CN104355606A - Corrosion resistant brick - Google Patents
Corrosion resistant brick Download PDFInfo
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- CN104355606A CN104355606A CN201410591795.8A CN201410591795A CN104355606A CN 104355606 A CN104355606 A CN 104355606A CN 201410591795 A CN201410591795 A CN 201410591795A CN 104355606 A CN104355606 A CN 104355606A
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- albite
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Abstract
The invention relates to a corrosion resistant brick. The corrosion resistant brick is characterized in that the green brick comprises the following raw materials in parts by weight: 8-12 parts of Zhangzhou carclazyte, 4-8 parts of Xiadai carclazyte, 3-10 parts of Zhangpu soil 1#, 10-15 parts of washed kaolin, 8-12 parts of washed sand, 1-5 parts of Longshan albite 4#, 8-12 parts of Longshan albite 2#, 1-3 parts of Changtai kaolin, 12-18 parts of Longhai feldspar 1#, 12-18 parts of Daping stone seeds, 3-7 parts of bentonite and 2-6 parts of Zhangpu soil 2# (dust). The corrosion resistant brick provided by the invention is high in corrosion resistance, low in water absorption and high in strength, and is simple in production process and low in cost.
Description
Technical field
The invention belongs to ceramic tile technical field, be specifically related to a kind of corrosion resistant brick.
Background technology
Ceramic product all has certain erosion resistance, along with National Industrial development, general anti-corrosion brick far can not meet industrial requirement, as: the industry such as oil, chemical industry, pharmacy, food, papermaking, chemical fertilizer, agricultural chemicals, chemical fibre, weaving, smelting, power plant, they are had higher requirement to the erosion resistance of product, require that energy stable existence is under strong acid-base.Improve ceramic tile antiseptic property, also require that ceramic tile possesses low water absorption, high compressive strength etc. simultaneously.But current anticorrosive tile as CN200910039375.8 the performance index of ceramic tile reported be not suitable for using in some place.
Summary of the invention
The object of this invention is to provide a kind of strong antiseptic property, low water absorption, high strength; And the ceramic tile that production technique is simple, with low cost.
A kind of anti-corrosion brick, is characterized in that: adobe body comprises the raw material composition of following parts by weight: ZhangZhou carclazyte 8 ~ 12 parts, under wear carclazyte 4 ~ 8 parts, Zhangpu soil 1
#3 ~ 10 parts, water-washed kaoline 10 ~ 15 parts, washed-out sand 8 ~ 12 parts, Longshan albite 4
#1 ~ 5 part, Longshan albite 2
#8 ~ 12 parts, Changtai kaolin 1 ~ 3 part, Longhai City's feldspar 1
#12 ~ 18 parts, greatly level ground chicken girt 12 ~ 18 parts, wilkinite 3 ~ 7 parts, Zhangpu soil 2
#(dirt) 2 ~ 6 parts.
In one embodiment, its adobe body of described anti-corrosion brick comprise following parts by weight raw material composition: ZhangZhou carclazyte 10 parts, under wear carclazyte 6 parts, Zhangpu soil 1
#7 parts, water-washed kaoline 12 parts, washed-out sand 10 parts, Longshan albite 4
#3.5 parts, Longshan albite 2
#10 parts, Changtai kaolin 2.0 parts, Longhai City's feldspar 1
#15 parts, greatly level ground chicken girt 15 parts, wilkinite 5 parts, Zhangpu soil 2
#(dirt) 4 parts.
The porcelain base substrate of described anti-corrosion brick pottery, its chemical constitution, according to weight percent meter, comprises following composition:
In order to better protect ceramic body not corroded, and increasing product surface decorative effect, one deck ceramic glaze can be executed on anti-corrosion brick.
The present invention provides a kind of anti-corrosion brick glaze on the other hand, and described glaze comprises the raw material composition of following parts by weight: TTKG556 80 ~ 92 parts, 3 ~ 7 parts, aluminum oxide, corundum (aluminum oxide (Al
2o
3) 4 ~ 10 parts, CMC (Xylo-Mucine) 0.1 ~ 0.5 part, STPP (industrial tripoly phosphate sodium STPP) 0.3 ~ 1.0 part.
In one embodiment, described glaze comprises the raw material composition of following parts by weight: TTKG55686 part, 5 parts, aluminum oxide, corundum (aluminum oxide (Al
2o
3) 7 parts, CMC (Xylo-Mucine) 0.3 part, STPP (industrial tripoly phosphate sodium STPP) 0.7 part.
