CN110831572A - Composition for hair treatment and spray cosmetic for hair treatment - Google Patents
Composition for hair treatment and spray cosmetic for hair treatment Download PDFInfo
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- CN110831572A CN110831572A CN201880043427.6A CN201880043427A CN110831572A CN 110831572 A CN110831572 A CN 110831572A CN 201880043427 A CN201880043427 A CN 201880043427A CN 110831572 A CN110831572 A CN 110831572A
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- hair treatment
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- treatment composition
- polyoxyethylene
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- A61K8/8147—Homopolymers or copolymers of acids; Metal or ammonium salts thereof, e.g. crotonic acid, (meth)acrylic acid; Compositions of derivatives of such polymers
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/86—Polyethers
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/59—Mixtures
- A61K2800/596—Mixtures of surface active compounds
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/80—Process related aspects concerning the preparation of the cosmetic composition or the storage or application thereof
- A61K2800/87—Application Devices; Containers; Packaging
Abstract
Provided is a hair treatment composition which is filled in a container and which, when discharged in the form of a mist by a pump dispenser or a trigger dispenser, is less likely to damage the hairstyle to be finished even when subjected to external impact and can maintain the finished hairstyle for a long period of time. The hair treatment composition of the present invention is a hair treatment composition which is filled in a container and is discharged in a mist form by a pump dispenser or a trigger dispenser, and contains a film-forming polymer (component a), an oxyalkylene addition polymer of a sugar alcohol (component B), and ethanol (component C).
Description
Technical Field
The present invention relates to a hair treatment composition which is filled in a container and is discharged in the form of mist by means of a pump dispenser or a trigger dispenser. The present invention also relates to a spray cosmetic for hair treatment using the hair treatment composition.
Background
Hair treatment compositions which are filled into a container and are discharged in the form of a mist using a pump dispenser or a trigger dispenser are known. When the composition is discharged in the form of mist, the composition can be uniformly applied to the hair over a wide range, and the composition can be prevented from dripping from the hair after application, and therefore, the feeling of use is excellent.
Conventionally, hair treatment compositions that are discharged in a mist form are imparted with hair styling properties or conditioning properties depending on the composition design.
Patent documents 1 to 3 listed below disclose hair treatment compositions that can be discharged in a mist form.
Patent document 1 below discloses a composition containing 0.01 to 10.0 wt% of a vinylpyrrolidone polymer having a weight average molecular weight of 1000 or more and less than 16 ten thousand, 0.01 to 5.0 wt% of a vinylpyrrolidone polymer having a weight average molecular weight of 16 ten thousand or more and 3000 ten thousand, and water. The composition may be discharged in the form of a mist.
Patent document 2 below discloses a composition containing a hydroxyalkyl urea, an alkylene oxide derivative, and a hydrophilic polyether-modified silicone. The composition may be discharged in the form of a mist.
Patent document 3 below discloses a composition containing two copolymers having a specific structural unit, ethanol, and water. The composition is a composition that is emitted in the form of a mist.
In general hair treatment compositions that are commercially available, a large amount of a film-forming component (film-forming polymer) is often blended in order to exhibit excellent hair styling properties, and the film-forming component can form a strong film on hair.
Documents of the prior art
Patent document
Patent document 1: japanese patent laid-open publication No. 2003-081786
Patent document 2: japanese laid-open patent publication No. 2009-234985
Patent document 3: japanese patent laid-open publication No. 2017-036229
Disclosure of Invention
Problems to be solved by the invention
When a coating forming component (coating forming polymer) is added to the hair treatment composition discharged in the form of mist, excellent hair styling performance can be imparted. However, when a coating forming component (coating forming polymer) is blended in a hair treatment composition, a coating formed between hairs becomes too hard, and a finished hair style is easily damaged by external impact such as a comb or wind. Further, when the film formed between the hairs is disintegrated, the finished hair style cannot be maintained for a long time.
Although the composition of patent document 1 can improve the hair styling ability to some extent, the finished hair style is easily damaged by external impact, and the finished hair style may not be maintained for a long time.
In the compositions of patent documents 2 and 3, the finished hair style is easily damaged by external impact, and the finished hair style may not be retained for a long time.
The present invention aims to provide a hair treatment composition which is filled in a container and which, when discharged in the form of a mist by a pump dispenser or a trigger dispenser, is less likely to damage the hairstyle to be finished even when subjected to external impact and which can maintain the finished hairstyle for a long period of time. Another object of the present invention is to provide a spray cosmetic for hair treatment using the hair treatment composition.
Means for solving the problems
The present invention provides a hair treatment composition which is filled in a container and is discharged in a mist form by a pump dispenser or a trigger dispenser, wherein the hair treatment composition contains the following component (a), the following component (B), and the following component (C).
Component (A): film-forming polymer
Component (B): oxyalkylene addition polymer of sugar alcohol
Component (C): ethanol
The hair treatment composition of the present invention preferably contains the following component (a1) as the component (a).
Component (a 1): anionic coating forming polymer obtained using alkyl (meth) acrylate as essential monomer component
The hair treatment composition of the present invention preferably contains the following component (a11) as the component (a).
