CN104662130B - 催化热解方法和由此形成的热解产物 - Google Patents

催化热解方法和由此形成的热解产物 Download PDF

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Publication number
CN104662130B
CN104662130B CN201380041665.0A CN201380041665A CN104662130B CN 104662130 B CN104662130 B CN 104662130B CN 201380041665 A CN201380041665 A CN 201380041665A CN 104662130 B CN104662130 B CN 104662130B
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China
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pyrolysis
catalyst
weight
reactor
biological material
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Expired - Fee Related
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Chinese (zh)
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CN104662130A (zh
Inventor
M.瓦西奇
M.H.普伦克
R.范杜伦
M.科赫
L.C.A.范登厄特拉尔
D.范德比克
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Albemarle Europe SPRL
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Albemarle Europe SPRL
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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B57/00—Other carbonising or coking processes; Features of destructive distillation processes in general
    • C10B57/04—Other carbonising or coking processes; Features of destructive distillation processes in general using charges of special composition
    • C10B57/06—Other carbonising or coking processes; Features of destructive distillation processes in general using charges of special composition containing additives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B49/00—Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated
    • C10B49/16—Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated with moving solid heat-carriers in divided form
    • C10B49/20—Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated with moving solid heat-carriers in divided form in dispersed form
    • C10B49/22—Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated with moving solid heat-carriers in divided form in dispersed form according to the "fluidised bed" technique
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B53/00—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form
    • C10B53/02—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form of cellulose-containing material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10C—WORKING-UP PITCH, ASPHALT, BITUMEN, TAR; PYROLIGNEOUS ACID
    • C10C5/00—Production of pyroligneous acid distillation of wood, dry distillation of organic waste
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
    • C10G1/08—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal with moving catalysts
    • C10G1/086—Characterised by the catalyst used
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/02—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1011—Biomass
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L2200/00—Components of fuel compositions
    • C10L2200/04—Organic compounds
    • C10L2200/0461—Fractions defined by their origin
    • C10L2200/0469—Renewables or materials of biological origin
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L2290/00—Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
    • C10L2290/02—Combustion or pyrolysis
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00—Technologies for the production of fuel of non-fossil origin
    • Y02E50/10—Biofuels, e.g. bio-diesel
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00—Technologies for the production of fuel of non-fossil origin
    • Y02E50/30—Fuel from waste, e.g. synthetic alcohol or diesel
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Combustion & Propulsion (AREA)
  • Dispersion Chemistry (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
CN201380041665.0A 2012-08-08 2013-08-07 催化热解方法和由此形成的热解产物 Expired - Fee Related CN104662130B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201261681072P 2012-08-08 2012-08-08
US61/681072 2012-08-08
PCT/EP2013/066533 WO2014023759A1 (en) 2012-08-08 2013-08-07 Catalytic pyrolysis process and pyrolysis products so formed

Publications (2)

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CN104662130A CN104662130A (zh) 2015-05-27
CN104662130B true CN104662130B (zh) 2017-10-03

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Country Link
US (1) US20150203761A1 (enExample)
EP (1) EP2882826B1 (enExample)
JP (1) JP6342394B2 (enExample)
CN (1) CN104662130B (enExample)
BR (1) BR112015002751B1 (enExample)
CA (1) CA2878709A1 (enExample)
DK (1) DK2882826T3 (enExample)
ES (1) ES2715320T3 (enExample)
HU (1) HUE042245T2 (enExample)
IN (1) IN2015DN00285A (enExample)
PL (1) PL2882826T3 (enExample)
WO (1) WO2014023759A1 (enExample)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106047385A (zh) * 2016-07-20 2016-10-26 昆明理工大学 添加聚磷酸铵微胶囊和硼酸的生物质热解工艺
CN108841442A (zh) * 2018-06-08 2018-11-20 安徽省宝天农贸有限公司 一种高品质芝麻油的制备方法
CN108865402A (zh) * 2018-06-08 2018-11-23 安徽省宝天农贸有限公司 一种菜籽油的制备方法
CN109762583B (zh) * 2019-01-22 2020-02-21 广西壮族自治区林业科学研究院 一种生物质热解制备气、液、炭产品的方法
CN110129086B (zh) * 2019-03-13 2021-07-13 盐城工业职业技术学院 一种催化裂解植物沥青制备生物航煤的方法
KR102337176B1 (ko) * 2019-06-11 2021-12-10 한국에너지기술연구원 연속식 공정으로 업그레이딩된 열분해유의 대량생산 방법 및 연속식 공정 장치
US20240092642A1 (en) * 2020-11-25 2024-03-21 Carbonx B.V. New production method of carbon (nano)-structures from pyrolysis oil
CN113311093B (zh) * 2021-06-23 2024-09-20 海南大学 防火封堵材料实验室热解及烟气收集装置与分析方法
CN115029148B (zh) * 2022-06-09 2023-06-06 武汉轻工大学 一种生物质和聚烯烃塑料催化热解联产高品质生物油和介孔生物炭的方法

