KR20150103232A - Hairstyling composition - Google Patents

Abstract

Provided is a carcass preparation composition capable of suppressing sedimentation of a powder during storage for a long period of time or increasing the storage stability by inhibiting the addition and separation of the composition and suppressing an increase in viscosity to increase spreading and absorbency at the time of coating. The cleaning agent composition according to the present invention comprises particles (component A) selected from the group consisting of silica, calcium carbonate, magnesium carbonate, hydroxyapatite, titanium oxide, zinc oxide, calcium silicate, magnesium silicate, aluminum silicate and magnesium hydroxide, (Component B) and a polysaccharide compound (Component C). In the stabilizer composition according to the present invention, the content of the component A is 0.1% by mass or more and 10% by mass or less, C is in the range of 2: 1 to 10: 1.

Description

HAIRSTYLING COMPOSITION < RTI ID = 0.0 >

The present invention relates to a cleaning agent composition suitably used for a hair conditioner to trim hair.

To prepare the hair, various constipating agent compositions such as liquid, gel, cream, and solid forms are used. Conventionally, a film-forming polymer is often used to impart a repulsive force, which is a main function, to the cleaning composition. However, when an effective amount of the film-forming polymer is blended, there is a problem in that the initial recovery force immediately after the straightening is increased, while the spreadability and absorbability of the stabilizer composition on the hair is deteriorated or stickiness is generated. Further, in the regular-agent composition using the film-forming polymer, a film is formed on the surface of the hair derived from the film-forming polymer after the treatment. For this reason, it is difficult to tune the hair into a natural state, and when the hair is stimulated with a hand or a comb after the hair is cleaned, the film is peeled off from the surface of the hair (so-called flaking occurs) .

In order to solve such a problem, it has been studied to increase the flexibility of a film formed from a film-forming polymer. Patent Document 1 below discusses the use of silicones as a plasticizer in a stabilizer composition containing a film-forming polymer.

Further, a method different from the method of using a film-forming polymer has been studied, and more specifically, it has been studied to impart a repulsive force to a cleaning agent composition using a powder.

The following Patent Document 2 discloses a hair cosmetic composition (regular-charge composition) comprising 0.1 to 10% by mass of a particulate powder having a specific surface area of 50 m ² / g or more. In Patent Document 2, it is described that by using a specific particulate powder at the specified content, a good feeling can be obtained, an excellent power can be obtained, a good feel can be maintained for a long time, and excellent retaliation can be obtained.

Japanese Patent Application Laid-Open No. 2001-240519 Japanese Patent Application Laid-Open No. 2003-342130

In the stabilizer composition described in Patent Document 1, the flexibility of the film derived from the film-forming polymer is increased to some extent. As a result, the feeling of use of the stabilizer composition is improved to some extent. However, there is a problem that the initial repulsive force, which is the main function of the stabilizer composition, is deteriorated as the flexibility of the coating improves. Further, there is also a problem in that the state of constantly being able to be maintained for a long period of time after the correcting operation. That is, when the process is performed by using the tablet composition as described in Patent Document 1, the initial repulsive force and the regular retention force may not be sufficiently increased.

In addition, as described in Patent Document 2, even when the composition is regularly cleaned using the anticorrosive composition containing the fine particle powder, the initial repulsive force and the regular retention force may not be sufficiently increased. Also, flaking may occur, or sticking may occur. Particularly, the stabilizer composition containing the fine particle powder sometimes increases viscosity when stored for a long period of time, and the spreadability and absorbability of the stabilizer composition on the hair tend to deteriorate. Further, in the case of a regular-agent composition containing a fine particle powder, storage of the powder for a long period of time is likely to cause precipitation of the powder or removal of the composition and deterioration of storage stability.

An object of the present invention is to provide a stabilizer composition capable of suppressing the sedimentation of the powder during storage for a long period of time or increasing the storage stability by suppressing the addition and the separation of the composition, will be.

It is a still further object of the present invention to provide a regular-care agent composition which can suppress the occurrence of flaking and tackiness during regular motion, and can increase the initial repulsive force and regular-holding power.

The propellant composition according to the present invention comprises the following components (A), (B) and (C), wherein the content of the component (A) is 0.1% by mass or more and 10% (B) and the content of the component (C) is in the range of 2: 1 to 10: 1.

Component (A): particles selected from the group consisting of silica, calcium carbonate, magnesium carbonate, hydroxyapatite, titanium oxide, zinc oxide, calcium silicate, magnesium silicate, aluminum silicate and magnesium hydroxide

Component (B): Clay mineral

Component (C): polysaccharide compound

In the conditioner composition according to the present invention, it is preferable that the total content of the component (B) and the component (C) is 0.3% by mass or more and 5% by mass or less.

The stabilizer composition according to the present invention preferably further comprises the following component (D).

Component (D): Polyethylene glycol

The stabilizer composition according to the present invention preferably further comprises the following component (E).

Component (E): a compound selected from the group consisting of a polyoxyalkylene alkyl glucoside and a polyoxyalkylene glycerin fatty acid ester

The present composition contains the specific components (A), (B) and (C), and the content of the component (A) is within a specific range, and the content of the component (B) Since the mass ratio of the content is a specific ratio, sedimentation of the powder at the time of storage for a long period of time or inhibition of addition and separation of the composition can be suppressed to increase the storage stability and increase viscosity and water absorption at the time of coating.

Hereinafter, the present invention will be described in detail.

The cleaning agent composition according to the present invention comprises particles selected from the group consisting of silica, calcium carbonate, magnesium carbonate, hydroxyapatite, titanium oxide, zinc oxide, calcium silicate, magnesium silicate, aluminum silicate and magnesium hydroxide, Polysaccharide compounds.

In the present specification, "particles selected from the group consisting of silica, calcium carbonate, magnesium carbonate, hydroxyapatite, titanium oxide, zinc oxide, calcium silicate, magnesium silicate, aluminum silicate and magnesium hydroxide" . Further, the " clay mineral " may be referred to as " component (B) ". The "polysaccharide compound" may also be referred to as "component (C)".