Component (a 11): anionic film-forming polymer selected from the group consisting of (acrylic acid/C1-18 alkanol acrylate/C1-8 alkyl acrylamide) copolymer and (alkyl acrylate/diacetone acrylamide) copolymer
The hair treatment composition of the present invention preferably contains the following component (B1) as the component (B).
Component (B1): polyoxypropylene sorbitol
The hair treatment composition of the present invention preferably contains the following component (D).
Component (D): nonionic surfactant
The hair treatment composition of the present invention preferably contains the following component (D1) as the component (D).
Ingredient (D1): nonionic surfactant selected from the group consisting of polyoxyethylene glyceryl monoisostearate, polyoxyethylene hydrogenated castor oil monoisostearate, polyoxyethylene butylene glycol monoisostearate and polyoxyethylene hydrogenated castor oil
The hair treatment composition of the present invention is preferably a hair styling composition.
The present invention provides a spray cosmetic for hair treatment, which comprises: a container having a container body and a pump or trigger dispenser; and the hair treatment composition, wherein the container is filled with the hair treatment composition.
ADVANTAGEOUS EFFECTS OF INVENTION
The hair treatment composition of the present invention is a hair treatment composition which is filled in a container and discharged in the form of mist by a pump dispenser or a trigger dispenser. Since the hair treatment composition of the present invention contains the specific components (a), (B), and (C), when the composition is filled in a container and then discharged in the form of mist by a pump dispenser or a trigger dispenser, the hairstyle set is not easily damaged even by external impact, and the hairstyle set can be maintained for a long period of time.
Detailed Description
The present invention will be described in detail below.
The hair treatment composition of the present invention is filled in a container and is used by being discharged in the form of mist by a pump dispenser or a trigger dispenser. The hair treatment composition of the present invention is usually a liquid composition which is liquid at 25 ℃ because it is discharged in a mist form. The mist (ミスト) includes a mist (mist).
The hair treatment composition of the present invention contains a film-forming polymer, an oxyalkylene addition polymer of a sugar alcohol, and ethanol.
In the present specification, the "coating forming polymer" may be referred to as "component (a)".
In the present specification, the "oxyalkylene addition polymer of a sugar alcohol" may be referred to as "component (B)".
In the present specification, the "ethanol" may be referred to as "component (C)".
The hair treatment composition of the present invention contains component (a), component (B), and component (C). The present inventors have found that a coating film capable of maintaining the adhesion between hairs for a long period of time can be formed by using a composition containing the component (a), the component (B), and the component (C) in the hair treatment composition. According to the above composition, the present invention can maintain the finished hair style for a long time without damaging the finished hair style even when external impact is applied.
The hair treatment composition of the present invention preferably contains a nonionic surfactant.
In the present specification, the "nonionic surfactant" may be referred to as "component (D)".
The hair treatment composition of the present invention may contain other components in addition to the components (a) to (D).
The above-mentioned components, for example, the component (A), the component (B), the component (C), the component (D) and others may be used alone or in combination of two or more.
The following will describe the details of the components used in the hair treatment composition of the present invention.
(component (A))
The component (a) is a film-forming polymer. The component (a) functions as a main hair styling component. Further, by using the component (a) together with the components (B) and (C), the finished hair style is not easily damaged even by external impact, and the finished hair style can be maintained for a long time. The component (A) may be used alone or in combination of two or more.
Examples of the component (a) include an anionic coating forming polymer, a cationic coating forming polymer, an amphoteric coating forming polymer, and a nonionic coating forming polymer.
Examples of the anionic coating forming polymer include alkyl (meth) acrylate copolymers, (meth) acrylic acid/alkyl (meth) acrylate copolymers, (acrylic acid/ester/C1-18 alkanol acrylate/C1-8 alkyl acrylamide) copolymers, (alkyl acrylate/diacetone acrylamide) copolymers, methyl vinyl ether/maleic acid ester copolymers, vinyl acetate/crotonic acid/vinyl neodecanoate copolymers, vinyl acetate/crotonic acid/vinyl propionate copolymers, vinyl acetate/monobutyl maleate/isobornyl acrylate copolymers, polyvinylpyrrolidone/acrylate/(meth) acrylic acid copolymers, vinyl acetate copolymers, vinyl butyrate, A (styrene/alkyl acrylate) copolymer, a (styrene/acrylamide) copolymer, a urethane-acrylic acid copolymer, sodium polystyrene sulfonate, and the like. In addition, "(meth) acrylic acid" means both "acrylic acid" and "methacrylic acid".
Examples of the cationic coating forming polymer include vinylpyrrolidone/N, N-dimethylaminoethylmethacrylate copolymer diethyl sulfate, oxolo- [ 2-hydroxy-3- (trimethylammonium) propyl ] hydroxyethylcellulose, vinylimidazolium trichloride/vinylpyrrolidone copolymer, hydroxyethylcellulose/dimethyldiallylammonium chloride, polyvinylpyrrolidone/alkylaminoacrylate/vinylcaprolactam copolymer, chloromethylvinylimidazolium-vinylpyrrolidone copolymer and (vinylpyrrolidone/dimethylaminopropylmethacrylamide/lauryldimethylaminopropylmethacrylamide) copolymer.
