TW201110998A - Hair dressing cosmetic - Google Patents

Abstract

Disclosed is a hair-dressing cosmetic which exerts good hair-dressing effect and hair-redressing effect, although having a low viscosity, shows no stickiness and high smoothness and gives the sense of a favorable light finish. Specifically disclosed is a hair-dressing cosmetic containing (a) 0.1-10 mass% of a pressure-sensitive adhesive resin, and (b) 0.01-20 mass% of an oily component, characterized in that said pressure-sensitive adhesive resin (a) has such properties that a film of 0.1 mm in thickness that is formed of a composition containing said resin substantially at a ratio of 50 mass% has, after drying for 1 day at 25 DEG C and humidity 50%, a pressure-sensitive adhesiveness of showing a ball number of 4-30 in the inclined ball tack test (inclination angle 30 DEG, measured at 25 DEG C, humidity 50%). Thus, a hair-dressing cosmetic, which exerts good hair-dressing effect and hair-redressing effect, shows no stickiness and high smoothness, gives the sense of a favorable light finish, and is suitable for application by mist-spraying, can be obtained.

Description

201110998 VI. Description of the invention: [Technical field to which the invention belongs] =_Yu Lin finishing·The details of the Qiqi q (4) are excellent in the health and the whole 4 reforming power, and are not sticky, smooth, and finished after the hair is finished. A lightweight, well-made cosmetic for finishing hair.

[Previous Art J. In the case of a cosmetic towel for finishing a hair style, a hair-like heterolipid such as a hair-fixing mucus or a film-forming polymer is used for the purpose of making a shape, and the fat is hardened. Adverse conditions such as fine non-uniformity and poor retention of shape under high humidity. Therefore, various countermeasures have been taken to solve this problem. For example, Japanese Patent Laid-Open Publication No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. The powder cosmetic has a good hair styling property and has a natural feeling of scent without a sticky feeling. - Japan, Li Tekaiping „_1()() 312 (patent document 2) describes: A hair cosmetic having a low-viscosity polyether compound and a polymer resin compound, which has the characteristics of $, has a hair styling power and a hair styling property, and does not cause a sticky feeling and a hard feeling, and can be combed after the city drying. ς Hair, etc., for hair styling.” Japanese Patent Laid-Open No. Hei (3) No. 3 (available in the patent literature: with a specific polyoxyalkylene compound and/or polyoxyalkylene alkylene) Glycoside Cp〇ly〇xyalkylene alkyl giyC0Side), high-molecular weight polyethylene glycol for hair fixing (molecular weight 6_~3__ hairy secret, which has a whole, smooth Shungu eight Japanese patent system 2G () 2_167317 Bulletin (Patent Document 4) : a hair cosmetic composition with an amphoteric molecule, a sugar alcohol, a sugar alcohol derivative (for example, a polyoxyalkylene adduct of a sugar alcohol, etc.) which has a hair styling property and a setting (four) retention force, and does not have any remaining Or a hard feeling. ^ Japanese Patent Laid-Open Publication No. 2004-5059-2 (Patent Document 5) discloses that a specific water-soluble filament biaxially-shaped filament compound is blended in a specific ratio, and Liquid 201110998 The hair care composition of the carrier is excellent in remodelability and feel. However, in the above Patent Documents 1 to 5, Patent Documents 2 to 5 are emulsions (_lsi〇n), that is, For the secret of water-containing secrets, although the secrets of waterlessness are recorded in the special sputum, the hair styling effect is to hide the filthy silk compound, and the county system records/teaching miscellaneous _ so-called the following The purpose or subject of the secret: low viscosity and thief to the full force and hair reforming force can be fully satisfied, in addition to the non-sticky, smooth, hair style after finishing light and good Effect. In the lower viscosity of the cosmetics for finishing hair 2, special female to New Zealand Type force and hair styling, so you will want to warm up _ kind of full set of force and hair styling 'and have (4) make the secret of the thief's temperament finishing (four) of the cosmetics. [Previous Technical Literature] [Patent Document 1 Japanese Laid-Open Patent Publication No. 2007-217314 (Patent Document 2) Japanese Patent Laid-Open Publication No. Hei No. 3-261713 (Patent Document 4) Japanese Patent Publication No. 2〇〇4_5〇59〇2 [Invention] The present invention is directed to the above-mentioned prior art, and its object is to provide a Low-viscosity and good hair-lifting and hair-reforming ability, and it will not be sticky, smooth, and the hair is fine and fine after finishing the hair. [The way to solve the problem] The signing, the foundation, and others have made great efforts to find out that the problem can be solved by solving the above problems by using an adhesive resin having a predetermined viscosity. invention. That is, the present invention provides a secret for finishing hair styles, and the miscellaneous contains: H has an inclined ball test (inclination angle of 30 degrees, 25t, and a fishing degree of 5〇%) in which the ball number is 4 to 30. The adhesive resin is 0_1 to 10% by mass; and (b) the oil agent 〇.〇1 to 2〇% by mass. [Effects of the Invention] This month's hair is used for finishing hair styles (4). It is suitable for spraying because it is used in a misty form with a combination of a salty resin and an oil agent 201110998, and at the same time, it can be excellently blended into a low viscosity. Force and hair reforming power. [Embodiment] The sub-system contains a test square body with a conjugated resin (formed as 0237 ^TM tacktest), and the test material (adhesive substance f) is placed in the test body. Fig.] The measuring device: the page is inclined: upper, and covers the 10 cm from the top of the inclined surface with a non-adhesive sheet as a running way, when the ball of the predetermined material and size is used From the top of the inclined surface 2, the persimmon is on the surface-position stop _ the towel, and the glue is specified by the most A-size shank number. The adhesive resin obtained in the present invention has a resin mass percentage of 5 G% by mass, and the product is formed into a film having a thickness of the composition on the inclined surface of Fig. 1 to form a film. . The age of the test after drying for 1 day at 50% is the test surface and the test is performed. The following adhesiveness is used as the adhesiveness of the present invention: the measurement condition is such that the inclination of the inclined surface in the measuring device shown in Fig. 30 is 30 degrees 'at the pit, M 5G%, and the ball number is 4 to 30, more preferably 4 to 20 people. Specific examples of the adhesive resin used in the present invention include acryl-based resins such as Acronal® V215ap, Acronal® N285, Acronal® V210, Acronal V212 (above, manufactured by BASF Corporation), and NCOR38. —088A ' Duro—Tak87 — 200A, Dur〇—Tak 387-2054/87-2054 (above, National Starch & Chemical), MG-〇560, MG—0580 (The above is Dow (made by Doming) , DAITOSOL 5000AD (manufactured by Daito Kasei Kogyo Co., Ltd.), YODOSOL AH955, PRIMAL PS83-D (manufactured by Rohm & HAAS Co., Ltd.), etc. The adhesive resin used in the present invention may also be an adhesive styling resin obtained by polymerizing the following monomer A and/or monomer B, monomer C and monomer D. 201110998 Monomer A: : 【化1】

