WO2011021682A1 - Hair-dressing cosmetic - Google Patents
Hair-dressing cosmetic Download PDFInfo
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- WO2011021682A1 WO2011021682A1 PCT/JP2010/064050 JP2010064050W WO2011021682A1 WO 2011021682 A1 WO2011021682 A1 WO 2011021682A1 JP 2010064050 W JP2010064050 W JP 2010064050W WO 2011021682 A1 WO2011021682 A1 WO 2011021682A1
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
Definitions
- the present invention relates to a hairdressing cosmetic. More specifically, the present invention relates to a hairdressing cosmetic composition that has excellent hair conditioning and re-styling power while having low viscosity, is non-sticky, is smooth, and has excellent lightness to finish.
- hair setting resins such as hair fixing polymers and film-forming polymers are blended for styling.
- the hair setting resin has problems such as stiffening, non-uniformity of the film, and a decrease in styling holding power under high humidity. Therefore, various countermeasures have been taken in order to solve this problem.
- Patent Document 1 Japanese Patent Application Laid-Open No. 2007-217314
- a mist-like powder cosmetic containing a specific amount of a hair fixing polymer compound, a polyhydric alcohol, a monohydric alcohol, and a propellant has been described. It is described that it has excellent properties, has no stickiness, and has a natural gloss.
- Patent Document 2 a hair cosmetic containing a specific amount of a specific low-viscosity polyether compound and a high-molecular resin compound has hair styling power and hair styling keeping power, and is sticky.
- the hair can be re-styled with a handbrush or the like even after drying, without being stiff.
- Patent Document 3 JP-A-3-261713 discloses a specific polyoxyalkylene compound and / or polyoxyalkylene alkylglycoside, a polymer compound for fixing hair, and a high molecular weight polyethylene glycol (molecular weight 6,000). It is described that a hair cosmetic containing ⁇ 30,000) has hair styling properties and smoothness (smoothness).
- Patent Document 4 JP 2002-167317 A discloses a hair cosmetic composition containing an amphoteric polymer, a sugar alcohol, and a sugar alcohol derivative (for example, a polyoxyalkylene adduct of a sugar alcohol). It describes that it has a set holding power and does not have a sticky or stiff feeling.
- the hair-styling cosmetic composition having a low viscosity and a water-based hairstyling ability is obtained to the extent that both hair styling ability and re-styling ability can be fully satisfied, and in addition, there is no stickiness, smoothness,
- a hairdressing cosmetic that has the effect of being light in finish.
- water-based hairdressing cosmetics with low viscosity it is particularly difficult to achieve both setting power and arranging power. Therefore, there has been a demand for the development of an aqueous low-viscosity cosmetic having a sufficient setting power and arranging power and having a good feeling of use.
- JP 2007-217314 A Japanese Patent Application Laid-Open No. 11-10032 JP-A-3-261713 JP 2002-167317 A JP-T-2004-505902
- the present invention has been made in view of the above-described conventional circumstances, and is an aqueous hairdressing makeup that is excellent in styling power and re-styling power while being low in viscosity, has no stickiness, is smooth, and has a light finish.
- the purpose is to provide a fee.
- the present inventors have found that the above problem can be solved by blending a predetermined amount of an adhesive resin having a predetermined adhesive property and a hair setting resin, and have completed the present invention. That is, the present invention (A) 0.1 to 10% by mass of an adhesive resin having adhesiveness with a ball number of 1 to 30 in an inclined ball tack test (inclination angle 30 °, 25 ° C., humidity 50%); (B) A hair styling cosmetic characterized by containing 0.1 to 10% by mass of a hair setting resin.
- the hairdressing cosmetic composition of the present invention contains a specific amount of an adhesive resin and a hair setting resin in a predetermined amount and is prepared to have a low viscosity. At the same time, it can exhibit excellent hair styling power and re-styling power, and is excellent in water resistance.
- the hairdressing cosmetic composition of the present invention contains an adhesive resin (component a) having a predetermined adhesiveness as an essential component.
- the tackiness of the tacky resin is specified by a ball tack test in accordance with JIS Z 0237.
- the ball tack test is an adhesive test method for measuring using a measuring apparatus as shown in FIG. Specifically, the sample to be measured (adhesive substance) is placed on the inclined surface of the measuring apparatus in FIG. 1 and the top portion of the inclined surface is covered with a non-adhesive sheet to form a runway. When a ball of material and size is rolled from the top of the inclined surface, the adhesiveness is specified by the number of the largest ball among the balls stopped at any position on the adhesive surface.
- the adhesive resin used in the present invention in particular, a composition having a resin real fraction of 50% by mass is prepared, and a coating film having a thickness of 0.1 mm is formed on the inclined surface of FIG.
- a ball tack test was performed using a sample surface dried at 50% for 1 day.
- the measurement conditions are as follows: the inclination angle of the inclined surface in the measurement apparatus shown in FIG. 1 is 30 degrees, the measurement is performed at 25 ° C. and 50% humidity, and the ball number is 1 to 30, more preferably 3 to 25
- the adhesive resin in the present invention was used.
- the adhesive resin used in the present invention include acrylic resins such as Acronal YJ2720D, Acronal V215ap, Acronal N285, Acronal V210, Acronal V212 (above, manufactured by BASF), NCOR38-088A, Duro -Tak87-200A, Duro-Tak387-2054 / 87-2054 (manufactured by National Starch & Chemical Co.), MG-0560, MG-0580 (manufactured by Dow Corning), Daitosol 5000AD (Daito Kasei), an alkyl acrylate ester Manufactured by Kogyo Co., Ltd.), Yodosol AH955 belonging to methacrylic acid alkyl ester / acrylic acid alkyl ester copolymer, PRIMAL PS83-D ( ohm & HAAS Co., Ltd.), and the like can be mentioned.
- acrylic resins such as Acronal YJ2720D, A
- an adhesive set resin obtained by polymerizing the following monomer A and / or monomer B, monomer C and monomer D may be selected.
- Monomer A the following formula: (Wherein, R1 is H or CH 3, n is an integer of 0 ⁇ 30 (CH 2) n comprises a branched chain, R2 is H, OH, with OCH 3, OCH 2 CH 3 or phenyl At least one monomer represented by
- Monomer B the following formula: (Wherein, R3 is H or CH 3, R4 and R5 may be the same or different, H, or (CH 2) l R 'a, l is an integer of 1 ⁇ 3, R' Is H, OH or —NR ′′ R ′ ′′, and R ′′ and R ′ ′′ may be the same or different and are H or a C1-C3 alkyl group). .
- Monomer C the following formula: (Wherein, R6 is H or CH 3, p is an integer of 1 ⁇ 100, m is an integer of 0 ⁇ 30, R7 is H, OH, OCH 3, OCH 2 CH 3, or phenyl And X is at least one monomer represented by an oxyethylene group (EO), an oxypropylene group (PO), an oxybutylene group (BO), or glyceryl).
- EO oxyethylene group
- PO oxypropylene group
- BO oxybutylene group
- glyceryl glyceryl
- Monomer D the following formula: (Wherein R8 is H or CH 3 , q is an integer of 1 to 100, Y is an oxyethylene group (EO), an oxypropylene group (PO), an oxybutylene group (BO), 5 or more carbon atoms) A linear or branched oxyalkylene group or glyceryl (provided that when Y is an oxyalkylene group having 5 or more carbon atoms, q is 1).
- R1 to R9, n, m, p and q have the same meanings as in the above formulas AD.
- EO oxyethylene group
- PO oxypropylene group
- BO oxybutylene group
- a is a number in the range of 40 ⁇ a ⁇ 400, b is 80 ⁇ b ⁇ 300, c is 30 ⁇ c ⁇ 300, and d is 0 ⁇ d ⁇ 10.
- the mass% of each monomer in the adhesive set resin (polymer of formula (I)) that satisfies the above conditions is approximately as follows. 7.5 ⁇ A ⁇ 62.5, 20 ⁇ B ⁇ 45, 7.5 ⁇ C ⁇ 60, 0 ⁇ D ⁇ 5.
- the adhesive set resin used in the present invention is prepared by mixing the above monomers A and / or B and C and D in an appropriate ratio, and performing a polymerization reaction using a standard method in an appropriate solvent as necessary.
- silicone-based adhesive resins examples include addition-reactive silicones SD4584, SD4560, SD4570, SD4580, SD4585, SD4587L (above, Toray Dow Silicone), TSR1512, TSR1516 (above, MOMENTIVE) Can do.
- the resin is not limited to the specific examples enumerated above as long as it satisfies the above-mentioned adhesive condition, and one or more of them can be used in combination.
- the blending amount of the adhesive resin in the cosmetic of the present invention is 0.1 to 10% by mass, more preferably 0.5 to 7.5% by mass. If it is less than 0.1% by mass, the desired effect cannot be obtained, and if it exceeds 10% by mass, stickiness occurs.
- the hairdressing cosmetic composition of the present invention contains a hair setting resin in addition to the adhesive resin, and the moisture resistance is improved by blending the hair setting resin.
- the hair set resin that can be blended in the cosmetics of the present invention is an anionic, cationic, amphoteric, nonionic film-forming polymer also called a set agent or a set resin, and has been conventionally blended in hair styling agents. It may be what you have. Specific examples include the following.
- Acrylic and vinyl hair set resins As anionic ones, alkyl acrylate / diacetone acrylamide copolymers (plus size L-53P, plus size L-9909B, plus size L-9948B etc. (all manufactured by Kyoyo Chemical Co., Ltd.)), alkyl acrylate ⁇ Octylacrylamide copolymer (Dermacryl 79 (made by NSC Japan)), polyethylene glycol ⁇ polypropylene glycol-25 ⁇ Dimethicone ⁇ Acrylates copolymer (Rubiflex SILK (made by BASF)), acrylic acid / acrylic acid amide ⁇ Ethyl acrylate copolymer (Ultrahold 8, Ultrahold Strong (manufactured by BASF)), alkyl acrylate copolymer (aniset NF-1000, aniset HS-3000, etc.) Etc.)) etc.
- alkyl acrylate / diacetone acrylamide copolymers plus size L-53P, plus size L-9909B
- acrylic acid octylamide / hydroxypropylpropyl acrylate / butylaminoethyl methacrylate copolymer (AMPHOMER SH30, AMPHOMER LV-71 (made by NSC Japan)), methacryloyloxyethylcarboxybetaine / methacrylic acid Alkyl copolymers (Yukaformer R205, Yukaformer 301, Yukaformer SM, Yukaformer 104D, etc.
- vinylpyrrolidone / dimethylaminoethyl methacrylate copolymer diethyl sulfate HC Polymer 1S (M), HC Polymer 2 (manufactured by Osaka Organic Chemical Industry Co., Ltd.), Guff Coat 755N ( ISP)), vinylpyrrolidone / dimethylaminopropyl methacrylamide / lauryl dimethylaminopropyl methacrylamide copolymer (Styrise W-20 (ISP)), vinylpyrrolidone / N, N-dimethylaminoethyl methacrylate / acrylic Alkyl diacrylate / tripropylene glycol copolymer (Coscut GA467, Koscut GA468 (manufactured by Osaka Organic Chemical Industry Co., Ltd.), polydimethylmethylenepiperidinium chloride (Mercoat 100 (manufactured by Nalco)), dimethyldiallylam
- Nonionic materials include polyvinylpyrrolidone (rubiscol K17, rubiscol K30, rubiscol K90 (manufactured by BASF), PVP K (manufactured by ISP)), vinylpyrrolidone / vinyl acetate copolymer (PVP / VA S-630).
- Urethane hair set resin Yodosol PUD (manufactured by NSC Japan), Ruby Set P.I. U. R. (A product of BASF), a polymer described in JP-A-2006-213706, etc., an acrylic-urethane type, Dynax (manufactured by NSC Japan), a polymer described in Japanese Patent Application No. 2006-183144, and the like.
- Polysaccharide hair set resin Gum arabic, glucan, succinoglycan, carrageenan, caraya gum, tragacanth gum, guar gum, locust bean gum, galactomannan gum, xanthan gum, starch, carob gum, quince seed (malmello), casein, dextrin, gelatin, sodium pectate, sodium alginate , Methylcellulose, ethylcellulose, carboxymethylcellulose, hydroxyethylcellulose, hydroxypropylcellulose, crystalline cellulose, chlorinated O- [2-hydroxy-3- (trimethylammonio) propyl] hydroxyethylcellulose, O- [2-hydroxy-3- (trimethyl) chloride Ammonio) propyl] guar gum, chloride O- [2-hydroxy-3- (trimethylammonio) propyl] locustobi Gum, chloride Hidorokishipuropirutorimoniumu starch.
- the hair set resin to be blended in the hairdressing cosmetic composition of the present invention is not particularly limited, and one or more of the hair set resins listed above can be appropriately selected and used. Vinyl-based or urethane-based hair setting resins are particularly preferable.
- the blending amount of the hair setting resin in the hairdressing cosmetic composition of the present invention is generally 0.1 to 10% by mass, more preferably 0.5 to 7.5% by mass. If it is less than 0.1% by mass, moisture resistance may not be sufficient, and if it exceeds 10% by mass, hair may be stiff.
- the hairdressing cosmetic composition of the present invention has a low viscosity, so that the solvent is quickly volatilized when applied to hair, and stickiness is obtained.
- the viscosity when measured with a B-type viscometer at 25 ° C. is preferably 100 mPa ⁇ s or less. It becomes easy to exhibit the effect of the present invention by spraying in the form of a mist. If the viscosity is greater than 100 mPa ⁇ s, it may not be suitable for spraying in the form of a mist, and may cause problems such as clogging of the nozzles of the spray device.
- the range of tackiness after the solvent in the cosmetic composition volatilizes is also an important factor.
- the adhesiveness By setting the adhesiveness within a predetermined range, stickiness when applied to hair can be suppressed and at the same time the re-styling power can be improved.
- the above-described ball tack test (shown in FIG. 1) was performed after forming a 0.1 mm thick film using the cosmetic of the present invention and drying it at 25 ° C. and 50% humidity for 1 day. It is preferable that the inclination angle of the inclined surface in the measuring apparatus is 10 degrees and the ball number is 1 to 30, more preferably 3 to 25 when measured at 25 ° C. If the adhesiveness is so low that the ball number 1 does not stop, the re-styling force is insufficient, and if the adhesiveness is so large that the ball larger than the ball number 30 stops, the hair may become sticky.
