SG11201502434YA - Synthesis of zsm-5 crystals with improved morphology - Google Patents

Synthesis of zsm-5 crystals with improved morphology

Info

Publication number
SG11201502434YA
SG11201502434YA SG11201502434YA SG11201502434YA SG11201502434YA SG 11201502434Y A SG11201502434Y A SG 11201502434YA SG 11201502434Y A SG11201502434Y A SG 11201502434YA SG 11201502434Y A SG11201502434Y A SG 11201502434YA SG 11201502434Y A SG11201502434Y A SG 11201502434YA
Authority
SG
Singapore
Prior art keywords
zsm
crystals
synthesis
improved morphology
morphology
Prior art date
Application number
SG11201502434YA
Inventor
Wenyih Frank Lai
Nicholas S Rollman
Original Assignee
Exxonmobil Res & Eng Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxonmobil Res & Eng Co filed Critical Exxonmobil Res & Eng Co
Publication of SG11201502434YA publication Critical patent/SG11201502434YA/en

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/16Alumino-silicates
    • B01J20/18Synthetic zeolitic molecular sieves
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30Processes for preparing, regenerating, or reactivating
    • B01J20/3085Chemical treatments not covered by groups B01J20/3007 - B01J20/3078
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/36Pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C01B39/38Type ZSM-5
    • C01B39/40Type ZSM-5 using at least one organic template directing agent
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/42Type ZSM-12

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Analytical Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Catalysts (AREA)
SG11201502434YA 2012-12-07 2013-10-25 Synthesis of zsm-5 crystals with improved morphology SG11201502434YA (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201261734437P 2012-12-07 2012-12-07
PCT/US2013/066819 WO2014088723A1 (en) 2012-12-07 2013-10-25 Synthesis of zsm-5 crystals with improved morphology

Publications (1)

Publication Number Publication Date
SG11201502434YA true SG11201502434YA (en) 2015-04-29

Family

ID=49578558

Family Applications (1)

Application Number Title Priority Date Filing Date
SG11201502434YA SG11201502434YA (en) 2012-12-07 2013-10-25 Synthesis of zsm-5 crystals with improved morphology

Country Status (10)

Country Link
US (1) US9289755B2 (en)
EP (1) EP2928823B1 (en)
JP (1) JP6185598B2 (en)
KR (1) KR101950552B1 (en)
CN (1) CN104812703B (en)
CA (1) CA2891025C (en)
RU (1) RU2615689C2 (en)
SG (1) SG11201502434YA (en)
WO (1) WO2014088723A1 (en)
ZA (1) ZA201504048B (en)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP6326257B2 (en) * 2014-03-24 2018-05-16 日立造船株式会社 Combustion exhaust gas purification catalyst and combustion exhaust gas purification method
CN105000573B (en) * 2015-06-26 2017-04-26 太原理工大学 Large block porous zeolite composed of nano-crystal grains and preparation method thereof
JP2017114755A (en) * 2015-12-25 2017-06-29 ユニオン昭和株式会社 Zeolite and manufacturing method therefor
US11001503B2 (en) 2016-12-14 2021-05-11 Sogang University Research Foundation MFI zeolite with microporous and mesoporous hierarchical structure, preparation method therefor, and catalytic use thereof
TW201917097A (en) * 2017-10-26 2019-05-01 大陸商中國石油化工科技開發有限公司 Molecular sieve having mesopores, preparation method therefor, and application thereof particularly relating to a high silica-alumina ratio molecular sieve having mesopores
RU2735849C1 (en) * 2019-05-27 2020-11-09 Федеральное государственное бюджетное образовательное учреждение высшего образования "Московский государственный университет имени М.В. Ломоносова" (МГУ) Method of producing aluminosilicate zeolite with mtw structure (zsm-12 type)
RU2707179C1 (en) * 2019-08-02 2019-11-25 федеральное государственное автономное образовательное учреждение высшего образования "Российский государственный университет нефти и газа (национальный исследовательский университет) имени И.М. Губкина" Bizeolitic catalyst for isomerization of aromatic hydrocarbons c-8
CN114684832A (en) 2022-04-18 2022-07-01 瑞声光电科技(常州)有限公司 Core-shell molecular sieve, preparation method thereof, sound absorption material and loudspeaker

