CA2878439C - Process for the preparation of polypropylene with improved productivity - Google Patents

Process for the preparation of polypropylene with improved productivity Download PDF

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Publication number
CA2878439C
CA2878439C CA2878439A CA2878439A CA2878439C CA 2878439 C CA2878439 C CA 2878439C CA 2878439 A CA2878439 A CA 2878439A CA 2878439 A CA2878439 A CA 2878439A CA 2878439 C CA2878439 C CA 2878439C
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CA
Canada
Prior art keywords
polypropylene
fraction
polymerization
range
propylene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CA2878439A
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English (en)
French (fr)
Other versions
CA2878439A1 (en
Inventor
Wolfgang Neissl
Dietrich Gloger
Thomas Horill
Martina Sandholzer
Gregory Potter
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Borealis GmbH
Original Assignee
Borealis GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Borealis GmbH filed Critical Borealis GmbH
Publication of CA2878439A1 publication Critical patent/CA2878439A1/en
Application granted granted Critical
Publication of CA2878439C publication Critical patent/CA2878439C/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/647—Catalysts containing a specific non-metal or metal-free compound
    • C08F4/649—Catalysts containing a specific non-metal or metal-free compound organic
    • C08F4/6491—Catalysts containing a specific non-metal or metal-free compound organic hydrocarbon
    • C08F4/6492—Catalysts containing a specific non-metal or metal-free compound organic hydrocarbon containing aliphatic unsaturation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652—Pretreating with metals or metal-containing compounds
    • C08F4/654—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof
    • C08F4/6543—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof halides of magnesium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C08L23/14—Copolymers of propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Laminated Bodies (AREA)
  • Polymerisation Methods In General (AREA)
CA2878439A 2012-08-07 2013-07-30 Process for the preparation of polypropylene with improved productivity Active CA2878439C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP12179547.0 2012-08-07
EP12179547 2012-08-07
PCT/EP2013/065944 WO2014023603A1 (en) 2012-08-07 2013-07-30 Process for the preparation of polypropylene with improved productivity

Publications (2)

Publication Number Publication Date
CA2878439A1 CA2878439A1 (en) 2014-02-13
CA2878439C true CA2878439C (en) 2016-08-30

Family

ID=48900988

Family Applications (1)

Application Number Title Priority Date Filing Date
CA2878439A Active CA2878439C (en) 2012-08-07 2013-07-30 Process for the preparation of polypropylene with improved productivity

Country Status (12)

Country Link
US (1) US9353203B2 (enExample)
EP (1) EP2882782B1 (enExample)
JP (1) JP6027240B2 (enExample)
KR (1) KR101706000B1 (enExample)
CN (1) CN104487463B (enExample)
AU (1) AU2013301726B2 (enExample)
BR (1) BR112015001309A2 (enExample)
CA (1) CA2878439C (enExample)
IN (1) IN2015DN00186A (enExample)
RU (1) RU2015104883A (enExample)
WO (1) WO2014023603A1 (enExample)
ZA (1) ZA201501080B (enExample)

