CN104402402B - A kind of ultra-thin brick - Google Patents
A kind of ultra-thin brick Download PDFInfo
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- CN104402402B CN104402402B CN201410591830.6A CN201410591830A CN104402402B CN 104402402 B CN104402402 B CN 104402402B CN 201410591830 A CN201410591830 A CN 201410591830A CN 104402402 B CN104402402 B CN 104402402B
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Abstract
A kind of ultra-thin brick, is characterized in that: its adobe body comprises the raw material composition of following parts by weight: 8～11 parts of ZhangZhou carclazytes, under wear 4～8 parts of carclazytes, Zhangpu soil 1#4～8 parts, 6～15 parts of water-washed kaolines, 2～8 parts, talcum, 6～16 parts of washed-out sands, Longshan albite 4#2～5 parts, Longshan albite 2#5～12 parts, 1～4 part of Changtai kaolin, Longhai City's feldspar 1#10～16 parts, 11～18 parts of large level ground chicken girts, 6～12 parts of bentonites, Zhangpu soil 2#(dirt) 2～7 parts. The physical property of the ultra-thin brick preparing of the present invention is: thickness is about 3.5mm-4.1mm, water absorption rate is about 0%-0.1%, breakdown strength is greater than 800N, and the modulus of rupture is greater than 45MPa, significantly alleviated the brick of unit are weight, saved the energy, reduced cost of transportation.
Description
Technical field
The present invention relates to a kind of ultra-thin ceramic outside-wall brick and production method thereof.
Background technology
The production process of architectural pottery product need to consume inorganic mineral resources such as a large amount of clay and sandstone etc., raw material processing, moulding, dry and the operation such as burn till and need again to consume a large amount of energy, be a typical high energy consumption, high pollution and resource-hungry industry, brought very large pressure to resource and the energy-consuming of entire society. At present, from architectural pottery itself, the most effective energy-saving and emission-reduction method is to produce slim ceramic tile. The ceramic thin plate of producing thickness 3～6mm, weight per unit area is only 6～12kg/m2, can replace traditional wall, floor tile for spatial decoration. With the above thickness of traditional 7mm, weight per unit area exceedes the internal wall brick of 14kg/m2 to be compared, and can economize in raw materials 29～57%; With tradition 10～15mm thickness, the polishing floor tile that Unit Weight is 22～32kg/m2 is compared, and can economize in raw materials 60～73%. The ceramic product burning till as high temperature, the vast scale minimizing of weight per unit area means that water, electricity, fuel consumption and pollutant decline at double, synthesis energy saving, environment-friendly advantage are given prominence to, and promote greatly ceramic industry technology upgrading, have great economic benefit and social benefit.
The method of producing ultrathin ceramic bricks both at home and abroad has two kinds: shaping method to suppress and extrusion moulding, and they respectively have pluses and minuses, and wherein, shaping method to suppress is succeeded in developing by domestic relevant enterprise, is used for producing large-sized ceramic ceramic thin plate (brick). And extrusion moulding is mainly used to make ceramic thin plate, ceramic thin plate is also in research and development. In these methods, there are some common bottleneck problems: the one, the problem that base substrate strengthens, because the very thin green compact of needs just can burn till splits, therefore only adopt general ceramic raw materials formulation, the intensity of green compact can not meet transmission requirement, need to take measures, and strengthens blank strength. Due to ceramic tile attenuation, in compacting (extruding), transport, be dried, burn till and add and all need slow speed man-hour, ensureing that product is indeformable, do not ftracture, not damaged.
Prior art discloses some relevant documents, for example: the water absorption rate of the ultra-thin ceramic outside-wall brick of CN200710195163 report is 0%-0.1%, breakdown strength: 651N, the modulus of rupture: 65.9 (units), thickness: 3.5mm-4.6mm, but the breakdown strength of this brick is lower, do not possess wear-resisting, resistant and corrosion resistance.
Summary of the invention
This for prior art exist deficiency, the invention provides a high-intensity bad body of ceramic tile, described high-intensity bad body of ceramic tile only need adopt a small amount of reinforcing agent, adopts traditional shaping method to suppress, ensure product indeformable, do not ftracture, not damaged. Another object of the present invention is to provide a kind of breakdown strength large and possess the ultra-thin brick of wear-resisting, resistant, chemical resistance.
