TW201124168A - Hairdressing cosmetic - Google Patents

Abstract

Provided is a cosmetic preparation for hair styling which is a water-based preparation having a low viscosity and, despite this, has excellent hair styling performance and hair restyling performance, and which is nonsticky and smooth and imparts an extremely light finish. The cosmetic preparation for hair styling comprises (a) 3-15 mass% surfactant that is solid at ordinary temperature (25 C), (b) a polyalkylene glycol polymer (b1) that is liquid at ordinary temperature and/or a polyhydric-alcohol derivative (b2) that is liquid at ordinary temperature, (c) a film-forming polymer, and (d) liquid oily matter, and has a viscosity of 10,000 mPas or lower (25 C; Brookfield viscometer).

Description

201124168 VI. Description of the Invention: [Technical Field to Which the Invention Is Applicable] The present invention relates to a hair styling property which has an excellent hair styling ability, a sticky feeling, a smoothness, and a finished cosmetic. Makeup material. As far as the details are concerned, the low-adhesive and hair-reducing ability's have the advantages of not having a hair styling and lightness. [Prior Art] In the conventional hair styling cosmetic, the hair polymer and the film are highly formed. Lipids have the disadvantages of stiffness, reduced non-uniformity of the membrane, and the like. Therefore, in order to eliminate the strategy. For example, special opening 2007-217314 contains a specific amount of hair solid 1 alcohol and a spray of mist powder, no sticky feeling and has a specific amount of a specific low viscosity combined with a specific amount. The hair cosmetic has a feeling of wholeness or stiffness. After drying, the special polyoxyalkylene compound hair-fixing polymer compound can be prepared by the special-purpose polystyrene-based compound, and the fixing of the hair molecules can be achieved in order to achieve the modeling effect. Resin. However, the hair styling tree's shape can maintain such a deficiency under high humidity. So far, various checkmarks (Patent Document 1) have been adopted to record the use of molecular compounds, polyols, and final cosmetics. The shine of the hair. In the report (Patent Document 2), the polyether compound, the polymer resinizing power and the hair styling maintenance force are described, and the hair is re-finished without sticking with a finger. In the newspaper (Patent Document 3), it is described that the hair cosmetic composition of the polyoxyalkylene alkyl monoglycoside and the high molecular weight polyethylene glycol (molecular weight -5 - 201124168 6,000 to 3 0,000) is integrated. Hair and smoothness (smoothness). Japanese Laid-Open Patent Publication No. 2002-1 673 1 (Patent Document 4) discloses a hair cosmetic containing an amphoteric polymer, a sugar alcohol, a sugar alcohol derivative (for example, a polyoxyalkylene addition of a sugar alcohol), and has a hair styling Ability, ability to maintain hair style, and no sticky or stiff feeling. Japanese Patent Publication No. 2004-505902 (Patent Document 5) discloses an excellent reshaping composition in which a specific water-soluble polyalkylene glycol and a film-forming polymer are blended in a specific ratio and further combined with a fluid composition of a fluid medium. Sex and touch. However, in the above publication, there is no cosmetic material for hair styling which is low in viscosity, in order to obtain a hair styling cosmetic which can fully satisfy the hair styling ability and the degree of hair styling ability, or to further achieve a non-sticky feeling, The description and suggestion of the purpose or subject of the hair styling for the finished hair styling. Low-viscosity hair styling materials are particularly difficult to stand for styling and reshaping. Therefore, it is currently seeking to develop a low-viscosity hair styling cosmetic which has both sufficient styling ability and reshaping ability and has a good feeling of use. Patent Document 1 JP-A-2007-217314 Patent Document 2 Special Kaiping 1 1 -1 0 0 3 1 2 Patent Document 3 Special Kaiping 3 - 2 6 1 7 1 3 Patent Document 4 Special Opening 2 0 0 2 - 1 6 7 3 3 专利 专利 专利 2004 2004 2004 2004 2004 2004 2004 2004 2004 2004 2004 2004 2004 2004 2004 2004 2004 2004 2004 2004 2004 2004 2004 2004 2004 2004 2004 2004 2004 2004 2004 2004 2004 2004 2004 2004 2004 2004 2004 2004 2004 2004 2004 2004 2004 2004 2004 2004 Excellent hair styling ability, hair styling ability, and the purpose of hair styling materials that do not produce a sticky feeling, smoothness, and lightness of the finished hair style. [Means for Solving the Problems] In order to solve the above problems, the present invention provides a surfactant containing 3 to 15% by mass of (a) a solid at room temperature (25 ° C), and (b) (b,) a liquid at normal temperature. a polyalkylene glycol polymer, and/or (b2) a polyol derivative which is liquid at normal temperature, and (c) a film-forming polymer and (d) a liquid oil, and the viscosity of the system is 10,000 mPa.s. In the following (25: (B type viscometer)), the hair styling agent for the hair styling agent of the present invention, wherein the surfactant of the component (a) is a nonionic surfactant. The above-mentioned cosmetic for hair styling provided has a hardness of 20 or more (measured by a curd meter (25 ° C), a load of 400 g, and a pressure sensitive axis (diameter lmm) is 5 mm from the surface of the sample, and the scale is The above-mentioned hair styling cosmetic material is provided by the present invention, wherein the component (h) is a polyethylene diol having a mass average molecular weight of 200 to 900. The above-mentioned hair styling composition provided by the present invention has a viscosity 〇〇mPa. s or less (25C, B type viscometer), and when used, the spray becomes foggy 201124168 [Effects of the Invention] According to the present invention, it is possible to provide a water-based hair styling cosmetic which has the advantages of low viscosity and excellent hair-reversing ability, and which has the advantages of no stickiness and smoothness. MODES OF THE INVENTION The present invention will be described in detail below, and the following POEs represent a polyline representing a polyoxypropylene and a POB system representing a polyoxybutylene. [(a) Component] (a) A component is a solid at room temperature (25 ° C) (活性 An active agent. It is found in the present invention to be a solid surfactant which is particularly effective. When a surfactant which replaces the square of the component (a) is used, sufficient hair styling ability cannot be obtained: Advantageous Effects of Invention In the present invention, the f-surfactant includes an anionic surfactant, a positive surfactant, an amphoteric surfactant, and a nonionic surfactant 5. It is preferred to use a nonionic surfactant. - Anionic surfactants and cationic interfacial surfactants are more irritating to the skin than those of the surfactants. In the case of mist sprays, the ingredients of the hair styling may be poorly coated. Anionic boundary Active agents, cationic: hair styling ability and enable the completion of the

