KR101789395B1 - Hairstyling composition and method for producing hairstyling composition - Google Patents

Abstract

When the hair is standing still, it has an excellent initial repulsive force to erect the hair, suppressing the occurrence of flaking and tackiness, tidily restraining the hair, and keeping the hair constantly maintained, The present invention provides a stabilizer composition which is capable of imparting a desired effect. The cleaning agent composition according to the present invention comprises 0.1 mass% or more of particles (component A) selected from the group consisting of silica, calcium carbonate, magnesium carbonate, hydroxyapatite, titanium oxide, zinc oxide, calcium silicate, magnesium silicate, aluminum silicate, (Component B) having a number average molecular weight of not less than 150 and not more than 450, polyethylene glycol (component C) having a number average molecular weight of not less than 550 and not more than 2000, and polyethylene glycol having a number average molecular weight of not less than 2500 and not more than 4000 ( Component D).

Description

TECHNICAL FIELD [0001] The present invention relates to a hair cosmetic composition, a hair cosmetic composition, a hair cosmetic composition,

TECHNICAL FIELD The present invention relates to a stabilizer composition suitably used as a stabilizer for trim hair and a method for producing the stabilizer composition.

To prepare the hair, various constipating agent compositions such as liquid, gel, cream, and solid forms are used. Conventionally, a film-forming polymer is often used to impart a repulsive force, which is a main function, to the cleaning composition. However, when an effective amount of the film-forming polymer is blended, there is a problem in that the initial recovery force immediately after the straightening is increased, while the spreadability and absorbability of the stabilizer composition on the hair is deteriorated or stickiness is generated. Further, in the regular-agent composition using the film-forming polymer, a film is formed on the surface of the hair derived from the film-forming polymer after the treatment. For this reason, it is difficult to tune the hair into a natural state, and when the hair is stimulated with a hand or a comb after the hair is cleaned, the film is peeled off from the surface of the hair (so-called flaking occurs) .

Accordingly, a method different from the method of using a film-forming polymer has been studied, and specifically, it has been studied to impart a repulsive force to a cleaning agent composition using a powder.

The following Patent Document 1 discloses a hair cosmetic composition (regular composition composition) containing 0.1 to 10% by mass of a particulate powder having a specific surface area of 50 m ² / g or more. Patent Document 1 discloses that by using a specific particulate powder at the specified content, a good feeling can be obtained, an excellent repulsive force can be obtained, a favorable feeling can be maintained for a long time, and excellent reverberation can be obtained.

Japanese Patent Application Laid-Open No. 2003-342130

As described in Patent Document 1, when the hair styling composition containing the particulate powder is used for regular treatment, the initial repulsive force to erect the hair and the constant retention force to continuously maintain the hair are not sufficiently increased. Also, flaking may occur, or sticking may occur. In addition, there is also a problem that the cleaning property after the treatment is poor.

Particularly, when the fine particle powder as described in Patent Document 1 is used in the liquid crystal composition or the gel composition, the dispersibility and stability of the fine particle powder tend to be lowered because of the high fluidity of the composition. Therefore, in the above-described liquid or gel-type stabilizer composition, unevenness tends to occur in the force to hold the hair and the force to hold the hair, and flaking and tackiness are likely to occur.

It is an object of the present invention to provide a hair styling composition which is excellent in initial repulsive force to erect a hair when standing still and is capable of suppressing the occurrence of flaking and tackiness and restraining the hair elasticity, A cleaning agent composition capable of satisfactorily cleaning after cleaning, and a method for producing the cleaning agent composition.

The propellant composition according to the present invention comprises the following components (A), (B), (C) and (D) % Or less.

Component (A): particles selected from the group consisting of silica, calcium carbonate, magnesium carbonate, hydroxyapatite, titanium oxide, zinc oxide, calcium silicate, magnesium silicate, aluminum silicate and magnesium hydroxide

Component (B): Polyethylene glycol having a number average molecular weight of 150 to 450

Component (C): Polyethylene glycol having a number average molecular weight of 550 to 2000

Component (D): Polyethylene glycol having a number average molecular weight of 2500 to 4000

In the conditioner composition according to the present invention, the mass ratio of the content of the component (A) to the total content of the component (B), the component (C) and the component (D) is 1: 2 to 1:25 .

The stabilizer composition according to the present invention preferably further comprises the following component (E).

Component (E): Clay mineral

The stabilizer composition according to the present invention preferably further comprises the following component (F).

Component (F): polysaccharide compound

In the stabilizer composition according to the present invention, the mass ratio of the content of the component (E) to the content of the component (F) is preferably 2: 1 to 15: 1.

The component (A), the component (B), the component (C) and the component (D) are mixed so that the content of the component (A) is 0.1 By mass to 10% by mass or less.

In the process for producing a stabilizer composition according to the present invention, it is preferable to further blend the component (E), and it is preferable to further blend the component (F).

The present composition contains the specific components (A), (B), (C) and (D), and since the content of the component (A) is within a specific range, Is excellent in initial repulsive force, suppresses the occurrence of flaking and tackiness, and tidies the hair firmly, while keeping the hair constantly maintained, and can improve the cleansing properties after the treatment.

Hereinafter, the present invention will be described in detail.

The tablet composition according to the present invention is a tablet composition comprising particles selected from the group consisting of silica, calcium carbonate, magnesium carbonate, hydroxyapatite, titanium oxide, zinc oxide, calcium silicate, magnesium silicate, aluminum silicate and magnesium hydroxide, Polyethylene glycol having a number average molecular weight of 550 or more and 450 or less, polyethylene glycol having a number average molecular weight of 550 or more and 2,000 or less, and polyethylene glycol having a number average molecular weight of 2500 or more and 4000 or less.

In the present specification, "particles selected from the group consisting of silica, calcium carbonate, magnesium carbonate, hydroxyapatite, titanium oxide, zinc oxide, calcium silicate, magnesium silicate, aluminum silicate and magnesium hydroxide" . Further, the "polyethylene glycol having a number average molecular weight of 150 or more and 450 or less" may be referred to as "component (B)". The "polyethylene glycol having a number average molecular weight of 550 or more and 2000 or less" may be referred to as "component (C)". The "polyethylene glycol having a number average molecular weight of 2500 or more and 4000 or less" is sometimes referred to as "component (D)".

It is preferable that the tablet composition according to the present invention further comprises a clay mineral. In the present specification, the term "clay mineral" is sometimes referred to as "component (E)".

It is preferable that the stabilizer composition according to the present invention further comprises a polysaccharide compound. In the present specification, the "polysaccharide compound" may be referred to as "component (F)".

