JP6092365B2 - Hairdressing composition - Google Patents

Description

  The present invention relates to a hair styling composition that is suitably used for a hair styling agent for shaping hair.

  In order to prepare hair, hair conditioner compositions having various properties such as liquid, gel, cream, and solid are used. Conventionally, a film-forming polymer is often used for imparting hair-styling power, which is a main function, to a hair-styling composition. In a hairdressing composition using a film-forming polymer, a film is formed on the surface of the hair after hair styling, derived from the film-forming polymer. For this reason, when a film-forming polymer is blended as the main hair styling component, the initial hair styling power immediately after hair styling is increased, while it is difficult to condition the hair in a natural state, or after hair styling, it is applied to the hair with a hand or a comb. When a stimulus is applied, the film peels off from the surface of the hair (so-called flaking occurs), and there is a problem that the appearance deteriorates.

  Therefore, a method different from the method using a film-forming polymer has been studied. Specifically, it has been studied to impart hair-styling power to a hair-styling composition using a powder.

The following Patent Document 1 discloses a hair cosmetic (hairdressing composition) containing 0.1 to 10% by mass of a fine particle powder having a specific surface area of 50 m ² / g or more. In Patent Document 1, by using the specific fine particle powder at a specific content, a good feel can be obtained, an excellent hair styling power can be obtained, a good feel can be maintained for a long time, and an excellent It describes that hair styling properties can be obtained.

JP 2003-342130 A

  However, as described in Patent Document 1, flaking may occur even when hair is set using a hairdressing composition containing fine particle powder. Furthermore, there is a current situation in which even better initial hair styling power and hair styling holding power are required.

  An object of the present invention is to provide a hair styling composition capable of suppressing the occurrence of flaking and stickiness and improving the initial hair styling power and hair styling holding power when hair is stipulated.

The hairdressing composition according to the present invention includes the following component (A) and the following component (B), and the content of the component (A) is 0.1% by mass or more and 10% by mass or less. Agent composition.
Component (A): Particles selected from the group consisting of silica, calcium carbonate, magnesium carbonate, hydroxyapatite, titanium oxide, zinc oxide, calcium silicate, magnesium silicate, aluminum silicate, and magnesium hydroxide Component (B) : A polyoxyethylene / polyoxypropylene copolymer which is liquid at 25 ° C. and has a number average molecular weight of 10,000 to 20000, and a polyoxyethylene / polyoxypropylene copolymer which is liquid at 25 ° C. and has a number average molecular weight of 300 to 1,000 A compound selected from the group consisting of oxypropylene sorbit

  In the hairdressing composition according to the present invention, the content of the component (B) is preferably 3% by mass or more and 40% by mass or less.

The hairdressing composition according to the present invention preferably further comprises the following component (C).
Component (C): a compound selected from the group consisting of polyoxyalkylene alkyl glucoside and polyoxyalkylene glycerin fatty acid ester

The hairdressing composition according to the present invention preferably further includes a component (D) that is a polymer selected from the group consisting of the following component (D1) and the following component (D2).
Component (D1): Polymer obtained by using two or more monomers selected from the group consisting of (meth) acrylic acid and (meth) acrylic acid alkyl ester as the essential monomer component Component (D2): Essential monomer As a component, a monomer selected from the group consisting of (meth) acrylic acid and (meth) acrylic acid alkyl ester, (meth) acrylic acid polyoxyethylene alkyl ether, itaconic acid polyoxyethylene alkyl ether, and vinyl neodecanoate Polymer obtained using a monomer selected from the group consisting of

  It is preferable that the hairdressing composition according to the present invention further includes a component (E) that is a clay mineral.

  In the hairdressing composition according to the present invention, the mass ratio of the content of the component (D) and the content of the component (E) is preferably 1: 0.1 to 1:30.

  The hair styling composition according to the present invention contains a specific component (A) and a specific component (B), and the content of the component (A) is within a specific range. Generation of king and stickiness can be suppressed, and initial hair styling power and hair styling holding power can be increased.

  Hereinafter, the present invention will be described in detail.

  The hairdressing composition according to the present invention was selected from the group consisting of silica, calcium carbonate, magnesium carbonate, hydroxyapatite, titanium oxide, zinc oxide, calcium silicate, magnesium silicate, aluminum silicate, and magnesium hydroxide. Particles, a polyoxyethylene / polyoxypropylene copolymer that is liquid at 25 ° C. and has a number average molecular weight of 10,000 to 20000, and a liquid that is liquid at 25 ° C. and has a number average molecular weight of 300 to 1,000 And at least a compound selected from the group consisting of a certain polyoxypropylene sorbit.

  In the present specification, the above-mentioned “particles selected from the group consisting of silica, calcium carbonate, magnesium carbonate, hydroxyapatite, titanium oxide, zinc oxide, calcium silicate, magnesium silicate, aluminum silicate, and magnesium hydroxide” May be referred to as “component (A)”. Further, the above-mentioned “polyoxyethylene / polyoxypropylene copolymer which is liquid at 25 ° C. and has a number average molecular weight of 10,000 or more and 20000 or less, and liquid at 25 ° C. and has a number average molecular weight of 300 or more and 1,000 or less. The “compound selected from the group consisting of polyoxypropylene sorbites” may be referred to as “component (B)”. Furthermore, the “polyoxyethylene / polyoxypropylene copolymer having a liquid state at 25 ° C. and having a number average molecular weight of 10,000 to 20,000” may be referred to as “component (B1)”. And “a polyoxypropylene sorbite having a number average molecular weight of 300 or more and 1000 or less” may be referred to as “component (B2)”.

  The hairdressing composition according to the present invention preferably further contains a compound selected from the group consisting of polyoxyalkylene alkyl glucoside and polyoxyalkylene glycerin fatty acid ester.

  In the present specification, the “compound selected from the group consisting of polyoxyalkylene alkyl glucoside and polyoxyalkylene glycerin fatty acid ester” may be referred to as “component (C)”. The “polyoxyalkylene alkyl glucoside” may be referred to as “component (C1)”, and the “polyoxyalkylene glycerin fatty acid ester” may be referred to as “component (C2)”.

  The hairdressing composition according to the present invention preferably further includes a polymer selected from the group consisting of the following first polymer and the following second polymer. The first polymer is a polymer obtained by using two or more monomers selected from the group consisting of (meth) acrylic acid and (meth) acrylic acid alkyl esters as essential monomer components. The second polymer includes, as essential monomer components, a monomer selected from the group consisting of (meth) acrylic acid and (meth) acrylic acid alkyl ester, (meth) acrylic acid polyoxyethylene alkyl ether, itaconic acid poly A polymer obtained using an oxyethylene alkyl ether and a monomer selected from the group consisting of vinyl neodecanoate.

  In the present specification, the “polymer selected from the group consisting of the first polymer and the second polymer” may be referred to as “component (D)”. The “first polymer” may be referred to as “component (D1)”, and the “second polymer” may be referred to as “component (D2)”. “(Meth) acrylic acid” means one or both of acrylic acid and methacrylic acid.

  The hairdressing composition according to the present invention may further contain a polysaccharide compound. In the present specification, the “polysaccharide compound” may be referred to as “component (D ′)”.

  It is preferable that the hairdressing composition according to the present invention further contains a clay mineral. In the present specification, the “clay mineral” may be referred to as “component (E)”.

