CN104349840A - 脒基和胍基配合物,作为链转移聚合催化剂的应用及由此获得的长链醇 - Google Patents

脒基和胍基配合物,作为链转移聚合催化剂的应用及由此获得的长链醇 Download PDF

Info

Publication number
CN104349840A
CN104349840A CN201380029386.2A CN201380029386A CN104349840A CN 104349840 A CN104349840 A CN 104349840A CN 201380029386 A CN201380029386 A CN 201380029386A CN 104349840 A CN104349840 A CN 104349840A
Authority
CN
China
Prior art keywords
composition
bis
mol
metal
independently
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201380029386.2A
Other languages
English (en)
Chinese (zh)
Inventor
托拉尔夫·格罗斯
霍尔格·齐尔
瑞特·肯普
温菲尔德·克雷奇默
克里斯蒂安·哈布纳
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sasol Olefins and Surfactants GmbH
Original Assignee
Sasol Olefins and Surfactants GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sasol Olefins and Surfactants GmbH filed Critical Sasol Olefins and Surfactants GmbH
Publication of CN104349840A publication Critical patent/CN104349840A/zh
Pending legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/122Metal aryl or alkyl compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22Organic complexes
    • B01J31/2282Unsaturated compounds used as ligands
    • B01J31/2295Cyclic compounds, e.g. cyclopentadienyls
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/14Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • B01J31/143Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C11/00Aliphatic unsaturated hydrocarbons
    • C07C11/02Alkenes
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08Catalytic processes
    • C07C2/26Catalytic processes with hydrides or organic compounds
    • C07C2/32Catalytic processes with hydrides or organic compounds as complexes, e.g. acetyl-acetonates
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C31/00Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
    • C07C31/18Polyhydroxylic acyclic alcohols
    • C07C31/20Dihydroxylic alcohols
    • C07C31/202Ethylene glycol
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C31/00Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
    • C07C31/18Polyhydroxylic acyclic alcohols
    • C07C31/20Dihydroxylic alcohols
    • C07C31/2051,3-Propanediol; 1,2-Propanediol
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/003Compounds containing elements of Groups 4 or 14 of the Periodic Table without C-Metal linkages
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/28Titanium compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02Ethene
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/10Polymerisation reactions involving at least dual use catalysts, e.g. for both oligomerisation and polymerisation
    • B01J2231/12Olefin polymerisation or copolymerisation
    • B01J2231/122Cationic (co)polymerisation, e.g. single-site or Ziegler-Natta type
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/40Substitution reactions at carbon centres, e.g. C-C or C-X, i.e. carbon-hetero atom, cross-coupling, C-H activation or ring-opening reactions
    • B01J2231/46C-H or C-C activation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/70Oxidation reactions, e.g. epoxidation, (di)hydroxylation, dehydrogenation and analogues
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/70Oxidation reactions, e.g. epoxidation, (di)hydroxylation, dehydrogenation and analogues
    • B01J2231/76Dehydrogenation
    • B01J2231/766Dehydrogenation of -CH-CH- or -C=C- to -C=C- or -C-C- triple bond species
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/001General concepts, e.g. reviews, relating to catalyst systems and methods of making them, the concept being defined by a common material or method/theory
    • B01J2531/002Materials
    • B01J2531/007Promoter-type Additives
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B01J2531/46Titanium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B01J2531/48Zirconium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B01J2531/49Hafnium
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • C07C2531/22Organic complexes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/52Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from boron, aluminium, gallium, indium, thallium or rare earths

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CN201380029386.2A 2012-06-04 2013-06-03 脒基和胍基配合物,作为链转移聚合催化剂的应用及由此获得的长链醇 Pending CN104349840A (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP12004263.5 2012-06-04
EP12004263.5A EP2671639B1 (en) 2012-06-04 2012-06-04 Guanidinate complexes and their use as chain transfer polymerization catalysts
PCT/EP2013/001614 WO2013182290A1 (en) 2012-06-04 2013-06-03 Amidinate and guanidinate complexes, their use as chain transfer polymerization catalysts and long chain alcohols obtained by such process

Publications (1)

Publication Number Publication Date
CN104349840A true CN104349840A (zh) 2015-02-11

Family

ID=48570057

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201380029386.2A Pending CN104349840A (zh) 2012-06-04 2013-06-03 脒基和胍基配合物,作为链转移聚合催化剂的应用及由此获得的长链醇

Country Status (10)

