CN104355606B - A kind of anti-corrosion brick - Google Patents
A kind of anti-corrosion brick Download PDFInfo
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- CN104355606B CN104355606B CN201410591795.8A CN201410591795A CN104355606B CN 104355606 B CN104355606 B CN 104355606B CN 201410591795 A CN201410591795 A CN 201410591795A CN 104355606 B CN104355606 B CN 104355606B
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Abstract
The present invention relates to a kind of anti-corrosion brick, it is characterised in that: adobe body comprises the raw material composition of following weight part number: ZhangZhou carclazyte 8��12 parts, under wear carclazyte 4��8 parts, Zhangpu soil 1#3��10 parts, water-washed kaoline 10��15 parts, washing 8��12 parts, sand, Longshan albite 4#1��5 part, Longshan albite 2#8��12 parts, Changtai kaolin 1��3 part, dragon sea feldspar 1#12��18 parts, greatly level ground chicken girt 12��18 parts, wilkinite 3��7 parts, Zhangpu soil 2#(dirt) 2��6 parts. Anti-corrosion brick provided by the present invention has strong antiseptic property, low water absorption, high strength; And production technique is simple, with low cost.
Description
Technical field
The invention belongs to ceramic tile technical field, it is specifically related to a kind of corrosion resistant brick.
Background technology
Ceramic product all has certain erosion resistance, along with country's industrial development, general anti-corrosion brick far can not meet industrial requirement, as: the industry such as oil, chemical industry, pharmacy, food, papermaking, chemical fertilizer, agricultural chemicals, chemical fibre, weaving, smelting, power plant, the erosion resistance of product is had higher requirement by they, it is desired to energy stable existence is under strong acid-base. Improve ceramic tile antiseptic property, also require that ceramic tile possesses low water absorption, high compressive strength etc. simultaneously. But the performance index of the ceramic tile that current anticorrosive tile is reported such as CN200910039375.8 are not suitable for using in some place.
Summary of the invention
It is an object of the invention to provide a kind of strong antiseptic property, low water absorption, high strength; And the ceramic tile that production technique is simple, with low cost.
A kind of anti-corrosion brick, it is characterised in that: adobe body comprises the raw material composition of following weight part number: ZhangZhou carclazyte 8��12 parts, under wear carclazyte 4��8 parts, Zhangpu soil 1#3��10 parts, water-washed kaoline 10��15 parts, washing 8��12 parts, sand, Longshan albite 4#1��5 part, Longshan albite 2#8��12 parts, Changtai kaolin 1��3 part, dragon sea feldspar 1#12��18 parts, greatly level ground chicken girt 12��18 parts, wilkinite 3��7 parts, Zhangpu soil 2#(dirt) 2��6 parts.
In one embodiment, its adobe body of described anti-corrosion brick comprise following weight part number raw material composition: ZhangZhou carclazyte 10 parts, under wear carclazyte 6 parts, Zhangpu soil 1#7 parts, water-washed kaoline 12 parts, washing 10 parts, sand, Longshan albite 4#3.5 parts, Longshan albite 2#10 parts, Changtai kaolin 2.0 parts, dragon sea feldspar 1#15 parts, greatly level ground chicken girt 15 parts, wilkinite 5 parts, Zhangpu soil 2#(dirt) 4 parts.
The porcelain base substrate of described anti-corrosion brick pottery, its chemistry composition, according to weight percent meter, comprises following composition:
In order to better protect ceramic body not corroded, and increase product surface decorative effect, it is possible on anti-corrosion brick, execute one layer of ceramic glaze.
The present invention provides a kind of anti-corrosion brick glaze on the other hand, and described glaze comprises the raw material composition of following weight part number: TTKG55680��92 part, 3��7 parts, aluminum oxide, corundum (aluminum oxide (Al2O3) 4��10 parts, CMC (Xylo-Mucine) 0.1��0.5 part, STPP (industry tripoly phosphate sodium STPP) 0.3��1.0 part.
In one embodiment, described glaze comprises the raw material composition of following weight part number: TTKG55686 part, 5 parts, aluminum oxide, corundum (aluminum oxide (Al2O3) 7 parts, CMC (Xylo-Mucine) 0.3 part, STPP (industry tripoly phosphate sodium STPP) 0.7 part.