The interface between the ethylene and POP forms is effective. The liquid is used at room temperature and the hair is maintained. The present invention is described. Agent and non-ionic use of the eye and the scalp. Sexual interface activity 201124168 The agent is prone to foaming when it is finished. When an anionic surfactant, a cationic surfactant, or an amphoteric surfactant is used, precipitation may occur due to combination with other ionic components. Further, the volatilization of the solvent component or the like is slower than that of the nonionic surfactant, and the hair styling effect is slowed down. In addition to the above reasons, the cationic surfactant has a high affinity for hair, and the hair is too soft to be easily used as a nonionic surfactant, and the nonionic surfactant used in the present invention is exemplified. Among the nonionic surfactants shown, those which are solid at normal temperature. 1. A polyoxyethylene monoalkyl ether represented by the following formula (I): RO-(C2H40) nH (1) [In the formula (I), R represents an alkyl group having a carbon number of 4 to 24; There are ethylene oxide and the number of moles is 2 to 100. Specifically, lauric lauryl ether (commercially available as "NONION Κ-220", etc.), cyanosyl ketone ether (commercially available as "NONION Ρ-210", etc.), and eucalyptol ether ( Commercial products are "ΝΟΝΙΟΝ Ε-215", etc., ΡΟΕ stearyl ether (commercially available as "NONION S-215", etc.) (all of which are manufactured by Nippon Oil Co., Ltd.), decyl alcohol ether (The commercial product is "FINESURF TD-150") (Aoki Oil Industry Co., Ltd.). 2. Polyoxyethylene polyoxypropylene alkyl ether (II) represented by the following formula (Π)

RO-(c2h4〇) m (c3h60) nH 201124168 [In the formula (R), R represents an alkyl group having a carbon number of 4 to 24; m represents a compound having ethylene oxide and a molar number of 2 to 100. The η system indicates that propylene oxide is added and the number of moles is from 2 to 100. Specifically, Ρ〇Ε·POP phytosterol (commercially available as "NIKKOLBPS-3007", "Sunlight Chemical Co., Ltd."), etc., may be mentioned. 3. A polyoxyethylene monoester represented by the following formula (ΙΠ): RCOO-(C2H40) nH (III) [In the formula (m), R represents an alkyl group having a carbon number of 4 to 24; η represents an addition There are ethylene oxide and the number of moles is 2 to 100. Specifically, a monooleic acid polyethylene glycol (a commercially available product is "ΝΟΝΙΟΝ 0-4" (such as a Japanese oil), etc. 4. Polypropanol represented by the following formula (IV) Monoester: RCOO-(C3H60) nH (IV) [In the formula (IV), R represents an alkyl group having a carbon number of 4 to 24; and η represents a group in which propylene oxide is added and the number of moles is 2 to 100. Specifically, a monostearic acid polyethylene glycol (commercially available as "BLAUNON S-400A" (available from Aoki Oil & Fats Co., Ltd.), etc.) is shown in the following formula (V). Isoocturonic acid polyoxyethylene glycerol:

CH20 - (C2H40}a-CR (V) CHO-(C2H4〇)bH ch2o-(c2h4o)ch [In the formula (V), R represents an alkyl group having a carbon number of 4 to 24; a, b, c The table is not attached with Epoxy and the number of moles a + b + c = 3 to 100.] Specifically, isostearyl acid POE glycerin is mentioned (commercial product is "-10-201124168 UNIOXGM-30IS" (Japanese oil (stock) system, etc.), etc. 6. Polyisoethylene glycol glycerol glycerol 0 ΟΗ 20~(〇2Η40)3—CR Ο GHO — (C2H40)b—is represented by the following formula (VI) CR (VI) Ο

CH2〇~(C2H40)c-CR [In the formula (VI), R represents a hospital base having independent carbon numbers of 4 to 24; and a, b, and c are added with ethylene oxide and a molar number a +b+c=3~100 〇 具体 具体 具体 具体 具体 具体 具体 具体 具体 具体 UNI UNI UNI UNI UNI UNI UNI UNI UNI UNI UNI UNI UNI UNI ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( Polyoxyethylene hardened castor oil represented by the following formula (W): CH2〇-(C2H4O)a-C(CH2}10CH(CH2)5CH3 〇0(C2H40)xH \\ CHO-(C2H40)b-C( CH2)10CH(CH2)5CH3 (VII)