- the hairdressing cosmetic composition of the present invention preferably contains 0.01 to 5% by mass, more preferably 0.1 to 3% by mass of oil. By containing oil, further smoothness can be imparted to the hair.
- the oil used in the present invention is not particularly limited, and can be selected from oils that have been conventionally blended in cosmetics, particularly hair cosmetics.
- heavy isoparaffin hydrogenated polyisobutene
- low-quality isoparaffin for example, Isopar A, C, E, G, H, K, L, M (all of which are manufactured by Exxon), shell Sol 71 (manufactured by Shell), salt roll 100, 130, 220 (all of which are manufactured by Philippe), etc.
- squalane liquid oil such as liquid paraffin; cetyl-2-ethylhexanoate, 2- Esters such as ethylhexyl palmitate, 2-octyldodecyl myristate, neopentyl glycol-2-ethylhexanoate, isopropyl myristate, myristyl myristate, pentaerythrityl tetra-2-ethylhexanoate; olive oil, avocado oil, jojoba Oil, sunflower oil, safflower oil, camellia oil, macadamia nut
- hair styling oil components that mean monovalent to tetravalent alcohols or EO / PO adducts of monovalent to trivalent carboxylic acids.
- Unilube 50 MB 168, Unilube MB370, Triol G-40, Sabondol SGP-7, Sabondol GP-9 (above NOF Corporation) and the like can be mentioned.
- the hairdressing cosmetic composition of the present invention preferably contains water and alcohol in addition to the above-described adhesive resin and hair setting resin.
- the alcohol in the hairdressing cosmetic composition of the present invention one or more selected from alcohols generally used in cosmetics such as ethanol can be appropriately selected and used.
- the blending amounts of water and alcohol are not particularly limited, and are appropriately adjusted within a range where the above-mentioned predetermined tackiness and viscosity are obtained.
- the hairdressing cosmetic composition of the present invention can be provided in various forms such as a hair liquid, a hair foam, a hair mousse, a hair spray, a hair mist, a hair gel, a hair wax, etc., but contains a predetermined amount of an adhesive resin and a hair set resin.
- a hair liquid a hair foam
- a hair mousse a hair spray
- a hair mist a hair gel
- a hair wax etc.
- it is a cosmetic that can have limited adhesiveness and viscosity
- it is particularly suitable for a form that is sprayed in the form of a mist during use. By using it in the form of a mist, the volatilization of the solvent is fast, and the tackiness and hair styling power can be exhibited quickly.
- the hairdressing cosmetic composition of the present invention may be blended, for example, with other components conventionally used in hairdressing cosmetic compositions in a range that does not impair the effects of the present invention, depending on its form.
- Fixing force 0.4 g of the sample was applied to black virgin hair (length: 15 cm, weight: 1 g), and the shape was adjusted so as to be straightened by using a comb. Five strands were prepared per sample. After drying this at 50 ° C. for 1 hour, it was suspended on a board with a scale, and the length of bending of the strand (b) was measured with a constant temperature and humidity chamber at a temperature of 30 ° C. and a humidity of 90% RH. Using the length (a) of the bent strand that was measured in advance when the sample was not applied, the fixing force (keep force) was determined according to the following equation. The closer the value is to 100%, the higher the fixing force and the better the moisture resistance.
- Hair style keeping power (%) ⁇ (ab) / a ⁇ ⁇ 100 ⁇ Evaluation criteria> ⁇ : Value is 90% or more ⁇ : Value is 70 to less than 90% ⁇ : Value is 50 to less than 70% ⁇ : Value is less than 50%
- Re-styling power A 0.5g sample is applied to a bundle of black virgin hair (length: 20cm, mass: 2g), and the hair bundle is dried at room temperature. The ease of hair styling (re-hair styling power) was evaluated by a sensory test by a specialized panelist.
- ⁇ Evaluation criteria> ⁇ : Total score is 40 or more ⁇ : Total score is 30 or more and less than 40 ⁇ : Total score is 20 or more and less than 30 ⁇ : Total score is less than 20
- the length of the hair strand is the maximum curl diameter in the curled state, while the maximum length from the end on the root side if the curl is partially or totally unrolled. It becomes the length (for example, the length from the end on the root side to the end on the hair end side).
- the curl retention value was calculated according to the following formula, and the moisture resistance was evaluated according to the following evaluation criteria.
- Curl retention value (%) ⁇ (20 ⁇ L2) / (20 ⁇ L0) ⁇ ⁇ 100 Note that the closer the curl retention value is to 100%, the stronger the curl retention rate and the better the moisture resistance (that is, the style retention force).
- the curl retention value is 50% or more and less than 70%.
- X The curl retention value is less than 50%.
- Example 11 Liquid styling agent (1) Residual ion exchange water (2) PEG-6 5 (3) PEG-8 5 (4) PEG-32 5 (5) Sorbitol 1 (6) Ethanol 50 (7) Perfume appropriate amount (8) Adhesive set resin 3 of Production Example 3 (9) (alkyl acrylate / diacetone acrylamide) Copolymer 2 (10) Citric acid appropriate amount
- Example 12 Liquid styling agent (1) Residual ion exchange water (2) PEG-6 3 (3) PEG-8 3 (4) PEG-32 3 (5) Sorbitol 2 (6) Ethanol 40 (7) Perfume appropriate amount (8) Adhesive set resin 3 of Production Example 3 (9) (alkyl acrylate / diacetone acrylamide) Copolymer 3 (10) PPG-40-butyl 1 (11) Citric acid appropriate amount
- Liquid styling agent (1) Residual ion exchange water (2) PEG-6 7 (3) PEG-32 7 (4) Maltitol 10 (5) PEG / PPG-55 / 28 dimethyl ether 1 (6) Ethanol 5 (7) Perfume appropriate amount (8) Acronal V215ap 1 (9) (alkyl acrylate / diacetone acrylamide) Copolymer 2 (10) Citric acid appropriate amount (11) Appropriate amount of phenoxyethanol
- ⁇ Production method> (1) Add water-soluble components (2) to (5) to water and dissolve with stirring to obtain water parts. Next, (6) (7) is added to ethanol and stirred to solubilize, and then (5), (9) and (11) are added and stirred to obtain an alcohol part. Water parts and alcohol parts were mixed and (8) and (10) were added to obtain a liquid styling agent.
Abstract
Disclosed is a hair-dressing cosmetic which exerts good hair-dressing effect and hair-redressing effect, although being water-based and having a low viscosity, shows no stickiness and high smoothness and gives the sense of a favorable light finish. Specifically disclosed is a hair-dressing cosmetic containing (a) 0.1-10 mass% of a pressure-sensitive adhesive resin having pressure-sensitive adhesiveness, and (b) 0.1-10 mass% of a hair-setting resin, characterized in that said pressure-sensitive adhesive resin (a) has such properties that a film of 0.1 mm in thickness that is formed of a composition containing said resin substantially at a ratio of 50 mass% has, after drying for 1 day at 25oC and humidity 50%, a pressure-sensitive adhesiveness of showing a ball number of 1-30 in the inclined ball tack test (inclination angle 30o, measured at 25oC, humidity 50%). Thus, a hair-dressing cosmetic, which exerts good hair-dressing effect and hair-redressing effect, shows no stickiness and high smoothness, gives the sense of a favorable light finish, and is suitable for application by mist-spraying, can be obtained.
Description
本発明は整髪用化粧料に関する。さらに詳しくは、低粘度でありながら整髪力および再整髪力に優れ、しかも、べたつきがなく、滑らかで、仕上がりの軽さに優れる整髪用化粧料に関する。
The present invention relates to a hairdressing cosmetic. More specifically, the present invention relates to a hairdressing cosmetic composition that has excellent hair conditioning and re-styling power while having low viscosity, is non-sticky, is smooth, and has excellent lightness to finish.
従来、整髪用化粧料においては、スタイリングのために毛髪固定用高分子、皮膜形成性高分子等の毛髪セット樹脂を配合している。しかし毛髪セット樹脂は、ごわつき、皮膜の非均一性、高湿度下におけるスタイリング保持力低下をもたらす等の不具合がある。そこでこの不具合を解消するために、種々の対応策が採られてきた。
Conventionally, in hairdressing cosmetics, hair setting resins such as hair fixing polymers and film-forming polymers are blended for styling. However, the hair setting resin has problems such as stiffening, non-uniformity of the film, and a decrease in styling holding power under high humidity. Therefore, various countermeasures have been taken in order to solve this problem.
例えば特開２００７－２１７３１４号公報（特許文献１）には、毛髪固定用高分子化合物、多価アルコール、一価のアルコール、および噴射剤をそれぞれ特定量配合した霧状粉末化粧料が、再整髪性に優れ、べたつき感がなく、自然な艶感を有するということが記載されている。
For example, in Japanese Patent Application Laid-Open No. 2007-217314 (Patent Document 1), a mist-like powder cosmetic containing a specific amount of a hair fixing polymer compound, a polyhydric alcohol, a monohydric alcohol, and a propellant has been described. It is described that it has excellent properties, has no stickiness, and has a natural gloss.
特開平１１－１００３１２号公報（特許文献２）には、特定の低粘度ポリエーテル化合物と、高分子樹脂化合物をそれぞれ特定量配合した毛髪化粧料が、整髪力および整髪キープ力を有し、べたつき、ごわつきがなく、ドライ後でも手ぐし等で再整髪可能であるということが記載されている。
In Japanese Patent Application Laid-Open No. 11-10032 (Patent Document 2), a hair cosmetic containing a specific amount of a specific low-viscosity polyether compound and a high-molecular resin compound has hair styling power and hair styling keeping power, and is sticky. In addition, it is described that the hair can be re-styled with a handbrush or the like even after drying, without being stiff.
特開平３－２６１７１３号公報（特許文献３）には、特定のポリオキシアルキレン系化合物および／またはポリオキシアルキレンアルキルグリコシドと、毛髪固定用高分子化合物と、高分子量のポリエチレングリコール（分子量６，０００～３０，０００）を配合した毛髪化粧料が、整髪性、平滑性（滑らかさ）を有するということが記載されている。
JP-A-3-261713 (Patent Document 3) discloses a specific polyoxyalkylene compound and / or polyoxyalkylene alkylglycoside, a polymer compound for fixing hair, and a high molecular weight polyethylene glycol (molecular weight 6,000). It is described that a hair cosmetic containing ˜30,000) has hair styling properties and smoothness (smoothness).
特開２００２－１６７３１７号公報（特許文献４）には、両性高分子、糖アルコール、糖アルコール誘導体（例えば糖アルコールのポリオキシアルキレン付加物など）を配合した毛髪化粧料組成物が、整髪力、セット保持力を有し、べたつき感やごわつき感がないということが記載されている。
JP 2002-167317 A (Patent Document 4) discloses a hair cosmetic composition containing an amphoteric polymer, a sugar alcohol, and a sugar alcohol derivative (for example, a polyoxyalkylene adduct of a sugar alcohol). It describes that it has a set holding power and does not have a sticky or stiff feeling.
特表２００４－５０５９０２号公報（特許文献５）には、特定の水溶性ポリアルキレングリコールと皮膜形成ポリマーを特定の比率で配合し、さらに液体キャリアを配合したヘアケア組成物が、再スタイリング性、感触に優れるということが記載されている。
In Japanese translations of PCT publication No. 2004-505902 (patent document 5), a hair care composition containing a specific water-soluble polyalkylene glycol and a film-forming polymer in a specific ratio and further containing a liquid carrier has a re-styling property and feel. It is described that it is excellent.
しかし上記公報には、特に水系で低粘度の整髪用化粧料において整髪力と再整髪力をともに十分に満足し得る程度に得るということ、およびそれに加えてさらに、べたつき感がなく、滑らかで、仕上がりの軽さに優れるという効果を奏する整髪用化粧料を得るという目的や課題についての記載・示唆がない。粘度の低い水系の整髪用化粧料においては、セット力とアレンジ力の両立は特に難しい。そのため、十分なセット力およびアレンジ力を併せ持ち、しかも良好な使用感を有する水系低粘度の整髪用化粧料の開発が求められていた。
However, in the above-mentioned publication, in particular, the hair-styling cosmetic composition having a low viscosity and a water-based hairstyling ability is obtained to the extent that both hair styling ability and re-styling ability can be fully satisfied, and in addition, there is no stickiness, smoothness, There is no description or suggestion about the purpose or problem of obtaining a hairdressing cosmetic that has the effect of being light in finish. In water-based hairdressing cosmetics with low viscosity, it is particularly difficult to achieve both setting power and arranging power. Therefore, there has been a demand for the development of an aqueous low-viscosity cosmetic having a sufficient setting power and arranging power and having a good feeling of use.
本発明は上記従来の事情に鑑みてなされたもので、水性系で低粘度でありながら整髪力および再整髪力に優れ、しかも、べたつきがなく、滑らかで、仕上がりの軽さに優れる整髪用化粧料を提供することを目的とする。
The present invention has been made in view of the above-described conventional circumstances, and is an aqueous hairdressing makeup that is excellent in styling power and re-styling power while being low in viscosity, has no stickiness, is smooth, and has a light finish. The purpose is to provide a fee.
本発明者等は、鋭意検討した結果、所定の粘着性を有する粘着性樹脂と、毛髪セット樹脂を所定量配合することにより前記課題が解決されることを見出し、本発明を完成した。即ち、本発明は、
（ａ）傾斜式ボールタック試験（傾斜角３０度、２５℃、湿度５０％）におけるボールナンバーが１～３０である粘着性を有する粘着性樹脂を０．１～１０質量％と、
（ｂ）毛髪セット樹脂を０．１～１０質量％とを含有することを特徴とする整髪用化粧料を提供する。 As a result of intensive studies, the present inventors have found that the above problem can be solved by blending a predetermined amount of an adhesive resin having a predetermined adhesive property and a hair setting resin, and have completed the present invention. That is, the present invention
(A) 0.1 to 10% by mass of an adhesive resin having adhesiveness with a ball number of 1 to 30 in an inclined ball tack test (inclination angle 30 °, 25 ° C., humidity 50%);
(B) A hair styling cosmetic characterized by containing 0.1 to 10% by mass of a hair setting resin.