It is preferable that the stabilizer composition according to the present invention further comprises polyethylene glycol. In the present specification, the above-mentioned " polyethylene glycol " is sometimes referred to as " component (D) ".

Preferably, the orthostatic composition according to the present invention further comprises a compound selected from the group consisting of a polyoxyalkylene alkyl glucoside and a polyoxyalkylene glycerin fatty acid ester.

In the present specification, the "compound selected from the group consisting of polyoxyalkylene alkyl glucosides and polyoxyalkylene glycerin fatty acid esters" is sometimes referred to as "component (E)". The "polyoxyalkylene alkyl glucoside" may be referred to as "component (E1)" in some cases, and the "polyoxyalkylene glycerin fatty acid ester" may be referred to as "component (E2)" in some cases.

As described above, the detergent composition according to the present invention contains at least the component (A), the component (B) and the component (C). It is preferable that the stabilizer composition according to the present invention further comprises a component (at least one component) selected from the group consisting of the component (D) and the component (E). Among them, the stabilizer composition according to the present invention preferably contains both of component (A), component (B), component (C), component (D) and component (E). The tonicity agent composition according to the present invention may further contain other components. The above components, for example, the component (A), the component (B), the component (C), the component (D) and the component (E) or the other components may be used alone or two or more thereof may be used.

The component (E) is a compound (at least one compound) selected from the group consisting of the component (E1) and the component (E2). Either one of the components (E1) and (E2) may be used, or two or more of them may be used.

Hereinafter, details of each component used in the cleaning composition of the present invention will be described.

(Component (A))

The component (A) is a particle selected from the group consisting of silica, calcium carbonate, magnesium carbonate, hydroxyapatite, titanium oxide, zinc oxide, calcium silicate, magnesium silicate, aluminum silicate and magnesium hydroxide. The component (A) mainly has a role of suppressing tackiness and enhancing the initial repulsive force and the regular retention force. Further, by using the above-mentioned component (A), it is possible to easily perform repetitive refinement once the refinement is once performed, and to improve the reverberation, as compared with the case where the film-forming polymer is used.

As the above-mentioned component (A), particles (at least one particle) selected from the group consisting of silica, calcium carbonate, hydroxyapatite, calcium silicate, magnesium silicate and aluminum silicate are preferable from the standpoint of improving the purification performance , Particles of silica (at least one particle) selected from the group consisting of silica and magnesium silicate are more preferable. The above-mentioned component (A) may be used alone, or two or more thereof may be used.

<Silica>

As the silica, known silica (silicic anhydride) can be used. The silica may be anhydrous silicic acid (hydrophilic silica) not subjected to hydrophobic treatment, or may be hydrophobic silicic anhydride. Further, the surface-treated silica may be an amino acid, ester, lecithin or the like. Further, the silica may be a so-called collapsible silica particle. The silica may be used alone or in combination of two or more.

The hydrophobic silicic anhydride is a material obtained by subjecting anhydrous silicic acid (for example, anhydrous silicic anhydride) to hydrophobic treatment. Examples of the treatment agent used in the hydrophobic treatment include an organosilyl compound and a silicone compound. Examples of the organosilyl compound include methyltrichlorosilane, dimethyldichlorosilane, trimethylchlorosilane, hexamethyldisilazane, methyltrialkoxysilane, dimethyl dialkoxysilane, trimethylalkoxysilane, ethyltrichlorosilane, propyltrichlorosilane, hexyl Long chain alkyl trichlorosilane, long chain alkyl trichlorosilane, ethyl trialkoxy silane, propyl trialkoxy silane, hexyl trialkoxy silane, long chain alkyl trialkoxy silane, methacryl silane, fluoroalkyl silane and perfluoroalkyl silane . Examples of the silicone compound include dimethylpolysiloxane (silicone oil), methylphenylpolysiloxane, methylhydrogenpolysiloxane and amino-modified silicone. As a method of the hydrophobic treatment, a known method can be employed. Examples of the hydrophobic treatment method include a liquid phase method, a vapor phase method, and an autoclave method.

Preferred examples of the hydrophobic silicic anhydride include dimethylsiloxylated silicic anhydride, trimethylsiloxylated silicic anhydride, octylsiloxylated silicic anhydride, silicon oil-treated silicic anhydride and methacrylosiloxylated silicic anhydride.

The bast / compactible silica particles are particles formed by aggregating a plurality of primary silica particles. Examples of the silica primary particles include, but are not limited to, spherical silica particles, phosphorus-based silica particles, and amorphous silica particles. The average particle diameter of the silica primary particles is not particularly limited.

The diblock compacted silica particles may contain components other than silica. The component other than the silica (hereinafter sometimes referred to as "inclusion component") is not particularly limited, and examples thereof include surfactants, polyhydric alcohols, higher alcohols, sugar alcohols, silicone oils, sequestering agents, Plant extracts, dyes, pigments, fragrances, moisturizers, vitamins, amino acids, and refreshing agents. Among them, amino acids, silicone oil and vitamins are preferable. Examples of the amino acids include, but are not limited to, dilauroyl glutamate lysine Na (e.g., trade name &quot; Perichea &quot;, manufactured by Asahi Kasei Chemicals Co., Ltd.), trimethylglycine and glutamic acid. When the biodestructured silica particles contain the inclusion component, the inclusion component is released when the biodisolidized silica particles collapse at the time of purification, and an effect depending on the type of inclusion component is exerted. For example, when the biodisolidized silica particles contain amino acids, the hair-damaging function of the hair is exerted.

The method for producing the bast / compactible silica particles is not particularly limited, and a known method can be used.