In one embodiment, described anti-corrosion brick, comprises brick idiosome and glaze, its adobe body comprise following parts by weight raw material composition: ZhangZhou carclazyte 10 parts, under wear carclazyte 6 parts, Zhangpu soil 1
#7 parts, water-washed kaoline 12 parts, washed-out sand 10 parts, Longshan albite 4
#3.5 parts, Longshan albite 2
#10 parts, Changtai kaolin 2.0 parts, Longhai City's feldspar 1
#15 parts, greatly level ground chicken girt 15 parts, wilkinite 5 parts, Zhangpu soil 2
#(dirt) 4 parts; Its glaze comprises the raw material composition of following parts by weight: TTKG556 86 parts, 5 parts, aluminum oxide, corundum (aluminum oxide (Al
2o
3) 7 parts, CMC (Xylo-Mucine) 0.3 part, STPP (industrial tripoly phosphate sodium STPP) 0.7 part.
Described its chemical constitution of anti-corrosion brick glaze, according to weight percent meter, comprises following composition:
TTKG556 is a kind of parent glaze, and be made up of raw materials such as kaolin, silica powder, lithium porcelain stone powder, burning talcum, calcium carbonate, large level ground chicken girt, Longhai City's feldspar in powder, Longshan potassium albites, its chemical constitution, according to weight percent meter, comprises following composition:
The proportion material of invention product all derives from business procurement, wherein wears down, county that Zhangpu, Changtai etc. are Zhangzhou, Fujian.In the present invention, the chemical composition of following raw materials according is roughly:
1) ZhangZhou carclazyte, under wear carclazyte, Zhangpu soil 1#, Zhangpu soil 2# (dirt), water-washed kaoline:
A kind of clay is particle very little (<2 μm) plastic aluminium silicate salt.Be made up of multiple hydrosilicate and a certain amount of aluminum oxide, alkalimetal oxide and alkaline earth metal oxide, and containing the impurity such as quartz, feldspar, mica and vitriol, sulfide, carbonate.The particle of clay mineral is tiny, is everlasting within the scope of colloid size, and in crystal or noncrystal, great majority are sheets, and minority is tubulose, bar-shaped.After clay mineral water is moistening, there is plasticity-, can be out of shape under less pressure and can maintain the original state for a long time, and specific surface area is large, with electronegativity on particle, therefore there are good physical adsorbability and chemical mobility of the surface, there is the ability with other cationic exchange.
Following four classes are divided into by its structure:
Kaolinite race (TheKaoliniteGroup), 1:1 type.
Montmorillonite race (TheMontmorillonite/SmectiteGroup), 2:1 type.
Illite race (TheIllite (orTheClay-mica) Group), 2:1 type.
Chlorite race (TheChloriteGroup), 2:1:1 type.
Wherein water-washed kaoline is tonerde, through crushing and water washing, sieve, the processes such as deironing forms.
2) Changtai kaolin:
Be a kind of based on the clay of kaolinite race clay mineral and tonstein, its mineralogical composition is primarily of kaolinite, halloysite, hydromica, illite, montmorillonite and the mineral composition such as quartz, feldspar.
Physico-chemical property: how matt, when matter is pure, face is fine and smooth in vain, as can with ash, yellow, brown isochrome time impure.Outward appearance can be loose soil block shape and densifie state sillar shape according to origin cause of formation difference.Density 2.54-2.60g/cm3.Fusing point about 1785 DEG C.Have plasticity-, wet soil can be moulded different shape and unlikely fragmentation, and can remain unchanged for a long time.
Massfraction according to its quality, plasticity-and chiltern is divided into three types:
1, hard kaoline: matter is hard, without plasticity-, tool plasticity-after pulverizing fine grinding.
2, soft kaolin: matter is soft, plasticity-is comparatively strong, chiltern massfraction <50%;
3, sandy kaoline: matter is soft, plasticity-is more weak, chiltern massfraction >50%.
3) Longshan albite 4
#, Longshan albite 2#, Longhai City feldspar 1#, large level ground chicken girt, washed-out sand:
Albite (Albite) is the one of feldspar, is the aluminosilicate (NaAlSi of sodium
3o
8).Albite is generally glassy crystal, can be colourless, also can have white, yellow, red, green or black.It is the raw material manufacturing glass and pottery.Have the composition of albite in a lot of rock, people claim such mineral to be rock forming mineral.Albite: Na
2o.Al
2o
3.6SiO
2, wherein Na
2o less than 8%, K
2o 5-6%, Al
2o
3more than 16%, SiO
270%, density 2.605g/cm
3, Mohs' hardness is 6, triclinic(crystalline)system, and color is white, fusing point 1100 DEG C.
Wherein washed-out sand is by colory feldspar, through fragmentation, ball milling, sieve, the processes such as deironing.
