CN104447090A - Ecological organic liquid fertilizer and production method thereof - Google Patents

Ecological organic liquid fertilizer and production method thereof Download PDF

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CN104447090A
CN104447090A CN201410708931.7A CN201410708931A CN104447090A CN 104447090 A CN104447090 A CN 104447090A CN 201410708931 A CN201410708931 A CN 201410708931A CN 104447090 A CN104447090 A CN 104447090A
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organic fertilizer
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CN104447090B (en
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韦方华
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    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • C05G3/60Biocides or preservatives, e.g. disinfectants, pesticides or herbicides; Pest repellants or attractants
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05DINORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
    • C05D9/00Other inorganic fertilisers
    • C05D9/02Other inorganic fertilisers containing trace elements
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • C05G3/80Soil conditioners

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  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Organic Chemistry (AREA)
  • Soil Sciences (AREA)
  • Plant Pathology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Fertilizers (AREA)

Abstract

The invention discloses an ecological organic liquid fertilizer which comprises components in parts by weight as follows; 70-80 parts of vitex negundo leaves, 30-40 parts of green manure, 10-20 parts of pyrethrum, 20-40 parts of molasses, 0.4-0.6 parts of choline chloride, 0.1-2 parts of an antibacterial peptide, 1-3 parts of microelements, 1-5 parts of an amino acid, 1-4 parts of biological bacteria, 2-3 parts of a dispersing agent, 3-10 parts of water-retaining agent and 100-150 parts of water. The ecological organic liquid fertilizer has the advantages of low cost, high fertilizer efficiency, high comprehensive effect, capability of controlling diseases and pests, reducing environmental pollution and improving the soil and the like.