Examples of the amphoteric coating forming polymer include N-methacryloyloxyethyl N, N-dimethylammonium- α -N-methylcarboxylbetaine-alkyl methacrylate copolymer, N-dimethyl-N- (2-methacryloyloxyethyl) amine-N-oxide-alkyl methacrylate copolymer, hydroxypropyl acrylate/butylaminoethyl methacrylate/octylamide acrylate copolymer, and monochloroacetic acid amphoteric product of dialkylaminoethyl methacrylate/alkyl methacrylate copolymer, and (isobutylene/diethylaminopropylmaleimide/maleic acid) copolymer.
Examples of the nonionic film-forming polymer include polyvinyl alcohol, polyvinylpyrrolidone, vinylpyrrolidone/vinyl acetate copolymer, vinyl methyl ether/ethyl maleate copolymer, and polyvinyl caprolactam.
The component (a) preferably contains an anionic coating forming polymer obtained by using an alkyl (meth) acrylate as an essential monomer component, from the viewpoint that a coating capable of maintaining the adhesive force between hairs for a long period of time is formed, the finished hair style is less likely to be damaged even if external impact is applied, and the finished hair style can be maintained for a longer period of time.
In the present specification, the "anionic coating forming polymer obtained by using an alkyl (meth) acrylate as an essential monomer component" may be referred to as "component (a 1)".
Therefore, in the hair treatment composition of the present invention, the component (a) preferably contains the component (a 1).
From the viewpoint of forming a coating film capable of maintaining the adhesion between hairs for a long period of time, making the finished hair style even more less likely to be damaged even by external impact, and further maintaining the finished hair style for a long period of time, the component (a) more preferably contains an anionic coating film-forming polymer (at least one anionic coating film-forming polymer) selected from the group consisting of (acrylic acid (ester)/C1-18 alkanol acrylate/C1-8 alkyl acrylamide) copolymer and (alkyl acrylate/diacetone acrylamide) copolymer.
In the present specification, the "anionic coating forming polymer selected from the group consisting of (acrylic acid (ester)/C1-18 alkanol acrylate/C1-8 alkyl acrylamide) copolymer and (alkyl acrylate/diacetone acrylamide) copolymer" may be referred to as "component (a 11)".
Therefore, in the hair treatment composition of the present invention, the component (a) more preferably contains the component (a 11).
In the hair treatment composition of the present invention, the component (a11) most preferably contains both an (acrylic acid (ester)/C1-18 alkanol acrylate/C1-8 alkyl acrylamide) copolymer and an (alkyl acrylate/diacetone acrylamide) copolymer.
The component (a11) can be neutralized with sodium salt, ammonium salt, triethanolamine salt, 2-amino-2-methyl-1-propanol salt (AMP), 2-amino-2-methyl-1, 3-propanediol salt (AMPD), and the like.
The content of the component (a) in 100% by mass of the hair treatment composition of the present invention is preferably 2% by mass or more, more preferably 3% by mass or more, preferably 10% by mass or less, more preferably 8% by mass or less. When the content of the component (a) is not less than the above lower limit, the finished hair style is less likely to be damaged, and the finished hair style can be maintained for a longer period of time. If the content of the component (a) is not more than the upper limit, the occurrence of clogging due to the hair treatment composition remaining in the discharge port of the dispenser can be suppressed. The content of the component (a) is the total of the contents of all the components (a) in the hair treatment composition of the present invention.
The content of the component (a1) in 100% by mass of the hair treatment composition of the present invention is preferably 2% by mass or more, more preferably 3% by mass or more, preferably 10% by mass or less, more preferably 8% by mass or less. When the content of the component (a1) is not less than the lower limit, the finished hair style is less likely to be damaged, and the finished hair style can be maintained for a longer period of time. If the content of the component (a1) is not more than the upper limit, the occurrence of clogging due to the hair treatment composition remaining in the discharge port of the dispenser can be suppressed. The content of the component (a1) is the total content of all the components (a1) in the hair treatment composition of the present invention.
The content of the component (a11) in 100% by mass of the hair treatment composition of the present invention is preferably 2% by mass or more, more preferably 3% by mass or more, preferably 10% by mass or less, more preferably 8% by mass or less. When the content of the component (a11) is not less than the lower limit, the finished hair style is less likely to be damaged, and the finished hair style can be maintained for a longer period of time. If the content of the component (a11) is not more than the upper limit, the occurrence of clogging due to the hair treatment composition remaining in the discharge port of the dispenser can be suppressed. The content of the component (a11) is the total of all the components (a11) in the hair treatment composition of the present invention.
(component (B))
The component (B) is an oxyalkylene addition polymer of a sugar alcohol. By using the component (B), adhesion can be imparted between hairs. Further, by using the component (B) together with the components (a) and (C), the finished hair style is not easily damaged even by external impact, and the finished hair style can be maintained for a long time. The component (B) may be used alone or in combination of two or more.
The component (B) can be obtained, for example, by adding an oxyalkylene group to a sugar alcohol. Examples of the sugar alcohol include sorbitol and maltitol. Examples of the oxyalkylene group (oxyalkylene group) include oxyethylene group (oxyethylene group), oxypropylene group (oxypropylene group), and the like.
The component (B) preferably contains polyoxypropylene sorbitol in order to improve the adhesion between hairs, thereby making it less likely that the finished hair style will be damaged even by external impact and to maintain the finished hair style for a longer period of time. Polyoxypropylene sorbitol is a propylene oxide addition polymer of sorbitol.