（ａ）傾斜式ボールタック試験（傾斜角３０度、２５℃、湿度５０％）におけるボールナンバーが１～３０である粘着性を有する粘着性樹脂を０．１～１０質量％と、
（ｂ）毛髪セット樹脂を０．１～１０質量％とを含有することを特徴とする整髪用化粧料を提供する。 As a result of intensive studies, the present inventors have found that the above problem can be solved by blending a predetermined amount of an adhesive resin having a predetermined adhesive property and a hair setting resin, and have completed the present invention. That is, the present invention
(A) 0.1 to 10% by mass of an adhesive resin having adhesiveness with a ball number of 1 to 30 in an inclined ball tack test (inclination angle 30 °, 25 ° C., humidity 50%);
(B) A hair styling cosmetic characterized by containing 0.1 to 10% by mass of a hair setting resin.
本発明の整髪用化粧料は、粘着性樹脂と毛髪セット樹脂という特定の成分を所定量配合し、低粘度に調製されているため、特に霧状に噴霧して使用するのに適していると同時に、優れた整髪力及び再整髪力を発揮することができ、しかも耐水性に優れている。
The hairdressing cosmetic composition of the present invention contains a specific amount of an adhesive resin and a hair setting resin in a predetermined amount and is prepared to have a low viscosity. At the same time, it can exhibit excellent hair styling power and re-styling power, and is excellent in water resistance.
本発明の整髪用化粧料は、所定の粘着性を有する粘着性樹脂（成分ａ）を必須成分として含有する。
本明細書においては、粘着性樹脂の粘着性を、ＪＩＳ Ｚ ０２３７に準じたボールタック試験により特定する。
ボールタック試験とは、図１に示すような測定装置を用いて測定する粘着性の試験方法である。具体的には、被測定試料（粘着性物質）を図１の測定装置の傾斜面に配置し傾斜面の頂部から１０ｃｍの部分までを非粘着性のシートで被覆して助走路とし、所定の材質及び大きさのボールを傾斜面の頂部から転がしたとき、粘着面上のいずれかの位置において停止したボールのうち、最大の大きさのボールのナンバーで粘着性を特定する。 The hairdressing cosmetic composition of the present invention contains an adhesive resin (component a) having a predetermined adhesiveness as an essential component.
In the present specification, the tackiness of the tacky resin is specified by a ball tack test in accordance with JIS Z 0237.
The ball tack test is an adhesive test method for measuring using a measuring apparatus as shown in FIG. Specifically, the sample to be measured (adhesive substance) is placed on the inclined surface of the measuring apparatus in FIG. 1 and the top portion of the inclined surface is covered with a non-adhesive sheet to form a runway. When a ball of material and size is rolled from the top of the inclined surface, the adhesiveness is specified by the number of the largest ball among the balls stopped at any position on the adhesive surface.
本明細書においては、粘着性樹脂の粘着性を、ＪＩＳ Ｚ ０２３７に準じたボールタック試験により特定する。
ボールタック試験とは、図１に示すような測定装置を用いて測定する粘着性の試験方法である。具体的には、被測定試料（粘着性物質）を図１の測定装置の傾斜面に配置し傾斜面の頂部から１０ｃｍの部分までを非粘着性のシートで被覆して助走路とし、所定の材質及び大きさのボールを傾斜面の頂部から転がしたとき、粘着面上のいずれかの位置において停止したボールのうち、最大の大きさのボールのナンバーで粘着性を特定する。 The hairdressing cosmetic composition of the present invention contains an adhesive resin (component a) having a predetermined adhesiveness as an essential component.
In the present specification, the tackiness of the tacky resin is specified by a ball tack test in accordance with JIS Z 0237.
The ball tack test is an adhesive test method for measuring using a measuring apparatus as shown in FIG. Specifically, the sample to be measured (adhesive substance) is placed on the inclined surface of the measuring apparatus in FIG. 1 and the top portion of the inclined surface is covered with a non-adhesive sheet to form a runway. When a ball of material and size is rolled from the top of the inclined surface, the adhesiveness is specified by the number of the largest ball among the balls stopped at any position on the adhesive surface.
本発明で用いられる粘着性樹脂は、特に、樹脂実分５０質量％の組成物を準備し、当該組成物で図１の傾斜面に厚さ０．１ｍｍの被膜を作成し、２５℃、湿度５０％で１日乾燥させたものを試料面としてボールタック試験を実施した。測定条件としては、図１に示した測定装置における傾斜面の傾斜角を３０度とし、２５℃、湿度５０％において測定し、ボールナンバーが１～３０、より好ましくは３～２５である粘着性を有するものを、本発明における粘着性樹脂とした。
For the adhesive resin used in the present invention, in particular, a composition having a resin real fraction of 50% by mass is prepared, and a coating film having a thickness of 0.1 mm is formed on the inclined surface of FIG. A ball tack test was performed using a sample surface dried at 50% for 1 day. The measurement conditions are as follows: the inclination angle of the inclined surface in the measurement apparatus shown in FIG. 1 is 30 degrees, the measurement is performed at 25 ° C. and 50% humidity, and the ball number is 1 to 30, more preferably 3 to 25 The adhesive resin in the present invention was used.
本発明において使用される粘着性樹脂の具体例としては、アクリル系樹脂としては、例えば、アクロナールＹＪ２７２０Ｄ、アクロナールＶ２１５ａｐ、アクロナールＮ２８５、アクロナールＶ２１０、アクロナールＶ２１２（以上、ＢＡＳＦ社製）、ＮＣＯＲ３８―０８８Ａ、Ｄｕｒｏ－Ｔａｋ８７－２００Ａ、Ｄｕｒｏ－Ｔａｋ３８７－２０５４／８７－２０５４（以上、Ｎａｔｉｏｎａｌ Ｓｔａｒｃｈ＆Ｃｈｅｍｉｃａｌ社製）、ＭＧ－０５６０、ＭＧ－０５８０（以上、Ｄｏｗ Ｃｏｒｎｉｎｇ社製）、アクリル酸アルキルエステルであるダイトゾール５０００ＡＤ（大東化成工業社製）、メタクリル酸アルキルエステル／アクリル酸アルキルエステルコポリマーに属するヨドゾールＡＨ９５５、ＰＲＩＭＡＬ ＰＳ８３－Ｄ（Ｒｏｈｍ＆ＨＡＡＳ社製）等を挙げることができる。
Specific examples of the adhesive resin used in the present invention include acrylic resins such as Acronal YJ2720D, Acronal V215ap, Acronal N285, Acronal V210, Acronal V212 (above, manufactured by BASF), NCOR38-088A, Duro -Tak87-200A, Duro-Tak387-2054 / 87-2054 (manufactured by National Starch & Chemical Co.), MG-0560, MG-0580 (manufactured by Dow Corning), Daitosol 5000AD (Daito Kasei), an alkyl acrylate ester Manufactured by Kogyo Co., Ltd.), Yodosol AH955 belonging to methacrylic acid alkyl ester / acrylic acid alkyl ester copolymer, PRIMAL PS83-D ( ohm & HAAS Co., Ltd.), and the like can be mentioned.
また、本発明で使用される粘着性樹脂として、下記のモノマーＡ及び／又はモノマーＢ及びモノマーＣ及びモノマーＤを重合させて得られる粘着性セット樹脂を選択してもよい。
モノマーＡ：下記式：
（式中、Ｒ１はＨ又はＣＨ３であり、ｎは０～３０の整数であって（ＣＨ２）ｎは分岐鎖を含み、Ｒ２はＨ、ＯＨ、ＯＣＨ３、ＯＣＨ２ＣＨ３又はフェニルである）で表されるモノマーの少なくとも１種。
Further, as the adhesive resin used in the present invention, an adhesive set resin obtained by polymerizing the following monomer A and / or monomer B, monomer C and monomer D may be selected.
Monomer A: the following formula:
(Wherein, R1 is H or CH 3, n is an integer of 0 ~ 30 (CH 2) n comprises a branched chain, R2 is H, OH, with OCH 3, OCH 2 CH 3 or phenyl At least one monomer represented by
モノマーＡ：下記式：
Monomer A: the following formula:
モノマーＢ：下記式：
（式中、Ｒ３はＨ又はＣＨ３であり、Ｒ４及びＲ５は同一でも異なっていてもよく、Ｈ又は（ＣＨ２）ｌＲ’であって、ｌは１～３の整数であり、Ｒ’はＨ、ＯＨ又は-ＮＲ”Ｒ’”であって、Ｒ”及びＲ’”は同一でも異なっていてもよく、Ｈ又はＣ１～Ｃ３のアルキル基である）で表されるモノマーの少なくとも１種。
Monomer B: the following formula:
(Wherein, R3 is H or CH 3, R4 and R5 may be the same or different, H, or (CH 2) l R 'a, l is an integer of 1 ~ 3, R' Is H, OH or —NR ″ R ′ ″, and R ″ and R ′ ″ may be the same or different and are H or a C1-C3 alkyl group). .
モノマーＣ：下記式：
（式中、Ｒ６はＨ又はＣＨ３であり、ｐは１～１００の整数であり、ｍは０～３０の整数であり、Ｒ７はＨ、ＯＨ、ＯＣＨ３、ＯＣＨ２ＣＨ３、又はフェニルであり、Ｘはオキシエチレン基（ＥＯ）、オキシプロピレン基（ＰＯ）、オキシブチレン基（ＢＯ）、又はグリセリルである）で表されるモノマーの少なくとも１種。
Monomer C: the following formula:
(Wherein, R6 is H or CH 3, p is an integer of 1 ~ 100, m is an integer of 0 ~ 30, R7 is H, OH, OCH 3, OCH 2 CH 3, or phenyl And X is at least one monomer represented by an oxyethylene group (EO), an oxypropylene group (PO), an oxybutylene group (BO), or glyceryl).
モノマーＤ：下記式：
（式中、Ｒ８はＨ又はＣＨ３であり、ｑは１～１００の整数であり、Ｙはオキシエチレン基（ＥＯ）、オキシプロピレン基（ＰＯ）、オキシブチレン基（ＢＯ）、炭素数５以上の直鎖または分岐のオキシアルキレン基、又はグリセリルである（但し、Ｙが炭素数５以上のオキシアルキレン基であるときは、ｑは１である）で表されるモノマーの少なくとも１種。
Monomer D: the following formula:
(Wherein R8 is H or CH 3 , q is an integer of 1 to 100, Y is an oxyethylene group (EO), an oxypropylene group (PO), an oxybutylene group (BO), 5 or more carbon atoms) A linear or branched oxyalkylene group or glyceryl (provided that when Y is an oxyalkylene group having 5 or more carbon atoms, q is 1).
本発明で使用される粘着性セット樹脂としては、下記式（Ｉ）で表される構造を有するものが特に好ましい。
上記式（Ｉ）において、Ｒ１～Ｒ９、ｎ、ｍ、ｐ、ｑは、上記式Ａ～Ｄと同じ意味である。なお、本明細書における用語は通常の意味で使用され、例えば、オキシエチレン基（ＥＯ）、オキシプロピレン基（ＰＯ）、オキシブチレン基（ＢＯ）は、各々、炭素数２、３及び４の直鎖又は分岐のオキシアルキレン基を意味する。また、上記式（Ｉ）におけるａは４０＜ａ＜４００、ｂは８０≦ｂ＜３００、ｃは３０＜ｃ＜３００、ｄは０＜ｄ＜１０の範囲の数である。
上記の条件を満たす粘着性セット樹脂（式（Ｉ）のポリマー）における各モノマーの質量％は、およそ次のようになる。７．５＜Ａ＜６２．５、２０≦Ｂ＜４５、７．５＜Ｃ＜６０、０＜Ｄ＜５。 As the adhesive set resin used in the present invention, those having a structure represented by the following formula (I) are particularly preferable.
In the above formula (I), R1 to R9, n, m, p and q have the same meanings as in the above formulas AD. Note that the terms in this specification are used in a normal sense. For example, an oxyethylene group (EO), an oxypropylene group (PO), and an oxybutylene group (BO) are each a straight chain having 2, 3, and 4 carbon atoms. It means a chain or branched oxyalkylene group. In the formula (I), a is a number in the range of 40 <a <400, b is 80 ≦ b <300, c is 30 <c <300, and d is 0 <d <10.
The mass% of each monomer in the adhesive set resin (polymer of formula (I)) that satisfies the above conditions is approximately as follows. 7.5 <A <62.5, 20 ≦ B <45, 7.5 <C <60, 0 <D <5.
上記の条件を満たす粘着性セット樹脂（式（Ｉ）のポリマー）における各モノマーの質量％は、およそ次のようになる。７．５＜Ａ＜６２．５、２０≦Ｂ＜４５、７．５＜Ｃ＜６０、０＜Ｄ＜５。 As the adhesive set resin used in the present invention, those having a structure represented by the following formula (I) are particularly preferable.
The mass% of each monomer in the adhesive set resin (polymer of formula (I)) that satisfies the above conditions is approximately as follows. 7.5 <A <62.5, 20 ≦ B <45, 7.5 <C <60, 0 <D <5.
本発明で使用される粘着性セット樹脂は、上記モノマーＡ及び／又はＢ及びＣ及びＤを適切な比率で混合し、必要に応じて適当な溶媒中において、標準的な方法を用いて重合反応させることにより調製することができる。例えば、エタノール中で、２，２’－アゾビスイソブチロニトリル等の重合開始剤を用い、約８０℃において８時間熱重合させることによって得得ることができ、得られたポリマーを適宜精製して使用することができる。
The adhesive set resin used in the present invention is prepared by mixing the above monomers A and / or B and C and D in an appropriate ratio, and performing a polymerization reaction using a standard method in an appropriate solvent as necessary. Can be prepared. For example, it can be obtained by performing thermal polymerization at about 80 ° C. for 8 hours using a polymerization initiator such as 2,2′-azobisisobutyronitrile in ethanol, and the obtained polymer is appropriately purified. Can be used.