R1

/

(wherein R1 is hydrazine or CH3, η is an integer of 0 to 30, (CH2) n includes a branch, and R2 is at least one of a monomer represented by hydrazine, OH, OCH3, OCH2CH3 or phenyl). Monomer B: in the following formula: [Chemical 2] R3

(wherein R3 is Η or CH3, R4 and R5 may be the same or different, and Η or (CH2) is only ', 1 is an integer of 1 to 3, which is H, OH or a NR"R,", R" And R' '' may be the same or different, and is at least one of the monomers represented by hydrazine or an alkyl group of C1 to C3. Monomer C: is represented by the following formula:

(C) (wherein R6 is Η or CH3, p is an integer from 1 to 100, m is an integer from 0 to 30, R7 is Η, 201110998 OH^ OCH3 ^ OCH2CH3, X (EO) (P〇) ^ butene At least the species of the monomer represented by the group (BO) or glyceryl group. Monomer D: in the following formula:

(wherein R8 is Η or CH3 'q is an integer of (10), γ is oxyethylene (10)), oxypropylene (10), oxybutanyl (10)> linear or branched oxynitride having a carbon number of 5 or more (〇xyalkylene) or at least one of glyceryl groups (only when Y is an oxygen county having a carbon number of 5 or more, q is υ). In the present invention, it is preferable to have a structure represented by the formula (1). 【化5】