In the present specification, the above-mentioned "polyoxypropylene sorbitol" may be referred to as "component (B1)".
Therefore, in the hair treatment composition of the present invention, the component (B) preferably contains the component (B1).
The component (B1) is a different component from the component (D).
When the component (B) includes the component (B1), the number average molecular weight of the component (B1) is not particularly limited. The number average molecular weight of the component (B1) is preferably 200 or more, more preferably 300 or more, preferably 1000 or less, more preferably 900 or less, from the viewpoint of imparting good adhesion between the hair to be styled.
The content of the component (B) in 100% by mass of the hair treatment composition of the present invention is preferably 2% by mass or more, more preferably 2.5% by mass or more, preferably 10% by mass or less, more preferably 7% by mass or less. When the content of the component (B) is not less than the lower limit and not more than the upper limit, the finished hair style is less likely to be damaged, and the finished hair style can be maintained for a longer period of time. The content of the component (B) is the total of the contents of all the components (B) in the hair treatment composition of the present invention.
The content of the component (B1) in 100% by mass of the hair treatment composition of the present invention is preferably 2% by mass or more, more preferably 2.5% by mass or more, preferably 10% by mass or less, more preferably 7% by mass or less. When the content of the component (B1) is not less than the lower limit and not more than the upper limit, the finished hair style is less likely to be damaged, and the finished hair style can be maintained for a longer period of time. The content of the component (B1) is the total content of all the components (B1) in the hair treatment composition of the present invention.
(component (C))
The component (C) is ethanol. By using the component (C), the hair treatment composition can be discharged in a mist form well, and the discharge stability of the hair treatment composition can be improved. Further, by using the component (C), the tack can be reduced while improving the quick-drying property at the time of coating.
The content of the component (C) in 100% by mass of the hair treatment composition of the present invention is preferably 30% by mass or more, more preferably 35% by mass or more, further preferably 40% by mass or more, preferably 95% by mass or less, more preferably 90% by mass or less, further preferably 80% by mass or less. When the content of the component (C) is not less than the lower limit, the discharge stability can be further improved.
(component (D))
Component (D) is a nonionic surfactant. By using the component (D), the hair can be easily gathered to form a thick hair bundle. Further, by using the component (D), the hair styling performance by the component (A) can be effectively improved. Further, by using the component (D), the hair treatment composition can be discharged well. The component (D) may be used alone or in combination of two or more.
Examples of the component (D) include linear polyoxyalkylene fatty acid esters such as polyethylene glycol fatty acid esters and polyoxyethylene alkyl ether fatty acid esters; multi-chain polyoxyalkylene fatty acid esters such as polyoxyethylene butanediol ether fatty acid esters, polyoxyethylene glyceryl ether fatty acid esters, polyoxyethylene sorbitan fatty acid esters, polyoxyethylene hydrogenated castor oil ethers, polyoxyethylene hydrogenated castor oil ether fatty acid esters, and polyoxyethylene trimethylolpropane ether fatty acid esters; polyoxyalkylene alkyl ethers such as polyoxyethylene alkyl ethers and polyoxyethylene-polyoxypropylene alkyl ethers; and fatty acid esters such as glycerin fatty acid ester, polyglycerin fatty acid ester, sorbitan fatty acid ester, and alkylene glycol fatty acid ester.
Examples of the polyoxyethylene butylene glycol fatty acid ester include polyoxyethylene butylene isostearate and polyoxyethylene butylene diisostearate. The average number of moles of ethylene oxide (polyoxyethylene group) added to the polyoxyethylene butanediol ether fatty acid ester is not particularly limited, but is preferably 5 or more and preferably 70 or less.
Examples of the polyoxyethylene glyceryl ether fatty acid ester include polyoxyethylene glyceryl monolaurate, polyoxyethylene glyceryl monostearate, polyoxyethylene glyceryl distearate, polyoxyethylene glyceryl tristearate, polyoxyethylene glyceryl monooleate, polyoxyethylene glyceryl trioleate, polyoxyethylene glyceryl monoisostearate, polyoxyethylene glyceryl diisostearate, and polyoxyethylene glyceryl triisostearate. The average number of moles of ethylene oxide (polyoxyethylene group) added to the polyoxyethylene glycerin ether fatty acid ester is not particularly limited, and is preferably 3 or more and preferably 70 or less.
Examples of the polyoxyethylene sorbitan fatty acid ester include monolauric acid polyoxyethylene sorbitan, monopalmitic acid polyoxyethylene sorbitan, monostearate polyoxyethylene sorbitan, monooleate polyoxyethylene sorbitan, monoisostearic acid polyoxyethylene sorbitan, coconut oil fatty acid polyoxyethylene sorbitan, tristearic acid polyoxyethylene sorbitan, trioleic acid polyoxyethylene sorbitan, and the like. The average number of moles of ethylene oxide (polyoxyethylene group) added to the polyoxyethylene sorbitan fatty acid ester is not particularly limited, but is preferably 10 or more and preferably 200 or less.
Examples of the polyoxyethylene hydrogenated castor oil ether include polyoxyethylene hydrogenated castor oil and the like. The average addition mole number of the ethylene oxide (polyoxyethylene group) of the polyoxyethylene hydrogenated castor oil ether is not particularly limited, and is preferably 10 or more and preferably 120 or less.
