CN104651942B - 一种多铁性甲酸盐类LiMn(COOH)3单晶材料及其制备方法 - Google Patents
一种多铁性甲酸盐类LiMn(COOH)3单晶材料及其制备方法 Download PDFInfo
- Publication number
- CN104651942B CN104651942B CN201510102057.7A CN201510102057A CN104651942B CN 104651942 B CN104651942 B CN 104651942B CN 201510102057 A CN201510102057 A CN 201510102057A CN 104651942 B CN104651942 B CN 104651942B
- Authority
- CN
- China
- Prior art keywords
- cooh
- limn
- monocrystalline
- beaker
- preparation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 229910015645 LiMn Inorganic materials 0.000 title claims abstract description 45
- 125000000896 monocarboxylic acid group Chemical group 0.000 title claims abstract description 43
- 239000000463 material Substances 0.000 title claims abstract description 22
- 238000002360 preparation method Methods 0.000 title claims abstract description 18
- BDAGIHXWWSANSR-UHFFFAOYSA-M Formate Chemical compound [O-]C=O BDAGIHXWWSANSR-UHFFFAOYSA-M 0.000 title claims abstract description 12
- 239000013078 crystal Substances 0.000 claims abstract description 27
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 29
- HYFPVPNWNRFTMP-UHFFFAOYSA-N formic acid;manganese Chemical compound [Mn].OC=O HYFPVPNWNRFTMP-UHFFFAOYSA-N 0.000 claims description 18
- XKPJKVVZOOEMPK-UHFFFAOYSA-M lithium;formate Chemical compound [Li+].[O-]C=O XKPJKVVZOOEMPK-UHFFFAOYSA-M 0.000 claims description 17
- 239000012153 distilled water Substances 0.000 claims description 16
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 11
- 239000007788 liquid Substances 0.000 claims description 9
- 238000007789 sealing Methods 0.000 claims description 9
- 239000011259 mixed solution Substances 0.000 claims description 8
- 238000003756 stirring Methods 0.000 claims description 8
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 6
- 238000004140 cleaning Methods 0.000 claims description 4
- 239000011572 manganese Substances 0.000 claims description 4
- 239000005416 organic matter Substances 0.000 claims description 4
- 238000001291 vacuum drying Methods 0.000 claims description 4
- 239000008367 deionised water Substances 0.000 claims description 3
- 229910021641 deionized water Inorganic materials 0.000 claims description 3
- 229910052748 manganese Inorganic materials 0.000 claims description 3
- 229910021645 metal ion Inorganic materials 0.000 claims description 3
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 claims 3
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 claims 2
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 claims 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims 1
- 235000019253 formic acid Nutrition 0.000 claims 1
- 238000010025 steaming Methods 0.000 claims 1
- 239000000047 product Substances 0.000 abstract description 16
- 238000001027 hydrothermal synthesis Methods 0.000 abstract description 7
- 238000000034 method Methods 0.000 abstract description 7
- 239000007791 liquid phase Substances 0.000 abstract description 4
- 239000000126 substance Substances 0.000 abstract description 4
- 238000003860 storage Methods 0.000 abstract description 3
- 239000003795 chemical substances by application Substances 0.000 abstract description 2
- 239000013065 commercial product Substances 0.000 abstract description 2
- 150000001875 compounds Chemical class 0.000 abstract description 2
- 239000004065 semiconductor Substances 0.000 abstract description 2
- KNZRPKMDWRVAFQ-UHFFFAOYSA-K lithium manganese(2+) triformate Chemical compound [Mn+2].C(=O)[O-].[Li+].C(=O)[O-].C(=O)[O-] KNZRPKMDWRVAFQ-UHFFFAOYSA-K 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 239000012621 metal-organic framework Substances 0.000 description 5
- WHQSYGRFZMUQGQ-UHFFFAOYSA-N n,n-dimethylformamide;hydrate Chemical compound O.CN(C)C=O WHQSYGRFZMUQGQ-UHFFFAOYSA-N 0.000 description 5
- 238000000026 X-ray photoelectron spectrum Methods 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 230000005621 ferroelectricity Effects 0.000 description 2
- 239000007775 ferroic material Substances 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 229910052744 lithium Inorganic materials 0.000 description 2