  That is, the hairdressing composition according to the present invention includes at least a component (A) and a component (B). The hairdressing composition according to the present invention preferably further comprises a component (at least one component) selected from the group consisting of component (C), component (D), and component (E). When using the component (E), it is preferable to use the component (E) in combination with a component selected from the group consisting of the component (D) and the component (D ′). Especially, it is preferable that the hairdressing composition which concerns on this invention contains all of a component (A), a component (B), a component (C), a component (D), and a component (E). The hairdressing composition according to the present invention may further contain other components. Only one kind of each of the above components, for example, the component (A), the component (B), the component (C), the component (D), the component (D ′), the component (E), and the other components is used. Two or more kinds may be used.

  The component (B) is a compound (at least one compound) selected from the group consisting of the component (B1) and the component (B2). The component (C) is a compound (at least one compound) selected from the group consisting of the component (C1) and the component (C2). Further, the component (D) is a polymer (at least one polymer) selected from the group consisting of the component (D1) and the component (D2). As for said component (B1), component (B2), component (C1), component (C2), component (D1), and component (D2), only 1 type may each be used and 2 or more types may be used. May be.

  Hereinafter, the detail of each component used for the hairdressing agent composition which concerns on this invention is demonstrated.

(Ingredient (A))
The component (A) is a particle selected from the group consisting of silica, calcium carbonate, magnesium carbonate, hydroxyapatite, titanium oxide, zinc oxide, calcium silicate, magnesium silicate, aluminum silicate, and magnesium hydroxide. . The said component (A) has a role which mainly suppresses stickiness and raises initial hair-setting power and hair-styling retention power. Further, by using the component (A), it is possible to facilitate hair styling again after hair styling once and to improve re-hair styling, as compared with the case where a film-forming polymer is used.

  The component (A) was selected from the group consisting of silica, magnesium carbonate, hydroxyapatite, calcium silicate, magnesium silicate, aluminum silicate, and magnesium hydroxide, among others, from the viewpoint of improving hairdressing performance. Particles (at least one particle) are preferable, and particles (at least one particle) selected from the group consisting of silica, magnesium silicate, and magnesium hydroxide are more preferable. As for the said component (A), only 1 type may be used and 2 or more types may be used.

<Silica>
As the silica, known and commonly used silica (anhydrous silicic acid) can be used. The silica may be silicic anhydride (hydrophilic silica) that has not been hydrophobized or may be hydrophobized silicic anhydride. The silica may be silica that has been surface-treated with an amino acid, an ester, lecithin, or the like. The silica may be so-called easily disintegrating silica particles. As for the said silica, only 1 type may be used and 2 or more types may be used.

  The hydrophobized silicic anhydride is a substance obtained by hydrophobizing silicic anhydride (for example, untreated silicic anhydride). Examples of the treating agent used for the hydrophobizing treatment include organic silyl compounds and silicone compounds. Examples of the organic silyl compound include methyltrichlorosilane, dimethyldichlorosilane, trimethylchlorosilane, hexamethyldisilazane, methyltrialkoxysilane, dimethyldialkoxysilane, trimethylalkoxysilane, ethyltrichlorosilane, propyltrichlorosilane, hexyltrichlorosilane, long Examples include chain alkyltrichlorosilane, ethyltrialkoxysilane, propyltrialkoxysilane, hexyltrialkoxysilane, long chain alkyltrialkoxysilane, methacryl silane, fluoroalkylsilane, and perfluoroalkylsilane. Examples of the silicone compound include dimethylpolysiloxane (silicone oil), methylphenylpolysiloxane, methylhydrogenpolysiloxane, and amino-modified silicone. A publicly known method can be adopted as a method of the above-mentioned hydrophobic treatment. Examples of the hydrophobic treatment method include a liquid phase method, a gas phase method, and an autoclave method.

  Preferred examples of the hydrophobic silicic anhydride include dimethylsiloxylated silicic anhydride, trimethylsiloxylated silicic anhydride, octylsiloxylated silicic anhydride, silicone oil treated silicic anhydride and methacrylsiloxylated silicic anhydride. Etc.

  The easily disintegratable silica particles are particles formed by aggregating a plurality of silica primary particles. Although it does not specifically limit as said silica primary particle, For example, a spherical silica particle, a scaly silica particle, an amorphous silica particle, etc. are mentioned. The average particle diameter of the silica primary particles is not particularly limited.

  Moreover, the said easily disintegrable silica particle may include components other than a silica. The component other than the silica (hereinafter may be referred to as “encapsulated component”) is not particularly limited, and examples thereof include surfactants, polyhydric alcohols, higher alcohols, sugar alcohols, silicone oils, sequestering agents, Examples include antioxidants, plant extracts, dyes, pigments, fragrances, moisturizers, vitamins, amino acids, and refreshing agents. Of these, amino acids, silicone oils, and vitamins are preferable. Although it does not specifically limit as said amino acids, Dilauroyl glutamate ricin Na (For example, the product name "Perisea" by Asahi Kasei Chemicals Corporation), a trimethylglycine, glutamic acid, etc. are mentioned. When the easily disintegratable silica particles encapsulate the inclusion component, the inclusion component is released when the easily disintegratable silica particles are disintegrated during hair styling, and an effect corresponding to the type of the inclusion component is exhibited. For example, the easily disintegratable silica particles encapsulate amino acids, thereby exhibiting a hair damage care function.

  It does not specifically limit as a manufacturing method of the said easily disintegrating silica particle, A well-known method can be used.

  The silica oil absorption is preferably 100 mL / 100 g or more, more preferably 150 mL / 100 g or more, still more preferably 200 mL / 100 g or more, preferably 1000 mL / 100 g or less, more preferably 800 mL / 100 g or less, more preferably 700 mL / 100 g or less. When the oil absorption amount of the silica is not less than the above lower limit and not more than the above upper limit, the initial hair styling power, the hair styling holding power and the re-hair styling property are further improved. The oil absorption is measured according to the method described in JIS K5101.

  Examples of commercially available products of the silica include silica silicic acid manufactured by Fuji Silysia Chemical Co., Ltd., trade name “Silisia 320”, trade name “Silisia 310P”, trade name “Silisia 250”, trade name “Silicia 250N”, and products. The name “Siricia 350”, the product name “Silicia 370”, the product name “Silicia 380”, the product name “Silicia 420”, the product name “Silicia 430”, the product name “Silicia 440”, the product name “Silicia 450”, and the product name. “Silicia 470”; manufactured by Nippon Aerosil Co., Ltd., which is silicic anhydride, trade name “AEROSIL 50”, trade name “AEROSIL 90G”, trade name “AEROSIL 130”, trade name “AEROSIL 150”, trade name “AEROSIL 200”, Product name “AEROSIL 300”, Product name “AEROSIL 380”, product name “AEROSIL 200V” and product name “AEROSIL OX50”; product name “Sunsphere H-31”, product name “Sunsphere H-31” manufactured by AGC S-Itech Co., Ltd., which is silicic anhydride. , Trade name "Sunsphere H-121", trade name "Sunsphere H-201", trade name "Sunsphere H-32", trade name "Sunsphere H-52", trade name "Sunsphere H-122" , Trade name "Sunsphere H-33" and trade name "Sunsphere H-53"; dimethylsiloxylated silicic acid manufactured by Nippon Aerosil Co., Ltd., trade name "AEROSIL R972", trade name "AEROSIL R974" and product Name “AEROSIL R9200”; a trimethylsiloxylated silicic anhydride Product name “AEROSIL RX200”, product name “AEROSIL R8200”, product name “AEROSIL RX300” and product name “AEROSIL R812S”; manufactured by Nippon Aerosil Co., Ltd., which is octylsiloxylated silicic acid, R805 "; manufactured by Nippon Aerosil Co., Ltd., a silicone oil-treated silicic acid, trade name" AEROSIL R202 ", trade name" AEROSIL RY200 ", trade name" AEROSIL RY200S "and trade name" AEROSIL RY300 "; methacrylosiloxylated silicic anhydride Product name “AEROSIL R711” manufactured by Nippon Aerosil Co., Ltd. which is an acid; product name “Silica Beads SB-705” manufactured by Miyoshi Kasei Co., Ltd. which is the above-mentioned disintegrating silica; , The trade name of "God Paul SF-16C", include the trade name "God Paul AF-6C" and the trade name of "God Paul AF-16C" and the like.