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1527799A (zh) * 2001-02-09 2004-09-08 ŵ�����˹ɷ����޹�˾ 制备阴离子粘土的方法
CN1956782A (zh) * 2004-04-26 2007-05-02 阿尔伯麦尔荷兰有限公司 含添加剂的阴离子粘土的制备方法
CN101511971A (zh) * 2006-07-17 2009-08-19 BIOeCON国际控股有限公司 细颗粒状生物质的催化热解以及降低固体生物质颗粒粒度的方法
EP2105486A1 (en) * 2008-03-25 2009-09-30 KiOR Inc. Low total acid number bio-crude
CN102361963A (zh) * 2009-03-24 2012-02-22 科伊奥股份有限公司 高质生物油的高产率生产方法
US20120047794A1 (en) * 2011-03-10 2012-03-01 Kior, Inc. Biomass Pretreatment for Fast Pyrolysis to Liquids
CN102574114A (zh) * 2009-04-22 2012-07-11 科伊奥股份有限公司 活性受控的热解催化剂

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7901568B2 (en) * 2006-05-05 2011-03-08 Kior Inc. Process for converting carbon-based energy carrier material
WO2010071677A1 (en) * 2008-12-16 2010-06-24 Kior Inc. Pretreatment of biomass with carbonaceous material
US8293952B2 (en) 2010-03-31 2012-10-23 Exxonmobil Research And Engineering Company Methods for producing pyrolysis products
US8921628B2 (en) * 2011-03-10 2014-12-30 Kior, Inc. Refractory mixed-metal oxides and spinel compositions for thermo-catalytic conversion of biomass

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1527799A (zh) * 2001-02-09 2004-09-08 ŵ�����˹ɷ����޹�˾ 制备阴离子粘土的方法
CN1956782A (zh) * 2004-04-26 2007-05-02 阿尔伯麦尔荷兰有限公司 含添加剂的阴离子粘土的制备方法
CN101511971A (zh) * 2006-07-17 2009-08-19 BIOeCON国际控股有限公司 细颗粒状生物质的催化热解以及降低固体生物质颗粒粒度的方法
EP2105486A1 (en) * 2008-03-25 2009-09-30 KiOR Inc. Low total acid number bio-crude
CN102361963A (zh) * 2009-03-24 2012-02-22 科伊奥股份有限公司 高质生物油的高产率生产方法
CN102574114A (zh) * 2009-04-22 2012-07-11 科伊奥股份有限公司 活性受控的热解催化剂
US20120047794A1 (en) * 2011-03-10 2012-03-01 Kior, Inc. Biomass Pretreatment for Fast Pyrolysis to Liquids

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Publication number Publication date
BR112015002751A2 (pt) 2018-04-10
CN104662130A (zh) 2015-05-27
JP2015524507A (ja) 2015-08-24
DK2882826T3 (en) 2019-04-01
US20150203761A1 (en) 2015-07-23
WO2014023759A1 (en) 2014-02-13
JP6342394B2 (ja) 2018-06-13
HUE042245T2 (hu) 2019-06-28
BR112015002751B1 (pt) 2020-04-14
EP2882826B1 (en) 2018-12-12
CA2878709A1 (en) 2014-02-13
PL2882826T3 (pl) 2019-07-31
ES2715320T3 (es) 2019-06-03
IN2015DN00285A (enExample) 2015-06-12
EP2882826A1 (en) 2015-06-17

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