JP5632586B2 - Hair cosmetics - Google Patents

Description

  The present invention relates to a hair cosmetic material that achieves both a fixing force and an arranging force (including a re-styling force) and is excellent in moisture resistance. More specifically, the present invention relates to a hair cosmetic that can contain a novel polymer and can be fixed with hair by blending a set resin, can be re-haired, and has excellent set retention.

  Hair styling includes two functions: creating a hairstyle and retaining the created hairstyle. The principle of exerting these two functions is said to be fixation and adhesion (Non-Patent Document 1).

  Hair styling by fixing is a method in which a film forming agent (polymer resin) called a set agent forms a solid film to fix the hair. For example, conventional hair gels and hair sprays are mainly based on a hair styling mechanism using a set resin. For example, Patent Document 1 describes hair cosmetics mainly using a film-forming polymer such as polyvinylpyrrolidone, sodium polyacrylate, polyvinylpyrrolidone-polyvinyl acetate copolymer as a set resin. Patent Document 2 discloses a hair cosmetic using a silylated urethane resin as a set resin in Patent Document 2, which forms a film having both softness and hardness, and has a natural texture and high keeping power. It is said that.

  However, in hair cosmetics using resins as described in Patent Documents 1 and 2, since the set resin forms a hard film, re-hairing from a hairstyle once made cannot be performed, and the film is broken. There was a disadvantage of losing the hair-styling function. That is, the styling agent based on fixing with the set resin has a problem that it is excellent in fixing the hairstyle but has poor arranging power.

  On the other hand, styling based on adhesion is a method in which hairs are adhered to each other by an oily component, and in recent years using a hair liquid mainly composed of an adhesive oily component such as polyalkylene glycol and the adhesiveness of a solid oil. Hair waxes that are preferred by young people are known. For example, Patent Document 3 describes a cosmetic for hair that contains a wax and a water-soluble polymer having a stringiness and is excellent in re-styling.

  However, such hair styling based on the stickiness of the oily component has a feature that it can be re-styled through a finger or a brush because the oily component maintains fluidity and stickiness on the hair. Although it is strong, it has a problem that it cannot obtain a fixing force (keep force) like a hair cosmetic using a set resin.

"Development of functional cosmetics II", supervised by Masato Suzuki, published by CMC Publishing, 1996, Chapter 10 Functions and latest technology of hairdressing agents

JP 2006-213706 A JP 2003-171244 A JP-A-10-45546

Therefore, the problem in the present invention is a hair cosmetic that can fix hair (hairstyle) based on fixation and is excellent in arranging power (including hair styling), and further improves moisture resistance. Another object of the present invention is to provide a hair cosmetic with enhanced set retention.
As a result of intensive studies to solve the above-mentioned problems, the present inventors have formulated a new adhesive set resin having a moderate hardness and high adhesive force during film formation as a set resin, thereby fixing strength and arrangement. The present inventors have found that a hair cosmetic material having strength can be obtained, and further that moisture resistance (set holding power) can be improved by blending a set agent resin, thereby completing the present invention.

That is, the present invention
The following formula (A):
(Wherein, R1 is H or CH _3, n is _{(CH 2) n} is an integer of 2 to 30 comprises a branched chain, R2 is _H, OCH 3, _OCH 2 CH ₃ or phenyl) At least one monomer represented by (hereinafter referred to as “monomer A”);
And the following formula (B):
(Wherein R ₃ is H or CH ₃ , R 4 and R 5 may be the same or different, and H or (CH ₂ ) _l R ′, where l is an integer of 1 to 3; Is H, OH or —NR ″ R ′ ″, and R ″ and R ′ ″ may be the same or different and are H or a C1-C3 alkyl group). (Hereinafter referred to as “monomer B”);
And the following formula (C):
(Wherein, R6 is H or CH _3, p is an integer of 6 to 100, m is an integer of 0 to 30, R7 is _{H, OH, OCH 3, OCH} 2 CH 3, or phenyl X is at least one monomer represented by an oxyethylene group (EO), an oxypropylene group (PO), an oxybutylene group (BO), or a glyceryl group) (hereinafter referred to as “monomer C”) ;
And the following formula D:
(Wherein, R8 and R9 are the same and are H or CH _3, q is an integer of 1 to 100, Y is an oxyethylene group (EO), an oxypropylene group (PO), oxybutylene group (BO) , A linear or branched oxyalkylene group having 5 or more carbon atoms, or a glyceryl group (provided that, when Y is a linear or branched oxyalkylene group having 5 or more carbon atoms, q is 1)) At least one monomer represented by (hereinafter referred to as "monomer D")
A hair cosmetic containing an adhesive set resin, a set agent resin, and an alcohol obtained by polymerizing the above is provided.

