CN104487463B - 制备具有提高的生产率的聚丙烯的方法 - Google Patents

制备具有提高的生产率的聚丙烯的方法 Download PDF

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Publication number
CN104487463B
CN104487463B CN201380038758.8A CN201380038758A CN104487463B CN 104487463 B CN104487463 B CN 104487463B CN 201380038758 A CN201380038758 A CN 201380038758A CN 104487463 B CN104487463 B CN 104487463B
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polypropylene
range
fraction
reactor
propylene homopolymer
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Chinese (zh)
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CN104487463A (zh
Inventor
沃尔夫冈·内斯尔
迪特里希·格洛格尔
托马斯·赫里
马蒂纳·桑德霍泽
格雷戈里·波特
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Borealis GmbH
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Borealis GmbH
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/647—Catalysts containing a specific non-metal or metal-free compound
    • C08F4/649—Catalysts containing a specific non-metal or metal-free compound organic
    • C08F4/6491—Catalysts containing a specific non-metal or metal-free compound organic hydrocarbon
    • C08F4/6492—Catalysts containing a specific non-metal or metal-free compound organic hydrocarbon containing aliphatic unsaturation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652—Pretreating with metals or metal-containing compounds
    • C08F4/654—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof
    • C08F4/6543—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof halides of magnesium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C08L23/14—Copolymers of propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Polymerisation Methods In General (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Laminated Bodies (AREA)
CN201380038758.8A 2012-08-07 2013-07-30 制备具有提高的生产率的聚丙烯的方法 Active CN104487463B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP121795470 2012-08-07
EP12179547 2012-08-07
PCT/EP2013/065944 WO2014023603A1 (en) 2012-08-07 2013-07-30 Process for the preparation of polypropylene with improved productivity

Publications (2)

Publication Number Publication Date
CN104487463A CN104487463A (zh) 2015-04-01
CN104487463B true CN104487463B (zh) 2017-04-05

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US (1) US9353203B2 (enExample)
EP (1) EP2882782B1 (enExample)
JP (1) JP6027240B2 (enExample)
KR (1) KR101706000B1 (enExample)
CN (1) CN104487463B (enExample)
AU (1) AU2013301726B2 (enExample)
BR (1) BR112015001309A2 (enExample)
CA (1) CA2878439C (enExample)
IN (1) IN2015DN00186A (enExample)
RU (1) RU2015104883A (enExample)
WO (1) WO2014023603A1 (enExample)
ZA (1) ZA201501080B (enExample)