The stabilizer composition according to the present invention may further comprise a polymer selected from the group consisting of the first polymer and the second polymer described below. The first polymer is a polymer obtained by using at least two monomers selected from the group consisting of (meth) acrylic acid and (meth) acrylic acid alkyl ester as a monomer component. The second polymer may include a monomer selected from the group consisting of (meth) acrylic acid and (meth) acrylic acid alkyl ester, (meth) acrylic acid polyoxyethylene alkyl ether, itaconic acid polyoxyethylene alkyl ether and neodecanoyl vinyl ether Based on the total weight of the polymer.

In the present specification, the "polymer selected from the group consisting of the first polymer and the second polymer" may be referred to as "component (F ')". The "first polymer" may be referred to as "component (F'1)", and the "second polymer" may be referred to as "component (F'2)". The term "(meth) acrylic acid" means one or both of acrylic acid and methacrylic acid.

As described above, the detergent composition according to the present invention contains at least the component (A), the component (B), the component (C) and the component (D). It is preferable that the stabilizer composition according to the present invention further comprises a component (at least one component) selected from the group consisting of the component (E) and the component (F). When the component (E) is used, the component (E) is preferably used in combination with the component selected from the group consisting of the component (F) and the component (F '), . Among them, the stabilizer composition according to the present invention preferably contains both of component (A), component (B), component (C), component (D), component (E) and component (F). The tonicity agent composition according to the present invention may further contain other components. Only one kind is used for each of the components, for example, component (A), component (B), component (C), component (D), component (E), component (F) Or two or more of them may be used.

The component (F ') is a compound (at least one compound) selected from the group consisting of the component (F'1) and the component (F'2). Further, only one of the above-mentioned components (F'1) and (F'2) may be used, or two or more of them may be used.

Hereinafter, details of each component used in the cleaning composition of the present invention will be described.

(Component (A))

The component (A) is particles (at least one particle) selected from the group consisting of silica, calcium carbonate, magnesium carbonate, hydroxyapatite, titanium oxide, zinc oxide, calcium silicate, magnesium silicate, aluminum silicate and magnesium hydroxide. The component (A) mainly has a role of suppressing tackiness and enhancing the initial repulsive force and the regular retention force. The use of the above-mentioned component (A) makes it easier to perform repetitive refinement once the refinement has been performed once, thereby enhancing the reverberation, as compared with the case where the film-forming polymer is used.

As the component (A), particles (at least one particle) selected from the group consisting of silica, magnesium carbonate, hydroxyapatite, calcium silicate, magnesium silicate, aluminum silicate and magnesium hydroxide are preferable from the viewpoint of improving the purification performance. And particles (at least one particle) selected from the group consisting of silica, magnesium silicate and magnesium hydroxide are more preferable. The above-mentioned component (A) may be used alone, or two or more thereof may be used.

<Silica>

As the silica, known silica (silicic anhydride) can be used. The silica may be anhydrous silicic acid (hydrophilic silica) not subjected to hydrophobic treatment, or may be hydrophobic silicic anhydride. Further, the surface-treated silica may be an amino acid, ester, lecithin or the like. Further, the silica may be a so-called collapsible silica particle. The silica may be used alone or in combination of two or more.

The hydrophobic silicic anhydride is a material obtained by subjecting anhydrous silicic acid (for example, anhydrous silicic anhydride) to hydrophobic treatment. Examples of the treatment agent used in the hydrophobic treatment include an organosilyl compound and a silicone compound. Examples of the organosilyl compound include methyltrichlorosilane, dimethyldichlorosilane, trimethylchlorosilane, hexamethyldisilazane, methyltrialkoxysilane, dimethyl dialkoxysilane, trimethylalkoxysilane, ethyltrichlorosilane, propyltrichlorosilane, hexyl Long chain alkyl trichlorosilane, long chain alkyl trichlorosilane, ethyl trialkoxy silane, propyl trialkoxy silane, hexyl trialkoxy silane, long chain alkyl trialkoxy silane, methacryl silane, fluoroalkyl silane and perfluoroalkyl silane . Examples of the silicone compound include dimethylpolysiloxane (silicone oil), methylphenylpolysiloxane, methylhydrogenpolysiloxane and amino-modified silicone. As a method of the hydrophobic treatment, a known method can be employed. Examples of the hydrophobic treatment method include a liquid phase method, a vapor phase method, and an autoclave method.

Preferred examples of the hydrophobic silicic anhydride include dimethylsiloxylated silicic anhydride, trimethylsiloxylated silicic anhydride, octylsiloxylated silicic anhydride, silicon oil-treated silicic anhydride and methacrylosiloxylated silicic anhydride.

The bast / compactible silica particles are particles formed by aggregating a plurality of primary silica particles. Examples of the silica primary particles include, but are not limited to, spherical silica particles, phosphorus-based silica particles, and amorphous silica particles. The average particle diameter of the silica primary particles is not particularly limited.

The diblock compacted silica particles may contain components other than silica. The component other than the silica (hereinafter sometimes referred to as "inclusion component") is not particularly limited, and examples thereof include surfactants, polyhydric alcohols, higher alcohols, sugar alcohols, silicone oils, sequestering agents, Plant extracts, dyes, pigments, fragrances, moisturizers, vitamins, amino acids, and refreshing agents. Among them, amino acids, silicone oil and vitamins are preferable. Examples of the amino acids include, but are not limited to, dilauroyl glutamate lysine Na (e.g., trade name &quot; Perichea &quot;, manufactured by Asahi Kasei Chemicals Co., Ltd.), trimethylglycine and glutamic acid. When the biodestructured silica particles contain the inclusion component, the inclusion component is released when the biodisolidized silica particles collapse at the time of purification, and an effect depending on the type of inclusion component is exerted. For example, when the biodisolidized silica particles contain amino acids, the hair-damaging function of the hair is exerted.

The method for producing the bast / compactible silica particles is not particularly limited, and a known method can be used.

The oil absorption of the silica is preferably 100 mL / 100 g or more, more preferably 150 mL / 100 g or more, further preferably 200 mL / 100 g or more, preferably 1000 mL / 100 g or less, more preferably 800 mL / Is not more than 700 mL / 100 g. When the oil absorption amount of the silica is not less than the lower limit and not more than the upper limit, the initial recovery power, the corrective holding power and the reverberation are further improved. The oil absorption amount is measured in accordance with the method described in JIS K5101.