Description

A kind of ecological organic fertilizer and preparation method thereof
Technical field
The present invention relates to environmental protection and technical field of biological fertilizer, particularly relate to a kind of ecological organic fertilizer and preparation method thereof.
Background technology
China's crop acreage is large, and agricultural provides the basic product supporting the development of the national economy and development.Fertilizer be can provide indispensable nutrition for plant-growth, improve soil property, a class material of level of increasing soil fertility, be one of basic substance of agriculture production.
The life-time service of chemical fertilizer, easily cause all kinds of nutrients ratio imbalance in soil compaction, soil, farmland ecosystem suffer to destroy, in soil profitable strain reduces, disease-resistant crops is less able, heavy metal and toxic element increases, quality of agricultural product declines and causes the problems such as environmental pollution.
Ecological organic fertilier refers to microorganisms with specific functions with main with plant and animal residues, if feces of livestock and poultry, agricultural crop straw etc. be originate and have the fertilizer of microbial fertilizer and fertilizer effect through the class that harmless treatment, the organic materials that becomes thoroughly decomposed are composited concurrently.Ecological organic fertilier nutritive element is complete, can improve soil physical and chemical property, strengthens the ability of soil water-retaining, fertilizer conservation, fertilizer.Form mutual symbiosis Relationship With Proliferation with Soil Microorganism after beneficial microorganism in ecological organic fertilier enters soil, suppress harmful bacteria grow and be converted into probiotics, interact, mutually promoting, play the synergy of colony, is a kind of environment-friendly type fertilizer.
Liquid fertilizer is compared with solid fertilizer, and have fertilizer efficiency fast, can not lump, using method is various, pollutes the advantages such as few when producing, transporting and using.
Existing ecological organic fertilizer also also exists that nutritive ingredient is complete, fertilizer efficiency is poor, the time length is shorter, does not have the shortcoming such as sterilization, insecticidal action concurrently.
Summary of the invention
The invention provides a kind of ecological organic fertilizer and preparation method thereof.Ecological organic fertilier provided by the invention has rich in nutrition content, use simple, the fertilizer efficiency time length is long, has the advantage such as sterilization, insecticidal action concurrently.
Technical scheme provided by the invention is:
A kind of ecological organic fertilizer, comprises the component of following parts by weight: Negundo Chastetree Leaf 70-80 part, green manure 30-40 part, pyrethrum 10-20 part, molasses 20-40 part, choline chloride 60 0.4-0.6 part, antibacterial peptide 0.1-2 part, micro-1-3 part, amino acid/11-5 parts, biological bacteria 1-4 part, dispersion agent 2-3 part, water-holding agent 3-10 part and water 100-150 part.
Preferably, in described ecological organic fertilizer, be made up of the component of following parts by weight: Negundo Chastetree Leaf 75 parts, 35 parts, green manure, pyrethrum 15 parts, 30 parts, molasses, choline chloride 60 0.5 part, antibacterial peptide 1 part, trace element 2 parts, 3 parts, amino acid, biological bacteria 3 parts, dispersion agent 2.5 parts, water-holding agent 6 parts and 125 parts, water.
Preferably, in described ecological organic fertilizer, described biological bacteria is any one or a few in vinelandii, phosphate solubilizing bacteria, potassium solubilizing bacteria, Ammonifying bacteria and nitrobacteria.
Preferably, in described ecological organic fertilizer, described green manure is any one or a few in sweet potato, pea, Cassia tora, bamboo beans and Gui fiber crops, and the water content of described green manure is 30-80%.
Preferably, in described ecological organic fertilizer, described trace element is any one or a few in iron, copper, zinc, manganese or boron.
Preferably, in described ecological organic fertilizer, described water is magnetized water.
A making method for ecological organic fertilizer, comprises the following steps:
Step one, be put into fermentation vat after the Negundo Chastetree Leaf of 75 parts is pulverized by parts by weight, backward fermentation vat in add parts by weight be the molasses of 15 parts and the water of 75 parts, seal after stirring, in 50-70 DEG C of bottom fermentation 30-40h, filter to obtain fermented liquid, for subsequent use;
Step 2, load in extraction kettle by the fermented liquid that leaches in step one, start CO 2 high pressure pump, carry out carbon dioxide upercritical fluid extraction, after cycling extraction 1-5h, termination of pumping, is depressurized to 5-6MP a, collect extraction liquid, for subsequent use;
Step 3, with the alkaloid floating on extraction liquid surface in siphon pipe extraction step two, collection of biological alkali, for subsequent use;
Step 4, to get parts by weight be abrasive dust after the flower of the pyrethrum of 15 parts dries in the shade, and crosses 150-120 object sieve extracting screen underflow, obtain the fines of pyrethrum flower, for subsequent use;
Step 5, be put into fermentation vat after the root, stem and leaf of the green manure of 35 parts and the pyrethrum of 15 parts is pulverized by parts by weight, backward fermentation vat in add parts by weight be the molasses of 15 parts and the water of 50 parts, seal after stirring, in 50-70 DEG C of bottom fermentation 30-40h, filter to obtain fermented liquid, for subsequent use;
Step 6, the alkaloid collected in step 3 is put into agitated pool, choline chloride 60 0.5 part, antibacterial peptide 1 part, biological bacteria 3 parts, trace element 2 parts, 3 parts, amino acid, dispersion agent 2.5 parts and water-holding agent 6 parts is added again in agitated pool, and gained fermented liquid in the fines of obtained pyrethrum flower and step 5 in step 4, stir, obtain ecological organic fertilizer.
