CN104364201B - 用于制备锂复合过渡金属氧化物的前体、用于制备所述前体的方法和锂复合过渡金属氧化物 - Google Patents

用于制备锂复合过渡金属氧化物的前体、用于制备所述前体的方法和锂复合过渡金属氧化物 Download PDF

Info

Publication number
CN104364201B
CN104364201B CN201380031477.XA CN201380031477A CN104364201B CN 104364201 B CN104364201 B CN 104364201B CN 201380031477 A CN201380031477 A CN 201380031477A CN 104364201 B CN104364201 B CN 104364201B
Authority
CN
China
Prior art keywords
transition metal
metal precursor
reducing agent
mol
lithium
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201380031477.XA
Other languages
English (en)
Chinese (zh)
Other versions
CN104364201A (zh
Inventor
朴炳天
姜成勋
姜玟锡
郑王谟
申昊锡
朴商珉
闵根基
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
LG Energy Solution Ltd
Original Assignee
LG Chem Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by LG Chem Ltd filed Critical LG Chem Ltd
Publication of CN104364201A publication Critical patent/CN104364201A/zh
Application granted granted Critical
Publication of CN104364201B publication Critical patent/CN104364201B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/50—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
    • H01M4/505—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G45/00—Compounds of manganese
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G53/00—Compounds of nickel
    • C01G53/40—Complex oxides containing nickel and at least one other metal element
    • C01G53/42—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2
    • C01G53/44—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2 containing manganese
    • C01G53/54—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2 containing manganese of the type (Mn2O4)-, e.g. Li(NixMn2-x)O4 or Li(MyNixMn2-x-y)O4
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G53/00—Compounds of nickel
    • C01G53/80—Compounds containing nickel, with or without oxygen or hydrogen, and containing one or more other elements
    • C01G53/84—Hydroxides
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/01—Particle morphology depicted by an image
    • C01P2004/03—Particle morphology depicted by an image obtained by SEM
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/60—Particles characterised by their size
    • C01P2004/61—Micrometer sized, i.e. from 1-100 micrometer
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/80—Particles consisting of a mixture of two or more inorganic phases
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/11—Powder tap density
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/40—Electric properties
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/52—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
    • H01M4/525—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
    • Y02T10/00—Road transport of goods or passengers
    • Y02T10/60—Other road transportation technologies with climate change mitigation effect
    • Y02T10/70—Energy storage systems for electromobility, e.g. batteries

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)
CN201380031477.XA 2012-07-09 2013-07-03 用于制备锂复合过渡金属氧化物的前体、用于制备所述前体的方法和锂复合过渡金属氧化物 Active CN104364201B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
KR10-2012-0074278 2012-07-09
KR20120074278 2012-07-09
PCT/KR2013/005903 WO2014010862A1 (ko) 2012-07-09 2013-07-03 리튬 복합 전이금속 산화물 제조용 전구체, 그 제조방법, 및 리튬 복합 전이금속 산화물

Publications (2)

Publication Number Publication Date
CN104364201A CN104364201A (zh) 2015-02-18
CN104364201B true CN104364201B (zh) 2017-04-12

Family

ID=49916261

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201380031477.XA Active CN104364201B (zh) 2012-07-09 2013-07-03 用于制备锂复合过渡金属氧化物的前体、用于制备所述前体的方法和锂复合过渡金属氧化物

Country Status (10)