Examples of the polyoxyethylene hydrogenated castor oil ether fatty acid ester include polyoxyethylene hydrogenated castor oil monolaurate, polyoxyethylene hydrogenated castor oil monoisostearate, and polyoxyethylene hydrogenated castor oil triisostearate. The average number of moles of ethylene oxide (polyoxyethylene group) added to the polyoxyethylene hydrogenated castor oil ether fatty acid ester is not particularly limited, and is preferably 3 or more and preferably 70 or less.
Examples of the polyoxyethylene trimethylolpropane ether fatty acid ester include trimyristic acid polyoxyethylene trimethylolpropane, distearic acid polyoxyethylene trimethylolpropane, tristearic acid polyoxyethylene trimethylolpropane, triisostearic acid polyoxyethylene trimethylolpropane, and the like. The average number of moles of ethylene oxide (polyoxyethylene group) added to the polyoxyethylene trimethylolpropane ether fatty acid ester is not particularly limited, but is preferably 3 or more, and preferably 50 or less.
The component (D) preferably contains a multi-chain polyoxyalkylene fatty acid ester in order to more effectively improve the hair styling performance of the component (a), to make the finished hair style less likely to be damaged even by external impact, and to maintain the finished hair style for a longer period of time.
Therefore, in the hair treatment composition of the present invention, the component (D) preferably contains a multi-chain polyoxyalkylene fatty acid ester.
From the viewpoint of more effectively improving the hair styling performance by the component (a), further, making the finished hair style less likely to be damaged even by external impact, and maintaining the finished hair style for a longer period of time, the component (D) more preferably contains a nonionic surfactant (at least one nonionic surfactant) selected from the group consisting of polyoxyethylene glyceryl monoisostearate, polyoxyethylene hydrogenated castor oil monoisostearate, polyoxyethylene butylene glycol monoisostearate, and polyoxyethylene hydrogenated castor oil.
In the present specification, the "nonionic surfactant selected from the group consisting of polyoxyethylene glyceryl monoisostearate, polyoxyethylene hydrogenated castor oil monoisostearate, polyoxyethylene butylene glycol monoisostearate and polyoxyethylene hydrogenated castor oil" may be referred to as "component (D1)".
Therefore, in the hair treatment composition of the present invention, the component (D) more preferably contains the component (D1).
The content of the component (D) in 100% by mass of the hair treatment composition of the present invention is preferably 0.1% by mass or more, more preferably 0.5% by mass or more, preferably 5% by mass or less, more preferably 4% by mass or less. When the content of the component (D) is not less than the lower limit and not more than the upper limit, the hair styling performance by the component (a) is more effectively improved, and the finished hair style is less likely to be damaged, and the finished hair style can be maintained for a longer period of time. When the content of the component (D) is not less than the lower limit and not more than the upper limit, the hair treatment composition can be discharged more favorably. The content of the component (D) is the total of the contents of all the components (D) in the hair treatment composition of the present invention.
The content of the component (D1) in 100% by mass of the hair treatment composition of the present invention is preferably 0.1% by mass or more, more preferably 0.5% by mass or more, preferably 5% by mass or less, more preferably 4% by mass or less. When the content of the component (D1) is not less than the lower limit and not more than the upper limit, the hair styling performance by the component (a) is more effectively improved, and the finished hair style is less likely to be damaged, and the finished hair style can be maintained for a longer period of time. When the content of the component (D1) is not less than the lower limit and not more than the upper limit, the hair treatment composition can be discharged more favorably. The content of the component (D1) is the total content of all the components (D1) in the hair treatment composition of the present invention.
(other Components)
The hair treatment composition of the present invention may contain water in a range not to impair the effects of the present invention.
When the hair treatment composition of the present invention contains water, the content of water in 100% by mass of the hair treatment composition of the present invention is preferably 60% by mass or less, and more preferably 50% by mass or less. When the water content is not more than the upper limit, the hair treatment composition can be favorably discharged in a mist form, and the tack can be favorably reduced while the quick-drying property at the time of application is favorably improved.
The hair treatment composition of the present invention may contain, as components different from the above components (a) to (D), a polyhydric alcohol, a higher alcohol having 12 to 18 carbon atoms, an ester oil, a hydrocarbon oil, an oil or fat, a silicone oil, a chelating agent, an antioxidant, a plant extract, a pigment, a pH adjuster, a perfume, a preservative, and the like.
Examples of the polyhydric alcohol include glycerin, diglycerin, 1, 3-butanediol, propylene glycol, dipropylene glycol, 1, 2-butanediol, 1, 2-pentanediol, 1, 2-hexanediol, 1, 2-octanediol, 1, 2-decanediol, and polyoxypropylene methyl glucoside.
Examples of the higher alcohol having 12 to 18 carbon atoms include lauryl alcohol, myristyl alcohol, cetyl alcohol, stearyl alcohol, isostearyl alcohol, cetearyl alcohol, oleyl alcohol, and the like.
Examples of the ester oil include isopropyl palmitate, glycerol tri-2-ethylhexanoate, isopropyl myristate, propylene glycol monostearate, propylene glycol monolaurate, and polyglyceryl isostearate.
