CN104812703B - 具有改进形态的zsm-5晶体的合成 - Google Patents

具有改进形态的zsm-5晶体的合成 Download PDF

Info

Publication number
CN104812703B
CN104812703B CN201380061630.3A CN201380061630A CN104812703B CN 104812703 B CN104812703 B CN 104812703B CN 201380061630 A CN201380061630 A CN 201380061630A CN 104812703 B CN104812703 B CN 104812703B
Authority
CN
China
Prior art keywords
zsm
crystals
crystal
mixture
framework structure
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN201380061630.3A
Other languages
English (en)
Chinese (zh)
Other versions
CN104812703A (zh
Inventor
文伊赫·法兰克·赖
尼古拉斯·S·罗尔曼
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Technology and Engineering Co
Original Assignee
ExxonMobil Research and Engineering Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ExxonMobil Research and Engineering Co filed Critical ExxonMobil Research and Engineering Co
Publication of CN104812703A publication Critical patent/CN104812703A/zh
Application granted granted Critical
Publication of CN104812703B publication Critical patent/CN104812703B/zh
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/16—Alumino-silicates
    • B01J20/18—Synthetic zeolitic molecular sieves
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/3085—Chemical treatments not covered by groups B01J20/3007 - B01J20/3078
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/36—Pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C01B39/38—Type ZSM-5
    • C01B39/40—Type ZSM-5 using at least one organic template directing agent
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/42—Type ZSM-12

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Analytical Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Catalysts (AREA)
CN201380061630.3A 2012-12-07 2013-10-25 具有改进形态的zsm-5晶体的合成 Expired - Fee Related CN104812703B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201261734437P 2012-12-07 2012-12-07
US61/734,437 2012-12-07
PCT/US2013/066819 WO2014088723A1 (en) 2012-12-07 2013-10-25 Synthesis of zsm-5 crystals with improved morphology

Publications (2)

Publication Number Publication Date
CN104812703A CN104812703A (zh) 2015-07-29
CN104812703B true CN104812703B (zh) 2018-05-29

Family

ID=49578558

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201380061630.3A Expired - Fee Related CN104812703B (zh) 2012-12-07 2013-10-25 具有改进形态的zsm-5晶体的合成

Country Status (10)

Country Link
US (1) US9289755B2 (enExample)
EP (1) EP2928823B1 (enExample)
JP (1) JP6185598B2 (enExample)
KR (1) KR101950552B1 (enExample)
CN (1) CN104812703B (enExample)
CA (1) CA2891025C (enExample)
RU (1) RU2615689C2 (enExample)
SG (1) SG11201502434YA (enExample)
WO (1) WO2014088723A1 (enExample)
ZA (1) ZA201504048B (enExample)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP6326257B2 (ja) 2014-03-24 2018-05-16 日立造船株式会社 燃焼排ガス浄化用触媒、および燃焼排ガスの浄化方法
CN105000573B (zh) * 2015-06-26 2017-04-26 太原理工大学 一种由纳米晶粒组成的大块状多孔沸石及其制备方法
JP2017114755A (ja) * 2015-12-25 2017-06-29 ユニオン昭和株式会社 ゼオライト、及びその製造方法
KR102035397B1 (ko) * 2016-12-14 2019-10-23 서강대학교산학협력단 마이크로다공성 및 메조다공성 계층적 구조의 mfi 제올라이트, 이의 제조방법 및 이의 촉매 용도
US11572283B2 (en) * 2017-10-26 2023-02-07 China Petroleum & Chemical Corporation Molecular sieve having mesopores, preparation method therefor, and application thereof
RU2735849C1 (ru) * 2019-05-27 2020-11-09 Федеральное государственное бюджетное образовательное учреждение высшего образования "Московский государственный университет имени М.В. Ломоносова" (МГУ) Способ получения алюмосиликатного цеолита со структурой mtw (типа zsm-12)
RU2707179C1 (ru) * 2019-08-02 2019-11-25 федеральное государственное автономное образовательное учреждение высшего образования "Российский государственный университет нефти и газа (национальный исследовательский университет) имени И.М. Губкина" Бицеолитный катализатор изомеризации ароматических углеводородов с-8
JP7687032B2 (ja) * 2021-04-15 2025-06-03 東ソー株式会社 Ｍｔｗ型ゼオライト
CN114684832A (zh) * 2022-04-18 2022-07-01 瑞声光电科技(常州)有限公司 一种核壳分子筛及其制备方法、吸声材料和扬声器

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101935053A (zh) * 2009-06-30 2011-01-05 中国石油化工股份有限公司石油化工科学研究院 一种zsm-5沸石及其合成方法