The hair cosmetic composition of the present invention can achieve both the fixing force and the arranging force, which were impossible with the conventional set resin, by blending the above-mentioned novel adhesive set resin.
Furthermore, the hair cosmetic composition of the present invention is superior in moisture resistance and has a set holding power for holding a hairstyle for a long time by further blending a conventionally used set agent resin in addition to the adhesive set resin. I was able to improve.

Hair cosmetic composition of the present invention contains the adhesive sets resin obtained by polymerizing a monomer A and monomer B and monomer C and monomer D described above as essential components. With a resin (polymer) lacking the monomer C or the monomer D, good adhesive force and arrangement force (re-hair-setting ability) cannot be obtained.

The adhesive set resin used in the present invention is particularly preferably one having a structure represented by the following formula (I).
In the above formula (I), R1 to R9, n, m, p, and q have the same meanings as in the above formulas A to D. Note that the terms in this specification are used in a normal sense. For example, an oxyethylene group (EO), an oxypropylene group (PO), and an oxybutylene group (BO) are each a straight chain having 2, 3, and 4 carbon atoms. It means a chain or branched oxyalkylene group. In the formula (I), a is a number in the range of 40 <a <400, b is 80 ≦ b <300, c is 30 <c <300, and d is 0 <d <10.
The mass% of each monomer in the adhesive set resin (polymer of formula (I)) that satisfies the above conditions is approximately as follows. 7.5 <A <62.5, 20 ≦ B <45, 7.5 <C <60, 0 <D <5.

  The adhesive set resin of the present invention is obtained by mixing the above monomers A and / or B and C and D in an appropriate ratio and subjecting them to a polymerization reaction using a standard method in an appropriate solvent as necessary. Can be prepared. For example, it can be obtained by thermal polymerization at about 80 ° C. for 8 hours using a polymerization initiator such as 2,2′-azobisisobutyronitrile in ethanol, and the resulting polymer is appropriately purified. Can be used.

  The blending amount of the adhesive set resin in the hair cosmetic composition of the present invention may vary depending on the product form, but is generally 0.1 to 30% by mass, preferably 1 to 20% by mass, more preferably 2 ˜15 mass%. If it is less than 0.1% by mass, a sufficient effect may not be exhibited even when used in combination with a set resin, and if it exceeds 30% by mass, hair may become stiff.

  The hair cosmetic composition of the present invention contains a set agent resin in addition to the adhesive set resin. The set agent resin in the present invention is an anionic, cationic, amphoteric or nonionic film-forming polymer also called a set agent or a set resin, and may be conventionally blended in a hair styling agent. Specific examples include the following.

Acrylic and vinyl setting resin:
As anionic ones, alkyl acrylate / diacetone acrylamide copolymer (plus size L-53P, plus size L-9909B, plus size L-9948B etc. (all manufactured by Kyodo Chemical Co., Ltd.)), alkyl acrylate・ Octylacrylamide copolymer (Dermacryl 79 (made by NSC Japan)), polyethylene glycol / polypropylene glycol-25 / dimethicone / acrylates copolymer (rubyflex SILK (made by BASF)), acrylic acid / acrylic acid amide・ Ethyl acrylate copolymer (Ultra Hold 8, Ultra Hold Strong (manufactured by BASF)), Alkyl acrylate copolymer (Aniset NF-1000, Aniset HS-3000, etc. (Osaka Organic Chemical Industry Co., Ltd.) Etc.)) etc.

  As amphoteric ones, octylamide acrylate / hydroxypropylpropyl acrylate / butylaminoethyl methacrylate copolymer (AMPHOMER SH30, AMPHOMER LV-71 (manufactured by NSC Japan)), methacryloyloxyethylcarboxybetaine / methacrylic acid Alkyl copolymers (Yuka Former R205, Yuka Former 301, Yuka Former SM, Yuka Former 104D, etc. (manufactured by Mitsubishi Chemical Corporation), RAM Resin-1000, RAM Resin-2000, RAM Resin-3000, RAM Resin-4000 (Osaka Organic Chemical Industries Ltd.) Company)), dimethyldiallylammonium chloride / acrylic acid copolymer (Mercoat 280, Marcoat 295 (Nalco)), dimethyldiallyl ammonium chloride Acrylamide / acrylic acid copolymer (Marcoat Plus 3330, Marquat Plus 3331 (manufactured by Nalco)), etc.