Examples of the hydrocarbon oil include liquid paraffin, vaseline, squalene, and squalane.
Examples of the oils and fats include olive oil, heaven tree oil, macadamia nut oil, and avocado oil.
Examples of the silicone oil include methyl polysiloxane, methylphenyl polysiloxane, and polymethylhydrosiloxane.
The hair treatment composition of the present invention preferably does not contain a wax that is solid at 25 ℃. The hair treatment composition of the present invention preferably does not contain a hydrocarbon oil which is solid at 25 ℃.
The hair treatment composition of the present invention can be produced by a known method for producing a conventional hair treatment composition. The hair treatment composition of the present invention is not particularly limited, and can be produced by, for example, mixing the component (a), the component (B), the component (C), and other components. A paddle mixer or the like can be used for the mixing.
(details of the composition for Hair treatment and spray cosmetic for Hair treatment)
The hair treatment composition of the present invention is characterized in that it is filled into a container and is discharged in the form of mist by means of a pump dispenser or a trigger dispenser. The hair treatment composition of the present invention is used for a spray cosmetic for hair treatment. When the hair treatment composition of the present invention is used in a spray cosmetic for hair, the composition can be uniformly applied to hair over a wide range without dripping, and hair can be styled without giving a sticky feeling. Further, when the hair treatment composition of the present invention is used in a spray cosmetic for hair, a coating film capable of maintaining the adhesion between hairs for a long period of time can be formed well, and the finished hair style is less likely to be damaged even by external impact, and the finished hair style can be maintained for a longer period of time.
The spray cosmetic for hair treatment of the present invention comprises a container and the above-mentioned hair treatment composition. The container has a container body and a pump dispenser or trigger dispenser. In the spray cosmetic for hair treatment of the present invention, the container is filled with the hair treatment composition. The container body preferably has an opening. Preferably, the pump dispenser or the trigger dispenser is attached to an opening of the container body.
The amount of the hair treatment composition of the present invention to be discharged by one discharge operation of the pump dispenser or the trigger dispenser is not particularly limited as long as the effect of the present invention can be exerted. The amount of the composition for hair treatment of the present invention to be discharged is preferably 0.05mL/1 times or more, more preferably 0.15mL/1 times or more, preferably 1.0mL/1 times or less, and even more preferably 0.5mL/1 times or less, from the viewpoint of being applied to the hair uniformly in a wide range without dropping and being capable of setting the hair without giving a sticky feeling.
The container having the container body and the pump dispenser or trigger dispenser is not particularly limited as long as the container can discharge the hair treatment composition of the present invention in the form of mist. Examples of commercially available products of the container having the pump dispenser include Y-150 (discharge amount: about 0.15mL/1 time) manufactured by Giye industries, and Z-155 (discharge amount: about 0.15mL/1 time) manufactured by Mitani Valve. Examples of commercially available containers having a trigger type dispenser include M3-M (discharge amount: about 0.5mL/1 time) manufactured by Giye industries, and Z-305 and T-305 (discharge amount: about 0.3mL/1 time) manufactured by Mitani Valve.
The method for producing the spray cosmetic for hair treatment of the present invention is not particularly limited, and a known method for producing a spray cosmetic for hair treatment can be used. Examples of the method for producing the spray cosmetic for hair treatment of the present invention include the following methods: the container body is filled with the hair treatment composition, and the pump dispenser or trigger dispenser is closed with the container body filled with the hair treatment composition.
The hair treatment composition of the present invention is suitable for use as a hair styling composition because the finished hair style is not easily damaged even when external impact is applied thereto and the finished hair style can be maintained for a long period of time.
The hair treatment composition of the present invention can also be used for maintaining a hairstyle finished with a hair styling composition containing a wax that is solid at 25 ℃ or a hydrocarbon oil that is solid at 25 ℃, such as a hair wax. The hair treatment composition of the present invention can be applied to hair finished with a hair styling composition containing a wax which is solid at 25 ℃ or a hydrocarbon oil which is solid at 25 ℃, such as a hair wax. In this case, the hair treatment composition of the present invention is a post-treatment agent composition, and the spray cosmetic for hair treatment of the present invention is a post-treatment agent. The hair styling agent composition containing a wax which is solid at 25 ℃ or a hydrocarbon oil which is solid at 25 ℃ may contain a wax which is solid at 25 ℃, may contain a hydrocarbon oil which is solid at 25 ℃, and may contain a wax which is solid at 25 ℃ and a hydrocarbon oil which is solid at 25 ℃.
The hair treatment composition of the present invention is preferably an after-treatment composition used for hair finished with a hair styling composition. The spray cosmetic for hair treatment of the present invention is preferably an after-treatment agent for hair finished with a hair styling composition.