Family Cites Families (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3354078A (en) 1965-02-04 1967-11-21 Mobil Oil Corp Catalytic conversion with a crystalline aluminosilicate activated with a metallic halide
GB1275745A (en) 1968-06-10 1972-05-24 Nyegaard & Co As 2,4,6-triiodobenzoic acid derivatives and their use as x-ray contrast agents
US3832449A (en) 1971-03-18 1974-08-27 Mobil Oil Corp Crystalline zeolite zsm{14 12
US4088605A (en) * 1976-09-24 1978-05-09 Mobil Oil Corporation ZSM-5 containing aluminum-free shells on its surface
US4375458A (en) * 1977-08-17 1983-03-01 Mobil Oil Corporation Synthesis of large crystallite zeolites
US4537758A (en) 1979-03-21 1985-08-27 Mobil Oil Corporation Process for preparing highly siliceous porous ZSM-12 type crystalline material
US4452769A (en) 1979-03-21 1984-06-05 Mobil Oil Corporation Method of preparing crystalline zeolite
JPS5973425A (ja) * 1982-10-20 1984-04-25 Asahi Chem Ind Co Ltd 結晶性アルミノシリケ−トの製造方法
CA1209121A (en) * 1983-07-12 1986-08-05 Guenter H. Kuehl Preparation of zeolite zsm-12
AU579656B2 (en) * 1984-09-04 1988-12-01 W.R. Grace & Co.-Conn. Process to make small crystallites of zsm-5
GB9122498D0 (en) * 1991-10-23 1991-12-04 Exxon Chemical Patents Inc Process for preparing uniform mfitype zeolite crystals
ZA933879B (en) * 1992-06-05 1993-12-27 Exxon Chemical Patents Inc ZSM-5-zeolite
US5369071A (en) * 1992-12-11 1994-11-29 Mobil Oil Corporation Manufacture of improved catalyst
CA2222585C (en) * 1995-06-06 2007-10-02 Mobil Oil Corporation Large crystal zsm-5, its synthesis and use
US6180550B1 (en) 1998-12-22 2001-01-30 Mobile Oil Corporation Small crystal ZSM-5, its synthesis and use
US6277355B1 (en) * 1999-07-13 2001-08-21 Exxonmobil Chemical Patents Inc. Synthesis of ZSM-5 and ZSM-11
US6893624B2 (en) 2002-11-15 2005-05-17 Exxonmobil Chemical Patents Inc. High activity small crystal ZSM-12
US7976822B2 (en) * 2004-11-19 2011-07-12 Agency For Science, Technology And Research Crystalline oxide material and its synthesis
CN101332995B (zh) * 2008-03-25 2010-12-01 北京惠尔三吉绿色化学科技有限公司 一种高岭土原位晶化zsm-5分子筛制备方法
JP2010126397A (ja) * 2008-11-27 2010-06-10 Jgc Catalysts & Chemicals Ltd ペンタシル型ゼオライトの合成方法
CN102464334B (zh) * 2010-11-18 2013-10-16 中国石油天然气股份有限公司 一种制备丝光沸石/zsm-5复合分子筛的方法

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101935053A (zh) * 2009-06-30 2011-01-05 中国石油化工股份有限公司石油化工科学研究院 一种zsm-5沸石及其合成方法

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
"Rapid crystallization and morphological adjustment of zeolite ZSM-5 in nonionic emulsions";Ying Zhang et al.;《Journal of Solid State Chemistry》;20101019;第184卷(第1期);第2.1节、3.2节、图2 *

Also Published As

Publication number Publication date
KR20150091518A (ko) 2015-08-11
KR101950552B1 (ko) 2019-02-20
JP6185598B2 (ja) 2017-08-23
US20140162867A1 (en) 2014-06-12
CA2891025A1 (en) 2014-06-12
EP2928823B1 (en) 2019-03-06
RU2615689C2 (ru) 2017-04-06
EP2928823A1 (en) 2015-10-14
CA2891025C (en) 2019-07-30
ZA201504048B (en) 2016-04-28
US9289755B2 (en) 2016-03-22
SG11201502434YA (en) 2015-04-29
JP2016503749A (ja) 2016-02-08
CN104812703A (zh) 2015-07-29
WO2014088723A1 (en) 2014-06-12
RU2015123925A (ru) 2017-01-12

Similar Documents

Publication Publication Date Title
CN104812703B (zh) 具有改进形态的zsm-5晶体的合成
CN101801848B (zh) 高活性zsm-48的合成
TWI490167B (zh) 使用奈米結晶質ｚｓｍ－５晶種製備ｚｓｍ－５沸石之方法
CN104870367B (zh) 小晶体zsm‑5,其合成和用途
RU2688542C2 (ru) Новый синтетический кристаллический материал EMM-26, его получение и применение
CN107690420B (zh) 铝硅酸盐沸石ssz-98的合成
WO2018227849A1 (zh) 分子筛scm-14、其合成方法及其用途
CN108622914B (zh) 在模板1,6-双(甲基哌啶鎓)己烷二氢氧化物的存在下合成izm-2沸石的方法
EP2461907B1 (en) Synthesis and use of zsm-12
CA2745398A1 (en) High activity mtt framework type molecular sieves
CN108622915B (zh) 在模板1,6-双(甲基哌啶鎓)己烷二溴化物的存在下合成izm-2沸石的方法
CN104379257B (zh) 具有euo骨架类型的结晶分子筛的合成
CN104884387B (zh) Zsm‑5的合成
US20250001404A1 (en) Method of Synthesizing Aluminum-Rich Molecular Sieve of *MRE Framework Type
CN108602683A (zh) 小晶体、高比表面积的emm-30沸石、其合成及用途
CN104812704A (zh) 具有不寻常形态的mfi
CN118591508A (zh) Emm-70沸石组合物、合成和用途
CN117957197A (zh) Emm-63铝硅酸盐沸石、合成及用途

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20180529

CF01 Termination of patent right due to non-payment of annual fee