In one embodiment, described anti-corrosion brick, comprises brick idiosome and glaze, its adobe body comprise following weight part number raw material composition: ZhangZhou carclazyte 10 parts, under wear carclazyte 6 parts, Zhangpu soil 1#7 parts, water-washed kaoline 12 parts, washing 10 parts, sand, Longshan albite 4#3.5 parts, Longshan albite 2#10 parts, Changtai kaolin 2.0 parts, dragon sea feldspar 1#15 parts, greatly level ground chicken girt 15 parts, wilkinite 5 parts, Zhangpu soil 2#(dirt) 4 parts; Its glaze comprises the raw material composition of following weight part number: TTKG55686 part, 5 parts, aluminum oxide, corundum (aluminum oxide (Al2O3) 7 parts, CMC (Xylo-Mucine) 0.3 part, STPP (industry tripoly phosphate sodium STPP) 0.7 part.
Its chemistry composition of described anti-corrosion brick glaze, according to weight percent meter, comprises following composition:
TTKG556 is a kind of basis glaze, is made up of kaolin, silica powder, lithium porcelain stone powder, burning talcum, calcium carbonate, big level ground chicken girt, the dragon sea raw material such as feldspar in powder, Longshan potassium albite, and its chemistry forms according to weight percent meter, comprises following composition:
The proportion material of invention product all derives from business procurement, wherein wears down, county that Zhangpu, Changtai etc. are ZhangZhou, Fujian. In the present invention, the chemical composition of following raw materials according is roughly:
1) ZhangZhou carclazyte, under wear carclazyte, Zhangpu soil 1#, Zhangpu soil 2# (dirt), water-washed kaoline:
A kind of clay is particle very little (< 2 ��m) plastic aluminium silicate salt. It is made up of multiple hydrosilicate and a certain amount of aluminum oxide, alkalimetal oxide and alkaline earth metal oxide, and containing impurity such as quartz, feldspar, mica and vitriol, sulfide, carbonate. The particle of clay mineral is tiny, is everlasting in colloid size range, and in crystal or noncrystal, great majority are sheets, and minority is tubulose, bar-shaped. After clay mineral water is moistening, there is plasticity-, can be out of shape under less pressure and original state can be kept for a long time, and specific surface area is big, with electronegativity on particle, therefore there are good physical adsorbability and chemical mobility of the surface, there is the ability with other cationic exchange.
It is divided into following four classes by its structure:
Kaolinite race (TheKaoliniteGroup), 1:1 type.
Montmorillonite race (TheMontmorillonite/SmectiteGroup), 2:1 type.
Illite race (TheIllite (orTheClay-mica) Group), 2:1 type.
Chlorite race (TheChloriteGroup), 2:1:1 type.
Wherein water-washed kaoline is tonerde, through crushing and water washing, sieve, the processes such as deironing and become.
2) Changtai kaolin:
Being a kind of clay based on kaolinite race clay mineral and tonstein, its mineralogical composition is primarily of kaolinite, halloysite, hydromica, illite, montmorillonite and the mineral such as quartz, feldspar composition.
Physico-chemical property: how matt, when matter is pure, face is fine and smooth in vain, as containing can with the look such as grey, yellow, brown during impurity. Outward appearance can be loose soil block shape and densifie state sillar shape according to origin cause of formation difference. Density 2.54-2.60g/cm3. Fusing point about 1785 DEG C. Having plasticity-, wet soil can be moulded different shape and unlikely fragmentation, and can remain unchanged for a long time.
Massfraction according to its quality, plasticity-and chiltern is divided into three types:
1, hard kaoline: matter is hard, without plasticity-, tool plasticity-after pulverizing fine grinding.
2, soft kaolin: matter is soft, plasticity-is relatively strong, chiltern massfraction < 50%;
3, sandy kaoline: matter is soft, plasticity-is more weak, chiltern massfraction > 50%.
