COPOLYMER Acrylate / diacetone acrylamide) copolymer.

The acrylic copolymer as the component (C) may be at least one selected from the group consisting of a sodium salt, an ammonium salt, a triethanolamine salt, a 2-amino-2-methyl-1-propanol salt, .

Specific examples of the salt-like copolymer corresponding to the component (C) include, for example, INCI (International Cosmetic Ingredient Dictionary and Handbook, 15th edition, Volume 1, 2014, p.212): (acrylate / diacetone acrylamide) copolymer AMP, denoted AMP-ACRYLATES / DIACETONEACRYLAMIDE COPOLYMER; (International Cosmetic Ingredient Dictionary and Handbook, 15th Edition, Vol 1, 2014, p.214) which is a 2-amino-2-methyl-1,3-propanediol salt: AMPD-ACRYLATES / DIACETONEACRYLAMIDE COPOLYMER (Acrylate / diacetone acrylamide) copolymer AMPD, and the like.

Commercially available products of the above-mentioned component (C) include, for example, "Plascize L-53" (trade name, manufactured by Ko Kagaku Kogyo Co., Ltd., copolymer (acrylate / diacetone acrylamide); PlasSize L-3200B "," Plasse size L-6010 "," Plasse size L-6330 "and" Plasse size L-3200B "manufactured by Ko Gogaku Kogyo Co., 7400B "," Plasse size L-9400B "," Plasse size L-9909 "; Plasse size L-1260 " and " Plasse size L-53D ", both manufactured by Ko Kagaku Kogyo Co., Ltd., which are copolymer (acrylate / diacetone acrylamide) copolymer AMPD.

The content of the component (C) in 100% by mass of the inventive purifier composition is 0.10% by mass or more, preferably 0.30% by mass or more, more preferably 0.40% by mass or more and 3.0% by mass or less, Is 2.0 mass% or less, and more preferably 1.8 mass% or less. When the content of the component (C) is at least the lower limit, the initial repulsive force for making the shape of the head is further improved. When the content of the component (C) is not more than the upper limit, the reverberation is further improved, and the effect of preventing flaking and the cleaning property are further improved. The content of the component (C) is the total amount of the components (C) in the tablet composition according to the present invention.

The mass ratio of the content of the component (B) to the content of the component (C) (content of the component (B): content of the component (C)) in the regular tablet composition according to the present invention is in the range of 5: Is preferably 70: 1, more preferably 6: 1 to 60: 1. When the content of the component (B) is relatively large, the regular holding power after the shape is formed, the effect of preventing flaking, the cleaning property and the shine of the hair are further improved. When the content of the component (C) is relatively large, the initial repulsive force for forming the shape of the head and the suppression effect of stickiness are further improved.

(Component (D))

The component (D) is at least one compound selected from the group consisting of the component (D1) and the component (D2). By using the above-mentioned component (D), it is possible to further suppress the flaking, improve the cleansing after the cleansing, and give a good feeling to the hair after the hair straightening while maintaining the initial repulsive force for making the shape of the hair. The above-mentioned component (D) may be used alone, or two or more thereof may be used. The component (D1) and the component (D2) may be used either singly or in combinations of two or more.

As the component (D), either one of the component (D1) and the component (D2) may be used, and the component (D1) and the component (D2) may be used in combination.

The component (D1) is a polyoxyalkylene alkyl glucoside. Examples of the oxyalkylene group in the component (D1) include an oxyethylene group and an oxypropylene group. The average addition mole number of the oxyalkylene group in the component (D1) is not particularly limited, but is preferably 5 or more, and preferably 40 or less. The number of carbon atoms of the alkyl group in the above-mentioned component (D1) is preferably 1 to 4, more preferably 1 to 3. The alkyl group in the component (D1) is preferably a methyl group or an ethyl group.

The component (D1) is not particularly limited, and examples thereof include polyoxyethylene methyl glucoside, polyoxyethylene ethyl glucoside, polyoxypropylene methyl glucoside, and polyoxypropylene ethyl glucoside.

From the viewpoint of imparting a better feeling to hair after regular hair removal while keeping the initial repulsive force for making the shape of hair high, the component (D1) preferably contains polyoxyalkylene methyl glucoside, and polyoxypropylene methyl It is preferable to include a glucoside.