One aspect of the present invention provides a kind of ultra-thin brick, and described ultra-thin brick is made up of bad body of brick and glaze, it is characterized in that: its adobe body comprises the raw material composition of following parts by weight: 8～11 parts of ZhangZhou carclazytes, under wear 4～8 parts of carclazytes, Zhangpu soil 1#4～8 parts, 6～15 parts of water-washed kaolines, 2～8 parts, talcum, 6～16 parts of washed-out sands, Longshan albite 4#2～5 parts, Longshan albite 2#5～12 parts, 1～4 part of Changtai kaolin, Longhai City's feldspar 1#10～16 parts, 11～18 parts of large level ground chicken girts, 6～12 parts of bentonites, Zhangpu soil 2# (dirt) 2～7 parts.
In one embodiment, its adobe body of described ultra-thin brick comprises the raw material composition of following parts by weight: 9 parts of ZhangZhou carclazytes, under wear 6 parts of carclazytes, Zhangpu soil 1#6 parts, 10 parts of water-washed kaolines, 5 parts, talcum, 11 parts of washed-out sands, Longshan albite 4#3.5 parts, Longshan albite 2#8 parts, 2.5 parts of Changtai kaolin, Longhai City's feldspar 1#13 parts, 14 parts of large level ground chicken girts, 9 parts of bentonites, Zhangpu soil 2#(dirt) 4.5 parts.
In one embodiment, described its glaze of ultra-thin brick comprises that the raw material composition of following parts by weight: TORRECID-CNK00348 is 75～90 parts, 3～8 parts, aluminium oxide, 5～9 parts of glittering-jade glazes, 0.3～1.2 part of 0.1～0.5 part of CMC (sodium carboxymethylcellulose), STPP (industrial sodium phosphate trimer).
In one embodiment, described its glaze of ultra-thin brick comprises that the raw material composition of following parts by weight: TORRECID-CNK00348 is 80 parts, 5 parts, aluminium oxide, 7 parts of glittering-jade glazes, 0.8 part of 0.3 part of CMC (sodium carboxymethylcellulose), STPP (industrial sodium phosphate trimer).
Wherein, TORRECID-CNK00348 is a kind of parent glaze, be made up of raw materials such as kaolin, silica flour, lithium porcelain stone powder, burning talcum, calcium carbonate, large level ground chicken girt, Longhai City's feldspar in powder, Longshan potassium albites, its chemical composition, according to weight percent meter, comprises following composition:
Glittering-jade glaze is a kind of fritted glaze, formed by raw materials such as silica flour, lithium porcelain stone powder, kaolin, calcium carbonate, feldspar in powder, zirconium English powder, zinc oxide, potassium nitrate, sodium carbonate, according to a certain ratio, after mixing, form through 1200 DEG C of-1300 DEG C of melting quenchings of high temperature, its chemical composition, according to weight percent meter, comprises following composition:
In some embodiments, described its chemical composition of ultra-thin brick, according to weight percent meter, comprises following composition:
Its chemical composition of glaze, according to weight percent meter, comprises following composition:
The proportion material of invention product all derives from business procurement, the county wherein wear down, Zhangpu, Changtai etc. being Zhangzhou, Fujian. In the present invention, the chemical composition of following raw materials according is roughly:
1) ZhangZhou carclazyte, under wear carclazyte, Zhangpu soil 1#, Zhangpu soil 2# (dirt), water-washed kaoline:
A kind of clay is that very little (< 2 μ are plastic aluminium silicate salt m) for particle. Formed by multiple hydrosilicate and a certain amount of aluminium oxide, alkali metal oxide and alkaline earth oxide, and contain the impurity such as quartz, feldspar, mica and sulfate, sulfide, carbonate. The particle of clay mineral is tiny, is everlasting in colloid size range, is crystal or noncrystal, and great majority are sheets, and minority is tubulose, bar-shaped. After clay mineral water is moistening, there is plasticity, under less pressure, can be out of shape and can maintain the original state for a long time, and specific area is large, on particle with elecrtonegativity, therefore there are good physical adsorbability and chemical mobility of the surface, there is the ability with other cation exchange.
Be divided into following four classes by its structure:
Kaolinite family (TheKaoliniteGroup), 1:1 type;
Montmorillonite family (TheMontmorillonite/SmectiteGroup), 2:1 type;
Illite family (TheIllite (orTheClay-mica) Group), 2:1 type;
Chlorite family (TheChloriteGroup), 2:1:1 type,
Wherein water-washed kaoline is tonerde, through crushing and water washing, sieve, the processes such as deironing forms.
2) Changtai kaolin:
Be a kind of taking kaolinite family clay mineral as main clay and clay rock, its mineralogical composition is mainly by mineral compositions such as kaolinite, galapectite, hydromica, illite, montmorillonite and quartz, feldspars.