The oil absorption of the silica is preferably 100 mL / 100 g or more, more preferably 150 mL / 100 g or more, further preferably 200 mL / 100 g or more, preferably 1000 mL / 100 g or less, more preferably 800 mL / Is not more than 700 mL / 100 g. When the oil absorption amount of the silica is not less than the lower limit and not more than the upper limit, the initial recovery power, the corrective holding power and the reverberation are further improved. The oil absorption amount is measured in accordance with the method described in JIS K5101.

Examples of commercially available products of the silica include commercially available products such as "Silica 320", trade name "Sarisia 310P", trade name "Sarisia 250", trade name "Sarisia 250N", trade name " Quot; Syriacia 350 &quot;, trade name &quot; Syriacia 440 &quot;, trade name &quot; Syriacia 450 &quot;, trade name &quot; Lycia 470 &quot;; AEROSIL 50 ", trade name" AEROSIL 90G ", trade name" AEROSIL 130 ", trade name" AEROSIL 150 ", trade name" AEROSIL 200 ", trade name" AEROSIL 50 "manufactured by Nippon Aerosil Co., 300 ", trade name" Aerosil 380 ", trade name" Aerosil 200V "and trade name" Aerosil OX50 "; And a trade name &quot; Sun Spear H-201 &quot;, trade name &quot; Sun Spear H-51 &quot;, trade name &quot; Sun Spear H- SunSpher H-52 ", trade name" SunSpher H-122 ", trade name" SunSpher H-33 "and trade name" SunSpher H-53 "; Trade name &quot; Aerosil R972 &quot;, trade name &quot; Aerosil R974 &quot;, trade name &quot; Aerosil R9200 &quot;, manufactured by Nippon Aerosil Co., Ltd., dimethylsiloxylated silicic anhydride, Trade name &quot; Aerosil RX300 &quot;, trade name &quot; Aerosil R812S &quot;, trade name &quot; Trade name &quot; Aerosil R805 &quot;, manufactured by Nippon Aerosil Co., Ltd., which is octylsiloxylated silicic anhydride; AEROSIL RY200 ", trade name" AEROSIL RY200S "and trade name" AEROSIL RY300 "manufactured by Nippon Aerosil Co., Trade name &quot; Sun Spear H-52-ET &quot;, manufactured by AGC Esotech Co., Ltd., which is a silicate-treated silicic anhydride; Trade name &quot; Aerosil R711 &quot;, manufactured by Nippon Aerosil Co., Ltd., which is methacrylsiloxylated silicic anhydride; Silica beads SB-705, manufactured by Miyoshi Kasei Co., Ltd., which is a biodossible silica; Trade name &quot; GAGBOL AF-16C &quot;, trade name &quot; GAGBOL AF-6C &quot;, manufactured by SUZUKI YUSHI CHEMICAL CO., LTD.

<Calcium carbonate>

The above-mentioned calcium carbonate is represented, for example, by the INCI name &quot; CALCIUM CARBONATE &quot;. The calcium carbonate may be used alone or in combination of two or more. Commercially available products of the above-mentioned calcium carbonate include, for example, trade name "Kalmar SCS M5", manufactured by SAKAI CHEMICAL INDUSTRIES, LTD .; Manufactured by Shiraishi Calcium Co., Ltd., trade name &quot; FUWALK &quot;, and the like.

<Magnesium carbonate>

The above-mentioned magnesium carbonate is represented, for example, by the INCI name &quot; MAGNESIUM CARBONATE &quot;. The above-mentioned magnesium carbonate may be used alone, or two or more of them may be used. As a commercially available product of the above-mentioned magnesium carbonate, for example, a trade name "hard magnesium carbonate" manufactured by Tomita Seiyaku Co., Ltd. and the like can be mentioned.

&Lt; Hydroxyapatite >

The hydroxyapatite is represented, for example, by the INCI name &quot; HYDROXYAPATITE &quot;. The hydroxyapatite may be used alone or in combination of two or more.

The hydroxyapatite is not particularly limited and includes, for example, spherical hydroxyapatite, plate-shaped hydroxyapatite, and amorphous hydroxyapatite. Among them, spherical hydroxyapatite is preferable from the standpoint of exhibiting high performance of the treatment. HAP-100 ", trade name" HAP-200 "and trade name" HAP-300 "(trade name, manufactured by Daihige Chemical Industries, Ltd.) &Quot; and the like.

<Titanium oxide>

The titanium oxide is represented, for example, by the INCI name &quot; TITANIUM DIOXIDE &quot;. The titanium oxide is not particularly limited and may be, for example, particulate titanium oxide or pigment titanium. The titanium oxide may be used alone or in a combination of two or more. Examples of commercially available titanium oxide include trade name "TTO-55 (A)" and trade name "CR-50" manufactured by Ishihara Sangyo Co.,

<Zinc Oxide>

The zinc oxide is represented, for example, by the INCI name &quot; ZINC OXIDE &quot;. The zinc oxide may be used alone, or two or more zinc oxides may be used. Examples of commercial products of zinc oxide include trade name "FINEX-30S-LP2" manufactured by SAKAI CHEMICAL CO., LTD.

<Calcium silicate>

The calcium silicate is represented, for example, by the INCI name &quot; CALCIUM SILICATE &quot;. The calcium silicate may be used alone or in combination of two or more. Commercially available products of the above calcium silicate include, for example, trade names &quot; Flowlight R &quot; Trade name &quot; Joon Notlite Powder XJ &quot;, trade name &quot; Tobermorite Powder TK &quot;, manufactured by Nihon Insulation Co., Ltd., and the like.

<Magnesium Silicate>

The magnesium silicate is expressed, for example, by the INCI name &quot; MAGNESIUM SILICATE &quot;. The magnesium silicate may be used alone or in combination of two or more. As a commercially available product of the magnesium silicate, for example, a trade name "magnesium silicate (hard)" manufactured by Tomita Seiyaku Co., Ltd. and the like can be mentioned.

