CN104262402B - 一种三维含锰配位聚合物及其制备方法 - Google Patents
一种三维含锰配位聚合物及其制备方法 Download PDFInfo
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- CN104262402B CN104262402B CN201410463651.4A CN201410463651A CN104262402B CN 104262402 B CN104262402 B CN 104262402B CN 201410463651 A CN201410463651 A CN 201410463651A CN 104262402 B CN104262402 B CN 104262402B
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- Prior art keywords
- manganese
- coordination polymer
- dimensional
- preparation
- polymer
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- 239000011572 manganese Substances 0.000 title claims abstract description 36
- 239000013256 coordination polymer Substances 0.000 title claims abstract description 28
- 229920001795 coordination polymer Polymers 0.000 title claims abstract description 28
- 229910052748 manganese Inorganic materials 0.000 title claims abstract description 27
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 title claims abstract description 25
- 238000002360 preparation method Methods 0.000 title claims abstract description 14
- 229920000642 polymer Polymers 0.000 claims abstract description 11
- 239000000126 substance Substances 0.000 claims abstract description 7
- QNRATNLHPGXHMA-XZHTYLCXSA-N (r)-(6-ethoxyquinolin-4-yl)-[(2s,4s,5r)-5-ethyl-1-azabicyclo[2.2.2]octan-2-yl]methanol;hydrochloride Chemical group Cl.C([C@H]([C@H](C1)CC)C2)CN1[C@@H]2[C@H](O)C1=CC=NC2=CC=C(OCC)C=C21 QNRATNLHPGXHMA-XZHTYLCXSA-N 0.000 claims abstract description 4
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims description 31
- 239000005711 Benzoic acid Substances 0.000 claims description 15
- 235000010233 benzoic acid Nutrition 0.000 claims description 15
- 239000002904 solvent Substances 0.000 claims description 14
- 150000002696 manganese Chemical class 0.000 claims description 8
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 claims description 6
- 230000015572 biosynthetic process Effects 0.000 claims description 6
- 239000013110 organic ligand Substances 0.000 claims description 6
- 230000004044 response Effects 0.000 claims description 6
- 229910021380 Manganese Chloride Inorganic materials 0.000 claims description 4
- GLFNIEUTAYBVOC-UHFFFAOYSA-L Manganese chloride Chemical compound Cl[Mn]Cl GLFNIEUTAYBVOC-UHFFFAOYSA-L 0.000 claims description 4
- 235000002867 manganese chloride Nutrition 0.000 claims description 4
- 239000011565 manganese chloride Substances 0.000 claims description 4
- 229940099607 manganese chloride Drugs 0.000 claims description 4
- MIVBAHRSNUNMPP-UHFFFAOYSA-N manganese(2+);dinitrate Chemical compound [Mn+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O MIVBAHRSNUNMPP-UHFFFAOYSA-N 0.000 claims description 4
- 238000010438 heat treatment Methods 0.000 claims description 2
- 229940099596 manganese sulfate Drugs 0.000 claims description 2
- 235000007079 manganese sulphate Nutrition 0.000 claims description 2
- 239000011702 manganese sulphate Substances 0.000 claims description 2
- SQQMAOCOWKFBNP-UHFFFAOYSA-L manganese(II) sulfate Chemical compound [Mn+2].[O-]S([O-])(=O)=O SQQMAOCOWKFBNP-UHFFFAOYSA-L 0.000 claims description 2
- 230000035484 reaction time Effects 0.000 claims description 2
- 238000010583 slow cooling Methods 0.000 claims description 2
- 239000007788 liquid Substances 0.000 claims 1
- 150000002697 manganese compounds Chemical class 0.000 claims 1
- 238000000034 method Methods 0.000 abstract description 7
- 239000013078 crystal Substances 0.000 abstract description 5
- 238000006555 catalytic reaction Methods 0.000 abstract description 2
- 230000007547 defect Effects 0.000 abstract description 2
- 238000004020 luminiscence type Methods 0.000 abstract description 2
- 238000000926 separation method Methods 0.000 abstract description 2
- ZHNUHDYFZUAESO-UHFFFAOYSA-N Formamide Chemical compound NC=O ZHNUHDYFZUAESO-UHFFFAOYSA-N 0.000 description 8
- 125000004429 atom Chemical group 0.000 description 6
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 3
- 239000003446 ligand Substances 0.000 description 3
- 125000004430 oxygen atom Chemical group O* 0.000 description 3
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- JTMWVTWRWHMERP-UHFFFAOYSA-N 4-(4H-imidazol-5-yl)benzoic acid Chemical compound N=1C=NCC=1C1=CC=C(C(=O)O)C=C1 JTMWVTWRWHMERP-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 150000001875 compounds Chemical group 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- -1 rare earth ion Chemical class 0.000 description 1
- 229910052761 rare earth metal Inorganic materials 0.000 description 1
- 239000011435 rock Substances 0.000 description 1
- 125000004434 sulfur atom Chemical group 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F13/00—Compounds containing elements of Groups 7 or 17 of the Periodic Table
- C07F13/005—Compounds without a metal-carbon linkage
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B2200/00—Indexing scheme relating to specific properties of organic compounds
- C07B2200/13—Crystalline forms, e.g. polymorphs
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
Abstract
Description
Claims (6)
Priority Applications (1)
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CN201410463651.4A CN104262402B (zh) | 2014-09-13 | 2014-09-13 | 一种三维含锰配位聚合物及其制备方法 |
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CN201410463651.4A CN104262402B (zh) | 2014-09-13 | 2014-09-13 | 一种三维含锰配位聚合物及其制备方法 |
Publications (2)
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CN104262402A CN104262402A (zh) | 2015-01-07 |
CN104262402B true CN104262402B (zh) | 2016-08-24 |
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CN201410463651.4A Expired - Fee Related CN104262402B (zh) | 2014-09-13 | 2014-09-13 | 一种三维含锰配位聚合物及其制备方法 |
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Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
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CN106349484B (zh) * | 2016-08-16 | 2019-06-18 | 南京科技职业学院 | 一种锰三维配位聚合物及其制备方法 |
CN110157003B (zh) * | 2019-05-27 | 2021-09-14 | 阜阳师范学院 | 一种4-(1-(羧亚甲基)-1h-咪唑-4-基)苯甲酸锌晶态材料、制备方法和应用 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1232526C (zh) * | 2003-11-21 | 2005-12-21 | 南开大学 | 自由基-金属配合物型分子铁磁体和制备方法 |
CN101397310A (zh) * | 2008-10-29 | 2009-04-01 | 沈阳化工学院 | 一种三维结构异金属配位聚合物及其制备方法 |
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2014
- 2014-09-13 CN CN201410463651.4A patent/CN104262402B/zh not_active Expired - Fee Related
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1232526C (zh) * | 2003-11-21 | 2005-12-21 | 南开大学 | 自由基-金属配合物型分子铁磁体和制备方法 |
CN101397310A (zh) * | 2008-10-29 | 2009-04-01 | 沈阳化工学院 | 一种三维结构异金属配位聚合物及其制备方法 |
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C41 | Transfer of patent application or patent right or utility model | ||
CB03 | Change of inventor or designer information |
Inventor after: Zhang Yuling Inventor before: Liu Guozheng Inventor before: Duan Da |
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TA01 | Transfer of patent application right |
Effective date of registration: 20160624 Address after: Changyuan County of Xinxiang City, Henan Province town village 453411 full Chen east two street 9 No. 95 group Applicant after: Zhang Yuling Address before: North shore village Huang Town Village 518104 ring of Guangdong province Dongguan City Road No. 17 Applicant before: Liu Guozheng |
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