Physico-chemical property: how matt, when matter is pure, face is fine and smooth in vain, can be with ash, yellow, brown isochrome when impure. Outward appearance can be loose soil block shape and fine and close state sillar shape according to origin cause of formation difference. Density 2.54-2.60g/cm3. Approximately 1785 DEG C of fusing points. Have plasticity, wet soil can be moulded various shapes and unlikely fragmentation, and can remain unchanged for a long time.
Be divided into three types according to the mass fraction of its quality, plasticity and chiltern:
1, hard kaoline: matter is hard, without plasticity, tool plasticity after pulverizing fine grinding.
2, soft kaolin: matter is soft, plasticity is stronger, chiltern mass fraction < 50%;
3, sandy kaoline: matter is soft, plasticity a little less than, chiltern mass fraction > 50%.
3) Longshan albite 4#, Longshan albite 2#, the feldspar 1# of Longhai City, large level ground chicken girt, washed-out sand:
Albite (Albite) is the one of feldspar, is the aluminosilicate (NaAlSi of sodium3O8). Albite is generally glassy crystal, can be colourless, also can have white, yellow, red, green or black. It is to manufacture glass and ceramic raw material. The composition that has albite in a lot of rocks, people claim that such mineral are rock-forming mineral. Albite: Na2O.Al2O3.6SiO2, wherein Na2Below O8%, K2O5-6％，Al2O3More than 16%, SiO270%, density 2.605g/cm3, Mohs' hardness is 6, anorthic system, and color is white, 1100 DEG C of fusing points.
Wherein washed-out sand is by colory feldspar, through fragmentation, ball milling, sieve, the processes such as deironing forms.
4) bentonite:
Bentonite (1.35～1.84g/cm3) be also bentonite or amargosite, is that chemical molecular formula is: Nax (H taking montmorillonite as main moisture clay pit2O)4(AI2-xMg0.83)Si4O10)(OH)2, the layered clay mineral being formed by two-layer silicon-oxy tetrahedron therebetween one deck alumina octahedral. After bentonite adds water, can expand into pasty state, there is good water-swelling property and dispersion and suspension and pulping, directly introduce in formula and use.
The technological process of the ultra-thin brick of described preparation is as follows:
Electronic proportioning → sieve → mud of former abrasive lapping → mud is old → and sieve → slurry iron-removing → mud of mud is old → and sieve → powder of slurry granulation → powder deironing → powder is old → sieve → powder of powder moulding → compressing → body drying → base face humidification → execute cosmetic glaze → ink jet printing → base substrate to dry → execute the sort → examination and test of products-product warehousing of glittering-jade glaze → high-temperature calcination → product deburring → product. Sieve → glaze slip of weigh → glaze slip of glaze batching → glaze grinding → glaze slip is old → and glaze slip deironing → glaze slip sieves.
The present invention provides a kind of preparation method of ultra-thin brick on the other hand, and its concrete steps are:
A) batching, requires weigh batching (pure deviation range 30kg/ time) according to the formula of the ultra-thin brick described in first aspect present invention;
B) ball milling, material: ball: water=1:1:0.8 ratio is carried out tinning ball milling, Ball-milling Time 10～12 hours, ball milling fineness is 250 orders, tails over 1.2%～1.8%;
C) prepare mud, mud enters iron removal system deironing after crossing 80 mesh sieves, and after deironing, mud is stored in slurry bucket more than old 12 hours for subsequent use;
D) powder by spraying, the mud powder by spraying after deironing of sieving, it is old for subsequent use that powder enters powder material tank after screening out iron, and powder moisture content 6.0%～6.8%, 40 order～20 order content are that the following content of 16%～25%, 100 order is less than 12%;
E) press brick, by old good powder equably cloth in mould, under specified pressure, be pressed into ceramic body;
F) dry, the brick suppressing enters dry kiln, under the drying system of setting, is dried, and dried base substrate moisture content is less than 4%;
G) glazing, according to the technological parameter requirement of corresponding product, required glaze is produced in preparation, and glaze is imposed on to dried billet surface.
H) stamp, the billet surface printed patterns after glazing;
I) burn till, at 1200 DEG C-1300 DEG C, ceramic body is carried out to high temperature sintering;
J) edging, polishing, sorting, packing, warehouse-in, carries out surface finish processing or edging by the semi-finished product after high temperature sintering, is divided into different quality grade, with being finished product warehouse-in after packed in cases.