シリコーン系の粘着性樹脂としては、付加反応型シリコーンであるＳＤ４５８４、ＳＤ４５６０、ＳＤ４５７０、ＳＤ４５８０、ＳＤ４５８５、ＳＤ４５８７Ｌ（以上、東レダウシリコーン社製）、ＴＳＲ１５１２、ＴＳＲ１５１６（以上、ＭＯＭＥＮＴＩＶＥ社製）等を挙げることができる。
Examples of silicone-based adhesive resins include addition-reactive silicones SD4584, SD4560, SD4570, SD4580, SD4585, SD4587L (above, Toray Dow Silicone), TSR1512, TSR1516 (above, MOMENTIVE) Can do.
本発明においては、前記の粘着性の条件を満たす樹脂であれば、上記に列挙した具体例に限られるものではなく、それらの１種又は２種以上を混合して使用することができる。
In the present invention, the resin is not limited to the specific examples enumerated above as long as it satisfies the above-mentioned adhesive condition, and one or more of them can be used in combination.
本発明の化粧料における粘着性樹脂の配合量は、０．１～１０質量％、より好ましくは ０．５～７．５質量％である。０．１質量％未満では所望の効果が得られず、１０質量％を越えるとべたつきを生じる。
The blending amount of the adhesive resin in the cosmetic of the present invention is 0.1 to 10% by mass, more preferably 0.5 to 7.5% by mass. If it is less than 0.1% by mass, the desired effect cannot be obtained, and if it exceeds 10% by mass, stickiness occurs.
本発明の整髪用化粧料は、前記粘着性樹脂に加えて毛髪セット樹脂を含有しており、毛髪セット樹脂を配合することにより耐湿性が向上する。
本発明の化粧料に配合されうる毛髪セット樹脂とは、セット剤又はセット樹脂等とも呼ばれるアニオン性、カチオン性、両性、ノニオン性の皮膜形成高分子であり、従来からヘアスタイリング剤に配合されているものでよい。具体例としては、以下のようなものを挙げることができる。 The hairdressing cosmetic composition of the present invention contains a hair setting resin in addition to the adhesive resin, and the moisture resistance is improved by blending the hair setting resin.
The hair set resin that can be blended in the cosmetics of the present invention is an anionic, cationic, amphoteric, nonionic film-forming polymer also called a set agent or a set resin, and has been conventionally blended in hair styling agents. It may be what you have. Specific examples include the following.
本発明の化粧料に配合されうる毛髪セット樹脂とは、セット剤又はセット樹脂等とも呼ばれるアニオン性、カチオン性、両性、ノニオン性の皮膜形成高分子であり、従来からヘアスタイリング剤に配合されているものでよい。具体例としては、以下のようなものを挙げることができる。 The hairdressing cosmetic composition of the present invention contains a hair setting resin in addition to the adhesive resin, and the moisture resistance is improved by blending the hair setting resin.
The hair set resin that can be blended in the cosmetics of the present invention is an anionic, cationic, amphoteric, nonionic film-forming polymer also called a set agent or a set resin, and has been conventionally blended in hair styling agents. It may be what you have. Specific examples include the following.
アクリル系及びビニル系毛髪セット樹脂：
アニオン性のものとして、アクリル酸アルキル・ジアセトンアクリルアミド共重合体（プラスサイズＬ－５３Ｐ、プラスサイズＬ－９９０９Ｂ、プラスサイズＬ－９９４８Ｂ等（いずれも互応化学工業株式会社製））、アクリル酸アルキル・オクチルアクリルアミド共重合体（Ｄｅｒｍａｃｒｙｌ ７９（日本エヌエスシー株式会社製））、ポリエチレングリコール・ポリプロピレングリコール－２５・ジメチコン・アクリレーツ共重合体（ルビフレックスＳＩＬＫ（ＢＡＳＦ社製））、アクリル酸・アクリル酸アミド・アクリル酸エチル共重合体（ウルトラホールド８、ウルトラホールドＳｔｒｏｎｇ（ＢＡＳＦ社製））、アクリル酸アルキル共重合体（アニセットＮＦ－１０００，アニセットＨＳ－３０００など（大阪有機化学工業株式会社製））等。 Acrylic and vinyl hair set resins:
As anionic ones, alkyl acrylate / diacetone acrylamide copolymers (plus size L-53P, plus size L-9909B, plus size L-9948B etc. (all manufactured by Kyoyo Chemical Co., Ltd.)), alkyl acrylate・ Octylacrylamide copolymer (Dermacryl 79 (made by NSC Japan)), polyethylene glycol ・ polypropylene glycol-25 ・ Dimethicone ・ Acrylates copolymer (Rubiflex SILK (made by BASF)), acrylic acid / acrylic acid amide・ Ethyl acrylate copolymer (Ultrahold 8, Ultrahold Strong (manufactured by BASF)), alkyl acrylate copolymer (aniset NF-1000, aniset HS-3000, etc.) Etc.)) etc.
アニオン性のものとして、アクリル酸アルキル・ジアセトンアクリルアミド共重合体（プラスサイズＬ－５３Ｐ、プラスサイズＬ－９９０９Ｂ、プラスサイズＬ－９９４８Ｂ等（いずれも互応化学工業株式会社製））、アクリル酸アルキル・オクチルアクリルアミド共重合体（Ｄｅｒｍａｃｒｙｌ ７９（日本エヌエスシー株式会社製））、ポリエチレングリコール・ポリプロピレングリコール－２５・ジメチコン・アクリレーツ共重合体（ルビフレックスＳＩＬＫ（ＢＡＳＦ社製））、アクリル酸・アクリル酸アミド・アクリル酸エチル共重合体（ウルトラホールド８、ウルトラホールドＳｔｒｏｎｇ（ＢＡＳＦ社製））、アクリル酸アルキル共重合体（アニセットＮＦ－１０００，アニセットＨＳ－３０００など（大阪有機化学工業株式会社製））等。 Acrylic and vinyl hair set resins:
As anionic ones, alkyl acrylate / diacetone acrylamide copolymers (plus size L-53P, plus size L-9909B, plus size L-9948B etc. (all manufactured by Kyoyo Chemical Co., Ltd.)), alkyl acrylate・ Octylacrylamide copolymer (Dermacryl 79 (made by NSC Japan)), polyethylene glycol ・ polypropylene glycol-25 ・ Dimethicone ・ Acrylates copolymer (Rubiflex SILK (made by BASF)), acrylic acid / acrylic acid amide・ Ethyl acrylate copolymer (Ultrahold 8, Ultrahold Strong (manufactured by BASF)), alkyl acrylate copolymer (aniset NF-1000, aniset HS-3000, etc.) Etc.)) etc.
両性のものとして、アクリル酸オクチルアミド・アクリル酸ヒドロキシプロピルプロピル・メタクリル酸ブチルアミノエチル共重合体（ＡＭＰＨＯＭＥＲ ＳＨ３０、ＡＭＰＨＯＭＥＲ ＬＶ－７１（日本エヌエスシー株式会社製））、メタクリロイルオキシエチルカルボキシベタイン・メタクリル酸アルキル共重合体（ユカフォーマーＲ２０５、ユカフォーマー３０１、ユカフォーマーＳＭ、ユカフォーマー１０４Ｄなど（三菱化学株式会社製）、ＲＡＭレジン－１０００、ＲＡＭレジン－２０００、ＲＡＭレジン－３０００、ＲＡＭレジン－４０００（大阪有機化学工業株式会社製））、塩化ジメチルジアリルアンモニウム・アクリル酸共重合体（マーコート２８０、マーコート２９５（ナルコ社製））、塩化ジメチルジアリルアンモニウム・アクリルアミド・アクリル酸共重合体（マーコートプラス３３３０、マーコートプラス３３３１（ナルコ社製））等。
As amphoteric ones, acrylic acid octylamide / hydroxypropylpropyl acrylate / butylaminoethyl methacrylate copolymer (AMPHOMER SH30, AMPHOMER LV-71 (made by NSC Japan)), methacryloyloxyethylcarboxybetaine / methacrylic acid Alkyl copolymers (Yukaformer R205, Yukaformer 301, Yukaformer SM, Yukaformer 104D, etc. (manufactured by Mitsubishi Chemical Corporation), RAM Resin-1000, RAM Resin-2000, RAM Resin-3000, RAM Resin-4000 (Osaka Organic Chemical Co., Ltd.) Company)), dimethyldiallylammonium chloride / acrylic acid copolymer (Mercoat 280, Mercoat 295 (Nalco)), dimethyldiallyl ammonium chloride Um acrylamide-acrylic acid copolymer (mer coat plus 3330, Ma coat plus 3331 (Nalco Co., Ltd.)), and the like.
カチオン性のものとして、ビニルピロリドン・メタクリル酸ジメチルアミノエチル共重合体ジエチル硫酸塩（Ｈ．Ｃ．ポリマー１Ｓ（Ｍ）、Ｈ．Ｃ．ポリマー２（大阪有機化学工業株式会社製）、ガフコート７５５Ｎ（ＩＳＰ社製））、ビニルピロリドン・ジメチルアミノプロピルメタクリルアミド・ラウリルジメチルアミノプロピルメタクリルアミド共重合体（スタイリーゼＷ－２０（ＩＳＰ社製））、ビニルピロリドン・メタクリル酸Ｎ，Ｎ－ジメチルアミノエチル・アクリル酸アルキル・ジアクリル酸トリプロピレングリコール共重合体（コスカットＧＡ４６７，コスカットＧＡ４６８（大阪有機化学工業株式会社製）、ポリ塩化ジメチルメチレンピペリジニウム（マーコート１００（ナルコ社製））、塩化ジメチルジアリルアンモニウム・アクリルアミド共重合体（マーコート５５０（ナルコ社製））、塩化トリメチルアミノプロピルアクリルアミド・ジメチルアクリルアミド共重合体等。
As a cationic substance, vinylpyrrolidone / dimethylaminoethyl methacrylate copolymer diethyl sulfate (HC Polymer 1S (M), HC Polymer 2 (manufactured by Osaka Organic Chemical Industry Co., Ltd.), Guff Coat 755N ( ISP)), vinylpyrrolidone / dimethylaminopropyl methacrylamide / lauryl dimethylaminopropyl methacrylamide copolymer (Styrise W-20 (ISP)), vinylpyrrolidone / N, N-dimethylaminoethyl methacrylate / acrylic Alkyl diacrylate / tripropylene glycol copolymer (Coscut GA467, Koscut GA468 (manufactured by Osaka Organic Chemical Industry Co., Ltd.), polydimethylmethylenepiperidinium chloride (Mercoat 100 (manufactured by Nalco)), dimethyldiallylammonium chloride Um acrylamide copolymer (manufactured by Merquat 550 (Nalco)), trimethyl amino propyl acrylamide chloride-dimethylacrylamide copolymer.
ノニオン性のものとして、ポリビニルピロリドン（ルビスコールＫ１７、ルビスコールＫ３０、ルビスコールＫ９０（ＢＡＳＦ社製）、ＰＶＰ Ｋ（ＩＳＰ社製））、ビニルピロリドン・酢酸ビニル共重合体（ＰＶＰ／ＶＡ Ｓ－６３０、ＰＶＰ／ＶＡ Ｅ－７３５、ＰＶＰ／ＶＡ Ｅ－３３５（以上ＩＳＰ社製）、ルビスコールＶＡ７３Ｗ、ルビスコール３７Ｅ（以上ＢＡＳＦ社製）、ＰＶＡ－６４５０（大阪有機化学工業株式会社製））、ビニルメチルエーテル・マレイン酸アルキル共重合体（ガントレッツＡ－４２５、ガントレッツＥＳ－２２５、ガントレッツＥＳ－３３５など（ＩＳＰ社製））、ビニルピロリドン・メタクリルアミド・ビニルイミダゾール共重合体（ルビセットクリア（ＢＡＳＦ社製））、ポリビニルカプロラクタム（ルビスコールプラス（ＢＡＳＦ社製））等。
Nonionic materials include polyvinylpyrrolidone (rubiscol K17, rubiscol K30, rubiscol K90 (manufactured by BASF), PVP K (manufactured by ISP)), vinylpyrrolidone / vinyl acetate copolymer (PVP / VA S-630). , PVP / VA E-735, PVP / VA E-335 (manufactured by ISP), Rubiscor VA73W, Rubiscol 37E (manufactured by BASF), PVA-6450 (manufactured by Osaka Organic Chemical Industry Co., Ltd.)), vinyl Methyl ether / alkyl maleate copolymer (Gantrez A-425, Gantrez ES-225, Gantrez ES-335, etc. (manufactured by ISP)), vinylpyrrolidone / methacrylamide / vinylimidazole copolymer (Rubiset Clear (BASF) Manufactured)), polyvinyl caprolak None (Luviskol Plus (BASF)), and the like.
ウレタン系毛髪セット樹脂：
ヨドゾールＰＵＤ（日本エヌエスシー株式会社製）、ルビセットＰ．Ｕ．Ｒ．（ＢＡＳＦ社製）、特開２００６－２１３７０６号公報に記載されたポリマー等、アクリル－ウレタン系として、ＤｙｎａｍＸ（日本エヌエスシー株式会社製）、特願２００６－１８３１４４号公報に記載されたポリマー等。 Urethane hair set resin:
Yodosol PUD (manufactured by NSC Japan), Ruby Set P.I. U. R. (A product of BASF), a polymer described in JP-A-2006-213706, etc., an acrylic-urethane type, Dynax (manufactured by NSC Japan), a polymer described in Japanese Patent Application No. 2006-183144, and the like.
ヨドゾールＰＵＤ（日本エヌエスシー株式会社製）、ルビセットＰ．Ｕ．Ｒ．（ＢＡＳＦ社製）、特開２００６－２１３７０６号公報に記載されたポリマー等、アクリル－ウレタン系として、ＤｙｎａｍＸ（日本エヌエスシー株式会社製）、特願２００６－１８３１４４号公報に記載されたポリマー等。 Urethane hair set resin:
Yodosol PUD (manufactured by NSC Japan), Ruby Set P.I. U. R. (A product of BASF), a polymer described in JP-A-2006-213706, etc., an acrylic-urethane type, Dynax (manufactured by NSC Japan), a polymer described in Japanese Patent Application No. 2006-183144, and the like.