The component (D2) is a polyoxyalkylene glycerin fatty acid ester. The number of carbon atoms of the fatty acid in the component (D2) is preferably 8 or more, and preferably 22 or less. Examples of the oxyalkylene group in the component (D2) include an oxyethylene group and an oxypropylene group. The average number of moles of the oxyalkylene group added in the component (D2) is preferably 5 or more, and preferably 40 or less.

It is preferable that the fatty acid in the component (D2) is a branched fatty acid, and the component (D2) is a polyoxyethylene Alkylene glycerin branched fatty acid ester.

The number of carbon atoms of the branched fatty acid in the polyoxyalkylene glycerin branched fatty acid ester is preferably 8 or more, more preferably 8 or more, and still more preferably 8 or more, in view of imparting a better feeling to the hair after regular hair removal while keeping the initial repulsive force, Is 22 or less. Examples of the branched fatty acid in the polyoxyalkylene glycerin branched fatty acid ester include 2-ethylhexanoic acid, isononanoic acid, isopalmitic acid and isostearic acid.

As the polyoxyalkylene glycerin branched fatty acid ester, polyoxyethylene glyceryl isostearate is particularly preferable.

Commercially available products of the above-mentioned component (D1) include, for example, niche-like manufacture, trade name "MACBIOBRIDE MG-10P"; GLUCAM E-10 " and trade name " GLUCAM E-20 ", both manufactured by Noveon; Glucam P-10 " manufactured by Amerchol Corp., and the like.

As a commercially available product of the above-mentioned component (D2), for example, trade name "NOIGEN GIS-125" manufactured by Daiichi Kogyo Seiyaku Co., Ltd.; EMALEX GWIS-120 ", trade name" EMALEX GWIS-125 "and trade name" EMALEX GWIS-130 "manufactured by Nihon Emulsion Co., Ltd., and the like.

The content of the component (D) in 100% by mass of the composition of the present invention is preferably 0.5% by mass or more, more preferably 1.0% by mass or more, and preferably 20.0% by mass or less, 10.0 mass% or less. When the content of the component (D) is lower than the lower limit described above, the flaking is further suppressed, the cleaning after the hair treatment is further improved, and the hair after the hair treatment is further imparted with a better feeling. When the content of the component (D) is less than the upper limit, the tackiness is further reduced. The content of the component (D) is the total amount of the contents of all the components (D) in the tablet composition according to the present invention.

The mass ratio of the content of the component (A) to the content of the component (D) (content of the component (A): content of the component (D)) in the regular tablet composition is from 1: 0.2 to 1:20 , More preferably from 1: 1 to 1:10. When the content of the component (D) is relatively large, the feeling of hair, the effect of suppressing flaking, and the cleaning property are further improved.

(Component (E))

The component (E) is a clay mineral. By using the above-mentioned component (E), the initial repulsive force for making the shape of the head and the storage stability of the stabilizer composition are further improved. The above-mentioned component (E) may be used alone, or two or more thereof may be used.

The component (E) may be a natural product or a compound. Examples of the component (E) include, but are not limited to, kaolin clay minerals, antigorite clay minerals, pyrophyllite clay minerals, mica clay minerals, smectite clay minerals, vermiculite clay minerals, Chlorinated clay minerals and organic modified clay minerals.

Examples of the kaolin clay minerals include kaolin, nacrite, dickite, and halloysite. Examples of the antigorite clay minerals include antigorite, amesite, and cronstedite. Examples of the pyrophyllite clay minerals include pyrophyllite and talc (talc). Examples of the mica clay minerals include ilite, glauconite, seladonite, sericite, mica (mica), muscovite, chromite muscovite and biotite. Examples of the smectite clay minerals include bentonite, montmorillonite, bederite, nontonite, saponite, hectorite and lucentite. Examples of the vermiculite clay minerals include vermiculite and the like. Examples of the chlorite-based clay minerals include chlorite (chlorite) and the like. Examples of the organically modified clay minerals include organic modified clay minerals obtained by organic modification treatment of smectite clay minerals or vermiculite clay minerals. For the organic modification treatment, a quaternary ammonium salt type cationic surfactant is suitably used. Examples of the quaternary ammonium salt type cationic surfactant include alkyl trimethylammonium chloride, dialkyldimethylammonium chloride, and benzalkonium chloride.

