TWI464948B - 用於製備鋰複合過渡金屬氧化物之前驅物、製備該前驅物之方法以及鋰複合過渡金屬氧化物 - Google Patents

用於製備鋰複合過渡金屬氧化物之前驅物、製備該前驅物之方法以及鋰複合過渡金屬氧化物 Download PDF

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TWI464948B
TWI464948B TW102124125A TW102124125A TWI464948B TW I464948 B TWI464948 B TW I464948B TW 102124125 A TW102124125 A TW 102124125A TW 102124125 A TW102124125 A TW 102124125A TW I464948 B TWI464948 B TW I464948B
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Taiwan
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transition metal
precursor
metal precursor
lithium
reducing agent
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TW102124125A
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English (en)
Chinese (zh)
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TW201419638A (zh
Inventor
朴炳天
姜成勳
姜玟錫
鄭王謨
申昊錫
朴商珉
閔根基
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Ｌｇ化學公司
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    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G45/00—Compounds of manganese
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/50—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
    • H01M4/505—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G53/00—Compounds of nickel
    • C01G53/40—Complex oxides containing nickel and at least one other metal element
    • C01G53/42—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2
    • C01G53/44—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2 containing manganese
    • C01G53/54—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2 containing manganese of the type (Mn2O4)-, e.g. Li(NixMn2-x)O4 or Li(MyNixMn2-x-y)O4
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G53/00—Compounds of nickel
    • C01G53/80—Compounds containing nickel, with or without oxygen or hydrogen, and containing one or more other elements
    • C01G53/84—Hydroxides
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/01—Particle morphology depicted by an image
    • C01P2004/03—Particle morphology depicted by an image obtained by SEM
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/60—Particles characterised by their size
    • C01P2004/61—Micrometer sized, i.e. from 1-100 micrometer
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/80—Particles consisting of a mixture of two or more inorganic phases
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/11—Powder tap density
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/40—Electric properties
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/52—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
    • H01M4/525—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
    • Y02T10/00—Road transport of goods or passengers
    • Y02T10/60—Other road transportation technologies with climate change mitigation effect
    • Y02T10/70—Energy storage systems for electromobility, e.g. batteries

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)
TW102124125A 2012-07-09 2013-07-05 用於製備鋰複合過渡金屬氧化物之前驅物、製備該前驅物之方法以及鋰複合過渡金屬氧化物 TWI464948B (zh)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
KR20120074278 2012-07-09

Publications (2)

Publication Number Publication Date
TW201419638A TW201419638A (zh) 2014-05-16
TWI464948B true TWI464948B (zh) 2014-12-11

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TW102124125A TWI464948B (zh) 2012-07-09 2013-07-05 用於製備鋰複合過渡金屬氧化物之前驅物、製備該前驅物之方法以及鋰複合過渡金屬氧化物

Country Status (10)

Country Link
US (1) US9966600B2 (enExample)
EP (1) EP2871161B1 (enExample)
JP (1) JP6072235B2 (enExample)
KR (2) KR101490852B1 (enExample)
CN (1) CN104364201B (enExample)
BR (1) BR112014031358B8 (enExample)
IN (1) IN2014DN10250A (enExample)
PL (1) PL2871161T3 (enExample)
TW (1) TWI464948B (enExample)
WO (1) WO2014010862A1 (enExample)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101497909B1 (ko) 2012-05-04 2015-03-03 주식회사 엘지화학 리튬 복합 전이금속 산화물 제조용 전구체 및 그 제조방법
CN104334499A (zh) 2012-07-09 2015-02-04 株式会社Lg化学 用于制备锂复合过渡金属氧化物的前体
KR101506640B1 (ko) * 2014-02-11 2015-03-27 한국화학연구원 이종 복합 소재를 이용한 전극 활물질 및 이의 제조방법
KR102273779B1 (ko) * 2014-04-04 2021-07-06 삼성에스디아이 주식회사 복합양극활물질 제조방법, 복합양극활물질 및 이를 채용한 양극과 리튬전지
KR101848979B1 (ko) 2014-10-31 2018-05-24 주식회사 엘지화학 전이금속 산화물 전구체, 리튬 복합 전이금속 산화물, 이를 포함하는 양극 및 이차전지
CN104577100A (zh) * 2014-12-13 2015-04-29 山东精工电子科技有限公司 通过添加高分子糖类作为成形介质制备锂离子二次电池正极材料LiNi0.5Co0.2Mn0.3O2的方法
EP3347936A4 (en) * 2015-09-11 2019-02-27 Umicore LITHIUM METAL OXIDE MATERIAL, USE THEREOF IN A POSITIVE ELECTRODE OF A SECONDARY BATTERY AND METHOD FOR PRODUCING SUCH A LITHIUM METAL OXIDE MATERIAL
EP3281915B1 (en) * 2016-08-10 2019-02-20 Umicore Precursors for lithium transition metal oxide cathode materials for rechargeable batteries
JP6980053B2 (ja) * 2020-05-07 2021-12-15 住友化学株式会社 リチウム二次電池用正極活物質前駆体、リチウム二次電池用正極活物質前駆体の製造方法及びリチウム二次電池用正極活物質の製造方法
WO2023070368A1 (zh) * 2021-10-27 2023-05-04 宁德时代新能源科技股份有限公司 锂镍锰复合氧化物材料、二次电池和用电装置
KR20260077244A (ko) * 2024-11-21 2026-05-28 포스코홀딩스 주식회사 리튬 이차 전지용 양극 활물질 전구체, 이의 제조방법 및 이에 의해 제조된 리튬 이차 전지용 양극 활물질

