CN104402402A - Ultra-thin brick - Google Patents
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- CN104402402A CN104402402A CN201410591830.6A CN201410591830A CN104402402A CN 104402402 A CN104402402 A CN 104402402A CN 201410591830 A CN201410591830 A CN 201410591830A CN 104402402 A CN104402402 A CN 104402402A
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Abstract
The invention relates to an ultra-thin brick which is characterized in that a brick blank is composed of the raw materials of, by weight, 8-11 parts of Zhangzhou clay, 4-8 parts of Xiadai clay, 4-8 parts of ZhangPu earth 1<#>, 6-15 parts of washed kaolin, 2-8 parts of talc, 6-16 parts of washed sand, 2-5 parts of Longshan albite 4<#>, 5-12 parts of Longshan albite 2<#>, 1-4 parts of Changtai kaolin, 10-16 parts of Longhai feldspar 1<#>, 11-18 parts of Daping stone grain, 6-12 parts of bentonite, and 2-7 parts of Zhangpu earth 2<#> (lime earth). The ultra-thin brick provided by the invention has the following physical properties: thickness is 3.5mm-4.1mm, water absorption rate is approximately 0-0.1%, breaking strength is greater than 800N, and modulus of rupture is greater than 45MPa. Therefore, unit-area brick weight is greatly reduced, energy is saved, and transportation cost is reduced.
Description
Technical field
The present invention relates to a kind of ultra-thin ceramic outside-wall brick and production method thereof.
Background technology
The production process of architectural pottery product needs to consume the inorganic Mineral resources such as a large amount of clays and sandstone, Feedstock treating, shaping, dry and the operation such as to burn till and need again to consume a large amount of energy, be a typical high energy consumption, high pollution and resource-hungry industry, bring very large pressure to the resource of entire society and energy expenditure.At present, from architectural pottery itself, the most effective energy-saving and emission-reduction method produces slim ceramic tile.Produce the ceramic thin plate of thickness 3 ~ 6mm, weight per unit area is only 6 ~ 12kg/m2, and conventional wall, floor tile can be replaced for spatial decoration.With traditional more than 7mm thickness, weight per unit area is compared more than the internal wall brick of 14kg/m2, can economize in raw materials 29 ~ 57%; With tradition 10 ~ 15mm thickness, unit weight is that the polishing floor tile of 22 ~ 32kg/m2 is compared, and can economize in raw materials 60 ~ 73%.As the ceramic product that high temperature burns till, the vast scale minimizing of weight per unit area means that water, electricity, fuel consumption and pollutent decline at double, synthesis energy saving, environment-friendly advantage are outstanding, promote ceramic industry technology upgrading greatly, have great economic benefit and social benefit.
The method of domestic and international production ultrathin ceramic bricks has two kinds: shaping method to suppress and extrusion moulding, and they respectively have relative merits, and wherein, shaping method to suppress is succeeded in developing by domestic relevant enterprise, is used for producing large-sized ceramic ceramic thin plate (brick).And extrusion moulding is mainly used to make ceramic thin plate, ceramic thin plate is also in research and development.In these methods, there are some common bottleneck problems: one is the problem that base substrate strengthens, because the very thin green compact of needs just can burn till splits, therefore general ceramic raw materials formulation is only adopted, the intensity of green compact can not meet transmission requirement, needs to take measures, and strengthens blank strength.Because ceramic tile is thinning, in compacting (extruding), transport, dry, burn till and add and all need slow speed man-hour, ensureing that product is indeformable, do not ftracture, not damaged.
Prior art discloses the document that some are relevant, such as: the water-intake rate of the ultra-thin ceramic outside-wall brick of CN200710195163 report is 0%-0.1%, strength at break: 651N, the modulus of rupture: 65.9 (units), thickness: 3.5mm-4.6mm, but the strength at break of this brick is lower, do not possess wear-resisting, resistant and erosion resistance.
Summary of the invention
This for prior art exist deficiency, the invention provides the ceramic tile bad body of a high strength, the ceramic tile bad body of described high strength only need adopt a small amount of toughener, adopts traditional shaping method to suppress, ensure product indeformable, do not ftracture, not damaged.Another object of the present invention is provide a kind of strength at break large and possess wear-resisting, resistant, chemical resistance ultra-thin brick.