<Aluminum silicate>

The aluminum silicate is represented, for example, by the INCI name &quot; ALUMINUM SILICATE &quot;. The aluminum silicate may be used alone, or two or more aluminum silicate may be used. Although aluminum silicate is not particularly limited, synthetic aluminum silicate is preferable. Examples of the synthesis method include a method of adding Na ₂ SiO ₃ to alum and drying the resulting precipitate, a method of producing a silicate sol by electrodialysis to thereby produce a gel, and a method of producing an aqueous solution of an aluminum salt And the like. As a commercially available product of the aluminum silicate, for example, trade name "synthetic aluminum silicate (heavy)" manufactured by Tomita Seiyaku Co., Ltd. and the like can be mentioned.

<Magnesium hydroxide>

The magnesium hydroxide is represented, for example, by the INCI name &quot; MAGNESIUM HYDROXIDE &quot;. The magnesium hydroxide may be used alone or in combination of two or more. As a commercially available product of the above-mentioned magnesium hydroxide, for example, a trade name "magnesium hydroxide (heavy)" manufactured by Tomita Seiyaku Co., Ltd. and the like can be mentioned.

The content of the above-mentioned component (A) in 100% by mass of the inventive cleaning agent composition is 0.1% by mass or more, preferably 0.5% by mass or more, more preferably 1% by mass or more and 10% By mass or less, more preferably 5% by mass or less. When the content of the component (A) is less than the lower limit described above, the initial recovery force immediately after the straightening can be increased, the constant holding force can be increased, and the tackiness can be suppressed. When the content of the component (A) is not more than the upper limit, occurrence of flaking can be suppressed. The content of the component (A) is the total amount of the contents of all the components (A) in the tablet composition according to the present invention. The content of the silica in 100 mass% of the inventive tablet composition according to the present invention and the content of the silica selected from the group consisting of calcium carbonate, magnesium carbonate, hydroxyapatite, titanium oxide, zinc oxide, calcium silicate, magnesium silicate, aluminum silicate and magnesium hydroxide The content of the particles (total content) is 0.1 mass% or more, preferably 0.5 mass% or more, more preferably 1 mass% or more and 10 mass% or less, preferably 7 mass% or less, % Or less.

(Component (B))

The component (B) is a clay mineral. By the use of the above-mentioned component (B), the component (B) and the component (C) are used in combination with each other, whereby the stabilizer composition is appropriately thickened. Thus, the dispersibility of the component (A) The addition and separation of the composition are suppressed, and the storage stability is further improved. In addition, it is possible to suppress the increase in viscosity of the regular-care agent composition and to improve the spreading and absorbency at the time of coating. The above-mentioned component (B) may be used alone, or two or more thereof may be used.

The component (B) may be a natural product or a compound. Examples of the component (B) include, but are not limited to, kaolin clay minerals, antigorite clay minerals, pyrophyllite clay minerals, mica clay minerals, smectite clay minerals, vermiculite clay minerals, Clay minerals and organic modified clay minerals.

Examples of the kaolin clay minerals include kaolin, nacrite, dickite, and halloysite. Examples of the above-mentioned antigorite clay minerals include antigorite, imidesite and kronostate. Examples of the pyrophyllite clay minerals include pyrophyllite and talc (talc). Examples of the mica clay minerals include ilite, seaweed, seladonite, selissite, mica (mica), muscovite, chromite muscovite and biotite. Examples of the smectite clay minerals include bentonite, montmorillonite, beidellite, nontonite, saponite, hectorite and lucentite. Examples of the vermiculite clay minerals include vermiculite and the like. Examples of the chlorite-based clay minerals include chlorite (chlorite) and the like. Examples of the organically modified clay minerals include organic modified clay minerals obtained by organic modification treatment of smectite clay minerals or vermiculite clay minerals. For the organic modification treatment, a quaternary ammonium salt type cationic surfactant is suitably used. Examples of the quaternary ammonium salt type cationic surfactant include alkyl trimethylammonium chloride, dialkyldimethylammonium chloride, and benzalkonium chloride.

From the viewpoint of further improving the storage stability and feeling of use of the regular-charge composition, the component (B) is preferably a clay mineral selected from the group consisting of a synthetic silicate and a derivative thereof. The synthetic silicate and derivative thereof refer not to a silicate mineral mainly composed of magnesium silicate or silicate (sodium / magnesium) derived from naturally occurring impurities, but also to silicates and silicate derivatives obtained by synthesis.

Examples of the synthetic silicate and derivatives thereof include synthetic silicate (sodium / aluminum silicate) represented by INCI name (International Cosmetic Ingredient Dictionary and Handbook, 14th Edition, CTFA, 2012, p.3076) Magnesium fluoride, INCI name (International Cosmetic Ingredient Dictionary and Handbook, 14th Edition, Volume 2, CTFA, 2012, p.1793): Magnesium fluorosilicate, INCI name (MAGNESIUM FLUOROSILICATE) (Sodium / Magnesium), INCI (International Cosmetic Ingredient Dictionary and Handbook, 14th edition, 2nd edition, CTFA, 2012, p.3076): SODIUM MAGNESIUM FLUOROSILICATE (International Cosmetic Ingredient Dictionary and Handbook, 14th Edition, Vol. 2, CTFA, 2012, p. 1799): MAGNESIUM POTASSIUM FLUOROSILICATE, fluorosilicic acid (magnesium / potassium) p.1800): Marked as MAGNESIUM SODIUM FLUOROSILICATE Synthetic aluminosilicates such as fluorosilicic acid (magnesium / sodium), INCI name (International Cosmetic Ingredient Dictionary and Handbook, 14th edition, Vol. 1, CTFA, 2012, page 156): ALUMINUM SILICATE have.

As the component (B), clay minerals (at least one clay mineral) selected from the group consisting of synthetic silicic acid (sodium / magnesium) and fluorosilicic acid (sodium / magnesium) are particularly preferable.

Examples of commercially available products of the above component (B) include trade name "Laponite XLG" and trade name "Laponite XL21" manufactured by Lockwood Co., Ltd.