<Calcium carbonate>
The said calcium carbonate is represented by the INCI name "CALCIUM CARBONATE", for example. As for the said calcium carbonate, only 1 type may be used and 2 or more types may be used. As a commercial item of the said calcium carbonate, Sakai Chemical Industry make, brand name "Karumaru SCS M5"; Shiraishi calcium company make, brand name "Fuwakaru" etc. are mentioned, for example.

<Magnesium carbonate>
The magnesium carbonate is represented by, for example, the INCI name “MAGNESIUM CARBONATE”. As for the said magnesium carbonate, only 1 type may be used and 2 or more types may be used. As a commercial item of the said magnesium carbonate, the Toda Pharmaceutical company make, brand name "light magnesium carbonate" etc. are mentioned, for example.

<Hydroxyapatite>
The hydroxyapatite is represented by, for example, the INCI name “HYDROXYAPATITE”. As for the said hydroxyapatite, only 1 type may be used and 2 or more types may be used.

  The hydroxyapatite is not particularly limited, and examples thereof include spherical hydroxyapatite, plate-like hydroxyapatite, and amorphous hydroxyapatite. Among these, spherical hydroxyapatite is preferable from the viewpoint of exhibiting high hair styling performance. As a commercial item of the said hydroxyapatite, the product name "Plate HAP", the brand name "spherical HAP", the brand name "HAP-100", the brand name "HAP-200" and the brand name made by Taihei Chemical Industry Co., Ltd. "HAP-300" etc. are mentioned.

<Titanium oxide>
The titanium oxide is represented by, for example, the INCI name “TITANIUM DIOXIDE”. The titanium oxide is not particularly limited, and may be fine particle titanium oxide or pigment titanium, for example. As for the said titanium oxide, only 1 type may be used and 2 or more types may be used. As a commercial item of the said titanium oxide, the Ishihara Sangyo company make, brand name "TTO-55 (A)", brand name "CR-50", etc. are mentioned, for example.

<Zinc oxide>
The zinc oxide is represented by, for example, the INCI name “ZINC OXIDE”. As for the said zinc oxide, only 1 type may be used and 2 or more types may be used. As a commercial item of the said zinc oxide, Sakai Chemical Industry Co., Ltd. make, brand name "FINEX-30S-LP2" etc. are mentioned, for example.

<Calcium silicate>
The calcium silicate is represented, for example, by the INCI name “CALCIUM SILICATE”. As for the said calcium silicate, only 1 type may be used and 2 or more types may be used. Examples of commercially available products of calcium silicate include Tomita Pharmaceutical Co., Ltd., trade name “FLORITE R”; Nippon Insulation Co., Ltd., trade name “Zonotolite Powder XJ”, and trade name “Tobermorite Powder TK”. .

<Magnesium silicate>
The magnesium silicate is represented by, for example, the INCI name “MAGNESIUM SILICATE”. As for the said magnesium silicate, only 1 type may be used and 2 or more types may be used. As a commercial item of the said magnesium silicate, the Tomita Pharmaceutical company make, brand name "magnesium silicate (light)" etc. are mentioned, for example.

<Aluminum silicate>
The aluminum silicate is represented by, for example, the INCI name “ALUMINUM SILICATE”. As for the said aluminum silicate, only 1 type may be used and 2 or more types may be used. Although it does not specifically limit as an aluminum silicate, A synthetic aluminum silicate is preferable. Examples of the synthesis method include, for example, a method of adding Na ₂ SiO ₃ to alum and drying the generated precipitate, a method of producing a silicate sol by electrodialysis, thereby producing a gel, and an aluminum salt in water glass. The method of adding the aqueous solution of this is mentioned. As a commercial item of the said aluminum silicate, the product name "Synthetic aluminum silicate (heavy)" by Tomita Pharmaceutical Co., Ltd. etc. are mentioned, for example.

<Magnesium hydroxide>
The magnesium hydroxide is represented by, for example, the INCI name “MAGNESIUM HYDROXIDE”. As for the said magnesium hydroxide, only 1 type may be used and 2 or more types may be used. As a commercial item of the said magnesium hydroxide, the Tomita Pharmaceutical company make, brand name "magnesium hydroxide (heavy)" etc. are mentioned, for example.

  In 100% by mass of the hairdressing composition according to the present invention, the content of the component (A) is 0.1% by mass or more, preferably 0.4% by mass or more, more preferably 1% by mass or more and 10% by mass. Hereinafter, it is preferably 7% by mass or less, more preferably 5% by mass or less. When the content of the component (A) is not less than the above lower limit, the initial styling power immediately after styling can be further increased, and the styling holding power can be further enhanced. When content of the said component (A) is below the said upper limit, the effect which gives gloss and the wash-off property further improve. The content of the component (A) is the total content of all the components (A) in the hairdressing composition according to the present invention. Further, in 100% by mass of the hairdressing composition according to the present invention, the content of silica, and calcium carbonate, magnesium carbonate, hydroxyapatite, titanium oxide, zinc oxide, calcium silicate, magnesium silicate, aluminum silicate, and The content (total content) of the particles selected from the group consisting of magnesium hydroxide is 0.1% by mass or more, preferably 0.4% by mass or more, more preferably 1% by mass or more and 10% by mass, respectively. % Or less, preferably 7% by mass or less, more preferably 5% by mass or less.

(Ingredient (B))
The component (B) is at least one compound selected from the group consisting of the component (B1) and the component (B2). The component (B) mainly has a role of effectively increasing the initial hair styling power and the hair styling holding power. Moreover, by using the component (B), flaking can be suppressed and the above effect can be exhibited. As for the said component (B), only 1 type may be used and 2 or more types may be used. In addition, only 1 type may be used for said component (B1) and said component (B2), respectively, and 2 or more types may be used.

  As the component (B), only one of the component (B1) and the component (B2) may be used, or the component (B1) and the component (B2) may be used in combination. Good. Especially, it is preferable that the said component (B1) and the said component (B2) are used together from a viewpoint of the sustainability improvement of hairdressing power.

  The component (B1) is a polyoxyethylene / polyoxypropylene copolymer. That is, the component (B1) is a copolymer having at least a plurality of oxyethylene units (ethylene oxide units) and a plurality of oxypropylene units (propylene oxide units). The component (B1) may be any of a block copolymer, a random copolymer, and an alternating copolymer, and the form of copolymerization in the component (B1) is not particularly limited.