Examples of commercially available products of the silica include commercially available products such as "Silica 320", trade name "Sarisia 310P", trade name "Sarisia 250", trade name "Sarisia 250N", trade name " Quot; Syriacia 350 &quot;, trade name &quot; Syriacia 440 &quot;, trade name &quot; Syriacia 450 &quot;, trade name &quot; Lycia 470 &quot;; AEROSIL 50 ", trade name" AEROSIL 90G ", trade name" AEROSIL 130 ", trade name" AEROSIL 150 ", trade name" AEROSIL 200 ", trade name" AEROSIL 50 "manufactured by Nippon Aerosil Co., 300 ", trade name" Aerosil 380 ", trade name" Aerosil 200V "and trade name" Aerosil OX50 "; And a trade name &quot; Sun Spear H-201 &quot;, trade name &quot; Sun Spear H-51 &quot;, trade name &quot; Sun Spear H- SunSpher H-52 ", trade name" SunSpher H-122 ", trade name" SunSpher H-33 "and trade name" SunSpher H-53 "; Trade name &quot; Aerosil R972 &quot;, trade name &quot; Aerosil R974 &quot;, trade name &quot; Aerosil R9200 &quot;, manufactured by Nippon Aerosil Co., Ltd., dimethylsiloxylated silicic anhydride, Trade name &quot; Aerosil RX300 &quot;, trade name &quot; Aerosil R812S &quot;, trade name &quot; Trade name &quot; Aerosil R805 &quot;, manufactured by Nippon Aerosil Co., Ltd., which is octylsiloxylated silicic anhydride; AEROSIL RY200 ", trade name" AEROSIL RY200S "and trade name" AEROSIL RY300 "manufactured by Nippon Aerosil Co., Trade name &quot; Sun Spear H-52-ET &quot;, manufactured by AGC Esotech Co., Ltd., which is a silicate-treated silicic anhydride; Trade name &quot; Aerosil R711 &quot;, manufactured by Nippon Aerosil Co., Ltd., which is methacrylsiloxylated silicic anhydride; The above bibulous silica can be obtained by mixing the above-mentioned disintegrative silica with a silica gel beads SB-705 manufactured by Miyoshi Kasei Sangyo Co., Ltd., a trade name of "Goatball AF-6C" .

<Calcium carbonate>

The above-mentioned calcium carbonate is represented, for example, by the INCI name &quot; CALCIUM CARBONATE &quot;. The calcium carbonate may be used alone or in combination of two or more. Commercially available products of the above-mentioned calcium carbonate include, for example, trade name "Kalmar SCS M5", manufactured by SAKAI CHEMICAL INDUSTRIES, LTD .; Manufactured by Shiraishi Calcium Co., Ltd., trade name &quot; FUWALK &quot;, and the like.

<Magnesium carbonate>

The above-mentioned magnesium carbonate is represented, for example, by the INCI name &quot; MAGNESIUM CARBONATE &quot;. The above-mentioned magnesium carbonate may be used alone, or two or more of them may be used. As a commercially available product of the above-mentioned magnesium carbonate, for example, a trade name "hard magnesium carbonate" manufactured by Tomita Seiyaku Co., Ltd. and the like can be mentioned.

&Lt; Hydroxyapatite >

The hydroxyapatite is represented, for example, by the INCI name &quot; HYDROXYAPATITE &quot;. The hydroxyapatite may be used alone or in combination of two or more.

The hydroxyapatite is not particularly limited and includes, for example, spherical hydroxyapatite, plate-shaped hydroxyapatite, and amorphous hydroxyapatite. Among them, spherical hydroxyapatite is preferable from the standpoint of exhibiting high performance of the treatment. HAP-100 ", trade name" HAP-200 "and trade name" HAP-300 "(trade name, manufactured by Daihige Chemical Industries, Ltd.) &Quot; and the like.

<Titanium oxide>

The titanium oxide is represented, for example, by the INCI name &quot; TITANIUM DIOXIDE &quot;. The titanium oxide is not particularly limited and may be, for example, particulate titanium oxide or pigment titanium. The titanium oxide may be used alone or in a combination of two or more. Examples of commercially available titanium oxide include trade name "TTO-55 (A)" and trade name "CR-50" manufactured by Ishihara Sangyo Co.,

<Zinc Oxide>

The zinc oxide is represented, for example, by the INCI name &quot; ZINC OXIDE &quot;. The zinc oxide may be used alone, or two or more zinc oxides may be used. Examples of commercial products of zinc oxide include trade name "FINEX-30S-LP2" manufactured by SAKAI CHEMICAL CO., LTD.

<Calcium silicate>

The calcium silicate is represented, for example, by the INCI name &quot; CALCIUM SILICATE &quot;. The calcium silicate may be used alone or in combination of two or more. Commercially available products of the above calcium silicate include, for example, trade names &quot; Flowlight R &quot; Trade name &quot; Joon Notlite Powder XJ &quot;, trade name &quot; Tobermorite Powder TK &quot;, manufactured by Nihon Insulation Co., Ltd., and the like.

<Magnesium Silicate>

The magnesium silicate is expressed, for example, by the INCI name &quot; MAGNESIUM SILICATE &quot;. The magnesium silicate may be used alone or in combination of two or more. As a commercially available product of the magnesium silicate, for example, a trade name "magnesium silicate (hard)" manufactured by Tomita Seiyaku Co., Ltd. and the like can be mentioned.

<Aluminum silicate>

The aluminum silicate is represented, for example, by the INCI name &quot; ALUMINUM SILICATE &quot;. The aluminum silicate may be used alone, or two or more aluminum silicate may be used. Although aluminum silicate is not particularly limited, synthetic aluminum silicate is preferable. Examples of the synthesis method include a method of adding Na ₂ SiO ₃ to alum and drying the resulting precipitate, a method of producing a silicate sol by electrodialysis to thereby produce a gel, and a method of producing an aqueous solution of an aluminum salt And the like. As a commercially available product of the aluminum silicate, for example, trade name "synthetic aluminum silicate (heavy)" manufactured by Tomita Seiyaku Co., Ltd. and the like can be mentioned.

<Magnesium hydroxide>

The magnesium hydroxide is represented, for example, by the INCI name &quot; MAGNESIUM HYDROXIDE &quot;. The magnesium hydroxide may be used alone or in combination of two or more. As a commercially available product of the above-mentioned magnesium hydroxide, for example, a trade name "magnesium hydroxide (heavy)" manufactured by Tomita Seiyaku Co., Ltd. and the like can be mentioned.

The content of the above-mentioned component (A) in 100% by mass of the inventive cleaning agent composition is 0.1% by mass or more, preferably 0.5% by mass or more, more preferably 1% by mass or more and 10% By mass or less, more preferably 5% by mass or less. When the content of the component (A) is less than the lower limit described above, an initial repulsive force to erect the hair immediately after the correct hair is further imparted, the hair that has been correctly hair can be further maintained, and the stickiness can be further suppressed. When the content of the component (A) is not more than the upper limit, occurrence of flaking can be further suppressed. The content of the component (A) is the total amount of the contents of all the components (A) in the tablet composition according to the present invention. The content of the silica in the 100% by mass of the inventive tablet composition according to the present invention is not particularly limited and may be selected from the group consisting of calcium carbonate, magnesium carbonate, hydroxyapatite, titanium oxide, zinc oxide, calcium silicate, magnesium silicate, aluminum silicate, The content of the selected particles (total content) is 0.1 mass% or more, preferably 0.5 mass% or more, more preferably 1 mass% or more, 10 mass% or less, preferably 7 mass% or less, Is not more than 5% by mass.