  As a cationic substance, vinylpyrrolidone / dimethylaminoethyl methacrylate copolymer diethyl sulfate (HC Polymer 1S (M), HC Polymer 2 (manufactured by Osaka Organic Chemical Industry Co., Ltd.), Guff Coat 755N ( ISP)), vinylpyrrolidone / dimethylaminopropyl methacrylamide / lauryl dimethylaminopropyl methacrylamide copolymer (Styrise W-20 (ISP)), vinylpyrrolidone / N, N-dimethylaminoethyl methacrylate / acrylic Alkyl acid / dipropylene tripropylene glycol copolymer (Coscut GA467, Koscut GA468 (Osaka Organic Chemical Co., Ltd.), Polydimethylmethylenepiperidinium chloride (Mercoat 100 (Nalco)), Dimethyldiallylammonium chloride Arm acrylamide copolymer (manufactured by Merquat 550 (Nalco)), trimethyl amino propyl acrylamide chloride-dimethylacrylamide copolymer.

  Nonionic materials include polyvinylpyrrolidone (rubiscol K17, rubiscol K30, rubiscol K90 (manufactured by BASF), PVP K (manufactured by ISP)), vinylpyrrolidone / vinyl acetate copolymer (PVP / VA S-630). , PVP / VA E-735, PVP / VA E-335 (manufactured by ISP), Rubiscor VA73W, Rubiscor 37E (manufactured by BASF), PVA-6450 (manufactured by Osaka Organic Chemical Industry Co., Ltd.)), vinyl Methyl ether / alkyl maleate copolymers (Gantrez A-425, Gantrez ES-225, Gantrez ES-335, etc. (manufactured by ISP)), vinylpyrrolidone / methacrylamide / vinylimidazole copolymer (Rubiset Clear (BASF) Manufactured)), polyvinyl caprolactam Luviskol Plus (BASF)), and the like.

Urethane set resin:
Yodosol PUD (manufactured by NSC Japan), Ruby Set P.I. U. R. Polymers described in Japanese Patent Application No. 2006-183144, Dynax (manufactured by NSC Japan, Inc.) as acrylic-urethane systems, such as polymers described in (BASF) and JP-A-2006-213706.

Polysaccharide set resin:
Gum arabic, glucan, succinoglycan, carrageenan, caraya gum, tragacanth gum, guar gum, locust bean gum, galactomannan gum, xanthan gum, starch, carob gum, quince seed (malmello), casein, dextrin, gelatin, sodium pectate, sodium alginate , Methylcellulose, ethylcellulose, carboxymethylcellulose, hydroxyethylcellulose, hydroxypropylcellulose, crystalline cellulose, chlorinated O- [2-hydroxy-3- (trimethylammonio) propyl] hydroxyethylcellulose, O- [2-hydroxy-3- (trimethyl) chloride Ammonio) propyl] guar gum, chloride O- [2-hydroxy-3- (trimethylammonio) propyl] locustobi Gum, chloride Hidorokishipuropirutorimoniumu starch.

  The set agent resin blended in the hair cosmetic composition of the present invention is not particularly limited, and one or more of the set agent resins as listed above can be appropriately selected and used. Of these, urethane type setting agent resins are particularly preferred.

  The blending amount of the set agent resin in the hair cosmetic composition of the present invention is generally 0.1 to 30% by mass, preferably 0.5 to 20% by mass, more preferably 1 to 15% by mass. If it is less than 0.1% by mass, the moisture resistance may not be sufficient, and if it exceeds 30% by mass, the hair may be stiff.

  The hair cosmetic composition of the present invention contains alcohol in addition to the above-mentioned adhesive set resin and set agent resin.

  As the alcohol in the hair cosmetic composition of the present invention, one or more selected from alcohols generally used in cosmetics such as ethanol can be appropriately selected and used. The compounding quantity of alcohol is not specifically limited, It can change with the aspect of hair cosmetics. Usually, it mix | blends from the lower limit used as a solvent of adhesive set resin to 80 mass%. Moreover, it may be preferable to adjust according to the compounding quantity of water at the point which controls usability.

The hair cosmetic composition of the present invention includes a novel adhesive set resin, and further exhibits fixing strength and arranging power by including a set agent resin, and exhibits excellent moisture resistance (set holding power). The form can be provided in various forms such as hair liquid, hair foam, hair mousse, hair spray, hair mist, hair gel, hair wax and the like.
For example, according to the form of the hair cosmetic of the present invention, other components conventionally used in hair cosmetics such as water may be blended within a range not impairing the effects of the present invention.