  The average added mole number of oxyethylene in the component (B1) is not particularly limited, but is preferably 100 or more, more preferably 200 or more, preferably 400 or less, more preferably 350 or less. The average added mole number of oxypropylene in the component (B1) is not particularly limited, but is preferably 30 or more, particularly preferably 40 or more, preferably 150 or less, particularly preferably 100 or less.

  The component (B1) is in a liquid state at 25 ° C. from the viewpoint of suppressing flaking, ease of application of the hairdressing agent, and imparting gloss to the hair.

  The number average molecular weight of the component (B1) is 10,000 or more and 20000 or less. If the number average molecular weight of the component (B1) is less than the lower limit, the hair styling property is lowered. When the number average molecular weight of the component (B1) exceeds the above upper limit, handling properties are deteriorated. The number average molecular weight of the component (B1) is preferably 12000 or more. The number average molecular weight of the component (B1) is preferably 18000 or less.

  The component (B2) is polyoxypropylene sorbit. The average added mole number of oxypropylene in the component (B2) is not particularly limited, but is preferably 4 or more, more preferably 8 or more, preferably 15 or less, more preferably 12 or less.

  The component (B2) is liquid at 25 ° C. from the viewpoint of suppressing flaking, ease of application of the hairdressing agent, and imparting gloss to the hair.

  The number average molecular weight of the component (B2) is 300 or more and 1000 or less. The number average molecular weight of the component (B2) is preferably 400 or more. The number average molecular weight of the component (B2) is preferably 800 or less.

  The component (B) is liquid at 25 ° C. The component (B) preferably has fluidity at 25 ° C., for example, when a 50 g sample is put in a glass bottle having a radius of 2 cm and a height of 7 cm, and the glass bottle is inverted at a temperature of 25 ° C. In addition, it is preferable that the sample has a property of dripping from the glass bottle within 5 minutes immediately after being inverted.

  As a commercial item of the said component (B1), the Sanyo Kasei Kogyo company make, brand name "New Paul 75H-90000" etc. are mentioned, for example.

  As a commercial item of the said component (B2), the Sanyo Chemical Industries make, brand name "New Paul SP-750", brand name "Sanix SP-750", etc. are mentioned, for example.

  In 100% by mass of the hairdressing composition according to the present invention, the content of the component (B) is preferably 3% by mass or more, more preferably 5% by mass or more, still more preferably 8% by mass or more, preferably 40% by mass. % Or less, more preferably 30% by mass or less, and still more preferably 20% by mass or less. When the content of the component (B) is not less than the above lower limit, the hair styling power and its sustainability are further improved. When the content of the component (B) is less than or equal to the above upper limit, the sticking suppression effect, the spread at the time of application, and the familiarity are further improved. The content of the component (B) is the total content of all the components (B) in the hairdressing composition according to the present invention.

  In the hairdressing composition according to the present invention, the mass ratio between the content of the component (A) and the content of the component (B) (content of the component (A): content of the component (B)). Is preferably 1: 0.1 to 1:30, more preferably 1: 1 to 1:20, and still more preferably 1: 3 to 1:20. When the content of the component (A) is relatively increased, the ability to form soft styling becomes even better. When the content of the component (B) is relatively increased, the styling property that creates a tight hair flow is further improved. Mass ratio of content of silica and content of component (B), and calcium carbonate, magnesium carbonate, hydroxyapatite, titanium oxide, zinc oxide, calcium silicate, magnesium silicate, aluminum silicate, and water The mass ratio of the content (total content) of the particles selected from the group consisting of magnesium oxide and the content of the component (B) is 1: 0.1 to 1:30, respectively. Preferably, it is 1: 1 to 1:20, more preferably 1: 3 to 1:20.

(Ingredient (C))
The component (C) is at least one compound selected from the group consisting of the component (C1) and the component (C2). By using the component (C), flaking can be further suppressed, washing off after hair styling is improved, and good hair feel can be imparted to the hair after styling while maintaining high initial hair styling power. Moreover, even if the hair-styling composition is applied to the hair and the hair is sufficiently hair-styled, the sense of discomfort to which the hair-styling composition is attached is suppressed, and hair can be styled in a natural state. As for the said component (C), only 1 type may be used and 2 or more types may be used. In addition, only 1 type may be used for said component (C1) and said component (C2), respectively, and 2 or more types may be used.

  As the component (C), only one of the component (C1) and the component (C2) may be used, or the component (C1) and the component (C2) may be used in combination. .

  The component (C1) is a polyoxyalkylene alkyl glucoside. Examples of the oxyalkylene group in the component (C1) include an oxyethylene group and an oxypropylene group. The average addition mole number of the oxyalkylene group in the component (C1) is not particularly limited, but is preferably 5 or more, and preferably 40 or less. Preferably carbon number of the alkyl group in the said component (C1) is 1-4, More preferably, it is 1-3. The alkyl group in the component (C1) is preferably a methyl group or an ethyl group.

  Although it does not specifically limit as said component (C1), Polyoxyethylene methyl glucoside, polyoxyethylene ethyl glucoside, polyoxypropylene methyl glucoside, polyoxypropylene ethyl glucoside, etc. are mentioned.

  From the viewpoint of imparting a better touch to the hair after styling while maintaining high initial hair styling power, the component (C1) is preferably polyoxyethylene methyl glucoside.

  The component (C2) is a polyoxyalkylene glycerin fatty acid ester. The number of carbon atoms of the fatty acid in the component (C2) is preferably 8 or more, and preferably 22 or less. Examples of the oxyalkylene group in the component (C2) include an oxyethylene group and an oxypropylene group. The average added mole number of the oxyalkylene group in the component (C2) is preferably 5 or more, and preferably 40 or less.

  From the viewpoint of imparting a better touch to the hair after styling while maintaining high initial hair styling power, the fatty acid in the component (C2) is preferably a branched fatty acid, and the component (C2) is a polyoxyalkylene. It is preferably a glycerin branched fatty acid ester.

  From the viewpoint of imparting a better touch to the hair after styling while maintaining high initial hair styling power, the number of carbon atoms of the branched fatty acid in the polyoxyalkylene glycerin branched fatty acid ester is preferably 8 or more, and preferably 22 or less. . Examples of the branched fatty acid in the polyoxyalkylene glycerin branched fatty acid ester include 2-ethylhexanoic acid, isononanoic acid, isopalmitic acid, and isostearic acid.

  As the polyoxyalkylene glycerin branched fatty acid ester, polyoxyethylene glyceryl isostearate is particularly preferable.

  As a commercial item of the said component (C1), the product name "Macbiobride MG-10P" by NOF Corporation; the product name "Glucam E-10" and the brand name "Glucam E-20" made by Noveon, for example. A product name “Glucam P-10” manufactured by Amacol Corporation.

  As a commercial item of the said component (C2), Daiichi Kogyo Seiyaku Co., Ltd. brand name "Neugen GIS-125"; Nippon Emulsion Co., Ltd. brand name "EMALEX GWIS-115", brand name "EMALEX GWIS-120", for example. ", Trade name" EMALEX GWIS-125 ", trade name" EMALEX GWIS-130 ", and the like.