(Component (B), component (C), component (D)),

The component (B) is a polyethylene glycol having a number average molecular weight of 150 or more and 450 or less. The component (C) is a polyethylene glycol having a number average molecular weight of 550 or more and 2000 or less. The component (D) is a polyethylene glycol having a number average molecular weight of 2500 or more and 4000 or less. The component (B), the component (C) and the component (D) each have a role of effectively increasing initial repulsive force and regular retention force. The polyethylene glycol to be used in combination with the component (A) is the component (B), the component (C) and the component (D) having a number average molecular weight within a specific range, thereby suppressing the occurrence of flaking , The hair can be firmly tidied and the cleaning property after the hair treatment can be improved. The component (B), the component (C) and the component (D) may each be used alone or two or more thereof may be used.

The content of the component (B) in 100% by mass of the inventive purifier composition is preferably more than 0% by mass, more preferably not less than 0.5% by mass, more preferably not less than 1% by mass, and preferably not more than 15% , And more preferably 12 mass% or less. When the content of the component (B) is lower than the lower limit described above, occurrence of flaking can be further suppressed, and the hair can be more evenly arranged. When the content of the component (B) is not more than the upper limit, tackiness can be further suppressed. The content of the component (B) is the total amount of the components (B) in the tablet composition according to the present invention.

The content of the above-mentioned component (C) in 100% by mass of the inventive purifier composition is more than 0% by mass, preferably not less than 0.5% by mass, more preferably not less than 1% by mass, and preferably not more than 10% , More preferably not more than 8 mass%. When the content of the component (C) is lower than the lower limit described above, the initial repulsive force can be effectively increased and the flaking can be further suppressed. When the content of the component (C) is not more than the upper limit, tackiness can be further suppressed. The content of the component (C) is the total amount of the components (C) in the tablet composition according to the present invention.

The content of the component (D) in 100% by mass of the inventive cleaning agent composition is more than 0% by mass, preferably not less than 0.5% by mass, more preferably not less than 1% by mass, preferably not more than 12% by mass , And more preferably 10 mass% or less. When the content of the component (D) is less than the lower limit described above, the constant-holding power can be effectively increased. When the content of the component (D) is not more than the upper limit, stickiness and flaking can be further suppressed. The content of the component (D) is the total amount of the contents of all the components (D) in the tablet composition according to the present invention.

The ratio of the content of the component (A) to the total content of the component (B), the component (C) and the component (D) in the stabilizer composition according to the present invention : The total content of the component (B), the component (C) and the component (D)) is preferably 1: 2 to 1:25, and more preferably 1: 3 to 1:20. When the content of the component (A) is relatively large, the initial repulsive force for standing the hair becomes even better. When the total content of the component (B), the component (C) and the component (D) is relatively large, the elasticity of the hair is further improved. Wherein the mass ratio of the silica content to the total content of the component (B), the component (C) and the component (D) and the mass ratio of the calcium carbonate, magnesium carbonate, hydroxyapatite, titanium oxide, zinc oxide, calcium silicate, The mass ratio of the content (total content) of the particles selected from the group consisting of magnesium silicate, aluminum silicate and magnesium hydroxide to the total content of the component (B), the component (C) and the component (D) : 2 to 1:25, and more preferably 1: 3 to 1:20.

The content of the component (B) in the 100% by weight of the total content of the component (B), the component (C) and the component (D) in the conditioner composition according to the present invention is preferably 10% , Preferably 80 mass% or less, and the content of the component (C) is preferably 10 mass% or more, preferably 80 mass% or less, and the content of the component (D) is preferably 10 mass% , Preferably 80 mass% or less. The content of each of the component (B), the component (C), and the component (D) is lower than or equal to the lower limit and higher than or equal to the upper limit so as to further enhance the initial repulsive force and corrective holding power, , And the hair can be more resiliently arranged.

(Component (E))

The component (E) is a clay mineral. By the use of the component (E), the initial repulsive force and the storage stability of the stabilizer composition are further improved. The component (E) may be used alone, or two or more thereof may be used.

The component (E) may be a natural product or a compound. Examples of the component (E) include, but are not limited to, kaolin clay minerals, antigorite clay minerals, pyrophyllite clay minerals, mica clay minerals, smectite clay minerals, vermiculite clay minerals, Clay minerals and organic modified clay minerals.

Examples of the kaolin clay minerals include kaolin, nacrite, dickite, and halloysite. Examples of the above-mentioned antigorite clay minerals include antigorite, imidesite and kronostate. Examples of the pyrophyllite clay minerals include pyrophyllite and talc (talc). Examples of the mica clay minerals include ilite, seaweed, seladonite, selissite, mica (mica), muscovite, chromite muscovite and biotite. Examples of the smectite clay minerals include bentonite, montmorillonite, beidellite, nontonite, saponite, hectorite and lucentite. Examples of the vermiculite clay minerals include vermiculite and the like. Examples of the chlorite-based clay minerals include chlorite (chlorite) and the like. Examples of the organically modified clay minerals include organic modified clay minerals obtained by organic modification treatment of smectite clay minerals or vermiculite clay minerals. For the organic modification treatment, a quaternary ammonium salt type cationic surfactant is suitably used. Examples of the quaternary ammonium salt type cationic surfactant include alkyl trimethylammonium chloride, dialkyldimethylammonium chloride, and benzalkonium chloride.

From the viewpoint of further improving the initial repulsive force to erect the hair, and from the viewpoint of further improving the storage stability and feeling of use of the composition, the component (E) is a clay mineral selected from the group consisting of synthetic silicates and derivatives thereof . The synthetic silicate and derivative thereof refer not to a silicate mineral mainly composed of magnesium silicate or silicate (sodium / magnesium) derived from naturally occurring impurities, but also to silicates and silicate derivatives obtained by synthesis.

Examples of the synthetic silicate and derivatives thereof include synthetic silicate (sodium / aluminum silicate) represented by INCI name (International Cosmetic Ingredient Dictionary and Handbook, 14th Edition, CTFA, 2012, p.3076) Magnesium fluoride, INCI name (International Cosmetic Ingredient Dictionary and Handbook, 14th Edition, Volume 2, CTFA, 2012, p.1793): Magnesium fluorosilicate, INCI name (MAGNESIUM FLUOROSILICATE) (Sodium / Magnesium), INCI (International Cosmetic Ingredient Dictionary and Handbook, 14th edition, 2nd edition, CTFA, 2012, p.3076): SODIUM MAGNESIUM FLUOROSILICATE (International Cosmetic Ingredient Dictionary and Handbook, 14th Edition, Vol. 2, CTFA, 2012, p. 1799): MAGNESIUM POTASSIUM FLUOROSILICATE, fluorosilicic acid (magnesium / potassium) p.1800): Marked as MAGNESIUM SODIUM FLUOROSILICATE Synthetic aluminosilicates such as fluorosilicic acid (magnesium / sodium), INCI name (International Cosmetic Ingredient Dictionary and Handbook, 14th edition, Vol. 1, CTFA, 2012, page 156): ALUMINUM SILICATE have.