Preferably, in the making method of described ecological organic fertilizer, described water-holding agent is Polyacrylamide Powder.
Preferably, in the making method of described ecological organic fertilizer, in described step 2, the reaction conditions of described carbon dioxide upercritical fluid extraction is: the pressure of supercritical co is 10-18MPa, and flow is 8-20L/h, and extraction kettle temperature is 32-40 DEG C.
The invention provides a kind of ecological organic fertilizer and preparation method thereof.When extracting the alkaloid in Negundo Chastetree Leaf, first adopt the mode of first fermenting, fermentation energy destroys the cell walls of plant, be conducive to the stripping of effective constituent, effectively improve alkaloidal extraction yield, and fermentation energy kills most of harmful microorganism and worm's ovum; Again by the effective constituent in carbon dioxide upercritical fluid extraction separating and extracting liquid, supercritical extraction using supercritical co as extraction agent, have nontoxic, there is not dissolvent residual, free from environmental pollution and extracting and separating rate advantages of higher.During the fermentation using molasses as fermented substrate, molasses are byproducts of sugar industry, if be underutilized, easily cause environmental pollution and the wasting of resources, molasses ferment together with other plant and animal residuess, become the bio-organic fertilizer being rich in amino acid, xanthohumic acid, humic acid etc. that utility value is very high.In liquid fertilizer, with the addition of alkaloid, it has unique effect removing insect pest pharmacological action and Promoting plant growth; In liquid fertilizer, with the addition of non-antibiotic series bactericidal agent-antibacterial peptide, antibacterial peptide has Heat stability is good, broad-spectrum antimicrobial, and the advantage such as have no drug resistance; In liquid fertilizer, with the addition of choline chloride 60, choline chloride 60 is a kind of plant photosynthesis promoter, has obvious effect to increase yield; In liquid fertilizer, with the addition of botanical pesticide one pyrethrum, pyrethrum not only can remove mosquito-killing, and can kill the insect of farm crop and forest, fruit tree; In liquid fertilizer, with the addition of beneficial organism bacterium, the biological bacteria such as vinelandii, phosphate solubilizing bacteria, potassium solubilizing bacteria are imposed on plant, makes it decompose, absorb the nutrient such as nitrogen, phosphorus, potassium in air, soil, make the comprehensive source of manure forming life and growth in nature in soil, reach fertilizer voluntarily.In liquid fertilizer, with the addition of the fermented liquid of green manure, green manure is a kind of nutrient biological source of manure completely, can provide abundant nutrient for soil, insoluble Nutrient Transformation in soil can be made, be beneficial to the absorption of crop, the physico-chemical property of soil can be improved, promote the activity of soil microorganisms.In liquid fertilizer, with the addition of water-holding agent, water-holding agent is the functional high molecule material that a kind of water-retaining capacity is strong especially, nontoxic, repeatedly releases water, water suction, can also absorb fertilizer, agricultural chemicals slow releasing, increases fertilizer efficiency, drug effect.The present invention has that cost is low, fertilizer efficiency is high, amount of increase in production is large, prevention and elimination of disease and pests, minimizing environmental pollution, improvement soil, preserve moisture and fertility, fertilizer comprehensive utilization are high, can improve the advantages such as crop alimentary quality and yield.
Embodiment
Below in conjunction with embodiment, the present invention is described in further detail, can implement according to this with reference to specification sheets word to make those skilled in the art.
Embodiment 1:
A kind of ecological organic fertilizer, comprises the component of following parts by weight: Negundo Chastetree Leaf 70 parts, sweet potato 30 parts, pyrethrum 10 parts, 20 parts, molasses, choline chloride 60 0.4 part, antibacterial peptide 0.1 part, trace element 1 part, amino acid/11 part, 1 part, vinelandii, dispersion agent 2 parts, polyacrylamide 3 parts and magnetized water 100 parts.
A making method for ecological organic fertilizer, comprises the following steps:
Step one, be put into fermentation vat after the Negundo Chastetree Leaf of 70 parts is pulverized by parts by weight, backward fermentation vat in add parts by weight be the molasses of 10 parts and the magnetized water of 55 parts, seal after stirring, in 50 DEG C of bottom fermentation 30h, filter to obtain fermented liquid, for subsequent use;
Step 2, the fermented liquid that leaches in step one is loaded in extraction kettle, start CO 2 high pressure pump, the supercritical co that pressure is 10MPa is passed in extraction kettle, the flow controlling carbonic acid gas is 8L/h, and extraction kettle temperature is 32 DEG C, after cycling extraction 1h, termination of pumping, be depressurized to 5MPa, collect extraction liquid, for subsequent use;
Step 3, with the alkaloid floating on extraction liquid surface in siphon pipe extraction step two, collection of biological alkali, for subsequent use;
Step 4, to get parts by weight be abrasive dust after the flower of the pyrethrum of 10 parts dries in the shade, and crosses 120 object sieve extracting screen underflows, obtain the fines of pyrethrum flower, for subsequent use;
The root, stem and leaf of step 5, to be 30 parts of water content by parts by weight the be sweet potato of 30% and the pyrethrum of 10 parts puts into fermentation vat after pulverizing, backward fermentation vat in add parts by weight be the molasses of 10 parts and the magnetized water of 45 parts, seal after stirring, in 50 DEG C of bottom fermentation 30h, filter to obtain fermented liquid, for subsequent use;