Due to choose reasonable and the proportioning of raw material of the present invention, only need to adopt a small amount of reinforcing agent, can make the ultra-thin brick preparing of the present invention have than the better physical property of general thin layer brick, be specially thickness and be about 3.5mm-4.1mm, water absorption rate is about 0%-0.1%, breakdown strength is greater than 800N, the modulus of rupture is greater than 45MPa, glaze anti-wear performance is more than 3 grades, 5 grades of resistances to soiling, chemical resistance is not less than GA level, 100 circulation flawlesses of frost resistance, and anti-glaze fragility 10KG depresses 2 hours flawlesses. Significantly alleviated the brick of unit are weight, saved the energy, reduced cost of transportation.
Detailed description of the invention
In order to make those skilled in the art understand better technical scheme of the present invention, below further disclose some unrestricted embodiment the present invention is described in further detail.
The formula material that invention is used is all to buy from the market.
Embodiment 1
1) batching: 9 parts of ZhangZhou carclazytes, under wear 6 parts of carclazytes, Zhangpu soil 1#6 parts, 10 parts of water-washed kaolines, 5 parts, talcum, 11 parts of washed-out sands, Longshan albite 4#3.5 parts, Longshan albite 2#8 parts, 2.5 parts of Changtai kaolin, Longhai City's feldspar 1#13 parts, 14 parts of large level ground chicken girts, 9 parts of bentonites, Zhangpu soil 2#(dirt) 4.5 parts, requires weigh batching (pure deviation range 30kg/ time) according to formula.
2) ball milling: material: ball: water=1:1:0.8 ratio is carried out tinning ball milling, Ball-milling Time 10～12 hours, ball milling fineness 1.2%～1.8% (250 eye mesh screen).
3) prepare mud: mud enters iron removal system deironing after crossing 80 mesh sieves, it is for subsequent use that after deironing, mud is stored in slurry bucket old (more than 12 hours).
4) powder by spraying: the mud powder by spraying after deironing of sieving, it is old for subsequent use that powder enters powder material tank after screening out iron, and powder moisture content 6.0%～6.8%, 40 order～20 order content are 16%～25%. The following content of 100 order is less than 12%.
5) press brick: by old good powder equably cloth in mould, under specified pressure, be pressed into ceramic body.
6) dry: the brick suppressing enters dry kiln, under the drying system of setting, be dried, dried base substrate moisture content is less than 4%.
7) glazing:
Preparation glaze: take TORRECID-CNK00348 and be 80 parts, 5 parts, aluminium oxide, 7 parts of glittering-jade glazes, 0.8 part of 0.3 part of CMC (sodium carboxymethylcellulose), STPP (industrial sodium phosphate trimer);
According to the technological parameter requirement of corresponding product, required glaze is produced in preparation,
Glaze is imposed on to dried billet surface.
Stamp, the billet surface printed patterns after glazing.
Burn till, at specific temperature, ceramic body is carried out to high temperature sintering.
After testing, the ultra-thin exterior wall tile that the thickness that obtains ceramic tile is 3.5mm, after testing, its water absorption rate is 0%, breakdown strength: 832N, the modulus of rupture: 65.9MPa.
Method of the present invention is described by preferred embodiment, and related personnel obviously can change methods and applications as herein described or suitably change and combination in content of the present invention, spirit and scope, realizes and apply the technology of the present invention. Those skilled in the art can use for reference content herein, suitably improve technological parameter and realize. Special needs to be pointed out is, all similar replacements and change apparent to those skilled in the artly, they are all deemed to be included in the present invention.