One aspect of the present invention provides a kind of ultra-thin brick, and described ultra-thin brick is made up of brick bad body and glaze, it is characterized in that: its adobe body comprise following parts by weight raw material composition: ZhangZhou carclazyte 8 ~ 11 parts, under wear carclazyte 4 ~ 8 parts, Zhangpu soil 1
#4 ~ 8 parts, water-washed kaoline 6 ~ 15 parts, 2 ~ 8 parts, talcum, washed-out sand 6 ~ 16 parts, Longshan albite 4
#2 ~ 5 parts, Longshan albite 2
#5 ~ 12 parts, Changtai kaolin 1 ~ 4 part, Longhai City's feldspar 1
#10 ~ 16 parts, greatly level ground chicken girt 11 ~ 18 parts, wilkinite 6 ~ 12 parts, Zhangpu soil 2# (dirt) 2 ~ 7 parts.
In one embodiment, its adobe body of described ultra-thin brick comprise following parts by weight raw material composition: ZhangZhou carclazyte 9 parts, under wear carclazyte 6 parts, Zhangpu soil 1
#6 parts, water-washed kaoline 10 parts, 5 parts, talcum, washed-out sand 11 parts, Longshan albite 4
#3.5 parts, Longshan albite 2
#8 parts, Changtai kaolin 2.5 parts, Longhai City's feldspar 1
#13 parts, greatly level ground chicken girt 14 parts, wilkinite 9 parts, Zhangpu soil 2
#(dirt) 4.5 parts.
In one embodiment, described its glaze of ultra-thin brick comprises the raw material composition of following parts by weight: TORRECID-CNK00348 is 75 ~ 90 parts, 3 ~ 8 parts, aluminum oxide, glittering-jade glaze 5 ~ 9 parts, CMC (Xylo-Mucine) 0.1 ~ 0.5 part, STPP (industrial tripoly phosphate sodium STPP) 0.3 ~ 1.2 part.
In one embodiment, described its glaze of ultra-thin brick comprises the raw material composition of following parts by weight: TORRECID-CNK00348 is 80 parts, 5 parts, aluminum oxide, glittering-jade glaze 7 parts, CMC (Xylo-Mucine) 0.3 part, STPP (industrial tripoly phosphate sodium STPP) 0.8 part.
Wherein, TORRECID-CNK00348 is a kind of parent glaze, be made up of raw materials such as kaolin, silica powder, lithium porcelain stone powder, burning talcum, calcium carbonate, large level ground chicken girt, Longhai City's feldspar in powder, Longshan potassium albites, its chemical constitution, according to weight percent meter, comprises following composition:
Glittering-jade glaze is a kind of fritted glaze, be made up of raw materials such as silica powder, lithium porcelain stone powder, kaolin, calcium carbonate, feldspar in powder, zirconium English powder, zinc oxide, saltpetre, sodium carbonate, according to a certain ratio, form through high temperature 1200 DEG C-1300 DEG C melting quenchings after mixing, its chemical constitution, according to weight percent meter, comprises following composition:
In some embodiments, described its chemical constitution of ultra-thin brick, according to weight percent meter, comprises following composition:
Its chemical constitution of glaze, according to weight percent meter, comprises following composition:
The proportion material of invention product all derives from business procurement, wherein wears down, county that Zhangpu, Changtai etc. are Zhangzhou, Fujian.In the present invention, the chemical composition of following raw materials according is roughly:
1) ZhangZhou carclazyte, under wear carclazyte, Zhangpu soil 1#, Zhangpu soil 2# (dirt), water-washed kaoline:
A kind of clay is particle very little (<2 μm) plastic aluminium silicate salt.Be made up of multiple hydrosilicate and a certain amount of aluminum oxide, alkalimetal oxide and alkaline earth metal oxide, and containing the impurity such as quartz, feldspar, mica and vitriol, sulfide, carbonate.The particle of clay mineral is tiny, is everlasting within the scope of colloid size, and in crystal or noncrystal, great majority are sheets, and minority is tubulose, bar-shaped.After clay mineral water is moistening, there is plasticity-, can be out of shape under less pressure and can maintain the original state for a long time, and specific surface area is large, with electronegativity on particle, therefore there are good physical adsorbability and chemical mobility of the surface, there is the ability with other cationic exchange.