As the component (E), clay minerals (at least one clay mineral) selected from the group consisting of synthetic silicic acid (sodium / magnesium) and fluorosilicic acid (sodium / magnesium) are particularly preferable.

Commercially available products of the above component (E) include, for example, trade name "Laponite XLG" and trade name "Laponite XL21" manufactured by Roquewood.

The content of the component (E) in 100% by mass of the composition of the present invention is preferably 0.1% by mass or more, more preferably 0.3% by mass or more, preferably 10% by mass or less, % Or less. When the content of the component (E) is lower than the lower limit, the initial repulsive force is further improved. When the content of the component (E) is not more than the upper limit, the preservative stability of the anticorrosive composition is further improved.

(Component (F))

The component (F) is a polysaccharide compound. The use of the component (F) improves the dispersibility of the component (A) because the stabilizer composition is appropriately thickened, and the stabilizer composition is hardly separated and the storage stability is further improved . The above-mentioned component (F) may be used alone, or two or more thereof may be used.

Examples of the component (F) include, but are not limited to, polysaccharides, modified polysaccharides (e.g., alkyl modified polysaccharides) and the like, and examples thereof include alginic acid, carrageenan, agar, perselen, guar gum, Polysaccharide-derived polysaccharide compounds such as konjac mannan, tamarind gum, tara gum, dextrin, starch, locust bean gum, gum arabic, ghatti gum, karaya gum, tragacanth gum, arabinogalactan, pectin and quince; Animal-derived polysaccharide compounds such as chitosan and hyaluronic acid; Polysaccharide-derived polysaccharide compounds such as curdlan, xanthan gum, gellan gum, cyclodextrin, dextran, pullulan and hyaluronic acid; Non-ionic cellulose such as microcrystalline cellulose, methylcellulose, ethylcellulose, hydroxymethylcellulose, hydroxyethylcellulose, hydroxypropylcellulose and hydroxypropylmethylcellulose; Anionic cellulose such as carboxymethylcellulose; Cationized cellulose such as O- [2-hydroxy-3- (trimethylammonio) propyl] hydroxyethylcellulose chloride; And cationized guar gum such as O- [2-hydroxy-3- (trimethylammonio) propyl] guar gum chloride.

As the component (F), a compound (at least one compound) selected from the group consisting of xanthan gum, guar gum, tamarind gum and gellan gum is preferable.

Examples of commercially available products of the above component (F) include trade name "Eco Gum T", trade name "Keldent" and trade name "Monat Gum", manufactured by Dainippon Sumitomo Seiyaku Co., Manufactured by Nippon Kagaku Kogyo Co., Ltd., trade name &quot; Ingel Guar gum CS &quot;; Manufactured by DSP Gokyo Food &amp; Chemical Co., Ltd .; trade name "Glyroid 6C"; CP Kelco U.S., Inc., Gellan Surname. , &Quot; Kerkogel &quot;, and the like.

The content of the above component (F) in 100% by mass of the composition of the present invention is preferably 0.01% by mass or more, more preferably 0.1% by mass or more, preferably 5% by mass or less, % Or less. When the content of the component (F) is not lower than the lower limit described above, the storage stability of the stabilizer composition is further improved. When the content of the component (F) is not more than the upper limit, tackiness is further suppressed. The content of the component (F) is the sum of the contents of all the components (F) in the tablet composition according to the present invention. When the component (F ') is used, the content of the component (F) in 100% by mass of the composition of the present invention may be 0% by mass (unused).

From the viewpoint of further enhancing the storage stability of the stabilizer composition by further increasing the viscosity of the stabilizer composition to an appropriate level and further increasing the initial repulsive force to build up the hair, the stabilizer composition according to the present invention contains the component (E) And the component (F). The dispersion stability of the component (A) is further increased by the combined use of the component (E) and the component (F), so that the purification developer composition is more difficult to be separated.

The mass ratio of the component (E) to the component (F) (content of the component (E): content of the component (F)) in the case of using the component (E) It is preferably 2: 1 to 15: 1, more preferably 2.5: 1 to 10: 1 in 100% by mass of the inventive composition. When the mass ratio is satisfied, the preservative stability of the anticorrosive composition, particularly the storage stability when stored for a long period of time, is further improved.

When the component (E) and the component (F) are used in combination, the total content of the component (E) and the component (F) in the 100% by mass of the composition of the present invention is preferably 0.1% More preferably not less than 0.3% by mass, preferably not more than 15% by mass, and more preferably not more than 7% by mass. When the content of the total amount is higher than or equal to the lower limit and lower than or equal to the upper limit, the storage stability of the stabilizer composition, particularly the storage stability upon storage for a long period of time, is further improved. In addition, the initial recovery power of standing the hair becomes even better.

(Component (F '))

The component (F ') is at least one polymer selected from the group consisting of the component (F'1) and the component (F'2). The use of the component (F ') improves the dispersibility of the component (A) because the stabilizer composition is appropriately thickened, and the stabilizer composition is hardly separated and the storage stability is further improved It becomes. In addition, the regularity is further improved. The component (F ') may be used alone or in combination of two or more. The component (F'1) and the component (F'2) may be used alone or two or more of them may be used.

The monomer component used to obtain the polymer of component (F'1) includes at least two monomers selected from the group consisting of (meth) acrylic acid and (meth) acrylic acid alkyl ester. That is, the component (F'1) is a polymer containing at least two or more structural units selected from the group consisting of a structural unit derived from (meth) acrylic acid and a structural unit derived from a (meth) acrylic acid alkyl ester. In the present specification, the polymer which can correspond to both the component (F'1) and the component (F'2) is not the component (F'1) but the component (F'2).

The component (F'1) is not particularly limited, but may be selected from the group consisting of "ACRYLATES COPOLYMER (Acrylate Aerials)" as INCI name (International Cosmetic Ingredient Dictionary and Handbook, 14th Edition, CTFA, 2012, p.60 to 61) Compound &quot;) is preferred.

Examples of commercial products of the above component (F'1) include trade name "Acculin 33" and trade name "Aculin 33A" manufactured by Dow Chemical Company.

The component (F'1) is not particularly limited, but is preferably neutralized with a basic substance or neutralized with a basic substance. Examples of the basic substance include alkanolamines such as triethanolamine and monoethanolamine; Inorganic base compounds such as ammonia, sodium hydroxide and potassium hydroxide; And basic amino acids such as arginine. The addition amount of the basic substance is an amount sufficient to neutralize the component (F'1) or an amount sufficient to neutralize the component (F'1), and the amount of the basic component And the amount of the component (F'1).