Claims (4)
1. a ultra-thin brick, described ultra-thin brick is made up of adobe body and glaze, it is characterized in that: its adobe body is made up of the raw material of following parts by weight: 8～11 parts of ZhangZhou carclazytes, under wear 4～8 parts of carclazytes, soil 1#4～8 part, Zhangpu, 6～15 parts of water-washed kaolines, 2～8 parts, talcum, 6～16 parts of washed-out sands, albite 4#2～5 part, Longshan, albite 2#5～12 part, Longshan, 1～4 part of Changtai kaolin, feldspar 1#10～16 part, Longhai City, 11～18 parts of large level ground chicken girts, 6～12 parts of bentonites, soil 2#2～7 part, Zhangpu, described its glaze of ultra-thin brick is made up of the raw material of following parts by weight: TORRECID-CNK00348 is 75～90 parts, 3～8 parts, aluminium oxide, 5～9 parts of glittering-jade glazes, 0.1～0.5 part of sodium carboxymethylcellulose, 0.3～1.2 part of industry sodium phosphate trimer, described TORRECID-CNK00348 is a kind of parent glaze, by kaolin, silica flour, lithium porcelain stone powder, burn talcum, calcium carbonate, large level ground chicken girt, Longhai City's feldspar in powder, Longshan potassium albite raw material composition, its chemical composition, according to weight percent meter, comprises following composition:
Described glittering-jade glaze is a kind of fritted glaze, formed by silica flour, lithium porcelain stone powder, kaolin, calcium carbonate, feldspar in powder, zirconium English powder, zinc oxide, potassium nitrate, sodium carbonate raw material, according to a certain ratio, after mixing, form through 1200 DEG C of-1300 DEG C of melting quenchings of high temperature, its chemical composition, according to weight percent meter, comprises following composition:
Described its chemical composition of ultra-thin brick, according to weight percent meter, comprises following composition:
2. ultra-thin brick as claimed in claim 1, is characterized in that its adobe body is made up of the raw material of following parts by weight: 9 parts of ZhangZhou carclazytes, under wear 6 parts of carclazytes, Zhangpu soil 1#6 part, 10 parts of water-washed kaolines, 5 parts, talcum, 11 parts of washed-out sands, Longshan albite 4#3.5 part, Longshan albite 2#8 part, 2.5 parts of Changtai kaolin, the feldspar 1#13 of Longhai City part, 14 parts of large level ground chicken girts, 9 parts of bentonites, Zhangpu soil 2#4.5 part.
3. ultra-thin brick as claimed in claim 1, described its glaze of ultra-thin brick is made up of the raw material of following parts by weight: TORRECID-CNK00348 is 80 parts, 5 parts, aluminium oxide, 7 parts of glittering-jade glazes, 0.3 part of sodium carboxymethylcellulose, 0.8 part of industrial sodium phosphate trimer.
4. prepare the method for the arbitrary described ultra-thin brick of claim 1-3, its concrete steps are:
Batching, the formula of ultra-thin brick according to claim 1 requires weigh batching, pure deviation range 30kg/ time;
Ball milling, material: ball: water=1:1:0.8 ratio is carried out tinning ball milling, Ball-milling Time 10～12 hours, ball milling fineness is 250 mesh screen residues 1.2%～1.8%;
Prepare mud, mud enters iron removal system deironing after crossing 80 mesh sieves, and after deironing, mud is stored in slurry bucket more than old 12 hours for subsequent use;
Powder by spraying, the mud powder by spraying after deironing of sieving, it is old for subsequent use that powder enters powder material tank after screening out iron, and powder moisture content 6.0%～6.8%, 40 order～20 order content are that the following content of 16%～25%, 100 order is less than 12%;
Press brick, by old good powder equably cloth in mould, under specified pressure, be pressed into ceramic body;
Dry, the brick suppressing enters dry kiln, under the drying system of setting, is dried, and dried base substrate moisture content is less than 4%;
Execute glaze claimed in claim 1, according to the technological parameter requirement of corresponding product, required glaze is produced in preparation, and glaze is imposed on to dried billet surface.
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| CN106673702A (en) * | 2016-12-11 | 2017-05-17 | 吴硕 | Silicon ceramic sheet and preparation method thereof |
| CN106673604B (en) * | 2016-12-24 | 2019-09-17 | 福建泉州顺盛达集团有限公司 | Environmentally-friendly multi-layer composite ceramic articles and preparation method thereof |
| CN107217808A (en) * | 2017-05-04 | 2017-09-29 | 万利(中国)有限公司 | A kind of structure and preparation technology for pushing glaze decorative brick aside |
| WO2019222953A1 (en) * | 2018-05-24 | 2019-11-28 | 湖州晶矽粉体材料有限公司 | Preparation method for inorganic filler powder without magnetic foreign matter, and inorganic filler powder prepared thereby and application thereof |
| CN112878338A (en) * | 2020-12-31 | 2021-06-01 | 中建八局第三建设有限公司 | Soil fixing structure for ecological restoration of steep soil slope |
| CN115536362B (en) * | 2022-09-21 | 2023-07-21 | 峨眉山金陶瓷业发展有限公司 | Mirror polished large-specification ultrathin ceramic rock plate and preparation method thereof |
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| CN102503576A (en) * | 2011-11-02 | 2012-06-20 | 广东博德精工建材有限公司 | Method for producing base coat being matched with blank and having excellent glazing effect |
| CN102976721B (en) * | 2012-11-09 | 2015-04-15 | 佛山欧神诺陶瓷股份有限公司 | Low-temperature sintered ceramic glazed tile and preparation method thereof |
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