  Hereinafter, the present invention will be described in more detail with specific examples, but the present invention is not limited to the following examples. Moreover, the compounding quantity in a following example etc. shows the mass% unless there is particular notice.

(Production example and comparative production example)
Polymerization was performed with the monomer composition shown in Table 1 below, and the adhesive set resin of the present invention (Production Examples 1 to 6) and Comparative Production Example 1 containing no monomer C and Comparative Production Example 2 containing no monomer D were prepared. .
Specifically, a mixture in which 100 parts of monomers are mixed is prepared in advance, and a dropping funnel containing this mixture, reflux cooling air, thermometer, nitrogen replacement tube, and a 1 L capacity 5 unit equipped with a stirrer are installed. In a neck flask, 100 parts of ethanol was charged, heated in a nitrogen stream, and when refluxed (about 80 ° C.), a polymerization initiator (2,2′-azobisisobutyronitrile) was added to the ethanol. 1 part is added and the mixture is added dropwise continuously for 2 hours. Thereafter, the polymerization reaction was allowed to proceed in a reflux state for 8 hours. Next, the solvent content of this solution was adjusted by distilling off the solvent from the solution in the five-necked flask and adding ethanol to obtain a solution of a hair cosmetic base having a solid content concentration of 50%.

(Examples and Comparative Examples)
Samples were prepared using the resins of the above production examples and comparative production examples, and the arrangement power, fixing power, hair styling power, and moisture resistance when the samples were used were evaluated.
The evaluation method and evaluation criteria for each characteristic are as follows.

1. Arranging power 10 gender panelists are able to arrange the hair bundle after applying 0.5g of sample to 1 bundle of black virgin hair (length 20cm, mass 2g) and drying at room temperature. Evaluation was made by a sensory test.

<Evaluation criteria>
5 points: Easy to arrange 4 points: Slightly easy to arrange 3 points: Normal 2 points: Slightly difficult to arrange 1 point: Difficult to arrange <Evaluation criteria>
◎: Total score is 40 or more ○: Total score is 30 or more and less than 40 △: Total score is 20 or more and less than 30 ×: Total score is less than 20

2. Fixing force 0.4 g of the sample was applied to black virgin hair (length: 15 cm, weight: 1 g), and the shape was adjusted so that it was straightened by using a comb. Five strands were prepared per sample. After drying this at 50 ° C. for 1 hour, it was suspended on a board with a scale, and the length of bending of the strand (b) was measured with a constant temperature and humidity chamber at a temperature of 30 ° C. and a humidity of 90% RH. Using the length (a) of the bent strand that was measured in advance when the sample was not applied, the fixing force (keep force) was determined according to the following equation. The closer the value is to 100%, the higher the fixing force and the better the moisture resistance.
Hair style keeping power (%) = {(ab) / a} × 100

<Evaluation criteria>
◎: Value is 90% or more ○: Value is less than 70 to 90% △: Value is less than 50 to 70% ×: Value is less than 50%

3. Re-styling power A 0.5g sample is applied to a bundle of black virgin hair (length: 20cm, mass: 2g), and the hair bundle is dried at room temperature. The ease of hair styling (re-hair styling ability) was evaluated by a sensory test with 10 female panelists.

<Evaluation criteria>
5 points: Re-styling ability 4 points: Slight re-styling ability 3 points: Normal 2 points: Slight re-styling ability 1 point: No re-styling ability <Evaluation criteria>
◎: Total score is 40 or more ○: Total score is 30 or more and less than 40 △: Total score is 20 or more and less than 30 ×: Total score is less than 20

4). Moisture resistance Black virgin hair (length: 20 cm, weight: 2 g) is coated with 0.5 g of the sample (hair cosmetic obtained in the examples or comparative examples) and immediately using a curler with a curl diameter of 2 cm. A curl was prepared and dried at 50 ° C. for 1 hour. The length of the curled hair strand is measured, and the length is set as an initial value (L0).
Next, the dried hair bundle is suspended on a graduated board and placed in a thermo-hygrostat with a temperature of 30 ° C. and a humidity of 90% RH for 3 hours, and then the length of the hair strand is measured. Is the length after humidification (L2).
The length of the hair strand is the maximum curl diameter in the curled state, while the maximum length from the end on the root side if the curl is partially or totally unrolled. It becomes the length (for example, the length from the end on the root side to the end on the hair end side).