3) Longshan albite 4#, Longshan albite 2#, dragon sea feldspar 1#, big level ground chicken girt, washing sand:
Albite (Albite) is the one of feldspar, is the aluminosilicate (NaAlSi of sodium3O8). Albite is generally glassy crystal, it is possible to be colourless, it is possibility to have white, yellow, red, green or black. It is the raw material manufacturing glass and pottery. The composition having albite in a lot of rock, people claim such mineral to be rock forming mineral. Albite: Na2O.Al2O3.6SiO2, wherein Na2Below O8%, K2O5-6%, Al2O3More than 16%, SiO270%, density 2.605g/cm3, Mohs' hardness is 6, triclinic(crystalline)system, and color is white, fusing point 1100 DEG C.
Wherein washing sand is by feldspar best in quality, through fragmentation, ball milling, sieve, the processes such as deironing becomes.
4) wilkinite:
Wilkinite (1.35��1.84g/cm3) be also otaylite or amargosite, is the moisture clay pit based on montmorillonite, and chemical molecular formula is: Nax (H2O)4(AI2-xMg0.83)Si4O10)(OH)2, the layered clay mineral being made up of two layers of silicon-oxy tetrahedron therebetween, one layer of alumina octahedral. Wilkinite can expand into pasty state after adding water, and has good water-swelling property and dispersion and suspension and pulping, directly introduces in formula and use.
Present invention also offers the technical process preparing anti-corrosion brick:
Electronic proportioning �� raw mill �� mud sieves �� mud is old �� mud sieves �� mud deironing �� mud is old �� slurry granulation �� powder sieves �� powder deironing �� powder is old �� powder sieves �� powder is shaping �� bad soma is dry �� bad face add wet �� execute cosmetic glaze �� ink jet printing �� bad body and dry �� execute anticorrosion glaze �� high-temperature calcination �� product deburring �� product and sort �� the examination and test of products-product warehousing.
Detecting according to GB/T4100-2006 GB, the folding strength of product of the present invention is more than 55Mpa; Can resistance to any strong acid except hydrofluoric acid; Can resistance to highly basic if organometallic thing and inorganic strong alkali are such as aminocompound; And specific absorption��0.05.
The useful effect of the present invention:
The present invention adopts the mine tailing in ZhangZhou, Fujian, soil property can prepare low water absorption by rational proportioning, glassy phase is few, crystalline phase is many and grows good high-strength ceramic base substrate, reduces acid-base material to the corrosive nature of stupalith. Anticorrosion ceramic body tool
There is following advantage:
1. the contact specific surface of acid-base material and ceramic body diminishes, thus reaches protective effect.
2. ceramic body has and grow good crystalline framework, not easily corroded by acid and alkali substance.
3. acid-alkali-corrosive-resisting, high strength, except the scope of existing use, expands field of employment.
4. reduce the calcium magnesia raw material of more use in architectural pottery Product Process, it is to increase the sial content in product, thus increase anticorrosion
Performance.
Embodiment
In order to make the technician of this area understand the technical scheme of the present invention better, below disclose further some unrestricted embodiments the present invention is described in further detail.
Embodiment 1
A kind of anti-corrosion brick, its adobe body comprises the raw material composition of following weight part number: ZhangZhou carclazyte 10 parts, under wear carclazyte 6 parts, Zhangpu soil 1#7 parts, water-washed kaoline 12 parts, washing 10 parts, sand, Longshan albite 4#3.5 parts, Longshan albite 2#10 parts, Changtai kaolin 2.0 parts, dragon sea feldspar 1#15 parts, greatly level ground chicken girt 15 parts, wilkinite 5 parts, Zhangpu soil 2#(dirt) 4 parts.
Embodiment 2
A kind of anti-corrosion brick, comprises brick idiosome and glaze, and its adobe body comprises the raw material composition of following weight part number: ZhangZhou carclazyte 10 parts, under wear carclazyte 6 parts, Zhangpu soil 1#7 parts, water-washed kaoline 12 parts, washing 10 parts, sand, Longshan albite 4#3.5 parts, Longshan albite 2#10 parts, Changtai kaolin 2.0 parts, dragon sea feldspar 1#15 parts, greatly level ground chicken girt 15 parts, wilkinite 5 parts, Zhangpu soil 2#(dirt) 4 parts;Its glaze comprises the raw material composition of following weight part number: TTKG55686 part, 5 parts, aluminum oxide, corundum (aluminum oxide (Al2O3) 7 parts, CMC (Xylo-Mucine) 0.3 part, STPP (industry tripoly phosphate sodium STPP) 0.7 part.