I

0(C2H40)yH Ο CH2〇-(C2H4〇)c—C(CH2)10CH(CH2)5CH3

0(C2H40)zH [In the formula (VH), a, b, c, X, y, z are the attached forces and have epoxy oxime and the molar number a + b + c + x + y + z = 2 ~150 people. Specifically, POE-hardened castor oil 60 (commercially available as "UNIOXHC-60" (Nippon Oil Co., Ltd.), etc.) -11 - 201124168 8. Polycondensation represented by the following formula (Vi) Oxyethylene alkyl ether: R, 〉CHCH20(CH2CH20)nH (VIII) R, [In the formula (VDI), R represents an alkyl group having an independent carbon number of 4 to 24; η represents the addition of ethylene oxide. And the molar number is 2 to 100.] Specifically, ΡΟΕ ( 20 ) octyl dodecyl ether (commercially available as "EMALEX OD-20" (Japan EMULS I Ο Ν (share) system, etc.), ΡΟΕ ( 25 ) Octyl dodecyl ether (commercially available as "EMALEX OD-25" (Japan EMULSION, etc.). 9. Polyoxyethylene polyoxypropylene decyltetradecyl ether: Commercially available products It is "UNILUB 50MT-2200B" (Nippon Oil Co., Ltd.), etc. (a) The composition is solid (solid) at normal temperature (25 ° C). By using (a) the component is solid (solid) It can effectively impart hair styling ability, hair style retention ability, and can also improve shampooness. Also indicates the basis of the solid (solid) state of component (a), which is 20 in the present invention. Preferably, the hardness is preferably 40 or more. Here, the "hardness" firstly causes the dissolved sample to flow into a cylindrical glass bottle having a diameter of 3 cm and a depth of 3 cm (the depth is equal to or more than icm), at 25 After acclimatization for 12 hours or more, a curd meter (made by a bird machine) was used to apply a load of 400 g to the sample at a sample temperature of 25 ° C, and the pressure sensitive shaft (diameter 1 mm) was allowed to enter the surface from the flat surface of the sample. The number of ticks at 5 mm is used as the hardness. The higher the number is, the higher the hardness is. -12- 201124168 In addition, the (a) component is based on the solubility or re-molding ability of an aqueous solvent such as water or an alcohol-based solvent. The HLB of the total non-ionic surfactant is preferably 10 or more, and more preferably HLB 12 or more. The HLB system is calculated according to the above formula (hereinafter referred to as H) = H+1 = 7 + 11.7 - log (MW/MO) (wherein MW represents the molecular weight of the hydrophilic group, and MO represents the molecular weight of the oleophilic group). In the hair styling cosmetic composition of the present invention, the compounding amount of the component (a) is 3 to 15% by mass. Good, 3~12% by mass is better. When it is less than 3% by mass, it is difficult to charge Obtaining the whole hair force and re-shaving force, and even if the mixing is more than 15% by mass, 'not only the effect of increasing the amount of the anastomotic mixture is found, but also the tendency of the viscosity to become large, the self-adhesive feeling and the weight of the finished hairstyle are [(b) component] (b) The component is one or two selected from the group consisting of (h) a polyalkylene glycol polymer which is liquid at normal temperature, and (b2) a polyol derivative which is liquid at normal temperature. the above. <(b!) component> A polyalkylene glycol polymer which is liquid at normal temperature (25 °C), and an EO polymer and PO which are polymerized by EO as a constituent unit are exemplified as a constituent unit. The PO polymer after polymerization, BO is a BO polymer polymerized in a constituent unit, or each of the-13-201124168 copolymers obtained by polymerization in the above-mentioned constituent units. In particular, an EO polymer, a ruthenium-ruthenium copolymer containing an EO constituent unit and a P〇 constituent unit, and an EO-containing BO copolymer having a unit composition unit of EO and BO are preferable. The form of the copolymerization is not particularly limited, and may be a molecular weight, smoothness, and non-stickiness of any of the EO polymers such as bulk copolymerization, graft copolymerization, and random copolymerization, from the viewpoints of molecular weight, smoothness, and non-stickiness. It is preferably polyethylene glycol (PEG) of not more than 900, and particularly preferably polyethylene glycol having a molecular weight of 600 or less. The lower limit of the molecular weight is not particularly limited, and is preferably about 200 or more, particularly preferably about 300 or more. Specific examples thereof include PEG200, PEG3 00, PEG400, and PEG600. A suitable example of the ruthenium PO copolymer is a ruthenium-ruthenium random copolymer represented by the following formula (X). Ch3 1 Ri〇— -ch2ch2o- P -ch2cho-r2 (X) The RMR 2 in the formula (X) represents an alkyl group or a hydrogen atom each having an independent carbon number of 1 to 4. The alkyl group having 1 to 4 carbon atoms may, for example, be a methyl group, an ethyl group, a n-propyl group, an isopropyl group, a n-butyl group, a second butyl group or a third butyl group. Among them, a methyl group and an ethyl group are preferred. Alkyl groups having a carbon number of 5 or more have low hydrophilicity and tend to have a poor moisturizing feeling. The ratio of P (= EO constitutes the unit's additional mole number) to q (=p〇 the number of additional moles of the unit) is preferably p/q = l 〇 ~ 0.5, and 5 to 0.8 is better. In addition, 2$p + q$l〇.