  In 100% by mass of the hairdressing composition according to the present invention, the content of the component (C) is preferably 0.5% by mass or more, more preferably 1% by mass or more, preferably 20% by mass or less, more preferably. It is 10 mass% or less. When the content of the component (C) is not less than the above lower limit, flaking is further suppressed, washing off after hair styling is further improved, and a better touch is imparted to the hair after hair styling. The When the content of the component (C) is not more than the above upper limit, stickiness is further reduced. Content of the said component (C) is a total amount of content of all the components (C) in the hairdressing composition which concerns on this invention.

  In the hairdressing composition, the mass ratio between the content of the component (A) and the content of the component (C) (content of the component (A): content of the component (C)) is 1 : 0.2 to 1:20 is preferable, and 1: 1 to 1:10 is more preferable. When the content of the component (C) is relatively increased, the hair texture, flaking suppression effect, and wash-off properties are further improved. Mass ratio of content of silica and content of component (C), and calcium carbonate, magnesium carbonate, hydroxyapatite, titanium oxide, zinc oxide, calcium silicate, magnesium silicate, aluminum silicate, and water The mass ratio of the content (total content) of particles selected from the group consisting of magnesium oxide and the content of the component (C) is 1: 0.2 to 1:20, respectively. Preferably, it is 1: 1 to 1:10.

(Component (D))
The component (D) is at least one polymer selected from the group consisting of the component (D1) and the component (D2). By using the component (D), the hairdressing composition is appropriately thickened, so that the dispersibility of the component (A) is further improved, and the hairdressing composition is more difficult to separate, so that the storage stability is improved. Even better. In addition, the hair styling property is further improved. As for the said component (D), only 1 type may be used and 2 or more types may be used. In addition, only 1 type may be used for said component (D1) and said component (D2), respectively, and 2 or more types may be used.

  The monomer component used to obtain the polymer of the component (D1) includes at least two or more monomers selected from the group consisting of (meth) acrylic acid and (meth) acrylic acid alkyl esters. That is, the component (D1) is a polymer containing at least two or more structural units selected from the group consisting of structural units derived from (meth) acrylic acid and structural units derived from (meth) acrylic acid alkyl esters. . In this specification, the polymer that can correspond to both the component (D1) and the component (D2) is not the component (D1) but the component (D2).

  Although it does not specifically limit as said component (D1), INCI name (International Cosmetic Ingredient Dictionary and Handbook, 14th edition, the 1st volume, CTFA, 2012, p.60-61) "ACRYLATES COPOLYMER ) "Is preferred.

  As a commercial item of the said component (D1), the Dow Chemical company make, a brand name "Aculin 33", and a brand name "Aculin 33A"; SEPPIC company make, a brand name "SepiMAX ZEN" etc. are mentioned, for example.

  The component (D1) is not particularly limited, but is preferably neutralized with a basic substance or used after being neutralized with a basic substance. Examples of the basic substance include alkanolamines such as triethanolamine and monoethanolamine; inorganic bases such as ammonia, sodium hydroxide, and potassium hydroxide; basic amino acids such as arginine. The basic substance is added in an amount sufficient to neutralize the component (D1), or an amount sufficient to neutralize the component (D1). ) And the type of the basic substance and the amount of the component (D1) used may be appropriately blended.

  The monomer component used to obtain the polymer of the component (D2) is at least one monomer component (d2a) selected from the group consisting of (meth) acrylic acid and (meth) acrylic acid alkyl ester, and (meth) And at least one monomer component (d2b) selected from the group consisting of polyoxyethylene alkyl ethers of acrylic acid, polyoxyethylene alkyl ethers of itaconic acid and vinyl neodecanoate. That is, the component (D2) is a polymer including at least a structural unit derived from the monomer component (d2a) and a structural unit derived from the monomer component (d2b). As for the said monomer component (d2a) and the said monomer component (d2b), only 1 type may respectively be used and 2 or more types may be used.

  Although it does not specifically limit as said component (D2), INCI name (International Cosmetic Ingredient Dictionary and Handbook, the 14th edition, the 1st volume, CTFA, 2012, p.66-67) "ACRYLATES / STEARETH-20 METHACRYLATE "POLYMER (Acrylates / Stearless Methacrylic Acid-20) Copolymer)"; "CIRYLATES" under the INCI name (International Cosmetic Ingredient Dictionary and Handbook, 14th edition, Volume 1, CTFA, 2012, p. 67) / STEARETH-20 METHACRYLATE CROSSPOLYM ER ((Acrylates / Stearless Methacrylic Acid-20) Crosspolymer) ”; the INCI name (International Cosmetic Ingredient Dictionary and Handbook, 14th edition, Volume 1, CTFA, 2012, p. 57) ACRYLATES / BEHENETH-25 METHACRYLATE COPOLYMER ((Acrylates / Beheneth-25 methacrylate) copolymer) ”; INCI name (International Cosmetic Ingredient Dictionary and Handbook, 14th edition, 20th edition, CT, p. 20, 68-69) "ACRYLATES / VINYL NEODECA A compound named “OATE CROSSPOLYMER ((Acrylates / Vinyl neodecanoate) crosspolymer)”; “ACRYLATES” under the INCI name (International Cosmetic Ingredient Dictionary and Handbook, 14th Edition, Volume 1, CTFA, 2012, p. 66) / STEARETTH-20 ITACONATE COPOLYMER ((Acrylates / Stearless Titaconate-20) Copolymer) ”; INCI name (International Cosmetic Ingredient Dictionary and Handbook, 14th edition, Vol. 1, p. 60), a compound represented by “ACRYLATES / CETETH-20 ITACONATE COPOLYMER ((acrylates / cetaconic acid ceteth-20) copolymer)” is preferable.

  As a commercial item of the said component (D2), the product made from Dow Chemical Co., Ltd., the brand name "Aculin 22", the brand name "Aculin 88", the brand name "Aculin 28", and the brand name "Aculin 38"; , Trade name “STRUCTURE 2001”, trade name “STRUCTURE 3001”, and the like.

  The component (D2) is not particularly limited, but is preferably neutralized with a basic substance or used after being neutralized with a basic substance. Examples of the basic substance in this case include the basic substances described above. The basic substance is added in an amount sufficient to neutralize the component (D2), or an amount sufficient to neutralize the component (D2). ) And the type of the basic substance and the amount of the component (D2) used may be appropriately blended.

  In 100% by mass of the hairdressing composition according to the present invention, the content of the component (D) is preferably 0.01% by mass or more, more preferably 0.1% by mass or more, and preferably 5% by mass or less. Preferably it is 2 mass% or less. When the content of the component (D) is not less than the above lower limit, the effect of imparting gloss and the storage stability of the hairdressing composition are further improved. When the content of the component (D) is not more than the above upper limit, the hair styling power is further improved and the feel of the hair is further improved. Content of the said component (D) is a total amount of content of all the components (D) in the hairdressing agent composition which concerns on this invention. In addition, especially when using the said component (D '), 0 mass% (unused) may be sufficient as content of the said component (D) in 100 mass% of hairdressing composition based on this invention.

(Ingredient (D ′))
The component (D ′) is a polysaccharide compound. By using the component (D ′), the hairdressing composition is moderately thickened, so that the dispersibility of the component (A) is further improved, and the hairdressing composition is more difficult to separate, so that the storage stability is improved. Becomes even better. As for the said component (D '), only 1 type may be used and 2 or more types may be used.