Families Citing this family (46)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101771831B1 (ko) * 2013-04-09 2017-08-25 보레알리스 아게 폴리프로필렌의 제조 방법
ES2651456T3 (es) 2013-08-14 2018-01-26 Borealis Ag Composición de propileno con mejor resistencia al impacto a baja temperatura
BR112016002682A8 (pt) 2013-08-21 2020-01-28 Borealis Ag composição de poliolefina de alto fluxo com alta rigidez e tenacidade
JP6190961B2 (ja) 2013-08-21 2017-08-30 ボレアリス・アクチェンゲゼルシャフトＢｏｒｅａｌｉｓ Ａｇ 高い剛性および靭性を有する高流動ポリオレフィン組成物
PT2853563T (pt) 2013-09-27 2016-07-14 Borealis Ag Filmes adequados para processamento de bopp a partir de polímeros com xs elevada e tm elevado
EP2860031B1 (en) 2013-10-11 2016-03-30 Borealis AG Machine direction oriented film for labels
ES2574428T3 (es) 2013-10-24 2016-06-17 Borealis Ag Artículo moldeado por soplado basado en copolímero al azar bimodal
EP3060589B9 (en) 2013-10-24 2018-04-18 Borealis AG Low melting pp homopolymer with high content of regioerrors and high molecular weight
WO2015062936A1 (en) 2013-10-29 2015-05-07 Borealis Ag Solid single site catalysts with high polymerisation activity
MX368147B (es) 2013-11-22 2019-09-20 Borealis Ag Homopolímero de propileno de baja emisión con alto flujo de masa fundida.
BR112016011829B1 (pt) 2013-12-04 2022-01-18 Borealis Ag Composição de polipropileno, fibra e trama soprada em fusão, artigo e uso da composição de polipropileno
EP3083778B1 (en) 2013-12-18 2020-11-11 Borealis AG Bopp film having low shrinkage
US9637602B2 (en) * 2013-12-18 2017-05-02 Borealis Ag BOPP film with improved stiffness/toughness balance
CN105829364B (zh) 2014-01-17 2017-11-10 博里利斯股份公司 用于制备丙烯/1‑丁烯共聚物的方法
WO2015117958A1 (en) 2014-02-06 2015-08-13 Borealis Ag Soft copolymers with high impact strength
PL3102634T3 (pl) 2014-02-06 2020-11-16 Borealis Ag Miękkie i przezroczyste kopolimery odporne na uderzenia
EP2907841A1 (en) 2014-02-14 2015-08-19 Borealis AG Polypropylene composite
CN104974369B (zh) * 2014-04-04 2018-01-23 中国石油化工股份有限公司 一种聚丙烯发泡珠粒的制备方法
CN104974368B (zh) * 2014-04-04 2018-01-23 中国石油化工股份有限公司 一种抗静电聚丙烯发泡珠粒的制备方法
CN104974367B (zh) * 2014-04-04 2018-01-23 中国石油化工股份有限公司 一种抗静电聚丙烯发泡板材或片材的制备方法
ES2659731T3 (es) 2014-05-20 2018-03-19 Borealis Ag Composición de polipropileno para aplicaciones en interiores de automóviles
CN110305605B (zh) * 2015-01-14 2021-12-14 埃克森美孚化学专利公司 由基于丙烯的聚合物和结晶c2/c3均聚物制成的粘结剂组合物
MX365523B (es) 2015-11-17 2019-06-06 Borealis Ag Composicion de poliolefina termoplastica (tpo) de flujo elevado con excelente impacto a baja temperatura.
ES2704727T3 (es) 2015-11-17 2019-03-19 Borealis Ag Composición de TPO de flujo elevado con excelente balance de propiedades mecánicas para interiores de automóviles
CA3003227C (en) 2015-11-17 2020-07-07 Borealis Ag High flow tpo composition with excellent tensile strain at break and low powder stickiness
EP3507311A4 (en) 2016-08-30 2020-07-08 W. R. Grace & Co. - Conn. CATALYST SYSTEM FOR THE PRODUCTION OF POLYOLEFINS AND METHOD FOR THE PRODUCTION AND USE THEREOF
ES2952512T3 (es) 2016-12-15 2023-10-31 Borealis Ag Composición de polipropileno con excelente adhesión de la pintura
EP3489296B1 (en) 2017-11-28 2021-09-01 Borealis AG Polymer composition with improved paint adhesion
EP3489297B1 (en) 2017-11-28 2021-08-04 Borealis AG Polymer composition with improved paint adhesion
EP3604425A1 (en) 2018-07-31 2020-02-05 Borealis AG Foamed polypropylene composition comprising polymeric fibers
CN112175117B (zh) * 2019-07-02 2023-07-21 中国石油化工股份有限公司 用于烯烃聚合的固体催化剂组分及其制备方法和用于烯烃聚合的催化剂及烯烃聚合的方法
CN112175115B (zh) * 2019-07-02 2023-07-21 中国石油化工股份有限公司 烯烃聚合催化剂的固体催化剂组分及其制备方法和烯烃聚合催化剂及烯烃聚合的方法
CN112175119B (zh) * 2019-07-02 2023-08-15 中国石油化工股份有限公司 烯烃聚合用固体催化剂组分及其制备方法、烯烃聚合催化剂和烯烃聚合的方法
CN112175118B (zh) * 2019-07-02 2023-11-14 中国石油化工股份有限公司 用于烯烃聚合的固体催化剂组分及其制备方法和烯烃聚合催化剂及烯烃聚合的方法
US11180587B2 (en) * 2019-12-13 2021-11-23 Chevron Phillips Chemical Company Lp Polymerization of propylene
JP7551755B2 (ja) * 2019-12-20 2024-09-17 パブリック・ジョイント・ストック・カンパニー・“シブール・ホールディング” 高処理速度でｂｏｐｐフィルムを製造するためのポリマー
WO2022162694A1 (en) 2021-01-27 2022-08-04 Hindustan Petroleum Corporation Limited Graft copolymer and method of preparation thereof
KR20240153317A (ko) * 2021-12-30 2024-10-22 페트로차이나 컴퍼니 리미티드 폴리프로필렌 수지 및 이의 제조 방법
WO2023180266A1 (en) 2022-03-23 2023-09-28 Borealis Ag Polypropylene composition for automotive applications
EP4375328A1 (en) 2022-11-23 2024-05-29 Borealis AG Polypropylene composition for automotive applications
CN120380039A (zh) * 2022-12-23 2025-07-25 北欧化工股份公司 聚丙烯共聚物的生产方法
EP4527884A1 (en) 2023-09-20 2025-03-26 Borealis AG Polypropylene composition for automotive applications
WO2025202314A1 (en) 2024-03-27 2025-10-02 Borealis Gmbh Polyolefin composition comprising polypropylene polymers and a blend of a plastic material comprising polypropylene and polyethylene
WO2025219533A1 (en) * 2024-04-18 2025-10-23 Borealis Gmbh Process for the preparation of a propylene homopolymer
WO2026093295A1 (en) 2024-10-30 2026-05-07 Borealis Gmbh Polypropylene composition with reduced emissions
WO2026093282A1 (en) 2024-10-30 2026-05-07 Borealis Gmbh Polypropylene composition with reduced stickiness