The above formula (1) towel 'R1 ~ 尺卜^心口... is in the same meaning as the above formula VIII. In addition, the terms used in this specification are used in a general sense, for example, oxyethylene (oxime), oxypropylene (Ρ0), and oxybutyl (ΒΟ) systems mean carbon numbers 2, 3, and 4, respectively. The oxygen bond of the direct key or the bond. Further, a in the above formula (I) is 4 〇 < a < 4 〇〇, b is 8 _ < 3 〇〇, c is 3 〇 7 201110998 < c < 300, d is 0 < d < 10 range The number. The mass % of each monomer in the adhesive styling resin (polymer of the formula ()) satisfying the above conditions is substantially as follows: 7.5 < A < 62.5, 20 SB < 45, 7.5 < C < 60, 0 <D<5. The adhesive styling resin used in the present invention can be prepared by subjecting the above monomers A and/or 8 and (: and D in an appropriate ratio) and performing polymerization in a suitable solvent in a suitable solvent as required. For example, it can be obtained by thermally polymerizing at a temperature of about 80 ° C for 8 hours by using a polymerization initiator such as 2,2, azobisisobutyronitrile in ethanol. And the obtained polymer can be suitably purified and used. As an adhesive resin of a polysiloxane, an addition reaction type polyoxyl