Step 6, the alkaloid collected in step 3 is put into agitated pool, choline chloride 60 0.5 part, antibacterial peptide 0.1 part, 1 part, vinelandii, trace element 1 part, amino acid/11 part, dispersion agent 2 parts and polyacrylamide 3 parts is added again in agitated pool, and gained fermented liquid in the fines of obtained pyrethrum flower and step 5 in step 4, stir, obtain ecological organic fertilizer.
Embodiment 2:
A kind of ecological organic fertilizer, comprises the component of following parts by weight: Negundo Chastetree Leaf 80 parts, pea 40 parts, pyrethrum 20 parts, 40 parts, molasses, choline chloride 60 0.6 part, antibacterial peptide 2 parts, trace element 3 parts, 5 parts, amino acid, phosphate solubilizing bacteria 4 parts, dispersion agent 3 parts, polyacrylamide 10 parts and magnetized water 150 parts.
A making method for ecological organic fertilizer, comprises the following steps:
Step one, be put into fermentation vat after the Negundo Chastetree Leaf of 80 parts is pulverized by parts by weight, backward fermentation vat in add parts by weight be the molasses of 20 parts and the magnetized water of 85 parts, seal after stirring, in 70 DEG C of bottom fermentation 40h, filter to obtain fermented liquid, for subsequent use;
Step 2, the fermented liquid that leaches in step one is loaded in extraction kettle, start CO 2 high pressure pump, the supercritical co that pressure is 18MPa is passed in extraction kettle, the flow controlling carbonic acid gas is 20L/h, and extraction kettle temperature is 40 DEG C, after cycling extraction 5h, termination of pumping, be depressurized to 6MPa, collect extraction liquid, for subsequent use;
Step 3, with the alkaloid floating on extraction liquid surface in siphon pipe extraction step two, collection of biological alkali, for subsequent use;
Step 4, to get parts by weight be abrasive dust after the flower of the pyrethrum of 20 parts dries in the shade, and crosses 150 object sieve extracting screen underflows, obtain the fines of pyrethrum flower, for subsequent use;
The root, stem and leaf of step 5, to be 40 parts of water content by parts by weight the be pea of 50% and the pyrethrum of 20 parts puts into fermentation vat after pulverizing, backward fermentation vat in add parts by weight be the molasses of 20 parts and the magnetized water of 65 parts, seal after stirring, in 70 DEG C of bottom fermentation 40h, filter to obtain fermented liquid, for subsequent use;
Step 6, the alkaloid collected in step 3 is put into agitated pool, choline chloride 60 0.6 part, antibacterial peptide 2 parts, phosphate solubilizing bacteria 4 parts, trace element 3 parts, 5 parts, amino acid, dispersion agent 3 parts and polyacrylamide 10 parts is added again in agitated pool, and gained fermented liquid in the fines of obtained pyrethrum flower and step 5 in step 4, stir, obtain ecological organic fertilizer.
Embodiment 3:
A kind of ecological organic fertilizer, comprises the component of following parts by weight: Negundo Chastetree Leaf 75 parts, bamboo beans 35 parts, pyrethrum 15 parts, 30 parts, molasses, choline chloride 60 0.5 part, antibacterial peptide 1 part, trace element 2 parts, 3 parts, amino acid, nitrobacteria 3 parts, dispersion agent 2.5 parts, polyacrylamide 6 parts and magnetized water 125 parts.
A making method for ecological organic fertilizer, comprises the following steps:
Step one, be put into fermentation vat after the Negundo Chastetree Leaf of 75 parts is pulverized by parts by weight, backward fermentation vat in add parts by weight be the molasses of 15 parts and the magnetized water of 75 parts, seal after stirring, in 60 DEG C of bottom fermentation 35h, filter to obtain fermented liquid, for subsequent use;
Step 2, the fermented liquid that leaches in step one is loaded in extraction kettle, start CO 2 high pressure pump, in extraction kettle, pass into the supercritical co that pressure is 14MPa, the flow controlling carbonic acid gas is 14L/h, and extraction kettle temperature is 36 DEG C, after cycling extraction 3h, termination of pumping, is depressurized to 5.5MP a, collect extraction liquid, for subsequent use;
Step 3, with the alkaloid floating on extraction liquid surface in siphon pipe extraction step two, collection of biological alkali, for subsequent use;
Step 4, to get parts by weight be abrasive dust after the flower of the pyrethrum of 15 parts dries in the shade, and crosses 130 object sieve extracting screen underflows, obtain the fines of pyrethrum flower, for subsequent use;
The root, stem and leaf of step 5, to be 35 parts of water content by parts by weight the be bamboo beans of 80% and the pyrethrum of 15 parts puts into fermentation vat after pulverizing, backward fermentation vat in add parts by weight be the molasses of 15 parts and the magnetized water of 50 parts, seal after stirring, in 60 DEG C of bottom fermentation 35h, filter to obtain fermented liquid, for subsequent use;
Step 6, the alkaloid collected in step 3 is put into agitated pool, choline chloride 60 0.5 part, antibacterial peptide 1 part, nitrobacteria 3 parts, trace element 2 parts, 3 parts, amino acid, dispersion agent 2.5 parts and polyacrylamide 6 parts is added again in agitated pool, and gained fermented liquid in the fines of obtained pyrethrum flower and step 5 in step 4, stir, obtain ecological organic fertilizer.
Although embodiment of the present invention are open as above, but it is not restricted to listed in specification sheets and embodiment utilization, it can be applied to various applicable the field of the invention completely, for those skilled in the art, can easily realize other amendment, therefore do not deviating under the universal that claim and equivalency range limit, the present invention is not limited to specific details and illustrates here and the embodiment described.