Country Link
US (1) US9579640B2 (enExample)
EP (2) EP2671639B1 (enExample)
JP (1) JP2015525268A (enExample)
CN (1) CN104349840A (enExample)
BR (1) BR112014030113A2 (enExample)
CA (1) CA2874682A1 (enExample)
ES (1) ES2620287T3 (enExample)
PL (1) PL2671639T3 (enExample)
RU (1) RU2014149897A (enExample)
WO (1) WO2013182290A1 (enExample)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113784995B (zh) * 2019-05-31 2024-05-24 陶氏环球技术有限责任公司 单齿、双齿和四齿胍iv族过渡金属烯烃共聚催化剂

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2857423B1 (en) * 2013-10-07 2020-09-16 Arlanxeo Netherlands B.V. Catalyst system
ES2869308T3 (es) * 2013-12-19 2021-10-25 Dow Global Technologies Llc Complejo metal-ligando, catalizador de polimerización de olefina derivado del mismo y método de polimerización de olefina que utiliza el catalizador
EP3037437A1 (en) * 2014-12-23 2016-06-29 SABIC Global Technologies B.V. Process for the preparation of a polyolefin having one or multiple end-functionalized branches.
EP3093280A1 (en) 2015-05-13 2016-11-16 Sasol Performance Chemicals GmbH Process for the oligomerisation of olefins by coordinative chain transfer polymerisation and catalyst synthesis
AU2016260568A1 (en) * 2015-05-13 2017-11-30 Sasol Performance Chemicals Gmbh Process for the oligomerisation of olefins by coordinative chain transfer polymerisation
CN104857989B (zh) * 2015-05-27 2017-03-01 山西大学 一种双胍基铝金属催化剂及其制备方法和应用
ES2919998T3 (es) * 2016-03-31 2022-07-29 Dow Global Technologies Llc Un catalizador de polimerización de olefinas
US11939137B2 (en) 2018-11-30 2024-03-26 Dow Global Technologies Llc Flexible container with dispensing pump

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0329891A2 (en) * 1988-02-23 1989-08-30 Petrolite Corporation End-functionalized low molecular weight polymers of ethylene
CN102432700A (zh) * 2011-09-01 2012-05-02 山西大学 桥联双脒基钛金属催化剂及其制备方法和应用

Family Cites Families (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3419352A (en) 1964-12-02 1968-12-31 Continental Oil Co Process for producing alpha alumina monohydrate
US3641085A (en) 1969-05-01 1972-02-08 Continental Oil Co Oxidation of aluminum alkyls
US3660447A (en) 1969-07-18 1972-05-02 Ethyl Corp Process of oxidizing aluminum alkyls
PL276385A1 (en) 1987-01-30 1989-07-24 Exxon Chemical Patents Inc Method for polymerization of olefines,diolefins and acetylene unsaturated compounds
US5153157A (en) 1987-01-30 1992-10-06 Exxon Chemical Patents Inc. Catalyst system of enhanced productivity
US5043515A (en) * 1989-08-08 1991-08-27 Shell Oil Company Ethylene oligomerization catalyst and process
US5064802A (en) 1989-09-14 1991-11-12 The Dow Chemical Company Metal complex compounds
JP2545006B2 (ja) 1990-07-03 1996-10-16 ザ ダウ ケミカル カンパニー 付加重合触媒
US5721185A (en) 1991-06-24 1998-02-24 The Dow Chemical Company Homogeneous olefin polymerization catalyst by abstraction with lewis acids
US5502128A (en) 1994-12-12 1996-03-26 University Of Massachusetts Group 4 metal amidinate catalysts and addition polymerization process using same
FI102476B1 (fi) 1996-05-31 1998-12-15 Borealis As Uudet siirtymämetallikompleksit ja menetelmä niiden valmistamiseksi
JP3588665B2 (ja) * 1996-06-04 2004-11-17 東ソー株式会社 遷移金属錯体を用いたオレフィン重合触媒およびそれを用いたポリオレフィンの製造法
US5777120A (en) 1997-03-14 1998-07-07 University Of Iowa Research Foundation Cationic aluminum alkyl complexes incorporating amidinate ligands as polymerization catalysts
EP1377614A2 (en) * 2000-12-12 2004-01-07 Baker Hughes Incorporated Low molecular weight isotactic polypropylene polymers, copolymers and derivatives and materials prepared therewith
DE102004030080A1 (de) * 2004-06-22 2006-01-12 Sasol Germany Gmbh Verfahren zur Herstellung primärer langkettiger Alkohole
US20100209610A1 (en) * 2007-07-16 2010-08-19 Advanced Technology Materials, Inc. Group iv complexes as cvd and ald precursors for forming metal-containing thin films
US20130131294A1 (en) * 2011-11-21 2013-05-23 John R. Hagadorn Amidinate Catalyst Compounds, Process for Their Use and Polymers Produced Therefrom