多糖類系毛髪セット樹脂：
アラビアガム、グルカン、サクシノグリカン、カラギーナン、カラヤガム、トラガカントガム、グアガム、ローカストビーンガム、ガラクトマンナンガム、キサンタンガム、デンプン、キャロブガム、クインスシード（マルメロ）、カゼイン、デキストリン、ゼラチン、ペクチン酸ナトリウム、アラギン酸ナトリウム、メチルセルロース、エチルセルロース、カルボキシメチルセルロース、ヒドロキシエチルセルロース、ヒドロキシプロピルセルロース、結晶セルロース、塩化Ｏ－［２－ヒドロキシ－３－（トリメチルアンモニオ）プロピル］ヒドロキシエチルセルロース、塩化Ｏ－［２－ヒドロキシ－３－（トリメチルアンモニオ）プロピル］グアガム、塩化Ｏ－［２－ヒドロキシ－３－（トリメチルアンモニオ）プロピル］ローカストビーンガム、塩化ヒドロキシプロピルトリモニウムでんぷん等。 Polysaccharide hair set resin:
Gum arabic, glucan, succinoglycan, carrageenan, caraya gum, tragacanth gum, guar gum, locust bean gum, galactomannan gum, xanthan gum, starch, carob gum, quince seed (malmello), casein, dextrin, gelatin, sodium pectate, sodium alginate , Methylcellulose, ethylcellulose, carboxymethylcellulose, hydroxyethylcellulose, hydroxypropylcellulose, crystalline cellulose, chlorinated O- [2-hydroxy-3- (trimethylammonio) propyl] hydroxyethylcellulose, O- [2-hydroxy-3- (trimethyl) chloride Ammonio) propyl] guar gum, chloride O- [2-hydroxy-3- (trimethylammonio) propyl] locustobi Gum, chloride Hidorokishipuropirutorimoniumu starch.
アラビアガム、グルカン、サクシノグリカン、カラギーナン、カラヤガム、トラガカントガム、グアガム、ローカストビーンガム、ガラクトマンナンガム、キサンタンガム、デンプン、キャロブガム、クインスシード（マルメロ）、カゼイン、デキストリン、ゼラチン、ペクチン酸ナトリウム、アラギン酸ナトリウム、メチルセルロース、エチルセルロース、カルボキシメチルセルロース、ヒドロキシエチルセルロース、ヒドロキシプロピルセルロース、結晶セルロース、塩化Ｏ－［２－ヒドロキシ－３－（トリメチルアンモニオ）プロピル］ヒドロキシエチルセルロース、塩化Ｏ－［２－ヒドロキシ－３－（トリメチルアンモニオ）プロピル］グアガム、塩化Ｏ－［２－ヒドロキシ－３－（トリメチルアンモニオ）プロピル］ローカストビーンガム、塩化ヒドロキシプロピルトリモニウムでんぷん等。 Polysaccharide hair set resin:
Gum arabic, glucan, succinoglycan, carrageenan, caraya gum, tragacanth gum, guar gum, locust bean gum, galactomannan gum, xanthan gum, starch, carob gum, quince seed (malmello), casein, dextrin, gelatin, sodium pectate, sodium alginate , Methylcellulose, ethylcellulose, carboxymethylcellulose, hydroxyethylcellulose, hydroxypropylcellulose, crystalline cellulose, chlorinated O- [2-hydroxy-3- (trimethylammonio) propyl] hydroxyethylcellulose, O- [2-hydroxy-3- (trimethyl) chloride Ammonio) propyl] guar gum, chloride O- [2-hydroxy-3- (trimethylammonio) propyl] locustobi Gum, chloride Hidorokishipuropirutorimoniumu starch.
本発明の整髪用化粧料に配合される毛髪セット樹脂は特に限定されず、上記に列挙したような毛髪セット樹脂の１種又は２種以上を適宜選択して用いることができるが、アクリル系、ビニル系、又はウレタン系の毛髪セット樹脂が特に好ましい。
The hair set resin to be blended in the hairdressing cosmetic composition of the present invention is not particularly limited, and one or more of the hair set resins listed above can be appropriately selected and used. Vinyl-based or urethane-based hair setting resins are particularly preferable.
本発明の整髪用化粧料における毛髪セット樹脂の配合量は、一般的には０．１～１０質量％、より好ましくは０．５～７．５質量％である。０．１質量％未満であると耐湿性が十分でない場合があり、１０質量％を越えて配合すると髪がごわつく場合がある。
The blending amount of the hair setting resin in the hairdressing cosmetic composition of the present invention is generally 0.1 to 10% by mass, more preferably 0.5 to 7.5% by mass. If it is less than 0.1% by mass, moisture resistance may not be sufficient, and if it exceeds 10% by mass, hair may be stiff.
本発明の整髪用化粧料は、低粘度とすることにより、毛髪への適用時に速やかに溶媒が揮発し、粘着性が出る。具体的には、２５℃でＢ型粘度計で測定したときの粘度を１００ｍＰａ・ｓ以下とするのが好ましい。霧状に噴霧することにより本発明の効果を発揮しやすくなる。粘度が１００ｍＰａ・ｓより大きいと、霧状に噴霧するのに適さなくなる場合があり、例えば噴霧装置のノズルに詰まる等の問題を生ずる場合がある。
The hairdressing cosmetic composition of the present invention has a low viscosity, so that the solvent is quickly volatilized when applied to hair, and stickiness is obtained. Specifically, the viscosity when measured with a B-type viscometer at 25 ° C. is preferably 100 mPa · s or less. It becomes easy to exhibit the effect of the present invention by spraying in the form of a mist. If the viscosity is greater than 100 mPa · s, it may not be suitable for spraying in the form of a mist, and may cause problems such as clogging of the nozzles of the spray device.
また、本発明の整髪用化粧料は、化粧料中の溶媒が揮発した後の粘着性の範囲も重要な要素である。所定範囲の粘着性とすることにより、毛髪に適用したときのべたつきを抑制できると同時に、再整髪力を向上させることができる。
具体的には、本発明の化粧料を用いて０．１ｍｍの厚みの皮膜を形成させ、２５℃・湿度５０％にて１日乾燥した後の、前記したボールタック試験（図１に示した測定装置）における傾斜面の傾斜角を１０度とし、２５℃において測定した場合のボールナンバーが１～３０、より好ましくは３～２５である粘着性を有することが好ましい。
ボールナンバー１が停止しないほど低い粘着性では再整髪力が不足し、ボールナンバー３０より大きなボールが停止するほど大きな粘着性では毛髪にべたつきが生じてしまう場合がある。 In the hairdressing cosmetic composition of the present invention, the range of tackiness after the solvent in the cosmetic composition volatilizes is also an important factor. By setting the adhesiveness within a predetermined range, stickiness when applied to hair can be suppressed and at the same time the re-styling power can be improved.
Specifically, the above-described ball tack test (shown in FIG. 1) was performed after forming a 0.1 mm thick film using the cosmetic of the present invention and drying it at 25 ° C. and 50% humidity for 1 day. It is preferable that the inclination angle of the inclined surface in the measuring apparatus is 10 degrees and the ball number is 1 to 30, more preferably 3 to 25 when measured at 25 ° C.
If the adhesiveness is so low that the ball number 1 does not stop, the re-styling force is insufficient, and if the adhesiveness is so large that the ball larger than the ball number 30 stops, the hair may become sticky.
具体的には、本発明の化粧料を用いて０．１ｍｍの厚みの皮膜を形成させ、２５℃・湿度５０％にて１日乾燥した後の、前記したボールタック試験（図１に示した測定装置）における傾斜面の傾斜角を１０度とし、２５℃において測定した場合のボールナンバーが１～３０、より好ましくは３～２５である粘着性を有することが好ましい。
ボールナンバー１が停止しないほど低い粘着性では再整髪力が不足し、ボールナンバー３０より大きなボールが停止するほど大きな粘着性では毛髪にべたつきが生じてしまう場合がある。 In the hairdressing cosmetic composition of the present invention, the range of tackiness after the solvent in the cosmetic composition volatilizes is also an important factor. By setting the adhesiveness within a predetermined range, stickiness when applied to hair can be suppressed and at the same time the re-styling power can be improved.
Specifically, the above-described ball tack test (shown in FIG. 1) was performed after forming a 0.1 mm thick film using the cosmetic of the present invention and drying it at 25 ° C. and 50% humidity for 1 day. It is preferable that the inclination angle of the inclined surface in the measuring apparatus is 10 degrees and the ball number is 1 to 30, more preferably 3 to 25 when measured at 25 ° C.
If the adhesiveness is so low that the ball number 1 does not stop, the re-styling force is insufficient, and if the adhesiveness is so large that the ball larger than the ball number 30 stops, the hair may become sticky.
更に、本発明の整髪用化粧料は、０．０１～５質量％、より好ましくは０．１～３質量％油分を含有するのが好ましい。油分を含有することにより、毛髪に更なる滑らかさを付与することができる。
本発明で用いられる油分は、特に限られず、従来から化粧料、特に毛髪化粧料に配合されている油分から選択できる。例えば、重質イソパラフィン（＝水添ポリイソブテン）、低質イソパラフィン（例えばアイソパーＡ、同Ｃ、同Ｅ、同Ｇ、同Ｈ、同Ｋ、同Ｌ、同Ｍ（以上、いずれもエクソン社製）、シェルゾール７１（シェル社製）、ソルトロール１００、同１３０、同２２０（以上、いずれもフィリップ社製）等）、スクワラン、流動パラフィン等の炭化水素油；セチル－２－エチルヘキサノエート、２－エチルヘキシルパルミテート、２－オクチルドデシルミリステート、ネオペンチルグリコール－２－エチルヘキサノエート、イソプロピルミリステート、ミリスチルミリステート、テトラ２－エチルヘキサン酸ペンタエリスリチル等のエステル類；オリーブ油、アボカド油、ホホバ油、ヒマワリ油、サフラワー油、ツバキ油、マカデミアナッツ油、ミンク油、液状ラノリン、酢酸ラノリン、ヒマシ油等の油脂；ジメチルポリシロキサン、メチルフェニルポリシロキサン、高重合度のガム状ジメチルポリシロキサン、ポリエーテル変性シリコーン、アミノ変性シリコーン、低沸点シリコーン油、（ヘキサメチルシクロトリシロキサン、オクタメチルテトラシクロシロキサン〔例えば、「エキセコールＤ－４」（信越シリコーン社製）、「ＳＨ２４４」、「ＳＨ３４４」（いずれも東レ・ダウコーニング・シリコーン社製）等〕、デカメチルシクロペンタシロキサン〔例えば、「エキセコールＤ－５」（信越シリコーン社製）、「ＳＨ２４５」、「ＤＣ３４５」（いずれも東レ・ダウコーニング・シリコーン社製）等〕、ドデカメチルシクロヘキサシロキサン〔例えば、「ＤＣ２４６」（東レ・ダウコーニング・シリコーン社製等〕、テトラデカメチルシクロヘプタシロキサン等）などのシリコーン系油分；フッ素変性ジメチルポリシロキサン、フッ素変性メチルフェニルポリシロキサン、パーフロロポリエーテル、パーフロロカーボン等のフッ素系油分等が挙げられる。
また、一価～四価のアルコール、または一価～三価のカルボン酸のＥＯ／ＰＯ付加体を意味する整髪油分があげられる。例えば、ユニルーブ５０ ＭＢ １６８、ユニルーブＭＢ３７０、トリオールＧ－４０、サボンドールＳＧＰ－７、サボンドールＧＰ－９（以上日油株式会社）などを挙げることができる。 Further, the hairdressing cosmetic composition of the present invention preferably contains 0.01 to 5% by mass, more preferably 0.1 to 3% by mass of oil. By containing oil, further smoothness can be imparted to the hair.
The oil used in the present invention is not particularly limited, and can be selected from oils that have been conventionally blended in cosmetics, particularly hair cosmetics. For example, heavy isoparaffin (= hydrogenated polyisobutene), low-quality isoparaffin (for example, Isopar A, C, E, G, H, K, L, M (all of which are manufactured by Exxon), shell Sol 71 (manufactured by Shell), salt roll 100, 130, 220 (all of which are manufactured by Philippe), etc.), squalane, liquid oil such as liquid paraffin; cetyl-2-ethylhexanoate, 2- Esters such as ethylhexyl palmitate, 2-octyldodecyl myristate, neopentyl glycol-2-ethylhexanoate, isopropyl myristate, myristyl myristate, pentaerythrityl tetra-2-ethylhexanoate; olive oil, avocado oil, jojoba Oil, sunflower oil, safflower oil, camellia oil, macadamia nut oil, mi Oils such as cucumber oil, liquid lanolin, lanolin acetate, castor oil; dimethylpolysiloxane, methylphenylpolysiloxane, highly polymerized gum dimethylpolysiloxane, polyether-modified silicone, amino-modified silicone, low-boiling silicone oil, (hexa Methylcyclotrisiloxane, octamethyltetracyclosiloxane [for example, “Execol D-4” (manufactured by Shin-Etsu Silicone), “SH244”, “SH344” (both manufactured by Toray Dow Corning Silicone), etc.], decamethyl Cyclopentasiloxane (for example, “Execol D-5” (manufactured by Shin-Etsu Silicone), “SH245”, “DC345” (all manufactured by Toray Dow Corning Silicone), etc.), dodecamethylcyclohexasiloxane [for example, “ DC246 "(Toray Silicone oils such as tetradecamethylcycloheptasiloxane etc.); fluorine oils such as fluorine-modified dimethylpolysiloxane, fluorine-modified methylphenylpolysiloxane, perfluoropolyether, perfluorocarbon, etc. Can be mentioned.
Further, there are hair styling oil components that mean monovalent to tetravalent alcohols or EO / PO adducts of monovalent to trivalent carboxylic acids. For example, Unilube 50 MB 168, Unilube MB370, Triol G-40, Sabondol SGP-7, Sabondol GP-9 (above NOF Corporation) and the like can be mentioned.