Hair styled using a hair styling composition such as a hair wax containing a wax which is solid at 25 ℃ or a hydrocarbon oil which is solid at 25 ℃ has an advantage of being able to be freely restyled, but has a disadvantage of not being able to retain the styled hair for a long time because of poor hair styling retention. However, when the composition for hair treatment of the present invention is applied to hair that is finished using a hair-setting composition such as a hair wax containing a wax that is solid at 25 ℃ or a hydrocarbon oil that is solid at 25 ℃, the finished hair style is not easily damaged even when external impact is applied thereto, and the finished hair style can be maintained for a long period of time. When the composition for hair treatment of the present invention (particularly, the component (a) and the component (B), particularly polyoxypropylene sorbitol in the component (B)) is locally present on the surface of hair finished with a hair styling composition containing a wax which is solid at 25 ℃ or a hydrocarbon oil which is solid at 25 ℃ such as a hair wax, adhesion between the finished hair can be more effectively imparted, a coating film which is less likely to damage the finished hair style even when external impact is applied can be formed, and it is considered that the finished hair style can be maintained for a long period of time.
(examples)
The present invention will be specifically described below with reference to examples and comparative examples. The present invention is not limited to the following examples.
The following ingredients were used in the examples and comparative examples.
(component (A))
(acrylic acid/C1-18 alkanol acrylate/C1-8 alkyl acrylamide) copolymer: trade name "PLASCIZE L-9909U", manufactured by KAPPI CHEMICAL INDUSTRY CORPORATION
(alkyl acrylate/diacetone acrylamide) copolymer: trade name "PLASCIZE L-9540U", manufactured by CORPORATION CHEMICAL INDUSTRIAL CO., LTD
(component (B))
Polyoxypropylene sorbitol (number average molecular weight 700): trade name "Sanix SP-750", manufactured by Sanyo chemical industries Ltd
(component (C))
Ethanol
(component (D))
Polyoxyethylene glyceryl monoisostearate 1 (average addition mole number of oxyethylene groups of 20): trade name "BLAUNON RGL-20 MISE", manufactured by Qingmu oil & fat industries Ltd
Polyoxyethylene glyceryl monoisostearate 2 (average addition mole number of oxyethylene groups 25): trade name "EMLEXGGIS-125", manufactured by Nihon Emulsion
Polyoxyethylene glyceryl monoisostearate 3 (average addition mole number of oxyethylene groups: 30): trade name "EMLEXGGIS-130", manufactured by Nihon Emulsion
Polyoxyethylene glyceryl monoisostearate 4 (average addition mole number of oxyethylene groups 60): trade name "EMLEXGGIS-160 EX", polyoxyethylene hydrogenated castor oil monoisostearate (average addition mole number of oxyethylene groups: 50) manufactured by Nihon Emulsion Co., Ltd.: trade name "EMALEX RWIS-150", manufactured by Nihon Emulsion
Polyoxyethylene hydrogenated castor oil 1 (average addition mole number of oxyethylene groups 20): trade name "EMALEX HC-20", manufactured by Nihon Emulsion
Polyoxyethylene hydrogenated castor oil 2 (average addition mole number of oxyethylene groups 40): trade name "BLANON RCW-40", manufactured by Qingmu oil & fat industries Ltd
Polyoxyethylene hydrogenated castor oil 3 (average addition mole number of oxyethylene groups 50): trade name "BLAUNON RCW-50", manufactured by Qing Wood oil and fat industries Ltd
Polyoxyethylene hydrogenated castor oil 4 (average addition mole number of oxyethylene groups 100): trade name "BLANONRCW-100" manufactured by Qing Wood oil and fat industries Ltd
Polyoxyethylene butylene monoisostearate (average molar number of addition of oxyethylene groups 10): trade name "EMALEX BGIS-110", manufactured by Nihon Emulsion
(others)
Purified water
Examples 1 to 10 and comparative examples 1 to 6
The compositions for hair treatment were prepared by blending the components shown in tables 1 to 2 (blending unit is% by mass). The blending amounts (blending amounts in 100% by mass of the hair treatment composition) in the table are expressed by the blending amounts (unit: mass%) of the pure components.
The obtained hair treatment composition was filled into a container body, and the container body and a pump dispenser ("Y-150" manufactured by giye industries) were closed to obtain a spray cosmetic for hair treatment.
(evaluation)
The obtained spray cosmetic for hair treatment was used to perform the following evaluation. The evaluation was performed by five professional judges, and the evaluation result was determined by negotiation.
(test example 1: discharge state)
The obtained spray cosmetic for hair treatment was evaluated according to the following criteria by repeatedly discharging the hair treatment composition 5 times, visually observing the state of the discharged droplets.
< evaluation criteria for discharge State >
○ good in that the spray is discharged
X (bad): is not discharged in the form of mist
(test example 2 formation of Hair Strand)
The obtained spray cosmetic for hair treatment was used to uniformly apply the hair treatment composition to the hair of a wig (practice model: manufactured by YUKARI JAPAN corporation), and after the composition was fused with the hair, the whole hair was allowed to flow backward and stroked with the fingertips and the palms, thereby setting the hair. The hair tresses after 5 minutes of the hair styling were observed, and the degree of hair gathering was visually evaluated according to the following criteria. The hair treatment compositions of comparative examples 5 to 6 were not tested because they could not be discharged in a mist form from a pump dispenser.
< evaluation criteria for Hair Strand formation >
○○ (quite well) that a bundle of hairs is formed with the hairs strongly bunched together.
○ (good): a bundle of hairs is formed in which the hairs have a closeness to each other.
△ (slightly better). to the extent that a fine hair bundle is formed, the hair has essentially no lift.
X (bad): no hair strands are formed and the hairs are not gathered together at all.
