CN104674350A - 一种多铁性甲酸盐类LiCo(COOH)3单晶材料及其制备方法 - Google Patents
一种多铁性甲酸盐类LiCo(COOH)3单晶材料及其制备方法 Download PDFInfo
- Publication number
- CN104674350A CN104674350A CN201510102060.9A CN201510102060A CN104674350A CN 104674350 A CN104674350 A CN 104674350A CN 201510102060 A CN201510102060 A CN 201510102060A CN 104674350 A CN104674350 A CN 104674350A
- Authority
- CN
- China
- Prior art keywords
- cooh
- lico
- multiferroic
- beaker
- formate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229910013733 LiCo Inorganic materials 0.000 title claims abstract description 47
- 239000013078 crystal Substances 0.000 title claims abstract description 35
- 239000000463 material Substances 0.000 title claims abstract description 25
- 238000002360 preparation method Methods 0.000 title claims abstract description 19
- BDAGIHXWWSANSR-UHFFFAOYSA-M Formate Chemical compound [O-]C=O BDAGIHXWWSANSR-UHFFFAOYSA-M 0.000 title claims abstract description 15
- 239000000126 substance Substances 0.000 claims abstract description 4
- 150000001875 compounds Chemical class 0.000 claims abstract description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 claims description 32
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 23
- PFQLIVQUKOIJJD-UHFFFAOYSA-L cobalt(ii) formate Chemical compound [Co+2].[O-]C=O.[O-]C=O PFQLIVQUKOIJJD-UHFFFAOYSA-L 0.000 claims description 19
- 239000012153 distilled water Substances 0.000 claims description 18
- XKPJKVVZOOEMPK-UHFFFAOYSA-M lithium;formate Chemical compound [Li+].[O-]C=O XKPJKVVZOOEMPK-UHFFFAOYSA-M 0.000 claims description 17
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 11
- 238000007789 sealing Methods 0.000 claims description 9
- 239000007788 liquid Substances 0.000 claims description 8
- 238000002156 mixing Methods 0.000 claims description 8
- 229920006395 saturated elastomer Polymers 0.000 claims description 8
- 238000003756 stirring Methods 0.000 claims description 8
- 238000001291 vacuum drying Methods 0.000 claims description 8
- 238000005406 washing Methods 0.000 claims description 8
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 6
- 238000004140 cleaning Methods 0.000 claims description 4
- 229910021645 metal ion Inorganic materials 0.000 claims description 4
- 229960000935 dehydrated alcohol Drugs 0.000 claims description 3
- 239000008367 deionised water Substances 0.000 claims description 3
- 229910021641 deionized water Inorganic materials 0.000 claims description 3
- 238000009413 insulation Methods 0.000 claims description 3
- 238000004506 ultrasonic cleaning Methods 0.000 claims description 2
- 125000000896 monocarboxylic acid group Chemical group 0.000 claims 11
- 238000000034 method Methods 0.000 abstract description 7
- 238000001027 hydrothermal synthesis Methods 0.000 abstract description 6
- 239000012621 metal-organic framework Substances 0.000 abstract description 6
- 239000007791 liquid phase Substances 0.000 abstract description 4
- 230000003287 optical effect Effects 0.000 abstract description 2
- 239000004065 semiconductor Substances 0.000 abstract description 2
- COHAIAIOWLZHFV-UHFFFAOYSA-K [Co+2].[Li+].C(=O)[O-].C(=O)[O-].C(=O)[O-] Chemical compound [Co+2].[Li+].C(=O)[O-].C(=O)[O-].C(=O)[O-] COHAIAIOWLZHFV-UHFFFAOYSA-K 0.000 abstract 1
- 239000003153 chemical reaction reagent Substances 0.000 abstract 1
- 239000013065 commercial product Substances 0.000 abstract 1
- 239000000047 product Substances 0.000 abstract 1
- 238000000026 X-ray photoelectron spectrum Methods 0.000 description 2
- 238000002425 crystallisation Methods 0.000 description 2
- 230000008025 crystallization Effects 0.000 description 2
- 239000007775 ferroic material Substances 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 239000002243 precursor Substances 0.000 description 2
- IGRCWJPBLWGNPX-UHFFFAOYSA-N 3-(2-chlorophenyl)-n-(4-chlorophenyl)-n,5-dimethyl-1,2-oxazole-4-carboxamide Chemical compound C=1C=C(Cl)C=CC=1N(C)C(=O)C1=C(C)ON=C1C1=CC=CC=C1Cl IGRCWJPBLWGNPX-UHFFFAOYSA-N 0.000 description 1
- 238000002441 X-ray diffraction Methods 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000005621 ferroelectricity Effects 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 230000005690 magnetoelectric effect Effects 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 238000010899 nucleation Methods 0.000 description 1
- 230000006911 nucleation Effects 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000000634 powder X-ray diffraction Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C30—CRYSTAL GROWTH
- C30B—SINGLE-CRYSTAL GROWTH; UNIDIRECTIONAL SOLIDIFICATION OF EUTECTIC MATERIAL OR UNIDIRECTIONAL DEMIXING OF EUTECTOID MATERIAL; REFINING BY ZONE-MELTING OF MATERIAL; PRODUCTION OF A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; SINGLE CRYSTALS OR HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; AFTER-TREATMENT OF SINGLE CRYSTALS OR A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; APPARATUS THEREFOR