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0329891A2 (en) * 1988-02-23 1989-08-30 Petrolite Corporation End-functionalized low molecular weight polymers of ethylene
CN102432700A (zh) * 2011-09-01 2012-05-02 山西大学 桥联双脒基钛金属催化剂及其制备方法和应用

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
MARZENA BLALEK: "Effect of Catalyst Composition on Chain-end Group of Polyethylene Produced by Salen-type Complexes of Titanium", 《JOURNAL OF POLYMER SCIENCE: PART A:POLYMER CHEMISTRY》, vol. 48, 31 December 2010 (2010-12-31) *
SCOTT COLLINS: "Polymerization catalysis with transition metal amidinate and related complexes", 《COORDINATION CHEMISTRY REVIEWS》, vol. 255, 27 July 2010 (2010-07-27) *
李志云,等: "高分子量端羟基聚乙烯及其嵌段共聚物的合成与表征", 《2010年全国高分子材料科学与工程研讨会》, 29 October 2010 (2010-10-29), pages 44 - 45 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113784995B (zh) * 2019-05-31 2024-05-24 陶氏环球技术有限责任公司 单齿、双齿和四齿胍iv族过渡金属烯烃共聚催化剂

Also Published As

Publication number Publication date
US20150148505A1 (en) 2015-05-28
BR112014030113A2 (pt) 2017-06-27
ES2620287T3 (es) 2017-06-28
US9579640B2 (en) 2017-02-28
PL2671639T3 (pl) 2017-07-31
JP2015525268A (ja) 2015-09-03
EP2671639B1 (en) 2017-01-11
EP2855015A1 (en) 2015-04-08
WO2013182290A1 (en) 2013-12-12
RU2014149897A (ru) 2016-08-10
EP2671639A1 (en) 2013-12-11
CA2874682A1 (en) 2013-12-12

Similar Documents

Publication Publication Date Title
CN104349840A (zh) 脒基和胍基配合物,作为链转移聚合催化剂的应用及由此获得的长链醇
US8399375B2 (en) Supported metallocene catalyst composition and a process for the preparation of polyolefin using the same
CN103492397B (zh) 吡啶基二氨基过渡金属络合物,其生产方法和用途
CN104955829B (zh) 配体化合物、用于烯烃低聚反应的催化剂体系及使用其的烯烃低聚方法
CN115803351B (zh) 减弱的混合催化剂
CN105722846B (zh) 配体化合物、用于烯烃低聚反应的催化剂体系及使用该催化剂体系的烯烃低聚方法
CN1561317A (zh) 链增长反应方法
CN103492398A (zh) 吡啶基二氨基过渡金属络合物,其生产方法和用途
CN105001255B (zh) [n,n,n,n]四齿配体第四副族过渡金属配合物及其制备方法和用途
CN107438616A (zh) 配体化合物,有机铬化合物,用于烯烃低聚的催化剂体系和使用其低聚烯烃的方法
JP6490226B2 (ja) オレフィンオリゴマー化反応用触媒システムおよびこれを用いたオレフィンオリゴマー化方法
JP6468539B2 (ja) オレフィンオリゴマーの製造方法
CN107207545B (zh) 配体化合物,低聚催化剂体系及使用其的烯烃低聚方法
CN106795229B (zh) 金属茂-负载型催化剂以及使用该催化剂制备聚烯烃的方法
CN104245712B (zh) 乙烯低聚方法
CN103254329B (zh) 水杨醛亚胺金属杂配体催化剂前体及其制备和应用
US20110294972A1 (en) Olefin Polymerization Catalysts
Rong et al. Insights into the Formation Process of Yttrium–Aluminum Bimetallic Alkyl Complexes Supported by a Bulky Phosphazene Ligand
JP2002519359A (ja) 1以上のシルセスキオキサン配位子を含有する金属錯体
CN102199170A (zh) 8-羟基喹啉类ivb族配合物及其制备方法与应用
CN115698102B (zh) 减弱的后茂金属催化剂
Gagieva et al. Ethylene polymerization using immobilized fluorine-containing bis-salicylidenimine-titanium complexes
US9856337B2 (en) Polymerization catalysts
US20180280951A1 (en) Process for the Oligomerisation of Olefins by Coordinative Chain Transfer Polymerisation
CN101817890B (zh) 一种负载型烯烃催化剂及制备与应用

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
AD01 Patent right deemed abandoned

Effective date of abandoning: 20180309

AD01 Patent right deemed abandoned