Specific examples of the copolymer represented by the above formula (X) include POE (9) ΡΟΡ(2) random copolymer dimethyl ether, p〇E (14). POP -14 - 201124168 (7) Random co-polymer dimethyl ether, ρ 〇Ε (36) · ΡΟΡ (41) random copolymer dimethyl ether, hydrazine (55) · Ρ〇Ρ (28) random copolymer dimethyl ether. Specific examples of the ruthenium ruthenium copolymer include ruthenium ( 52 ) · ruthenium ( 32) bulk copolymer dimethyl ether. From the viewpoints of the lightness, smoothness, and non-stickiness of the finished hair style, the ruthenium polymer preferably has a polypropylene glycol (PPG) having a molecular weight of 4,000 or less, particularly a polypropylene glycol having a molecular weight of 2,000 or less. good. The lower limit of the molecular weight is not limited, and is preferably about 200 or more, and more preferably 300 or more. Specific examples thereof include PPG700, PPG1,000, PPG1, and 200. In the hair styling cosmetic composition of the present invention, it is mainly expected that the (b!) component has a reshaping force, a non-sticky feeling, and a smooth hair. One or two or more (b !) ingredients can be used. In the present invention, the (b!) component is particularly preferably a polyethylene glycol having a molecular weight of 200 to 900. < (b2) component> The polyol constituting the component (b2) may, for example, be an alcohol having 2 or more members, and specific examples thereof include ethylene glycol, dipropylene glycol, propylene glycol, 1,3-butylene glycol, glycerin, and diglycerin. Wait 2 to 4 yuan alcohol, and sorbitol, mannitol and other 5 to 6 yuan alcohol. A suitable example of such a polyol derivative is an alkylene oxide additional polymer of a polyhydric alcohol. The alkylene oxide to be additionally polymerized is preferably a constituent unit such as EO, P〇 or BO. Specifically, POP sorbitol (commercially available as "UNIOL HS-1 600D" (made by Nippon Oil Co., Ltd.), and P0E (i〇) methyl glucoside (commercially available as "GLUCAM E-10") (Japan-15-201124168 LUBRIZOL (share) system), etc.). Further, ethylene glycol alkyl ethers (for example, ethylene glycol monomethyl ether, ethylene glycol monoethyl ether, ethylene glycol monobutyl ether, ethylene glycol monophenyl acid, ethylene glycol monohexyl group) are mentioned. Ether, ethylene glycol mono-2-methylhexyl ether, ethylene glycol monoisoamine ether, ethylene glycol monobenzyl ether, ethylene glycol monoisopropyl, ethylene glycol dimethyl ether, ethylene Alcohol diethyl ether, ethylene glycol dibutyl ether, etc.; polyethylene glycol alkyl ethers (such as diethylene glycol monomethyl ether, diethylene glycol monoethyl ether, diethylene glycol monobutyl Ether, diethylene glycol dimethyl ether, diethylene glycol diethyl ether, diethylene glycol monobutyl ether, diethylene glycol methyl ethyl ether, triethylene glycol monomethyl ether, three Ethylene glycol monoethyl ether, etc.): propylene glycol alkyl ethers (for example, propylene glycol monomethyl ether, propylene glycol monoethyl ether, propylene glycol monobutyl ether, propylene glycol monoisopropyl ether, etc.): polypropylene glycol alkyl ethers (eg dipropylene glycol monomethyl ether, dipropylene glycol monoethyl ether, dipropylene glycol monobutyl ether, etc.); glycol ether esters (eg ethylene glycol methyl ether acetate, ethylene glycol ethyl ether acetate, ethylene two) Alcohol butyl ether Ethyl ester, ethylene glycol phenyl ether acetate, etc.): ethylene glycol diester (ethylene glycol diadipate, ethylene glycol disuccinate, etc.): polyglycol ether ester (diethylene) Alcohol ether acetate, diethylene glycol butyl ether acetate, etc.; propylene glycol ether esters (propylene glycol methyl ether acetate, propylene glycol ethyl ether acetate, propylene glycol propyl ether acetate, propylene glycol phenyl ether acetate, etc.); glycerol monoalkyl Ether (eg, heparin, shark alcohol, shark liver alcohol, etc.); Glysolid cream; tetrahydrofuran methanol, and the like. A suitable example is PEG-5-PPG-65 pentaerythritol (commercially available as "BE RU Τ Α Μ Ο RU P-7〇〇") (Japanese oil (stock) system, etc.), PPG-40 (Commercial product is "UNILUB MB-3 70" (Nippon Oil Co., Ltd.), etc. -16- 201124168 In the hair styling cosmetic composition of the present invention, the hair styling power of the component (b2) is mainly expected. It is possible to use one or two or more (b) components. The blending amount of the component (b) in the hair styling cosmetic composition of the present invention is preferably 0.1 to 30% by mass. 3 to 15% by mass is more preferable, and 5 to 15% by mass is particularly preferable. When the amount is not 0.1% by mass, it is difficult to sufficiently obtain the effect of the component (b), and conversely, even if the mixing exceeds 30% by mass, not only the increase in the amount of the anastomotic mixture is not found. The large effect has also been found to have a tendency to become more viscous, and the self-adhesive feeling and the weight of the finished hair styling are not good. In terms of the self-shaving force and the hair styling power of the present invention, it is used (b,). The component (b2) is preferred. [(c) component] The film-forming polymer is not particularly limited, and can be used arbitrarily for use in hair styling agents, etc. The film forming polymer of the hair styling agent is a film-forming polymer film of an acrylic type, an ethylene type, an urethane type, or a polysaccharide type. Acrylic-based and vinyl-based film-forming polymer> An anionic polymer may, for example, be an alkyl acrylate/diacetone acrylate amine copolymer [?1] 八3 (: 12 £1^53?, ?1) ^3(:12£1^9909B, PLAS CIZE L-9948B, etc. (all manufactured by GOO CHEMICAL), alkyl octyl acrylate copolymer (DERMACRYL 79 (AKZONOBEL)), Polyethylene glycol-17- 201124168 • Polypropylene glycol-25 · Dimethyl polyoxyalkylene acrylate copolymer [LUVIFLEX Silk (made by BASF)], acrylic acid · Acrylamide. Aromatic acid vinegar copolymer [Ultrahold] 8. Ultrahold Strong (all manufactured by BASF Corporation), alkyl acrylate copolymer [ANISETNF-1000, ANISET HS-3000, etc. (all manufactured by Osaka Organic Chemical Industry Co., Ltd.)], etc. For example, octylamine acrylate·hydroxy acrylate Propyl methacrylate butylamine ethyl copolymer [AMPHOMER SH30, AMPHOMER LV-71 (all manufactured by AKZ0ΝΟBEL), methacryloyloxyethylcarboxybetaine·methacrylic acid alkane Base polymer (YUKAFORMER R205, YUKAFΟRΜER3 0 1 , YUKAFORMER SM > YUKAF0RΜER 1 04D, etc. (all of which are manufactured by Mitsubishi Chemical Corporation), RAM resin - 1 000, RAM resin - 2000, RAM resin - 3 000, RAM Resin-4000 (all of which are manufactured by Osaka Organic Chemical Industry Co., Ltd.), dimethyldiallyl ammonium chloride-acrylic acid copolymer [MERQUAT 280, MERQUAT 295 (all manufactured by Nalco), and chlorination Methyl diallyl ammonium, acrylamide, acrylic acid copolymer (MERQUAT Plus 3 3 3 0, MERQUAT Plus 3 3 3 1 (all manufactured by NALCO)), and the like. The cationic polymer may, for example, be vinylpyrrolidone dimethylamine ethyl acrylate diethyl sulphate [HC polymer 1S (M) or HC polymer 2 (all manufactured by Osaka Organic Chemical Industry Co., Ltd.). ), GAFQUAT 7 5 5N (made by ISP), vinylpyrrolidone, dimethylaminopropyl methacrylamide, lauryl dimethylamine propyl methacrylate-18- 201124168 guanamine copolymer [STYLEZE W-20 (made by ISP)], vinylpyrrolidone. N,N-dimethylaminoethyl methacrylate. Alkyl acrylate. Tripropylene glycol diacrylate copolymer [COSQUAT GA467, CO SQUAT GA46 8 (both Osaka) Organic Chemical Industry Co., Ltd.), polydimethyl dimethyl hexahydropyridine [MERQUAT 100 (manufactured by NALCO)], polydimethyl dimethyl diallyl ammonium acrylate amide copolymer [ MERQUAT 550 (manufactured by NALCO Co., Ltd.), dimethylamine propyl acrylate phthalamide ♦ dimethyl methacrylate methacrylate copolymer. Examples of the nonionic polymer include polyvinylpyrrolidone [LUVISKOL K17, LUVISKOL K30, LUVISKOL K90 (above, BASF), PVPK (manufactured by ISP)], and vinylpyrrolidone-vinyl acetate copolymer [PVP/VA S]. -630, PVP/VA E-735 'PVP/VA E-3 3 5 (above is made by ISP), LUVISK 0 L VA73W, LUVISKOL 37E (above is BASF), PVA-6450 (Osaka Organic Chemical Industry ( ())), vinyl methyl ether·maleic acid alkyl copolymer [GANTREZ A-42 5 > GANTREZ ES-225, GANTREZ ES-335 (all manufactured by ISP)], vinylpyrrolidone methyl A acrylamide-vinylimidazole copolymer (LUVISET Clear (manufactured by BASF Corporation)). <Amino urethane-based film-forming polymer> The urethra-based ethylenic acid-based film-forming polymer may, for example, be a cerium oxide/polyether-based polyurethane resin [YUDOZOL PUD ( Akzo Nobel Co., Ltd.), "LUVISETP.U.R." (BASF Corporation -19 - 201124168), and JP-A-2006-2 1 3 706 For example, "DynamX" (manufactured by Akzo Nobel Co., Ltd.) or the like can be given as the "acrylic acid-urethane-based film-forming polymer". <Polysaccharide-based film-forming polymer> The polysaccharide-based film-forming polymer may, for example, be a gum arabic, polydextrose, succinose, carrageenan, carrageenan, tragacanth, or Guanhua bean gum. Locust bean gum, galactomannan gum, Sanxian gum, starch, long bean gum '榲椁 seed (榲悖), casein, cyclodextrin, gelatin, sodium pectinate, sodium alginate, methyl fiber , ethyl cellulose, carboxymethyl cellulose, hydroxyethyl cellulose, hydroxypropyl cellulose, crystalline cellulose, 〇-[2_hydroxy-3-(trimethylamino)propyl]hydroxyethyl Chlorinated cellulose, 〇_[2_hydroxy-3-(trimethylamino)propyl] chlorinated Guanhua bean gum, 〇_[2_hydroxy_3-(trimethylamino)propyl] chlorination Locust bean gum, hydroxypropyltrimethyl chloride starch, and the like. In the present invention, it is preferred to use an acrylic, vinyl or urethane-based film-forming polymer from the viewpoint of re-synthesis. In the hair styling cosmetic composition of the present invention, it is mainly desired that the component (c) can impart a styling power, a hair styling ability, and a lightness of the finished hair styling. One or two or more kinds of the components (c) can be used. The compounding amount of the component (c) in the cosmetic preparation for hair styling of the present invention is preferably from 1 to 15% by mass, more preferably from 1 to 6% by mass. When it is less than 1% by mass, it is difficult to sufficiently obtain the effect of the component (c). On the other hand, even if the mixing exceeds 15% by mass', not only the