The curl retention value was calculated according to the following formula, and the moisture resistance was evaluated according to the following evaluation criteria.
Curl retention value (%) = {(20−L2) / (20−L0)} × 100
Note that the closer the curl retention value is to 100%, the stronger the curl retention and the better the moisture resistance (that is, the style retention).

<Evaluation criteria>
A: The curl retention value is 90% or higher.
○: The curl retention value is 70% or more and less than 90%.
Δ: The curl retention value is 50% or more and less than 70%.
X: The curl retention value is less than 50%.

(1) When a nonionic resin is used as the setting agent resin Samples having the compositions listed in Table 2 below were prepared. The sample was prepared by adding each polymer of (3) and / or (4) to the mixture of (1) and (2) and stirring. The characteristics of each sample were then evaluated according to the above criteria. The results are also shown in Table 2.

  As is clear from the results shown in Table 2, the sample (Comparative Example 1) that does not contain the adhesive set resin (Production Example 3) has poor arranging power and re-styling power, and has insufficient moisture resistance. It was. Moreover, the sample (Examples 1-4) containing both adhesive set resin and set agent resin is compared with the sample (Comparative Example 2) which does not mix | blend (vinylpyrrolidone / VA) copolymer which is set agent resin. Improved moisture resistance.

Samples having the compositions listed in Table 3 below were prepared, and the characteristics of each sample were evaluated according to the above criteria. The results are also shown in Table 3.

  In the sample (Comparative Examples 1 and 2) which does not contain the adhesive set resin (Production Examples 1 to 6) and the resin (Comparative Production Example 1 or 2) which does not contain the monomer C or D (Comparative Examples 3 and 4) The sufficient arrangement and re-styling ability could not be demonstrated.

(2) When an anionic resin is used as the setting agent resin Samples having the compositions listed in Table 4 below were prepared. The sample was prepared by adding each polymer of (3) and / or (4) to the mixture of (1) and (2) and stirring. The characteristics of each sample were then evaluated according to the above criteria. The results are also shown in Table 4.

  As is clear from the results shown in Table 4, the sample (Comparative Example 4) that does not contain the adhesive set resin (Production Example 3) is inferior in arranging power and re-styling power and is a set agent resin (alkyl). The sample containing no (alkyl acid / diacetone acrylamide) copolymer (Comparative Example 2) did not have sufficient moisture resistance.

Samples having the compositions listed in Table 5 below were prepared, and the characteristics of each sample were evaluated according to the above criteria. The results are also shown in Table 5.

  In the sample (Comparative Examples 1 and 2) containing no adhesive set resin (Production Examples 1 to 6) and the sample containing the resin (Comparative Production Example 1 or 2) containing no monomer C or D (Comparative Examples 6 and 7) The sufficient arrangement and re-styling ability could not be demonstrated.

(3) When a cationic resin is used as the setting agent resin Samples having the compositions listed in Table 6 below were prepared. The sample was prepared by adding each polymer of (3) and / or (4) to the mixture of (1) and (2) and stirring. The characteristics of each sample were then evaluated according to the above criteria. The results are also shown in Table 6.

  As is clear from the results shown in Table 6, the sample (Comparative Example 8) that does not contain the adhesive set resin (Production Example 3) has poor arranging power and re-styling power, and is a polyquater that is a set agent resin. The sample not containing Ni-11 (Comparative Example 2) did not have sufficient moisture resistance.

Samples having the compositions listed in Table 7 below were prepared, and the characteristics of each sample were evaluated according to the above criteria. The results are also shown in Table 7.

  In the sample (Comparative Examples 1 and 2) that does not contain the adhesive set resin (Production Examples 1 to 6) and the resin that does not contain the monomer C or D (Comparative Production Example 1 or 2) (Comparative Examples 9 and 10) The sufficient arrangement and re-styling ability could not be demonstrated.

(4) When an amphoteric resin is used as the setting agent resin Samples having the compositions listed in Table 8 below were prepared. The sample was prepared by adding each polymer of (3) and / or (4) to the mixture of (1) and (2) and stirring. The characteristics of each sample were then evaluated according to the above criteria. The results are also shown in Table 8.

  As is apparent from the results shown in Table 8, the sample (Comparative Example 11) that does not contain the adhesive set resin (Production Example 3) is inferior in arranging power and re-styling power and is a set agent resin (methacryloyl) The sample containing no (oxyethylcarboxybetaine / alkyl methacrylate) copolymer (Comparative Example 2) did not have sufficient moisture resistance.