  Although it does not specifically limit as said component (D '), A polysaccharide, modified polysaccharide (for example, alkyl modified polysaccharide etc.), etc. are preferable, for example, alginic acid, carrageenan, agar, fercelan, guar gum, quince seed, konjac mannan, tamarind gum Plant-derived polysaccharide compounds such as tara gum, dextrin, starch, locust bean gum, gum arabic, gati gum, karaya gum, tragacanth gum, arabinogalactan, pectin and quince; animal-derived polysaccharide compounds such as chitosan and hyaluronic acid; Microbial-derived polysaccharide compounds such as xanthan gum, gellan gum, cyclodextrin, dextran, pullulan and hyaluronic acid; microcrystalline cellulose, methylcellulose, ethylcellulose, hydroxymethylcellulose Nonionic cellulose such as hydroxyethylcellulose, hydroxypropylcellulose and hydroxypropylmethylcellulose; anionic cellulose such as carboxymethylcellulose; cationization such as O- [2-hydroxy-3- (trimethylammonio) propyl] hydroxyethylcellulose chloride Cellulose; and cationized guar gum such as O- [2-hydroxy-3- (trimethylammonio) propyl] guar gum.

  As the component (D ′), among these, a compound selected from the group consisting of xanthan gum, guar gum, tamarind gum and gellan gum (at least one compound) is preferable.

  Examples of commercially available products of the component (D ′) include xanthan gum manufactured by Dainippon Sumitomo Pharma Co., Ltd., trade name “Echo Gum T”, trade name “Keldent”, and trade name “Monato Gum”; Product name “Ingel Guar Gum CS”; manufactured by DSP Gokyo Food & Chemical Co., a tamarind gum, product name “Glyroid 6C”; CP Kelco U. S. , Inc. Manufactured and trade name "Kelcogel".

  In 100% by mass of the hairdressing composition according to the present invention, the content of the component (D ′) is preferably 0.01% by mass or more, more preferably 0.1% by mass or more, preferably 5% by mass or less. More preferably, it is 2 mass% or less. When the content of the component (D ′) is not less than the above lower limit, the storage stability of the hairdressing composition is further improved. When the content of the component (D ′) is not more than the above upper limit, the stickiness becomes even better. The content of the component (D ′) is the total content of all the components (D ′) in the hairdressing composition according to the present invention. In particular, when the component (D) is used, the content of the component (D ′) may be 0% by mass (unused) in 100% by mass of the hairdressing composition according to the present invention.

(Ingredient (E))
The component (E) is a clay mineral. By using the component (E), the hair styling power and the storage stability of the hair styling composition are further improved. As for the said component (E), only 1 type may be used and 2 or more types may be used.

  The component (E) may be a natural product or a synthetic product. The component (E) is not particularly limited. For example, kaolin group clay mineral, antigolite group clay mineral, pyrophyllite group clay mineral, mica group clay mineral, smectite group clay mineral, vermiculite group clay mineral, green mud Examples include stone group clay minerals and organically modified clay minerals.

  Examples of the kaolin group clay mineral include kaolin, nacrite, dickite and halosite. Examples of the antigolite group clay mineral include antigolite, amesite, and cronstedite. Examples of the pyrophyllite clay mineral include pyrophyllite and talc (talc). Examples of the mica group clay minerals include illite, sea chlorite, ceradonite, sericite, mica (mica), muscovite, chromium muscovite and biotite. Examples of the smectite clay mineral include bentonite, montmorillonite, beidellite, nontonite, saponite, hectorite, and lucentite. Vermiculite etc. are mentioned as said vermiculite group clay mineral. Examples of the chlorite group clay mineral include chlorite. Examples of the organic modified clay mineral include an organic modified clay mineral obtained by organically modifying a smectite group clay mineral or a vermiculite group clay mineral. A quaternary ammonium salt type cationic surfactant is preferably used for the organic modification treatment. Examples of the quaternary ammonium salt type cationic surfactant include the above alkyltrimethylammonium chloride, dialkyldimethylammonium chloride, and benzalkonium chloride.

  From the viewpoint of further improving storage stability and usability, the component (E) is preferably a clay mineral selected from the group consisting of synthetic silicates and derivatives thereof. The above-mentioned synthetic silicate and its derivative are not a silicate mineral mainly composed of magnesium silicate or silicic acid (sodium / magnesium) derived from nature, which contains impurities, but silicic acid obtained by synthesis. Refers to salts and silicate derivatives.

  Examples of the synthetic silicate and its derivatives include, for example, the INCI name (International Cosmetic Indictional Dictionary and Handbook, 14th edition, Volume 2, CTFA, 2012, p. 3076): SODIUM MAGNESIUM SILICATE Acid (sodium / magnesium), INCI name (International Cosmetic Ingredient Dictionary and Handbook, 14th edition, Volume 2, CTFA, 2012, p. 1793): MAGNESIUM FLUOROSILICATE Magnesium fluorosilicate, Internal name Cosmetic Ingred ent Dictionary and Handbook, 14th edition, Volume 2, CTFA, 2012, p. 3076): SODIUM MAGNESIUM FLUOROSILICATE, fluorosilicic acid (sodium / magnesium), INCI name (International Cosmetic Indicient Hidden Dict. 14th edition, 2nd volume, CTFA, 2012, p. 1799): MAGNESIUM POTASSIUM FLUOROSILIC fluorosilicic acid (magnesium / potassium), INCI name (International Cosmetic Ingredient Dictionary and Handbook, 14th edition) Volume, CTFA, 2012, p. 1800): MAGNESIUM SODIUM FLUOROSILICATE, fluorosilicic acid (magnesium / sodium), INCI name (International Cosmetic Ingredient Dictionary and Handbook, 14th edition, Volume 1, CTFA, 20 , P. 156): synthetic aluminum silicate represented by ALUMINUM SILICATE.

  As the component (E), among them, a clay mineral selected from the group consisting of synthetic silicic acid (sodium / magnesium), fluorosilicic acid (sodium / magnesium), and fluorosilicic acid (sodium / magnesium) (at least one Clay minerals) are particularly preferred.

  As a commercial item of the said component (E), the Rockwood company make, brand name "Laponite XLG", brand name "Laponite XL21", etc. are mentioned, for example.

  In 100% by mass of the hairdressing composition according to the present invention, the content of the component (E) is preferably 0.1% by mass or more, more preferably 0.3% by mass or more, and further preferably 0.5% by mass. As mentioned above, Preferably it is 10 mass% or less, More preferably, it is 5 mass% or less, More preferably, it is 3 mass% or less. When the content of the component (E) is not less than the above lower limit, the hair styling property is further improved. When the content of the component (E) is not more than the above upper limit, the storage stability of the hairdressing composition is further improved.

  From the viewpoint of increasing the viscosity of the hairdressing composition more appropriately and further enhancing the storage stability of the hairdressing composition, the hairdressing composition according to the present invention comprises the component (D) and the component (E ). By the combined use of the component (D) and the component (E), the dispersion stability of the component (A) is further enhanced, and separation of the hairdressing composition is more difficult to occur. Furthermore, since the hairdressing composition shows good thixotropic properties, the applicability of the hairdressing composition is improved.

  When the component (D) and the component (E) are used in combination, the mass ratio of the component (D) and the component (E) (content of the component (D): content of the component (E) The amount) is preferably 1: 0.1 to 1:30, more preferably 1: 0.2 to 1:20, and even more preferably 1: 0.5 to 1:10. . When the above mass ratio is satisfied, the storage stability of the hairdressing composition, particularly the storage stability when stored for a long period of time, becomes even better.

