CN104788504A - 一种成分可控钴掺杂金属-有机框架DMMnF单晶材料及其制备方法 - Google Patents
一种成分可控钴掺杂金属-有机框架DMMnF单晶材料及其制备方法 Download PDFInfo
- Publication number
- CN104788504A CN104788504A CN201510101593.5A CN201510101593A CN104788504A CN 104788504 A CN104788504 A CN 104788504A CN 201510101593 A CN201510101593 A CN 201510101593A CN 104788504 A CN104788504 A CN 104788504A
- Authority
- CN
- China
- Prior art keywords
- dmmnf
- organic framework
- cobalt
- beaker
- monocrystalline
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000463 material Substances 0.000 title claims abstract description 31
- 229910017052 cobalt Inorganic materials 0.000 title claims abstract description 28
- 239000010941 cobalt Substances 0.000 title claims abstract description 28
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 title claims abstract description 28
- 239000012621 metal-organic framework Substances 0.000 title claims abstract description 25
- 238000002360 preparation method Methods 0.000 title claims abstract description 18
- 239000011572 manganese Substances 0.000 claims abstract description 9
- 229910052748 manganese Inorganic materials 0.000 claims abstract description 6
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims abstract description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 23
- 239000013078 crystal Substances 0.000 claims description 21
- GVPFVAHMJGGAJG-UHFFFAOYSA-L cobalt dichloride Chemical compound [Cl-].[Cl-].[Co+2] GVPFVAHMJGGAJG-UHFFFAOYSA-L 0.000 claims description 18
- 239000012153 distilled water Substances 0.000 claims description 18
- CNFDGXZLMLFIJV-UHFFFAOYSA-L manganese(II) chloride tetrahydrate Chemical compound O.O.O.O.[Cl-].[Cl-].[Mn+2] CNFDGXZLMLFIJV-UHFFFAOYSA-L 0.000 claims description 18
- 239000000203 mixture Substances 0.000 claims description 14
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 11
- 238000007789 sealing Methods 0.000 claims description 9
- 239000007788 liquid Substances 0.000 claims description 8
- 229920006395 saturated elastomer Polymers 0.000 claims description 8
- 238000003756 stirring Methods 0.000 claims description 8
- 238000001291 vacuum drying Methods 0.000 claims description 8
- 238000005406 washing Methods 0.000 claims description 8
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 6
- 238000004140 cleaning Methods 0.000 claims description 4
- 229910021645 metal ion Inorganic materials 0.000 claims description 4
- 229960000935 dehydrated alcohol Drugs 0.000 claims description 3
- 239000008367 deionised water Substances 0.000 claims description 3
- 229910021641 deionized water Inorganic materials 0.000 claims description 3
- 238000004506 ultrasonic cleaning Methods 0.000 claims description 2
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-dimethylformamide Substances CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 claims 3
- 238000000034 method Methods 0.000 abstract description 7
- 238000001027 hydrothermal synthesis Methods 0.000 abstract description 6
- 239000007791 liquid phase Substances 0.000 abstract description 4
- 230000003287 optical effect Effects 0.000 abstract description 2
- 230000008569 process Effects 0.000 abstract description 2
- 239000004065 semiconductor Substances 0.000 abstract description 2
