CN104487463B - 制备具有提高的生产率的聚丙烯的方法 - Google Patents

制备具有提高的生产率的聚丙烯的方法 Download PDF

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Publication number
CN104487463B
CN104487463B CN201380038758.8A CN201380038758A CN104487463B CN 104487463 B CN104487463 B CN 104487463B CN 201380038758 A CN201380038758 A CN 201380038758A CN 104487463 B CN104487463 B CN 104487463B
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polypropylene
range
fraction
reactor
propylene homopolymer
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CN104487463A (zh
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沃尔夫冈·内斯尔
迪特里希·格洛格尔
托马斯·赫里
马蒂纳·桑德霍泽
格雷戈里·波特
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Borealis GmbH
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/647—Catalysts containing a specific non-metal or metal-free compound
    • C08F4/649—Catalysts containing a specific non-metal or metal-free compound organic
    • C08F4/6491—Catalysts containing a specific non-metal or metal-free compound organic hydrocarbon
    • C08F4/6492—Catalysts containing a specific non-metal or metal-free compound organic hydrocarbon containing aliphatic unsaturation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652—Pretreating with metals or metal-containing compounds
    • C08F4/654—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof
    • C08F4/6543—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof halides of magnesium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C08L23/14—Copolymers of propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Polymerisation Methods In General (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Laminated Bodies (AREA)
CN201380038758.8A 2012-08-07 2013-07-30 制备具有提高的生产率的聚丙烯的方法 Active CN104487463B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP121795470 2012-08-07
EP12179547 2012-08-07
PCT/EP2013/065944 WO2014023603A1 (en) 2012-08-07 2013-07-30 Process for the preparation of polypropylene with improved productivity

Publications (2)

Publication Number Publication Date
CN104487463A CN104487463A (zh) 2015-04-01
CN104487463B true CN104487463B (zh) 2017-04-05

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US (1) US9353203B2 (enExample)
EP (1) EP2882782B1 (enExample)
JP (1) JP6027240B2 (enExample)
KR (1) KR101706000B1 (enExample)
CN (1) CN104487463B (enExample)
AU (1) AU2013301726B2 (enExample)
BR (1) BR112015001309A2 (enExample)
CA (1) CA2878439C (enExample)
IN (1) IN2015DN00186A (enExample)
RU (1) RU2015104883A (enExample)
WO (1) WO2014023603A1 (enExample)
ZA (1) ZA201501080B (enExample)