From the viewpoint of further improving storage stability and feeling of use, the component (E) is preferably a clay mineral selected from the group consisting of synthetic silicates and derivatives thereof. The synthetic silicate and the derivative thereof refer not to a silicate mineral mainly composed of magnesium silicate or silicate (sodium / magnesium) derived from natural materials containing many impurities, but to silicates and silicate derivatives obtained by synthesis.

Examples of the synthetic silicate and derivatives thereof include synthetic silicates (sodium / potassium silicate) represented by SODIUM MAGNESIUM SILICATE, INCI name (International Cosmetic Ingredient Dictionary and Handbook, 14th edition, Vol. 2, Magnesium fluoride, INCI name (International Cosmetic Ingredient Dictionary and Handbook, 14th Edition, Volume 2, 2012, p.1793): Magnesium fluorosilicate represented by MAGNESIUM FLUOROSILICATE, INCI name 14th edition, volume 2, 2012, p. 3076): fluorosilicic acid (sodium / magnesium), INCI name (SODIUM MAGNESIUM FLUOROSILICATE, 14th edition, , p.1799): MAGNESIUM SODIUM FLUOROSILICATE (Magnesium / Potassium), INCI Name (International Cosmetic Ingredient Dictionary and Handbook, 14th Edition, Book 2, 2012, p.1800), as MAGNESIUM POTASSIUM FLUOROSILICATE: MAGNESIUM SODIUM FLUOROSILICATE Fluorosilicic acid < RTI ID = 0.0 > (& / Sodium), INCI name (International Cosmetic Ingredient Dictionary and Handbook, 14th edition, Volume 1, 2012, p.156): there may be mentioned synthetic aluminum silicate, such as denoted by ALUMINUM SILICATE.

Among the clay minerals, the clay minerals selected from the group consisting of synthetic silicic acid (sodium / magnesium), fluorosilicic acid (sodium / magnesium) and fluorosilicic acid (sodium / magnesium) (at least one clay mineral ) Is particularly preferable.

Commercially available products of the above component (E) include, for example, trade name "LAPONITE XLG" and trade name "Laponite XL21" manufactured by Lockwood.

The content of the component (E) is preferably 0.10% by mass or more, more preferably 0.30% by mass or more, further preferably 0.50% by mass or more, and more preferably 0.50% by mass or more, 10.0 mass% or less, more preferably 5.0 mass% or less, and further preferably 3.0 mass% or less. When the content of the component (E) is lower than the lower limit described above, the storage stability and the scratch resistance are further improved. When the content of the component (E) is not more than the upper limit, the preservative stability of the anticorrosive composition is further improved.

(Component (F))

The component (F) is a polysaccharide compound. The use of the component (F) improves the dispersibility of the component (A) because the stabilizer composition is appropriately thickened, and the stabilizer composition is hardly separated and the storage stability is further improved . The above-mentioned component (F) may be used alone, or two or more thereof may be used.

Examples of the component (F) include, but are not limited to, polysaccharides, modified polysaccharides (e.g., alkyl modified polysaccharides) and the like, and examples thereof include alginic acid, carrageenan, agar, purcellan, guar gum, Polysaccharide-derived polysaccharide compounds such as konjac mannan, tamarind gum, tara gum, dextrin, starch, locust bean gum, gum arabic, ghatti gum, karaya gum, tragacanth gum, arabinogalactan, pectin and quince; Animal-derived polysaccharide compounds such as chitosan and hyaluronic acid; Polysaccharide-derived polysaccharide compounds such as curdlan, xanthan gum, gellan gum, cyclodextrin, dextran, pullulan and hyaluronic acid; Non-ionic cellulose such as microcrystalline cellulose, methylcellulose, ethylcellulose, hydroxymethylcellulose, hydroxyethylcellulose, hydroxypropylcellulose and hydroxypropylmethylcellulose; Anionic cellulose such as carboxymethylcellulose; Cationized cellulose such as O- [2-hydroxy-3- (trimethylammonio) propyl] hydroxyethylcellulose chloride; And cationized guar gum such as O- [2-hydroxy-3- (trimethylammonio) propyl] guar gum chloride.