Claims (9)

1. an ecological organic fertilizer, it is characterized in that, comprise the component of following parts by weight: Negundo Chastetree Leaf 70-80 part, green manure 30-40 part, pyrethrum 10-20 part, molasses 20-40 part, choline chloride 60 0.4-0.6 part, antibacterial peptide 0.1-2 part, micro-1-3 part, amino acid/11-5 parts, biological bacteria 1-4 part, dispersion agent 2-3 part, water-holding agent 3-10 part and water 100-150 part.
2. ecological organic fertilizer as claimed in claim 1, it is characterized in that, be made up of the component of following parts by weight: Negundo Chastetree Leaf 75 parts, 35 parts, green manure, pyrethrum 15 parts, 30 parts, molasses, choline chloride 60 0.5 part, antibacterial peptide 1 part, trace element 2 parts, 3 parts, amino acid, biological bacteria 3 parts, dispersion agent 2.5 parts, water-holding agent 6 parts and 125 parts, water.
3. ecological organic fertilizer as claimed in claim 1, is characterized in that, described biological bacteria is any one or a few in vinelandii, phosphate solubilizing bacteria, potassium solubilizing bacteria, Ammonifying bacteria and nitrobacteria.
4. ecological organic fertilizer as claimed in claim 1, is characterized in that, described green manure is any one or a few in sweet potato, pea, Cassia tora, bamboo beans and Gui fiber crops, and the water content of described green manure is 30-80%.
5. ecological organic fertilizer as claimed in claim 1, is characterized in that, described trace element is any one or a few in iron, copper, zinc, manganese or boron.
6. ecological organic fertilizer as claimed in claim 1, is characterized in that, described water is magnetized water.
7. a making method for ecological organic fertilizer, is characterized in that, comprises the following steps:
Step one, be put into fermentation vat after the Negundo Chastetree Leaf of 75 parts is pulverized by parts by weight, backward fermentation vat in add parts by weight be the molasses of 15 parts and the water of 75 parts, seal after stirring, in 50-70 DEG C of bottom fermentation 30-40h, filter to obtain fermented liquid, for subsequent use;
Step 2, load in extraction kettle by the fermented liquid that leaches in step one, start CO 2 high pressure pump, carry out carbon dioxide upercritical fluid extraction, after cycling extraction 1-5h, termination of pumping, is depressurized to 5-6MPa, collects extraction liquid, for subsequent use;
Step 3, with the alkaloid floating on extraction liquid surface in siphon pipe extraction step two, collection of biological alkali, for subsequent use;
Step 4, to get parts by weight be abrasive dust after the flower of the pyrethrum of 15 parts dries in the shade, and crosses 150-120 object sieve extracting screen underflow, obtain the fines of pyrethrum flower, for subsequent use;
Step 5, be put into fermentation vat after the root, stem and leaf of the green manure of 35 parts and the pyrethrum of 15 parts is pulverized by parts by weight, backward fermentation vat in add parts by weight be the molasses of 15 parts and the water of 50 parts, seal after stirring, in 50-70 DEG C of bottom fermentation 30-40h, filter to obtain fermented liquid, for subsequent use;
Step 6, the alkaloid collected in step 3 is put into agitated pool, choline chloride 60 0.5 part, antibacterial peptide 1 part, biological bacteria 3 parts, trace element 2 parts, 3 parts, amino acid, dispersion agent 2.5 parts and water-holding agent 6 parts is added again in agitated pool, and gained fermented liquid in the fines of obtained pyrethrum flower and step 5 in step 4, stir, obtain ecological organic fertilizer.
8. the making method of ecological organic fertilizer as claimed in claim 6, is characterized in that, described water-holding agent is Polyacrylamide Powder.
9. the making method of ecological organic fertilizer as claimed in claim 6, it is characterized in that, in described step 2, the reaction conditions of described carbon dioxide upercritical fluid extraction is: the pressure of supercritical co is 10-18MPa, flow is 8-20L/h, and extraction kettle temperature is 32-40 DEG C.
CN201410708931.7A 2014-11-28 2014-11-28 A kind of ecological organic fertilizer and preparation method thereof Expired - Fee Related CN104447090B (en)