The monomer component used for obtaining the polymer of component (F'2) is at least one monomer component (f2a) selected from the group consisting of (meth) acrylic acid and (meth) acrylic acid alkyl ester, At least one monomer component (f2b) selected from the group consisting of ethylene alkyl ether, itaconic acid polyoxyethylene alkyl ether and neodecanoic acid vinyl. That is, the component (F'2) is a polymer containing at least a constituent unit derived from the monomer component (f2a) and a constituent unit derived from the monomer component (f2b). The monomer component (f2a) and the monomer component (f2b) may be used alone or in a combination of two or more.

As the component (F'2), there is no particular limitation, but "ACRYLATES / STEARETH-20 METHACRYLATE (International Cosmetic Ingredient Dictionary and Handbook, 14th edition, Vol 1, CTFA, 2012, p.66 to 67) COPOLYMER ((acrylate / stearate-20) copolymer) "; Quot; ACRYLATES / STEARETH-20 METHACRYLATE CROSSPOLYMER (Acrylate / Stearate-20 acrylate) &quot; as the INCI name (International Cosmetic Ingredient Dictionary and Handbook, 14th edition, Vol 1, CTFA, 2012, p.67) Polymer &quot;) &quot; "ACRYLATES / BEHENETH-25 METHACRYLATE COPOLYMER (Acrylate / Behen Methacrylate-25)" as INCI name (International Cosmetic Ingredient Dictionary and Handbook, 14th edition, Vol 1, CTFA, 2012, p.57) Compound &quot;); "ACRYLATES / VINYL NEODECANOATE CROSSPOLYMER" (Crosslinked acrylate / neodecanoate) as INCI name (International Cosmetic Ingredient Dictionary and Handbook, 14th edition, Vol. 1, CTFA, 2012, p.68 to 69) &Lt; / RTI &gt; "ACRYLATES / STEARETH-20 ITACONATE COPOLYMER" ("Acrylate / Itaconic Acid-20") copolymer as INCI name (International Cosmetic Ingredient Dictionary and Handbook, 14th Edition, Vol. 1, CTFA, 2012, p.66) ) &Quot; "ACRYLATES / CETETH-20 ITACONATE COPOLYMER (acrylate / itaconate ceteth-20) copolymer" as INCI name (International Cosmetic Ingredient Dictionary and Handbook, 14th edition, Vol. 1, CTFA, 2012, p.60) ) &Quot; and the like are preferable.

Examples of commercially available products of the above component (F'2) include trade name "Acculin 22", trade name "Aculin 88", trade name "Aculin 28" and trade name "Aculin 38", manufactured by Dow Chemical Company; Trade name &quot; STRUCTURE 2001 &quot;, trade name &quot; STRUCTURE 3001 &quot;, manufactured by Akzo Nobel.

The component (F'2) is not particularly limited, but is preferably neutralized with a basic substance or neutralized with a basic substance. As the basic substance in this case, the above-mentioned basic substance can be mentioned. The addition amount of the basic substance is an amount sufficient to neutralize the component (F'2) or an amount sufficient to neutralize the component (F'2), and the amount of the basic component And the amount of the component (F'2).

The content of the component (F ') in 100% by mass of the inventive purifier composition is preferably 0.01% by mass or more, more preferably 0.1% by mass or more, preferably 5% by mass or less, % Or less. When the content of the component (F ') is not lower than the lower limit described above, the storage stability of the stabilizer composition is further improved. When the content of the component (F ') is not more than the upper limit, tackiness is further suppressed. The content of the component (F ') is the total amount of the contents of all the components (F') in the tablet composition according to the present invention. When the component (F) is used, the content of the component (F ') may be 0 mass% (unused) in 100 mass% of the composition of the present invention.

(Other components)

In addition, the cleaning agent composition according to the present invention further suppresses flaking, further improves cleansing properties after cleansing, imparts a better feeling to the hair after cleansing while maintaining a high initial cleansing power, (At least one compound) selected from the group consisting of a polyoxyalkylene alkyl glucoside and a polyoxyalkylene glycerin fatty acid ester may be contained from the viewpoint of being purified to a natural feel (finished state). These compounds may be used alone or in combination of two or more.

Examples of the oxyalkylene group in the polyoxyalkylene alkyl glucoside include an oxyethylene group and an oxypropylene group. The average number of moles of the oxyalkylene group added is not particularly limited, but is preferably 5 or more, and preferably 40 or less. The alkyl group in the polyoxyalkylene alkyl glucoside preferably has 1 to 4 carbon atoms, more preferably 1 to 3 carbon atoms, and is preferably a methyl group or an ethyl group.

Specific examples of the polyoxyalkylene alkyl glucoside include polyoxyethylene methyl glucoside, polyoxyethylene ethyl glucoside, polyoxypropylene methyl glucoside, polyoxypropylene ethyl glucoside, and the like.

The number of carbon atoms in the fatty acid in the polyoxyalkylene glycerin fatty acid ester is preferably 8 or more, and preferably 22 or less. Examples of the oxyalkylene group in the polyoxyalkylene glycerin fatty acid ester include an oxyethylene group and an oxypropylene group. The average addition mole number of the oxyalkylene group is preferably 5 or more, and preferably 40 or less.

The fatty acid is preferably a branched fatty acid, and the polyoxyalkylene glycerin fatty acid ester is preferably a polyoxyalkylene glycerin branched fatty acid ester.

The number of carbon atoms in the branched fatty acid in the polyoxyalkylene glycerin branched fatty acid ester is preferably 8 or more, and preferably 22 or less. Examples of the branched fatty acid in the polyoxyalkylene glycerin branched fatty acid ester include 2-ethylhexanoic acid, isononanoic acid, isopalmitic acid and isostearic acid.

As the polyoxyalkylene glycerin branched fatty acid ester, polyoxyethylene glyceryl isostearate is particularly preferable.

Examples of commercial products of the polyoxyalkylene alkyl glucosides include Nippon Petrochemical Co., Ltd., "Nippon Petrochemical Co., Ltd.", "Nippon Petrochemical Co., Ltd." Trade name &quot; Glukam E-10 &quot;, trade name &quot; Glukam E-20 &quot;, manufactured by Noveon; Glucam P-10 &quot; manufactured by Amerchol Corp., and the like.

Examples of commercially available products of the above polyoxyalkylene glycerin fatty acid esters include trade names "NOIGEN GIS-125" manufactured by Dai-ichi Kogyo Seiyaku Co., EMALEX GWIS-120 ", trade name" EMALEX GWIS-125 "and trade name" EMALEX GWIS-130 "manufactured by Nihon Emulsion Co., Ltd., and the like.