  When using the said component (D) and the said component (E) together, the total amount of content of the said component (D) and content of the said component (E) becomes like this. Preferably it is 0.2 mass% or more, More Preferably it is 0.4 mass% or more, More preferably, it is 0.6 mass% or more, Preferably it is 10 mass% or less, More preferably, it is 8 mass% or less, More preferably, it is 5 mass% or less. When the total amount is within the above range, the storage stability of the hairdressing composition, particularly when stored for a long period of time, is further improved.

(Other ingredients)
The hairdressing composition according to the present invention is not particularly limited, but preferably contains water. Although the said water will not be specifically limited if it is the water used for cosmetics, Purified water is preferable. In 100% by mass of the hairdressing composition according to the present invention, the content of water is preferably 30% by mass or more, more preferably 40% by mass or more, preferably 95% by mass or less, more preferably 90% by mass or less. .

  Moreover, although the hairdressing composition which concerns on this invention is not specifically limited, It is preferable that a C2-C5 lower alcohol (especially ethanol) is included. In 100% by mass of the hairdressing composition according to the present invention, the content of the lower alcohol (particularly ethanol) is preferably 2% by mass or more, more preferably 5% by mass or more, preferably 50% by mass or less, more preferably. 30% by mass or less.

  In the range which does not inhibit the effect of the present invention, for example, a surfactant such as a nonionic surfactant, a cationic surfactant and an amphoteric surfactant; glycerin, 1,3-butylene glycol Polyhydric alcohols such as propylene glycol, 1,2-butanediol, 1,2-pentanediol, 1,2-hexanediol, 1,2-octanediol, 1,2-decanediol; lauryl alcohol, myristyl alcohol, Higher alcohols having 12 to 18 carbon atoms such as cetyl alcohol, stearyl alcohol, isostearyl alcohol, cetostearyl alcohol and oleyl alcohol; sugar alcohols such as sorbitol, maltitol and trehalose; silicone oil; sequestering agent; antioxidant; Plant extract; dye; face ; PH adjusting agents; perfumes; may contain a solvent such as, preservatives.

(Other details of hairdressing composition)
The properties of the hairdressing composition according to the present invention are not particularly limited, but may be any of liquid, gel, cream and solid. The hair styling composition is preferably liquid or gel. Generally, in the liquid or gel hair styling composition, when particles are used, the flowability of the hair styling composition is high. Tends to decrease. As a result, in the liquid or gel hairdressing composition, the initial hairstyling power and the hairstyling holding power tend to be reduced, and stickiness and flaking tend to occur. On the other hand, by adopting the above-described composition in the hairdressing composition according to the present invention, even if it is a liquid or gel hairdressing composition, the occurrence of flaking and stickiness is suppressed, and the initial hairstyling power and hairstyling are achieved. Holding power can be increased.

  The viscosity at 25 ° C. of the hairdressing composition is preferably 1000 mPa · s or more, more preferably 2000 mPa · s or more, preferably 100,000 mPa · s or less, more preferably 50000 mPa · s or less. When the viscosity is not less than the above lower limit and not more than the above upper limit, applicability is further enhanced, flaking and stickiness are further suppressed, and initial hair styling power and hair styling holding power are further enhanced. In the hair styling composition, even if the viscosity is not more than the above upper limit and the fluidity is high, the occurrence of flaking and stickiness can be suppressed, and the initial hair styling power and hair styling holding power can be increased.

  The above viscosity was measured using a viscometer, No. It is measured under the conditions of a rotation speed of 12 rpm and a rotation time of 1 minute using a 4-rotor. A TV-22 type viscometer manufactured by Toki Sangyo Co., Ltd. can be used as the viscometer.

  The manufacturing method of the hairdressing composition which concerns on this invention is not specifically limited, As a manufacturing method of the hairdressing composition which concerns on this invention, the manufacturing method of a well-known hairdressing composition can be used. The method for producing the hairdressing composition according to the present invention is not particularly limited. For example, the component (A) and water (if necessary, the component (E)) are stirred with a disper mixer and then replaced with a paddle mixer. And mixing and homogenizing other components while stirring.

  The hairdressing composition according to the present invention includes at least a component (A) and a component (B) as main hairstyling components. While only component (B) causes stickiness, the combined use of component (A) and component (B) can increase the initial hair-styling power immediately after hair styling while suppressing stickiness, and the hair-styling retention force. Can be increased. In addition, by using the component (B) that is a liquid component at 25 ° C., it is possible to suppress the occurrence of flaking (a phenomenon in which white powder or a film appears to adhere to the hair) when hair is arranged. it can. Thereby, if the hair-styling agent composition according to the present invention is used, not only hair can be properly sculpted, but the state of shampooing can be favorably sustained for a long period of time.

  In addition, by blending the component (C), the hair styling power and flaking suppression effect are further improved, and the effect of shining the hair after hair styling and washing off are improved.

  Furthermore, by blending the component (D) and the component (E), the hairdressing composition is moderately thickened and the applicability of the hairdressing composition is improved. Furthermore, by setting the blending ratio of the component (D) and the component (E) to a specific preferable range, the component (A) is less likely to settle or aggregate, and the storage stability of the hairdressing composition is increased. (Stability during long-term storage) is improved.

  Although the hairdressing composition which concerns on this invention is not specifically limited, For example, it can be used with the form with which the container was filled.

  Examples of the container include a bottle container, a jar container, and a tube container. The container is preferably a bottle container or a tube container.

(Example)
Hereinafter, the present invention will be specifically described with reference to Examples and Comparative Examples. The present invention is not limited only to the following examples.

  In the examples and comparative examples, the following components were used.

(Ingredient (A))
Product name “Silysia 320”: Silica, manufactured by Fuji Silysia Chemical Co., Ltd. Product name “Aerosil 200”: Silica, manufactured by Nippon Aerosil Co., Ltd. Product name “Spherical HAP”: Hydroxyapatite (manufactured by Taihei Chemical Industrial Co., Ltd.)
Product name "FLORITE R": calcium silicate (manufactured by Tomita Pharmaceutical)
Product name "Synthetic aluminum silicate (heavy)": Aluminum silicate (manufactured by Tomita Pharmaceutical)
Product name "Magnesium hydroxide (heavy)": Magnesium hydroxide (Tonda Pharmaceutical)

(Ingredient (B))
Product name "New Paul 75H-90000": Polyoxyethylene polyoxypropylene hexylene glycol ether, manufactured by Sanyo Chemical Industries, number average molecular weight 14000, liquid Product name "New Paul SP-750": Polyoxypropylene sorbit, Sanyo Chemical Manufactured by Kogyo Co., Ltd., number average molecular weight 690, liquid
(Other)
Product name “New Pole 50HB-55”: polyoxyethylene polyoxypropylene butyl ether, manufactured by Sanyo Chemical Industries, Ltd., number average molecular weight 300, liquid

(Ingredient (C))
Product name “Neugen GIS-125”: Polyoxyethylene glyceryl isostearate, manufactured by Daiichi Kogyo Seiyaku Co., Ltd. Product name “Macbiobride MG-10P”: Polyoxypropylene methyl glucoside, manufactured by NOF Corporation

(Component (D))
Product name “Aculin 22”: alkyl acrylate, alkyl methacrylate, polyoxyethylene stearyl ether (20EO) copolymer emulsion, 30% by weight aqueous solution manufactured by Dow Chemical Co., Ltd. Product name “Aculin 28”: Acrylic Alkyl acid / alkyl methacrylate / polyoxyethylene behenyl ether (25EO) copolymer emulsion, manufactured by Dow Chemical Co., Ltd., 20% by mass aqueous solution Product name “Aculin 33A”: alkyl acrylate copolymer emulsion, Dow 28% by mass aqueous solution manufactured by Chemical Co., Ltd. Trade name “Aculin 38”: alkyl acrylate / vinyl neodecanoate cross polymer, 29% by mass aqueous solution manufactured by Dow Chemical

(Ingredient (D ′))
Product name “Echo Gum T”: xanthan gum, manufactured by Dainippon Sumitomo Pharma Co., Ltd.