Following four classes are divided into by its structure:
Kaolinite race (TheKaoliniteGroup), 1:1 type;
Montmorillonite race (TheMontmorillonite/SmectiteGroup), 2:1 type;
Illite race (TheIllite (orTheClay-mica) Group), 2:1 type;
Chlorite race (TheChloriteGroup), 2:1:1 type,
Wherein water-washed kaoline is tonerde, through crushing and water washing, sieve, the processes such as deironing forms.
2) Changtai kaolin:
Be a kind of based on the clay of kaolinite race clay mineral and tonstein, its mineralogical composition is primarily of kaolinite, halloysite, hydromica, illite, montmorillonite and the mineral composition such as quartz, feldspar.
Physico-chemical property: how matt, when matter is pure, face is fine and smooth in vain, as can with ash, yellow, brown isochrome time impure.Outward appearance can be loose soil block shape and densifie state sillar shape according to origin cause of formation difference.Density 2.54-2.60g/cm3.Fusing point about 1785 DEG C.Have plasticity-, wet soil can be moulded different shape and unlikely fragmentation, and can remain unchanged for a long time.
Massfraction according to its quality, plasticity-and chiltern is divided into three types:
1, hard kaoline: matter is hard, without plasticity-, tool plasticity-after pulverizing fine grinding.
2, soft kaolin: matter is soft, plasticity-is comparatively strong, chiltern massfraction <50%;
3, sandy kaoline: matter is soft, plasticity-is more weak, chiltern massfraction >50%.
3) Longshan albite 4
#, Longshan albite 2#, Longhai City feldspar 1#, large level ground chicken girt, washed-out sand:
Albite (Albite) is the one of feldspar, is the aluminosilicate (NaAlSi of sodium
3o
8).Albite is generally glassy crystal, can be colourless, also can have white, yellow, red, green or black.It is the raw material manufacturing glass and pottery.Have the composition of albite in a lot of rock, people claim such mineral to be rock forming mineral.Albite: Na
2o.Al
2o
3.6SiO
2, wherein Na
2o less than 8%, K
2o 5-6%, Al
2o
3more than 16%, SiO
270%, density 2.605g/cm
3, Mohs' hardness is 6, triclinic(crystalline)system, and color is white, fusing point 1100 DEG C.
Wherein washed-out sand is by colory feldspar, through fragmentation, ball milling, sieve, the processes such as deironing.
4) wilkinite:
Wilkinite (1.35 ~ 1.84g/cm3) be also otaylite or amargosite, and be the moisture clay pit based on montmorillonite, chemical molecular formula is: Nax (H
2o)
4(AI2-xMg0.83) Si
4o
10) (OH)
2, the layered clay mineral be made up of two-layer silicon-oxy tetrahedron therebetween one deck alumina octahedral.Can pasty state be expand into after wilkinite adds water, there is good water-swelling property and dispersion and suspension and pulping, directly introduce in formula and use.
The technical process of the ultra-thin brick of described preparation is as follows:
Electronic proportioning → raw mill → mud sieves → and mud is old → mud sieves → slurry iron-removing → mud is old → slurry granulation → powder sieves → powder deironing → powder is old → powder sieves → powder is shaping → compression moulding → body drying → base face humidification → execute cosmetic glaze → ink jet printing → base substrate to dry → execute glittering-jade glaze → high-temperature calcination → product deburring → product and sort → the examination and test of products-product warehousing.Glaze batching → glaze weighs → and glaze slip grinding → glaze slip sieves → glaze slip is old → and glaze slip deironing → glaze slip sieves.
The present invention provides a kind of preparation method of ultra-thin brick on the other hand, and its concrete steps are:
A) prepare burden, the recipe requirements weigh batching (pure deviation range 30kg/ time) of ultra-thin brick described according to a first aspect of the present invention;
B) ball milling, material: ball: water=1:1:0.8 ratio carries out tinning ball milling, Ball-milling Time 10 ~ 12 hours, ball milling fineness is 250 orders, tails over 1.2% ~ 1.8%;
C) prepare mud, mud enters iron removal system deironing after crossing 80 mesh sieves, after deironing mud be stored in slurry bucket in old more than 12 hours for subsequent use;
D) spray pulverization, mud sieves spray pulverization after deironing, and it is old for subsequent use that powder enters powder material tank after screening out iron, powder lot humidity 6.0% ~ 6.8%, and 40 order ~ 20 order content are that the following content of 16% ~ 25%, 100 order is less than 12%;
E) press brick, by old good powder equably cloth in a mold, be pressed into ceramic body at a particular pressure;
F) dry, the brick suppressed enters dry kiln, and under the drying system of setting, carry out drying, dried base substrate moisture content is less than 4%;
G) glazing, according to the processing parameter requirement of corresponding product, the glaze needed for preparation production, imposes on dried billet surface by glaze.