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2070956A1 (en) * 2007-12-14 2009-06-17 Total Petrochemicals Research Feluy Process for the production of a bimodal polypropylene having low ash content
EP2368937A1 (en) * 2010-03-22 2011-09-28 Borealis AG Heterophasic polypropylene with excellent creep performance

Family Cites Families (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FI80055C (fi) 1986-06-09 1990-04-10 Neste Oy Foerfarande foer framstaellning av katalytkomponenter foer polymerisation av olefiner.
FI86866C (fi) 1990-12-19 1992-10-26 Neste Oy Foerfarande foer modifiering av katalysatorer avsedda foer polymerisation av olefiner
FI86867C (fi) 1990-12-28 1992-10-26 Neste Oy Flerstegsprocess foer framstaellning av polyeten
FI88047C (fi) 1991-05-09 1993-03-25 Neste Oy Pao tvenne elektrondonorer baserad katalysator foer polymerisation av olefiner
FI88048C (fi) 1991-05-09 1993-03-25 Neste Oy Grovkornig polyolefin, dess framstaellningsmetod och en i metoden anvaend katalysator
FI111845B (fi) 1997-06-24 2003-09-30 Borealis Tech Oy Menetelmä propeenin homopolymeerien ja iskulujuudeltaan modifioitujen polymeerien valmistamiseksi
FI111847B (fi) 1997-06-24 2003-09-30 Borealis Tech Oy Menetelmä propeenin kopolymeerien valmistamiseksi
FI111848B (fi) 1997-06-24 2003-09-30 Borealis Tech Oy Menetelmä ja laitteisto propeenin homo- ja kopolymeerien valmistamiseksi
FI111846B (fi) 1997-06-24 2003-09-30 Borealis Tech Oy Menetelmä ja laitteisto polypropeeniseosten valmistamiseksi
FI974175L (fi) 1997-11-07 1999-05-08 Borealis As Menetelmä polypropeenin valmistamiseksi
FI980342A0 (fi) 1997-11-07 1998-02-13 Borealis As Polymerroer och -roerkopplingar
FI991057A0 (fi) 1999-05-07 1999-05-07 Borealis As Korkean jäykkyyden propeenipolymeerit ja menetelmä niiden valmistamiseksi
DE60239297D1 (de) 2002-06-25 2011-04-07 Borealis Tech Oy Polyolefin mit verbesserter kratzfestigkeit und verfahren zu seiner herstelung
EP1484343A1 (en) 2003-06-06 2004-12-08 Universiteit Twente Process for the catalytic polymerization of olefins, a reactor system and its use in the same process
EP2070954A1 (en) * 2007-12-14 2009-06-17 Total Petrochemicals Research Feluy Process for the production of a propylene polymer having a broad molecular weight distribution and a low ash content
ATE536390T1 (de) * 2008-10-29 2011-12-15 Borealis Ag Feste zusammensetzung für lebensmittelanwendungen
BR112012028659A2 (pt) * 2010-05-12 2016-08-09 Borealis Ag polipropileno com conteúdo específico de estearato de cálcio para capacitores especiais

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2070956A1 (en) * 2007-12-14 2009-06-17 Total Petrochemicals Research Feluy Process for the production of a bimodal polypropylene having low ash content
EP2368937A1 (en) * 2010-03-22 2011-09-28 Borealis AG Heterophasic polypropylene with excellent creep performance

Also Published As

Publication number Publication date
CA2878439C (en) 2016-08-30
EP2882782B1 (en) 2018-09-05
KR101706000B1 (ko) 2017-02-10
RU2015104883A (ru) 2016-10-10
WO2014023603A1 (en) 2014-02-13
CA2878439A1 (en) 2014-02-13
JP6027240B2 (ja) 2016-11-16
AU2013301726A1 (en) 2015-01-29
US20150152203A1 (en) 2015-06-04
AU2013301726B2 (en) 2015-09-17
US9353203B2 (en) 2016-05-31
BR112015001309A2 (pt) 2017-07-04
IN2015DN00186A (enExample) 2015-06-12
JP2015528517A (ja) 2015-09-28
KR20150036619A (ko) 2015-04-07
ZA201501080B (en) 2016-01-27
CN104487463A (zh) 2015-04-01
EP2882782A1 (en) 2015-06-17

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