- 239000012071 phase Substances 0.000 description 2
- IGRCWJPBLWGNPX-UHFFFAOYSA-N 3-(2-chlorophenyl)-n-(4-chlorophenyl)-n,5-dimethyl-1,2-oxazole-4-carboxamide Chemical compound C=1C=C(Cl)C=CC=1N(C)C(=O)C1=C(C)ON=C1C1=CC=CC=C1Cl IGRCWJPBLWGNPX-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 238000002441 X-ray diffraction Methods 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 235000019628 coolness Nutrition 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 150000004675 formic acid derivatives Chemical class 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000000634 powder X-ray diffraction Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000036632 reaction speed Effects 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 229910001428 transition metal ion Inorganic materials 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C30—CRYSTAL GROWTH
- C30B—SINGLE-CRYSTAL GROWTH; UNIDIRECTIONAL SOLIDIFICATION OF EUTECTIC MATERIAL OR UNIDIRECTIONAL DEMIXING OF EUTECTOID MATERIAL; REFINING BY ZONE-MELTING OF MATERIAL; PRODUCTION OF A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; SINGLE CRYSTALS OR HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; AFTER-TREATMENT OF SINGLE CRYSTALS OR A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; APPARATUS THEREFOR
- C30B29/00—Single crystals or homogeneous polycrystalline material with defined structure characterised by the material or by their shape
- C30B29/54—Organic compounds
-
- C—CHEMISTRY; METALLURGY
- C30—CRYSTAL GROWTH
- C30B—SINGLE-CRYSTAL GROWTH; UNIDIRECTIONAL SOLIDIFICATION OF EUTECTIC MATERIAL OR UNIDIRECTIONAL DEMIXING OF EUTECTOID MATERIAL; REFINING BY ZONE-MELTING OF MATERIAL; PRODUCTION OF A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; SINGLE CRYSTALS OR HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; AFTER-TREATMENT OF SINGLE CRYSTALS OR A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; APPARATUS THEREFOR
- C30B7/00—Single-crystal growth from solutions using solvents which are liquid at normal temperature, e.g. aqueous solutions
- C30B7/14—Single-crystal growth from solutions using solvents which are liquid at normal temperature, e.g. aqueous solutions the crystallising materials being formed by chemical reactions in the solution
Abstract
Description
Claims (3)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201510102057.7A CN104651942B (zh) | 2015-03-09 | 2015-03-09 | 一种多铁性甲酸盐类LiMn(COOH)3单晶材料及其制备方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201510102057.7A CN104651942B (zh) | 2015-03-09 | 2015-03-09 | 一种多铁性甲酸盐类LiMn(COOH)3单晶材料及其制备方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN104651942A CN104651942A (zh) | 2015-05-27 |
CN104651942B true CN104651942B (zh) | 2018-03-20 |
Family
ID=53243563
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201510102057.7A Active CN104651942B (zh) | 2015-03-09 | 2015-03-09 | 一种多铁性甲酸盐类LiMn(COOH)3单晶材料及其制备方法 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN104651942B (zh) |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3679907A (en) * | 1970-08-03 | 1972-07-25 | Bell Telephone Labor Inc | Lithium formate nonlinear devices |
DE4123062A1 (de) * | 1991-07-12 | 1993-01-14 | Degussa | Verfahren zur herstellung von calciumformiat |
DE19807996A1 (de) * | 1998-02-26 | 1999-09-02 | Bayer Ag | Stückiges Calciumformiat |
DE19929346A1 (de) * | 1999-06-26 | 2000-12-28 | Bayer Ag | Staubfreies Calciumformiat |
-
2015
- 2015-03-09 CN CN201510102057.7A patent/CN104651942B/zh active Active
Non-Patent Citations (2)
Title |
---|
Alkali Metal Ion Templated Transition Metal Formate Framework Materials: Synthesis, Crystal Structures, Ion Migration, and Magnetism;Espen Eikeland,et al.;《Inorganic Chemistry》;20140918;第53卷;第10178-10188页 * |
Tuning the Structure and Magnetism of Heterometallic Sodium(1+)-Cobalt(2+) Formate Coordination Polymers by Varying the Metal Ratio and Solvents;Jiong-Peng Zhao, et al.;《Inorganic Chemistry》;20130305;第52卷;第2862-2869页 * |
Also Published As
Publication number | Publication date |