H) stamp, the billet surface printed patterns after glazing;
I) burn till, at 1200 DEG C-1300 DEG C, high temperature sintering is carried out to ceramic body;
Work in-process after high temperature sintering are carried out surface finish process or edging by j) edging, polishing, sorting, packing, warehouse-in, are divided into different mass grade, with after packed in cases be finished product warehouse-in.
Due to choose reasonable and the proportioning of raw material of the present invention, only need adopt a small amount of toughener, the ultra-thin brick prepared of the present invention can be made to have the physicals better than general thin layer brick, be specially thickness and be about 3.5mm-4.1mm, water-intake rate is about 0%-0.1%, strength at break is greater than 800N, the modulus of rupture is greater than 45MPa, glaze paint wear resisting property more than 3 grades, resistance to soiling 5 grades, chemical resistance is not less than GA level, and frost resistance 100 circulation flawlesses, anti-glaze fragility 10KG depresses 2 hours flawlesses.Significantly alleviate the weight of the brick of unit surface, save the energy, decrease transportation cost.
Embodiment
In order to make those skilled in the art understand technical scheme of the present invention better, below disclose further some non-limiting embodiments the present invention is described in further detail.
Inventing the formula material used is all buy from the market.
Embodiment 1
1) prepare burden: ZhangZhou carclazyte 9 parts, under wear carclazyte 6 parts, Zhangpu soil 1
#6 parts, water-washed kaoline 10 parts, 5 parts, talcum, washed-out sand 11 parts, Longshan albite 4
#3.5 parts, Longshan albite 2
#8 parts, Changtai kaolin 2.5 parts, Longhai City's feldspar 1
#13 parts, greatly level ground chicken girt 14 parts, wilkinite 9 parts, Zhangpu soil 2
#(dirt) 4.5 parts, according to recipe requirements weigh batching (pure deviation range 30kg/ time).
2) ball milling: material: ball: water=1:1:0.8 ratio carries out tinning ball milling, Ball-milling Time 10 ~ 12 hours, ball milling fineness 1.2% ~ 1.8% (250 eye mesh screen).
3) prepare mud: mud enters iron removal system deironing after crossing 80 mesh sieves, after deironing mud be stored in slurry bucket in old (more than 12 hours) for subsequent use.
4) spray pulverization: mud sieves spray pulverization after deironing, and it is old for subsequent use that powder enters powder material tank after screening out iron, powder lot humidity 6.0% ~ 6.8%, and 40 order ~ 20 order content are 16% ~ 25%.The following content of 100 order is less than 12%.
5) press brick: by old good powder equably cloth in a mold, be pressed into ceramic body at a particular pressure.
6) dry: the brick suppressed enters dry kiln, under the drying system of setting, carry out drying, dried base substrate moisture content is less than 4%.
7) glazing:
Preparation glaze: take that TORRECID-CNK00348 is 80 parts, 5 parts, aluminum oxide, glittering-jade glaze 7 parts, CMC (Xylo-Mucine) 0.3 part, STPP (industrial tripoly phosphate sodium STPP) 0.8 part;
According to the processing parameter requirement of corresponding product, the glaze needed for preparation production,
Glaze is imposed on dried billet surface.
Stamp, the billet surface printed patterns after glazing.
Burn till, within specified temperatures high temperature sintering is carried out to ceramic body.
After testing, the thickness obtaining ceramic tile is the ultra-thin exterior wall tile of 3.5mm, and after testing, its water-intake rate is 0%, strength at break: 832N, the modulus of rupture: 65.9MPa.
Method of the present invention is described by preferred embodiment, and related personnel obviously can change methods and applications as herein described or suitably change and combination in content of the present invention, spirit and scope, realizes and applies the technology of the present invention.Those skilled in the art can use for reference present disclosure, and suitable improving technique parameter realizes.Special needs to be pointed out is, all similar replacements and change apparent to those skilled in the art, they are all deemed to be included in the present invention.