Family Cites Families (22)

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US3354078A (en) 1965-02-04 1967-11-21 Mobil Oil Corp Catalytic conversion with a crystalline aluminosilicate activated with a metallic halide
GB1275745A (en) 1968-06-10 1972-05-24 Nyegaard & Co As 2,4,6-triiodobenzoic acid derivatives and their use as x-ray contrast agents
US3832449A (en) 1971-03-18 1974-08-27 Mobil Oil Corp Crystalline zeolite zsm{14 12
US4088605A (en) * 1976-09-24 1978-05-09 Mobil Oil Corporation ZSM-5 containing aluminum-free shells on its surface
US4375458A (en) * 1977-08-17 1983-03-01 Mobil Oil Corporation Synthesis of large crystallite zeolites
US4537758A (en) 1979-03-21 1985-08-27 Mobil Oil Corporation Process for preparing highly siliceous porous ZSM-12 type crystalline material
US4452769A (en) 1979-03-21 1984-06-05 Mobil Oil Corporation Method of preparing crystalline zeolite
JPS5973425A (en) * 1982-10-20 1984-04-25 Asahi Chem Ind Co Ltd Preparation of crystalline aluminosilicate
CA1209121A (en) * 1983-07-12 1986-08-05 Guenter H. Kuehl Preparation of zeolite zsm-12
AU579656B2 (en) * 1984-09-04 1988-12-01 W.R. Grace & Co.-Conn. Process to make small crystallites of zsm-5
GB9122498D0 (en) * 1991-10-23 1991-12-04 Exxon Chemical Patents Inc Process for preparing uniform mfitype zeolite crystals
ZA933879B (en) * 1992-06-05 1993-12-27 Exxon Chemical Patents Inc ZSM-5-zeolite
US5369071A (en) * 1992-12-11 1994-11-29 Mobil Oil Corporation Manufacture of improved catalyst
DE69620612T2 (en) * 1995-06-06 2003-02-06 Exxonmobil Oil Corp LARGE CRYSTALINE ZEOLITH ZSM-5, ITS SYNTHESIS AND USE
US6180550B1 (en) * 1998-12-22 2001-01-30 Mobile Oil Corporation Small crystal ZSM-5, its synthesis and use
US6277355B1 (en) * 1999-07-13 2001-08-21 Exxonmobil Chemical Patents Inc. Synthesis of ZSM-5 and ZSM-11
US6893624B2 (en) 2002-11-15 2005-05-17 Exxonmobil Chemical Patents Inc. High activity small crystal ZSM-12
EP1824782A1 (en) * 2004-11-19 2007-08-29 Agency for Science, Technology and Research Crystalline oxide material and its synthesis
CN101332995B (en) 2008-03-25 2010-12-01 北京惠尔三吉绿色化学科技有限公司 Method for preparing kaolin in-situ crystallization ZSM-5 molecular sieve
JP2010126397A (en) * 2008-11-27 2010-06-10 Jgc Catalysts & Chemicals Ltd Method for synthesizing pentasil type zeolite
CN101935053B (en) * 2009-06-30 2012-07-18 中国石油化工股份有限公司 ZSM-5 zeolite and synthesis method thereof
CN102464334B (en) * 2010-11-18 2013-10-16 中国石油天然气股份有限公司 Method for preparing mordenite/ Zeolite Socony Mobil (ZSM)-5 composite molecular sieve

Also Published As

Publication number Publication date
JP2016503749A (en) 2016-02-08
CN104812703B (en) 2018-05-29
CN104812703A (en) 2015-07-29
RU2015123925A (en) 2017-01-12
ZA201504048B (en) 2016-04-28
EP2928823A1 (en) 2015-10-14
JP6185598B2 (en) 2017-08-23
KR101950552B1 (en) 2019-02-20
KR20150091518A (en) 2015-08-11
CA2891025C (en) 2019-07-30
EP2928823B1 (en) 2019-03-06
RU2615689C2 (en) 2017-04-06
US20140162867A1 (en) 2014-06-12
WO2014088723A1 (en) 2014-06-12
US9289755B2 (en) 2016-03-22
CA2891025A1 (en) 2014-06-12

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