- 239000003153 chemical reaction reagent Substances 0.000 abstract 1
- WHQSYGRFZMUQGQ-UHFFFAOYSA-N n,n-dimethylformamide;hydrate Chemical compound O.CN(C)C=O WHQSYGRFZMUQGQ-UHFFFAOYSA-N 0.000 description 7
- 230000005690 magnetoelectric effect Effects 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- 238000002441 X-ray diffraction Methods 0.000 description 2
- 238000000026 X-ray photoelectron spectrum Methods 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 238000002425 crystallisation Methods 0.000 description 2
- 230000008025 crystallization Effects 0.000 description 2
- 239000007775 ferroic material Substances 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 239000002243 precursor Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- IGRCWJPBLWGNPX-UHFFFAOYSA-N 3-(2-chlorophenyl)-n-(4-chlorophenyl)-n,5-dimethyl-1,2-oxazole-4-carboxamide Chemical compound C=1C=C(Cl)C=CC=1N(C)C(=O)C1=C(C)ON=C1C1=CC=CC=C1Cl IGRCWJPBLWGNPX-UHFFFAOYSA-N 0.000 description 1
- BDAGIHXWWSANSR-UHFFFAOYSA-M Formate Chemical compound [O-]C=O BDAGIHXWWSANSR-UHFFFAOYSA-M 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 230000005621 ferroelectricity Effects 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 238000010899 nucleation Methods 0.000 description 1
- 230000006911 nucleation Effects 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
Landscapes
- Inorganic Compounds Of Heavy Metals (AREA)
Abstract
Description
Claims (5)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201510101593.5A CN104788504B (zh) | 2015-03-09 | 2015-03-09 | 一种成分可控钴掺杂金属‑有机框架DMMnF单晶材料及其制备方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201510101593.5A CN104788504B (zh) | 2015-03-09 | 2015-03-09 | 一种成分可控钴掺杂金属‑有机框架DMMnF单晶材料及其制备方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN104788504A true CN104788504A (zh) | 2015-07-22 |
CN104788504B CN104788504B (zh) | 2017-09-01 |
Family
ID=53553734
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201510101593.5A Active CN104788504B (zh) | 2015-03-09 | 2015-03-09 | 一种成分可控钴掺杂金属‑有机框架DMMnF单晶材料及其制备方法 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN104788504B (zh) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106637414A (zh) * | 2016-12-15 | 2017-05-10 | 浙江理工大学 | 一种金属‑有机框架DMMnF/甲酸锶异质结单晶光学材料及其制备方法 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102134747A (zh) * | 2011-01-18 | 2011-07-27 | 浙江理工大学 | 一种制备铈掺杂硼酸铝纳米线的方法 |
CN102962036A (zh) * | 2012-10-30 | 2013-03-13 | 中国科学院大连化学物理研究所 | 基于过渡金属钴的多孔金属有机骨架材料及其制备方法 |
-
2015
- 2015-03-09 CN CN201510101593.5A patent/CN104788504B/zh active Active
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102134747A (zh) * | 2011-01-18 | 2011-07-27 | 浙江理工大学 | 一种制备铈掺杂硼酸铝纳米线的方法 |
CN102962036A (zh) * | 2012-10-30 | 2013-03-13 | 中国科学院大连化学物理研究所 | 基于过渡金属钴的多孔金属有机骨架材料及其制备方法 |
Non-Patent Citations (1)
Title |
---|
PRASHANT JAIN 等,: "Multiferroic Behavior Associated with an Order-Disorder Hydrogen Bonding Transition in Metal-Organic Frameworks (MOFs) with the Perovskite ABX3 Architecture", 《JOURNAL OF THE AMERICAN CHEMICAL SOCIETY》 * |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106637414A (zh) * | 2016-12-15 | 2017-05-10 | 浙江理工大学 | 一种金属‑有机框架DMMnF/甲酸锶异质结单晶光学材料及其制备方法 |
Also Published As