Alkyl SD4584, SD4560, SD4570, SD4580, SD4585, SD4587L (above is Toray DOW SILICONE Co., Ltd.), TSR1512, TSR1516 (above, MOMENTIVE), etc. In the present invention, 'as long as the resin satisfies the adhesive condition The present invention is not limited to the specific examples listed above, and may be used in combination of two or more kinds thereof. The amount of the adhesive resin in the cosmetic of the present invention is from 01 to 10% by mass, more preferably from 5% to 7.5% by mass. When it is less than 11% by mass, the desired effect cannot be obtained, and if it exceeds 1 〇 mass ° / 〇, a sticky feeling is generated. The cosmetic of the present invention contains an oil agent in addition to the adhesive resin. The oil agent used in the present invention is not particularly limited as long as it is a cosmetic oil for cosmetics which has been conventionally used in combination with a cosmetic. Examples of the oil agent for such a cosmetic material include castor oil, CaCa〇〇il, eucalyptus oil, avocadooil, and glyceride such as olive oil; beeswax and cetyl wax; Lanolins, waxes such as carnaubawax; cetyl alcohol (cetyl alcohol, cetyiak〇h〇1), oleyl alcohol, hexadecanol (hexadecyl alcohol), twelve Alcohol, stearyl alcohol, isostearyl alcohol, 2-octyldodecanol, polypropylene glycol and other alcohols; isopropyl myristate (is〇pr〇pyl myristate), decyl decanoate, ant milk Ester (cetyi iactate), propylene glycol monostearate, / oleyloleate, hexadecyl2-ethylhexanoate, octyldodecyl myristate Class; polydimethyl methoxy oxane, polyfluorene basic ash burning, polyether modified LY tempering oil, epoxy modified Shixia oil (ep〇Xy_m〇d out of the fairy (7) to receive oil), amine A polyxane derivative such as a modified eucalyptus oil or an alkyl-modified eucalyptus oil. 201110998 Further, a hair styling component of an E〇/p〇 adduct (adduct) of one to four tetrahydric alcohols or one to three carboxylic acids may be mentioned. For example, 〇 168, MB 370, TRIOL G-40, SAVON DOR SGP-7, SAVON DOR GP-9 (above, Nippon Oil Co., Ltd. product), etc., may be mentioned. The blending amount of the oil agent in the hair styling material of the present invention is 〇〇1 to 2% by mass, preferably 0.1 to 1% by mass. If the matching amount is less than (10) 丨 mass%, there will be no smoothness after the completion of the hair styling, and the finished hairstyle will become dry. Also, if it is more than 2〇% by mass, it will be sticky due to the feeling of stickiness. The cosmetic for finishing hair of the present invention is made into a low viscosity. Thus, when applied to hair, the solvent is quickly volatilized to exhibit adhesiveness. Specifically, it is preferable that the viscosity at the time of measurement by a B-type viscometer is 100 mPa·s, and the effect of the present invention can be easily exhibited by spraying into a mist. If the viscosity is more than 100 mPa·s, there is discomfort. In the case of spraying into a mist, for example, there may be a problem that a nozzle that blocks the spray device is generated. Further, in the case of the cosmetic for finishing hair of the present invention, the solvent in the cosmetic is volatilized. The range of adhesion is also an important factor. By making the adhesion of a predetermined range, the sticky feeling applied to the hair can be suppressed, and at the same time, the hair reforming power can be improved. Specifically, it is preferable to have: The cosmetic of the invention forms a film having a thickness of 〇1 mm, and the tilting angle of the inclined surface is set to 10 degrees in the ball test (measuring device shown in FIG. 后) after drying at 25 ° C and a humidity of 50% for one day. And the ball number is 1 to 3 〇, more preferably 3 to 25, when measured at 25 ° C. When the adhesion is as low as the ball number 1 does not stop, the hair styling force will be insufficient, and Adhesiveness is greater than the ball number 30, the ball will still stop The hair will have a sticky feeling. The cosmetic material for finishing hair of the present invention may contain a hair-type resin in addition to the above-mentioned adhesive resin, which can further enhance the finishing hairstyle/hair style by being matched with the hair styling resin. Refining force and improving moisture resistance. Hair styling resin which can be combined with the cosmetic of the present invention means: anionic, cationic, amphoteric, nonionic film formation, also known as a setting agent or a styling resin. The polymer may be a conventional one with a hair styling agent. Specific examples include the following: acryl and vinyl (viny丨) hair styling tree deer: anionic material is acrylonitrile (Brewed) / propylene acrylamide copolymer (Plus size 201110998 L - 53P, PlussizeL - 9909B 'PlussizeL - 9948B, etc. (all manufactured by Mutual Chemical Industry Co., Ltd.)), burnt acrylic acid (S / octyl acrylamide copolymer (Dermacryl 79 (Nippon NSC Co., Ltd.)), polyethylene glycol / polypropylene glycol-25 / polydimethyl oxime / acrylate copolymer (Luvif) Lex SILK (manufactured by BASF), acrylic acid/acrylic acid amide/ethyl acrylate copolymer (Ultra Hold 8, Ultra Hold Strong (BASF)), alkyl acrylate copolymer (Anicet NF-1000, Anicet HS-3000, etc. (made by Osaka Organic Chemical Industry Co., Ltd.)), etc. The amphoteric substance is octylamine acrylate/hydroxypropyl acrylate/butyl methacrylate copolymer (AMPHOMER SH30, AMPHOMER LV-71 (made by NSC Co., Ltd.)) methacryloyl oxyethyl carboxylbetaine / alkyl acrylate copolymer (Yukaformer R205, Yukaformer 301, Yukaformer SM, Yukaformer 104 (manufactured by Mitsubishi Chemical Corporation), RAM resin _ 1000, RAM resin 2,000, RAM resin _ 3000, RAM resin 4,000 (made by Osaka Organic Chemical Industry Co., Ltd.), dimethyl diallyl (diallyl) vaporized ammonium/acrylic acid copolymer (MERQUAT280, MERQUAT295 (manufactured by NALCO)), dimethyldiallyl ammonium hydride/acrylamide/acrylic acid copolymer (MERQ) UAT plus3330, MERQUAT plus3331 (made by NALCO)), etc. The cationic substance is vinylpyrrolidone/dimethylamine ethyl methacrylate copolymer diethyl sulfate (HC PolymerlS (M), HC Polymer 2 (manufactured by Osaka Organic Chemical Industry Co., Ltd.), Gafquart 755N (manufactured by ISP)) , vinylpyrrolidone / dimethylaminopropyl monomethacrylamide / dodecyl dimethylaminopropyl monomethacrylamide copolymer (STYLEZEW-20 (manufactured by ISP)), vinylpyrrolidinium / N , N-dimethylamino methacrylate ethyl acrylate / alkyl acrylate / tripropylene glycol diacrylate copolymer (Cos-cut GA467, Cos-cut GA468 (Osaka Organic Chemical Industry Co., Ltd.), poly Gasified dimethylmethylenepiperidine (MERQUAT100 (manufactured by NALCO)), dimethyldiallyl vaporized/acrylamide copolymer (MERQUAT550 (manufactured by NALCO)), gasified trimethylaminopropyl A acrylamide/dimethyl methacrylate copolymer, etc. The nonionic substance is polyvinylpyrrolidone (Luviskol K17, Luviskol K30, Luviskol K90 (manufactured by BASF), PVP K (manufactured by ISP)), vinylpyrrolidone /vinyl acetate Polymer (PVP/VA S-630 'PVP/VA E-735 'PVP/VA E-335 201110998 (manufactured by ISP)) Luviskol VA73W, Luviskol 37E (manufactured by BASF Corporation), PVA-6450 (Osaka Organic Chemistry) Industrial Co., Ltd.)), mercapto vinyl ether/alkyl maleate copolymer (GANTREZA-425, GANTREZES-225, GANTREZES-335, etc. (produced by ISP)), vinylpyrrolidone/methacryl Amine/ethylene imidazole copolymer