(Ingredient (E))
Product name “Laponite XL21”: fluorosilicic acid (sodium / magnesium), manufactured by Rockwood Corporation Product name “Laponite XLG”: synthetic silicic acid (sodium / magnesium), manufactured by Rockwood Corporation

(Examples 1-44 and Comparative Examples 1-13)
Blending components shown in the following Tables 1 to 8 were blended (blending unit is mass%) to prepare a hairdressing composition. The properties of the hairdressing composition obtained in Examples 1 to 44 were all gel-like. In addition, the compounding quantity in a table | surface was shown by the actual compounding quantity (composition quantity of goods).

  The obtained hairdressing composition was filled in a plastic container to obtain a hairdressing agent.

(Test Example 1: Evaluation of stickiness)
20 professional panelists apply the above hairdressing composition uniformly onto the hair of the wig (Lesson Mannequin: Eucalyptus Japan), and styling the hair so that the hair is stroked from front to back along the shape of the wig. After giving, I answered whether there was stickiness. From the above answers, stickiness was evaluated according to the following criteria.

<Evaluation criteria for stickiness>
○ (Remarkably good): More than 16 out of 20 responded that there was no stickiness △ (Good): 10-15 out of 20 responded that there was no stickiness × (Bad): 9 or less out of 20 Responded that there was no stickiness

(Test Example 2: Evaluation of initial hair styling power)
20 professional panelists apply the above hairdressing composition uniformly on the hair of the wig (Lesson Mannequin: Eucalyptus Japan), and shave the hair from the front to the back along the shape of the wig. After applying, the answer was whether there was any initial hair styling ability. In addition, it was determined that there was an initial hair-styling ability if the shape of the hair that had been styled was clearly held. From the above answers, initial hair styling power was evaluated according to the following criteria.

<Evaluation criteria for initial hair styling power>
○ (Remarkably good): More than 16 out of 20 responded that they had initial hair styling △ (Good): 10 to 15 out of 20 responded that they had initial hair styling power × (Bad): Out of 20 Nine or less responded that they had initial hair styling

(Test Example 3: Evaluation of hair holding ability)
Twenty expert panels observed the hair of the wig that had undergone hair styling after 6 hours after the above Test Example 2 (evaluation of initial hair styling ability), and answered whether hair was retained. In addition, it was determined that there was a hair-styling holding power when the hair shape of Test Example 2 continued to be held. Based on the above answers, hair holding ability was evaluated according to the following criteria.

<Evaluation criteria for hair styling retention power>
○ (Remarkably good): More than 16 out of 20 responded that they have hair styling retention △ (Good): 10 to 15 out of 20 responded that they had hair styling retention × (Poor): Out of 20 Nine or less responded that they have hair styling retention

(Test Example 4: Evaluation of flaking)
Twenty expert panels combed the hair of the wig from the root of the hair to the tip of the hair with the fingertips five times after the above Test Example 3 (evaluation of hair holding ability), and answered the presence or absence of flaking. In addition, when it appeared that white powder had adhered on the hair, it determined with there being flaking. From the above answers, flaking was evaluated according to the following criteria.

<Evaluation criteria for flaking>
○ (Remarkably good): More than 16 out of 20 responded that there was no flaking △ (Good): 10-15 out of 20 responded that there was no flaking × (Poor): 9 out of 20 The following responded that there was no flaking

(Test Example 5: Evaluation of washing off)
After 20 specialist panels, after the above test example 4 (evaluation of flaking), the hair of the wig was shampooed using a shampoo (trade name “Lucido Shampoo”, manufactured by Mandom Co., Ltd.), washed with warm water, and then dried. The answer was good or bad. In addition, when there was no squeaky feeling or sticky feeling at the time of shampooing, it was said that washing off was good. From the above answers, wash-off was evaluated according to the following criteria.

<Evaluation criteria for wash-off>
○ (Remarkably good): More than 16 out of 20 responded that the wash-off was good. △ (Good): 10-15 out of 20 answered that the wash-out was good. × (Bad): 9 out of 20 The following are good to wash off

(Test Example 6: Evaluation of gloss)
20 expert panels answered the presence or absence of gloss of the hair of the wig after the above Test Example 2 (evaluation of initial hair styling ability). From the above answers, gloss was evaluated according to the following criteria.

<Evaluation criteria for hair gloss>
○ (Remarkably good): 16 or more out of 20 responded that they were shiny △ (Good): 10 to 15 out of 20 responded that they were shiny × (Poor): 9 or less of 20 persons answered Answers that are shiny

  The results are shown in Tables 1 to 8 below. The sum total of the compounding component in each Example and each comparative example of Tables 1-8 is 100 mass%.

Claims (5)

Including the following component A, the following component B, and the following component E ,
The content of the component A is 0.1% by mass or more and 10% by mass or less,
The content of the component B is 3 mass% or more, Ru der 40 wt% or less, hair fixative composition.
Component A: Particles selected from the group consisting of silica, calcium carbonate, magnesium carbonate, hydroxyapatite, titanium oxide, zinc oxide, calcium silicate, magnesium silicate, aluminum silicate, and magnesium hydroxide Component B: at 25 ° C From a polyoxyethylene / polyoxypropylene copolymer that is liquid and has a number average molecular weight of 10,000 to 20000, and a polyoxypropylene sorbite that is liquid at 25 ° C. and has a number average molecular weight of 300 to 1,000 A compound selected from the group consisting of
Component E: Clay mineral Further comprises the following component C, hair fixative composition according to claim 1.
Component C: Compound selected from the group consisting of polyoxyalkylene alkyl glucoside and polyoxyalkylene glycerin fatty acid ester The hairdressing composition according to claim 1 or 2, comprising a component selected from the group consisting of the following component D1, the following component D2, and the following component D '.
Component D1: Polymer obtained using two or more monomers selected from the group consisting of (meth) acrylic acid and (meth) acrylic acid alkyl esters as essential monomer components
  Component D2: As an essential monomer component, a monomer selected from the group consisting of (meth) acrylic acid and (meth) acrylic acid alkyl ester, (meth) acrylic acid polyoxyethylene alkyl ether, itaconic acid polyoxyethylene alkyl Polymer obtained by using a monomer selected from the group consisting of ether and vinyl neodecanoate
Component D ': polysaccharide compound Containing component D is selected from the group consisting of pre-SL component D1 and before SL component D2 polymer hair fixative composition according to claim 3. The hairdressing composition according to claim 3 or 4, comprising the component D '.