- C30B29/00—Single crystals or homogeneous polycrystalline material with defined structure characterised by the material or by their shape
- C30B29/54—Organic compounds
-
- C—CHEMISTRY; METALLURGY
- C30—CRYSTAL GROWTH
- C30B—SINGLE-CRYSTAL GROWTH; UNIDIRECTIONAL SOLIDIFICATION OF EUTECTIC MATERIAL OR UNIDIRECTIONAL DEMIXING OF EUTECTOID MATERIAL; REFINING BY ZONE-MELTING OF MATERIAL; PRODUCTION OF A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; SINGLE CRYSTALS OR HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; AFTER-TREATMENT OF SINGLE CRYSTALS OR A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; APPARATUS THEREFOR
- C30B7/00—Single-crystal growth from solutions using solvents which are liquid at normal temperature, e.g. aqueous solutions
- C30B7/10—Single-crystal growth from solutions using solvents which are liquid at normal temperature, e.g. aqueous solutions by application of pressure, e.g. hydrothermal processes
-
- C—CHEMISTRY; METALLURGY
- C30—CRYSTAL GROWTH
- C30B—SINGLE-CRYSTAL GROWTH; UNIDIRECTIONAL SOLIDIFICATION OF EUTECTIC MATERIAL OR UNIDIRECTIONAL DEMIXING OF EUTECTOID MATERIAL; REFINING BY ZONE-MELTING OF MATERIAL; PRODUCTION OF A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; SINGLE CRYSTALS OR HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; AFTER-TREATMENT OF SINGLE CRYSTALS OR A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; APPARATUS THEREFOR
- C30B7/00—Single-crystal growth from solutions using solvents which are liquid at normal temperature, e.g. aqueous solutions
- C30B7/14—Single-crystal growth from solutions using solvents which are liquid at normal temperature, e.g. aqueous solutions the crystallising materials being formed by chemical reactions in the solution
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Crystallography & Structural Chemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Liquid Crystal Substances (AREA)
Abstract
Description
Claims (6)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201510102060.9A CN104674350B (zh) | 2015-03-09 | 2015-03-09 | 一种多铁性甲酸盐类LiCo(COOH)3单晶材料及其制备方法 |
Applications Claiming Priority (1)
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CN201510102060.9A CN104674350B (zh) | 2015-03-09 | 2015-03-09 | 一种多铁性甲酸盐类LiCo(COOH)3单晶材料及其制备方法 |
Publications (2)
Publication Number | Publication Date |
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CN104674350A true CN104674350A (zh) | 2015-06-03 |
CN104674350B CN104674350B (zh) | 2017-12-12 |
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CN201510102060.9A Active CN104674350B (zh) | 2015-03-09 | 2015-03-09 | 一种多铁性甲酸盐类LiCo(COOH)3单晶材料及其制备方法 |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105926040A (zh) * | 2016-06-24 | 2016-09-07 | 哈尔滨工业大学 | 一种以二异丙胺卤盐为前体材料的有机-无机杂化钙钛矿结构晶体的制备方法 |
CN113235165A (zh) * | 2021-04-26 | 2021-08-10 | 上海大学 | 一种新型Fe1-xTMxS单晶材料的制备方法 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE4123062A1 (de) * | 1991-07-12 | 1993-01-14 | Degussa | Verfahren zur herstellung von calciumformiat |
CN1358166A (zh) * | 1999-06-26 | 2002-07-10 | 拜尔公司 | 无尘甲酸钙 |
-
2015
- 2015-03-09 CN CN201510102060.9A patent/CN104674350B/zh active Active
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE4123062A1 (de) * | 1991-07-12 | 1993-01-14 | Degussa | Verfahren zur herstellung von calciumformiat |
CN1358166A (zh) * | 1999-06-26 | 2002-07-10 | 拜尔公司 | 无尘甲酸钙 |
Non-Patent Citations (6)
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105926040A (zh) * | 2016-06-24 | 2016-09-07 | 哈尔滨工业大学 | 一种以二异丙胺卤盐为前体材料的有机-无机杂化钙钛矿结构晶体的制备方法 |
CN105926040B (zh) * | 2016-06-24 | 2019-01-04 | 哈尔滨工业大学 | 一种以二异丙胺卤盐为前体材料的有机-无机杂化钙钛矿结构晶体的制备方法 |
CN113235165A (zh) * | 2021-04-26 | 2021-08-10 | 上海大学 | 一种新型Fe1-xTMxS单晶材料的制备方法 |
CN113235165B (zh) * | 2021-04-26 | 2022-10-14 | 上海大学 | 一种Fe1-xTMxS单晶材料的制备方法 |
Also Published As
Publication number | Publication date |
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CN104674350B (zh) | 2017-12-12 |
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Effective date of registration: 20190606 Address after: 311200 Zidong Village, Heshang Town, Xiaoshan District, Hangzhou City, Zhejiang Province Patentee after: Hangzhou Xiaohe New Materials Technology Co.,Ltd. Address before: 233010 Pioneering Building 316, Huineng Small and Micro Enterprises Pioneering Center, 1750 Shengli West Road, Yuhui District, Bengbu City, Anhui Province Patentee before: BENGBU DINGRONG TECHNOLOGY INFORMATION CONSULTING Co.,Ltd. |
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Effective date of registration: 20240503 Address after: Room 3342, Building 7, No. 1197, Bin'an Road, Changhe Street, Binjiang District, Hangzhou, Zhejiang 310000, China (Zhejiang) Pilot Free Trade Zone Patentee after: Hangzhou Chuangming Zhicai Intelligent Technology Co.,Ltd. Country or region after: China Address before: 311200 he Shang Zhen Zi Dong Cun, Xiaoshan District, Hangzhou City, Zhejiang Province Patentee before: Hangzhou Xiaohe New Materials Technology Co.,Ltd. Country or region before: China |