effect of increasing the amount of the anastomotic mixture but also the tendency to increase the viscosity is obtained, and it becomes stiff. The reason is not good. -20- 201124168 [Component (d)] The liquid oil component as the component (d) is not particularly limited as long as it is in the form of a liquid at room temperature, and can be used for cosmetics. For example, linseed oil and camellia are mentioned. Oil, Australian apple oil, corn oil, leeole oil, olive oil, avocado oil, camellia oil, castor oil, sunflower oil, apricot kernel oil, bay oil, jojoba oil, grape seed oil, almond oil, vegetables Seed oil, sesame oil, wheat germ oil, rice germ oil, rice bran oil, cotton oil, soybean oil, peanut oil, tea oil, evening primrose oil, egg butter, beef foot oil, glycerin, triglycerin, tricaprylate, three Iso-palmitate. Further, examples of the liquid oil include ethylhexanoate such as cetyl ethylhexanoate, glycerol tris(ethylhexanoate), and pentaerythritol tetrakis(ethylhexanoate). ) esters such as lauric acid esters such as esters and hexyl laurate, isopropyl myristate, octyldodecanol myristate, palmitic acid esters such as octyl palmitate, and iso-cetyl alcohol. Examples include isostearyl esters such as ester esters and isostearyl esters such as isopropanol isostearyl esters, isopalmitate such as isohexyl palmitate, and oleic acid esters such as isododecanol oleate. An ester oil such as a fatty acid diester such as a propyl fatty acid ester or a sebacic acid diester such as diethyl sebacate or diisostearyl malate. Further, examples of the cerium oxide oil which is liquid at normal temperature as the above-mentioned oil component include chain cerium oxide such as dimethyl polyoxy siloxane, methyl phenyl polyoxy siloxane or polymethyl polyoxy siloxane, and eight Cyclic cerium oxide such as methylcyclotetradecane oxide, decamethylcyclotetradecyl oxide, dodecamethylcyclotetradecyl oxide, amine modified cerium oxide oil, polyether modified cerium oxide oil, carboxy modification Sulphur dioxide oil, alkane modified cerium oxide oil, ammonium salt modified cerium oxide oil, fluorine modified cerium oxide oil, and the like. -21 - 201124168 In these liquid oils, by using a polar oil such as tris(ethylhexanoate) or pentaerythritol tetrakis(ethylhexanoate), the moisturizing feeling of the hair cosmetic can be imparted. Further, by using cerium oxide oil, it is possible to effectively impart a moist feeling and a smooth feeling. Further, the above-mentioned liquid oil component may be completely exemplified as the oil component, and if it is an oil component belonging to another category, it may be used as the "liquid oil component" of the present invention as long as it is liquid at normal temperature. In the hair styling cosmetic composition of the present invention, the amount of the component (d) is preferably from 1 to 5% by mass, more preferably from 1 to 3% by mass. When it is less than 0.1% by mass, it is difficult to obtain a sufficient smoothness. On the other hand, when it is more than 5% by mass, the hair styling ability is lowered or the viscosity is made poor. The hair styling cosmetic of the present invention has a system viscosity of 10,000 mPa.s or less (25 ° C, B type viscosity meter), preferably 10,000 mPa.s or less. In particular, when the hair styling cosmetic composition of the present invention is used as a hair spray or a mist-like hair styling agent, the viscosity is preferably 1 〇〇 mPa_s or less. The lower limit 黏 of the viscosity is not particularly limited, but it is preferably 8 mPa·s or more from the viewpoint of usability, etc. The hair styling cosmetic composition of the present invention is a component (a) to (d) and optionally added thereto. The component is dissolved in an aqueous solvent (for example, water, an alcohol-based solvent of a low-valent alcohol having 1 to 6 carbon atoms (for example, ethanol or isopropyl alcohol), or a mixed solvent thereof). The hair styling cosmetic composition of the present invention is aqueous and has low viscosity and viscosity adjustment. For example, by controlling the degree of copolymerization of the mixed copolymer, increasing or decreasing the amount of the polymer, etc., adjusting the mixing amount of the aqueous solvent. Wait for adjustments. In the past, the water-based low-viscosity hair styling cosmetic material has a hair styling ability because it is difficult to obtain sufficient hair styling power and hair styling force when it is -22-201124168. The hair styling cosmetic of the present invention has a low viscosity and at the same time has a sufficient hair styling ability, hair styling ability, and hair styling ability. In addition to the above-mentioned components, the hair styling cosmetic composition of the present invention can be arbitrarily added to other components generally used for cosmetics and pharmaceuticals, without damaging the effects of the present invention. Examples of such components include powder components, higher fatty acids, ultraviolet absorbers, polyols, metal chelators, sugars, amino acids, organic amines, polymer emulsions, pH adjusters, skin nutrients, vitamins, antioxidants, and the like. Antioxidant additives, spices, etc. The ingredients may be appropriately mixed as needed, and the hair styling cosmetic of the present invention may be produced according to a usual method according to the intended dosage form. The hair styling cosmetic composition of the present invention may be any of a solubilized system, an emulsified system, a powder dispersion system, an oil-water two-layer system, and an oil-water-powder three-layer system. It is preferably a solubilized system or an oily type emulsion in water. The best embodiment of the hair styling cosmetic composition of the present invention may be a gas gel hair spray, a non-air gel hair spray, a mist hair styling agent, a styling lotion, a hair mousse, a hair styling gel. , hair lotion, etc. Since the hair styling cosmetic composition of the present invention is water-based and has low viscosity, even if a hair spray or a mist-like hair styling agent is used in a spray form, the spray port of the spray container is not clogged, and the spray can be stably sprayed. It is foggy and has excellent hair styling ability, hair styling ability and can be uniformly applied to the hair. The gas gel type is generally filled into the spray container together with the propellant. As the propellant, a compressed gas such as liquefied petroleum gas such as propane, butane, pentane or dimethyl ether, nitrogen gas or compressed air, or a propellant known in the field of gas gel can be used. -23- 201124168 The mixing amount of the propellants is preferably from about 5 to 200% by mass based on 100% by mass of the cosmetic (stock solution) for hair styling. EXAMPLES Hereinafter, the present invention will be described in more detail with reference to examples, but the present invention is not limited by the examples. The amount of the mixture is expressed as % by mass (solid part) when it is not specifically labeled. First, the evaluation method used in the present embodiment will be described. [Viscosity] The sample (100 to 200 mL) was placed in a BL type viscometer (rotor No. 2, rotation speed 60 rpm, 25 ± 2 ° C), and the sample viscosity was measured after the rotor was rotated. [Finishing ability] Take a bunch of black hair that has not been damaged by hot dyeing (length 2 〇cm, mass 4g) 'Apply 〇.5g sample on it', apply it evenly after the finger, the difficulty of hair styling, according to Specialized testers (1 position) were evaluated for functional tests. [Re-finishing ability] Take a bunch of black hair that has not been damaged by hot dyeing (length 2〇cm, mass 4g) 'Apply 〇.5g sample on it' for hair bundles dried at room temperature for 1 hour, The ease of shaping of the hair when picking up the hair bundle and turning it, according to the -24-201124168 special test reviewer € 10 bit) push ~ 仃 仃 functional test evaluation. [The degree of no sticky feeling] Take a bunch of black hair dyed to the &grass and hair (length 20cm, mass 4g)' coated with 0 · 5 g sample, evenly spread with fingers The degree of non-stickiness of the hair 'according to the special, the test reviewer (! 〇 position) for the functional test evaluation. [Slip] Take a bundle of black undyed hair (length 2〇cm, mass 4g), and apply 〇.5g sample on it, for the smoothness of the hair surface after evenly applying with fingers. The functional test was evaluated according to the special test reviewer (i 〇 position). [Lightness of hair style] Take a bunch of black hair that has not been damaged by hot dyeing (length 20cm, mass 4g) 'Apply 〇.5g sample on it, apply it evenly after finger to the lightness of hair style, according to the special The test reviewer (1 position) was evaluated for the functional test. <Evaluation Points> 5 points: Excellent 4 points: Good 3 points: Normal (not bad or not bad) -25- 201124168 2 points: slightly worse 1 point: poor < evaluation criteria> ◎: Evaluation point The total number is 40 or more. 〇: The total number of evaluation points is 3 5 points or more and less than 40 points. △: The total number of evaluation points is 30 points or more and less than 3 points. △: The total number of evaluation points is 20 points or more. 30 points X: The total number of evaluation points is less than 20 points (Examples 1 to 8 and Comparative Examples 1 to 8) Using the samples shown in the following Tables 1 to 2, according to the above evaluation method, the hair styling ability and the The hair styling ability, the degree of non-stickiness, the smoothness, and the lightness of the hairstyle were evaluated. The results are shown in Tables 1 to 2. Further, in Tables 1 and 2, the following products were used. • POE ( 25 ) Whale methyl ether (M): "EMALEX 125" (made by Nippon Oil Co., Ltd.) • ΡΟΕ (20) Hawthorn ether (·2) "NIKKOL ΒΒ-20" (Sunlight Chemical Co., Ltd.) )) (ΡΟΕ) (25) Octyl Dodecyl Ether (*3): “EMALEXOD-25” (made by EMULSION, Japan) • POE (3 0) -POP (7) Phytosterol (·4): NIKKOL BPS-3 007" (Daily Chemical Co., Ltd.) • PEG-5-PPG-65 Pentaerythritol (*5): "BERUTAMORU Ρ-700" -26- 201124168 (Nippon Oil Co., Ltd.) • Dimerization Oxane (t6): "cerium oxide KF-96A-6CS" (manufactured by the company) • Acrylic acid alkyl diacetone acrylate amine copolymer (<7) CIZE L-9909B" (G Ο Ο C Η Ε ΜI CAL (share) system

