CN104788475B - 一种金属‑有机框架DMMgF单晶材料及其制备方法 - Google Patents
一种金属‑有机框架DMMgF单晶材料及其制备方法 Download PDFInfo
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- CN104788475B CN104788475B CN201510101697.6A CN201510101697A CN104788475B CN 104788475 B CN104788475 B CN 104788475B CN 201510101697 A CN201510101697 A CN 201510101697A CN 104788475 B CN104788475 B CN 104788475B
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- dmmgf
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- monocrystal
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- 239000000463 material Substances 0.000 title claims abstract description 22
- 238000002360 preparation method Methods 0.000 title claims abstract description 16
- 229910052751 metal Inorganic materials 0.000 title abstract description 4
- 239000002184 metal Substances 0.000 title abstract description 4
- 239000013078 crystal Substances 0.000 claims abstract description 25
- 239000000126 substance Substances 0.000 claims abstract description 6
- 150000001875 compounds Chemical class 0.000 claims abstract description 3
- 239000000203 mixture Substances 0.000 claims abstract description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-dimethylformamide Substances CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 claims description 31
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 29
- 239000012153 distilled water Substances 0.000 claims description 16
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 claims description 12
- 238000004140 cleaning Methods 0.000 claims description 12
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 11
- 239000012621 metal-organic framework Substances 0.000 claims description 10
- 239000007788 liquid Substances 0.000 claims description 8
- 239000011777 magnesium Substances 0.000 claims description 8
- 239000011259 mixed solution Substances 0.000 claims description 8
- 238000003756 stirring Methods 0.000 claims description 8
- 238000005406 washing Methods 0.000 claims description 8
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 6
- 238000007789 sealing Methods 0.000 claims description 5
- 239000005416 organic matter Substances 0.000 claims description 4
- 239000008367 deionised water Substances 0.000 claims description 3
- 229910021641 deionized water Inorganic materials 0.000 claims description 3
- 229910001629 magnesium chloride Inorganic materials 0.000 claims description 3
- 229910021645 metal ion Inorganic materials 0.000 claims description 3
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 3
- 238000001291 vacuum drying Methods 0.000 claims description 3
- 238000004821 distillation Methods 0.000 claims description 2
- 229910052749 magnesium Inorganic materials 0.000 claims description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims 1
- 238000005660 chlorination reaction Methods 0.000 claims 1
- 239000000047 product Substances 0.000 abstract description 11
- 238000000034 method Methods 0.000 abstract description 9
- 238000001027 hydrothermal synthesis Methods 0.000 abstract description 7
- 239000007791 liquid phase Substances 0.000 abstract description 4
- 239000003795 chemical substances by application Substances 0.000 abstract description 2
- 239000013065 commercial product Substances 0.000 abstract description 2
- 239000004065 semiconductor Substances 0.000 abstract description 2
- CBOCVOKPQGJKKJ-UHFFFAOYSA-L Calcium formate Chemical compound [Ca+2].[O-]C=O.[O-]C=O CBOCVOKPQGJKKJ-UHFFFAOYSA-L 0.000 abstract 1
- 229940044172 calcium formate Drugs 0.000 abstract 1
- 235000019255 calcium formate Nutrition 0.000 abstract 1
- 239000004281 calcium formate Substances 0.000 abstract 1
- 235000011147 magnesium chloride Nutrition 0.000 description 8
- 238000002441 X-ray diffraction Methods 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 230000005621 ferroelectricity Effects 0.000 description 2
- 239000007775 ferroic material Substances 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- IGRCWJPBLWGNPX-UHFFFAOYSA-N 3-(2-chlorophenyl)-n-(4-chlorophenyl)-n,5-dimethyl-1,2-oxazole-4-carboxamide Chemical compound C=1C=C(Cl)C=CC=1N(C)C(=O)C1=C(C)ON=C1C1=CC=CC=C1Cl IGRCWJPBLWGNPX-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 238000000026 X-ray photoelectron spectrum Methods 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- GMDNUWQNDQDBNQ-UHFFFAOYSA-L magnesium;diformate Chemical compound [Mg+2].[O-]C=O.[O-]C=O GMDNUWQNDQDBNQ-UHFFFAOYSA-L 0.000 description 1
- 230000005690 magnetoelectric effect Effects 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 230000006911 nucleation Effects 0.000 description 1
- 238000010899 nucleation Methods 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000000634 powder X-ray diffraction Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000036632 reaction speed Effects 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 229910001428 transition metal ion Inorganic materials 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Crystals, And After-Treatments Of Crystals (AREA)
Abstract
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Priority Applications (1)
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CN201510101697.6A CN104788475B (zh) | 2015-03-09 | 2015-03-09 | 一种金属‑有机框架DMMgF单晶材料及其制备方法 |
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CN201510101697.6A CN104788475B (zh) | 2015-03-09 | 2015-03-09 | 一种金属‑有机框架DMMgF单晶材料及其制备方法 |
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CN104788475A CN104788475A (zh) | 2015-07-22 |
CN104788475B true CN104788475B (zh) | 2017-06-13 |
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Effective date of registration: 20200722 Address after: 423, floor 4, block a, Xinhua future city building, No. 175, Litang Road, Changping District, Beijing 102200 Patentee after: Li Qiannan Address before: 310018, No. 5, 2 Avenue, Baiyang Poplar Street, Xiasha, Zhejiang, Hangzhou Patentee before: Zhejiang University of Technology |
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Effective date of registration: 20201130 Address after: 221700 Fengxian County Economic Development Zone, Xuzhou City, the north side of the weft Road, two, Jiangsu Patentee after: JIANGSU JUJIE ELECTROMECHANICAL Co.,Ltd. Address before: 423, floor 4, block a, Xinhua future city building, No. 175, Litang Road, Changping District, Beijing 102200 Patentee before: Li Qiannan |
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Application publication date: 20150722 Assignee: Fengxian wisdom automation equipment Research Institute Co., Ltd Assignor: JIANGSU JUJIE ELECTROMECHANICAL Co.,Ltd. Contract record no.: X2021980015758 Denomination of invention: Metal organic frame dmmgf single crystal material and preparation method thereof Granted publication date: 20170613 License type: Exclusive License Record date: 20211222 |