Publication number | Publication date |
---|---|
CN104788504B (zh) | 2017-09-01 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN104141166B (zh) | 大尺寸钙钛矿结构甲胺溴铅晶体的制备方法 | |
CN102286007B (zh) | 一种金属多氮唑框架材料的无溶剂合成方法 | |
CN105384188A (zh) | 一种溴铅铯粉体制备方法 | |
CN104788505A (zh) | 一种金属-有机框架单晶外延生长的DMCoF/DMMnF异质结材料及其制备方法 | |
CN104674350A (zh) | 一种多铁性甲酸盐类LiCo(COOH)3单晶材料及其制备方法 | |
CN104788504A (zh) | 一种成分可控钴掺杂金属-有机框架DMMnF单晶材料及其制备方法 | |
CN111647167A (zh) | 一种新型金属有机框架材料Zn-MOF及其合成方法、应用 | |
CN101654408B (zh) | 无水酒石酸锌铁电功能材料及其制备方法 | |
CN104788507A (zh) | 一种镁掺杂金属-有机框架DMMg0.5Mn0.5F单晶材料及其制备方法 | |
CN104725434A (zh) | 一种镁掺杂金属-有机框架DMMg0.5Co0.5F单晶材料及其制备方法 | |
CN104788506A (zh) | 一种金属-有机框架单晶外延生长的DMMnF/DMCoF异质结材料及其制备方法 | |
CN104788476A (zh) | 一种金属-有机框架DMCaF单晶材料及其制备方法 | |
CN104762662A (zh) | 一种铜掺杂金属-有机框架DMCoF单晶材料及其制备方法 | |
CN104762661A (zh) | 一种铜掺杂金属-有机框架DMMnF单晶材料及其制备方法 | |
CN104788497A (zh) | 一种锂掺杂金属-有机框架DMMnF单晶材料及其制备方法 | |
CN104651942B (zh) | 一种多铁性甲酸盐类LiMn(COOH)3单晶材料及其制备方法 | |
CN104788475A (zh) | 一种金属-有机框架DMMgF单晶材料及其制备方法 | |
CN104674334A (zh) | 一种甲酸盐类LiMg(COOH)3单晶光学材料及其制备方法 | |
CN104726937B (zh) | 一种甲酸钙单晶光学材料及其制备方法 | |
CN1322607C (zh) | 锂二次电池正极材料-正交晶系LiMnO2的制备方法 | |
CN104674351B (zh) | 一种甲酸盐类LiCa(COOH)3单晶光学材料及其制备方法 | |
CN113667457B (zh) | 具有二次谐波效应的铁电材料及其制备方法 | |
CN104610050B (zh) | 一种水合邻氯扁桃酸锰铁电功能材料及其制备方法 | |
Li et al. | The Precursor Chemistry and High Performance Hybrid perovskites Solar Cells | |
CN103449509A (zh) | 一种亚微米钛酸镉晶体及其制备方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
EXSB | Decision made by sipo to initiate substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
GR01 | Patent grant | ||
GR01 | Patent grant | ||
TR01 | Transfer of patent right | ||
TR01 | Transfer of patent right |
Effective date of registration: 20181129 Address after: 233010 Pioneering Building 316, Huineng Small and Micro Enterprises Pioneering Center, 1750 Shengli West Road, Yuhui District, Bengbu City, Anhui Province Patentee after: BENGBU DINGRONG TECHNOLOGY INFORMATION CONSULTING Co.,Ltd. Address before: 322200 Dafang Village, Dafang Township, Pujiang County, Jinhua City, Zhejiang Province, 63 Patentee before: Chen Qian |
|
TR01 | Transfer of patent right | ||
TR01 | Transfer of patent right |
Effective date of registration: 20190531 Address after: 311265 Zidong Village, Heshang Town, Xiaoshan District, Hangzhou City, Zhejiang Province Patentee after: Hangzhou Xiaohe New Materials Technology Co.,Ltd. Address before: 233010 Pioneering Building 316, Huineng Small and Micro Enterprises Pioneering Center, 1750 Shengli West Road, Yuhui District, Bengbu City, Anhui Province Patentee before: BENGBU DINGRONG TECHNOLOGY INFORMATION CONSULTING Co.,Ltd. |
|
TR01 | Transfer of patent right | ||
TR01 | Transfer of patent right |
Effective date of registration: 20240503 Address after: Room 3342, Building 7, No. 1197, Bin'an Road, Changhe Street, Binjiang District, Hangzhou, Zhejiang 310000, China (Zhejiang) Pilot Free Trade Zone Patentee after: Hangzhou Chuangming Zhicai Intelligent Technology Co.,Ltd. Country or region after: China Address before: 311265 Zidong Village, Heshang Town, Xiaoshan District, Hangzhou City, Zhejiang Province Patentee before: Hangzhou Xiaohe New Materials Technology Co.,Ltd. Country or region before: China |