(信信化 "PLAS -27- 201124168 i Example 8 Add to 100 ca r - 1 1 1 1 CO CO 2 i S CM ◎ ◎ 1 Ο Δ 1 1 〇 Δ 1 实施 Example 7 Add to 100 2 CO 1 1 1 1 1 CO I 0.05 s 〇ΟΔ 1 ΟΔ ο ο Example 6 Addition to 100 2 CO 1 1 1 1 CO 1 Cj 1 so ΟΔ ◎ ο ο Example 5 Add to 100 <〇1 1 1 1 CO CO CO r -·I 0.05 1 ◎ ο Ο 1 ΟΔ ο Example 4 Add to 100 00 i0 1 1 1 CO I CO CO 0.05 so 0 ΟΔ ◎ ΟΔ Example 3 Add to 100 00 (d 1 1 CO 1 1 CO CO r— § s 0 0 Ο ◎ 1 Ο Δ Example 2 Add to 100 i〇1 CO 1 1 1 CO CO § s ◎ ◎ Ο Ο 实施 Example 1 Add to 100 CO (d CO 1 1 1 1 CO CO 2 in g § ◎ ◎ Ο Ο Δ ◎ Mixed component ion exchange water ethanol POE (25) cetyl ether (M) (HLB = 15, hardness > 100) m irnj © f vd II PQ 邑梅 3 cs ω 〇 (X, POE ( 60) Hardened castor oil (HLB=14, hardness 10.95) POE (25) Octyl dodecyl ether (*3) (HLB=14.3, hardness 26.4) s © rH 3 a 1 Draw back /*~N Bu Sw/ Ο /-Ν cn / Ο CL, polyethylene glycol (molecular weight 400) PEG-5-PPG-65 pentaerythritol dimethoxane (*6 Acrylic acid alkyl diacetone acrylate amine copolymer ('7) perfume viscosity (mPa «s / 25t) hair styling ability (after coating) hair styling ability (coating 1 hour) no sticky feeling degree smoothness Lightness of hair style -28- 201124168 s Comparative example added to 100 2 T- s 1 1 1 1 CO CO 1 0.05 1 cvj CO ◎ ο X < X Comparative Example 7 Add to 100 LA CO 1 1 1 1 CO CO 1 1 0.05 m ΟΔ ο <3 X <1 Comparative Example 6 Add to 100 00 1 1 1 1 1 CO CO 1 1 0.05 1 m in XX ο X <1 Comparative Example 5 Add to 100 <〇CO 1 1 1 1 1 1 τ-· 1 0.05 1 ΟΔΔ X ΟΔ <1 0 Comparative Example 4 i is added to 100 〇〇<0 r- 1 1 1 1 CO CO m § 卜<X ο ο <1 Comparison Example 3 Addition to 100 m CO 1 1 1 1 CO CO 1 1 0.05 1 <〇<1 o ο < ο < Comparative Example 1, added to 100 «〇<d CQ I 1 1 1 CO CO 1 1 0.05 1 oo o ο <3 X ο Comparative Example 1 Add to 100 CO 1 1 1 1 I CO CO τ-· 1 0.05 1 (OXX ο ο <3 Mixed component ion exchange water ethanol 1 m 1 © rr-^ II 3 δ mwm disk <N go Λ m to/ ffi f VO »—H It PQ J s O) 匕憩 slightly*3 /-'S (N g POE (60) hardened castor oil (HLB=14, hardness 10.95) s CN tej ts f rn 一Π PQ hJ s ll + m speak d CN ω 〇S' δ teJ ® f oi I-H PQ hJ 1 © /-N 卜 a. o CU m V—/ ω s Polyethylene glycol (molecular weight 400) PEG-5-PPG-65 pentaerythritol (*5) dimethyl polyoxyalkylene (t6) 狴Μ Ε Ε Ll ή 氍 perfume viscosity (mPa-s/25^) hair styling ability (after coating) § seven 鲴 warming m τ*π w: no sticky feeling smoothness hair style lightness -29- 201124168 As can be clearly seen from the results of 1 to 2, the hair styling cosmetic of the present invention has a low viscosity, and at the same time, an excellent balance can be achieved between the hair styling ability and the hair styling ability, and the merging has no stickiness. It is greasy, smooth and gives the finished hair a lighter look. On the other hand, the cosmetic for hair styling other than the scope of the present invention cannot simultaneously have all the effects of the present invention. (Formulation example: misty hair styling agent) (mixed component) (mass ° /.) (1) ΡΟΕ (30) · ΡΟΡ (7) phytosterol 3 (2) ΡΟΕ (60) hardened castor oil 1 (3 Dimethyl polyoxane 4 (4) PPG-1 6 glycerol ether 3 (UNIOL TG-1000; manufactured by Nippon Oil Co., Ltd.) (5) Polyethylene glycol (molecular weight 400) 1 (6) Vinyl pyrrolidone. Vinyl acetate copolymer 2 (PVP/VA S-630 ISP) (7) Butanediol 2 (8) Sorbitol 〇.5