Samples having the compositions listed in Table 9 below were prepared, and the characteristics of each sample were evaluated according to the above criteria. The results are also shown in Table 9.

  In the sample (Comparative Example 1 or 2) that does not contain the adhesive set resin (Production Examples 1 to 6) and the resin that does not contain the monomer C or D (Comparative Production Example 1 or 2) (Comparative Examples 12 and 13) The sufficient arrangement and re-styling ability could not be demonstrated.

(5) When a urethane resin is used as the setting agent resin Samples having the compositions listed in Table 10 below were prepared. The sample was prepared by adding each polymer of (3) and / or (4) to the mixture of (1) and (2) and stirring. The characteristics of each sample were then evaluated according to the above criteria. The results are also shown in Table 10.

  As is clear from the results shown in Table 10, the sample (Comparative Example 14) that does not contain the adhesive set resin (Production Example 3) is inferior in arranging power and re-styling power, and silylated as a set agent resin. The sample containing no urethane resin (Comparative Example 2) did not have sufficient moisture resistance.

Samples having the compositions listed in Table 11 below were prepared, and the characteristics of each sample were evaluated according to the above criteria. The results are also shown in Table 11.

  In the sample (Comparative Examples 15 and 16) in which the adhesive set resin (Production Examples 1 to 6) is not included (Comparative Example 14) and the resin that does not contain monomer C or D (Comparative Production Example 1 or 2) is blended The sufficient arrangement and re-styling ability could not be demonstrated.

Other examples are shown below.
(Example 51)
Liquid styling agent
(1) Residual ion exchange water
(2) PEG-6 5
(3) PEG-8 5
(4) PEG-32 5
(5) Sorbitol 3
(6) Ethanol 35
(7) Perfume appropriate amount
(8) Polymer 5 obtained in Production Example 3
(9) (alkyl acid alkyl / diacetone acrylamide) copolymer 2.5
(10) Citric acid appropriate amount

<Production method>
(1) Add water-soluble components (2) to (5) to water and dissolve with stirring to obtain water parts. Next, after (7) is added to (6) and stirred to solubilize, (8) and (9) are added and stirred to obtain alcohol parts. Water parts and alcohol parts were mixed and (10) was added to obtain a liquid styling agent.

(Example 52)
Hair Styling Gel (1) Carboxyvinyl Polymer 0.7
(2) Polymer obtained in Production Example 3 5.0
(3) Glycerin 2.5
(4) 1,3-butylene glycol 2.5
(5) Polyoxyethylene octyldodecyl ether (20EO) 0.5
(6) Polyether-modified dimethylpolysiloxane 1.0
(7) Sodium hydroxide (prepared to pH 7.5) Appropriate amount (8) Ethanol 20.0
(10) Fragrance 0.1
(11) Trisodium edetate 0.03
(12) Ion-exchanged water Residue (13) (alkyl alkylate / diacetone acrylamide) copolymer 5.0

<Production method>
(3), (4), (5), (6) is added to a part of (12) and emulsified with a homomixer. Next, a part of (12) is added to form an emulsifying part. On the other hand, (1), (2), (7), (8), (9), (10), (11) and (13) are uniformly dissolved in the remaining (12), and the previous emulsifying part is added thereto. The emulsified hair styling gel was obtained.

(Example 53)
Hair Styling Gel (1) Hydroxyethylcellulose 0.7
(2) Polymer obtained in Production Example 3 12.0
(3) Propylene glycol 2.5
(4) 1,3-butylene glycol 2.5
(5) Polyoxyethylene hydrogenated castor oil (40EO) 0.5
(6) Amino-modified high molecular weight silicone 1.0
(7) Sodium hydroxide (prepared to pH 7.5) Appropriate amount (8) Ethanol 20.0
(9) Polyoxyethylene octyldodecyl ether 0.1
(10) Fragrance 0.1
(11) Trisodium edetate 0.03
(12) Ion exchange water Residue (13) (Octylacrylamide / Hydroxypropyl acrylate /
Butylaminoethyl methacrylate) copolymer 16.0

<Production method>
Prepared according to Example 52.