Country Link
US (1) US9966600B2 (enExample)
EP (1) EP2871161B1 (enExample)
JP (1) JP6072235B2 (enExample)
KR (2) KR101490852B1 (enExample)
CN (1) CN104364201B (enExample)
BR (1) BR112014031358B8 (enExample)
IN (1) IN2014DN10250A (enExample)
PL (1) PL2871161T3 (enExample)
TW (1) TWI464948B (enExample)
WO (1) WO2014010862A1 (enExample)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101497909B1 (ko) 2012-05-04 2015-03-03 주식회사 엘지화학 리튬 복합 전이금속 산화물 제조용 전구체 및 그 제조방법
CN104334499A (zh) 2012-07-09 2015-02-04 株式会社Lg化学 用于制备锂复合过渡金属氧化物的前体
KR101506640B1 (ko) * 2014-02-11 2015-03-27 한국화학연구원 이종 복합 소재를 이용한 전극 활물질 및 이의 제조방법
KR102273779B1 (ko) * 2014-04-04 2021-07-06 삼성에스디아이 주식회사 복합양극활물질 제조방법, 복합양극활물질 및 이를 채용한 양극과 리튬전지
KR101848979B1 (ko) 2014-10-31 2018-05-24 주식회사 엘지화학 전이금속 산화물 전구체, 리튬 복합 전이금속 산화물, 이를 포함하는 양극 및 이차전지
CN104577100A (zh) * 2014-12-13 2015-04-29 山东精工电子科技有限公司 通过添加高分子糖类作为成形介质制备锂离子二次电池正极材料LiNi0.5Co0.2Mn0.3O2的方法
EP3347936A4 (en) * 2015-09-11 2019-02-27 Umicore LITHIUM METAL OXIDE MATERIAL, USE THEREOF IN A POSITIVE ELECTRODE OF A SECONDARY BATTERY AND METHOD FOR PRODUCING SUCH A LITHIUM METAL OXIDE MATERIAL
EP3281915B1 (en) * 2016-08-10 2019-02-20 Umicore Precursors for lithium transition metal oxide cathode materials for rechargeable batteries
JP6980053B2 (ja) * 2020-05-07 2021-12-15 住友化学株式会社 リチウム二次電池用正極活物質前駆体、リチウム二次電池用正極活物質前駆体の製造方法及びリチウム二次電池用正極活物質の製造方法
WO2023070368A1 (zh) * 2021-10-27 2023-05-04 宁德时代新能源科技股份有限公司 锂镍锰复合氧化物材料、二次电池和用电装置
KR20260077244A (ko) * 2024-11-21 2026-05-28 포스코홀딩스 주식회사 리튬 이차 전지용 양극 활물질 전구체, 이의 제조방법 및 이에 의해 제조된 리튬 이차 전지용 양극 활물질

Family Cites Families (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4032624B2 (ja) * 2000-09-26 2008-01-16 三菱化学株式会社 リチウム遷移金属複合酸化物の製造方法
JP3827545B2 (ja) 2001-09-13 2006-09-27 松下電器産業株式会社 正極活物質、その製造方法および非水電解質二次電池
JP4475941B2 (ja) * 2003-12-12 2010-06-09 日本化学工業株式会社 リチウムマンガンニッケル複合酸化物の製造方法
JP4411157B2 (ja) 2004-07-27 2010-02-10 日本化学工業株式会社 リチウムマンガンニッケル系複合酸化物、その製造方法及びそれを用いたリチウム二次電池
WO2006071972A2 (en) * 2004-12-28 2006-07-06 Boston-Power, Inc. Lithium-ion secondary battery
JP2006219323A (ja) * 2005-02-09 2006-08-24 Sumitomo Metal Mining Co Ltd リチウムマンガンニッケルアルミニウム複合酸化物およびその製造方法
KR100633287B1 (ko) * 2005-07-05 2006-10-11 한양대학교 산학협력단 고용량, 고율특성의 이중층 구조를 가지는 리튬이차전지용양극 활물질, 그 제조 방법 및 그를 사용한 리튬이차전지
CN101282911A (zh) * 2005-08-12 2008-10-08 户田工业欧洲有限公司 无机化合物
KR100872370B1 (ko) * 2007-03-29 2008-12-05 대정이엠(주) 리튬 이차전지용 스피넬형 양극 활물질 및 그 제조방법
KR100960137B1 (ko) * 2007-12-12 2010-05-27 주식회사 에너세라믹 리튬 이차 전지용 양극 활물질 및 이를 포함하는 리튬 이차전지
KR100999563B1 (ko) * 2008-01-14 2010-12-08 한양대학교 산학협력단 리튬 이차 전지용 양극 활물질, 이의 제조방법, 및 이를포함하는 리튬 이차 전지
WO2009098835A1 (ja) * 2008-02-04 2009-08-13 Panasonic Corporation リチウム含有遷移金属酸化物の製造方法
KR100959589B1 (ko) * 2008-04-03 2010-05-27 주식회사 엘지화학 리튬 복합 전이금속 산화물 제조용 신규 전구체
US8394299B2 (en) 2008-04-03 2013-03-12 Lg Chem, Ltd. Precursor for the preparation of a lithium composite transition metal oxide
US8268198B2 (en) 2008-04-03 2012-09-18 Lg Chem, Ltd. Precursor for preparation of lithium transition metal oxide
US8580155B2 (en) * 2008-09-03 2013-11-12 Sumitomo Osaka Cement Co., Ltd. Method for producing electrode material, electrode material, electrode and battery
US20110250499A1 (en) * 2009-04-03 2011-10-13 Hidekazu Hiratsuka Positive electrode active material for lithium ion secondary battery, method for producing the same, and lithium ion secondary battery
CN102498609B (zh) * 2009-09-18 2015-03-25 松下电器产业株式会社 锂二次电池中的正极活性物质的充放电方法、以及包含锂二次电池的充放电系统、电池包、电池模块、电子设备和车辆
KR101217453B1 (ko) * 2009-12-24 2013-01-02 제이에이치화학공업(주) 리튬이차전지 양극활물질용 전구체인 니켈계 복합금속수산화물 및 그 제조방법
CN102306776A (zh) * 2011-08-26 2012-01-04 北大先行科技产业有限公司 一种锂离子电池正极材料的制备方法
JP5863065B2 (ja) * 2011-12-09 2016-02-16 株式会社Ｇｓユアサ 非水電解質二次電池用活物質、非水電解質二次電池用電極及び非水電解質二次電池
KR101497909B1 (ko) * 2012-05-04 2015-03-03 주식회사 엘지화학 리튬 복합 전이금속 산화물 제조용 전구체 및 그 제조방법
KR20130125124A (ko) * 2012-05-08 2013-11-18 한국과학기술연구원 리튬이차전지용 나노복합체 양극 활물질을 제조하는 방법