Claims (9)
1. a ultra-thin brick, described ultra-thin brick is made up of brick bad body and glaze, it is characterized in that: its adobe body comprise following parts by weight raw material composition: ZhangZhou carclazyte 8 ~ 11 parts, under wear carclazyte 4 ~ 8 parts, Zhangpu soil 1
#4 ~ 8 parts, water-washed kaoline 6 ~ 15 parts, 2 ~ 8 parts, talcum, washed-out sand 6 ~ 16 parts, Longshan albite 4
#2 ~ 5 parts, Longshan albite 2
#5 ~ 12 parts, Changtai kaolin 1 ~ 4 part, Longhai City's feldspar 1
#10 ~ 16 parts, greatly level ground chicken girt 11 ~ 18 parts, wilkinite 6 ~ 12 parts, Zhangpu soil 2# (dirt) 2 ~ 7 parts.
2. ultra-thin brick as claimed in claim 1, it is characterized in that its adobe body comprise following parts by weight raw material composition: ZhangZhou carclazyte 9 parts, under wear carclazyte 6 parts, Zhangpu soil 1
#6 parts, water-washed kaoline 10 parts, 5 parts, talcum, washed-out sand 11 parts, Longshan albite 4
#3.5 parts, Longshan albite 2
#8 parts, Changtai kaolin 2.5 parts, Longhai City's feldspar 1
#13 parts, greatly level ground chicken girt 14 parts, wilkinite 9 parts, Zhangpu soil 2
#4.5 part.
3. ultra-thin brick as claimed in claim 1, described its glaze of ultra-thin brick comprises the raw material composition of following parts by weight: TORRECID-CNK00348 is 75 ~ 90 parts, 3 ~ 8 parts, aluminum oxide, glittering-jade glaze 5 ~ 9 parts, Xylo-Mucine 0.1 ~ 0.5 part, industrial tripoly phosphate sodium STPP 0.3 ~ 1.2 part.
4. ultra-thin brick as claimed in claim 1, described its glaze of ultra-thin brick comprises the raw material composition of following parts by weight: TORRECID-CNK00348 is 80 parts, 5 parts, aluminum oxide, glittering-jade glaze 7 parts, Xylo-Mucine 0.3 part, industrial tripoly phosphate sodium STPP 0.8 part.
5. ultra-thin brick as claimed in claim 4, described TORRECID-CNK00348 is a kind of parent glaze, be made up of raw materials such as kaolin, silica powder, lithium porcelain stone powder, burning talcum, calcium carbonate, large level ground chicken girt, Longhai City's feldspar in powder, Longshan potassium albites, its chemical constitution, according to weight percent meter, comprises following composition:
6. ultra-thin brick as claimed in claim 4, described glittering-jade glaze is a kind of fritted glaze, be made up of raw materials such as silica powder, lithium porcelain stone powder, kaolin, calcium carbonate, feldspar in powder, zirconium English powder, zinc oxide, saltpetre, sodium carbonate, according to a certain ratio, form through high temperature 1200 DEG C-1300 DEG C melting quenchings after mixing, its chemical constitution, according to weight percent meter, comprises following composition:
7. ultra-thin brick as claimed in claim 1, described its chemical constitution of ultra-thin brick, according to weight percent meter, comprises following composition:
8. prepare the technique of the arbitrary described ultra-thin brick of claim 1-7, the technical process of the ultra-thin brick of described preparation is as follows:
Electronic proportioning → raw mill → mud sieves → and mud is old → mud sieves → slurry iron-removing → mud is old → slurry granulation → powder sieves → powder deironing → powder is old → powder sieves → powder is shaping → compression moulding → body drying → base face humidification → execute cosmetic glaze → ink jet printing → base substrate to dry → execute glittering-jade glaze → high-temperature calcination → product deburring → product and sort → the examination and test of products-product warehousing; Glaze batching → glaze weighs → and glaze slip grinding → glaze slip sieves → glaze slip is old → and glaze slip deironing → glaze slip sieves.