(Example 54)
Hair Styling Gel (1) (PEG-240 / decyltetradeceth-20 / HDI) copolymer 2.0
(2) Polymer obtained in Production Example 3 1.0
(3) Diglycerin 2.5
(4) Polyethylene glycol 1000 2.5
(5) Polyoxyethylene hydrogenated castor oil (40EO) 0.5
(6) Both-terminal hydroxy-modified dimethylpolysiloxane (1,000,000 mPa · s) 1.0
(7) Sodium hydroxide (prepared to pH 7.5) Appropriate amount (8) Ethanol 20.0
(9) Polyoxyethylene octyldodecyl ether 0.1
(10) Fragrance 0.1
(11) Trisodium edetate 0.03
(12) Ion-exchanged water Residue (13) (alkyl alkylate / diacetone acrylamide) copolymer 1.0

<Production method>
Prepared according to Example 52.

(Example 55)
Hair Styling Gel (1) Polymer obtained in Production Example 3 1.0
(2) Silylated urethane resin (Production example of JP-A-2006-213706) 2.5
(3) Glycerin 2.5
(4) Hydroxyethylurea 2.5
(5) Polyoxyethylene hydrogenated castor oil (40EO) 0.5
(6) Dimethylpolysiloxane (1,000 mPa · s) 1.0
(7) Triethanolamine (adjusted to pH 7.5) Appropriate amount (8) Ethanol 20.0
(9) Polyoxyethylene octyldodecyl ether 0.1
(10) Fragrance 0.1
(11) Trisodium edetate 0.03
(12) Ion exchange water Residue (13) (Octylacrylamide / Hydroxypropyl acrylate /
(Butylaminoethyl methacrylate) copolymer 1.0

<Production method>
Prepared according to Example 52.

(Example 56)
Styling mousse (1) Dimethylpolysiloxane (20 mPa · s) 5.0
(2) Isoparaffin 5.0
(3) High molecular weight polysiloxane 2.0
(4) Amino-modified high molecular weight silicone 0.5
(5) 1,3-butylene glycol 3.0
(6) Polyoxyethylene hydrogenated castor oil (40EO) 2.0
(7) Polymer obtained in Production Example 3 10.0
(8) Polyoxyethylene / polyoxypropylene decyl ether (12EO · 2PO) 1.0
(9) Behenyltrimethylammonium chloride 0.1
(10) Phenoxyethanol 0.1
(11) Ethanol 8.0
(12) Ion exchange water Residue (13) Fragrance Appropriate amount (14) (Octylacrylamide / hydroxypropyl acrylate /
(Butylaminoethyl methacrylate) copolymer 1.0

<Production method>
Add (3) and (4) with stirring and dissolution to (1) and (2) to (5), (6) and a part of (12), and emulsify with a homomixer (emulsification part). On the other hand, (7) is added to the remaining (12) (water phase parts). Add (8), (9), (10), (13), (14) to (11), dissolve with stirring, add this to the previous aqueous phase part, and then add the emulsified part, Mix uniformly to make a stock solution. 90 parts of this stock solution was filled in an aerosol can, valved, and filled with 10 parts of liquefied petroleum gas (LPG) to obtain a styling mousse.

(Example 57)
Styling mousse (1) Dimethylpolysiloxane (20mPa · s) 5.0
(2) Both terminal hydroxy-modified high molecular weight methylpolysiloxane 5.0
(3) (Octylacrylamide / Hydroxypropyl acrylate /
(Butylaminoethyl methacrylate) copolymer 1.0
(4) 1,3-butylene glycol 3.0
(5) Polyoxyethylene hydrogenated castor oil (40EO) 2.0
(6) Polymer obtained in Production Example 3 10.0
(7) Polyoxyethylene cetyl ether (20EO) 0.5
(8) Stearyltrimethylammonium chloride 0.1
(9) Phenoxyethanol 0.5
(10) Ethanol 8.0
(11) Ion exchange water Residual (12) Perfume appropriate amount

<Production method>
Prepared according to Example 56.

(Example 58)
Styling mousse (1) Dimethylpolysiloxane (6 mPa · s) 5.0
(2) Isoparaffin 5.0
(3) (PEG / amodimethicone) copolymer 1.0
(4) 1,3-butylene glycol 3.0
(5) Polyoxyethylene hydrogenated castor oil (40EO) 2.0
(6) Polymer obtained in Production Example 3 1.0
(7) Lauric acid diethanolamide 0.2
(8) Stearoxyhydroxypropylamine 0.1
(9) Phenoxyethanol 0.1
(10) Ethanol 8.0
(11) Ion exchange water Residue (12) Perfume appropriate amount (13) (octylacrylamide / hydroxypropyl acrylate /
(Butylaminoethyl methacrylate) copolymer 0.5

<Production method>
Prepared according to Example 56.

