CN104403063B - 一种有机硅共聚物表面活性剂及其应用 - Google Patents
一种有机硅共聚物表面活性剂及其应用 Download PDFInfo
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- CN104403063B CN104403063B CN201410648652.6A CN201410648652A CN104403063B CN 104403063 B CN104403063 B CN 104403063B CN 201410648652 A CN201410648652 A CN 201410648652A CN 104403063 B CN104403063 B CN 104403063B
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- 239000004094 surface-active agent Substances 0.000 title claims abstract description 70
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- 239000006260 foam Substances 0.000 claims abstract description 102
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- 239000011496 polyurethane foam Substances 0.000 claims abstract description 36
- 229920000570 polyether Polymers 0.000 claims abstract description 22
- 238000000034 method Methods 0.000 claims abstract description 13
- 239000004721 Polyphenylene oxide Substances 0.000 claims abstract description 7
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 claims abstract description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 22
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 claims description 14
- 239000002202 Polyethylene glycol Substances 0.000 claims description 11
- 229920001223 polyethylene glycol Polymers 0.000 claims description 11
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 10
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical group C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 8
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 8
- 150000004808 allyl alcohols Chemical class 0.000 claims description 8
- 230000000903 blocking effect Effects 0.000 claims description 8
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- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 5
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- 238000011534 incubation Methods 0.000 claims description 4
- 239000007788 liquid Substances 0.000 claims description 4
- 229910052757 nitrogen Inorganic materials 0.000 claims description 4
- 101100115801 Streptomyces mobaraensis daip gene Proteins 0.000 claims description 3
- 239000013078 crystal Substances 0.000 claims description 3
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 2
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 claims description 2
- 150000001336 alkenes Chemical class 0.000 claims 1
- 239000003795 chemical substances by application Substances 0.000 abstract description 11
- 238000005187 foaming Methods 0.000 abstract description 7
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- 238000013461 design Methods 0.000 abstract description 4
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- 238000005227 gel permeation chromatography Methods 0.000 description 8
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- 239000012948 isocyanate Substances 0.000 description 6
- 229910052710 silicon Inorganic materials 0.000 description 6
- 239000010703 silicon Substances 0.000 description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 5
- 239000003054 catalyst Substances 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 210000000497 foam cell Anatomy 0.000 description 5
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 230000035699 permeability Effects 0.000 description 5
- 239000002994 raw material Substances 0.000 description 5
- 150000005846 sugar alcohols Polymers 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 229910020388 SiO1/2 Inorganic materials 0.000 description 4
- 229910020447 SiO2/2 Inorganic materials 0.000 description 4
- 125000003636 chemical group Chemical group 0.000 description 4