The content of the compound selected from the group consisting of the polyoxyalkylene alkyl glucoside and the polyoxyalkylene glycerin fatty acid ester in 100% by mass of the purifier composition according to the present invention is preferably 0.5% by mass or more, more preferably 1% Or more, preferably 20 mass% or less, and more preferably 10 mass% or less. When the content of the compound is lower than the lower limit, the initial repulsive force is further improved, the flaking is further suppressed, and the cleansing properties after purification are further improved. When the content of the compound is not more than the upper limit, a better feeling is given to the hair after regular hair removal. The content of the above compound is the total amount of these compounds in the tablet composition according to the present invention.

(Other components)

The stabilizer composition according to the present invention is not particularly limited, but preferably contains water. The water is not particularly limited as long as it is water used in cosmetics, but purified water is preferable. The content of water in 100 mass% of the antiseptic composition according to the present invention is preferably 20 mass% or more, more preferably 30 mass% or more, preferably 95 mass% or less, more preferably 90 mass% or less.

The stabilizer composition according to the present invention is not particularly limited, but it preferably contains a lower alcohol having 2 to 5 carbon atoms (particularly, ethanol). The content of the lower alcohol (particularly, ethanol) in 100% by mass of the purifier composition according to the present invention is preferably 2% by mass or more, more preferably 5% by mass or more, and preferably 50% by mass or less, 30% by mass or less.

The cleaning agent composition according to the present invention may contain, for example, a surfactant such as a nonionic surfactant, a cationic surfactant and an amphoteric surfactant within a range that does not impair the effect of the present invention; Polyhydric alcohols such as glycerin, 1,3-butylene glycol, propylene glycol, 1,2-butanediol, 1,2-pentanediol, 1,2-hexanediol, ; Higher alcohols having 12 to 18 carbon atoms such as lauryl alcohol, myristyl alcohol, cetyl alcohol, stearyl alcohol, isostearyl alcohol, cetostearyl alcohol and oleyl alcohol; Sugar alcohols such as sorbitol, maltitol and trehalose; Silicone oil; Metal ion sequestrants; Antioxidants; Plant extracts; dyes; Pigments; pH adjusters; Spices; antiseptic; A solvent, and the like.

(Other details of the stabilizer composition)

The properties of the tablet composition according to the present invention are not particularly limited, and examples thereof include a liquid, a gel, a cream, and a solid. Particularly, it is preferable that the stabilizer composition is liquid or gel-like.

The viscosity of the stabilizer composition at 25 ° C is preferably 1000 mPa · s or more, more preferably 2000 mPa · s or more, preferably 100000 mPa · s or less, and furthermore preferably 50000 mPa · s or less. When the viscosity is not less than the lower limit and not more than the upper limit, the coating property is further increased, the occurrence of flaking and tackiness are further suppressed, and the initial repulsive force and the regular retention force are further increased. In the above-described stabilizer composition, since the viscosity is not more than the upper limit, generation of flaking and tackiness can be suppressed even when fluidity is high, and the initial recovery power and the regular holding power can be increased.

The viscosity was measured using a viscometer at a rotational speed of 12 rpm and a rotation time of 1 minute using a No. 4 rotor. As the above-mentioned viscometer, a TV-22 type viscometer manufactured by Ohshiku Co., Ltd. can be used.

The method for producing the stabilizer composition according to the present invention is not particularly limited, and a known method for producing the stabilizer composition can be used as the method for producing the stabilizer composition according to the present invention. The method for producing the stabilizer composition according to the present invention is not particularly limited, and for example, the components (A) and (optionally, the component (E)) are stirred with a dispenser and then exchanged with a paddle mixer And a method of blending and homogenizing other components.

(A) is contained in an amount of 0.1% by mass or less, and the content of the component (A) is 0.1% by mass or less, Or more and 10 mass% or less. The component (E) may be blended, the component (F) may be blended, or the component (F ') may be blended in the method for producing a regular tablet composition according to the present invention.

The propellant composition according to the present invention contains at least a component (A), a component (B), a component (C) and a component (D) as main components. By using the component (A), the component (B), the component (C) and the component (D) in combination, the initial repulsive force of standing the hair is lowered only by the component (B), the component (C) It is possible to increase the initial repulsive force immediately afterwards, to increase the regular retention force, and to suppress the stickiness. By using the component (B), the component (C) and the component (D), it is possible to suppress the occurrence of flaking (a phenomenon in which white powder or a film appears on the hair) Thereby, the use of the tablet composition according to the present invention makes it possible not only to satisfactorily stabilize the hair, but also to maintain the hair straightening state for a long period of time. Further, by using the component (B), the component (C) and the component (D), the cleaning property after the treatment can be improved.

Further, by blending the components selected from the group consisting of the component (E), the component (F) and the component (F '), the stabilizer composition is appropriately thickened to improve the applicability of the stabilizer composition, It is possible to further improve the initial repulsive force. Further, by setting the blending ratio of the component (E) and the component selected from the group consisting of the component (F) and the component (F ') within a specific preferable range, the component (A) precipitates, The storage stability of the composition is improved.

The stabilizer composition according to the present invention is not particularly limited, but can be used in the form filled in a container, for example.

Examples of the container include a bottle container, a self-container, and a tube container. The container is preferably a bottle container or a tube container.

(Example)

Hereinafter, the present invention will be specifically described with reference to examples and comparative examples. The present invention is not limited to the following embodiments.

In the Examples and Comparative Examples, the following components were used.

(Component (A))

Trade name &quot; Sarisia 320 &quot;: silica (manufactured by Fuji Silysia Chemical Industries, Ltd.)

Trade name &quot; Aerosil 200 &quot;: silica (manufactured by Nippon Aerosil Co., Ltd.)

"Hard magnesium carbonate": magnesium carbonate (manufactured by Tomita Seiyaku Co., Ltd.)

&Quot; Conformational HAP &quot;: Hydroxyapatite (manufactured by Daihei Chemical Industry Co., Ltd.)

Trade name &quot; Flowlight R &quot;: calcium silicate (manufactured by Tomita Seiyaku Co., Ltd.)

"Magnesium silicate (hard)": Magnesium silicate (manufactured by Tomita Seiyaku Co., Ltd.)

Synthetic aluminum silicate (heavy) ": Silicate aluminum (manufactured by Tomita Seiyaku Co., Ltd.)

Magnesium hydroxide (heavy): Magnesium hydroxide (manufactured by Tomita Seiyaku Co., Ltd.)

(Component (B))

Trade name &quot; PEG-200 &quot;: polyethylene glycol, number average molecular weight 200 (manufactured by Sanyo Chemical Industries, Ltd.)

Trade name &quot; PEG-400 &quot;: polyethylene glycol, number average molecular weight 400 (manufactured by Sanyo Chemical Industries, Ltd.)

(Component (C))

Trade name &quot; PEG # 1000 &quot;: polyethylene glycol, number average molecular weight 1000 (manufactured by Nichi-

Trade name &quot; PEG-1540 &quot;: polyethylene glycol, number average molecular weight 1540 (manufactured by Sanyo Chemical Industries, Ltd.)