(Example 59)
Styling mousse (1) Dimethylpolysiloxane (20mPa · s) 5.0
(2) Volatile isoparaffin 5.0
(3) Polyether-modified high molecular weight silicone 3.5
(4) 1,3-butylene glycol 3.0
(5) Polyoxyethylene hydrogenated castor oil (40EO) 2.0
(6) Silylated urethane resin (Production example of JP-A-2006-213706) 10.0
(7) Polyoxyethylene / polyoxypropylene behenyl ether (12EO / 1PO) 1.0
(8) Cationized trehalose 0.1
(9) Phenoxyethanol 0.1
(10) Ethanol 8.0
(11) Ion-exchanged water Residue (12) Perfume appropriate amount (13) Polymer obtained in Production Example 3 3.0

<Production method>
Prepared according to Example 56.

(Example 60)
Styling spray (1) Polymer obtained in Production Example 3 5.0
(2) Pyrocarboxylic acid-modified dimethylpolysiloxane 0.5
(3) Alcohol Residue (4) Perfume Appropriate amount (5) (alkyl alkylate / diacetone acrylamide) copolymer 10.0

<Production method>
(1) to (5) are mixed and dissolved to obtain a stock solution. An aerosol can is filled with 50% of the stock solution and 50% of dimethyl ether to form an aerosol spray.

(Example 61)
Styling spray The stock solution is prepared in the same manner as in Example 15. Mix 99.33% of the stock solution and 0.67% of nitrogen gas and fill the aerosol can to make an aerosol spray that does not use flammable gas.

(Example 62)
Hair wax (1) Kaolin 1.0
(2) Volatile isoparaffin 5.0
(3) Cetyl octanoate 5.0
(4) Phenylmethylpolysiloxane 0.5
(5) Candelilla wax 3.0
(6) Paraffin wax 8.0
(7) Propylene glycol 5.0
(8) Glyceryl stearate 1.0
(9) Polystearic acid polyoxyethylene glycerol (5EO) 1.0
(10) Isostearic acid 1.0
(11) Carboxyvinyl polymer 0.4
(12) Potassium hydroxide (prepared to pH 7.5) Appropriate amount (13) Ion exchange water Residue (14) Polymer obtained in Production Example 3 5.0
(15) Sorbitol 3.0
(16) EDTA-2Na.2H2O 0.05
(17) Phenoxyethanol 0.5
(18) Perfume appropriate amount (19) Highly polymerized polyethylene glycol 0.1
(20) Silylated urethane-based resin (Production example of JP-A-2006-213706) 1.0

<Production method>
(16), (7) and (15) are added to (13) and dissolved, then (11) is added and uniformly stirred and dispersed, (1) is added and uniformly dispersed using a disper and heated to 85 ° C., Similarly, the mixture of (2) to (9) that was stirred and dissolved at 85 ° C. was added, and after uniform stirring, (12) was added and emulsified with a homomixer, and (14), (15), (17) to (17) 20) was sequentially added and cooled to 25 ° C. to obtain a hair wax.

Claims (2)

The following formula (I):
In formula (I):
R1 is H or CH _3, n is an integer of 2~30 _{(CH 2) n} comprises a branched chain,
R2 is H, OCH ₃ , OCH ₂ CH ₃ or phenyl;
R3 is H or CH _3, R4 and R5 may be the same or different, H, or _{(CH 2) l} R 'a, l is an integer from 1 to 3, R' is H, OH Or —NR ″ R ′ ″, where R ″ and R ′ ″ may be the same or different and are H or a C ₁ -C ₃ alkyl group;
R6 is H or CH _3, p is an integer of 6 to 100, m is an integer of 0 to 30,
R7 is H, OH, OCH ₃ , OCH ₂ CH ₃ , or phenyl, X is an oxyethylene group (EO), an oxypropylene group (PO), an oxybutylene group (BO), or a glyceryl group,
R8 and R9 are the same, H or CH ₃ , q is an integer of 1 to 100, Y is an oxyethylene group (EO), oxypropylene group (PO), oxybutylene group (BO), carbon number 5 The above linear or branched oxyalkylene group or glyceryl group (provided that when Y is a linear or branched oxyalkylene group having 5 or more carbon atoms, q is 1);
a is an adhesive set resin having a structure represented by 40 <a <400, b is 80 ≦ b <300, c is 30 <c <300, and d is a number in the range of 0 <d <10), A hair cosmetic containing a setting agent resin and alcohol. The setting agent resin, anionic, cationic, amphoteric, and wherein the at least one selected from nonionic film-forming polymer, the hair cosmetic according to claim 1.