Its performance index of anti-corrosion brick provided by the present invention are as follows: (see table one)
Table one:
Embodiment 3
A kind of concrete steps preparing anti-corrosion brick described in embodiment 2 are:
A) material choice, according to embodiment 2, raw material and ratio thereof mix;
B) prepare burden, according to recipe requirements weigh batching (thin material deviation scope 30kg/ time);
C) ball milling, material: ball: water=1:1:0.8 ratio carries out tinning ball milling, 10��12 hours ball milling time, ball milling fineness 1.2%��1.8% (250 eye mesh screen);
D) preparing mud, mud is crossed after 80 orders sieve and is entered deironing system deironing, and after deironing, mud is stored in slurry bucket old for subsequent use;
E) spray pulverization, mud sieves spray pulverization after deironing, and it is old for subsequent use that powder enters powder material tank after screening out iron, powder lot humidity 6.0%��6.8%, and 40 order��20 order content are that 16%��25%, the 100 following content of order are less than 10%;
F) press brick, by old good powder evenly cloth in a mold, be pressed into ceramic body at a particular pressure;
G) dry, the brick suppressed enters dry kiln, is dried under the drying system of setting, and dried base substrate moisture content is less than 4%;
H) glazing, according to the processing parameter requirement of corresponding product, the glaze needed for preparation production, imposes on dried billet surface by glaze;
I) stamp, the billet surface printed patterns after glazing.
J) burn till, under 1220 degrees Celsius, ceramic body is carried out high temperature sintering;
K) edging, polishing, sorting, packing, warehouse-in, the work in-process after high temperature sintering are carried out surface finish process or edging, are divided into different mass grade, with after packed in cases be finished product warehouse-in.
The method of the present invention is described by better embodiment, and methods and applications as herein described obviously can be changed in content of the present invention, spirit and scope or suitably change and combination by related personnel, realize and apply the technology of the present invention. Those skilled in the art can use for reference content herein, and suitable improving technique parameter realizes. Special needs to be pointed out is, all similar replacements and change apparent to those skilled in the art, they are all deemed to be included in the present invention.
Claims (6)
1. an anti-corrosion brick, it is characterised in that: adobe body comprises the raw material composition of following weight part number: ZhangZhou carclazyte 8��12 parts, under wear carclazyte 4��8 parts, soil 1#3��10 part, Zhangpu, water-washed kaoline 10��15 parts, washing 8��12 parts, sand, albite 4#1��5 part, Longshan, albite 2#8��12 part, Longshan, Changtai kaolin 1��3 part, feldspar 1#12��18 part, dragon sea, big level ground chicken girt 12��18 parts, wilkinite 3��7 parts, soil 2#2��6 part, Zhangpu; Also being included on brick idiosome and execute one layer of glaze, described glaze comprises the raw material composition of following weight part number: TTKG55680��92 part, 3��7 parts, aluminum oxide, 4��10 parts, corundum, Xylo-Mucine 0.1��0.5 part, industry tripoly phosphate sodium STPP 0.3��1.0 part; Described TTKG556 is a kind of basis glaze, is made up of kaolin, silica powder, lithium porcelain stone powder, burning talcum, calcium carbonate, big level ground chicken girt, dragon sea feldspar in powder, Longshan potassium albite raw material, and its chemistry forms according to weight percent meter, comprises following composition:
2. anti-corrosion brick as claimed in claim 1, it is characterised in that its adobe body comprises the raw material composition of following weight part number: ZhangZhou carclazyte 10 parts, under wear carclazyte 6 parts, Zhangpu soil 1#7 part, water-washed kaoline 12 parts, washing 10 parts, sand, Longshan albite 4#3.5 part, Longshan albite 2#10 part, Changtai kaolin 2.0 parts, dragon sea feldspar 1#15 part, big level ground chicken girt 15 parts, wilkinite 5 parts, Zhangpu soil 2#4 part.