本発明で用いられる油分は、特に限られず、従来から化粧料、特に毛髪化粧料に配合されている油分から選択できる。例えば、重質イソパラフィン（＝水添ポリイソブテン）、低質イソパラフィン（例えばアイソパーＡ、同Ｃ、同Ｅ、同Ｇ、同Ｈ、同Ｋ、同Ｌ、同Ｍ（以上、いずれもエクソン社製）、シェルゾール７１（シェル社製）、ソルトロール１００、同１３０、同２２０（以上、いずれもフィリップ社製）等）、スクワラン、流動パラフィン等の炭化水素油；セチル－２－エチルヘキサノエート、２－エチルヘキシルパルミテート、２－オクチルドデシルミリステート、ネオペンチルグリコール－２－エチルヘキサノエート、イソプロピルミリステート、ミリスチルミリステート、テトラ２－エチルヘキサン酸ペンタエリスリチル等のエステル類；オリーブ油、アボカド油、ホホバ油、ヒマワリ油、サフラワー油、ツバキ油、マカデミアナッツ油、ミンク油、液状ラノリン、酢酸ラノリン、ヒマシ油等の油脂；ジメチルポリシロキサン、メチルフェニルポリシロキサン、高重合度のガム状ジメチルポリシロキサン、ポリエーテル変性シリコーン、アミノ変性シリコーン、低沸点シリコーン油、（ヘキサメチルシクロトリシロキサン、オクタメチルテトラシクロシロキサン〔例えば、「エキセコールＤ－４」（信越シリコーン社製）、「ＳＨ２４４」、「ＳＨ３４４」（いずれも東レ・ダウコーニング・シリコーン社製）等〕、デカメチルシクロペンタシロキサン〔例えば、「エキセコールＤ－５」（信越シリコーン社製）、「ＳＨ２４５」、「ＤＣ３４５」（いずれも東レ・ダウコーニング・シリコーン社製）等〕、ドデカメチルシクロヘキサシロキサン〔例えば、「ＤＣ２４６」（東レ・ダウコーニング・シリコーン社製等〕、テトラデカメチルシクロヘプタシロキサン等）などのシリコーン系油分；フッ素変性ジメチルポリシロキサン、フッ素変性メチルフェニルポリシロキサン、パーフロロポリエーテル、パーフロロカーボン等のフッ素系油分等が挙げられる。
また、一価～四価のアルコール、または一価～三価のカルボン酸のＥＯ／ＰＯ付加体を意味する整髪油分があげられる。例えば、ユニルーブ５０ ＭＢ １６８、ユニルーブＭＢ３７０、トリオールＧ－４０、サボンドールＳＧＰ－７、サボンドールＧＰ－９（以上日油株式会社）などを挙げることができる。 Further, the hairdressing cosmetic composition of the present invention preferably contains 0.01 to 5% by mass, more preferably 0.1 to 3% by mass of oil. By containing oil, further smoothness can be imparted to the hair.
The oil used in the present invention is not particularly limited, and can be selected from oils that have been conventionally blended in cosmetics, particularly hair cosmetics. For example, heavy isoparaffin (= hydrogenated polyisobutene), low-quality isoparaffin (for example, Isopar A, C, E, G, H, K, L, M (all of which are manufactured by Exxon), shell Sol 71 (manufactured by Shell), salt roll 100, 130, 220 (all of which are manufactured by Philippe), etc.), squalane, liquid oil such as liquid paraffin; cetyl-2-ethylhexanoate, 2- Esters such as ethylhexyl palmitate, 2-octyldodecyl myristate, neopentyl glycol-2-ethylhexanoate, isopropyl myristate, myristyl myristate, pentaerythrityl tetra-2-ethylhexanoate; olive oil, avocado oil, jojoba Oil, sunflower oil, safflower oil, camellia oil, macadamia nut oil, mi Oils such as cucumber oil, liquid lanolin, lanolin acetate, castor oil; dimethylpolysiloxane, methylphenylpolysiloxane, highly polymerized gum dimethylpolysiloxane, polyether-modified silicone, amino-modified silicone, low-boiling silicone oil, (hexa Methylcyclotrisiloxane, octamethyltetracyclosiloxane [for example, “Execol D-4” (manufactured by Shin-Etsu Silicone), “SH244”, “SH344” (both manufactured by Toray Dow Corning Silicone), etc.], decamethyl Cyclopentasiloxane (for example, “Execol D-5” (manufactured by Shin-Etsu Silicone), “SH245”, “DC345” (all manufactured by Toray Dow Corning Silicone), etc.), dodecamethylcyclohexasiloxane [for example, “ DC246 "(Toray Silicone oils such as tetradecamethylcycloheptasiloxane etc.); fluorine oils such as fluorine-modified dimethylpolysiloxane, fluorine-modified methylphenylpolysiloxane, perfluoropolyether, perfluorocarbon, etc. Can be mentioned.
Further, there are hair styling oil components that mean monovalent to tetravalent alcohols or EO / PO adducts of monovalent to trivalent carboxylic acids. For example, Unilube 50 MB 168, Unilube MB370, Triol G-40, Sabondol SGP-7, Sabondol GP-9 (above NOF Corporation) and the like can be mentioned.
本発明の整髪用化粧料は、上記した粘着性樹脂及び毛髪セット樹脂に加えて、水及びアルコールを含有しているのが好ましい。
本発明の整髪用化粧料におけるアルコールとしては、エタノール等の化粧品で一般に使用されているアルコール類から選択される１種又は２種以上を適宜選択して用いることができる。水及びアルコールの配合量は、特に限定されるものではなく、上記所定の粘着性及び粘度となる範囲内で適宜調節される。 The hairdressing cosmetic composition of the present invention preferably contains water and alcohol in addition to the above-described adhesive resin and hair setting resin.
As the alcohol in the hairdressing cosmetic composition of the present invention, one or more selected from alcohols generally used in cosmetics such as ethanol can be appropriately selected and used. The blending amounts of water and alcohol are not particularly limited, and are appropriately adjusted within a range where the above-mentioned predetermined tackiness and viscosity are obtained.
本発明の整髪用化粧料におけるアルコールとしては、エタノール等の化粧品で一般に使用されているアルコール類から選択される１種又は２種以上を適宜選択して用いることができる。水及びアルコールの配合量は、特に限定されるものではなく、上記所定の粘着性及び粘度となる範囲内で適宜調節される。 The hairdressing cosmetic composition of the present invention preferably contains water and alcohol in addition to the above-described adhesive resin and hair setting resin.
As the alcohol in the hairdressing cosmetic composition of the present invention, one or more selected from alcohols generally used in cosmetics such as ethanol can be appropriately selected and used. The blending amounts of water and alcohol are not particularly limited, and are appropriately adjusted within a range where the above-mentioned predetermined tackiness and viscosity are obtained.
本発明の整髪用化粧料は、ヘアリキッド、ヘアフォーム、ヘアムース、ヘアスプレー、ヘアミスト、ヘアジェル、ヘアワックス等の様々な態様で提供することができるが、粘着性樹脂及び毛髪セット樹脂を所定量含有し、限定された粘着性及び粘度を有し得る化粧料であるため、特に、使用時に霧状に噴霧して用いる形態に適している。霧状にして用いることで、溶媒の揮発が速く、速やかに粘着性・整髪力を発揮することができる。
The hairdressing cosmetic composition of the present invention can be provided in various forms such as a hair liquid, a hair foam, a hair mousse, a hair spray, a hair mist, a hair gel, a hair wax, etc., but contains a predetermined amount of an adhesive resin and a hair set resin. However, since it is a cosmetic that can have limited adhesiveness and viscosity, it is particularly suitable for a form that is sprayed in the form of a mist during use. By using it in the form of a mist, the volatilization of the solvent is fast, and the tackiness and hair styling power can be exhibited quickly.
本発明の整髪用化粧料は、例えば、その形態に応じて、従来から整髪用化粧料に使用されている他の成分を、本発明の効果を損なわない範囲で配合してもよい。
The hairdressing cosmetic composition of the present invention may be blended, for example, with other components conventionally used in hairdressing cosmetic compositions in a range that does not impair the effects of the present invention, depending on its form.
以下に具体例を挙げて本発明を更に詳細に説明するが、本発明は以下の実施例に限定されるものではない。また、以下の実施例等における配合量は特に断らない限り質量％を示す。
Hereinafter, the present invention will be described in more detail with specific examples, but the present invention is not limited to the following examples. Moreover, the compounding quantity in a following example etc. shows the mass% unless there is particular notice.
（製造例及び比較製造例）
下記表１に示したモノマー組成で重合を行い、本発明で使用しうる粘着性セット樹脂（製造例１～６）及びモノマーＣを含まない比較製造例１及びモノマーＤを含まない比較製造例２を調製した。
具体的には、モノマー類１００部を混合した混合物をあらかじめ用意し、この混合物の入った滴下漏斗、還流冷却気、温度計、窒素置換用管および、撹拌機が取り付けられた容量１Ｌの五つ口フラスコに、エタノール１００部を仕込み、窒素気流下、昇温し、還流状態（約８０℃）になったところで、このエタノール中に重合開始剤（２，２’－アゾビスイソブチロニトリル）１部を添加し、上記混合物を２時間連続して滴下する。その後、還流状態にて、８時間放置し重合反応を進行させた。次に五つ口フラスコ中の溶液から溶媒を留去および、エタノールを加えることでこの溶液の溶媒含有量を調整し、固形分濃度５０％の化粧料基剤の溶液を得た。 (Production example and comparative production example)
Polymerization is carried out with the monomer composition shown in Table 1 below, and the adhesive set resin (Production Examples 1 to 6) that can be used in the present invention and Comparative Production Example 1 containing no monomer C and Comparative Production Example 2 containing no monomer D Was prepared.
Specifically, a mixture in which 100 parts of monomers are mixed is prepared in advance, and a dropping funnel containing this mixture, reflux cooling air, thermometer, nitrogen replacement tube, and a 1 L capacity 5 unit equipped with a stirrer are installed. In a neck flask, 100 parts of ethanol was charged, heated in a nitrogen stream, and when refluxed (about 80 ° C.), the polymerization initiator (2,2′-azobisisobutyronitrile) was added to the ethanol. 1 part is added and the mixture is added dropwise continuously for 2 hours. Thereafter, the polymerization reaction was allowed to proceed in a reflux state for 8 hours. Next, the solvent content of this solution was adjusted by distilling off the solvent from the solution in the five-necked flask and adding ethanol to obtain a cosmetic base solution having a solid concentration of 50%.
下記表１に示したモノマー組成で重合を行い、本発明で使用しうる粘着性セット樹脂（製造例１～６）及びモノマーＣを含まない比較製造例１及びモノマーＤを含まない比較製造例２を調製した。
具体的には、モノマー類１００部を混合した混合物をあらかじめ用意し、この混合物の入った滴下漏斗、還流冷却気、温度計、窒素置換用管および、撹拌機が取り付けられた容量１Ｌの五つ口フラスコに、エタノール１００部を仕込み、窒素気流下、昇温し、還流状態（約８０℃）になったところで、このエタノール中に重合開始剤（２，２’－アゾビスイソブチロニトリル）１部を添加し、上記混合物を２時間連続して滴下する。その後、還流状態にて、８時間放置し重合反応を進行させた。次に五つ口フラスコ中の溶液から溶媒を留去および、エタノールを加えることでこの溶液の溶媒含有量を調整し、固形分濃度５０％の化粧料基剤の溶液を得た。 (Production example and comparative production example)
Polymerization is carried out with the monomer composition shown in Table 1 below, and the adhesive set resin (Production Examples 1 to 6) that can be used in the present invention and Comparative Production Example 1 containing no monomer C and Comparative Production Example 2 containing no monomer D Was prepared.
Specifically, a mixture in which 100 parts of monomers are mixed is prepared in advance, and a dropping funnel containing this mixture, reflux cooling air, thermometer, nitrogen replacement tube, and a 1 L capacity 5 unit equipped with a stirrer are installed. In a neck flask, 100 parts of ethanol was charged, heated in a nitrogen stream, and when refluxed (about 80 ° C.), the polymerization initiator (2,2′-azobisisobutyronitrile) was added to the ethanol. 1 part is added and the mixture is added dropwise continuously for 2 hours. Thereafter, the polymerization reaction was allowed to proceed in a reflux state for 8 hours. Next, the solvent content of this solution was adjusted by distilling off the solvent from the solution in the five-necked flask and adding ethanol to obtain a cosmetic base solution having a solid concentration of 50%.
（実施例及び比較例）
下記表２の粘着性樹脂について、それらの粘着性をボールタック試験により測定した。なお、表中、ボールタック試験の結果が「－」とされているものは、粘着性が低くナンバー１のボールも停止しなかったことを示す。 (Examples and Comparative Examples)
About the adhesive resin of following Table 2, those adhesiveness was measured by the ball tack test. In the table, when the result of the ball tack test is “−”, it indicates that the ball having the low tack and the number 1 ball did not stop.
下記表２の粘着性樹脂について、それらの粘着性をボールタック試験により測定した。なお、表中、ボールタック試験の結果が「－」とされているものは、粘着性が低くナンバー１のボールも停止しなかったことを示す。 (Examples and Comparative Examples)
About the adhesive resin of following Table 2, those adhesiveness was measured by the ball tack test. In the table, when the result of the ball tack test is “−”, it indicates that the ball having the low tack and the number 1 ball did not stop.
次に、下記表３及び表４に掲げた組成の試料を調製し、当該試料を使用したときのアレンジ力、粘着力、固定力、再整髪力、ぱさつきのなさについて評価した。それらの結果も表３及び４に併せて示す。なお、各特性の評価方法及び評価基準は以下の通りである。
Next, samples having the compositions listed in Tables 3 and 4 below were prepared, and the arrangement power, adhesive power, fixing power, re-hair styling power, and lack of roughness were evaluated when the samples were used. The results are also shown in Tables 3 and 4. In addition, the evaluation method and evaluation criteria of each characteristic are as follows.
１．アレンジ力
１束の黒色バージンヘア（長さ２０ｃｍ，質量２ｇ）に試料を０．５ｇ塗布し、常温にて乾燥させた後の毛束について、アレンジのしやすさを専門パネラーによる官能試験にて評価した。
＜評価点基準＞
５点：かなりアレンジしやすい
４点：ややアレンジしやすい
３点：普通
２点：ややアレンジしにくい
１点：アレンジしにくい
＜評価基準＞
◎：合計点が４０点以上
○：合計点が３０点以上４０点未満
△：合計点が２０点以上３０点未満
×：合計点が２０点未満 1. Arranging force 0.5g of sample is applied to one bundle of black virgin hair (length 20cm, mass 2g), and the hair bundle after drying at room temperature is determined by a sensory test using a specialized paneler. evaluated.