- 238000004132 cross linking Methods 0.000 description 4
- 150000002513 isocyanates Chemical class 0.000 description 4
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 4
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- 239000004814 polyurethane Substances 0.000 description 4
- 206010000269 abscess Diseases 0.000 description 3
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- 239000011148 porous material Substances 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- 239000004604 Blowing Agent Substances 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical group C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- 239000004593 Epoxy Substances 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 239000012752 auxiliary agent Substances 0.000 description 2
- 210000004027 cell Anatomy 0.000 description 2
- ZSWFCLXCOIISFI-UHFFFAOYSA-N cyclopentadiene Chemical compound C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 229920002521 macromolecule Polymers 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 239000000376 reactant Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 239000012974 tin catalyst Substances 0.000 description 2
- PMJHHCWVYXUKFD-SNAWJCMRSA-N (E)-1,3-pentadiene Chemical compound C\C=C\C=C PMJHHCWVYXUKFD-SNAWJCMRSA-N 0.000 description 1
- STMDPCBYJCIZOD-UHFFFAOYSA-N 2-(2,4-dinitroanilino)-4-methylpentanoic acid Chemical group CC(C)CC(C(O)=O)NC1=CC=C([N+]([O-])=O)C=C1[N+]([O-])=O STMDPCBYJCIZOD-UHFFFAOYSA-N 0.000 description 1
- GTACSIONMHMRPD-UHFFFAOYSA-N 2-[4-[2-(benzenesulfonamido)ethylsulfanyl]-2,6-difluorophenoxy]acetamide Chemical compound C1=C(F)C(OCC(=O)N)=C(F)C=C1SCCNS(=O)(=O)C1=CC=CC=C1 GTACSIONMHMRPD-UHFFFAOYSA-N 0.000 description 1
- ATVJXMYDOSMEPO-UHFFFAOYSA-N 3-prop-2-enoxyprop-1-ene Chemical group C=CCOCC=C ATVJXMYDOSMEPO-UHFFFAOYSA-N 0.000 description 1
- 101710130081 Aspergillopepsin-1 Proteins 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- 102100031007 Cytosolic non-specific dipeptidase Human genes 0.000 description 1
- 239000004641 Diallyl-phthalate Substances 0.000 description 1
- HECLRDQVFMWTQS-UHFFFAOYSA-N Dicyclopentadiene Chemical compound C1C2C3CC=CC3C1C=C2 HECLRDQVFMWTQS-UHFFFAOYSA-N 0.000 description 1
- 229910002621 H2PtCl6 Inorganic materials 0.000 description 1
- 229920000079 Memory foam Polymers 0.000 description 1
- 229910018540 Si C Inorganic materials 0.000 description 1
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical compound C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- QUDWYFHPNIMBFC-UHFFFAOYSA-N bis(prop-2-enyl) benzene-1,2-dicarboxylate Chemical compound C=CCOC(=O)C1=CC=CC=C1C(=O)OCC=C QUDWYFHPNIMBFC-UHFFFAOYSA-N 0.000 description 1
- 230000017531 blood circulation Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
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- 230000009477 glass transition Effects 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 230000003301 hydrolyzing effect Effects 0.000 description 1
- 238000006459 hydrosilylation reaction Methods 0.000 description 1
- 230000016784 immunoglobulin production Effects 0.000 description 1
- 238000001802 infusion Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 description 1
- 239000008210 memory foam Substances 0.000 description 1
- NFWSQSCIDYBUOU-UHFFFAOYSA-N methylcyclopentadiene Chemical compound CC1=CC=CC1 NFWSQSCIDYBUOU-UHFFFAOYSA-N 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000006911 nucleation Effects 0.000 description 1
- 238000010899 nucleation Methods 0.000 description 1
- 125000000963 oxybis(methylene) group Chemical group [H]C([H])(*)OC([H])([H])* 0.000 description 1
- 208000035824 paresthesia Diseases 0.000 description 1