(test example 3 hardness of Hair)
After the evaluation of test example 2, the finished hair was touched, and sensory evaluation was performed on the hardness of the hair according to the following criteria. The hair treatment compositions of comparative examples 5 to 6 were not tested because they could not be discharged in a mist form from a pump dispenser.
< evaluation criteria for Hair hardness >
○○ (quite good), the adhesive force between hairs is strong, and the hair has a firm coating feel due to the hairs being gathered.
○ (good) has adhesive force between hairs and has a film-covered feeling due to the hairs being gathered.
△ (slightly good), the adhesion between the hairs was weak, and the feeling of filming due to the hairs being gathered was substantially eliminated.
X (bad): the hair is not adhered to each other, and the filming feeling caused by the hair gathering is not generated at all.
(test example 4 Hair-styled Retention force after styling)
The obtained spray cosmetic for hair treatment was used to uniformly apply the hair treatment composition to the hair of a wig (practice model: manufactured by YUKARI JAPAN corporation), and after the composition was fused with the hair, the whole hair was allowed to flow backward and stroked with the fingertips and the palms, thereby setting the hair. Next, the wig after hair setting was left to stand in a constant temperature and humidity machine (25 ℃ C., 60% RH) for 1 hour.
After standing still, cold air was blown to the wig for 30 seconds from a distance of 50cm from the wig by an air blowing tube, the degree of disorder of the haircut at that time was observed, and the haircut holding force after haircut was visually evaluated according to the following criteria. In the evaluation of the haircut holding power after haircut, it was judged that the haircut holding power after haircut was maintained when the shape of the hair after haircut was maintained. The hair treatment compositions of comparative examples 5 to 6 were not tested because they could not be discharged in a mist form from a pump dispenser.
< evaluation criteria for Hair-holding force after Hair styling >
○○ (quite good) sustained maintenance of hair shape after setting
○ good: slightly disturbed, but the shape of the hair after the haircut was maintained.
△ (slightly better) had a marked disturbance and the hair shape after styling began to disintegrate.
X (bad): the hair shape after hair styling was not maintained at all, and was disturbed.
The compositions and results are shown in tables 1 and 2 below.
Claims (8)
1. A hair treatment composition which is filled in a container and discharged in the form of mist by means of a pump dispenser or a trigger dispenser, wherein,
the hair treatment composition comprises the following component A, the following component B and the following component C,
component A: a film-forming polymer;
component B: oxyalkylene addition polymers of sugar alcohols;
component C: and (3) ethanol.
2. The hair treatment composition according to claim 1, wherein the component A comprises the following component A1,
component A1: an anionic coating forming polymer obtained by using an alkyl (meth) acrylate as an essential monomer component.
3. The hair treatment composition according to claim 1 or 2, wherein the component A comprises the following component A11,
component A11: an anionic coating forming polymer selected from the group consisting of (acrylic acid/C1-18 alkanol acrylate/C1-8 alkyl acrylamide) copolymer and (alkyl acrylate/diacetone acrylamide) copolymer.
4. The hair treatment composition according to any one of claims 1 to 3, wherein the component B comprises the following component B1,
ingredient B1: polyoxypropylene sorbitol.
5. The hair treatment composition according to any one of claims 1 to 4, wherein the hair treatment composition comprises the following component D,
component D: a non-ionic surfactant.
6. The hair treatment composition according to claim 5, wherein the component D comprises the following component D1,
ingredient D1: a nonionic surfactant selected from the group consisting of polyoxyethylene glyceryl monoisostearate, polyoxyethylene hydrogenated castor oil monoisostearate, polyoxyethylene butylene glycol monoisostearate and polyoxyethylene hydrogenated castor oil.
7. The hair treatment composition according to any one of claims 1 to 6, wherein the hair treatment composition is a hair styling composition.
8. A spray cosmetic for hair treatment, which comprises:
a container having a container body and a pump or trigger dispenser; and
the hair treatment composition according to any one of claims 1 to 7,
the container is filled with the hair treatment composition.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2017-184717 | 2017-09-26 | ||
| JP2017184717 | 2017-09-26 | ||
| PCT/JP2018/027366 WO2019064851A1 (en) | 2017-09-26 | 2018-07-20 | Composition for hair treatment and mist cosmetic for hair treatment |
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| Publication Number | Publication Date |
|---|---|
| CN110831572A true CN110831572A (en) | 2020-02-21 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201880043427.6A Pending CN110831572A (en) | 2017-09-26 | 2018-07-20 | Composition for hair treatment and spray cosmetic for hair treatment |
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| Country | Link |
|---|---|
| JP (1) | JP6938105B2 (en) |
| KR (1) | KR102339025B1 (en) |
| CN (1) | CN110831572A (en) |
| WO (1) | WO2019064851A1 (en) |
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| KR102528583B1 (en) | 2023-03-16 | 2023-05-08 | 자이언트코리아 주식회사 | Mist composition for hair care |
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Also Published As
| Publication number | Publication date |
|---|---|
| WO2019064851A1 (en) | 2019-04-04 |
| JP6938105B2 (en) | 2021-09-22 |
| KR20200013038A (en) | 2020-02-05 |
| KR102339025B1 (en) | 2021-12-14 |
| JPWO2019064851A1 (en) | 2020-05-28 |
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