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SG10201708291WA (en) * 2013-04-09 2017-11-29 Borealis Ag Process for the manufacture of polypropylene
JP6216887B2 (ja) 2013-08-14 2017-10-18 ボレアリス・アクチェンゲゼルシャフトＢｏｒｅａｌｉｓ Ａｇ 低温における耐衝撃性が改善されたプロピレン組成物
BR112016002682A8 (pt) 2013-08-21 2020-01-28 Borealis Ag composição de poliolefina de alto fluxo com alta rigidez e tenacidade
BR112016003128B1 (pt) 2013-08-21 2021-08-24 Borealis Ag Composição de poliolefina de alto fluxo com alta rigidez e resistência e artigos automotivos
PL2853563T3 (pl) 2013-09-27 2016-12-30 Folie odpowiednie do przetwarzania BOPP z polimerów o wysokiej XS i wysokiej Tm
ES2568615T3 (es) 2013-10-11 2016-05-03 Borealis Ag Película para etiquetas orientada en la dirección de la máquina
ES2574428T3 (es) 2013-10-24 2016-06-17 Borealis Ag Artículo moldeado por soplado basado en copolímero al azar bimodal
WO2015059229A1 (en) 2013-10-24 2015-04-30 Borealis Ag Low melting pp homopolymer with high content of regioerrors and high molecular weight
EP3063185B9 (en) 2013-10-29 2017-11-15 Borealis AG Solid single site catalysts with high polymerisation activity
KR101682342B1 (ko) 2013-11-22 2016-12-05 보레알리스 아게 고 용융 유동을 갖는 저 배출 프로필렌 단독중합체
US9828698B2 (en) 2013-12-04 2017-11-28 Borealis Ag Phthalate-free PP homopolymers for meltblown fibers
CN105829409B (zh) 2013-12-18 2019-08-06 北欧化工公司 具有低收缩率的bopp膜
EP3083777B1 (en) * 2013-12-18 2019-04-24 Borealis AG Bopp film with improved stiffness/toughness balance
EP3094660B1 (en) 2014-01-17 2018-12-19 Borealis AG Process for preparing propylene/1-butene copolymers
JP2017508032A (ja) 2014-02-06 2017-03-23 ボレアリス エージー 高衝撃強さを有する軟質コポリマー
US10100186B2 (en) 2014-02-06 2018-10-16 Borealis Ag Soft and transparent impact copolymers
EP2907841A1 (en) 2014-02-14 2015-08-19 Borealis AG Polypropylene composite
CN104974369B (zh) * 2014-04-04 2018-01-23 中国石油化工股份有限公司 一种聚丙烯发泡珠粒的制备方法
CN104974367B (zh) * 2014-04-04 2018-01-23 中国石油化工股份有限公司 一种抗静电聚丙烯发泡板材或片材的制备方法
CN104974368B (zh) * 2014-04-04 2018-01-23 中国石油化工股份有限公司 一种抗静电聚丙烯发泡珠粒的制备方法
ES2659731T3 (es) 2014-05-20 2018-03-19 Borealis Ag Composición de polipropileno para aplicaciones en interiores de automóviles
EP3245266A1 (en) * 2015-01-14 2017-11-22 ExxonMobil Chemical Patents Inc. Adhesive compositions made from propylene-based polymers and crystalline c2/c3 homopolymer
WO2017085195A1 (en) 2015-11-17 2017-05-26 Borealis Ag High flow tpo composition with excellent low temperature impact
CA3003227C (en) 2015-11-17 2020-07-07 Borealis Ag High flow tpo composition with excellent tensile strain at break and low powder stickiness
PL3170864T3 (pl) 2015-11-17 2019-04-30 Borealis Ag Wysokopłynąca kompozycja TPO o doskonałej równowadze właściwości mechanicznych, do wyposażenia wewnętrznego pojazdu
BR112019003864B1 (pt) 2016-08-30 2023-02-14 W. R. Grace & Co. - Conn Composição para uso com catalisador para polimerização de misturas
ES2952512T3 (es) 2016-12-15 2023-10-31 Borealis Ag Composición de polipropileno con excelente adhesión de la pintura
ES2890961T3 (es) 2017-11-28 2022-01-25 Borealis Ag Composición de polímero con adherencia de la pintura mejorada
ES2886432T3 (es) 2017-11-28 2021-12-20 Borealis Ag Composición de polímero con adherencia de la pintura mejorada
EP3604425A1 (en) 2018-07-31 2020-02-05 Borealis AG Foamed polypropylene composition comprising polymeric fibers
CN112175115B (zh) * 2019-07-02 2023-07-21 中国石油化工股份有限公司 烯烃聚合催化剂的固体催化剂组分及其制备方法和烯烃聚合催化剂及烯烃聚合的方法
CN112175118B (zh) * 2019-07-02 2023-11-14 中国石油化工股份有限公司 用于烯烃聚合的固体催化剂组分及其制备方法和烯烃聚合催化剂及烯烃聚合的方法
CN112175119B (zh) * 2019-07-02 2023-08-15 中国石油化工股份有限公司 烯烃聚合用固体催化剂组分及其制备方法、烯烃聚合催化剂和烯烃聚合的方法
CN112175117B (zh) * 2019-07-02 2023-07-21 中国石油化工股份有限公司 用于烯烃聚合的固体催化剂组分及其制备方法和用于烯烃聚合的催化剂及烯烃聚合的方法
US11180587B2 (en) 2019-12-13 2021-11-23 Chevron Phillips Chemical Company Lp Polymerization of propylene
JP7551755B2 (ja) * 2019-12-20 2024-09-17 パブリック・ジョイント・ストック・カンパニー・“シブール・ホールディング” 高処理速度でｂｏｐｐフィルムを製造するためのポリマー
WO2022162694A1 (en) 2021-01-27 2022-08-04 Hindustan Petroleum Corporation Limited Graft copolymer and method of preparation thereof
JP2025501306A (ja) * 2021-12-30 2025-01-17 ペトロチャイナ カンパニー リミテッド 超清浄ポリプロピレン樹脂及びその製造方法
EP4496848A1 (en) 2022-03-23 2025-01-29 Borealis AG Polypropylene composition for automotive applications
EP4375328A1 (en) 2022-11-23 2024-05-29 Borealis AG Polypropylene composition for automotive applications
TW202440670A (zh) * 2022-12-23 2024-10-16 奧地利商柏列利斯股份公司 聚丙烯共聚物的製造方法
EP4527884A1 (en) 2023-09-20 2025-03-26 Borealis AG Polypropylene composition for automotive applications
WO2025202314A1 (en) 2024-03-27 2025-10-02 Borealis Gmbh Polyolefin composition comprising polypropylene polymers and a blend of a plastic material comprising polypropylene and polyethylene
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Also Published As

Publication number Publication date
US20150152203A1 (en) 2015-06-04
EP2882782B1 (en) 2018-09-05
BR112015001309A2 (pt) 2017-07-04
CN104487463B (zh) 2017-04-05
AU2013301726A1 (en) 2015-01-29
US9353203B2 (en) 2016-05-31
RU2015104883A (ru) 2016-10-10
CA2878439A1 (en) 2014-02-13
JP2015528517A (ja) 2015-09-28
KR20150036619A (ko) 2015-04-07
JP6027240B2 (ja) 2016-11-16
EP2882782A1 (en) 2015-06-17
AU2013301726B2 (en) 2015-09-17
ZA201501080B (en) 2016-01-27
WO2014023603A1 (en) 2014-02-13
IN2015DN00186A (enExample) 2015-06-12
CN104487463A (zh) 2015-04-01
KR101706000B1 (ko) 2017-02-10

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Effective date: 20150106