CN104788476A - 一种金属-有机框架DMCaF单晶材料及其制备方法 - Google Patents
一种金属-有机框架DMCaF单晶材料及其制备方法 Download PDFInfo
- Publication number
- CN104788476A CN104788476A CN201510101661.8A CN201510101661A CN104788476A CN 104788476 A CN104788476 A CN 104788476A CN 201510101661 A CN201510101661 A CN 201510101661A CN 104788476 A CN104788476 A CN 104788476A
- Authority
- CN
- China
- Prior art keywords
- dmcaf
- metal
- organic framework
- beaker
- monocrystal material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000463 material Substances 0.000 title claims abstract description 27
- 239000012621 metal-organic framework Substances 0.000 title claims abstract description 21
- 238000002360 preparation method Methods 0.000 title claims abstract description 16
- 239000013078 crystal Substances 0.000 claims description 24
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 23
- 239000012153 distilled water Substances 0.000 claims description 18
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 11
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 claims description 10
- 229910001628 calcium chloride Inorganic materials 0.000 claims description 10
- 239000001110 calcium chloride Substances 0.000 claims description 10
- 238000007789 sealing Methods 0.000 claims description 9
- 239000011575 calcium Substances 0.000 claims description 8
- 239000007788 liquid Substances 0.000 claims description 8
- 238000002156 mixing Methods 0.000 claims description 8
- 229920006395 saturated elastomer Polymers 0.000 claims description 8
- 238000003756 stirring Methods 0.000 claims description 8
- 238000001291 vacuum drying Methods 0.000 claims description 8
- 238000005406 washing Methods 0.000 claims description 8
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 6
- 238000004140 cleaning Methods 0.000 claims description 4
- 229910021645 metal ion Inorganic materials 0.000 claims description 4
- 229960000935 dehydrated alcohol Drugs 0.000 claims description 3
- 239000008367 deionised water Substances 0.000 claims description 3
- 229910021641 deionized water Inorganic materials 0.000 claims description 3
- 239000000126 substance Substances 0.000 claims description 3
- 150000001875 compounds Chemical class 0.000 claims description 2
- 239000000203 mixture Substances 0.000 claims description 2
- 238000004506 ultrasonic cleaning Methods 0.000 claims description 2
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-dimethylformamide Substances CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 claims 3
- 238000000034 method Methods 0.000 abstract description 7
- 238000001027 hydrothermal synthesis Methods 0.000 abstract description 6
- 239000007791 liquid phase Substances 0.000 abstract description 4
- 230000003287 optical effect Effects 0.000 abstract description 2
- 239000004065 semiconductor Substances 0.000 abstract description 2
- 239000003153 chemical reaction reagent Substances 0.000 abstract 1
- WHQSYGRFZMUQGQ-UHFFFAOYSA-N n,n-dimethylformamide;hydrate Chemical compound O.CN(C)C=O WHQSYGRFZMUQGQ-UHFFFAOYSA-N 0.000 description 7
- 238000002441 X-ray diffraction Methods 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 238000002425 crystallisation Methods 0.000 description 2
- 230000008025 crystallization Effects 0.000 description 2
- 239000007775 ferroic material Substances 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 239000002243 precursor Substances 0.000 description 2
- IGRCWJPBLWGNPX-UHFFFAOYSA-N 3-(2-chlorophenyl)-n-(4-chlorophenyl)-n,5-dimethyl-1,2-oxazole-4-carboxamide Chemical compound C=1C=C(Cl)C=CC=1N(C)C(=O)C1=C(C)ON=C1C1=CC=CC=C1Cl IGRCWJPBLWGNPX-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- BDAGIHXWWSANSR-UHFFFAOYSA-M Formate Chemical compound [O-]C=O BDAGIHXWWSANSR-UHFFFAOYSA-M 0.000 description 1
- 238000000026 X-ray photoelectron spectrum Methods 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000005621 ferroelectricity Effects 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 230000005690 magnetoelectric effect Effects 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 238000010899 nucleation Methods 0.000 description 1
- 230000006911 nucleation Effects 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000000634 powder X-ray diffraction Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F3/00—Compounds containing elements of Groups 2 or 12 of the Periodic Table
- C07F3/003—Compounds containing elements of Groups 2 or 12 of the Periodic Table without C-Metal linkages
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Crystals, And After-Treatments Of Crystals (AREA)
Abstract
Description
Claims (6)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201510101661.8A CN104788476B (zh) | 2015-03-09 | 2015-03-09 | 一种金属‑有机框架DMCaF单晶材料及其制备方法 |
Applications Claiming Priority (1)
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CN201510101661.8A CN104788476B (zh) | 2015-03-09 | 2015-03-09 | 一种金属‑有机框架DMCaF单晶材料及其制备方法 |
Publications (2)
Publication Number | Publication Date |
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CN104788476A true CN104788476A (zh) | 2015-07-22 |
CN104788476B CN104788476B (zh) | 2017-06-16 |
Family
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CN201510101661.8A Active CN104788476B (zh) | 2015-03-09 | 2015-03-09 | 一种金属‑有机框架DMCaF单晶材料及其制备方法 |
Country Status (1)
Country | Link |
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CN (1) | CN104788476B (zh) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106637414A (zh) * | 2016-12-15 | 2017-05-10 | 浙江理工大学 | 一种金属‑有机框架DMMnF/甲酸锶异质结单晶光学材料及其制备方法 |
-
2015
- 2015-03-09 CN CN201510101661.8A patent/CN104788476B/zh active Active
Non-Patent Citations (1)
Title |
---|
ANDREA ROSSIN, ET AL.: "Hydrogen Uptake by {H[Mg(HCOO)3]NHMe2}∞ and Determination of Its H2 Adsorption Sites through Monte Carlo Simulations", 《LANGMUIR》 * |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106637414A (zh) * | 2016-12-15 | 2017-05-10 | 浙江理工大学 | 一种金属‑有机框架DMMnF/甲酸锶异质结单晶光学材料及其制备方法 |
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Publication number | Publication date |
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CN104788476B (zh) | 2017-06-16 |
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PB01 | Publication | ||
EXSB | Decision made by sipo to initiate substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
GR01 | Patent grant | ||
TR01 | Transfer of patent right |
Effective date of registration: 20200730 Address after: 423, floor 4, block a, Xinhua future city building, No. 175, Litang Road, Changping District, Beijing 102200 Patentee after: Li Qiannan Address before: 310018, No. 5, 2 Avenue, Baiyang Poplar Street, Xiasha, Zhejiang, Hangzhou Patentee before: ZHEJIANG SCI-TECH University |
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TR01 | Transfer of patent right | ||
TR01 | Transfer of patent right |
Effective date of registration: 20201123 Address after: 226400 Yangkou Port Economic Development Zone, Nantong City, Jiangsu Province (Changsha Town, Rudong County) Patentee after: Jiangsu Yangkou Port Construction and Development Group Co.,Ltd. Address before: 423, floor 4, block a, Xinhua future city building, No. 175, Litang Road, Changping District, Beijing 102200 Patentee before: Li Qiannan |
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TR01 | Transfer of patent right | ||
PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: A metal-organic framework DMCaF single crystal material and its preparation method Effective date of registration: 20221230 Granted publication date: 20170616 Pledgee: Jiangsu Rudong Rural Commercial Bank Co.,Ltd. Pledgor: Jiangsu Yangkou Port Construction and Development Group Co.,Ltd. Registration number: Y2022980029322 |
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PE01 | Entry into force of the registration of the contract for pledge of patent right |