4) wilkinite:
Wilkinite (1.35 ~ 1.84g/cm3) be also otaylite or amargosite, and be the moisture clay pit based on montmorillonite, chemical molecular formula is: Nax (H
2o)
4(AI2-xMg0.83) Si
4o
10) (OH)
2, the layered clay mineral be made up of two-layer silicon-oxy tetrahedron therebetween one deck alumina octahedral.Can pasty state be expand into after wilkinite adds water, there is good water-swelling property and dispersion and suspension and pulping, directly introduce in formula and use.
Present invention also offers the technical process preparing anti-corrosion brick:
Electronic proportioning → raw mill → mud sieves → and mud is old → mud sieves → slurry iron-removing → mud is old → slurry granulation → powder sieves → powder deironing → powder is old → powder sieves → powder is shaping → bad soma dry → bad face humidification → execute cosmetic glaze → ink jet printing → bad body to dry → execute anticorrosion glaze → high-temperature calcination → product deburring → product and sort → the examination and test of products-product warehousing.
Detect according to GB/T4100-2006 GB, the folding strength of product of the present invention is more than 55Mpa; Can resistance to any strong acid except hydrofluoric acid; Can resistance to highly basic if organic metallide and inorganic strong alkali are as aminocompound; And specific absorption≤0.05.
Beneficial effect of the present invention:
The present invention adopts that the mine tailing of Zhangzhou, Fujian, soil property can prepare low water absorption by rational proportioning, glassy phase is few, crystalline phase is many and well-developed high-strength ceramic base substrate, reduces the corrosive nature of acid-base material to stupalith.Anti-acid ceramic base substrate tool
There is following advantage:
1. the contact gear ratio surface of acid-base material and ceramic body diminishes, thus reaches protective effect.
2. there is well-developed crystalline framework in ceramic body, not easily corroded by acid and alkali substance.
3. acid-alkali-corrosive-resisting, high strength, except the scope of existing use, expands field of employment.
4. reduce the calcium magnesia raw material of more use in architectural pottery Product Process, improve the sial content in product, thus increase anticorrosion
Performance.
Embodiment
In order to make those skilled in the art understand technical scheme of the present invention better, below disclose further some non-limiting embodiments the present invention is described in further detail.
Embodiment 1
A kind of anti-corrosion brick, its adobe body comprises the raw material composition of following parts by weight: ZhangZhou carclazyte 10 parts, under wear carclazyte 6 parts, Zhangpu soil 1
#7 parts, water-washed kaoline 12 parts, washed-out sand 10 parts, Longshan albite 4
#3.5 parts, Longshan albite 2
#10 parts, Changtai kaolin 2.0 parts, Longhai City's feldspar 1
#15 parts, greatly level ground chicken girt 15 parts, wilkinite 5 parts, Zhangpu soil 2
#(dirt) 4 parts.
Embodiment 2
A kind of anti-corrosion brick, comprises brick idiosome and glaze, and its adobe body comprises the raw material composition of following parts by weight: ZhangZhou carclazyte 10 parts, under wear carclazyte 6 parts, Zhangpu soil 1
#7 parts, water-washed kaoline 12 parts, washed-out sand 10 parts, Longshan albite 4
#3.5 parts, Longshan albite 2
#10 parts, Changtai kaolin 2.0 parts, Longhai City's feldspar 1
#15 parts, greatly level ground chicken girt 15 parts, wilkinite 5 parts, Zhangpu soil 2
#(dirt) 4 parts; Its glaze comprises the raw material composition of following parts by weight: TTKG556 86 parts, 5 parts, aluminum oxide, corundum (aluminum oxide (Al
2o
3) 7 parts, CMC (Xylo-Mucine) 0.3 part, STPP (industrial tripoly phosphate sodium STPP) 0.7 part.
Its performance index of anti-corrosion brick provided by the present invention are as follows: (see table one)
Table one:
Embodiment 3
A kind of concrete steps preparing anti-corrosion brick described in embodiment 2 are:
A) material choice, according to embodiment 2, raw material and ratio thereof mix;
B) prepare burden, according to recipe requirements weigh batching (pure deviation range 30kg/ time);
C) ball milling, material: ball: water=1:1:0.8 ratio carries out tinning ball milling, Ball-milling Time 10 ~ 12 hours, ball milling fineness 1.2% ~ 1.8% (250 eye mesh screen);
D) prepare mud, mud enters iron removal system deironing after crossing 80 mesh sieves, and after deironing, mud is stored in slurry bucket old for subsequent use;
E) spray pulverization, mud sieves spray pulverization after deironing, and it is old for subsequent use that powder enters powder material tank after screening out iron, powder lot humidity 6.0% ~ 6.8%, and 40 order ~ 20 order content are that the following content of 16% ~ 25%, 100 order is less than 10%;
F) press brick, by old good powder equably cloth in a mold, be pressed into ceramic body at a particular pressure;
G) dry, the brick suppressed enters dry kiln, and under the drying system of setting, carry out drying, dried base substrate moisture content is less than 4%;
H) glazing, according to the processing parameter requirement of corresponding product, the glaze needed for preparation production, imposes on dried billet surface by glaze;
I) stamp, the billet surface printed patterns after glazing.