Also Published As

Publication number Publication date
BR112014031358A2 (pt) 2017-06-27
KR101490852B1 (ko) 2015-02-09
EP2871161A1 (en) 2015-05-13
BR112014031358B1 (pt) 2021-08-24
TW201419638A (zh) 2014-05-16
EP2871161A4 (en) 2016-01-27
KR20140007748A (ko) 2014-01-20
KR20140130376A (ko) 2014-11-10
US9966600B2 (en) 2018-05-08
BR112014031358B8 (pt) 2023-01-17
US20150090926A1 (en) 2015-04-02
CN104364201A (zh) 2015-02-18
PL2871161T3 (pl) 2019-08-30
IN2014DN10250A (enExample) 2015-08-07
JP6072235B2 (ja) 2017-02-01
TWI464948B (zh) 2014-12-11
WO2014010862A1 (ko) 2014-01-16
JP2015523955A (ja) 2015-08-20
EP2871161B1 (en) 2019-03-13

Similar Documents

Publication Publication Date Title
CN102272986B (zh) 锂二次电池用正极活性材料
JP6072235B2 (ja) リチウム複合遷移金属酸化物製造用前駆体、及びその製造方法
CN104303345B (zh) 用于制备锂复合过渡金属氧化物的前体及其制备方法
CN107925077A (zh) 用于制造包含具有多层结构的金属氧化物的正极活性材料的前体和使用所述前体制造的锂二次电池用正极活性材料
CN102272984A (zh) 锂二次电池用正极活性材料
JP6483723B2 (ja) 正極活物質及びそれを含むリチウム二次電池
CN104364944B (zh) 正极活性材料和包含其的锂二次电池
CN103975464B (zh) 锂二次电池用锂复合过渡金属氧化物的前体粒子及包含其的正极活性材料
US10903489B2 (en) Precursor for preparation of lithium composite transition metal oxide, method for preparing the same and lithium composite transition metal oxide obtained from the same
KR20160066227A (ko) 양극 활물질의 제조방법 및 이로부터 제조되는 양극 활물질
KR101570970B1 (ko) 리튬 복합 전이금속 산화물 제조용 전구체

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant
TR01 Transfer of patent right
TR01 Transfer of patent right

Effective date of registration: 20211130

Address after: Seoul, South Kerean

Patentee after: LG Energy Solution

Address before: Seoul, South Kerean

Patentee before: LG CHEM, Ltd.