(Luviset Clear (manufactured by BASF Corporation)), polyethylene caprolactam (Luviskol Plus (manufactured by BASF Corporation)), and the like. Urethane hair styling resin:

Yodosol PUD (manufactured by 曰本NSC Co., Ltd.), Luviset PUR (manufactured by BASF Corporation), and the polymer described in JP-A-2006-213706, acrylonitrile-carbamic acid S-based system is DynamX (曰本A polymer or the like described in Japanese Patent Application No. 2006-183144. Polysaccharide hair styling resin: gum arabic, dextran, succin 〇glycan, carrageen, gum karaya, gum tragacanth , guar gum, i〇cust bean gum, galactomannan, xanthan gum, win powder, carabe gum, quince seed, cheese Protein, dextrin, gelatin, sodium pectinate, sodium sulphate, methyl cellulose, ethyl cellulose, methine cellulose, hydroxyethyl cellulose, hydroxypropyl cellulose, microcrystalline cellulose, Gasification 〇[[2-hydroxy_3_(三甲叙)propyl] via ethyl cellulose, gasification 〇-[2_录_3_ (三甲土叙) propyl T 瓜尔胜, Ο- 2- mercapto-3-(triterpenoid) propyl]canthamoylmethylammonium sulfate starch, etc. — The hair styling resin to be used in the cosmetic preparation for styling hair of the present invention is not particularly limited, and may be appropriately selected. The above-mentioned hair is fixed or torn, or it is preferably used as the emulsified base, the ethylene base, or the amine f acid age. The amount of the hair styling resin in the cosmetic of the hair styling is preferably 〇.1 to 1 〇% by mass, more preferably 0.5 to 7.5% by mass. If the amount of G"f is insufficient, the miscellaneous amount exceeds Π The discussion will have a hairy touch, and there is no tolerance for the invention. The preparation of the hair style is better. The step contains the choice from the sugar alcohol, the polyalkyleneglycd and its derivatives. One or more kinds of work soils, one of the four (4) sugar alcohols in the invention, the sugar _ recorded by the Gusaki's plural 201110998 alcohol. Maltitol (rMarbit), manufactured by F〇〇d Science Co., Ltd.), sorbitol ("SorbitoIC"; manufactured by Food Science Co., Ltd.), ribitol (oil 11〇1), mannose Alcohol, arabitol, galactitol, xylitol, erythritol inositol, and the like. Further, the present invention may also use a derivative of lin. For example, addition (polyoxyethylene sorbitan oleate rRHE0D0L 43〇V): Kao Chemical, polyoxypropylene sorbitol "UNIOL HS-1600D"), calcination addition, cationization, anionization, Shi Xi burning (silylation) and so on. Among them, there is no sticky feeling and hard feeling, and it is preferable to use sorbitol or maltitol. The polyfluorene hydrocarbon diol and the derivative thereof used in the present invention include a PO polymer in which an E0 polymer composed of an epoxy resin (Ethylene Oxide (EO) unit and a polymerized epoxy propylene compound (10)) are used. A B 〇 polymer having a unit of butyl bromide (B0) or a copolymer obtained by copolymerizing the above constituent units is preferably used. Particularly preferred are E 〇 polymer, EO/PO copolymer containing E 〇 constituent unit and PO constituent unit, EO/BO filament containing E 〇 constituent unit and B 〇 constituent unit, and the like. The form of the silk is not limited to, and may be any of block copolymerization (10) light copolymerization, graft copolymerization (complex cop〇lymerizati〇n), random copolymerization (coffee copolymerization), and the like. The polyolefin-based diol used in the present invention may be a commercially available product, and examples thereof include E 〇 addition polymers: PEG 200, PEG 300, PEG 400, PEG 600, PEG 1000, PEG 1540, PEG 2000 〇, PEG 4000, PEG 6000, PEG 11000, EG 20000 ( Oyster Oil Co., Ltd. or Toho Chemical Industry Co., Ltd.), P◦ Addition Polymer: UXIOLD — 700, UNIOLD — 1 —, UNIOLD-1200, UNI 〇 LD-2000 (above, manufactured by Nippon Oil Co., Ltd.). The polyolefin-based diol used in the present invention is not limited, and among them, polyethylene glycol is most preferable. The blending amount of the sugar alcohol and/or the polyolefin-based diol derivative in the cosmetic of the present invention is 丨 to, for example, % by mass, more preferably 3 to 25% by mass. If the match is less than! If the mass is %, there is a case where the desired effect cannot be obtained, and if the matching amount exceeds 30 mass ❶ /. There is a situation in which a sticky feeling or a hard feeling is generated. The cosmetic material for tidying up the hair of the present invention is not particularly limited, but is preferably a cosmetic containing an adhesive resin and an oil agent having a predetermined adhesiveness. It is possible to use a hak liquid, a hair spray, a hair mist, or the like, in particular, as a cosmetic having a low viscosity in which the cosmetic properties and adhesiveness are within the above range. Each type 12 201110998, such as a hair 〇 ii, is used as a spray, and when it is used in a mist form, it has a solvent evapotranspiration, and it is easy to smash, singularly, and unexpectedly. By using it as a trap, it is possible to accelerate the volatilization of the solvent and quickly exert the adhesion/hair styling power. The cosmetic material for tidying up the hair of the present invention may, for example, not be