As the component (F), among the polysaccharide compounds, compounds (at least one compound) selected from the group consisting of xanthan gum, guar gum, tamarind gum and gellan gum are preferable.

Examples of commercially available products of the above component (F) include, for example, a trade name "Echo gum T", trade name "Kerudento" and trade name "Monat gum ) "; Manufactured by Ina Food Industry Co., Ltd.), trade name "Inagel Guar Gum CS"; Manufactured by DSP Gokyo Food & Chemical Co., Ltd., trade name "Glyroid 6C"; CP Kelco U.S., Inc., Gellan Surname. (Trade name) " Kelcogel ", and the like.

The content of the component (F) in the 100% by weight of the antiseptic composition according to the present invention is preferably 0.01% by mass or more, more preferably 0.10% by mass or more, preferably 5.0% by mass or less, 2.0% by mass or less. When the content of the component (F) is not lower than the lower limit described above, the storage stability of the stabilizer composition is further improved. When the content of the component (F) is not more than the upper limit, tackiness is further suppressed. The content of the component (F) is the total amount of the contents of all the components (F) in the tablet composition according to the present invention.

From the viewpoint of further increasing the storage stability of the stabilizer composition by properly thickening the stabilizer composition, it is preferable that the stabilizer composition according to the present invention comprises the component (E) and the component (F). The dispersion stability of the component (A) is further increased by the combined use of the component (E) and the component (F), so that the purification developer composition is more difficult to be separated. Further, since the stabilizer composition shows good thixotropic properties, the applicability of the stabilizer composition is improved.

The mass ratio (content of the component (E): content of the component (F)) of the component (E) and the component (F) when the component (E) and the component (F) : 1 to 10: 1, more preferably 2.5: 1 to 8: 1. When the mass ratio is satisfied, the stickiness is further suppressed, and the storage stability of the stabilizer composition, particularly the storage stability when stored for a long period of time, is further improved.

When the component (E) and the component (F) are used in combination, the total amount of the content of the component (E) and the content of the component (F) is preferably 0.30 mass% or more, more preferably 0.40 mass% %, Preferably 5.0 mass% or less, and more preferably 4.0 mass% or less. When the total amount is within the above range, the stickiness is further suppressed and the storage stability of the stabilizer composition, particularly the storage stability when stored for a long period of time, is further improved.

(Other components)

The stabilizer composition according to the present invention is not particularly limited, but preferably contains water. The water is not particularly limited, and water and the like used for cosmetics and the like can be used, and purified water is preferable. The content of water in the 100% by mass of the inventive purifier composition is preferably 30% by mass or more, more preferably 40% by mass or more, preferably 95% by mass or less, and still more preferably 90% by mass or less .

The stabilizer composition according to the present invention is not particularly limited, but preferably contains a lower alcohol having 2 to 5 carbon atoms (particularly, ethanol). The content of the lower alcohol (particularly, ethanol) in the 100% by mass composition of the present composition according to the present invention is preferably 2.0% by mass or more, more preferably 5.0% by mass or more, and further preferably 50.0% Is not more than 30.0 mass%.

The cleaning agent composition according to the present invention may contain, for example, a surfactant such as a nonionic surfactant, a cationic surfactant, and an amphoteric surfactant within a range that does not impair the effect of the present invention; Polyhydric alcohols such as glycerin, 1,3-butylene glycol, propylene glycol, 1,2-butanediol, 1,2-pentanediol, 1,2-hexanediol, Alcohol; Higher alcohols having 12 to 18 carbon atoms such as lauryl alcohol, myristyl alcohol, cetyl alcohol, stearyl alcohol, isostearyl alcohol, cetostearyl alcohol and oleyl alcohol; Sugar alcohols such as sorbitol, maltitol and trehalose; Silicone oil; Metal ion sequestrants; Antioxidants; Plant extracts; dyes; Pigments; pH adjusters; Spices; antiseptic; A solvent, and the like.