9. a preparation method for ultra-thin brick, its concrete steps are:
A) prepare burden, the recipe requirements weigh batching (pure deviation range 30kg/ time) of ultra-thin brick described according to a first aspect of the present invention;
B) ball milling, material: ball: water=1:1:0.8 ratio carries out tinning ball milling, Ball-milling Time 10 ~ 12 hours, ball milling fineness is 250 mesh screen residues 1.2% ~ 1.8%;
C) prepare mud, mud enters iron removal system deironing after crossing 80 mesh sieves, after deironing mud be stored in slurry bucket in old more than 12 hours for subsequent use;
D) spray pulverization, mud sieves spray pulverization after deironing, and it is old for subsequent use that powder enters powder material tank after screening out iron, powder lot humidity 6.0% ~ 6.8%, and 40 order ~ 20 order content are that the following content of 16% ~ 25%, 100 order is less than 12%;
E) press brick, by old good powder equably cloth in a mold, be pressed into ceramic body at a particular pressure;
F) dry, the brick suppressed enters dry kiln, and under the drying system of setting, carry out drying, dried base substrate moisture content is less than 4%;
G) glazing, according to the processing parameter requirement of corresponding product, the glaze needed for preparation production, imposes on dried billet surface by glaze.
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| CN201410591830.6A CN104402402B (en) | 2014-10-29 | 2014-10-29 | A kind of ultra-thin brick |
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| CN104402402B CN104402402B (en) | 2016-05-04 |
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| CN106673702A (en) * | 2016-12-11 | 2017-05-17 | 吴硕 | Silicon ceramic sheet and preparation method thereof |
| CN106673604A (en) * | 2016-12-24 | 2017-05-17 | 福建泉州顺盛达集团有限公司 | Environment-friendly multi-layer composite ceramic product and preparation method thereof |
| CN107217808A (en) * | 2017-05-04 | 2017-09-29 | 万利(中国)有限公司 | A kind of structure and preparation technology for pushing glaze decorative brick aside |
| CN111819161A (en) * | 2018-05-24 | 2020-10-23 | 浙江三时纪新材科技有限公司 | Preparation method of inorganic filler powder without magnetic foreign matters, inorganic filler powder prepared by preparation method and application of inorganic filler powder |
| CN112878338A (en) * | 2020-12-31 | 2021-06-01 | 中建八局第三建设有限公司 | Soil fixing structure for ecological restoration of steep soil slope |
| CN115536362A (en) * | 2022-09-21 | 2022-12-30 | 峨眉山金陶瓷业发展有限公司 | Mirror-polished large-size ultrathin ceramic rock plate and preparation method thereof |
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| CN102503576A (en) * | 2011-11-02 | 2012-06-20 | 广东博德精工建材有限公司 | Method for producing base coat being matched with blank and having excellent glazing effect |
| CN102976721A (en) * | 2012-11-09 | 2013-03-20 | 佛山欧神诺陶瓷股份有限公司 | Low-temperature sintered ceramic glazed tile and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN102503576A (en) * | 2011-11-02 | 2012-06-20 | 广东博德精工建材有限公司 | Method for producing base coat being matched with blank and having excellent glazing effect |
| CN102976721A (en) * | 2012-11-09 | 2013-03-20 | 佛山欧神诺陶瓷股份有限公司 | Low-temperature sintered ceramic glazed tile and preparation method thereof |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106673702A (en) * | 2016-12-11 | 2017-05-17 | 吴硕 | Silicon ceramic sheet and preparation method thereof |
| CN106673604A (en) * | 2016-12-24 | 2017-05-17 | 福建泉州顺盛达集团有限公司 | Environment-friendly multi-layer composite ceramic product and preparation method thereof |
| CN107217808A (en) * | 2017-05-04 | 2017-09-29 | 万利(中国)有限公司 | A kind of structure and preparation technology for pushing glaze decorative brick aside |
| CN111819161A (en) * | 2018-05-24 | 2020-10-23 | 浙江三时纪新材科技有限公司 | Preparation method of inorganic filler powder without magnetic foreign matters, inorganic filler powder prepared by preparation method and application of inorganic filler powder |
| CN112878338A (en) * | 2020-12-31 | 2021-06-01 | 中建八局第三建设有限公司 | Soil fixing structure for ecological restoration of steep soil slope |
| CN115536362A (en) * | 2022-09-21 | 2022-12-30 | 峨眉山金陶瓷业发展有限公司 | Mirror-polished large-size ultrathin ceramic rock plate and preparation method thereof |
| CN115536362B (en) * | 2022-09-21 | 2023-07-21 | 峨眉山金陶瓷业发展有限公司 | Mirror polished large-specification ultrathin ceramic rock plate and preparation method thereof |
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| Publication number | Publication date |
|---|---|
| CN104402402B (en) | 2016-05-04 |
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