(9) Red wine extract 0J (1〇) citric acid (food) 〇.1 (11) Perfume 0.1 (12) Ethyl p-hydroxybenzoate 0.2 (13) Ion exchange water is added to 1〇〇-30- 201124168 Manufacture In the method, a part (1 3 ) is sequentially added to (7), (1), (2), (8), (9), (10), and (12) to form a water component. In (3), (4) and (1 1 ) are added in order to form an oil component. While stirring, the oil component was added to the water component to be emulsified. Further, it is stirred and mixed with the residual (13) solution to which (5) and (6) have been added to obtain a mist-like hair styling agent (m i s t ). (Formulation Example 2: misty hair styling agent) (mixed component) (% by mass) (1) ΡΟΕ (25) cetyl ether 1 〇 (2) dimethyl polyoxy siloxane 2 (3) pentaerythritol tetra (ethyl) Caproic acid ester 3 (4) POE (10) methyl glucoside 2 (GLUCAM E-10; manufactured by LUBRIZOL Co., Ltd.) (5) POP (40) butyl ether. 1 (UNILUB MB-370; (6) (6) cerium oxide/polyether-based polyurethane resin 1 (YUDOZOL PUD; manufactured by Nippon NSC Co., Ltd.) (7) Acryl acrylate diacetone acrylate amine copolymer 1 (PLAS CIZE L-9909B; GOO CHEMICAL Co., Ltd.) (8) NaCl °·5 (9) Diglycerin 3 -31 - 201124168 (10) L-menthol 〇 (11) Perfume 0.1 (12) Benzene Oxyethanol oxime 5 (13) Ion-exchanged water is added to 100. A part (13) is sequentially added to (9), (1), (1〇), and (12) to form a water component. (3), (4), (5), and (11) are sequentially added to the oil component in (2). While stirring, the oil component is added to the water component to be emulsified. Then, it is stirred and mixed with the residual (1 3 ) solution to which (6), (7), and (8) have been added to obtain a misty hair styling agent (Mist) » (Formulation Example 3: misty gas gelatinization) Hair supplement) (mixed component) (% by mass) (1) POE (20) eucalyptus ether 5 (2) ΡΟΕ (30) · ΡΟΡ (7) phytosterol 1 (3) Mineral oil 3 (4) ΡΟΡ 梨 pear Sugar alcohol 4 (UNIOL HS-1600D; made from eucalyptus oil) (5) ΡΟΕ(9)·ΡΟΡ(2) random copolymer dimethyl ether 1 (6) methacryloyloxyethyl carboxybetaine . Methyl propylene phthalate 3 alkyl copolymer (YUKAFORMER 301; Mitsubishi Chemical Co., Ltd.) (7) Polyethylene glycol (molecular weight 400) 0.25 -32- 201124168 (8) Polyethylene glycol (molecular weight 1000) 0.2 5 (9) Butanediol 2 (1〇) Amino acid 0.05 (11) LPG 50 (12) Spice 〇 (13) Ethyl p-hydroxybenzoate 0.2 (14) Ion exchange water is added to 100 Manufacturing method Take part (14) Add (9), (1), (2), (4), (7), (1〇), and (13) in order, and add the melt (8) to the water component. (4) and (12) are sequentially added to the oil component in (3). The oil component is added to the water component portion while stirring, and emulsification is performed. Then, it is stirred and mixed with the residual (14) solution to which (5) and (6) have been added, and after filling (1 1 ), a misty gas gel conditioner (aerogel spray) can be obtained (formulation example) 4: misty hair lotion) (% by mass) 3 0.5 4 3 2 (mixed component) (1) ΡΟΕ (25) cetyl ether (2) P〇E (10) eucalyptus ether (3) pentaerythritol IV (ethylhexanoic acid) ester (4) polyethylene glycol (molecular weight 400) (5) cerium oxide/polyether-based polyurethane resin-33- 201124168 (YUDOZOL PUD; 曰本NSC(股) (6) vinylpyrrolidone·vinyl acetate copolymer (PVP/VA S-630; manufactured by ISP) (7) Polyethylene glycol (molecular weight 6000) 0.5 (8) Diglycerol 1 (9) Hydrolyzed wheat protein 0.1 (10) Nitrogen gas 40 (11) Citric acid (food) 〇.1 (12) Perfume 0.1 (13) Phenoxyethanol 0.5 (14) Ion exchange water is added to 1 〇〇 Manufacturing method Take part (14) in order Add (8), (1), (2), (7), (9), (11), and (13) to form a water component. In (3), (I2) is sequentially added to become an oil component. While stirring, the oil component is added to the water component to be emulsified. Then, it is mixed with (4), (5^, (6) residual (1 4) solution, and the wall is filled with water (10) to obtain a misty gas gel conditioner (a gas gel spray). (Formulation Example 5: Foam Hair Conditioner) (mixed ingredients) (1) POE (20) cetyl ether (2) POE (60) hardened castor oil 〇.1 -34- 3 201124168 (3) Hydrogenation Polyisobutylene (4) POE (10) methyl glucoside (GLUCAM E-10; manufactured by LUBRIZOL Co., Ltd.) (5) Methacrylic oxiranyloxyethylcarboxybetaine. Alkyl methacrylate copolymerization (YUKAFORMER301; Mitsubishi Chemical Co., Ltd.) (6) Butanediol (7) Perfume (8) Ethanol (9) The method for producing ion-exchanged water is added in (8) in order (1), (2), ( 3) (5) and (7) Stirring at the same time to form the alcohol component. Add the solutions after (9) and (6), and mix and mix the whole material (mist). Industrial Applicability The hair styling cosmetic of the invention belongs to the aqueous system and has low hair styling ability, excellent hair styling ability, hair styling ability, and has the advantages of non-feeling, smoothness, and lightness of the finished hair style. 3 2 0.1 10 To 1 0 0, (4) ' Will be able to obtain a haze, and produce a sticky -35-