(Component (D))

Trade name &quot; PEG # 4000 &quot;: polyethylene glycol, number average molecular weight 4000 (manufactured by Nichi-

(Component (E))

&Quot; Laponite XL21 &quot;: fluorosilicic acid (sodium / magnesium) (manufactured by Roquewood Co.)

Trade name &quot; Laponite XLG &quot;: Synthetic silicic acid (sodium / magnesium) (manufactured by Roquewood Co.)

(Component (F))

"Eco Gum T": xanthan gum (manufactured by Dainippon Sumitomo Seiyaku Co., Ltd.)

(Component (F '))

(Acrylate / Stearate-20 methacrylate) copolymer, 30 mass% aqueous solution (manufactured by Dow Chemical Co.)

Trade name &quot; Acculin 33A &quot;: acrylate copolymer, 28 mass% aqueous solution (manufactured by Dow Chemical Company)

(Examples 1 to 51 and Comparative Examples 1 to 17)

The formulation ingredients shown in Tables 1 to 6 below were blended (the mixing unit was% by mass) to prepare a stabilizer composition.

The obtained tonicity agent composition was charged into a plastic container to obtain a correcting agent. All the evaluations were carried out under constant conditions of constant temperature and humidity of 23 DEG C and a humidity of 60%. The blending amount in the table is expressed by the actual blending amount (blending amount of the product).

(Test Example 1: Evaluation of initial repulsive force)

Twenty professional panelists uniformly applied the composition of the present invention in the container onto the hair of a wig (lesson mannequin: manufactured by Yukari Japan), and performed hair straightening as if standing the hair from the root portion, and then replied whether or not there was a repulsive force. In addition, the evaluation of the repulsive force was judged to have an initial repulsive force when the shape of the standing hair was hardly maintained. From the answer, the initial repulsive force was evaluated based on the following criteria.

<Evaluation Criteria of Initial Power>

○ (very good): More than 16 out of 20 responded that they had early recovery power

△ (good): 10 to 15 out of 20 responded that they had early reproductive power

× (bad): Less than nine out of 20 responded that they had early recovery power

(Test Example 2: Stickiness and Condition of Hair Conditioning)

Twenty members of the same specialized panel responded to sensory evaluation of the presence or absence of tackiness during the regular test of Test Example 1 and the condition of hair after the treatment. From the answers, stickiness and state of hair arrangement were evaluated based on the following criteria.

<Evaluation criteria of stickiness>

○ (very good): More than 16 out of 20 responded that they are not sticky

△ (Good): 10 to 15 out of 20 responded that they are not sticky

× (bad): Less than 9 out of 20 responded that they are not sticky

<Evaluation Criteria of Hair Condition>

○ (very good): More than 16 out of 20 people have hair resiliently arranged answer

△ (Good): 10-15 people out of 20 answered that hair is arranged firmly

× (bad): Less than nine out of 20 people said hair is resiliently arranged Answer

(Test Example 3: evaluation of retention force)

Twenty members of the same expert panel observed the hair of the wig after the lapse of 1 hour from Test Example 1 (evaluation of the initial repulsive force), and replied whether or not there was a constant retention force. The evaluation of the regular holding power was made by judging that the case where the shape of the standing hair of the test example 1 was continuously maintained was the regular holding power. From the answers, the regular retention force was evaluated based on the following criteria.

<Criteria for Evaluation of Retention Force>

○ (very good): More than 16 out of 20 respondents said that they had regular maintenance

△ (Good): 10 to 15 out of 20 respondents answered that they had a positive remedy

× (bad): Less than nine out of 20 responded

(Test Example 4: evaluation of flaking)

Twenty of the same expert panels combed five times successively from the roots of the hair to the ends of the hair with the fingertips after Test Example 3 (evaluation of regular retention force), and replied whether or not there was flaking. Further, in the case where white powder appeared to be attached on the hair, it was judged that there was flaking. From the answers, flaking was evaluated based on the following criteria.

<Evaluation criteria of flaking>

○ (very good): More than 16 out of 20 responded that there is no play king

△ (Good): 10 to 15 out of 20 responded that there was no play king

× (bad): Less than 9 out of 20 answered that there is no play king

(Test Example 5: evaluation of cleaning property)

Twenty of the same expert panels were used after the test example 4 (evaluation of the flaking), the hair of the wig was cleaned with lukewarm water using a shampoo (trade name "Lucido shampoo", manufactured by Mendumusa), dried, Good or bad). In addition, when there was no discoloration or stickiness of the hair at the time of shaving, it was judged that the cleaning property was good. From the answers, cleaning properties were evaluated according to the following criteria.

&Lt; Evaluation Criteria of Cleanliness &

○ (very good): More than 16 out of 20 responded well

△ (Good): 10 to 15 out of 20 people answered that they had good cleanliness

× (bad): Less than nine out of 20 answered that they are clean

The results are shown in Tables 1 to 6 below. The total of the blending components in each of Examples and Comparative Examples shown in Tables 1 to 6 is 100% by mass.

Claims (7)

Comprising the following component A, the following component B, the following component C, the following component D, the following component E and the following component F,
Wherein the content of the component A is 0.1% by mass or more and 7% by mass or less,
Wherein the mass ratio of the content of the component A to the total content of the component B, the component C, and the component D is 1: 2 to 1:20,
Wherein the mass ratio of the content of the component E to the content of the component F is from 2: 1 to 15: 1.
Component A: particles selected from the group consisting of silica, calcium carbonate, magnesium carbonate, hydroxyapatite, titanium oxide, zinc oxide, calcium silicate, magnesium silicate, aluminum silicate and magnesium hydroxide
Component B: Polyethylene glycol having a number average molecular weight of 150 to 450
Component C: Polyethylene glycol having a number average molecular weight of 550 to 2000
Component D: Polyethylene glycol having a number average molecular weight of 2500 to 4000
Component E: Clay Minerals
Component F: polysaccharide compound delete delete delete delete , The following Component A, the following Component B, the following Component C, the following Component D, the following Component E and the following Component F, wherein the content of the above Component A is from 0.1% by mass to 7% by mass, The mass ratio of the content of A to the total content of the component B, the component C and the component D is 1: 2 to 1:20, the mass ratio of the content of the component E to the content of the component F is 2: 1 to 15: 1. &Lt; / RTI &gt;
Component A: particles selected from the group consisting of silica, calcium carbonate, magnesium carbonate, hydroxyapatite, titanium oxide, zinc oxide, calcium silicate, magnesium silicate, aluminum silicate and magnesium hydroxide
Component B: Polyethylene glycol having a number average molecular weight of 150 to 450
Component C: Polyethylene glycol having a number average molecular weight of 550 to 2000
Component D: Polyethylene glycol having a number average molecular weight of 2500 to 4000
Component E: Clay Minerals
Component F: polysaccharide compound delete