detrimental to the effects of the present invention depending on its type. The present invention will be described in more detail below by way of specific examples, but the present invention is set forth in the following examples. In addition, the amount of the collocation in the present specification means that "the manufacturing example and the comparative manufacturing example" are polymerized by the monomer composition shown in the following Table 1, and the preparation does not contain the adhesive setting which can be made in the present invention. (Production Example 66) and Comparative Production Example i of the monomer c and Comparative Production Example 2 in which the monomer D was not contained. > Specifically, a mixture in which a monomer (10) by weight was mixed was prepared in advance. Adding a dropping funnel with a dropping funnel, a reflux cooling gas, a thermometer, a nitrogen replacement tube, and a flask equipped with a stirrer having a capacity of 1 L, 1 part by weight of ethanol was placed under a nitrogen stream. The temperature was raised to form a reflux state (about 8 Torr.), and a part by weight of a polymerization initiator (2,2'-azobisisobutyronitrile) was added to the ethanol, and the mixture was continuously dropped for 2 hours. Thereafter, it was allowed to stand under reflux for 8 hours to carry out polymerization. Secondly, the solvent content of the solution was adjusted by distilling off the solvent from the solution in the five flasks and adding ethanol, thereby obtaining a solid content concentration. 50% 13 201110998 [Table 1] Classification chemical structure (trade name) Manufacturer's manufacturing example 1 Manufacturing example 2 Manufacturing example 3 Manufacturing example 4 Manufacturing example 5 Manufacturing example 6 Comparative manufacturing example 1 Comparative manufacturing example 2 A butyl acrylate Ester luminescence 40 35 30 15 40 A Ethyl acrylate East Asia synthesis 30 30 A octadecyl methacrylate (BLEMMERSMA) Nippon oil A hydroxyethyl acrylate (HEA) Osaka organic 15 30 A methoxyethyl acrylate (ALIXC) -1) East Asian synthesis 15 B Dimercaptopropenylamine (DMAA) Xingrenhua 40 30 30 40 35 30 B Diamylpropyl propyl decylamine (DMAPAA) East Asian synthesis 20 C polyoxyethylene glycol acrylate (n =10) (BLEMMER AE-400) Nippon Oil 55 20 15 15 30 C Polyoxypropylene acrylate (η二6) (BLEMMER AP-400) Nippon Oil 20 20 30 55 D Dioxyethylene Glycol S n=23) (NK ESTER A-1000) Xinzhongcun Chemical 5 5 5 5 5 D Dioxyethylene glycol diacetate S (n=14) (NK ESTER 14G) Xinzhongcun Chemical 5 D Dimercaptopropionic acid Glycerin (BLEMMER NDMA) Nippon Oil 5 14 201110 998 <Examples and Comparative Examples> The adhesiveness of the adhesive resin of the following Table 2 was measured by a ball test. In addition, the result of the ball test in the table is "-" who has a low turn and the numbered ball has not stopped. [Table 2] Adhesive resin ball test (30 degrees, 25. 〇, 50% of fishing) Type (manufacturer) Acrylate based system (BASF company) Trade name----------- Acronal ®YJ2720D a v / ~~--- 1 propylene brewing system (BASF) Acronal® V215ap 12 succinic acid S for DAITOSOL 5000AD — ----- 4 yard based methyl acrylate acid acrylic Butyl ester/acrylic acid 2-ethylhexene/methyl methacrylate copolymer emulsion (*n 1 decane series (Dongli Dow Coming Co., Ltd.) SD4584PSA 4 Adhesive styling resin of Production Example 3 - 5 Acetic acid Vinyl ester s-dine 5301 (*1) n-butyl acrylate / 2-ethylhexyl acrylate / methacrylate methacrylate copolymer emulsion (made by Dadong Chemical Co., Ltd.) 'Resin solid in resin emulsion: water = 1 : j. The second sample is prepared by modulating the composition of the composition shown in Tables 3 and 4 below, and the sample is evaluated for the presence or absence of the fixing force, the hair styling power, the hair styling force, the dry feeling and the sticky feeling. At the same time, the results are shown in Tables 3 and 4. In addition, the evaluation methods and evaluation criteria for each characteristic are as follows. The virgin hair (length 15 cm 'weight lg) was coated with a sample of 4 g, and the shape was adjusted by using a comb to adjust the shape to make it straight, that is, a hair bundle containing 5 pieces per unit of the sample was produced. After drying for 1 hour at ° C, it was hung on a plate with a scale, and the bending length (b) of the hair bundle was measured in a constant temperature and humidity machine at a temperature of 3 (rc, humidity: 9〇% RH. Uncoated sample was used. When the length of the curved hair bundle (a) is measured in advance, the fixing force (holding force) is obtained according to the following formula, and it is shown that the higher the holding force is, the higher the fixing force is, and the better the moisture resistance is. 15 201110998 Hair style retention Force (%) = {(a - b) / a} χ 100 &lt; Evaluation Criteria > ◎: 値 is 90% or more 値 値 is less than 70 to 90% △: 値 is less than 50 to 70% x : 値Full 50% 2·The hair is applied to the black natural hair (length 2〇cm, mass 2g) coated with the test material, 5g and the hair bundle dried at room temperature is based on the consultation Sensory test (functional test) test to assess