The content of the component (B) in 100% by mass of the composition of the present invention is preferably 0.1% by mass or more, more preferably 0.3% by mass or more, preferably 5% by mass or less, % Or less. When the content of the component (B) is not lower than the lower limit described above, the precipitation of the component (A) is further suppressed, and the separation of the composition is suppressed, whereby the storage stability is further improved. When the content of the component (B) is not more than the upper limit, increase in viscosity is suppressed, and spreadability and water absorbency at the time of coating are further improved. The content of the component (B) is the total amount of the components (B) in the tablet composition according to the present invention.

(Component (C))

The component (C) is a polysaccharide compound. By the use of the above-mentioned component (C), the component (C) and the component (B) are used in combination with each other, whereby the stabilizer composition is appropriately thickened and the dispersibility of the component (A) The addition and separation of the composition are suppressed, and the storage stability is further improved. Further, it is possible to suppress the increase in the viscosity of the stabilizer composition and to improve the spreading and absorbency at the time of coating. The above-mentioned component (C) may be used alone, or two or more thereof may be used.

The component (C) is not particularly limited, but polysaccharides and modified polysaccharides (for example, alkyl modified polysaccharides and the like) are preferable, and for example, alginic acid, carrageenan, agar, perselen, guar gum, Polysaccharide-derived polysaccharide compounds such as tamarind gum, tara gum, dextrin, starch, locust bean gum, gum arabic, ghatti gum, karaya gum, tragacanth gum, arabinogalactan, pectin and quince; Animal-derived polysaccharide compounds such as chitosan and hyaluronic acid; Polysaccharide-derived polysaccharide compounds such as curdlan, xanthan gum, gellan gum, cyclodextrin, dextran, pullulan and hyaluronic acid; Non-ionic cellulose such as microcrystalline cellulose, methylcellulose, ethylcellulose, hydroxymethylcellulose, hydroxyethylcellulose, hydroxypropylcellulose and hydroxypropylmethylcellulose; Anionic cellulose such as carboxymethylcellulose; Cationized cellulose such as O- [2-hydroxy-3- (trimethylammonio) propyl] hydroxyethylcellulose chloride; And cationized guar gum such as O- [2-hydroxy-3- (trimethylammonio) propyl] guar gum chloride.

As the component (C), a compound (at least one compound) selected from the group consisting of xanthan gum, guar gum, tamarind gum and gellan gum is preferable.

Examples of commercially available products of the above component (C) include trade name "Eco Gum T", trade name "Keldent" and trade name "Monat gum", manufactured by Dainippon Sumitomo Seiyaku Co., Manufactured by Nippon Kagaku Kogyo Co., Ltd., trade name &quot; Ingel Guar gum CS &quot;; Manufactured by DSP Gokyo Food &amp; Chemical Co., Ltd .; trade name "Glyroid 6C"; CP Kelco U.S., Inc., Gellan Surname. , &Quot; Kerkogel &quot;, and the like.

The content of the above-mentioned component (C) in 100% by mass of the inventive purifier composition is preferably at least 0.01% by mass, more preferably at least 0.1% by mass, preferably at most 3% by mass, % Or less. When the content of the component (C) is not lower than the lower limit described above, addition of the purification stabilizer composition and separation are suppressed, and the storage stability is further improved. When the content of the component (C) is not more than the upper limit, viscosity increase is suppressed so that spreadability and absorbability at the time of coating are further improved, and the repulsive force is not lowered. The content of the component (C) is the total amount of the components (C) in the tablet composition according to the present invention.

The content of the total amount of the component (B) and the component (C) in the 100% by weight of the antiseptic composition according to the present invention is preferably 0.3% by mass or more, more preferably 0.4% by mass or more, Or less, more preferably 4 mass% or less. When the total content of the component (B) and the component (C) is not lower than the lower limit described above, the sedimentation of the component (A) is suppressed and the recovery and separation of the stabilizer composition is suppressed, . If the total content of the component (B) and the component (C) is not more than the upper limit, increase in viscosity is suppressed, and spreadability and water absorbability at the time of coating are further improved.

The mass ratio of the component (B) to the component (C) (content of the component (B): content of the component (C)) is from 2: 1 to 10: 1 in 100% by mass of the composition of the present invention , Preferably 2.5: 1 to 8: 1. When the mass ratio is satisfied, the initial recovery force is further improved, and the storage stability of the stabilizer composition is further improved. In particular, viscosity increase of the stabilizer composition during storage for a long period of time is suppressed, And becomes even better.

(Component (D))

The component (D) is polyethylene glycol. The component (D) has a role of effectively increasing the initial repulsive force and the regular retention force. In addition, by using the above-mentioned component (D), it is possible to impart a better feel to the hair after the hair growth, while maintaining a high initial repulsive force. The above-mentioned component (D) may be used alone, or two or more thereof may be used.

The number average molecular weight of the component (D) is preferably 150 or more, more preferably 200 or more, preferably 6000 or less, and more preferably 4000 or less, from the viewpoint of further increasing the initial repulsive force and the regular holding power.

The content of the above-mentioned component (D) in 100% by mass of the antiseptic composition according to the present invention is preferably 1% by mass or more, more preferably 3% by mass or more, preferably 30% by mass or less, % Or less. When the content of the component (D) is equal to or more than the lower limit described above, the initial repulsive force and the regular retention force can be further enhanced. When the content of the component (D) is equal to or less than the upper limit, generation of flaking is further suppressed, stiffness and burr staining can be suppressed, and a better feeling can be imparted to the hair after hair growth. The content of the component (D) is the total amount of the contents of all the components (D) in the tablet composition according to the present invention.

The mass ratio of the content of the component (A) to the content of the component (D) (content of the component (A): content of the component (D)) in the conditioner composition according to the present invention is from 1: : 25, and more preferably 1: 3 to 1:20. Is relatively large, the initial repulsive force is further improved. When the content of the component (D) is relatively large, it is better that the stiffness and discoloration disappear. The ratio of the mass ratio of the silica content to the content of the component (D) and the mass ratio of the particles selected from the group consisting of calcium carbonate, magnesium carbonate, hydroxyapatite, titanium oxide, zinc oxide, calcium silicate, magnesium silicate, aluminum silicate and magnesium hydroxide The mass ratio of the content (content of the total) to the content of the component (D) is preferably 1: 1 to 1:25, and more preferably 1: 3 to 1:20.