(Other details of the stabilizer composition)

The characteristics of the tablet composition according to the present invention are not particularly limited and may be any of liquid, gel, cream, and solid. It is preferable that the stabilizer composition is liquid or gel-like. Generally, in the case of the liquid crystal composition or the gel composition, when the particles are used, the flowability of the stabilizer composition is high, so that the dispersibility of the particles tends to decrease. As a result, in the liquid or gel-based stabilizer composition, the initial repulsive force for making the shape of the head and the regular retention force after the shape are formed tend to decrease, and tackiness and flaking tend to occur easily. On the other hand, by employing the above-described composition in the composition for a charge control agent according to the present invention, even in the case of a liquid or gel-type antiperspirant composition, an initial repulsive force and a shape for suppressing the occurrence of flaking and tackiness, It is possible to increase the regular retention force after being made.

The viscosity of the stabilizer composition at 25 占 폚 is preferably 1000 mPa 占 퐏 or more, more preferably 2000 mPa 占 퐏 or more, preferably 100000 mPa 占 퐏 or less, and still more preferably 50000 mPa 占 퐏 or less. When the viscosity is lower than the lower limit and lower than the upper limit, the coating property is further increased, and generation of flaking and tackiness are further suppressed, and the initial repulsive force to make the shape of the head and the constant- . In the above-described stabilizer composition, even if the viscosity is lower than the upper limit and the fluidity is high, it is possible to suppress the occurrence of flaking and tackiness, and to improve the initial repulsive force for making the shape of the head and the constant-

The viscosity was measured using a viscometer at a rotational speed of 12 rpm and a rotation time of 1 minute using a No. 4 rotor. As the viscometer, a TV-22 type viscometer manufactured by Toki Sansu Co., Ltd. can be used.

The method for producing the stabilizer composition according to the present invention is not particularly limited, and a known method for producing the stabilizer composition can be used as the method for producing the stabilizer composition according to the present invention. As the method for producing the stabilizer composition according to the present invention, for example, the component (A) and the water (optionally the component (E)) are stirred with a dispenser and then replaced with a paddle mixer And a method of blending and homogenizing other components.

With the composition of the present invention, it is possible to suppress the generation of flaking and tackiness and improve the regular holding power after the initial repulsive force and the shape of the head are formed.

In the present specification, the term " make a shape of a head " is not particularly limited, but refers to setting a hair relatively firmly, for example, for setting a hair.

The tonicity agent composition according to the present invention contains at least component (A), component (B) and component (C) as main purification components. The component (B) has an excellent effect of binding and holding hair, and even when a long time has elapsed after correcting hair, it is possible to prevent the hair from being scattered and collapsing the hair form having the shape. Also, the effect of suppressing flaking is excellent. On the other hand, the component (C) is excellent in the effect of imparting hardness to the hair and, for example, excellent in the ability to raise hair. The component (A) has both an effect of holding the hair tied and an effect of imparting hardness to the hair, further suppressing tackiness, suppressing unnatural gloss and giving a natural appearance.

Therefore, by using the component (A), the component (B), and the component (C) in combination, it is possible to increase the initial repulsive force for making the shape of the head while suppressing tackiness and unnatural gloss, . Particularly, hair can be gathered and set up well, and the gathered hair can be kept well. In addition, it is possible to suppress the occurrence of flaking (a phenomenon in which white powder or a film appears to adhere on the hair) at the time of correcting.

In addition, by blending the component (D), the repulsive force and the effect of suppressing the flaking can be further improved, and the effect of imparting luster to the hair after the cleansing and cleansing properties are improved.

Further, by blending the component (E) and the component (F), the stabilizer composition is properly thickened to improve the applicability of the stabilizer composition. By setting the blending ratio of the component (E) and the component (F) within a specific preferable range, the component (A) precipitates or becomes less likely to aggregate, and the storage stability of the stabilizer composition (stability in long-term storage) is improved .

The stabilizer composition according to the present invention is not particularly limited, and can be used, for example, in a form packed in a container.

Examples of the container include a bottle container, a jar container, and a tube container. The container is preferably a bottle container or a tube container.

Example

Hereinafter, the present invention will be specifically described with reference to examples and comparative examples. The present invention is not limited to the following embodiments.

The following components were used in Examples and Comparative Examples.