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TW201000407A (en) * 2008-04-03 2010-01-01 Lg Chemical Ltd Precursor for preparation of lithium transition metal oxide
TW201114095A (en) * 2004-12-28 2011-04-16 Boston Power Inc Lithium-ion secondary battery
CN102306776A (zh) * 2011-08-26 2012-01-04 北大先行科技产业有限公司 一种锂离子电池正极材料的制备方法

Family Cites Families (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4032624B2 (ja) * 2000-09-26 2008-01-16 三菱化学株式会社 リチウム遷移金属複合酸化物の製造方法
JP3827545B2 (ja) 2001-09-13 2006-09-27 松下電器産業株式会社 正極活物質、その製造方法および非水電解質二次電池
JP4475941B2 (ja) * 2003-12-12 2010-06-09 日本化学工業株式会社 リチウムマンガンニッケル複合酸化物の製造方法
JP4411157B2 (ja) 2004-07-27 2010-02-10 日本化学工業株式会社 リチウムマンガンニッケル系複合酸化物、その製造方法及びそれを用いたリチウム二次電池
JP2006219323A (ja) * 2005-02-09 2006-08-24 Sumitomo Metal Mining Co Ltd リチウムマンガンニッケルアルミニウム複合酸化物およびその製造方法
KR100633287B1 (ko) * 2005-07-05 2006-10-11 한양대학교 산학협력단 고용량, 고율특성의 이중층 구조를 가지는 리튬이차전지용양극 활물질, 그 제조 방법 및 그를 사용한 리튬이차전지
CN101282911A (zh) * 2005-08-12 2008-10-08 户田工业欧洲有限公司 无机化合物
KR100872370B1 (ko) * 2007-03-29 2008-12-05 대정이엠(주) 리튬 이차전지용 스피넬형 양극 활물질 및 그 제조방법
KR100960137B1 (ko) * 2007-12-12 2010-05-27 주식회사 에너세라믹 리튬 이차 전지용 양극 활물질 및 이를 포함하는 리튬 이차전지
KR100999563B1 (ko) * 2008-01-14 2010-12-08 한양대학교 산학협력단 리튬 이차 전지용 양극 활물질, 이의 제조방법, 및 이를포함하는 리튬 이차 전지
WO2009098835A1 (ja) * 2008-02-04 2009-08-13 Panasonic Corporation リチウム含有遷移金属酸化物の製造方法
KR100959589B1 (ko) * 2008-04-03 2010-05-27 주식회사 엘지화학 리튬 복합 전이금속 산화물 제조용 신규 전구체
US8394299B2 (en) 2008-04-03 2013-03-12 Lg Chem, Ltd. Precursor for the preparation of a lithium composite transition metal oxide
US8580155B2 (en) * 2008-09-03 2013-11-12 Sumitomo Osaka Cement Co., Ltd. Method for producing electrode material, electrode material, electrode and battery
US20110250499A1 (en) * 2009-04-03 2011-10-13 Hidekazu Hiratsuka Positive electrode active material for lithium ion secondary battery, method for producing the same, and lithium ion secondary battery
CN102498609B (zh) * 2009-09-18 2015-03-25 松下电器产业株式会社 锂二次电池中的正极活性物质的充放电方法、以及包含锂二次电池的充放电系统、电池包、电池模块、电子设备和车辆
KR101217453B1 (ko) * 2009-12-24 2013-01-02 제이에이치화학공업(주) 리튬이차전지 양극활물질용 전구체인 니켈계 복합금속수산화물 및 그 제조방법
JP5863065B2 (ja) * 2011-12-09 2016-02-16 株式会社Ｇｓユアサ 非水電解質二次電池用活物質、非水電解質二次電池用電極及び非水電解質二次電池
KR101497909B1 (ko) * 2012-05-04 2015-03-03 주식회사 엘지화학 리튬 복합 전이금속 산화물 제조용 전구체 및 그 제조방법
KR20130125124A (ko) * 2012-05-08 2013-11-18 한국과학기술연구원 리튬이차전지용 나노복합체 양극 활물질을 제조하는 방법

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TW201114095A (en) * 2004-12-28 2011-04-16 Boston Power Inc Lithium-ion secondary battery
TW201000407A (en) * 2008-04-03 2010-01-01 Lg Chemical Ltd Precursor for preparation of lithium transition metal oxide
CN102306776A (zh) * 2011-08-26 2012-01-04 北大先行科技产业有限公司 一种锂离子电池正极材料的制备方法

Also Published As

Publication number Publication date
BR112014031358A2 (pt) 2017-06-27
KR101490852B1 (ko) 2015-02-09
EP2871161A1 (en) 2015-05-13
BR112014031358B1 (pt) 2021-08-24
TW201419638A (zh) 2014-05-16
EP2871161A4 (en) 2016-01-27
KR20140007748A (ko) 2014-01-20
KR20140130376A (ko) 2014-11-10
US9966600B2 (en) 2018-05-08
BR112014031358B8 (pt) 2023-01-17
US20150090926A1 (en) 2015-04-02
CN104364201A (zh) 2015-02-18
PL2871161T3 (pl) 2019-08-30
IN2014DN10250A (enExample) 2015-08-07
JP6072235B2 (ja) 2017-02-01
CN104364201B (zh) 2017-04-12
WO2014010862A1 (ko) 2014-01-16
JP2015523955A (ja) 2015-08-20
EP2871161B1 (en) 2019-03-13

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