(Component (E))

The component (E) is at least one compound selected from the group consisting of the component (E1) and the component (E2). By using the above-mentioned component (E), it is possible to further suppress the flaking, to improve the cleansing properties after the cleansing, and to impart a good touch to the hair after the cleansing while maintaining a high initial repulsive force. In addition, even when the hair is applied with the regular-care agent and the hair is sufficiently cleaned, the discomfort felt with the regular-agent can be suppressed and the hair can be smoothly restored in a natural state. The component (E) may be used alone, or two or more thereof may be used. The component (E1) and the component (E2) may be used singly or two or more of them may be used.

As the component (E), either one of the component (E1) and the component (E2) may be used, and the component (E1) and the component (E2) may be used in combination.

The component (E1) is a polyoxyalkylene alkyl glucoside. Examples of the oxyalkylene group in the component (E1) include an oxyethylene group and an oxypropylene group. The average number of moles of the oxyalkylene group added in the component (E1) is not particularly limited, but is preferably 5 or more, and preferably 40 or less. The number of carbon atoms of the alkyl group in the component (E1) is preferably 1 to 4, more preferably 1 to 3. The alkyl group in the component (E1) is preferably a methyl group or an ethyl group.

The component (E1) is not particularly limited, and examples thereof include polyoxyethylene methyl glucoside, polyoxyethylene ethyl glucoside, polyoxypropylene methyl glucoside and polyoxypropylene ethyl glucoside.

The component (E1) is preferably polyoxyethylene methyl glucoside from the viewpoint of imparting a better feeling to the hair after the regular hair whilst maintaining a high initial repulsive force.

The component (E2) is a polyoxyalkylene glycerin fatty acid ester. The number of carbon atoms of the fatty acid in the component (E2) is preferably 8 or more, and preferably 22 or less. Examples of the oxyalkylene group in the component (E2) include an oxyethylene group and an oxypropylene group. The average number of moles of the oxyalkylene group added in the component (E2) is preferably 5 or more, and preferably 40 or less.

It is preferable that the fatty acid in the component (E2) is a branched fatty acid, and the component (E2) is a polyoxyalkylene glycerin branched fatty acid ester (E2) in view of giving a better feeling to the hair .

The number of carbon atoms in the branched fatty acid in the polyoxyalkylene glycerin branched fatty acid ester is preferably 8 or more, and preferably 22 or less, from the viewpoint of imparting a better feeling to hair after regular hair removal while maintaining a high initial repulsive force. Examples of the branched fatty acid in the polyoxyalkylene glycerin branched fatty acid ester include 2-ethylhexanoic acid, isononanoic acid, isopalmitic acid and isostearic acid.

As the polyoxyalkylene glycerin branched fatty acid ester, polyoxyethylene glyceryl isostearate is particularly preferable.

Commercially available products of the above component (E1) include, for example, those sold under the trade names &quot; Macbie Ride MG-10P &quot; Trade name &quot; Glukam E-10 &quot;, trade name &quot; Glukam E-20 &quot;, manufactured by Noveon; Glucam P-10 &quot; manufactured by Amerchol Corp., and the like.

As a commercially available product of the above component (E2), for example, trade name "NOIGEN GIS-125" manufactured by Dai-ichi Kogyo Seiyaku Co., EMALEX GWIS-120 ", trade name" EMALEX GWIS-125 "and trade name" EMALEX GWIS-130 "manufactured by Nihon Emulsion Co., Ltd., and the like.

The content of the component (E) in 100% by mass of the inventive purifier composition is preferably 0.5% by mass or more, more preferably 1% by mass or more, preferably 20% by mass or less, % Or less. When the content of the component (E) is not lower than the lower limit, the initial repulsive force is further increased, the flaking is further suppressed, and the cleaning property after the cleaning is further improved. When the content of the component (E) is not more than the upper limit, a better feeling is imparted to the hair after the hair growth. The content of the component (E) is the sum of the contents of all the components (E) in the stabilizer composition according to the present invention.

(A): the content of the component (E)) of the content of the component (A) and the content of the component (E) in the regular developer composition is 1: 0.2 to 1:20 , More preferably from 1: 1 to 1:10. When the content of the component (A) is relatively large, it is possible to impart a better feeling to the hair after regular hair removal while maintaining a high initial repulsive force. When the content of the component (E) is relatively large, the flaking is further suppressed, and the cleaning property after the cleaning treatment is further improved. The ratio of the mass ratio of the silica content to the content of the component (E) and the mass ratio of the particles selected from the group consisting of calcium carbonate, magnesium carbonate, hydroxyapatite, titanium oxide, zinc oxide, calcium silicate, magnesium silicate, aluminum silicate, The mass ratio of the content (content of the total) to the content of the component (E) is preferably 1: 0.2 to 1:20, and more preferably 1: 1 to 1:10.

(Other components)

The stabilizer composition according to the present invention is not particularly limited, but preferably contains water. The water is not particularly limited as long as it is water used in cosmetics, but purified water is preferable. The content of water in 100 mass% of the antiseptic composition according to the present invention is preferably 20 mass% or more, more preferably 30 mass% or more, preferably 95 mass% or less, more preferably 90 mass% or less.

The stabilizer composition according to the present invention is not particularly limited, but it preferably contains a lower alcohol having 2 to 5 carbon atoms (particularly, ethanol). The content of the lower alcohol (particularly, ethanol) in 100% by mass of the purifier composition according to the present invention is preferably 2% by mass or more, more preferably 5% by mass or more, and preferably 50% by mass or less, 30% by mass or less.