<Evaluation criteria>
5 points: Easy to arrange 4 points: Slightly easy to arrange 3 points: Normal 2 points: Slightly difficult to arrange 1 point: Difficult to arrange <Evaluation criteria>
◎: Total score is 40 or more ○: Total score is 30 or more and less than 40 △: Total score is 20 or more and less than 30 ×: Total score is less than 20
１束の黒色バージンヘア（長さ２０ｃｍ，質量２ｇ）に試料を０．５ｇ塗布し、常温にて乾燥させた後の毛束について、アレンジのしやすさを専門パネラーによる官能試験にて評価した。
＜評価点基準＞
５点：かなりアレンジしやすい
４点：ややアレンジしやすい
３点：普通
２点：ややアレンジしにくい
１点：アレンジしにくい
＜評価基準＞
◎：合計点が４０点以上
○：合計点が３０点以上４０点未満
△：合計点が２０点以上３０点未満
×：合計点が２０点未満 1. Arranging force 0.5g of sample is applied to one bundle of black virgin hair (length 20cm, mass 2g), and the hair bundle after drying at room temperature is determined by a sensory test using a specialized paneler. evaluated.
<Evaluation criteria>
5 points: Easy to arrange 4 points: Slightly easy to arrange 3 points: Normal 2 points: Slightly difficult to arrange 1 point: Difficult to arrange <Evaluation criteria>
◎: Total score is 40 or more ○: Total score is 30 or more and less than 40 △: Total score is 20 or more and less than 30 ×: Total score is less than 20
２．固定力
黒色バージンヘア（長さ１５ｃｍ，重さ１ｇ）に、試料を０．４ｇ塗布し、くしを使いなじませ、まっすぐになるよう形を整え、１試料あたり５本のストランドを作製した。これを５０℃で１時間乾燥させた後目盛りの付いたボードに吊り下げ、温度３０℃，湿度９０％ＲＨの恒温恒湿器にてストランドの撓んだ長さを（ｂ）を測定した。試料未塗布時にあらかじめ測定しておいた、撓んだストランドの長さ（ａ）を用い、次式に従い固定力（キープ力）を求めた。数値が１００％に近いほど固定力が高く、耐湿性に優れることを示している。
ヘアスタイルキープ力（％）＝｛（ａ－ｂ）／ａ｝×１００
＜評価基準＞
◎：値が９０％以上
○：値が７０～９０％未満
△：値が５０～７０％未満
×：値が５０％未満 2. Fixing force 0.4 g of the sample was applied to black virgin hair (length: 15 cm, weight: 1 g), and the shape was adjusted so as to be straightened by using a comb. Five strands were prepared per sample. After drying this at 50 ° C. for 1 hour, it was suspended on a board with a scale, and the length of bending of the strand (b) was measured with a constant temperature and humidity chamber at a temperature of 30 ° C. and a humidity of 90% RH. Using the length (a) of the bent strand that was measured in advance when the sample was not applied, the fixing force (keep force) was determined according to the following equation. The closer the value is to 100%, the higher the fixing force and the better the moisture resistance.
Hair style keeping power (%) = {(ab) / a} × 100
<Evaluation criteria>
◎: Value is 90% or more ○: Value is 70 to less than 90% △: Value is 50 to less than 70% ×: Value is less than 50%
黒色バージンヘア（長さ１５ｃｍ，重さ１ｇ）に、試料を０．４ｇ塗布し、くしを使いなじませ、まっすぐになるよう形を整え、１試料あたり５本のストランドを作製した。これを５０℃で１時間乾燥させた後目盛りの付いたボードに吊り下げ、温度３０℃，湿度９０％ＲＨの恒温恒湿器にてストランドの撓んだ長さを（ｂ）を測定した。試料未塗布時にあらかじめ測定しておいた、撓んだストランドの長さ（ａ）を用い、次式に従い固定力（キープ力）を求めた。数値が１００％に近いほど固定力が高く、耐湿性に優れることを示している。
ヘアスタイルキープ力（％）＝｛（ａ－ｂ）／ａ｝×１００
＜評価基準＞
◎：値が９０％以上
○：値が７０～９０％未満
△：値が５０～７０％未満
×：値が５０％未満 2. Fixing force 0.4 g of the sample was applied to black virgin hair (length: 15 cm, weight: 1 g), and the shape was adjusted so as to be straightened by using a comb. Five strands were prepared per sample. After drying this at 50 ° C. for 1 hour, it was suspended on a board with a scale, and the length of bending of the strand (b) was measured with a constant temperature and humidity chamber at a temperature of 30 ° C. and a humidity of 90% RH. Using the length (a) of the bent strand that was measured in advance when the sample was not applied, the fixing force (keep force) was determined according to the following equation. The closer the value is to 100%, the higher the fixing force and the better the moisture resistance.
Hair style keeping power (%) = {(ab) / a} × 100
<Evaluation criteria>
◎: Value is 90% or more ○: Value is 70 to less than 90% △: Value is 50 to less than 70% ×: Value is less than 50%
３．再整髪力
１束の黒色バージンヘア（長さ２０ｃｍ，質量２ｇ）に試料を０．５ｇ塗布し、常温にて乾燥させた後の毛束について、塗布直後に整髪を行い、その後１時間後に再度整髪した際のしやすさ（再整髪力）を専門パネラーによる官能試験にて評価した。
＜評価点基準＞
５点：かなり再整髪力がある
４点：やや再整髪力がある
３点：普通
２点：やや再整髪力がない
１点：再整髪力がない
＜評価基準＞
◎：合計点が４０点以上
○：合計点が３０点以上４０点未満
△：合計点が２０点以上３０点未満
×：合計点が２０点未満 3. Re-styling power A 0.5g sample is applied to a bundle of black virgin hair (length: 20cm, mass: 2g), and the hair bundle is dried at room temperature. The ease of hair styling (re-hair styling power) was evaluated by a sensory test by a specialized panelist.
<Evaluation criteria>
5 points: Re-styling ability 4 points: Slight re-styling ability 3 points: Normal 2 points: Slight re-styling ability 1 point: No re-styling ability <Evaluation criteria>
◎: Total score is 40 or more ○: Total score is 30 or more and less than 40 △: Total score is 20 or more and less than 30 ×: Total score is less than 20
１束の黒色バージンヘア（長さ２０ｃｍ，質量２ｇ）に試料を０．５ｇ塗布し、常温にて乾燥させた後の毛束について、塗布直後に整髪を行い、その後１時間後に再度整髪した際のしやすさ（再整髪力）を専門パネラーによる官能試験にて評価した。
＜評価点基準＞
５点：かなり再整髪力がある
４点：やや再整髪力がある
３点：普通
２点：やや再整髪力がない
１点：再整髪力がない
＜評価基準＞
◎：合計点が４０点以上
○：合計点が３０点以上４０点未満
△：合計点が２０点以上３０点未満
×：合計点が２０点未満 3. Re-styling power A 0.5g sample is applied to a bundle of black virgin hair (length: 20cm, mass: 2g), and the hair bundle is dried at room temperature. The ease of hair styling (re-hair styling power) was evaluated by a sensory test by a specialized panelist.
<Evaluation criteria>
5 points: Re-styling ability 4 points: Slight re-styling ability 3 points: Normal 2 points: Slight re-styling ability 1 point: No re-styling ability <Evaluation criteria>
◎: Total score is 40 or more ○: Total score is 30 or more and less than 40 △: Total score is 20 or more and less than 30 ×: Total score is less than 20
４．耐湿性
黒色バージンヘア（長さ：２０ｃｍ、重さ：２ｇ）に、試料（実施例または比較例で得られた毛髪化粧料）を０．５ｇ塗布し、直ちに、カール径が２ｃｍのカーラーを用いてカールを作製し、これを５０℃で１時間乾燥させた。このカールした毛髪ストランドの長さを測定して、該長さを初期値（Ｌ０）とする。
次に、乾燥させた毛髪束を目盛りの付いたボードに吊り下げ、温度３０℃、湿度９０％ＲＨの恒温恒湿器に３時間入れた後、毛髪ストランドの長さを測定し、該長さを、加湿後の長さ（Ｌ２）とする。
なお、毛髪ストランドの長さとしては、カールされた状態であれば、カールの最大径になり、一方、カールが部分的に又は全体的にほどけていれば、根元側の端部からの最大の長さ（例えば、根元側の端部から毛先側の端部までの長さ）になる。 4). Moisture resistance Black virgin hair (length: 20 cm, weight: 2 g) is coated with 0.5 g of the sample (hair cosmetic obtained in the examples or comparative examples) and immediately using a curler with a curl diameter of 2 cm. A curl was prepared and dried at 50 ° C. for 1 hour. The length of the curled hair strand is measured, and the length is set as an initial value (L0).
Next, the dried hair bundle is suspended on a graduated board and placed in a thermo-hygrostat with a temperature of 30 ° C. and a humidity of 90% RH for 3 hours, and then the length of the hair strand is measured. Is the length after humidification (L2).
The length of the hair strand is the maximum curl diameter in the curled state, while the maximum length from the end on the root side if the curl is partially or totally unrolled. It becomes the length (for example, the length from the end on the root side to the end on the hair end side).
黒色バージンヘア（長さ：２０ｃｍ、重さ：２ｇ）に、試料（実施例または比較例で得られた毛髪化粧料）を０．５ｇ塗布し、直ちに、カール径が２ｃｍのカーラーを用いてカールを作製し、これを５０℃で１時間乾燥させた。このカールした毛髪ストランドの長さを測定して、該長さを初期値（Ｌ０）とする。
次に、乾燥させた毛髪束を目盛りの付いたボードに吊り下げ、温度３０℃、湿度９０％ＲＨの恒温恒湿器に３時間入れた後、毛髪ストランドの長さを測定し、該長さを、加湿後の長さ（Ｌ２）とする。
なお、毛髪ストランドの長さとしては、カールされた状態であれば、カールの最大径になり、一方、カールが部分的に又は全体的にほどけていれば、根元側の端部からの最大の長さ（例えば、根元側の端部から毛先側の端部までの長さ）になる。 4). Moisture resistance Black virgin hair (length: 20 cm, weight: 2 g) is coated with 0.5 g of the sample (hair cosmetic obtained in the examples or comparative examples) and immediately using a curler with a curl diameter of 2 cm. A curl was prepared and dried at 50 ° C. for 1 hour. The length of the curled hair strand is measured, and the length is set as an initial value (L0).
Next, the dried hair bundle is suspended on a graduated board and placed in a thermo-hygrostat with a temperature of 30 ° C. and a humidity of 90% RH for 3 hours, and then the length of the hair strand is measured. Is the length after humidification (L2).
The length of the hair strand is the maximum curl diameter in the curled state, while the maximum length from the end on the root side if the curl is partially or totally unrolled. It becomes the length (for example, the length from the end on the root side to the end on the hair end side).
次式に従って、カールリテンション値を算出し、下記の評価基準により、耐湿性について評価した。
カールリテンション値（％）＝｛（２０－Ｌ２）／（２０－Ｌ０）｝×１００
なお、カールリテンション値が１００％に近いほど、カール保持率が強く、耐湿性（即ち、スタイル保持力）が優れている。
＜評価基準＞
◎：カールリテンション値が９０％点以上である。
○：カールリテンション値が７０％以上９０％未満である。
△：カールリテンション値が５０％以上７０％未満である。
×：カールリテンション値が５０％未満である。 The curl retention value was calculated according to the following formula, and the moisture resistance was evaluated according to the following evaluation criteria.
Curl retention value (%) = {(20−L2) / (20−L0)} × 100
Note that the closer the curl retention value is to 100%, the stronger the curl retention rate and the better the moisture resistance (that is, the style retention force).
<Evaluation criteria>
A: The curl retention value is 90% or higher.
○: The curl retention value is 70% or more and less than 90%.
Δ: The curl retention value is 50% or more and less than 70%.
X: The curl retention value is less than 50%.
カールリテンション値（％）＝｛（２０－Ｌ２）／（２０－Ｌ０）｝×１００
なお、カールリテンション値が１００％に近いほど、カール保持率が強く、耐湿性（即ち、スタイル保持力）が優れている。
＜評価基準＞
◎：カールリテンション値が９０％点以上である。
○：カールリテンション値が７０％以上９０％未満である。
△：カールリテンション値が５０％以上７０％未満である。
×：カールリテンション値が５０％未満である。 The curl retention value was calculated according to the following formula, and the moisture resistance was evaluated according to the following evaluation criteria.
Curl retention value (%) = {(20−L2) / (20−L0)} × 100
Note that the closer the curl retention value is to 100%, the stronger the curl retention rate and the better the moisture resistance (that is, the style retention force).
<Evaluation criteria>
A: The curl retention value is 90% or higher.
○: The curl retention value is 70% or more and less than 90%.
Δ: The curl retention value is 50% or more and less than 70%.
X: The curl retention value is less than 50%.
その他の実施例を以下に示す。
（実施例１１）
リキッド状スタイリング剤
(１) イオン交換水 残余
(２) ＰＥＧ－６ ５
(３) ＰＥＧ－８ ５
(４) ＰＥＧ－３２ ５
(５) ソルビトール １
(６) エタノール ５０
(７) 香料 適量
(８) 製造例３の粘着性セット樹脂 ３
(９)（アクリル酸アルキル／ジアセトンアクリルアミド）
コポリマー ２
(１０)クエン酸 適量 Other examples are shown below.
(Example 11)
Liquid styling agent
(1) Residual ion exchange water
(2) PEG-6 5
(3) PEG-8 5
(4) PEG-32 5
(5) Sorbitol 1
(6) Ethanol 50
(7) Perfume appropriate amount
(8) Adhesive set resin 3 of Production Example 3
(9) (alkyl acrylate / diacetone acrylamide)
Copolymer 2
(10) Citric acid appropriate amount
（実施例１１）
リキッド状スタイリング剤
(１) イオン交換水 残余
(２) ＰＥＧ－６ ５
(３) ＰＥＧ－８ ５
(４) ＰＥＧ－３２ ５
(５) ソルビトール １
(６) エタノール ５０
(７) 香料 適量
(８) 製造例３の粘着性セット樹脂 ３
(９)（アクリル酸アルキル／ジアセトンアクリルアミド）
コポリマー ２
(１０)クエン酸 適量 Other examples are shown below.