3. anti-corrosion brick as claimed in claim 1, described glaze comprises the raw material composition of following weight part number: TTKG55686 part, 5 parts, aluminum oxide, 7 parts, corundum, Xylo-Mucine 0.3 part, industry tripoly phosphate sodium STPP 0.7 part.
4. anti-corrosion brick as claimed in claim 1, the adobe body of described anti-corrosion brick, its chemistry composition, according to weight percent meter, comprises following composition:
5. anti-corrosion brick as claimed in claim 1, its chemistry composition of described anti-corrosion brick glaze, according to weight percent meter, comprises following composition:
6. prepare the arbitrary described anti-corrosion brick of claim 1-5 a method, its concrete steps are:
A) prepare burden, according to recipe requirements weigh batching;
B) ball milling, material: ball: the weight ratio between water is that 1:1:0.8 ratio carries out tinning ball milling, 10��12 hours ball milling time, ball milling fineness 1.2%��1.8%, 250 eye mesh screen;
C) preparing mud, mud is crossed after 80 orders sieve and is entered deironing system deironing, and after deironing, mud is stored in slurry bucket old for subsequent use;
D) spray pulverization, mud sieves spray pulverization after deironing, and it is old for subsequent use that powder enters powder material tank after screening out iron, and powder lot humidity weight content is 6.0%��6.8%, 40 order��20 object weight contents are that 16%��25%, the 100 following weight contents of order are less than 10%;
E) press brick, by old good powder evenly cloth in a mold, be pressed into ceramic body at a particular pressure;
F) dry, the brick suppressed enters dry kiln, is dried under the drying system of setting, and dried base substrate moisture content is less than 4%;
G) glazing, according to the processing parameter requirement of corresponding product, the glaze described in preparation, imposes on dried billet surface by glaze;
H) stamp, the billet surface printed patterns after glazing;
I) burn till, under 1220 degrees Celsius, ceramic body is carried out high temperature sintering.
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| CN201410591795.8A CN104355606B (en) | 2014-10-29 | 2014-10-29 | A kind of anti-corrosion brick |
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| CN201410591795.8A CN104355606B (en) | 2014-10-29 | 2014-10-29 | A kind of anti-corrosion brick |
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| CN104355606B true CN104355606B (en) | 2016-06-08 |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN105819825B (en) * | 2016-03-10 | 2018-04-06 | 万利(中国)有限公司 | A kind of large size ceramic decoration slab and Recipe |
| CN106220134A (en) * | 2016-07-14 | 2016-12-14 | 万利(中国)有限公司 | A kind of abnormity deck plate |
| CN107217808A (en) * | 2017-05-04 | 2017-09-29 | 万利(中国)有限公司 | A kind of structure and preparation technology for pushing glaze decorative brick aside |
| CN111533578B (en) * | 2020-07-08 | 2021-03-02 | 佛山市东鹏陶瓷发展有限公司 | Anti-corrosion glazed tile and preparation method thereof |
| CN112878338A (en) * | 2020-12-31 | 2021-06-01 | 中建八局第三建设有限公司 | Soil fixing structure for ecological restoration of steep soil slope |
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| WO2007024062A1 (en) * | 2005-08-25 | 2007-03-01 | Shin-A At Co., Ltd | Multifunctional ceramic compounds |
| CN102153336B (en) * | 2010-12-04 | 2013-05-15 | 黄俊杰 | Heat-resistant porcelain clay for manufacturing porcelain product and heat-resistant porcelain made from same |
| CN102976721B (en) * | 2012-11-09 | 2015-04-15 | 佛山欧神诺陶瓷股份有限公司 | Low-temperature sintered ceramic glazed tile and preparation method thereof |
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Effective date of registration: 20170801 Address after: The town of Fujian province 362200 Industrial Zone Jinjiang City Patentee after: Jinjiang, Fujian Province ten thousand Li Ci industry Co., Ltd Address before: 361009 Nanjing hi tech Industrial Park, Fujian, Zhangzhou Patentee before: MANLEY (CHINA) CO., LTD. |
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