The cleaning agent composition according to the present invention may contain, for example, a surfactant such as a nonionic surfactant, a cationic surfactant and an amphoteric surfactant within a range that does not impair the effect of the present invention; Polyhydric alcohols such as glycerin, 1,3-butylene glycol, propylene glycol, 1,2-butanediol, 1,2-pentanediol, 1,2-hexanediol, ; Higher alcohols having 12 to 18 carbon atoms such as lauryl alcohol, myristyl alcohol, cetyl alcohol, stearyl alcohol, isostearyl alcohol, cetostearyl alcohol and oleyl alcohol; Sugar alcohols such as sorbitol, maltitol and trehalose; Acrylate copolymer, (acrylate / methacrylic acid stearates-20) copolymer, (acrylate / methacrylic acid stearates-20) crosspolymer and (acrylate / neodecanoylvinyl) crosspolymer; Silicone oil; Metal ion sequestrants; Antioxidants; Plant extracts; dyes; Pigments; pH adjusters; Spices; antiseptic; A solvent, and the like.

(Other details of the stabilizer composition)

The properties of the tablet composition according to the present invention are not particularly limited, and examples thereof include a liquid, a gel, a cream, and a solid. Particularly, it is preferable that the stabilizer composition is liquid or gel-like.

The viscosity of the stabilizer composition at 25 ° C is preferably 1000 mPa · s or more, more preferably 2000 mPa · s or more, preferably 100000 mPa · s or less, and furthermore preferably 50000 mPa · s or less. When the viscosity is not less than the lower limit and not more than the upper limit, the coating property is further increased, the occurrence of flaking and tackiness are further suppressed, and the initial repulsive force and the regular retention force are further increased. In the above-described stabilizer composition, since the viscosity is not more than the upper limit, generation of flaking and tackiness can be suppressed even when fluidity is high, and the initial recovery power and the regular holding power can be increased.

The viscosity was measured using a viscometer at a rotational speed of 12 rpm and a rotation time of 1 minute using a No. 4 rotor. As the above-mentioned viscometer, a TV-22 type viscometer manufactured by Ohshiku Co., Ltd. can be used.

The method for producing the stabilizer composition according to the present invention is not particularly limited, and a known method for producing the stabilizer composition can be used as the method for producing the stabilizer composition according to the present invention. The method for producing the stabilizer composition according to the present invention is not particularly limited. For example, after stirring the components (A), (B) and water with a dispenser, the components are mixed with a paddle mixer, And a method of homogenization.

The propellant composition according to the present invention contains at least component (A), component (B) and component (C) as main components. By the combined use of the component (B) and the component (C), the stabilizer composition is appropriately thickened so that the dispersibility of the component (A) becomes better and the addition and separation of the stabilizer composition are suppressed, do. Further, by setting the compounding ratio of the component (B) and the component (C) to a specific preferable range, the component (A) precipitates or becomes difficult to agglomerate or become difficult to cause the viscosity rise of the stabilizer composition when the stabilizer composition is stored for a long period of time And the spreadability and the absorbency at the time of coating are further improved. Further, in the composition of the present invention, it is possible to suppress the occurrence of flaking and tackiness during regular motion, and to increase the initial repulsive force and the regular retention force.

Further, it is preferable that the stabilizer composition according to the present invention further comprises component (D). By using the component (A) and the component (D) in combination, the initial repulsive force immediately after the straightening can be increased while the stickiness is suppressed, and the constant retention force can be increased. Further, by using the component (D), it is possible to suppress the occurrence of flaking (a phenomenon in which white powder or a film appears to adhere on the hair) at the time of correcting. Thereby, the use of the tablet composition according to the present invention makes it possible not only to satisfactorily stabilize the hair, but also to maintain the hair straightening state for a long period of time.

Further, by blending the component (D), the repulsive force and the suppressing effect of flaking can be further improved, and the effect of imparting luster to the hair after the treatment and cleansing properties are improved.

The stabilizer composition according to the present invention is not particularly limited, but can be used in the form filled in a container, for example.

Examples of the container include a bottle container, a self-container, and a tube container. The container is preferably a bottle container or a tube container.

Hereinafter, the present invention will be specifically described with reference to examples and comparative examples. The present invention is not limited to the following embodiments.

(Example)

In the Examples and Comparative Examples, the following components were used.

(Component (A))

Trade name &quot; Sarisia 320 &quot;: silica (manufactured by Fuji Silysia Chemical Industries, Ltd.)

Trade name &quot; Aerosil 200 &quot;: silica (manufactured by Nippon Aerosil Co., Ltd.)

&Quot; Calmaru SCS M5 &quot;: Calcium carbonate (manufactured by SAKAI KAGAKU KOGYO KABUSHIKI KAISHA)

&Quot; Conformational HAP &quot;: Hydroxyapatite (manufactured by Daihei Chemical Industry Co., Ltd.)

Trade name &quot; Flowlight R &quot;: calcium silicate (manufactured by Tomita Seiyaku Co., Ltd.)

"Magnesium silicate (hard)": Magnesium silicate (manufactured by Tomita Seiyaku Co., Ltd.)

Synthetic aluminum silicate (heavy) ": Silicate aluminum (manufactured by Tomita Seiyaku Co., Ltd.)

(Component (B))

&Quot; Laponite XL21 &quot;: fluorosilicic acid (sodium / magnesium) (manufactured by Roquewood Co.)

Trade name &quot; Laponite XLG &quot;: Synthetic silicic acid (sodium / magnesium) (manufactured by Roquewood Co.)

(Component (C))

"Eco Gum T": xanthan gum (manufactured by Dainippon Sumitomo Seiyaku Co., Ltd.)

(Component (D))

Trade name &quot; PEG # 1000 &quot;: polyethylene glycol, number average molecular weight 1000 (manufactured by Nichi-

(Component (E))

Trade name &quot; NOIGEN GIS-125 &quot;: polyoxyethylene glyceryl isostearate (manufactured by Dai-ichi Kogyo Seiyaku Co., Ltd.)