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ES2651456T3 (es) 2013-08-14 2018-01-26 Borealis Ag Composición de propileno con mejor resistencia al impacto a baja temperatura
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EA031054B1 (ru) 2013-08-21 2018-11-30 Бореалис Аг Композиция полиолефина с высокой текучестью, жесткостью и ударной вязкостью
PL2853563T3 (pl) 2013-09-27 2016-12-30 Folie odpowiednie do przetwarzania BOPP z polimerów o wysokiej XS i wysokiej Tm
ES2568615T3 (es) 2013-10-11 2016-05-03 Borealis Ag Película para etiquetas orientada en la dirección de la máquina
ES2574428T3 (es) 2013-10-24 2016-06-17 Borealis Ag Artículo moldeado por soplado basado en copolímero al azar bimodal
CN105612188B (zh) 2013-10-24 2018-09-28 北欧化工公司 具有高含量的区域错误和高分子量的低熔点pp均聚物
CN105722869B (zh) 2013-10-29 2017-09-12 北欧化工公司 具有高聚合活性的固体单点催化剂
WO2015075088A1 (en) 2013-11-22 2015-05-28 Borealis Ag Low emission propylene homopolymer with high melt flow
EP3077426B1 (en) 2013-12-04 2022-10-05 Borealis AG Phthalate-free pp homopolymers for meltblown fibers
JP6203405B2 (ja) * 2013-12-18 2017-09-27 ボレアリス エージー 剛性／靭性バランスが改良されたｂｏｐｐフィルム
EP3083778B1 (en) 2013-12-18 2020-11-11 Borealis AG Bopp film having low shrinkage
CN105829364B (zh) 2014-01-17 2017-11-10 博里利斯股份公司 用于制备丙烯/1‑丁烯共聚物的方法
PL3102634T3 (pl) 2014-02-06 2020-11-16 Borealis Ag Miękkie i przezroczyste kopolimery odporne na uderzenia
ES2827285T3 (es) 2014-02-06 2021-05-20 Borealis Ag Copolímeros blandos con alta resistencia al impacto
EP2907841A1 (en) 2014-02-14 2015-08-19 Borealis AG Polypropylene composite
CN104974368B (zh) * 2014-04-04 2018-01-23 中国石油化工股份有限公司 一种抗静电聚丙烯发泡珠粒的制备方法
CN104974369B (zh) * 2014-04-04 2018-01-23 中国石油化工股份有限公司 一种聚丙烯发泡珠粒的制备方法
CN104974367B (zh) * 2014-04-04 2018-01-23 中国石油化工股份有限公司 一种抗静电聚丙烯发泡板材或片材的制备方法
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EP3170864B1 (en) 2015-11-17 2018-10-17 Borealis AG High flow tpo composition with excellent balance in mechanical properties for automotive interior
CN108350241B (zh) 2015-11-17 2020-12-04 博里利斯股份公司 具有优异的低温冲击的高流动性tpo组合物
US11236222B2 (en) 2016-08-30 2022-02-01 W.R. Grace & Co.-Conn. Catalyst system for the production of polyolefins and method of making and using same
EP3336109B1 (en) 2016-12-15 2023-06-07 Borealis AG Polypropylene composition with excellent paint adhesion
EP3489297B1 (en) 2017-11-28 2021-08-04 Borealis AG Polymer composition with improved paint adhesion
ES2890961T3 (es) 2017-11-28 2022-01-25 Borealis Ag Composición de polímero con adherencia de la pintura mejorada
EP3604425A1 (en) 2018-07-31 2020-02-05 Borealis AG Foamed polypropylene composition comprising polymeric fibers
CN112175117B (zh) * 2019-07-02 2023-07-21 中国石油化工股份有限公司 用于烯烃聚合的固体催化剂组分及其制备方法和用于烯烃聚合的催化剂及烯烃聚合的方法
CN112175118B (zh) * 2019-07-02 2023-11-14 中国石油化工股份有限公司 用于烯烃聚合的固体催化剂组分及其制备方法和烯烃聚合催化剂及烯烃聚合的方法
CN112175119B (zh) * 2019-07-02 2023-08-15 中国石油化工股份有限公司 烯烃聚合用固体催化剂组分及其制备方法、烯烃聚合催化剂和烯烃聚合的方法
CN112175115B (zh) * 2019-07-02 2023-07-21 中国石油化工股份有限公司 烯烃聚合催化剂的固体催化剂组分及其制备方法和烯烃聚合催化剂及烯烃聚合的方法
US11180587B2 (en) * 2019-12-13 2021-11-23 Chevron Phillips Chemical Company Lp Polymerization of propylene
JP7551755B2 (ja) * 2019-12-20 2024-09-17 パブリック・ジョイント・ストック・カンパニー・“シブール・ホールディング” 高処理速度でｂｏｐｐフィルムを製造するためのポリマー
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Publication number Publication date
KR20150036619A (ko) 2015-04-07
WO2014023603A1 (en) 2014-02-13
CA2878439C (en) 2016-08-30
EP2882782A1 (en) 2015-06-17
AU2013301726A1 (en) 2015-01-29
EP2882782B1 (en) 2018-09-05
RU2015104883A (ru) 2016-10-10
CN104487463A (zh) 2015-04-01
JP2015528517A (ja) 2015-09-28
US20150152203A1 (en) 2015-06-04
CA2878439A1 (en) 2014-02-13
JP6027240B2 (ja) 2016-11-16
BR112015001309A2 (pt) 2017-07-04
US9353203B2 (en) 2016-05-31
ZA201501080B (en) 2016-01-27
IN2015DN00186A (enExample) 2015-06-12
AU2013301726B2 (en) 2015-09-17
KR101706000B1 (ko) 2017-02-10

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