---|---|
CN104651942A (zh) | 2015-05-27 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
EP3708540B1 (en) | A preparation method for zeolitic imidazolate frameworks | |
CN102286007B (zh) | 一种金属多氮唑框架材料的无溶剂合成方法 | |
CN105384188A (zh) | 一种溴铅铯粉体制备方法 | |
CN104788505B (zh) | 一种金属‑有机框架单晶外延生长的DMCoF/DMMnF异质结材料及其制备方法 | |
CN101830918B (zh) | 一种多氮唑锌/镉框架材料的合成方法 | |
CN104674350B (zh) | 一种多铁性甲酸盐类LiCo(COOH)3单晶材料及其制备方法 | |
WO2014024149A2 (en) | Process for the colloidal synthesis of lithium iron phosphate | |
CN101428857B (zh) | 一种钼酸锌纳米材料的诱导控制合成方法 | |
CN113955792B (zh) | 一种卤铜铯晶体的制备方法 | |
CN110128134B (zh) | 一种以掺铌钛酸锶为基底的钛酸铅薄膜的制备方法 | |
CN104651942B (zh) | 一种多铁性甲酸盐类LiMn(COOH)3单晶材料及其制备方法 | |
CN104788476B (zh) | 一种金属‑有机框架DMCaF单晶材料及其制备方法 | |
CN104788506B (zh) | 一种金属‑有机框架单晶外延生长的DMMnF/DMCoF异质结材料及其制备方法 | |
CN104788507B (zh) | 一种镁掺杂金属‑有机框架DMMg0.5Mn0.5F单晶材料及其制备方法 | |
CN104725434B (zh) | 一种镁掺杂金属‑有机框架DMMg0.5Co0.5F单晶材料及其制备方法 | |
CN104674334B (zh) | 一种甲酸盐类LiMg(COOH)3单晶光学材料及其制备方法 | |
CN104788504B (zh) | 一种成分可控钴掺杂金属‑有机框架DMMnF单晶材料及其制备方法 | |
CN104762662A (zh) | 一种铜掺杂金属-有机框架DMCoF单晶材料及其制备方法 | |
CN104788475B (zh) | 一种金属‑有机框架DMMgF单晶材料及其制备方法 | |
CN104762661A (zh) | 一种铜掺杂金属-有机框架DMMnF单晶材料及其制备方法 | |
CN102614737B (zh) | 一种金属有机骨架材料储气释放的方法 | |
CN104674351B (zh) | 一种甲酸盐类LiCa(COOH)3单晶光学材料及其制备方法 | |
CN104788497A (zh) | 一种锂掺杂金属-有机框架DMMnF单晶材料及其制备方法 | |
Lee et al. | Crystallization of ionically bonded organic metal halide hybrids | |
CN104726937B (zh) | 一种甲酸钙单晶光学材料及其制备方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
GR01 | Patent grant | ||
GR01 | Patent grant | ||
TR01 | Transfer of patent right | ||
TR01 | Transfer of patent right |
Effective date of registration: 20191115 Address after: No.1, Chuangye building, 1750 Shengli West Road, Yuhui District, Bengbu City, Anhui Province Patentee after: Bengbu xiaoshuren Software Technology Co., Ltd Address before: 322204 Zhejiang County of Pujiang Province Huang Zhai Zhen Yong Zhai village a Central District No. 69 Patentee before: Wang Junliu |
|
TR01 | Transfer of patent right |
Effective date of registration: 20200714 Address after: 423, floor 4, block a, Xinhua future city building, No. 175, Litang Road, Changping District, Beijing 102200 Patentee after: Li Qiannan Address before: No.1, Chuangye building, 1750 Shengli West Road, Yuhui District, Bengbu City, Anhui Province Patentee before: Bengbu xiaoshuren Software Technology Co.,Ltd. |
|
TR01 | Transfer of patent right | ||
TR01 | Transfer of patent right | ||
TR01 | Transfer of patent right |
Effective date of registration: 20201120 Address after: 274000 high tech chemical industry park, Mudan District, Heze City, Shandong Province (north of Huaihe East Road) Patentee after: Heze Far East Qiangya New Material Co., Ltd Address before: 423, floor 4, block a, Xinhua future city building, No. 175, Litang Road, Changping District, Beijing 102200 Patentee before: Li Qiannan |
|
TR01 | Transfer of patent right | ||
TR01 | Transfer of patent right |
Effective date of registration: 20201209 Address after: Yishan Economic Development Zone Patentee after: Shandong Minghao Chemical Co.,Ltd. Address before: 274000 high tech chemical industry park, Mudan District, Heze City, Shandong Province (north of Huaihe East Road) Patentee before: Heze Far East Qiangya New Material Co., Ltd |
|
TR01 | Transfer of patent right | ||
TR01 | Transfer of patent right |
Effective date of registration: 20210903 Address after: 276400 North East of Yufeng road and west of the Second Ring Road, economic development zone, Linyi City, Shandong Province Patentee after: Shandong Zhongbang Packaging Printing Co.,Ltd. Address before: Yishan Economic Development Zone Patentee before: Shandong Minghao Chemical Co.,Ltd. |
|
PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Multiferroic formate limn (COOH)3single crystal material and preparation method thereof Effective date of registration: 20211009 Granted publication date: 20180320 Pledgee: Shandong Yishui Rural Commercial Bank Co., Ltd Pledgor: Shandong Zhongbang Packaging Printing Co.,Ltd. Registration number: Y2021980010407 |