 &Quot; Macbio Ride MG-10P &quot;: polyoxypropylene methyl glucoside (manufactured by Nichi-

(Examples 1 to 35 and Comparative Examples 1 to 25)

The formulation ingredients shown in the following Tables 1 to 7 were compounded (mixing unit is% by mass) to prepare a stabilizer composition.

The evaluation was carried out under constant conditions of constant temperature and constant humidity at 23 DEG C and a humidity of 60%, unless otherwise specified. The blending amount in the table is expressed by the actual blending amount (blending amount of the product).

(Test Example 1: Evaluation of storage stability)

The viscosity of the stabilizer composition immediately after preparation was measured. Subsequently, each sample was filled in a transparent glass container, and the appearance and properties of each sample after storage for 4 weeks in a thermostat at 50 캜 were observed and evaluated. The viscosity was subsequently measured, and the viscosity increase rate (%) was calculated from the viscosity value after storage and the viscosity value immediately after the production, and the viscosity increase rate (%) was evaluated according to the following criteria.

<Evaluation Criteria for Storage Stability (Appearance and Appearance)>

○ (very good): no precipitation of powder and no separation or separation of composition

DELTA (good): at least one of the sedimentation of the powder and the separation or addition of the composition is slightly observed

X (poor): at least one of the precipitation of the powder and the separation or addition of the composition appears clearly

The viscosity was measured using a TV-22 type viscometer (manufactured by Axis KK) using a No. 4 rotor under the conditions of a rotation speed of 12 rpm and a rotation time of 1 minute.

The viscosity increase rate was calculated by substituting the viscosity value (T0) immediately after preparation and the viscosity value (T1) after storage into the following equation.

[Rate of increase in viscosity (%)] = (T1 / T0) x100

&Lt; Evaluation criteria of storage stability (viscosity) >

○ (very good): viscosity increase rate (%) is more than 100% and less than 150%

(Good): The viscosity increase rate (%) is 150% or more and less than 180%

× (poor): viscosity increase rate (%) is more than 180%

(Test Example 2: Evaluation of initial repulsive force)

20 professional panels filled in a plastic container were uniformly applied to the hair of a wig (lesson mannequin: manufactured by Yukari Japan), and hair was straightened from the root portion, . In addition, the evaluation of the repulsive force was judged to have an initial repulsive force when the shape of the standing hair was hardly maintained. From the answer, the initial repulsive force was evaluated based on the following criteria.

<Evaluation Criteria of Initial Power>

○ (very good): More than 16 out of 20 responded that they had early recovery power

△ (good): 10 to 15 out of 20 responded that they had early reproductive power

× (bad): Less than nine out of 20 responded that they had early recovery power

(Test Example 3: Evaluation of water absorption and stickiness)

Twenty of the same expert panel responded to sensory evaluations of the water-absorbing and sticking properties of the water-absorbing composition during the regular application of Test Example 2. From the above answer, evaluation was made of the water absorbing ability and stickiness by the following criteria.

&Lt; Evaluation Criteria of Leaf Absorption >

○ (very good): More than 16 out of 20 responded that they had good absorbency

△ (Good): 10 to 15 out of 20 respondents answered that they had good water absorption

× (bad): Less than nine out of 20 responded that they had good water absorption

<Evaluation criteria of stickiness>

○ (very good): More than 16 out of 20 responded that they are not sticky

△ (Good): 10 to 15 out of 20 responded that they are not sticky

× (bad): Less than 9 out of 20 responded that they are not sticky

(Test Example 4: Evaluation of retentive holding force)

Twenty members of the same expert panel observed the hair of the wig after the lapse of 1 hour from the aforementioned Test Example 2 (evaluation of the initial repulsive force), and replied whether or not there was a constant retention force. The evaluation of the regular retention force was determined to have a regular retention force when the shape of the standing hair of Test Example 2 was continuously maintained. From the answers, the regular retention force was evaluated based on the following criteria.

<Criteria for Evaluation of Retention Force>

○ (very good): More than 16 out of 20 respondents said that they had regular maintenance

△ (Good): 10 to 15 out of 20 respondents answered that they had a positive remedy

× (bad): Less than nine out of 20 responded

(Test Example 5: evaluation of flaking)

After 20 Expert panels were tested in the above Test Example 4 (evaluation of regular hair holding force), the hair was combed 5 times from the root of the hair to the tip of the hair with a fingertip to answer whether there was flaking. Further, in the case where white powder appeared to be attached on the hair, it was judged that there was flaking. From the answers, flaking was evaluated based on the following criteria.

<Evaluation criteria of flaking>

○ (very good): More than 16 out of 20 responded that there is no play king

△ (Good): 10 to 15 out of 20 responded that there was no play king

× (bad): Less than 9 out of 20 answered that there is no play king

The results are shown in Tables 1 to 7 below. The total of the blending components in each of Examples and Comparative Examples shown in Tables 1 to 7 is 100% by mass.

Claims (4)

Which comprises the following component A, the following component B and the following component C,
Wherein the content of the component A is 0.1% by mass or more and 10% by mass or less, and the mass ratio of the content of the component B to the content of the component C is 2: 1 to 10: 1.
Component A: particles selected from the group consisting of silica, calcium carbonate, magnesium carbonate, hydroxyapatite, titanium oxide, zinc oxide, calcium silicate, magnesium silicate, aluminum silicate and magnesium hydroxide
Component B: Clay Minerals
Component C: polysaccharide compound The cleaning agent composition according to claim 1, wherein the total content of the component B and the component C is 0.3 mass% or more and 5 mass% or less. 3. The stabilizer composition according to claim 1 or 2, further comprising the following component D.
Component D: Polyethylene glycol 4. The stabilizer composition according to any one of claims 1 to 3, further comprising the following component (E).
Component E: a compound selected from the group consisting of a polyoxyalkylene alkyl glucoside and a polyoxyalkylene glycerin fatty acid ester