- 238000005191 phase separation Methods 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 125000003367 polycyclic group Chemical group 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- UIDUKLCLJMXFEO-UHFFFAOYSA-N propylsilane Chemical compound CCC[SiH3] UIDUKLCLJMXFEO-UHFFFAOYSA-N 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 229910010271 silicon carbide Inorganic materials 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Silicon Polymers (AREA)
- Polyurethanes Or Polyureas (AREA)
Abstract
Description
测量参数 | 对照组 | 组1 | 组2 |
熟化高度(mm) | 100.0 | 102.4 | 103.0 |
吐气时间(s) | 123 | 124 | 128 |
收缩(是/否) | No | No | No |
泡孔结构 | 细小 | 细小 | 超细小 |
压缩变形恢复时间(s) | 5 | 3 | 6 |
透气性(L/min) | 0.4 | 2.4 | 2.0 |
泡沫体密度(kg/m3) | 51.74 | 51.36 | 51.20 |
泡沫体手感 | 柔软 | 非常柔软 | 非常柔软 |
测量参数 | 对照组 | 组1 |
上升高度(cm) | 37.9 | 37.9 |
吐气时间(s) | 100 | 98 |
泡沫体密度(g/cm3) | 15.15 | 15.18 |
泡孔结构 | 细小 | 细小 |
透气性(L/min) | 13.7 | 16.4 |
Claims (3)
Priority Applications (1)
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CN201410648652.6A CN104403063B (zh) | 2014-11-14 | 2014-11-14 | 一种有机硅共聚物表面活性剂及其应用 |
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CN201410648652.6A CN104403063B (zh) | 2014-11-14 | 2014-11-14 | 一种有机硅共聚物表面活性剂及其应用 |
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CN104403063A CN104403063A (zh) | 2015-03-11 |
CN104403063B true CN104403063B (zh) | 2017-12-19 |
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Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104987524B (zh) * | 2015-08-13 | 2017-12-22 | 上海麦浦新材料科技有限公司 | 一种活性开孔剂、网状聚氨酯泡沫体及其制备方法 |
CN105085928B (zh) * | 2015-08-20 | 2017-07-25 | 江苏奥斯佳材料科技有限公司 | 一种泡沫稳定剂在制备聚氨酯发泡产品中的应用 |
CN105085929B (zh) * | 2015-08-20 | 2017-07-21 | 江苏奥斯佳材料科技有限公司 | 一种聚氨酯表面处理剂和在合成聚氨酯材料中的应用 |
CN105694054A (zh) * | 2016-04-15 | 2016-06-22 | 江门市中联塑化科技有限公司 | 一种亲水性有机硅微球、制备方法及应用 |
CN109485855A (zh) * | 2018-11-19 | 2019-03-19 | 江西麦豪化工科技有限公司 | 一种阻燃型有机硅表面活性剂及其应用 |
CN110283323A (zh) * | 2019-06-26 | 2019-09-27 | 上海麦浦新材料科技有限公司 | 一种有机硅共聚物表面活性剂及其应用 |
CN110982106A (zh) * | 2019-12-27 | 2020-04-10 | 江苏美思德化学股份有限公司 | 一种有机硅表面活性剂、软质聚氨酯泡沫及其制备方法 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2132252A2 (en) * | 2007-03-08 | 2009-12-16 | Momentive Performance Materials Inc. | Hydrolysis resistant organomodified trisiloxane surfactants |
CN101821319A (zh) * | 2007-08-10 | 2010-09-01 | 莫门蒂夫性能材料股份有限公司 | 用于聚氨酯泡沫的有机硅共聚物表面活性剂 |
CN102015838A (zh) * | 2008-04-03 | 2011-04-13 | 迈图高新材料责任有限公司 | 含有有机硅表面活性剂的聚氨酯泡沫 |
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2014
- 2014-11-14 CN CN201410648652.6A patent/CN104403063B/zh active Active
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2132252A2 (en) * | 2007-03-08 | 2009-12-16 | Momentive Performance Materials Inc. | Hydrolysis resistant organomodified trisiloxane surfactants |
CN101821319A (zh) * | 2007-08-10 | 2010-09-01 | 莫门蒂夫性能材料股份有限公司 | 用于聚氨酯泡沫的有机硅共聚物表面活性剂 |
CN102015838A (zh) * | 2008-04-03 | 2011-04-13 | 迈图高新材料责任有限公司 | 含有有机硅表面活性剂的聚氨酯泡沫 |
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Address after: 201507 Shanghai city Jinshan District Caojing town industry Road No. 88 building 3 Patentee after: Shanghai Mahou New Material Technology Co.,Ltd. Address before: 201507 Shanghai city Jinshan District Caojing town industry Road No. 88 building 3 Patentee before: SHANGHAI MAIPU NEW MATERIAL TECHNOLOGY Co.,Ltd. |
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Denomination of invention: An Organosilicon Copolymer Surfactant and Its Application Granted publication date: 20171219 Pledgee: Agricultural Bank of China Limited Shanghai Fengxian Branch Pledgor: Shanghai Mahou New Material Technology Co.,Ltd. Registration number: Y2024310000073 |