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CN105061111A (en) * 2015-08-06 2015-11-18 丁德凤 Compound microbial fertilizer
CN105152796A (en) * 2015-07-10 2015-12-16 诸卫平 Plant liquid, and preparation method and application thereof
CN105175126A (en) * 2015-09-06 2015-12-23 黑龙江省达丰科技开发有限责任公司 Preparation method of active ferment liquid fertilizer
CN105198567A (en) * 2015-09-09 2015-12-30 山东乡约生物工程科技有限公司 Compounded amino-acid microbial bacterium agent and preparation method therefor
CN105254425A (en) * 2015-10-26 2016-01-20 广西农垦国有立新农场 Ecological organic fertilizer and preparing method thereof
CN105254445A (en) * 2015-10-26 2016-01-20 广西农垦国有立新农场 Biological insecticidal organic fertilizer and preparation method thereof
CN105254426A (en) * 2015-10-26 2016-01-20 广西农垦国有立新农场 Organic fertilizer and preparation method thereof
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CN107032904A (en) * 2017-06-12 2017-08-11 青海科华生物工程有限公司 With the plant source amino acid matrimony vine special foliar fertilizer for increasing production and preventing and treating pest and disease damage
CN107371669A (en) * 2016-11-16 2017-11-24 田阳农瑞德种苗专业合作社 A kind of cultural method of organic vegetable
CN107879796A (en) * 2017-10-27 2018-04-06 石阡县万家红农业综合发展农民专业合作社 A kind of lotus leaf is sustained leaf fertilizer with insect-pest
CN109180296A (en) * 2018-08-20 2019-01-11 惠州市源茵畜牧科技有限公司 A kind of vegetable growing nutrient solution

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