the ease of finishing the hair style. ° &lt;Scoring Criteria&gt; 5 points. Very easy to organize hair style 4 points: slightly easier to organize hair style 3 points: Ordinary 2 points: slightly difficult to organize hair style 1 point: difficult to organize hair style &lt; evaluation criteria &gt; ◎: total score of 40 points or more 总: total score of 30 points or more less than 4 points △: total score of 20 points or more Over 30 points x: The total score is less than 20 points 3. Hairstyle re-strength force is applied to the black hair (2 cm long, 2 g mass) coated with the sample 〇 'The hair is immediately finished after coating' and then consulted专家 ° ^ carried out by experts, finishing the hair of Wei 1 small domain money line finishing (hair hair reforming power). &lt;Scoring Criteria&gt; 5 points · Very hair style re-strength force 4 points: slightly hair style re-strength force 3 points: ordinary 16 201110998 2 points: slightly no hair style re-strength force 1 point: no hair reforming force &lt;Assessment Criteria&gt; ◎: Total score of 40 or more 〇: Total score of 30 or more and less than 40 points △: Total score of 20 or more and less than 30 minutes x: Total score of less than 20 points 4. Cognac The presence or absence of the sensation in the black hair (2 cm long, 2 g in mass) coated with the sample after drying is based on the presence or absence of a dry hair sensation by a functional expert. «City (4)&lt;Scoring Criteria&gt; 5 points: Extremely dry 4 points: slightly dry 3 points: Normal 2 points: slightly dry 1 point: Cognac &lt;Assessment Criteria&gt; ◎: Total score of 40 or more〇 The total score is 30 points or more and less than 4 points. △. The total score is 20 points or more and less than 30 points X. The total score is less than 2 points. 5. The presence or absence of sticky feeling is on the black natural hair (length 20cm) The hair bundle after drying under the quality is based on the scale of the special g", the cloth material G.5g and the presence or absence of the sticky feeling of the hair at room temperature. The functional test of the cockroach to assess the finishing of the hair style &lt;score;&gt; 5 points: Extremely non-sticky 4 points: slightly sticky 10 points: ordinary 17 201110998 2 points: slightly sticky 1 point: sticky &lt; rating benchmarks ◎: total score of 40 points or more 总: total score 30 points or more and less than 40 minutes △: Total score of 20 points or more and less than 30 minutes X: Total score of less than 20 points [Table 3] Comparative Example 1 Comparative Example 2 Comparative Example 3 Example 1 Example 2 Example 3 Implementation Example 4 (1) Water 60 55 60 59 55 50 40 (2) Alcohol 35 35 35 35 35 35 35 (3) Adhesive setting resin of Production Example 5 5 5 5 5 5 (4) PPG-70 Polyglycerol-1 5 5 1 5 10 20 100 100 100 100 100 100 Fixing force XX 〇〇〇〇〇 Whole hair X Δ 〇〇〇 ◎ ◎ Hair reforming force X Δ 〇〇〇 ◎ Dry feeling X 0 X 〇 ◎ ◎ 〇 sticky feeling 〇〇 Δ 〇〇◎ 〇〇 Other embodiments are as follows. <Example 5> Liquid styling agent (1) Ion exchange water residue (2) PEG-6 5 18 201110998 5 5 1 50 Appropriate amount 3 2 Appropriate amount 3 3 3 2 40 Appropriate amount 3 3 1 Appropriate amount (3) PEG-8 (4) PEG-32 (5) Sorbitol (6) Ethanol (7) Perfume (8) Adhesive styling resin of Production Example 3 (9) Alkyl acrylate )/Diacetone acrylamide copolymer (10) Citric acid &lt;Preparation method> (1) Dissolve and dissolve in water to make water and stir to make it soluble, then add (8) water and alcohol Mix and add (10) Add the water-soluble ingredients of (2) to (5) to the waterparts. Next, add (7) to (6) to (9) and stir to prepare the alcohol part. (alc〇h〇i parts). A liquid shaped styling agent. <Example 6> Liquid styling (1) Ion exchange water (2) PEG-6 (3) PEG-8 (4) PEG-32 ( 5) Sorbitol (6) Ethanol (7) Perfume (8) Adhesive styling resin of Production Example 3 (9) Alkyl acrylate (diester) / diacetone acrylamide copolymer (10) PPG-40 - Ding Yue (11) Citric acid &lt;Manufacturing &gt; The water-soluble components of (2) to (5) are added to (1) water and stirred and dissolved to prepare a water portion. Next, (7) is added to (4) and stirred to make it soluble, and (8) to (9) are added and stirred to obtain an alcohol portion. The liquid portion is mixed with the alcohol portion, and (10)) 〇1) is added to prepare a liquid solution of the type 19 201110998. <Example 7> Liquid styling agent (1) Ion exchange water residue (2) PEG-6 7 (3) PEG-32 7 (4) Maltitol 10 (5) PEG/PPG-55/28 Dimethyl ether 1 (6) Ethanol 5 (7) Proper amount (8) Acronal® V215ap 1 (9) Alkyl acrylate / diacetone acrylamide copolymer 2 (10) citric acid amount (11) phenoxyethanol amount &lt;;Preparationmethod&gt; The water-soluble components of (2) to (5) are added to (1) water and stirred to dissolve to prepare a water portion. Next, (7) is added to (6) ethanol and stirred to make it soluble, and (5), (9), and (11) are added and stirred to prepare an alcohol portion. The liquid portion is mixed with the alcohol portion, and (8) (10) is added to prepare a liquid styling agent. BRIEF DESCRIPTION OF THE DRAWINGS Fig. 1 is a schematic view showing an apparatus for a ball test. [Main component symbol description] None 20