(Example 11)
Liquid styling agent
(1) Residual ion exchange water
(2) PEG-6 5
(3) PEG-8 5
(4) PEG-32 5
(5) Sorbitol 1
(6) Ethanol 50
(7) Perfume appropriate amount
(8) Adhesive set resin 3 of Production Example 3
(9) (alkyl acrylate / diacetone acrylamide)
Copolymer 2
(10) Citric acid appropriate amount
＜製法＞
（１）水に（２）～（５）の水溶性成分を加え撹拌溶解し水パーツとする。次に、（６）に（７）を加え撹拌し可溶化させた後、（８）～（９）を加え撹拌しアルコールパーツとする。水パーツとアルコールパーツとを混ぜ、（１０）を加えてリキッド状のスタイリング剤を得た。 <Production method>
(1) Add water-soluble components (2) to (5) to water and dissolve with stirring to obtain water parts. Next, after (7) is added to (6) and stirred to solubilize, (8) to (9) are added and stirred to obtain alcohol parts. Water parts and alcohol parts were mixed and (10) was added to obtain a liquid styling agent.
（１）水に（２）～（５）の水溶性成分を加え撹拌溶解し水パーツとする。次に、（６）に（７）を加え撹拌し可溶化させた後、（８）～（９）を加え撹拌しアルコールパーツとする。水パーツとアルコールパーツとを混ぜ、（１０）を加えてリキッド状のスタイリング剤を得た。 <Production method>
(1) Add water-soluble components (2) to (5) to water and dissolve with stirring to obtain water parts. Next, after (7) is added to (6) and stirred to solubilize, (8) to (9) are added and stirred to obtain alcohol parts. Water parts and alcohol parts were mixed and (10) was added to obtain a liquid styling agent.
（実施例１２）
リキッド状スタイリング剤
(１) イオン交換水 残余
(２) ＰＥＧ－６ ３
(３) ＰＥＧ－８ ３
(４) ＰＥＧ－３２ ３
(５) ソルビトール ２
(６) エタノール ４０
(７) 香料 適量
(８) 製造例３の粘着性セット樹脂 ３
(９)（アクリル酸アルキル／ジアセトンアクリルアミド）
コポリマー ３
(１０)ＰＰＧ－４０－ブチル １
(１１)クエン酸 適量 (Example 12)
Liquid styling agent
(1) Residual ion exchange water
(2) PEG-6 3
(3) PEG-8 3
(4) PEG-32 3
(5) Sorbitol 2
(6) Ethanol 40
(7) Perfume appropriate amount
(8) Adhesive set resin 3 of Production Example 3
(9) (alkyl acrylate / diacetone acrylamide)
Copolymer 3
(10) PPG-40-butyl 1
(11) Citric acid appropriate amount
リキッド状スタイリング剤
(１) イオン交換水 残余
(２) ＰＥＧ－６ ３
(３) ＰＥＧ－８ ３
(４) ＰＥＧ－３２ ３
(５) ソルビトール ２
(６) エタノール ４０
(７) 香料 適量
(８) 製造例３の粘着性セット樹脂 ３
(９)（アクリル酸アルキル／ジアセトンアクリルアミド）
コポリマー ３
(１０)ＰＰＧ－４０－ブチル １
(１１)クエン酸 適量 (Example 12)
Liquid styling agent
(1) Residual ion exchange water
(2) PEG-6 3
(3) PEG-8 3
(4) PEG-32 3
(5) Sorbitol 2
(6) Ethanol 40
(7) Perfume appropriate amount
(8) Adhesive set resin 3 of Production Example 3
(9) (alkyl acrylate / diacetone acrylamide)
Copolymer 3
(10) PPG-40-butyl 1
(11) Citric acid appropriate amount
＜製法＞
（１）水に（２）～（５）の水溶性成分を加え撹拌溶解し水パーツとする。次に、（６）に（７）を加え撹拌し可溶化させた後、（８）～（９）を加え撹拌しアルコールパーツとする。水パーツとアルコールパーツとを混ぜ、（１０）(１１)を加えてリキッド状のスタイリング剤を得た。 <Production method>
(1) Add water-soluble components (2) to (5) to water and dissolve with stirring to obtain water parts. Next, after (7) is added to (6) and stirred to solubilize, (8) to (9) are added and stirred to obtain alcohol parts. Water parts and alcohol parts were mixed, and (10) and (11) were added to obtain a liquid styling agent.
（１）水に（２）～（５）の水溶性成分を加え撹拌溶解し水パーツとする。次に、（６）に（７）を加え撹拌し可溶化させた後、（８）～（９）を加え撹拌しアルコールパーツとする。水パーツとアルコールパーツとを混ぜ、（１０）(１１)を加えてリキッド状のスタイリング剤を得た。 <Production method>
(1) Add water-soluble components (2) to (5) to water and dissolve with stirring to obtain water parts. Next, after (7) is added to (6) and stirred to solubilize, (8) to (9) are added and stirred to obtain alcohol parts. Water parts and alcohol parts were mixed, and (10) and (11) were added to obtain a liquid styling agent.
（実施例１３）
リキッド状スタイリング剤
(１) イオン交換水 残余
(２) ＰＥＧ－６ ７
(３) ＰＥＧ－３２ ７
(４) マルチトール １０
(５) ＰＥＧ/ＰＰＧ-５５/２８ジメチルエーテル １
(６) エタノール ５
(７) 香料 適量
(８) アクロナールＶ２１５ａｐ １
(９)（アクリル酸アルキル／ジアセトンアクリルアミド）
コポリマー ２
(１０)クエン酸 適量
(１１)フェノキシエタノール 適量 (Example 13)
Liquid styling agent
(1) Residual ion exchange water
(2) PEG-6 7
(3) PEG-32 7
(4) Maltitol 10
(5) PEG / PPG-55 / 28 dimethyl ether 1
(6) Ethanol 5
(7) Perfume appropriate amount
(8) Acronal V215ap 1
(9) (alkyl acrylate / diacetone acrylamide)
Copolymer 2
(10) Citric acid appropriate amount
(11) Appropriate amount of phenoxyethanol
リキッド状スタイリング剤
(１) イオン交換水 残余
(２) ＰＥＧ－６ ７
(３) ＰＥＧ－３２ ７
(４) マルチトール １０
(５) ＰＥＧ/ＰＰＧ-５５/２８ジメチルエーテル １
(６) エタノール ５
(７) 香料 適量
(８) アクロナールＶ２１５ａｐ １
(９)（アクリル酸アルキル／ジアセトンアクリルアミド）
コポリマー ２
(１０)クエン酸 適量
(１１)フェノキシエタノール 適量 (Example 13)
Liquid styling agent
(1) Residual ion exchange water
(2) PEG-6 7
(3) PEG-32 7
(4) Maltitol 10
(5) PEG / PPG-55 / 28 dimethyl ether 1
(6) Ethanol 5
(7) Perfume appropriate amount
(8) Acronal V215ap 1
(9) (alkyl acrylate / diacetone acrylamide)
Copolymer 2
(10) Citric acid appropriate amount
(11) Appropriate amount of phenoxyethanol
＜製法＞
（１）水に（２）～（５）の水溶性成分を加え撹拌溶解し水パーツとする。次に、（６）エタノールに（７）を加え撹拌し可溶化させた後、（５）・（９）・(１１)を加え撹拌しアルコールパーツとする。水パーツとアルコールパーツとを混ぜ、（８）(１０)を加えてリキッド状のスタイリング剤を得た。 <Production method>
(1) Add water-soluble components (2) to (5) to water and dissolve with stirring to obtain water parts. Next, (6) (7) is added to ethanol and stirred to solubilize, and then (5), (9) and (11) are added and stirred to obtain an alcohol part. Water parts and alcohol parts were mixed and (8) and (10) were added to obtain a liquid styling agent.
（１）水に（２）～（５）の水溶性成分を加え撹拌溶解し水パーツとする。次に、（６）エタノールに（７）を加え撹拌し可溶化させた後、（５）・（９）・(１１)を加え撹拌しアルコールパーツとする。水パーツとアルコールパーツとを混ぜ、（８）(１０)を加えてリキッド状のスタイリング剤を得た。 <Production method>
(1) Add water-soluble components (2) to (5) to water and dissolve with stirring to obtain water parts. Next, (6) (7) is added to ethanol and stirred to solubilize, and then (5), (9) and (11) are added and stirred to obtain an alcohol part. Water parts and alcohol parts were mixed and (8) and (10) were added to obtain a liquid styling agent.
Claims (5)
- （ａ）粘着性を有する粘着性樹脂を０．１～１０質量％と、
（ｂ）毛髪セット樹脂を０．１～１０質量％とを含有する化粧料であって、
前記（ａ）粘着性樹脂が、当該樹脂を実分５０質量％で含有する組成物で０．１ｍｍの厚みの皮膜を形成させ、２５℃・湿度５０％にて１日乾燥した後の、傾斜式ボールタック試験（傾斜角３０度、２５℃、湿度５０％）におけるボールナンバーが１～３０である粘着性を有することを特徴とする整髪用化粧料。 (A) 0.1 to 10% by mass of an adhesive resin having adhesiveness,
(B) a cosmetic containing 0.1 to 10% by weight of a hair setting resin,
(A) Inclined after the adhesive resin forms a 0.1 mm thick film with a composition containing the resin in an amount of 50% by mass and dried for one day at 25 ° C. and 50% humidity A hair styling cosmetic characterized by having an adhesiveness with a ball number of 1 to 30 in a ball tack test (inclination angle 30 °, 25 ° C., humidity 50%). - 化粧料の粘度が１００ｍＰａ・ｓ以下（２５℃、Ｂ型粘度計）であることを特徴とする、請求項１に記載の整髪用化粧料。 The cosmetic for hairdressing according to claim 1, wherein the cosmetic has a viscosity of 100 mPa · s or less (25 ° C, B-type viscometer).
- 化粧料が、当該化粧料を用いて０．１ｍｍの厚みの皮膜を形成させ、２５℃・湿度５０％にて１日乾燥した後の、傾斜式ボールタック試験（傾斜角１０度、２５℃）におけるボールナンバーが１～３０である粘着性を有することを特徴とする、請求項１又は２に記載の整髪用化粧料。 Inclined ball tack test (inclination angle 10 degrees, 25 ° C.) after the cosmetic is formed with a 0.1 mm thick film using the cosmetic and dried for one day at 25 ° C. and 50% humidity. The hair styling cosmetic composition according to claim 1 or 2, characterized in that it has adhesiveness with a ball number of 1-30.
- ０．０１～５質量％の油分を更に含有することを特徴とする、請求項１から３のいずれか一項に記載の整髪用化粧料。 The hair styling cosmetic composition according to any one of claims 1 to 3, further comprising 0.01 to 5% by mass of an oil component.
- 使用時に霧状に噴霧して用いることを特徴とする、請求項１から４のいずれか一項に記載の整髪用化粧料。 The hair styling cosmetic composition according to any one of claims 1 to 4, wherein the hair styling cosmetic composition is used by being sprayed in a mist state at the time of use.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2009-191487 | 2009-08-20 | ||
| JP2009191487A JP2011042617A (en) | 2009-08-20 | 2009-08-20 | Cosmetic for hair styling |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO2011021682A1 true WO2011021682A1 (en) | 2011-02-24 |
Family
ID=43607130
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/JP2010/064050 WO2011021682A1 (en) | 2009-08-20 | 2010-08-20 | Hair-dressing cosmetic |
Country Status (3)
| Country | Link |
|---|---|
| JP (1) | JP2011042617A (en) |
| TW (1) | TW201110999A (en) |
| WO (1) | WO2011021682A1 (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5670652B2 (en) * | 2010-06-15 | 2015-02-18 | 株式会社ダイゾー | Aerosol products |
| JP6218276B2 (en) * | 2013-08-21 | 2017-10-25 | 株式会社 資生堂 | Makeup cosmetic resins and makeup cosmetics |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2004067668A (en) * | 2002-07-31 | 2004-03-04 | Wella Ag | Method for forming, grooming and re-removing temporary rasta hair style |
| JP2005508917A (en) * | 2001-10-03 | 2005-04-07 | ザ プロクター アンド ギャンブル カンパニー | Hair styling composition containing particles |
| JP2006521302A (en) * | 2003-03-24 | 2006-09-21 | ユニリーバー・ナームローゼ・ベンノートシヤープ | Hair treatment composition |
| JP2008162945A (en) * | 2006-12-28 | 2008-07-17 | Kao Corp | Hair cosmetic |
| JP2009062482A (en) * | 2007-09-07 | 2009-03-26 | Kao Corp | Adhesive |
| JP2009520708A (en) * | 2005-12-22 | 2009-05-28 | ユニリーバー・ナームローゼ・ベンノートシヤープ | Hair treatment composition comprising a pressure sensitive adhesive |
| JP2010168294A (en) * | 2009-01-21 | 2010-08-05 | Kao Corp | Hair cosmetic |
-
2009
- 2009-08-20 JP JP2009191487A patent/JP2011042617A/en active Pending
-
2010
- 2010-08-20 WO PCT/JP2010/064050 patent/WO2011021682A1/en active Application Filing
- 2010-08-20 TW TW99127924A patent/TW201110999A/en unknown
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2005508917A (en) * | 2001-10-03 | 2005-04-07 | ザ プロクター アンド ギャンブル カンパニー | Hair styling composition containing particles |
| JP2004067668A (en) * | 2002-07-31 | 2004-03-04 | Wella Ag | Method for forming, grooming and re-removing temporary rasta hair style |
| JP2006521302A (en) * | 2003-03-24 | 2006-09-21 | ユニリーバー・ナームローゼ・ベンノートシヤープ | Hair treatment composition |
| JP2009520708A (en) * | 2005-12-22 | 2009-05-28 | ユニリーバー・ナームローゼ・ベンノートシヤープ | Hair treatment composition comprising a pressure sensitive adhesive |
| JP2008162945A (en) * | 2006-12-28 | 2008-07-17 | Kao Corp | Hair cosmetic |
| JP2009062482A (en) * | 2007-09-07 | 2009-03-26 | Kao Corp | Adhesive |
| JP2010168294A (en) * | 2009-01-21 | 2010-08-05 | Kao Corp | Hair cosmetic |
Also Published As
| Publication number | Publication date |
|---|---|
| TW201110999A (en) | 2011-04-01 |
| JP2011042617A (en) | 2011-03-03 |
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