Claims (1)

25201124168 VII. Patent application scope 1. A cosmetic material for hair styling containing (a) a surfactant which is solid under normal 3 3 to 15 mass%, (b) (b,) a liquid at normal temperature Alkanediol poly(%) or (b2) a liquid polyol derivative at room temperature, (c) a film-forming polymer, and (d) a liquid oil, and the viscosity of the system is l〇, 〇〇〇mPa' Below s (25 ° c). 2. The cosmetic preparation for hair styling according to item 1 of the patent application is dissolved in water and/or an alcohol-based solvent. 3. The surfactant of the hair styling component of the hair styling ingredient of claim 1 is a nonionic surfactant. 4. The cosmetic material for hair styling according to item 1 of the patent application range is 20 or more in hardness (measured by a curd meter (25 ^ 4 〇〇 g' pressure-sensitive axis (diameter 1 mm) when entering the surface of the sample, the scale 5. The cosmetic material for hair styling according to item 1 of the patent application, wherein the component (b) is a polyethylene glycol having a mass average molecular weight of 20 0 to 900. 6 · As claimed in claim 1 Cosmetics for hair styling, the viscosity is below 100mPa.s (25t 'B type viscometer), and the spray is used as a mist when used. And B type viscosity, among which 'the charge department is -36- 201124168 IV. Representative diagram: (1) The representative representative of the case is: No. (2) The symbolic symbol of the representative figure is simple. 201124168 If there is a chemical formula in the case, please disclose the chemical formula that best shows the characteristics of the invention: None