J) burn till, under 1220 degrees Celsius, high temperature sintering is carried out to ceramic body;
Work in-process after high temperature sintering are carried out surface finish process or edging by k) edging, polishing, sorting, packing, warehouse-in, are divided into different mass grade, with after packed in cases be finished product warehouse-in.
Method of the present invention is described by preferred embodiment, and related personnel obviously can change methods and applications as herein described or suitably change and combination in content of the present invention, spirit and scope, realizes and applies the technology of the present invention.Those skilled in the art can use for reference present disclosure, and suitable improving technique parameter realizes.Special needs to be pointed out is, all similar replacements and change apparent to those skilled in the art, they are all deemed to be included in the present invention.
Claims (8)
1. an anti-corrosion brick, is characterized in that: adobe body comprise following parts by weight raw material composition: ZhangZhou carclazyte 8 ~ 12 parts, under wear carclazyte 4 ~ 8 parts, Zhangpu soil 1
#3 ~ 10 parts, water-washed kaoline 10 ~ 15 parts, washed-out sand 8 ~ 12 parts, Longshan albite 4
#1 ~ 5 part, Longshan albite 2
#8 ~ 12 parts, Changtai kaolin 1 ~ 3 part, Longhai City's feldspar 1
#12 ~ 18 parts, greatly level ground chicken girt 12 ~ 18 parts, wilkinite 3 ~ 7 parts, Zhangpu soil 2
#(dirt) 2 ~ 6 parts.
2. anti-corrosion brick as claimed in claim 1, is characterized in that its adobe body comprises the raw material composition of following parts by weight: ZhangZhou carclazyte 10 parts, under wear carclazyte 6 parts, Zhangpu soil 1
#7 parts, water-washed kaoline 12 parts, washed-out sand 10 parts, Longshan albite 4
#3.5 parts, Longshan albite 2
#10 parts, Changtai kaolin 2.0 parts, Longhai City's feldspar 1
#15 parts, greatly level ground chicken girt 15 parts, wilkinite 5 parts, Zhangpu soil 2
#(dirt) 4 parts.
3. anti-corrosion brick as claimed in claim 1, also be included on brick idiosome and execute one deck glaze, described glaze comprises the raw material composition of following parts by weight: TTKG556 80 ~ 92 parts, 3 ~ 7 parts, aluminum oxide, 4 ~ 10 parts, corundum, Xylo-Mucine 0.1 ~ 0.5 part, industrial tripoly phosphate sodium STPP 0.3 ~ 1.0 part.
4. anti-corrosion brick as claimed in claim 3, described glaze comprises the raw material composition of following parts by weight: TTKG556 86 parts, 5 parts, aluminum oxide, 7 parts, corundum, Xylo-Mucine 0.3 part, industrial tripoly phosphate sodium STPP 0.7 part.