Claims (1)

201110998 VII. Patent application scope: 1. A cosmetic material for finishing hair style, which comprises: (a) an adhesive resin 0.1 to 10% by mass; and (b) an oil agent 〇〇1 to 2% by mass of a cosmetic material The (a) adhesive resin has a film having a thickness of 〇.1 mm and a composition containing the resin in a mass percentage of 5% by mass, and dried at 25 ° C and a humidity of 5 〇 %. The ball number of the ball is 4 to 30 in the inclined ball test (inclination angle of 30 degrees, 25 ° C, and humidity of 50%). 2. The cosmetic material for finishing hair as described in the scope of the patent application, wherein the viscosity of the cosmetic material is l〇〇mpa·s or less, and the B-type viscosity meter). 3. The cosmetic material for finishing a hair style according to the first or second aspect of the patent application, wherein the cosmetic material has a film having a thickness of 〇lmm formed at 25 乞 and a humidity of 5 〇0. / Tilting ball test after drying for 1 day under the armpit (inclination angle 1 、, 25. 〇 球 ball number is 1 to 3 〇 adhesion. 4. If any of the patent scopes 1 to 3) The cosmetic for finishing a hair style, wherein the cosmetic further comprises a hair styling resin of 0.1 to 10 masses per ounce. 5. The method according to any one of claims 1 to 4 A cosmetic material for finishing a hair style, wherein the cosmetic material is sprayed into a mist to be used.