(Component (A))

Trade name " Silysia 320 ": silica (manufactured by Fuji Silysia Kagaku)

Trade name " Aerosil 200 ": silica (manufactured by Nippon Aerosil Co., Ltd.)

&Quot; Conceptual HAP ": hydroxyapatite (manufactured by Daihei Kagaku Co.)

Trade name " FLOWRITE R ": calcium silicate (manufactured by Tomita Seiyaku Co., Ltd.)

Synthetic aluminum silicate (heavy): Aluminum silicate (manufactured by Tomita Seiyaku Co., Ltd.)

Magnesium hydroxide (heavy): Magnesium hydroxide (manufactured by Tomita Seiyaku Co., Ltd.)

(Component (B))

Trade name " Newpol 75H-90000 ": polyoxyethylene polyoxypropylene hexylene glycol ether, manufactured by Sanyo Chemical Industries, Ltd., number average molecular weight 14000,

Newpol SP-750 ": polyoxypropylene sorbitol, manufactured by Sanyo Chemical Industries, Ltd., number average molecular weight 690, liquid phase

(A polyoxyethylene / polyoxypropylene copolymer other than the component (B) (component (B '))

Newpol 50HB-55 ": polyoxyethylene polyoxypropylene butyl ether, manufactured by Sanyo Chemical Industries, Ltd., number average molecular weight 300, liquid phase

(Component (C))

Quot; Plasse size L-6330 ", pure substance 30% by mass, manufactured by Koji Kagaku Co.,

"Plasse size L-53", 50% by mass of pure substance, manufactured by Koji Kagaku Co., Ltd.

Plasse size L-53D ", 50% by mass of pure substance, manufactured by Ko Kagaku Kogyo Co.,

(Component (D))

Trade name " NOIGEN GIS-125 ": polyoxyethylene glyceryl isostearate, manufactured by Daiichi Kogyo Seiyakusa

Product name " Macbio Ride MG-10P ": polyoxypropylene methyl glucoside,

(Component (E))

Trade name " Laponite XL21 ": fluorosilicic acid (sodium / magnesium), manufactured by Lockwood

Product name "Laponite XLG": Synthetic silicate (sodium / magnesium), manufactured by Lockwood

(Component (F))

"Eco Gum T": Zanthan gum, manufactured by Dainippon Sumitomo Seiyaku Co., Ltd.

(Other)

ethanol

2-Amino-2-methyl-1-propanol

Purified water

(Examples 1 to 17 and Comparative Examples 1 to 5)

The formulation ingredients shown in Tables 1 and 2 below were blended (the mixing unit was% by mass) to prepare a regular-charge formulation composition. All the properties of the tonicity composition of Examples 1 to 17 were in the form of gel. The amount in the table is expressed as the blending amount in pure water.

The obtained tonicity agent composition was filled in a plastic container to obtain a correcting agent.

(Test Example 1: Evaluation of stickiness)

Twenty professional panelists uniformly applied the above-described composition for cleaning composition on the hair of a short hair wig (Lesson Mannequin: manufactured by Yukari Japan Co., Ltd.), and hair was raised upward from the roots of the hair to perform a regular hair, I replied whether it was sticky or not. From the answers, stickiness was evaluated based on the following criteria.

○ (very good): More than 16 out of 20 responded that they are not sticky

△ (Good): 10 to 15 out of 20 responded that they are not sticky

× (bad): Less than 9 out of 20 responded that they are not sticky

(Test Example 2: Evaluation of initial repulsive force (standing force)) [

Twenty professional panels were uniformly applied to the hair of a short hair wig (Lesson mannequin: manufactured by Yukari Japan Co., Ltd.) and the hair was raised upward from the roots of the hair to perform regular hair growth. Thereafter, . Further, it was judged that there was an initial repulsive force that the shape of the regular hair was reliably maintained. From the answer, the initial repulsive force was evaluated based on the following criteria.

○ (very good): More than 16 out of 20 responded that they had early recovery power

△ (Good): 10 to 15 out of 20 responded that they had early detection ability

× (bad): Less than nine out of 20 responded that they had early recovery power

(Test Example 3: evaluation of retention force)

20 professional panelists witnessed the hair of the wig after the lapse of 6 hours after the test Example 2 (evaluation of the initial repulsive force), and answered the presence or absence of the constant-retention force after standing. Further, it was judged that there was a constant holding force in the case where the shape of the hair that had been normally held in Test Example 2 was still maintained. From the above answer, the regular retention force was evaluated on the following basis.