5. as described in claim 3 or 4 anti-corrosion brick, described TTKG556 is a kind of parent glaze, be made up of raw materials such as kaolin, silica powder, lithium porcelain stone powder, burning talcum, calcium carbonate, large level ground chicken girt, Longhai City's feldspar in powder, Longshan potassium albites, its chemical constitution, according to weight percent meter, comprises following composition:
6. anti-corrosion brick as claimed in claim 1, the adobe body of described anti-corrosion brick pottery, its chemical constitution, according to weight percent meter, comprises following composition:
7. anti-corrosion brick as claimed in claim 3, described its chemical constitution of anti-corrosion brick glaze, according to weight percent meter, comprises following composition:
8. prepare the arbitrary described anti-corrosion brick of claim 1-7 a method, its concrete steps are:
A) prepare burden, according to recipe requirements weigh batching;
B) ball milling, material: ball: water=1:1:0.8 ratio carries out tinning ball milling, Ball-milling Time 10 ~ 12 hours, ball milling fineness 1.2% ~ 1.8% (250 eye mesh screen);
C) prepare mud, mud enters iron removal system deironing after crossing 80 mesh sieves, and after deironing, mud is stored in slurry bucket old for subsequent use;
D) spray pulverization, mud sieves spray pulverization after deironing, and it is old for subsequent use that powder enters powder material tank after screening out iron, powder lot humidity 6.0% ~ 6.8%, and 40 order ~ 20 order content are that the following content of 16% ~ 25%, 100 order is less than 10%;
E) press brick, by old good powder equably cloth in a mold, be pressed into ceramic body at a particular pressure;
F) dry, the brick suppressed enters dry kiln, and under the drying system of setting, carry out drying, dried base substrate moisture content is less than 4%;
G) glazing, according to the processing parameter requirement of corresponding product, the glaze needed for preparation production, imposes on dried billet surface by glaze;
H) stamp, the billet surface printed patterns after glazing;
I) burn till, under 1220 degrees Celsius, high temperature sintering is carried out to ceramic body.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410591795.8A CN104355606B (en) | 2014-10-29 | 2014-10-29 | A kind of anti-corrosion brick |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410591795.8A CN104355606B (en) | 2014-10-29 | 2014-10-29 | A kind of anti-corrosion brick |
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| Publication Number | Publication Date |
|---|---|
| CN104355606A true CN104355606A (en) | 2015-02-18 |
| CN104355606B CN104355606B (en) | 2016-06-08 |
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ID=52522946
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|---|---|---|---|
| CN201410591795.8A Expired - Fee Related CN104355606B (en) | 2014-10-29 | 2014-10-29 | A kind of anti-corrosion brick |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105819825A (en) * | 2016-03-10 | 2016-08-03 | 万利(中国)有限公司 | Large-sized ceramic decoration thick plate, and formula and making technology thereof |
| CN106220134A (en) * | 2016-07-14 | 2016-12-14 | 万利(中国)有限公司 | A kind of abnormity deck plate |
| CN107217808A (en) * | 2017-05-04 | 2017-09-29 | 万利(中国)有限公司 | A kind of structure and preparation technology for pushing glaze decorative brick aside |
| CN111533578A (en) * | 2020-07-08 | 2020-08-14 | 佛山市东鹏陶瓷发展有限公司 | Anti-corrosion glazed tile and preparation method thereof |
| CN112878338A (en) * | 2020-12-31 | 2021-06-01 | 中建八局第三建设有限公司 | Soil fixing structure for ecological restoration of steep soil slope |
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| WO2007024062A1 (en) * | 2005-08-25 | 2007-03-01 | Shin-A At Co., Ltd | Multifunctional ceramic compounds |
| CN102153336A (en) * | 2010-12-04 | 2011-08-17 | 黄俊杰 | Heat-resistant porcelain clay for manufacturing porcelain product and heat-resistant porcelain made from same |
| CN102976721A (en) * | 2012-11-09 | 2013-03-20 | 佛山欧神诺陶瓷股份有限公司 | Low-temperature sintered ceramic glazed tile and preparation method thereof |
-
2014
- 2014-10-29 CN CN201410591795.8A patent/CN104355606B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2007024062A1 (en) * | 2005-08-25 | 2007-03-01 | Shin-A At Co., Ltd | Multifunctional ceramic compounds |
| CN102153336A (en) * | 2010-12-04 | 2011-08-17 | 黄俊杰 | Heat-resistant porcelain clay for manufacturing porcelain product and heat-resistant porcelain made from same |
| CN102976721A (en) * | 2012-11-09 | 2013-03-20 | 佛山欧神诺陶瓷股份有限公司 | Low-temperature sintered ceramic glazed tile and preparation method thereof |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105819825A (en) * | 2016-03-10 | 2016-08-03 | 万利(中国)有限公司 | Large-sized ceramic decoration thick plate, and formula and making technology thereof |
| CN105819825B (en) * | 2016-03-10 | 2018-04-06 | 万利(中国)有限公司 | A kind of large size ceramic decoration slab and Recipe |
| CN106220134A (en) * | 2016-07-14 | 2016-12-14 | 万利(中国)有限公司 | A kind of abnormity deck plate |
| CN107217808A (en) * | 2017-05-04 | 2017-09-29 | 万利(中国)有限公司 | A kind of structure and preparation technology for pushing glaze decorative brick aside |
| CN111533578A (en) * | 2020-07-08 | 2020-08-14 | 佛山市东鹏陶瓷发展有限公司 | Anti-corrosion glazed tile and preparation method thereof |
| CN112878338A (en) * | 2020-12-31 | 2021-06-01 | 中建八局第三建设有限公司 | Soil fixing structure for ecological restoration of steep soil slope |
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| Publication number | Publication date |
|---|---|
| CN104355606B (en) | 2016-06-08 |
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