○ (very good): More than 16 out of 20 respondents said that they had regular maintenance

△ (Good): 10 to 15 out of 20 respondents said that they had a positive ability to maintain

× (bad): Less than nine out of 20 responded

(Test Example 4: evaluation of flaking)

After 20 Expert Panels, the hair of the wig was combed with the tip of the hair from the root of the hair to the end of the hair five times in succession after the test Example 3 (evaluation of the regular holding power) to answer whether or not flaking was performed. Further, when white powder appeared to be attached on the hair, it was judged that there was flaking. From the answers, flaking was evaluated based on the following criteria.

○ (very good): More than 16 out of 20 responded that there is no play king

△ (Good): 10 to 15 out of 20 people answered that there is no play king

× (bad): Less than 9 out of 20 answered that there is no play king

(Test Example 5: Evaluation of cleaning)

Twenty professional panelists washed the hair of the wig with lukewarm water using shampoo (trade name "LUCIDO shampoo", manufactured by Mandom) after Test Example 4 (Evaluation of flaking) , Dried, and returned the good or bad of cleaning. Also, it was said that washing is good when there is no feeling of discoloration of hair or feeling of stickiness at the time of shaving. From the answer, the cleaning was evaluated according to the following criteria.

○ (very good): More than 16 out of 20 answered that washing is good

△ (Good): 10 to 15 out of 20 responded that cleaning is good

× (bad): Less than nine out of 20 answered that washing is good

(Test Example 6: Evaluation of glossiness)

Twenty professional panelists answered the presence or absence of hair shine on the wig after Test Example 2 (evaluation of initial repulsive force). From the answer, the gloss was evaluated on the following criteria.

&Lt; Evaluation standard of shine of hair >

○ (very good): More than 16 out of 20 responded that there was gloss

△ (Good): 10-15 out of 20 people answered that there was luster

× (bad): Less than nine out of 20 answered with gloss

(Test Example 7: Evaluation of Storage Stability)

Each of the tonicity compositions immediately after the preparation was filled in a clear glass container and stored in a thermostatic chamber at 40 캜 for 4 weeks. Appearance and properties of each of the tonicity compositions after storage were observed and evaluated according to the following criteria.

○ (very good): no rise in viscosity or viscosity of the composition is not recognized

? (Good): slight rise in viscosity or viscosity of the composition is recognized

X (poor): The increase in the solubility or viscosity of the composition is clearly recognized

The results are shown in Tables 1 and 2 below. The total content of the blending components in each of Examples and Comparative Examples shown in Tables 1 and 2 is 100% by mass.

[Table 1]

[Table 2]

Claims

Comprising the following component A, the following component B, the following component C and the following component E,
The content of the component A is 0.05 mass% or more and 7.0 mass% or less,
The content of the component B is 3.0% by mass or more and 35.0% by mass or less,
Wherein the content of the component C is 0.10% by mass or more and 3.0% by mass or less,
Component A: particles selected from the group consisting of silica, calcium carbonate, magnesium carbonate, hydroxyapatite, titanium oxide, zinc oxide, calcium silicate, magnesium silicate, aluminum silicate,
Component B: a polyoxyethylene / polyoxypropylene random copolymer having a number average molecular weight of 10000 or more and 20,000 or less, and a polyoxypropylene sorbitol having a number average molecular weight of 300 or more and 1000 or less
Component C: An acrylic copolymer obtained by using diacetone acrylamide as an essential monomer component
Component E: Clay minerals.

The method according to claim 1,
Further, a tonicity agent composition comprising the following component D:
Component D: a polyoxyalkylene alkyl glucoside, and a polyoxyalkylene glycerin fatty acid ester.

delete

3. The method according to claim 1 or 2,
Additionally, a tonicity agent composition comprising:
Component F: polysaccharide compound.

3. The method according to claim 1 or 2,
In addition, it comprises the following component F,
Wherein the mass ratio of the content of the component E to the content of the component F is 2: 1 to 10: 1.
Component F: polysaccharide compound.